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By Alastair Torrance, Italo Onederra, Do Sun Kim, Kush Patel, Gary Cavanough

Reactivity of ammonium nitrate-based explosives is associated with the presence of sulphide in the ground reacting with explosive products and in some instances causing spontaneous reactions which can lead to detonation. This paper explains the mechanism of these reactions, the potential cause of spontaneous detonation and how inhibited explosives prevent the reaction

Jan 1, 2019

By Victor Munoz, Jorge Oliva, Gonzalo Marias

Cerro Vanguardia is a known gold and silver deposit located in the province of Santa Cruz, Argentina. The mine has been in operation since 1998 and is thought to be one of the most important mines in Patagonia. More than 102 epithermal quartz veins have been identified in the area, with variable lengths, thicknesses, orientations and dips that constitute what is possibly one of the most extensive outcropping vein systems on earth.

Jan 1, 2019

By T. M. Klemetti, T. J. Batchler, T. Matthews

From 2013–2017, there were over 1,120 documented injuries, including fourteen fatalities, from ground falls in underground mines in the United States (MSHA 2017). The majority of these ground-fall injuries were not caused by a major roof collapse, but from falls of smaller rocks from the immediate roof. Roof screen can significantly reduce the number of these injuries and has been widely used in underground coal mines for surface control. Because of the potential of reducing ground-fall injuries, the National Institute for Occupational Safety and Health (NIOSH) is further evaluating the performance characteristics of welded-wire screen as used in underground coal mines by conducting a laboratory testing program using the Mine Roof Simulator (MRS) in NIOSH’s Bruceton Research Center Laboratory in Pittsburgh, PA. The load-displacement characteristics of an 8-ft x 12-ft area of 8-gauge welded-wire screen were evaluated using a test frame designed for testing multiple load-pull locations. In previous tests, load-pull contact was always in the center of the bolted screen section. In this study, larger pull contact areas are used to simulate roof falls. The information obtained in this and similar studies can be used to better understand the loading behavior and surface control capability of roof screen in underground mines. INTRODUCTION AND BACKGROUND The large majority of ground-fall injuries are caused by falls of smaller rocks from the immediate roof. Various controls are currently being used in mines to control this surface rock, including the use of wire roof screen. In mines where wire roof screen has been installed, injuries from rock falls have been reduced dramatically (Robertson and Hinshaw, 2001). Roof screen has the potential to prevent hundreds of injuries caused by the fall of small rocks between permanent roof supports (Compton et al., 2007). Because of this potential for reducing ground-fall injuries, the National Institute for Occupational Safety and Health (NIOSH) is evaluating the performance characteristics of welded-wire screen as used in underground coal mines by conducting a laboratory testing program in the Mine Roof Simulator (MRS) in NIOSH’s Bruceton Research Center Laboratory in Pittsburgh, PA. Previous tests to evaluate the performance characteristics of various types of screen have been conducted by the University of Alberta (Tannant, 2001). In this study, the load-displacement properties of welded-wire, chain-link, and expanded-metal mesh were measured by performing full-scale pull tests. A flat steel plate was pulled through a screen test sample that was bolted to a special test frame while the pulling force and mesh displacement were measured. These tests established the general load-displacement behavior of the screen. Peak load capacities and stiffness were determined for each screen type, showing how welded-wire mesh has a much stiffer initial loading response, whereas chain-link and expanded-metal mesh have large displacement capabilities and exhibit significant post-peak ductility.

Jan 1, 2019

By Thomas L. Barkley

My historic auditing of Underground Drilling and Blasting Practices has demonstrated to the author the need for reviews of many mines' procedures in these processes. Poor understanding of the basic principles and practices of the drilling and blasting science in Underground Development Mining has created significant costs to mining operations in many instances.

Jan 1, 2019

By G. A. Sutton

This paper, describes a case example from San Manuel mine, where in situ copper leaching of the supergene zone was done over a 14 year period (1986–1999) in conjunction with underground and open-pit mining operations of a copper porphyry deposit. In 1993–1994, testing of well fields was done to determine the amount of copper that would be recovered from in situ leaching of the supergene zone, which was composed primarily of chrysocolla and copper-clay minerals. It was determined that the leach fluid would reach 70% (‘sweep efficiency’) of the copper minerals and that 75% of them would be leached for a recovery of 52% of the acid soluble copper. However, the final results from Zone 6, which had the longest leach history, showed that approximately 42% of the acid soluble copper was recovered, indicating that the `sweep efficiency’ was closer to 55%. Comparison of drill-core assay data from two holes, one drilled before (ARM158) and the other after (SMO9607) leaching, also indicate that approximately 42% of the acid soluble copper was recovered. The discrepancy between the predicted (52%) and actual (42%) recovery is probably related to a combination of factors, including difficulty in maintaining fluid saturation, channeling effects and gypsum precipitation. INTRODUCTION In situ copper leaching at the San Manuel mine, Arizona, was initiated in 1986. It was recognized that some of the copper oxide resource was not going to be economically recoverable by conventional open pit and heap leach methods using solvent extraction and electrowinning (SXEW). A high stripping ratio would be required to access part of the resource. At the time, in situ leaching was becoming popular in the uranium industry but the approach was virtually unknown in the copper industry, especially not at a large scale.

Jan 1, 2019

By Xian Jian Guo, Lei Li, Hua Wang

Direct smelting of copper concentrate to blister copper has the advantages of energy saving and environmental protection. There has been a lot of effort invested in process development including test work and theoretic analysis in the past half century. However, the process has only been applied commercially to a few smelters that treat chalcocite types of copper concentrate. The main limitation to treating chalcopyrite types of copper concentrate is high copper content in smelting slag and low direct copper recovery. Thus intensive slag cleaning is needed. In this paper, the thermodynamic analysis was mainly carried out for the multiphase equilibrium of direct to blister copper smelting for both chalcopyrite and chalcocite concentrates. The practical problems in direct to blister copper smelting, which are mainly in copper content in slag, are clarified. The operational window of slag composition for different temperatures and oxygen partial pressure for the treatment of chalcocite type concentrates is identified. The process operation optimization for the blending of chalcocite, pyrite and chalcopyrite concentrates was done. INTRODUCTION The extractive metallurgy of copper can be divided into two broad groups of processes, namely, pyrometallurgy and hydrometallurgy, and the former is dominant. About 80% of copper in the world is produced by pyrometallurgy (Christopher et al., 2006). The first stage of conventional copper pyrometallurgy processing is to smelt copper concentrate to copper matte composed of FeS and Cu2S with slagging to remove a proportion of the iron (Gargul, Boryczko, & Bukowska, 2017). The smelting processes include bath and flash smelting. The second stage of the process is to convert copper matte to blister copper. In most cases, the copper matte is converted in Peirce Smith (P-S) converters, which are batch operations (Kubiszewski, 2015). The P-S converting can be divided into two periods, slagging and copper blowing. During slagging period, FeS in copper matte is oxidized to FeO, which reacts with silica flux forming slag. When the iron content in matte is less than 1%, copper begins to oxidize and reduce to form blister copper (Kucharski, Sak, Madej, Wędrychowicz, & Mróz, 2013).

Jan 1, 2019

By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By T. M. Klemetti, T. J. Batchler, T. J. Matthews

How representative are partial-panel screen tests of the in situ response of screen to roof and rib deterioration and displacements? Can a more representative procedure that tests up to two full screen panels improve the utilization and effectiveness of screen as a roof and rib support? This paper details a new full-panel screen test procedure and the initial results. The full-panel test frame was designed to test a 2.4 by 3.6-meter screened area with bolt spacing as small as 0.3-meter increments. The initial design included up to 6 screen pull points, but additional locations can be added to produce a more uniform loading. The test frame was developed to capitalize on the capabilities of the Mine Roof Simulator (MRS) at the Pittsburgh Mining Research Division (PMRD) of the National Institute for Occupational Safety and Health (NIOSH). The initial tests included a baseline test of a partial panel (1.22 by 1.22-m screen section) using the original 1.52 by 1.52-meter test frame, a 1.22 by 1.22-meter screen section test in the new full-panel test frame, and two tests of 2.4 by 3.6-meter screened area in the full-panel test frame. The 1.22 by 1.22-meter screen section tests in the full-panel test frame produced a peak load 6% higher and a yield load 30% lower than the partial-panel (original) test frame. The multiple pull points of the full-panel frame produced variable yield, peak, and intermediate loads, but on average were lower than the single pull-point tests. INTRODUCTION Roof and rib surface support has become a major component of the stability and safety of underground coal openings in the past 15 years. The use of screen, either metal or synthetic, has proven to decrease the injuries of underground coal miners. By 2005, there were 466 injuries in the United States caused by roof skin failures, with numerous mines not employing roof screen. In contrast, in 2015 there were 175 injuries caused by roof skin failures, with at least some of the reduction due to the increased use of roof screen. A continued effort to increase the utilization of screen in areas of underground coal mines where workers are traveling and working can reduce these injuries even further. To aid in this effort, the testing of various screen types under various loading and attachment conditions is required. Past testing efforts have primarily consisted of partial-panel testing in a laboratory setting. Laboratory testing of roof screen, both metal and composite, has been conducted in several ways by researchers, manufacturers, and other entities. The primary focus on the testing has been evaluating weld integrity of 1.22 by 1.22-meter screen section tests of various screen types utilized in mining (Dolinar, 2006; Dolinar, 2009; Tannant, 2001). There have also been several efforts at numerical simulation of the screen and screen/rock interactions (Murali et al., 2006; Shan et al., 2014). A few full-panel tests were performed with one pull or loading point in the center of the screen panel (Shan et al., 2014). As most previous efforts have mentioned, the only true way to evaluate the capabilities of screen is to conduct full-panel testing. Single wire strand, weld, and partial-panel (1.22 x 1.22-m) tests as well as numerical modeling only provide insight into the actual response of full-panel screen. A new test frame and procedure have been developed at PMRD to conduct various loading, anchoring, and material testing.

Jan 1, 2019

By R. T. Seaman

There are several hydrometallurgical alternative processing options under development for high enargite and arsenic containing copper concentrates ranging from biological, atmospheric, medium temperature oxidation to total oxidative leaching. The most developed of these options is the CESL process boasting pilot campaigns totaling more than 8760 hours of fully integrated continuous operation, as well as, over two thousand batch scale oxidation tests performed on dozens of concentrates for flowsheet development. This paper reports the observed deportment of arsenic under varying arsenic, iron and acid oxidation conditions; it also describes the impact of iron to arsenic ratios and residue recycle on overall arsenic behavior and its stability in residue. INTRODUCTION The CESL Hydrometallurgical Process (CESL) was originally developed to compete with smelting of clean chalcopyrite concentrates. High Treatment Charges and Refining Charges (TC/RCs) combined with premiums on London Metal Exchange (LME) grade copper from onsite refining made treatment of copper concentrates using CESL a viable option at the time. As world demand for copper increased and a subsidized Chinese refining market developed, smelting contracts became more favourable for the miner and focus was placed on modifying the CESL Hydrometallurgical Process to handle concentrates with elevated deleterious elements. Dozens of pilot campaigns processing concentrates containing elevated concentrations of uranium, fluoride, mercury and nickel all led to further developments of the CESL Hydrometallurgical Process. In 2016 a United States patent was granted for a novel modification of the CESL Hydrometallurgical Process for recovery of copper from arsenic-bearing and/or antimony-bearing copper sulphide concentrates, Henry Salomon de Friedberg (2016). To date, over 2000 bench scale tests along with five fully integrated closed loop pilot campaigns, totaling over a year of online operation time, have been conducted processing arsenic bearing copper concentrates. This paper summarizes the observed behavior of arsenic under varying autoclave and process conditions.

Jan 1, 2019

By Tristan Worsey, Nathan Rouse

Florida is one of the major limestone producing states in the United States. The state has unique regional geology and groundwater characteristics that require equally unique mining methods to extract limestone for construction materials. In many regions, aggregates quarries operate by drilling and blasting underwater limestone and then digging the muck with large draglines, while in others, mining operations are able to operate above the water table.

Jan 1, 2019

By M. Massinaei, S. Abasi, M. Oliazadeh

Reliable measurement and control of the pulp-froth interface (froth depth) in the flotation columns is critical to achieve the desired metallurgical performance. Shallow froths result in a reduction of grade because of particle entrainment and deep froths reduce recovery because of the drop back of entrained and weak hydrophobic particles to the pulp zone. The cleaner circuit at Miduk copper concentrator consists of three parallel MicrocelTM flotation columns 4 m in diameter and 12 m in height. The interface level of the flotation columns is measured by two pressure sensors located at 1.4 and 2.4 m from the cell lip (in the collection zone). In this study the performance of the level detection system at different operating conditions was evaluated. A calibrated float-ultrasonic location system was used for measuring the actual froth depth. The results indicated that the existing level control system was subject to considerable error. The absolute error was found to be 33.27 cm. This was mainly attributed to the constant set-point value assigned to the froth density (ρf=0.3 g/cm3), which actually varies with the operating conditions. The actual froth density at different conditions was calculated and its average value (ρf=0.12 g/cm3) was re-set in the control system. This resulted in substantial reduction in the level-detecting error. Recommendations for more accurate measurement of the interface level were presented. INTRODUCTION Froth flotation is a complicated process because of many involved variables. One of the most significant controlled variables in the flotation process is the pulp-froth interface (froth depth). The froth depth has a profound influence on the metallurgical performance parameters (i.e. grade and recovery). Shallow froths result in grade reduction because of particle entrainment and deep froths reduce recovery resulted from the drop back of entrained and weak hydrophobic particles to the pulp zone (Finch and Dobby, 1990). Various techniques have been developed for measuring the interface level of the flotation cells in the last few decades. These techniques can be classified as: Techniques based on hydrostatic pressure measurements (Finch & Dobby, 1990), Techniques based on the density gradient (float) (Moys & Finch, 1988), Techniques based on conductivity measurements (Uribe-Salas, 1991), Techniques based on temperature measurements (Moys & Finch, 1989).

Jan 1, 2019

By K. Scalise, M. Teixeira, K. C. Kocsis, J. Parrish

"This paper aims to introduce and discuss a newly developed algorithm, which can be uploaded on smart watches and other mobile devices to inform and protect underground personnel working in hot and humid environments. Using this algorithm, the metabolic rate (M) of a worker can be determined in “real-time”. In addition, besides warning signs and alarm signals emitted by the smart watch, the algorithm has the ability to determine work-rest time periods based on the worker’s physiological parameters (e.g. age, height, weight, gender) and the climatic parameters (Td, Tw, flow velocity). This paper also investigates whether a re-designed auxiliary ventilation system can provide appropriate work conditions in the production stopes. INTRODUCTION An underground environment with high temperature and humidity conditions generated from various heat and moisture sources can significantly affect the thermoregulation processes of the human body. This can lead to heat-related illnesses such as heat rash, heat cramps, heat exhaustion, and heat stroke. Heat stroke is a serious illness that carries a high risk of fatality, if the underground workers are not immediately treated and the climatic conditions are not corrected (McPherson, 1993). There are two methods used to control the climatic conditions in underground mines: (1) Using ventilation and cooling systems to reduce the thermal stress on the mine workers, and (2) Reducing the heat transferred to the ventilating air from major sources such as: strata, auto-compression, mining equipment, groundwater, blasting, etc. The heat from strata and auto-compression is transferred to the ventilating air at varying degrees, based on factors such as the virgin rock temperature (VRT), the thermal properties of the surrounding rock formations, and the surface air temperature. However, the use of mining equipment and blasting processes can be managed to reduce their contribution to the mines’ overall heat load. To provide appropriate work conditions, selecting the most suitable cooling method depends on the level of heat to be removed, the location of the problem areas, and economic constraints (Brake & Bates, 2002; McPherson, 1993). Because every mine is unique, it is essential to monitor the climatic conditions to select the most appropriate method of cooling. A majority of the time, simply adjusting or re-designing the auxiliary ventilation system can efficiently remove the heat and dilute the contaminants. This may involve moving the ducting system, changing the size of the duct, changing the size of the auxiliary fan, or switching from forcing to an exhausting fan arrangement. If the required air volumes are higher than the existing primary ventilation system can supply, other measures may need to be taken to increase the airflow delivery. This may include regulating the flow in some areas of the mine to increase airflow to the desired area, adding booster fans, or replacing the primary fans."

Jan 1, 2019

By Frank Hirthammer

Productivity, customer relations, and effectiveness of work depend to an ever-increasing extent on a functioning logistics system tailored to the needs of the user. Of course, it is not possible to cover and explain all aspects of the logistical requirements of even a small part of an industry, in a single article. The article speaks specifically about the particularities and differences in the logistical requirements in the explosives sector. Starting with questions of safety, handling and quality up to the legal basis, there are special requirements regarding the logistics in the explosives sector. The results of innovative logistics solutions are presented using three examples from daily work practice.

Jan 1, 2019

By T. Imgrund, A. Bischoff, S. Spürk

"Specific conditions of underground coal mines at great depth, such as high temperatures, high rates of methane inflow and natural ventilation pressure provide considerable challenges for the reliable design of appropriate mine ventilation systems. For decades coal mining in Germany has coped with these extreme circumstances. Based on these experiences appropriate software tools for simulating mine ventilation networks have been developed and continuously enhanced. This paper examines differences in the simulation results and underlying calculation methods of two software solutions. The analysis is based on the comparison of FlowNetTM and VentSim DesignTM (Version 5.1) regarding the accurate prediction of fluid mechanical quantities and their validation with real measurements. A special focus lies on exceptional ventilation scenarios typical for deep coal mines, like gas inflows, fire events and buoyancy effects. The purpose of the comparison is the future utilization of the experiences gained during mining at up to 1,500 m depth for state of the art ventilation design. INTRODUCTION Ventilation is an essential component of mine operations—as providing fresh air to workplaces, diluting and removing explosive, toxic or asphyxiating pollutants and assuring sufficient climate conditions. On the other hand, the costs of ventilation contribute to a large extend to the overall operating costs of a mine, as the share in the energy consumption of a mine may be in the range of 25–50% (Belle, 2008). Accordingly, proper design of ventilation systems has been a task since early times. Consequently software for modelling of ventilation networks has been developed in order to improve efficiency and accuracy of calculations (Maleki, 2018). Compressible flow has not been considered by initial ventilation modelling software tools. In Germany, the consideration of changes in airflow density—depending on pressure and temperature—in the algorithms of ventilation simulation software has been started in 1974 by Duepre & Hofbauer. This development had been continued by the Pruefstelle fuer Grubenbewetterung (Test Centre for Mine Ventilation) and resulted in the release of a computer ventilation software named “Wetter”. The mine inspectorate of the German state of North Rhine-Westphalia, which supervises the major coal mining district in Germany, declared ventilation simulation based on compressible flow being “state of the art” in 1985 (Pollak, 1985). This pronouncement made allowance for assessing the consequences of underground fires and downtimes of main fans based on advanced software solutions."

Jan 1, 2019

By C. Chongo, L. Little, Q. Mclennan

Since commissioning in 2005, First Quantum Minerals’ Kansanshi Mine in Zambia has produced over three million tons of copper and 1.8 million ounces of gold from a deposit with highly varied copper mineralization. The processing plant is complex with three independent flotation circuits, gold gravity concentration, atmospheric and high pressure leaching, solvent extraction, and electro-winning. For the first ten years of operating the plant, copper mineralogy was inferred from total copper and acid soluble copper assays, and various misconceptions developed about the mineralogy which impacted operational strategy and project decisions. In 2015, an on-site mineralogy section was set up with an Automated Scanning Electron Microscope, the Zeiss MinScan. This instrument has provided detailed mineralogical data that have debunked some of the mineralogy myths that had developed, highlighting the key underlying issues affecting processing performance. This has enabled the development of projects targeting losses of specific copper minerals in defined size classes, unlocking significant value. This paper describes some of the early misconceptions around mineralogy at Kansanshi processing plant, outlining projects that have benefitted from understanding copper mineral distribution. Learnings from Kansanshi are to be applied at other FQM sites, with a similar mineralogy program being set up at the Cobre Panama project. INTRODUCTION The deposit Kansanshi Mine is located in the North Western Province of Zambia, and it has been the largest copper producer in Africa for over a decade. The deposit occurs within a broad northwest trending antiform that can be traced for 12 km, hosted in a zone of complicated faulting, abundant vein injection, breccia development and down-dropped rock units that lies within Kansanshi’s mining license. The copper mineralization within the deposit is predominantly vein-hosted, although some is strata-bound, occurring in thin bands and veinlets parallel to foliation, and some is disseminated associated with albite-carbonate alteration (Gray, 2015). Supergene enrichment has led to significant variety in the copper mineral speciation. This alteration is complex, and has not followed the text-book principles with a neat layer of supergene mineralization overlying fresh hypogene ore. Rather, the occurrence and extent of oxidation and supergene enrichment is highly irregular throughout the deposit, sometimes occurring at significant depth in localized pockets and along fault lines. Gold mineralization tends to follow the copper within the deposit, but it is dominated by coarse-grained, free-milling native gold. The extent of copper oxidation – measured as the fraction of total copper that assays as acid soluble – is used to classify ore into three main ore types, named Sulphide, Mixed, and Oxide, which are then fed to three different primary crushers for processing in independent circuits.

Jan 1, 2019

By K. Lambrych

Hydrometallurgical equipment used to extract and refine copper and other metals is exposed to extremely corrosive chemical environments. These systems must be fabricated from materials that are durable against corrosion, meet exacting mechanical requirements, and perform economically over the life of the mineral processing plant. In several recent large hydromet projects, fiber reinforced plastic (FRP) has been shown to provide equal if not superior durability relative to alternative materials of construction. This paper will compare corrosion performance and cost of plant equipment fabricated with corrosion resistant alloys, rubber lined steel, and FRP made with Epoxy Vinyl Ester thermoset resins. Case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory-based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment. Specific examples from projects such as El Boleo, Long Harbour and others will be used to demonstrate how the versatility of FRP allows for remote fabrication of durable corrosion-resistant large-scale equipment for hydrometallurgical refinement of copper and other metals. INTRODUCTION Fiber reinforced plastic (FRP) began to emerge as a material of construction for corrosion service in many industrial processes in the late 1950s because of its ease of use and overall performance. Corrosion resistant (CR) FRP, as an alternative construction material to alloys, rubber and tile linings, grew steadily in following decades. The aggressive operating conditions associated with hydrometallurgical processes typically require materials of construction that can withstand acids and acid chlorides at temperatures up to 90°C, sometimes higher. Common metallic materials of construction, such as carbon steel, are not compatible with these conditions. High nickel alloys are capable of meeting performance requirements, but often at a high cost. In many cases FRP mining equipment based on epoxy vinyl ester resin (EVER) offers durability, long service life and lower maintenance costs. Through demonstrated performance and decades of case histories, more and more design engineers are confidently specifying FRP as the material of construction for new mineral processing equipment.

Jan 1, 2019

By J. M. Beck

Mineral property appraisers engaged in eminent domain actions on properties for which mining is the highest and best use must be fully competent in all phases of mineral resource estimation, mine project development, and mine operations (or retain the requisite competent assistance), as well as educated in eminent domain appraisal (USPAP Competency Rule). Failure to ensure such triggers the issue of appraisal competence and demonstrates a flagrant disregard of the myriad code(s) and guidelines to which the appraiser is subject. The cavalier assertion of some vague, undefined “latitude” in the valuation process does not exonerate the appraiser from a disregard of the USPAP Competency Rule. Lack of independence (i.e., “advocacy”) in mineral property appraisal is the usual result of a weak background in mining and/or appraisal theory. While it is readily apparent to those able to recognize it in reports and testimony, judges and juries cannot be expected to detect or recognize purposefully misleading (or even fraudulent) valuation concepts or testimony. Purposeful deception by the appraiser can lead to specious over-compensation of the property owner (thus victimizing the taxpayer); or, a failure to provide appropriate and just compensation to the property owner – yet, the purpose of an eminent domain proceeding is to leave the property owner no richer or poorer as a result of the taking. This paper highlights some of the deceptive practices encountered in litigation settings and raises issues of competency, professional ethics, and the effectiveness of the inherent enforcement capabilities within those institutions awarding professional certifications. INTRODUCTION The practice of eminent domain mineral property appraisal requires (particularly with respect to undeveloped mineral properties) that the appraiser possess the requisite level of competence in all phases of mineral resource estimation, mine project evaluation, mine development, and mine operation (through closure). To the extent the appraiser lacks such competence, it is incumbent on the appraiser not only to divulge this lack of expertise but also to seek competent assistance in the performance of the appraisal. This competence or expertise can only be obtained through a combination of appropriate and relevant technical education and direct mining industry experience. There exist a number of professional certification and/or credentialing authorities that speak to such competency. In a similar manner, eminent domain mineral property appraisal (as the term implies) also requires that the appraiser possess the requisite level of competence in the practice of eminent domain appraisal. This competence or expertise can only be obtained through appropriate and relevant education, direct knowledge of appraisal theory, particularly as it relates to the concept of eminent domain, and licensure.

Jan 1, 2019

By K. Parameswaran, A. Veek, A. Fernandez, P. Safe

ASARCO LLC (Asarco) Hayden Copper smelter, in Hayden, Arizona, has operated continuously (except for minor labor and economic curtailments) since 1912. The current plant configuration comprises INCO flash smelting, Peirce Smith (P-S) converting and fire refining/anode casting. In order to comply with the U.S. Environmental Protection Agency (EPA) 1-hour National Ambient Air Quality Standards (NAAQS) for sulfur dioxide promulgated in June 2010, the Hayden smelter had to increase overall sulfur fixation from approximately 95 % to 99+ %, requiring a retrofit of the existing converter department and upgrade of associated emissions controls systems. The Converter Retrofit Project (CRP) involved replacing the five existing 13’ diameter Peirce-Smith converters (2 blowing, 2 hot standby) with three new 15’ diameter Peirce- Smith converters (1 blowing, 1 hot standby) to allow for more effective process gas capture using the existing acid plant contact section. Significant upgrades were made to the acid plant wet gas cleaning section and converter primary gas handling system to improve capture performance, reliability, and sludge handling. In addition, a new tertiary gas capture system was installed to further minimize fugitive emissions from the converter aisle. The existing furnace tapping ventilation ESP was replaced with a new baghouse to enable at least 50% SO2 removal using high-surface-area dry lime injection, which was also implemented on the existing converter secondary gas baghouse system. The first two converters and all gas handling system improvements were started up in April 2018, and the third converter was brought online in November 2018. This paper presents the regulatory context; genesis and rationale for CRP; detailed description of the project; challenges during commissioning; system improvements implemented, and design considerations made, and systems performance and process optimization achieved since startup.

Jan 1, 2019

By G. Stokreef, B. R. Davis, M. Kadiyski, T. LeBel, Alvear Montenegro, R. Parra, V. Montenegro

A drop tower and methodology were developed to study the impact of mineralogy on the flash combustion behaviour of copper concentrates. Reaction shaft conditions of a flash furnace were simulated using a drop tower reactor and different molar ratios of oxygen gas to sulphur in the feed. Five feeds were tested in the drop tower including pure minerals chalcopyrite and pyrite as well as two mineralogically distinct copper concentrates and a blend of the two. The behaviour of each of these five feeds were evaluated through analysis of the solid combustion products for elemental sulphur, mineralogy and particle size. Desulphurization curves for each of the feeds were produced. It is thought that the desulphurization behaviour of pure minerals can be used to estimate the behaviour of a concentrate and that a blending recipe could be developed, which can optimize the chemical and mineralogical inputs to the flash furnace and guide operations on the optimum furnace conditions. Overall, the drop tower has proven to be a useful tool for studying flash combustion processes. Experimental results suggest that mineralogy has a significant impact on the conditions required for the production of matte with consistent grade. This finding is especially significant for custom smelters, which may see several different blends in a day. INTRODUCTION Flash furnace smelting is a continuous feed, batch tap, pyrometallurgical process that is used to produce copper matte from copper sulphide concentrates. Dried concentrate(s), silica flux, and secondary materials are blended to a target chemical composition, typically given by the Cu/S ratio, before processing. This fine, dried feed is dispersed throughout the heated furnace reaction shaft with an O2-enriched reaction gas. The particles heat up in the shaft of the furnace, ignite and undergo reactions that pre-oxidize the iron sulphide and some of the impurities in the feed. Oxidation reactions in the shaft of the furnace desulphurize the feed and produce an SO2-containing off gas. The reacted particles fall into the furnace settler and separate into a Cu-rich matte and an iron-silicate slag, while the SO2-containing off gas is carried out of the furnace for heat and dust recovery, as well as H2SO4 production. Some concerns during operation of the furnace are dusting, over or under oxidation of the feed, and a stable flame.

Jan 1, 2019

By A. Miura, R. Winarko, D. B. Dreisinger

Chalcopyrite leaching in acidic ferric sulfate media at ambient temperature exhibits slow kinetics and poor leaching efficiency, which is typically attributed to surface passivation. Recently, the presence of small amounts of iodide in the leaching media has been reported to significantly accelerate chalcopyrite dissolution. To further explore the behavior of chalcopyrite leaching in the presence of iodide, it is essential to determine the factors that control the leaching kinetics. In this study, we investigated the effect of initial solution potential, iodide concentration, particle size, and temperature on the kinetics of copper extraction from chalcopyrite. The key in the experimental setup was to minimize iodide loss by iodine evaporation and precipitation as cuprous iodide. The former was achieved by performing the leaching tests in fully sealed leaching systems. The latter was achieved by maintaining the solution potential higher than 420 mV (versus Ag/AgCl electrode), where formation of CuI precipitate is possible. The experimental results show that higher solution potential and higher iodide concentration had a pronounced positive effect on the rate of chalcopyrite dissolution. There was no effect associated with particle size, which might be due to the narrow size range tested. The positive effect of increasing temperature only manifested itself when the solution potential was sufficiently high. INTRODUCTION The main challenge of chalcopyrite leaching using ferric ions as the oxidant at ambient temperature is the slow kinetics and poor extraction. The reason for this leaching behavior has been attributed to passivation resulting from formation of insoluble passivating layers on chalcopyrite surfaces, which could be metal-deficient sulfides, elemental sulfur, polysulfides, and iron precipitates (Klauber, 2008). To overcome passivation, technologies using higher temperature and pressure have been developed to leach chalcopyrite concentrates, such as the CESL process (Mayhew, McCoy, Mean, & Woeller, 2013), FLSmidth Rapid Oxidative Leach (ROL) process (Mulligan et al., 2017), Galvanox (Dixon, Mayne, & Baxter, 2008), Albion process (Hourn, Turner, & Hourn, 2012), HydroCopper (Hyvärinen & Hämäläinen, 2005), TPOX (Dreisinger, 2006), and AAC/UBC process (Dreisinger, Dempsey, Steyl, Sole, & Gnoinski, 2003). Even though they are effective in accelerating copper leaching kinetics, those technologies typically have higher capital and operating costs associated with production of concentrates and application of autoclaves. This makes them unsuitable for treating low grade primary copper sulfide ores.

Jan 1, 2019