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By Y-B Kang, J H. Park, J Park

In order to understand the effect of oxygen injection into the molten metal on the valuable metals (VM) recovery and interfacial phenomena, several high-temperature experiments were conducted using a high-frequency induction furnace with a quartz tube as the reaction chamber at 1673 K. Copper-based waste printed circuit board (PCB) that contains some impurities was selected as the end-of-life resource. CaO-SiO2 based pre-fused slag and oxygen gas were used in present works. The composition change and microstructure of the samples were analysed. As oxygen was injected into the system, impurities were rapidly removed. After the removal of impurities, continuously injected oxygen lowered interfacial tension between liquid slag and liquid metal. Lowered interfacial tension induced Cu loss into the slag.

Aug 21, 2024

By M G. Shaw, M A. Rhamdhani, S P. Singh, A R. Duffy, B Eisenbart, A K. Shukla, G A. Brooks

The field of astrometallurgy is a growing area of study. Metal production on the Moon is likely to begin in less than a decade as major space agencies such as NASA (National Aeronautics and Space Administration) and CNSA (China National Space Administration) are preparing to construct permanent lunar bases. The utilisation of regolith to generate oxygen and metals is expected to be important in the development of a sustainable lunar habitat. This paper provides an overview of potential metallurgical processing methods for lunar conditions, emphasising the impact of lunar factors on slag chemistry. The interaction between regolith and the extracted metals, as well as their impact on slag composition and refractory performance, are critical considerations in metal production on the lunar surface. The initial research on lunar metallurgical technologies is focused on oxygen extraction and Fe-Si alloys are reported as the by-products of these processes. This paper delves into the fundamental thermodynamics associated with the carbothermic reduction of lunar regolith. Thermodynamic analysis using the FactSage™ ver 8.2 software package indicates that the Fe-Si alloy can be produced as a metallic product from the lunar regolith at temperatures ranging from 1400°C to 1600°C under terrestrial conditions. However, under ultra-high vacuum conditions (3 × 10-15 bar) on the Moon, the required operating temperature for producing ferrosilicon would be significantly reduced. Thermodynamic modelling results indicate that under lunar vacuum conditions, Fe-Si alloys only exist as solid phases at lower temperatures below 650°C. At higher temperatures, both Fe and Si are expected to be present in the gas phase. In this work, the carbothermic reduction of the Lunar Mare Simulant (LMS-1) is conducted under terrestrial conditions. The findings indicate that the process can readily yield Fe-Si alloys with 7–10 wt per cent Si at 1600°C. Additionally, energy dispersive spectroscopy (EDS) analysis of the resulting Fe-Si alloy indicates the presence of phosphorus up to 1 wt per cent.

Aug 21, 2024

By M Zhu, G Tranell, J You, K Tang, X Ma

The thermal conductivity of slag is critical for the efficiency of high temperature metallurgical processes such as the smelting reduction of ferroalloys, the ladle refining and the continuous casting mold flux in steelmaking. Experimental determination of slag’s thermal conductivity is fraught with challenges, as seen in yielding data for the SiO2-Al2O3-CaO system that are often inconsistent and widely dispersed. In molten slags of this system, thermal transport occurs via phonons within the network structure. To quantitatively describe thermal conductivity based on the microstructure, hightemperature Raman spectroscopy was employed to measure the silicate tetrahedra Qi (i = 0, 1, 2, 3), with Q4 species inferred from mass balance. This study also integrated molecular dynamics simulations to provide a fundamental understanding of the microstructure units distributions. Machine learning algorithms, especially deep neural networks, were applied to establish the relationship between slag composition and the configuration of tetrahedra. The thermal conductivities were then connected with silicate tetrahedra Qi using an Arrhenius-type formalism. This study sets the stage for extending our findings to more complex, multicomponent slags, enhancing their practical application in industrial processes.

Aug 21, 2024

By V Rimal, d M. Tangstad

Multiphase slags form the basis of the reduction pathway for manganese ferroalloy production. The present work aims to understand the flow of slag through the coke bed based on experimentation in controlled conditions. Synthetic slags of different basicities were evaluated for their phase composition, viscosity, and flow. The two-phase slag will have two zones: a liquid slag zone and a multiphase zone. The multiphase zone will consist mostly of a solid phase with some liquid slag between the solid particles. The multiphase part will hence have a high viscosity. The liquid zone will flow into the coke bed while the multiphase area will stay. With increasing reduction, the multiphase area will decrease in size until the solid phase is gone and the whole slag will flow into the coke bed. The effective viscosity of slag will decrease with the lowering of the solid oxide phase. The results from flow experiments confirmed that the segregation of phases occurs when slag flows through the coke bed. It is observed that the flow is dependent both on the size of the void and the viscosity of slag.

Aug 21, 2024

By T Kon, K Ohno

Slag foaming is an important control item in the process of refining molten steel. This study aims to investigate the factors controlling slag foaming by observing the bubble formation behaviour resulting from the chemical reaction between iron oxide and Fe-C alloy in the slag. In this study, 0.06 g of Fe- C alloy was introduced at the bottom of a BN crucible, and 6.0 g of slag (SiO2:CaO:Fe2O3 = 40:40:30) was placed on top of it. The crucible was positioned inside an infrared image heating furnace, where the temperature was rapidly raised to 1370°C at a rate of 1000°C/min in a nitrogen stream, and then held at that temperature for a predetermined time before rapid cooling. Following rapid cooling, the internal structure of the sample was examined using a high-resolution X-ray CT device. The spherical equivalent volume was calculated based on the number of observed bubbles and their equivalent circle diameter. Additionally, the relationship between the volume ratio of small bubbles in the slag volume and the distance from the bottom of the crucible was determined, along with the calculation of bubble density and volume ratio. Under various experimental conditions, numerous bubbles with equivalent circular diameters ranging from 200 to 300 μm were consistently observed. The density and volume fraction of bubbles with circular equivalent diameters between 200 and 500 μm showed a tendency to increase as the distance from the bottom of the crucible increased. Bubbles with equivalent circular diameters of 500 μm or more consistently exhibited lower bubble densities, regardless of their height within the crucible. The formation of larger bubbles is attributed to a decrease in iron oxide concentration within the slag as the reaction progresses. However, this is believed to be due to their higher buoyancy, resulting in shorter residence times within the slag and a reduction in the number of encapsulated bubbles.

Aug 21, 2024

By Y B. Kang, Y J. Park

Ti-added ultra-low carbon (ULC) steel is produced by adding Al and Ti during the secondary refining process to deoxidise molten steel and to bind C and N which are detrimental to the deep drawing quality of the steel product. However, the production of Ti-added ULC steel faces challenges, including submerged entry nozzle clogging and surface defects on cold rolled coils. The troubles were often attributed to ‘Al-Ti complex inclusions’ in the molten steel. However, the evolution of oxide inclusions including their stability has been still unclear. In the present study, the evolution of these inclusions in Ti-added ULC steel was investigated by phase diagram measurement, CALPHAD thermodynamic modelling, high-temperature stability test for the oxides, and observation of transient behaviour of oxide inclusions in the steel. The phase diagram of the Al-Ti-O system was elucidated with an emphasis on oxygen potential, which significantly controls the stability of the oxides. CALPHAD thermodynamic models and a self-consistent database were developed. The transient behaviour of Al-Ti complex inclusions in Ti-added ULC steel was observed in situ using a confocal scanning laser microscope. This was additionally validated by the new thermodynamic model. The equilibrium phases of the oxide inclusions were investigated using a high-temperature resistance furnace, and were analysed using a secondary electron microscope, energy dispersive spectrometer, and electron back-scattered diffraction. By considering the morphology and crystal structure of these inclusions, the evolution of Al-Ti oxide inclusions was elucidated. Various behaviour of Al-Ti inclusions and their influence on steel cleanliness are discussed.

Aug 21, 2024

By S Zummar, A Van den Bulck, T De Staercke, T Van Rompaey

An increase of 22 per cent in lead usage is expected in the European Union by 2050. During lead refining, the Harris process is a critical step in which a salt melt is used to remove arsenic, tin and antimony. During this process, the caustic salt melt absorbs these impurities, requiring regular evacuation before saturation. Current metallurgical practices for: 1) determining the end point of the lead alloy involve time-consuming sampling and offline analysis, and 2) determining the end point of the caustic salt melt are based on subjective visual observations by the operator. In the context of Industry 4.0 concept, automating these processes becomes desirable, as smart sensors systematically collect real-time data in an unbiased manner. This research focuses on monitoring the Harris refining process using objective methodologies. Two different methodologies are investigated. The first methodology focuses on electrical conductivity changes of the caustic salt melt as function of Sb content. For this study, synthetic and industrial samples are used. A lab-scale electrical conductivity set-up was built to accommodate the aggressiveness of the salt melt. Initial findings suggest a promising relationship between electrical conductivity and Sb content in the caustic salt melt. Although the results are preliminary, the study provides valuable insights by enabling real-time measurements. The second methodology focuses on measuring the electromotive force (EMF) in lead doped with Sb at pilot-scale. Multiple probes are reevaluated for their effectiveness in Sb measurement. Ultimately, a partially stabilised MgO probe with Ni as a reference, without cardboard and copper protection caps, yields promising results. A correlation between EMF and Sb content is observed. However, repeatability issues arise due to possible wire interference at low temperatures. The results underscore the potential of advanced measurement techniques in optimising lead alloy production within the context of Industry 4.0.

Aug 21, 2024

By N Voller, A Ishmurzin, G Hackl, M Wu, A Kharicha, M Chintinne, C M. G Rodrigues, A Ludwig

Slag fuming (SF) is a critical process for recycling zinc-containing slags, but the corrosive nature of molten slag poses challenges to the reactor durability. The freeze-lining (FL) technique offers a solution by forming a protective layer on the reactor wall. It requires intensive cooling using watercooled jackets, which can stabilise the FL while compromising the energy efficiency of the process. This study presents a computational fluid dynamic (CFD)-based model to optimise the SF process by considering FL formation and its impact on heat transfer and reactor wall temperature. A volumeof- fluid (VOF) model is coupled with a mixture continuum (MC) solidification model to capture the intricate multiphase flow dynamics within the SF furnace. Two FL types are considered: FL solidifying on the reactor wall in the slag bath region; and FL solidifying on the reactor wall in the freeboard region. The FL of the first type forms when the slag temperature drops below liquidus temperature. The FL of the second type only forms when a splash-induced slag droplet collides with the freeboard wall and solidifies. A series of splashing events are necessary to coat the freeboard wall. The simulation was run until a global energy balance was reached. This means that the heat losses from the water-cooled jacket, bottom wall, outlet and fuming balance the heat gains from the hot gas injected through the submerged plasma torches. The increase in FL thickness, due to its low thermal conductivity, reduces the heat losses through the reactor walls. The calculated FL thickness and heat fluxes were in good agreement with industrial data, validating the model’s credibility. The simulation results provided valuable insights into the fuming process, including slag bath temperature evolution, slag splashing dynamics, FL formation patterns, local heat fluxes through the reactor wall and overall energy balance. These findings can inform process optimisation strategies to enhance the energy efficiency and sustainability of SF operations. The authors have built a prior version of the model framework and applied it to simulate FL formation in an electric smelting furnace (ESF). The results from both the ESF and the current SF highlight the applicability of such model framework to a range of industrial processes involving FL formation. This model framework can ultimately contribute to more energy-efficient and sustainable industrial operations.

Aug 21, 2024

By M I. Pownceby, M A. Rhamdhani, S Palanisamy, D Fellicia, B Satritama, G A. Brooks, A Ang

Metal production have long been using carbon sources as both reducing agents and energy sources. Consequently, the global extractive metal sector contributes significantly to greenhouse gas emissions, accounting for approximately 9.5 per cent. Hydrogen gas offers as a promising ecofriendly alternative to carbon in metallurgical processes, serving as both a reductant and energy supplier with a by-product being only water vapour. However, the implementation of molecular hydrogen faces certain challenges related to the thermodynamics and kinetics of metal oxide reduction. In addressing these challenges, researchers have explored the application of hydrogen plasma, generated by subjecting molecular hydrogen to high energy to produce atomic, ionic and excited hydrogen species. Hydrogen plasma offers thermodynamic and kinetic advantages over molecular hydrogen and carbon-based reductants, exhibiting lower standard Gibbs free energy of reaction and activation energy. Therefore, hydrogen plasma can produce metal in fewer steps, process any oxide feed and feed size and even be used to refine metals. Despite these advantages, challenges exist in utilising hydrogen plasma in extractive metallurgy, including electricity costs, potential reverse reactions and industrial-scale implementation. This study provides a mini review of prior research on hydrogen plasma for metal oxides reduction, particularly iron oxide, as well as state-of-the-art techniques for its use in extractive metallurgy applications by mentioning several reactor types. Future prospects and scale-up possibilities of the hydrogen plasma in extractive metallurgy will also be presented.

Aug 21, 2024

By M K. Nahian, R G. Reddy

The thermodynamic model for species distribution in aluminium chloride (AlCl3) and 1-butyl-3- methylimidazolium chloride (BMIC) system was developed. The experimental thermodynamic data, considering a range of aluminium chloride species, such as AlCl4-, Al2Cl7-, Al3Cl10-, Al4Cl13-, and Al2Cl6 were used in developing the model. When the XAlCl3 was in the range of 0 to 0.50, only anion species Cl- and AlCl4- were existing in the solution. As the XAlCl3 value increased more than 0.50, the available anions were Al2Cl7-, Al3Cl10-, Al4Cl13-, and Al2Cl6. Specifically, the concentration of Al2Cl7- increased in the composition range from 0.50 to 0.67 XAlCl3, after which it decreased. This change in the concentration of Al2Cl7- was due to its reaction with excess AlCl3, leading to the formation of Al3Cl10-. The average cathode current density was determined by the electrochemical experiments varying XAlCl3 from 0.50 to 0.71 in the AlCl3:BMIC solutions. The average cathode current density increased as the XAlCl3 increased from 0.50 to 0.67. However, it decreased when the XAlCl3 > 0.67. This trend can be attributed to the electroactive species Al2Cl7-. The Al2Cl7- promotes the reduction rate at the cathode, resulting in an increase in the average cathode current density.

Aug 21, 2024

By Y Zhang, Z Zhao

The green production of the steelmaking process has urgent requirements for fluorine-free fluxes. In this article, a new solid waste-based slagging flux was applied in the external dephosphorisation test of low silicon hot metal to replace the traditional fluorite-lime dephosphorisation slag. The results showed that under laboratory conditions, the new flux was utilised for smelting low-silicon molten iron with a phosphorus content of 0.10~0.13 wt per cent, the temperature of the molten iron was 1350°C and the slag amount was controlled at 2 per cent. Within ten minutes of smelting, the dephosphorisation rate of the molten iron reached more than 50 per cent. When making slag with new flux, the slag melting time was about 40 seconds and the P2O5 content in the final slag was higher than 8 wt per cent. In the industrial test of a 150 t molten iron ladle, under the same molten iron conditions, an out-of-furnace dephosphorisation test was conducted in the Kambara Reactor (KR) process. The flux material consumption per ton of steel was 8~10 kg. Within 15 minutes of smelting, the dephosphorisation rate of the molten iron was about 30 per cent. During flux slag making, the slag melting time was about three minutes and the P2O5 content in the final slag was higher than 6 wt per cent. This new solid waste-based flux has significant cost advantages and outof- furnace dephosphorisation effects and is expected to become the benchmark for a new generation of fluorine-free steelmaking fluxes.

Aug 21, 2024

By Y Mita, T Iwama, R Inoue, S Ueda

In the iron and steel manufacturing industries, efforts are being made to achieve carbon neutrality by 2050, and the transition from a coal-based steelmaking process to that utilising renewable energy is being pursued. An alternative process in which directly hydrogen-reduced iron is melted in an electric furnace is being investigated. It is known that foaming slag reduces heat loss from the steel bath in electric arc furnace, but iron loss due to the suspension of steel particles in the slag is indispensable. To improve the separation of steel particles from the slag, the control of the slag viscosity is important. Although the slag viscosity has been extensively studied, in those studies the slag was considered to be a simple liquid. However, in actual operations, slag is a multiphase fluid consisting of solid, gas and liquid phases. Therefore, in this study, by measuring the sedimentation velocity of titanium, stainless steel and glass spheres in an aqueous glycerin solution containing bubbles generated by the reaction between NaHCO3 and C2H2O4, the apparent viscosity of the gas-liquid fluid was evaluated based on Stoke’s law. It was found that the apparent viscosity of the gas-liquid fluid is larger than the viscosity of liquid phase and depends on both the bubble volume ratio in solution and the density of the falling solid sphere, and the apparent viscosity was different from that previously obtained by the rotation method. The apparent viscosity derived from the sedimentation velocity of solid spheres changed depending on the specific gravity of the ball. This is because the apparent viscosity is derived from the velocity of a ball falling in a static bubble in this method, whereas that is derived from the force applied by a stationary flow in the rotational method.

Aug 21, 2024

By K L. Avarmaa, M A. Rhamdhani, A D. P Putera, H T. B M Petrus, G A. Brooks

Multistage slag treatment was carried out to investigate boron removal from metallurgical grade silicon. Boron is known to be one of the most difficult elements to remove from silicon. Depending on boron initial concentration, boron can be removed from silicon into certain level; most previous studies have attained final 50–100 ppmw (parts per million weight) boron in the silicon using slag treatment. The term ‘multistage’ refers to a process where the resulting silicon from the initial slag treatment is further refined multiple times using a new slag. In this study, an initial slag composition of 45CaO-45SiO2-10Al2O3 (wt per cent) was utilised. Using this technique, boron level in the silicon was expected to be gradually lowered because the new slag will always have more capacity to reach the equilibrium distribution coefficient (LB = (ppmwB)slag/(ppmwB)Si). The current study was carried out through combined thermodynamic calculations (using FactSage™ ver 8.2, by Thermfact Ltd, thermochemical package) and high-temperature experimentation. The thermodynamic calculations were carried out for reactions at 1500, 1550, and 1600°C for three different scenarios: 1. Single stage refining with varied slag to Si ratio. 2. Multistage refining with slag to Si ratio of 1:1. 3. Multistage refining with slag to Si ratio of 2:1. The multistage experimental work was carried out at 1550°C under inert gas atmosphere each time for 2 hrs, with slag to Si ratio of 2:1. The simulation results indicate that the boron distribution coefficient stay essentially constant with varying slag to Si ratio and temperature, around 1.8 to 2, and the experimental results measured LB in the same range, between 1.5 and 2.5. By harnessing this feature, the simulation showed that boron can be removed by approximately 78 per cent in each stage. The experimental result confirmed that the boron concentration in the silicon was reduced by a total of 97.8 per cent from its initial value using four stages of slag treatment, from initial 270 ppmw down to 6 ppmw.

Aug 21, 2024

By H Yuan, H Tian, Y Zhang, Z Wang, C Wang

Submerged arc welding (SAW) is one of the significant metal-joining processes for manufacturing marine vessels, steel pipes, and offshore structures with high deposition rate and engineering reliability. Welding flux serves several essential functions, including atmospheric shielding, arc stabilisation, bead morphology control and weld metal (WM) refinement. Therefore, from a thermodynamic point of view, the focus for flux design and WM compositional/microstructural modification has been placed to elucidating the transfer pathways and mechanisms of major alloying elements, such as Si, Mn, Ti and O during welding. To this end, a thermodynamic model has been established to predict alloying element contents in the WM. Such functions are enabled by the physicochemical properties of the fluxes, which are inherently rooted in the nature of the fluxes. A unique yet systematical investigation, including physicochemical property changes and structural evolution behaviours, has been conducted over the wide range of fluxes applied to actual welding of EH36 shipbuilding steels. Combined with spectroscopic methods, structural behaviours of network formers such as SiO2, Al2O3 and TiO2 and network modifiers such as MgO, MnO and CaO have been illustrated. Viscosity and ionic conductivity have been found to be positively associated with the degree of polymerisation.

Aug 21, 2024

By S Kakara, A Kamaraj, S S. Varanasi, B V. R Mandalika, M B. Shaik

The properties of top slags play a very important role in secondary steelmaking. Fluxes should be chosen based on the ladle furnace (LF) slag requirements like viscosity, melting temperature, sulfide capacity, etc. CaF2 and CaO-Al2O3-based synthetic slags are the most used fluxes in secondary steelmaking to improve slag fluidity and interfacial chemical reactions. CaF2 is obsolete due to fluorine pollution and CaO-Al2O3 based slags have 40–50 wt per cent Al2O3 and 30–40 per cent CaO which is not beneficial for desulfurisation. Yet another drawback is that LF slag disintegrates into fine powder during cooling due to phase transformation C2S (2CaO.SiO2). Hence, there is a need for the development of low melting fluxes with high CaO content and the capability to prevent slag disintegration. The current work studied the effect of 0–9 wt per cent B2O3 on physico-chemical properties and characterisation of LF slags. X-ray diffraction (XRD) analyses were carried out to identify mineralogical phases present in slag and Fourier-transform infrared spectroscopy (FT-IR) analysis was done to understand the changes in bonds of B2O3 added LF slag. The characteristic temperature of slag was determined by a hemispherical method using high-temperature microscopy. Empirical models were used to calculate viscosity, break temperature, and sulfide capacity. FactSage™, ver 8.2 (by GTT-Technologies) simulations were carried out to find the equilibrium phase fractions and percentage of liquid slag at different temperatures. New phases such as Ca11B2Si4O22 and Ca2B3O5 were formed in LF slag with B2O3 addition. Based on the results, 0.5–1.0 wt per cent B2O3 was found to be sufficient to prevent C2S-driven disintegration of LF slag. Also, the melting temperature and viscosity of LF slag were reduced by adding 3–8 wt per cent B2O3 due to the formation of BO3 planar triangular structure and low melting eutectics in slag. Liquid slag started forming at a temperature as low as 800°C when B2O3 is >6 wt per cent. It was found that the sulfide capacity, viscosity, and break temperature of the slag decreased with increasing wt per cent B2O3. Based on the analysis carried out, B2O3 can be a promising fluxing material in secondary steelmaking, for improving the desulfurisation kinetics and valourisation potential of LF slag.

Aug 21, 2024

By J H. Zietsman

The transition to more sustainable metal production is receiving much attention at present, and the iron and steel industry is at the centre of the conversation. New, more environmentally friendly production technologies, such as direct reduced iron (DRI) smelting furnaces, need to be developed in a short period of time. This necessitates increased use of computational modelling that incorporates more accurate material descriptions. The combination of large-scale multiphysics models of high-temperature processes with CALPHAD material descriptions leads to infeasible computation times. This can be resolved with the previously reported RapidThermo framework, which has been demonstrated to make equilibrium calculations orders of magnitude faster, within controllable limits of accuracy. In this paper, we explain how further material properties, which are important to modelling hightemperature reactors, can be added to the RapidThermo framework. This can improve the accuracy and usefulness of process and multiphysics models in the development of new technologies, which can significantly accelerate development cycles.

Aug 21, 2024

By Z Li, Z Yan, M Yang

Recycled cement paste (RCP) is a kind of CaO-rich recourse, which is separated and recycled from waste concrete. Due to its chemical composition, RCP could partially replace lime as a flux and be loaded into electric arc furnace (EAF) steelmaking process. Rapid RCP assimilation and liquid slag formation have significant effects on EAF steelmaking process. In this study, the dissolution behaviours of RCP and lime at temperatures of 1400°C to 1500°C were investigated using static dissolution experiment. The dissolution rate, interfacial microstructure, as well as dissolution mechanisms were discussed. It was found that the dissolution rate of RCP was much higher than that of lime. RCP could be completely dissolved into slag in 60 secs at 1500°C. The dissolution rate of lime was in range of 3.910-4 g/(cm2ꞏs) to 2.610-3 g/(cm2ꞏs), while that for RCP was in range of 1.510-3 g/(cm2ꞏs) to 4.910-3 g/(cm2ꞏs). As for lime dissolution, a dense layer of dicalcium silicate (C2S) generated at the dissolution interface, and the diffusion of Ca2+ in C2S layer was the limited step for lime dissolution. Some of calcium ferrite could be observed at the interface between lime and C2S layer. As for the RCP dissolution, there is no obvious product layer of C2S formed at the dissolution interface, Fe2+ continuously diffused into RCP layer during the dissolution, and small amount of FeOꞏMgO solid solution generated and gathered at the dissolution interface. The dissolution rate of RCP in EAF slag was quite higher than that of lime, partially add RCP as flux in EAF could accelerate the slag formation process.

Aug 21, 2024

By R. L. Machunda, A. M. Rugaika, D. D. Mdachi

Sedimentary and igneous rocks are the two primary sources of phosphate that are mined and beneficiated to fertilizer. During the beneficiation process, phosphate is lost into the tailings. We investigated phosphate concentrations in tailings dumps at Minjingu mine, Tanzania using energy-dispersive X-ray fluorescence spectrometry to quantify the chemical compositions. The phosphate content in the tailings varied from 12.91% phosphorus pentoxide (P2O5) in Tailings 2 to 19.61% in Tailings Dump 1. The naturally occurring phosphate concentration in rocks ranges from 3% to 35%, and phosphate tailings from various locations with P2O5 concentrations as low as 6.46-12.65% have been beneficiated to commercial fertilizer. Our investigation revealed that phosphate concentrations in Minjingu tailings may be sufficient to be recovered for commercial applications. Suitable recovery methods are discussed, and we recommend that beneficiation should be performed to minimize the loss of phosphate into tailings. Further research is needed to identify the optimal beneficiation methodology.

Aug 8, 2024

By A. Drumond, J. F. C. L. Costa, M. G. Lemos, A. L. Rodrigues, F. G. Niquini

The past decade has seen a renewed possibility of using machine learning algorithms to solve a large collection of problems in several fields. Data acquisition for mining operations has increased with the growth in sensor-based technologies, and therefore the amount of information available for mining applications has dramatically increased. Ore sorting equipment is available for separating ore from waste based on differences in physical properties detected by a real-time analyser. The separation efficiency depends on the contrast in these properties. In this study we investigate the application of machine learning models trained using data from the output of a dual-energy X-ray ore sorting apparatus at a gold mine. The particles were first hand-sorted into ore and gangue classes based on their mineralogical composition. Classification models were then used to help decide the balance between the number of true and false positives for ore in the concentrate, with a view to economic parameters, using their receiver operator characteristic (ROC) curves. The results showed AUC (area under the ROC curve) scores of up to 0.85 for the classification models and a maximum reward condition Fpr/Tpr around 0.5/0.9 for a simplified economic model.

Aug 8, 2024

By T. Marin, J. E. Seccatore, M. Cardu

The most energy-intensive process in the mining industry is particle size reduction – comminution. The first phase of this process is blasting to fragment the rock from the initial Boussinesq’s halfspace size. Scientific literature demonstrates that the output of a blast in terms of fragment size distribution can be manipulated by varying the specific charge (powder factor) and charge distribution. This study focuses on the influence of blasting on the internal resistance of the blasted fragments; in particular the influence of the spatial distribution of charges. Small-scale blasts were performed on 14 marble blocks using different powder factors and charge distributions. Three control blocks were fragmented by mechanical means for comparison. The results show the correlations between charge distributions and the specific energy of mechanical comminution. Opportunities for adjusting charge diameter and distribution in opencast blasts to improve the performancet of comminution circuits are discussed.

Aug 8, 2024