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By X. Xie

The dissolution behavior of palladium powder in thiourea solutions has been studied. The variables studied included temperature, stirring speed, and concentrations of thiourea, acid and ferric ion. Palladium was found to be soluble in thiourea solutions in the presence of an oxidant such as ferric ion. The dissolution of palladium in thiourea solutions was found to be chemical reaction controlled with an apparent activation energy of about 2S.3 kJ/mol.

Jan 1, 1995

By X. Shi, F. -Y. Wang

Automation and robotics are the keys to new intelligent autonomous mining systems that can remove operators from hazardous and stressful mining environments and provide the tools for greater productivity. This paper presents the components necessary for an Intelligent Task Control System (ITCS) for machine control in dynamic unstructured mining environments. In particular, the design details of a controller for an automated excavator are developed. The excavator controller uses fuzzy logic to interpret forces and torques gathered from a wrist mounted force/ torque sensor during the excavation process. This approach enables the transfer of human heuristics and expert knowledge to the controller. Several excavation tests using the fuzzy logic controller are described. These experimental results represent the first step toward an integrated approach that uses force/torque, vision and other sensor data to perform generic tasks in uncertain mining environments.

Jan 1, 1995

By G. A. Goller, Y. C. Lo

Microscale studies involving an ultrafast load cell have been shown to provide direct and accurate measurements of particle strength, particle fracture energy and particle breakage functions under different loading geometry conditions. The effect of grinding media size, shape, density and surface properties on the energy efficiency can be quantitatively determined for different materials to be ground. The applications of microscale comminution studies have been demonstrated to provide good predictions of grinding mill performance with different grinding media.

Jan 1, 1995

By F. W. Petersen

In the precious metal industry, activated carbon is used extensively for the recovery of gold and silver from cyanide solutions, particularly from slimy pulps and unclarified solutions. However, carbon can easily become fouled by inert particles in the pulp, thus decreasing the activity or gold loading of the carbon. This paper attempts to quantify the distribution of fine inert particles in activated carbon. Furthermore, a possible mechanism for the intrusion of fines will be postulated. Precipitated silica and ground silica sand were used to simulate pulp conditions and their loadings on activated carbon were determined by ashing. The kinetics of intrusion of fines into the pores of carbon were relatively fast, and were dependent on the concentration in the pulp. Results indicated that particle size of the solids and zeta potential of the fines influenced the loading of inert species on carbon. Scanning electron microscopy and secondary ion mass spectrometry showed a decrease in solids concentration to the centre of the carbon particle.

Jan 1, 1995

By J. G. Groppo

In 1992, 48 million tons of fly ash (not including bottom ash, boiler slag and FGD material) was produced in the United States, according to the American Coal Ash Association. Of this amount, 27.2% was utilized; although the percentage of fly ash utilized increased from 20% in 1980, there is significant potential to increase utilization. One of the primary driving forces behind increased utilization is increased disposal costs due to more stringent environmental controls and regulation. Fly ash is classified as a natural pozzolan and finds significant use as a cement additive. It has been found to increase the plasticity of the cement mixture while lowering the amount of mix water needed. In addition to improving leveling and finishing properties, fly ash improves pumpability as well as decreases the heat of hydration of the concrete mix which is particularly important in massive concrete structures such as dams where the concrete needs to cool as quickly as possible. The Loss on Ignition (LOI) of fly ash is an important quality when considering utilization. The LOI is primarily due to the presence of unburned carbon and the standard specifications for the use of fly ash as a mineral admixture in Portland cement concrete are given in ASTM C618-89a. which sets an LOI limit of 6%. However, many states have set a more stringent limit of 3%. The primary reason for the lower LOI specification is that carbon adsorbs air entraining agents which limits freeze-thaw resistance. This is particularly important in climates such as the midwestern US where multiple cycles of freezing and thawing are typical in winter.

Jan 1, 1995

By R. S. Mateer

Linear programming on desktop computers is commonly used to optimize coal blending proportions. The objective function is usually the cost of the blend. The constraints consist of materials and heat balances as expressed as linear functions of the blend. This is illustrated in Example 1. Inclusion of a sulfur compliance constraint in more complex because the maximum permitted sulfur percentage is not a pre-specified constant. Rather, it is a function of the calorific power of the blend itself. The current limit of 1.2 pounds of sulfur dioxide per million Btu may be expressed as: [Sulfur Max%= 0.6 . Hl10,OOO with H in Btu/lb.] A proper constraint equation may be formed by defining for each coal a function that is the difference between the actual sulfur percentage and the maximum sulfur percentage. This may be regarded us an excess sulfur percentage. For Coal A of Example 1. this would be: [ Sulfur Excess%=0.5-0.6 13,000/10,000=-0.28] This value would be used as the coefficient of the weight proportions of this coal in the blend. The complete constraint equation would then be the sum of such terms for each coal set less than or equal to zero. This is illustrated in Example II. [ ]

Jan 1, 1995

By M. L. Free

Several studies of the fluorite/oleate flotation system have shown that under certain conditions calcium dioleate is formed at or transported to the fluorite surface. Adsorption of significant amounts of calcium dioleate is generally observed above oleate concentrations of -6 -5 between 4 x 10 and 4 x 10 M, yet little explanation of the onset of calcium dioleate adsorption is provided. In this study in-situ and ex-situ FTIR/IRS experiments have been performed in connection with thermodynamic solution phase analysis to better understand oleate adsorption as well as the onset of calcium dioleate formation. Results from this study are analyzed and compared to industrial practice.

Jan 1, 1995

By J. J. Gusek

The Riley Pass strip mine is an abandoned uranium-bearing lignite deposit in Harding County, South Dakota, covering about 150 acres of highwalls, pit floor and mine spoils exhibiting elevated levels of radioactivity. Six reclamation design alternatives were developed, ranging from doing nothing to reclaiming to approximate original con-tour. The alternatives were evaluated for expense, site stabilization, and mitigation of public safety hazards. A comparative economic evaluation on three of the alternatives was completed for the Forest Service in selecting an alternative and substantiating federal funding requests. This evaluation included economic impacts associated with physical and radiologic health hazards, affects on recreational users, socioeconomic impacts and environmental improvement.

Jan 1, 1995

By R. M. Carland, F. F. Aplan

Six natural zeolites were evaluated for their ability to selectively remove heavy metal cations from solution. Ion selectivity was found to be Pb+2>Zn+2>Ni+2 and Cu+2>Co+2 from their respective solutions. The presence of K+, Ca+2 and Mg+2 in the actual waters to be used may seriously interfere with the ion exchange and elution of cations from zeolites. Zeolites were found not to be effective in removing precious metals from their cyanide solutions.

Jan 1, 1995

By Q. Lin, D. Z. Wang

Molecular design plays an important role in development of new flotation reagents. Group electronegativity calculation is a main method of molecular design. It is commonly used in calculating the hydrophilic-hydrophobic balance of reagents, particularly in designing chain length of flotation reagents for located minerals. But there is a limit to group electronegativity method. The method can only apply to those of [Ø]known straight-chain compounds ([Ø] is the hydrophobic energy of each -CH2- , determined by experiment). In this Paper, we propose another new calculation method: fragment method of flotation reagent. The method could be used as a supplement of group electronegativity method to design and calculate flotation reagents without any limitation. With the fragment method, we can calculate the hydrophilic-hydrophobic performance of any known or unknown reagents including those complicate structure compounds such as cyclic, branch, heterocyclic and so on by summing the appropriate structural elements (fragment). The principle, calculation stages and some results of designing new-type flotation reagents by fragment method are presented in this paper.

Jan 1, 1995

By J. Burgess Winter

It is an honor to present the lecture in honor of Daniel C. Jackling, the developer of the technology of copper mining that we continue to use 100 years later. He made a dramatic breakthrough in the early part of this century in the development of bulk-mining methods for large, low-grade porphyry copper-sulfide ore bodies. At Magma Copper, we are particularly proud that the Jackling Award states we have "made significant contributions to technical progress." Before Jackling's time, copper mining had exploited with primitive equipment very high-grade underground ore bodies and high-grade open pits. During the 20th century, the situation changed. Three significant innovations occurred within about 10 years around the turn of the century. In 1903, Jackling's concept of large-scale mining with steam shovels and rail haulage was implemented at the Bingham Canyon mine in Utah. Eighty years after the introduction of rail haulage, the mine converted to truck haulage with large-capacity high-efficiency haul trucks and reduced the stripping ratio from 3.5:1 to less than 1:1.

Jan 1, 1995

By C. B. Queja

Flexible synthetic membrane liners have become a standard facet to copper and gold heap leach pad design. While gold heap leach operations have utilized most types of synthetic liners, copper leach operations have commonly only been lined with polyethylene. The objective of this study was to determine if there are any chemical reasons why other synthetic membrane types could not be used to line a copper heap leach facility. With engineered consideration, the flexible membrane liner under the ore pile serves two purposes. The first provides a near impermeable boundary which aides greatly in the collection of the metal laden process solution. The second advantage to the flexible membrane is the almost non-permeable barrier to benefit increased environmental awareness that has led to an increase in solution containment technology. The Environmental Protection Agency (EPA) has developed a compatibility test for solutions and membrane liners. The EPA Method 9090 is intended for use in determining the chemical effects of a solution on the physical properties of the flexible membrane liner material intended to contain them. Data from these tests would assist in deciding whether a given liner material is acceptable for the intended application.

Jan 1, 1995

By M. Jaramillo

The Expanded West Pit of the 15 MTY El Cerrejon Mine will reach a maximum depth of270 m. Slope stability evaluations indicated that this depth, combined with structural complexities, would create a serious risk of footwall instability. Stabilization call for anchoring the footwall by installation of cable bolts, 9 to 33 m long, of multi-strand steel cable. For each of the 15 m high mining benches, a row of bolts is installed with variable horizontal spacing, depending on dip magnitude. Cable bolting is now standard operating practice and 11800 bolts will have been installed during the life of the mine.

Jan 1, 1995

By Li Honggui, Liu Maosheng, Zhao Zhongwei, Sun Peimci, Li Yunjiao

Leaching of Shizhuyuan low-grade refractory tungsten ore was carried out in a mechanically activating reactor. The effect of experimental parameters-temperature, amount of Na2C03, addition of NaOH, ratio of liquid to solid and leaching time - on the recovery of WO3 was studied. The WO3 recovery up to 96.99% have been achieved when the tungsten ore was digested by soda not more than three times the stoichiometric amount at 185-195°C for 1 .O-2.0 hours. Iso-extraction countour diagrams were drawn to illustrate the effect of various parameters on leaching. The WO3 recovery could be expected to increase 10-15% compared to that of conventional soda autoclave process.

Jan 1, 1995

By Joe Scheuering, Don Poulter, John Trirnble

Closure of the Grey Eagle Mine tailings impoundment is an example of closing a "wet" tailings impoundment at the cessation of milling operations. This paper presents a summary of tailings cover design and construction, tailings deposition sequences to facilitate closure, construction schedules, costs, and post-closure monitoring. Permit requirements which influenced the design and construction of the tailings are summarized. The performance of the cover and post-closure monitoring issues are also discussed.

Jan 1, 1995

By Ross R. Bhappu

In 1989, William A. Vogely created the Mineral Economics and Management Society (MEMS). He did this after SME disbanded the Minerals Resource Management Committee, a group dedicated to technical programming of minerals economics and management issues. A few years later, SME reinstated this committee. MEMS held its fourth annual conference "Mineral resources: Managing dilemmas and opportunities," in Boulder, CO March 9-11, 1995. Some of the MEMS programs are similar to the Minerals Resource Management Committee programs. However, MEMS conferences cover more diverse issues. These include minerals policy, environmental legislation impacts on the minerals industry and minerals economics issues. The 1995 MEMS conference included six sessions and three distinguished speaker addresses. Papers topics included US and Canadian mineral policy, financial strategies for managing mining companies, Latin American mineral investment opportunities, quantitative economic modeling and the impact of environmental interest groups on the minerals sector in the United States and Canada. One session was dedicated to students who competed for $1900 in prizes for outstanding papers.

Jan 1, 1995

By G. S. Dobby

The Cu-Au flotation cleaning circuit at Freeport Indonesia consists of three stages: two flotation column stages, in series, followed by one stage of mechanical cells. Concentrate from both column stages is combined as final concentrate. The mechanical cell stage has two parallel rows of seven Wemco 500's. The Wemco concentrate is recycled to feed of the second column stage and Wemco tails report to final tailings. This paper examines cleaner circuit performance, focusing on size-by-size performance of the individual stages and the individual mineral groups -copper sulfides, gold and in sol minerals. The recovery mechanisms of insol minerals are examined.

Jan 1, 1995

By B. C. Paul, R. Q. Honaker, K. Ho

Recent research has shown that froth flotation is not effective at treating fine coals (-28 mesh) containing a large portion of middling particles. Due to their relatively large density differences, middling particles can be separated more efficiently using gravity-based processes. The ability of gravity separators to treat fine particles has been limited by the lack of particle inertia relative to the surface drag forces. However, particle inertia can be enhanced by the application of a centrifugal field. A commercial-scale centrifugal Falcon concentrator capable of treating a mass flow rate of greater than 1 tph continuously has been used to evaluate its feasibility for treating fine coal as an alternative to froth flotation. Tests conducted on a -28 mesh fine coal circuit feed have found the Falcon concentrator to be very effective at cleaning the 28 x 325 mesh size fraction. For an Illinois No. 5 coal sample, the ash content was reduced in the 100 x 325 mesh size fraction from about 18% to 8% while achieving a high combustible recovery value of nearly 97%. In addition, the total sulfur content was substantially decreased from 2.6% to 1.7%. The effects of the critical operating parameters on separation performance have been studied and their values optimized.

Jan 1, 1995

By Michael Fahey, Ravi M. Damodaran, Brij M. Moudgil

The flotation behavior of Florida phosphates was studied using statistical design of experiments to evaluate conditioning parameters and their effect on flotation performance. The solids loading, conditioning time and agitation speed during conditioning were identified as the important variables affecting the reagent coating onto particles. Flotation of the conditioned slurry was carried out at fixed collector dosage and flotation conditions. Phosphate recovery upon flotation was statistically modelled as a function of the conditioning variables. The results indicated that the conditioning variables had an interactive effect on the phosphate flotation performance. Statistical optimization revealed two conditioning regimes in which optimum flotation recovery was obtained. It was determined that optimal recovery can be obtained at lower conditioning energies.

Jan 1, 1995

By B. Govindarajan, T. C. Rao, J. P. Barnwal

A simple modelling methodology has been proposed to predict the performance of industrial coal flotation circuit based on the observations made on the actual performance. The solid content in the tailings of the coal flotation circuit has been identified as a lode-star to predict the performance in terms of yield and ash content of the concentrate. The modelling parameters are directly measurable.

Jan 1, 1995