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By A. Pearson, Auld. F. A., S. O. Colbeck

"To minimise mine shaft maintenance over the long-term, some potash mine shaft sinking projects have required the provision of a continuous fully welded waterproof steel liner over a substantial depth to achieve zero water ingress. This brings many challenges, including the implementation of a bottom-up construction sequence incorporating extensive waterproof welding and how to ensure the integrity of the welded liner when subject to substantial temperature fluctuations that are likely to occur with a composite steel-concrete liner placed within an artificially frozen shaft excavation. This paper highlights the key challenges and discusses multiple mitigation measures including vertical shaft movement joints and a combined structural-thermal analysis approach. INTRODUCTION Whilst the application of combined steel and concrete shaft liners using a fully welded steel liner is not new and has been used in several previous projects, most notably at Lanigan (Storck, 1968 & Roesner, 1980), recently the need to provide a continuously welded steel waterproof liner for over 800 m length of shaft for a potash mine has been considered. The need for a fully continuous welded steel liner arises from the perceived benefits of providing a fully dry shaft environment to; increase the life expectancy of the shaft; reduce routine maintenance particularly combatting salt accretion and minimising wash down practices; and improve long-term ground stability by preventing salt dissolution. Whereas previous projects have employed discontinuous sections of steel liner, when a fully continuous liner is employed longitudinal shaft strains from thermal changes result in significant deformations that must be either explicitly accommodated or resisted. Note, these thermal vertical expansion forces are more than capable of lifting the shaft collar and head frame structures should they be fixed in place. Typically, shafts are designed to resist vertical forces (collar loads and self-weight) by creating mechanical interlock with the adjacent ground. In competent rock this occurs incrementally with the construction of the shaft liner, and occasional hitch/crib structures are constructed as intermediate foundations to guarantee the transfer of vertical forces at distinct horizons. Usually this means cribs are constructed at first rock head, above the station level, and at the sump, although sometimes additional cribs are formed when entering and exiting weak strata or when a change in shaft liner construction is required."

Jan 1, 2019

By Catherine T. Aimone-Martin, Elena Oana Jacobs, Brent Meins

Accurate pressure measurements during underwater detonations are critical for the protection of structures and mitigating impacts to fish and marine mammals. Current guidelines that limit underwater pressures are based on past studies, many of which used sample rates of 48 and 65 kS/s (48,000 and 65,000 samples per second). These sample rates may be insufficient to accurately record high frequency, sharp rise time blast pressures. As such, pressure thresholds associated with fish and marine mammal injury or mortality may be underestimated, calling into question the pressure and sound pressure level guidelines that govern underwater blasting today.

Jan 1, 2019

By Matthew Russell, Bobby Randhawa, Leopoldo Mariscal Samaniego, Jose A. Puente, D. Brosig, Paykan Safe

The La Caridad copper smelter, located in Nacozari, Mexico, have started a multi-year plan to reduce sulfur dioxide and particulate matter emissions into the environment. In 2014 the smelter completed a voluntary plant-wide SO2 process emissions inventory as part of the smelter’s proactive environmental stewardship policy. In turn, this triggered the development of several environmental projects to alleviate these emissions. A strategy consisting of improved capture efficiency of the sources with greatest impact has been followed to maximize cost-effectiveness. The reduction of secondary emissions from the Teniente Converter, as well as of primary and secondary emissions from the Peirce-Smith Converters have been key areas of priority. Additionally, a new system to capture and recover particulate matter from the Anode Refining Furnaces off-gas is also in the process of being implemented. This paper presents an overview of the work developed behind this effort and the smelter’s vision towards a greener future. INTRODUCTION The La Caridad copper smelter is owned and operated by Metalurgica de Cobre S.A. de C.V. (a subsidiary of Grupo Mexico). Currently, the smelter has a production capacity of 300,000 tonnes of anodic copper per year. The smelter is coupled with a 300,000 t/y electrolytic refinery. Other by-products (such as precious metals and sulfuric acid) are also generated as part of an integrated process. The original smelter started operating in 1986 with one Furukawa concentrate dryer, one Outokumpu Flash Smelting Furnace (FSF), two slag cleaning electric furnaces (SCFs), three Peirce-Smith Converters (PSCs), two Anode Refining Furnaces (ARFs) and one casting wheel. In 1997, a plant expansion project was concluded with the installation of one steam dryer, one Modified Teniente Converter (MTC), one additional ARF, one additional casting wheel, and the electrolytic refinery [1]. Over the years, the smelter management has implemented numerous environmental projects to alleviate SO2 and particulate matter (PM) emissions. The smelter process gas handling system captures the process gases from the FSF, MTC, and the three PSCs. The process gases are cleaned and conditioned and sent to the two acid plants. The first acid plant (with a capacity of 226,000 Nm3/h, wet basis) was commissioned in 1988 to process the FSF and PSC off-gases. A second acid plant (with a capacity of 195,000 Nm3/h, wet basis) was commissioned as part of the smelter expansion project [1]. The PSCs also have a secondary gas handling system with a dedicated baghouse and stack. The Furukawa dryer off-gas reports to a dedicated electrostatic precipitator (ESP) for dedusting before venting via a local stack. Process gas from the two SCFs, along with hygiene ventilation from various sources inside the smelter (including matte and slag tapping hoods from the FSF) report to a baghouse-based gas handling system and vent to atmosphere via a local stack. The original ARFs do not have an off-gas handling system, however, each ARF has a post- combustion chamber which naturally vents the process gases to the atmosphere via a dedicated stack.

Jan 1, 2019

By C. Cristonffanini, S. Nazari

"In the past, simulation was considered to be an offline tool disconnected from plant operation. Advancements in the computation power combined with utilizing physics and chemistry sciences have allowed us to significantly improve the modeling and simulation technology for mining and mineral processing. This paper investigates the benefits of first principle models and simulation by connecting them to real time operation. Process data are connected to high fidelity models executed in parallel to the operation. In recent literature, this concept is known as Digital Twins. The Digital Twin is used for various purposes such as optimization, virtual instrumentation and condition monitoring. Using IDEAS™ simulation software we are able to construct a digital twin for different equipment inside a mineral processing plant. Two case studies for building a digital twin for the primary hydrocyclone feed pump and thickener underflow are presented. Using the pump’s model, a digital twin is developed and is installed in a gold extraction plant that is able to infer the slurry density in real time. Additionally, it is used for detecting sanding in the pipes and impeller condition monitoring.INTRODUCTION Since the eighties, thanks to advances in computation technologies, computer based simulation of processes using first principle models has become a well-known engineering tool for various industries. As our understanding of processes has increased, their representative models have become more realistic and more sophisticated. Due to this increase of accuracy, use of simulation is becoming more fundamental in process industries. The main goals to use accurate simulation is to decrease the engineering and construction cost, optimize the process design and improve the operation performance by decreasing operation cost and increasing efficiency. The term Digital Twin was first introduced in 2010 by NASA (Shafto et al., 2012) in aerospace industry. Subsequently, the concept quickly spread through other industries. As of today, no standard organization has provided an official and unique definition of Digital Twin for process industries. However, there are three important aspects that are common throughout various descriptions. When simulation is core functionality of the process (1) along the entire life cycle of the plant (2) with direct linkage to operation (3), it is called that process has a Digital Twin. According to Gartner, the concept of Digital Twin has elected as fourth most important disruptive technology for the year 2018 (https://www.gartner.com/, 2017)."

Jan 1, 2019

By Gamal Rashed, Zorica Radakovic-Guzina, Khaled Mohamed

"Underground coal mines use mechanical bolts in addition to other types of bolts to control the rib deformation and to stabilize the yielded coal ribs. Limited research has been conducted to understand the performance of the mechanical bolts in coal ribs. Researchers from the National Institute for Occupational Safety and Health (NIOSH) conducted this work to understand the loading characteristics of mechanical bolts (stiffness and capacity) installed in coal ribs at five underground coal mines. Standard pull-out tests were performed in this study to define the loading characteristics of mechanical rib bolts. Different installation torques were applied to the tested bolts based on the strength of the coal seam. A typical tri-linear load-deformation response for mechanical bolts was obtained from these tests. It was found that the anchorage capacity depends mainly on the coal strength. Guidelines for modeling mechanical bolts have been developed using the tri-linear load-deformation response. The outcome of this research provides essential data for rib support design.INTRODUCTIONThe design of rib bolting in U.S. coal mines is based on a trial-and-error process, which is insufficient to eliminate injuries and fatalities caused by rib falls. In the last 10 years, rib failures have resulted in 17 fatalities, representing 52% of the ground-fall fatalities in underground coal mines in the United States (MSHA, 2018). Recently, NIOSH researchers surveyed 90 sites in 14 underground coal mines in the Eastern United States and found that 11 mines are bolting coal ribs, with 4 of those mines using the conventional mechanical bolts and the others using fully-grouted bolts. NIOSH researchers are developing an engineering design procedure for rib support. Pull-out test programs for mechanical and grouted rib bolts were conducted to understand the rib control mechanisms of rib bolts. Only the test results of mechanical bolts are presented in this paper.Mechanical bolt (or point-anchored bolt) is a tensioned bolt anchored down the borehole with a mechanical expansion shell or a resin-grouted medium (Peng and Tang, 1984). The mechanical anchor bolt consists of a plug, a shell anchor, a headed bar with the top end threaded, a bearing plate, a hardened washer, and occasionally a friction-reducing washer. The shell anchor can be either standard or bail type (Figure 1). The standard type shell is held in place by a nut, while the bail anchor uses a strap to hold the shell in place (Peng, 2008). The diameter of the bar is generally 16 mm (? in) for the #5 bolt or 19 mm (6/8 in) for the #6 bolt. The diameter of the hole that the bolt is inserted into must be carefully controlled, since an oversized hole can result in poor anchorage (Moss, 1971). The anchorage is obtained by applying torque to the bolt head, which in turn pulls the plug down in the shell and expands the serrated leaves against the sides of the hole-wall. In the resin-grouted anchor, the resin replaces the mechanical expansion shell at the end of the hole. The anchorage is achieved by bonding between the resin, bolt, and the hole-wall."

Jan 1, 2019

By M. Li, T. H. Dubaniewicz, H. N. Dougherty

"INTRODUCTION Underground mines have the risk of accumulation of gases if not ventilated properly or during and after emergency situations when ventilation controls become damaged or stop working. Common gases that are monitored in underground coal are carbon monoxide (CO), oxygen (O2), and methane (CH4). Methane is a gas found in coal and released through mining; its explosive range is between 5% and 15%. Methane is commonly monitored on all mining equipment and with handheld gas sensors carried by most underground coal miners. Fiber optics (FO) is a popular technology applied in underground mining, particularly for its electric isolation. Many miners are familiar with FO cables hung throughout the mine, which are primarily used in the communication of voice and data (Taylor et al. 2010). Advancements in laser and fiber optics have made this technology well suited for gas sensing the harsh environment of mining applications. The work of the U.S. Bureau of Mines on the use of fiber optic monitoring of gases in mines started in 1992. Dubaniewicz et al. (1992, 1993, 1995, 1999, 2003) developed prototype gas sensors, including methane gas sensors, for research purposes. Previous research (Dubaniewicz & Chilton 1992) identified potential fiber optic gas detection cross-sensitivities associated with the index of refraction of various gases. Index of refraction effects was noted for carbon dioxide (CO2), which is produced in significant quantities by mine fires or explosions. NIOSH released a broad agency announcement (BAA) for the development and demonstration of mine safety and health technology (CDC NIOSH 2017). The objective of this announcement was to validate a sensor, specifically fiber optic, for the mine environment and test it in an actual working mine. The RSL FO sensor “OptoSniff” provided from this work is capable of hundreds of sensing points over distances of up to 20 km, has a measurement range of 0.05% to 100%, senses in an oxygen- deficient environment, and has no gas cross-sensitivity (RSL, 2014). The RSL system is totally electrically passive outside the central control unit (CCU), which can be housed in an MSHA-approved explosion-proof (XP) enclosure or in a control room outside of the permissive area. The sensor was tested in dusty and signal loss situations, showing it is tolerant of dust, has functioned at signal losses up to 90%, and was successfully tested in a mine environment for a five-month period (Walsh et al. 2014). This paper describes how the RSL FO sensor is used for testing using smoke and its contaminants for applicability in emergency situations. The testing investigates individual contaminants such as CO2, temperature, and smoke. Each test was performed separately and methane concentration, laser power, and response time data were collected."

Jan 1, 2019

By É. Poulin, J. Bouchard, E. M. Pérez-García

Process control and optimization have always been crucial aspects in the mineral processing industry, and expectations constantly increase to cope with more stringent security, quality, efficiency, and environmental performances. The main challenges to reduce variability of key process variables, and steer profits to higher values while maintaining sustainability indexes within acceptable ranges come from nonlinear responses and circulating loads. The most commonly implemented control strategies rely on simple PID controllers for practical implementation and maintenance considerations. If arguably good performances are accomplished when these are adequately set up, there is also room for further gains by using more advanced methods such as model-based techniques. There is thus a need for more realistic process and equipment models. Based on advances of the past few decades, this paper introduces an autogenous/semi-autogenous mill (AG/SAG) model to be included in a modular comminution circuit simulation toolbox comprising ball/rod mills, material handling, and classification devices. The proposed mill model incorporates a modified version of the classic comminution equation that makes grinding rates proportional to the energy input. It requires the determination of a selection function (fragmentation rates) and a breaking function (fragments distribution). The former is modelled with an S-shaped curve characteristic of AG/SAG processes and the latter is a size-relative distribution of the produced fragments. The power draw is predicted employing the empirical equation of Austin. The paper also develops a case study to illustrate how the proposed simulation framework can capture the behaviour of an actual plant. Model calibration consists in an optimization problem that search the global minimum of the difference between predicted and measured/estimated size distributions, power draw, solid fractions, etc. Results demonstrate that the mill simulator can mimic an actual process in its operation conditions. INTRODUCTION Comminution is a key stage in the mineral processing industry, obviously because the phases of interest must be liberated to be able to recover them. In general terms, the global performance of a plant depends largely on the efficiency of the grinding circuit and on the material properties such as its grindability, density, and mineral grades. The subject has vastly been studied since as early as the 19th century, when Rittinger (1867) and Kick (1883) developed some of the first empirical models to relate grinding and energy input. The great interest in the subject comes from the fact that this operation is costly and, probably most concerning, highly inefficient. Buckingham et al. (2011) estimated that ore comminution can represent up to 60% of the overall plant power draw. Moreover, only a modest fraction of the power draw effectively translates into rock fragmentation. For grinding, estimates range between 1% and 25%, depending on the reference used, while the rest is mainly lost as heath (Fuerstenau & Abouzeid, 2002; Tromans & Meech, 2002; Bouchard et al., 2017).

Jan 1, 2019

By Sushil Bhandari, Amit Bhandari

Blast optimization in open-pit operations is a task that often remains at a theoretical stage. Indeed, when it comes to operational blast design and onsite implementation, time restrictions and field conditions make it difficult to execute a planned pattern accurately and optimization according to local conditions is even more difficult. For example, adjusting a drill pattern to a complex face geometry is not something that can be easily undertaken on site. Blasters and engineers will do their best trying to distribute boreholes over the bench and even then, it can take them hours to achieve an acceptable layout. Similar situations occur with delay sequences, when trying to adjust them to address selectivity or vibration issues. For these reasons, operational blast design will often remain at a very basic level and the required adjustments are laid aside due to the difficulty of implementing them on site.

Jan 1, 2019

By Andrew Artzer, Michael Moats, Jack Bender

Antimony and bismuth in copper electrorefining electrolytes can cause cathode contamination, leading to the careful control of their concentrations. This study examined the laboratory scale removal of bismuth and antimony from an electrorefining electrolyte using a solvent extraction mini-pilot plant. The ability of a proprietary phosphonic acid ester extractant (REX-2) in a commercial diluent was studied in a simulated commercial setting. Antimony and bismuth were both extracted effectively from the electrolyte (72% Bi and 70% Sb removed) and Bi was effectively stripped (92% Bi recovered) with 400 g/L sulfuric acid. A final strip solution was obtained from the SX circuit containing 0.36 g/L Bi, 0.043 g/L Sb, 1.3 g/L Cu, and 0.18 g/L As. Unfortunately, most of the extracted Sb remained in the organic phase. Following the pilot study, experiments were performed to examine the precipitation of bismuth from the aqueous strip phase and the removal of antimony loaded on to REX-2. INTRODUCTION For many years, antimony and bismuth have been some of the most problematic impurities in copper electrorefining (ER) (Bardwell & Lapee, 1933). Along with surface roughening, high concentrations of Sb and Bi can contaminate the copper cathode and precipitate at the copper grain boundaries. This drastically reduces the drawing ability of the metal (Bender & Emmerich, 2016). For these reasons, it is necessary to control Sb and Bi concentration in the cathode, which is done by controlling their concentration in the electrolyte. Conventionally, Sb and Bi concentrations are controlled by maintaining a proper As/(Sb+Bi) molar ratio in the anode and arsenic concentration in the electrolyte. Antimony and bismuth are removed during electrolyte purification using liberators (electrowinning cells) and/or ion exchange. Liberators treat an electrolyte bleed stream from the ER circuit and electrodeposit increasingly impure copper as the copper concentration of the solution decreases. Traditionally, first stage liberators reduce the copper concentration from ~45 g/L to ~15 g/L and produce saleable copper. Second stage liberators decrease the copper concentration to ~8 g/L (Biswas & Davenport, 1980) which results in contaminated cathode that is returned to anode production (Biswas & Davenport, 1980; Wang, 2004). Further electrolyte purification is not always required but third stage liberators can be used to reduce copper concentration below 2 g/L which results in significant removal of As, Sb and Bi and very impure deposits which are recycled to a smelter or used for As production. However, liberators do not have very high energy efficiency (Acharya, 2014; Ando & Tsuchida, 1997) and below 0.5 g/L copper, highly toxic arsine gas may form (Biswas & Davenport, 1980).

Jan 1, 2019

By W. Díaz, R. A. Parra, L. E. Arias, C. A. Toro, M. Marin, E. Balladares, V. Parra, G. Reyes, S. N. Torres, D. Sbarbaro

This work presents visible-near infrared (VIS-NIR) spectroscopy measurements, and signal analytical techniques to characterize minerals and relevant pyrometallurgical process variables for the copper extractive industry. Data signal processing techniques such as baseline correction and numerical analysis are used to estimate the continuous and discontinuous spectral components. Such spectral components are used to estimate the process temperature, and patterns such as the integrated radiation. Also, metal combustion emissivity calculation are depicted. Our findings suggest that VIS-NIR spectroscopy may be a suitable technique to assess the process condition state, appearing as an interesting sensing alternative. INTRODUCTION Although the flash smelting process is one key stage in the copper extractive industry, representing about 40% of copper matte production worldwide (Cantallopts, 2017), few attention is dedicated to develop sensing solutions to assess process variables, such as mineralogical composition and temperature, in the feeding and bleeding stages, compared to the steel industry (Strakowski, et al., 2014). In this process and other industries, e.g. the thermoelectric power generation one, combustion and particularly the generated flame are the production chain’s heart. Since the flame is a highly radiative emitting process where chemical and physical transformations take place, many works had been dedicated to characterize the combustion state by sensing its radiation using optical and photonic technologies (Ballester & García-Armingol, 2010). In this context, this work aims to contribute with visible-near infrared (VIS-NIR) spectroscopy and pyrometry techniques to retrieve relevant information from a laboratory scale flash smelting process. On the other hand, since photonic instrumentation allow us to perform contactless measurements of emitted, absorbed, transmitted or scattered radiation, it appears as a suitable technique for sensing process properties in harsh environments, e.g. high temperature processes. One of these techniques is the Visible- Near Infrared (VIS-NIR) spectroscopy, which provides information about the spectral radiation intensity distribution, in this work, the emitted flame’s radiation. It is well known in combustion research that the spectral emission from a flame is composed by a black body continuous radiation background, molecular emissions, elemental emissions and additive noise features (Arias et al., 2011). To make sense of such information signal processing techniques are needed, here we propose to analyse the continuous and discontinuous spectral components separately.

Jan 1, 2019

By J. Navoyski, B. Macdonald, W. J. Helfrich, J. L. Bellanca, B. Demich

DISCLAIMER The findings and conclusions in this paper are those of the authors and do not necessarily represent the official position of the National Institute for Occupational Safety and Health, Centers for Disease Control and Prevention. Mention of company names or products does not constitute endorsement by NIOSH. ABSTRACT Recent advances in computing, rendering, and display technologies have generated increased accessibility for virtual reality (VR). VR allows the creation of dynamic, high-fidelity environments to simulate dangerous situations, test conditions, and visualize concepts. Consequently, numerous products have been developed, but many of these are limited in scope. Therefore, National Institute for Occupational Safety and Health researchers developed a VR framework, called VR Mine, to rapidly create an underground mine for human data collection, simulation, visualization, and training. This paper describes the features of VR Mine using self-escape and proximity detection as case studies. Features include mine generation, simulated networks, proximity detection systems, and the integration and visualization of real-time ventilation models. INTRODUCTION There are many definitions of virtual reality (VR) that include various levels of immersion and features [1]. Some definitions refer to specific technologies [2], while others are limited to visualization [3]. For this paper, a more general definition of VR will be adopted. VR is defined as the collection of hardware and software that interactively engages users and stimulates their senses within a synthetic or virtual environment. From a hardware standpoint, this can include anything from a phone to a head-mounted display (HMD) to a large-scale theater as well as speakers, microphones, haptic sensors, and interaction devices. The software used to create virtual environments (VEs) generally includes a game engine, custom software components and libraries, and two-dimensional and three-dimensional graphical assets. Recent hardware and software advances have increased the fidelity and availability of VR. New and improved technologies including HMDs and high-resolution monitors and projectors can display sharper, more detailed visualizations. For example, in the past five years between the release of the Oculus Rift DK1 (2013) and the HTC Vive Pro (2018), there was a three-fold increase in resolution along with a 50% increase in the refresh rate. Furthermore, despite early claims that low-cost VR technology was readily available [4], computational power has not been sufficient to handle the large amount of data generated by these systems [5]. In the past five years, however, rendering speeds have more than doubled and memory has more than tripled [6], allowing these visualizations to be incorporated into higher-complexity and -fidelity VEs that more closely mirror the real world. Similarly, software capabilities have also significantly improved through game engine advancements and feature development. In the past several years, game engines have added and improved features such as physics, lighting, platform support (e.g. Android), and asset development integration. Some of the current leading commercial game engines are Amazon Lumberyard, CryEngine, Unreal, and Unity, but this can quickly change as is evident in the literature [7, 8].

Jan 1, 2019

By Greg Canivan, Bernie Hertlein, Les Chernauskas, Joram Amir, Garland Likins, E. Anna Sellountou, Tim Kovacs, Peter Kandaris

Nondestructive testing of drilled shaft foundations via Crosshole Sonic Logging (CSL) is often performed as part of the quality assurance process to assess the soundness of concrete. The intent of CSL testing is to identify irregularities such as soil intrusion, necking, soft bottom, segregation, voids and other defects that could result in poor structural performance of the foundation. Over time, CSL rating criteria based on first arrival time and relative energy have incorrectly evolved to often be the sole means of determining the acceptability of a shaft. Some of these criteria have found their way into regulatory agency specifications, with acceptance values often differing from agency to agency.The purpose of this document is to review the state of the practice (including experience gained over the past 20 years), propose improved CSL rating criteria and make recommendations for additional assessment, as well as educate the industry on the proper interpretation of CSL test. CSL test results alone should not be the sole means of rejecting or accepting a shaft. A task force of industry exerts was formed to review the existing CSL rating criteria and propose improvements where appropriate. The recommendations presented herein are the consensus of the task force, which believes that they should be incorporated into future criteria, codes and specifications. This paper was produced as a joint effort between the Codes and Standards Committee, the Drilled Shafts Committee and Testing and Evaluation Committee. A task force was authorized under Testing and Evaluation Committee. The task force contributed their expertise in web-based discussions often every two weeks over a period of three years. Interested participants were invited to participate at any time. The document had two rounds of broad industry review, two rounds of DFI Technical Advisory Committee reviews, and a Public Comments process. All comments were considered in producing the final document.

Jan 1, 2019

By M. S. Moats, C. M. Campbell

Samples of a high impurity (90.05 wt. % Cu, 4076 ppm Pb, 1939 ppm As and 635 ppm Bi) commercial copper anode were characterized and then electrorefined in a laboratory scale cell. Anode inclusions were examined using backscatter mode scanning electron microscopy and energy dispersive spectroscopy. Hundreds of inclusions were measured for size, morphology and composition. Commonly found inclusions were copper oxide (Cu2O), complex oxides (Cu-Pb-Bi-As-O) and copper selenides/tellurides. The weight percent of lead and arsenic increased with increasing inclusion size up to 4- 5 microns. During electrorefining, starter sheet ductility was negatively impacted by thiourea addition. The importance of arsenic (V) concentration on the electrolyte concentration of bismuth was observed. INTRODUCTION Copper electrorefining is a commercial process used to produce the majority of the world’s refined copper. During this process, impure copper anodes are dissolved electrolytically, and high purity copper is deposited on cathodes. As the anodes dissolve, the impurities either accumulate in the electrolyte or report to solids that form on anodes surfaces or at the bottom of the refining cell. These solids are called slimes. Slimes contain precious metals and are collected for further processing. Slimes are also an important outlet for problem impurities such as lead, antimony and bismuth. The electrorefining process is operated in such a way to encourage the deportment of these elements to the slimes. Impurities in copper anodes have been studied extensively by Chen and Dutrizac (1990, 1993 and 2005). The most common impurities found in modern copper anodes include: Ag, As, Au, Bi, Fe, Ni, O, Pb, Sb, Se, Sn and Te. Impure copper anodes are produced by pyrometallurgical methods and have purities ranging from 97.7–99.7% Cu (Moats et al., 2019). The composition ranges of commercial copper anodes from the 2019 worldwide tankhouse survey are given in Table 1. The concentrations of anode impurities vary widely dependent on the source material and prior processing steps. Based on the work of Chen and Dutrizac, both gold and silver are predominantly found in solid solution within the copper grains while a minor amount of Ag can be found in Cu2(Se/Te) inclusions. Nickel is entirely soluble within the copper grains up to anode compositions of 2500–3000 ppm Ni; above which NiO and kupferglimmer phases are formed (Chen & Dutrizac, 1990). As, Bi, Pb and Sb are found in solid solution within copper and within oxide inclusions typically found along grain boundaries. Oxides are formed due to the presence of 0.13-0.18 wt. % O (Chen & Dutrizac, 1990). This is because during solidification of the cast anodes, impurities are enriched in the liquid phase as the copper grains nucleate and grow. The inclusions form from the last liquid to freeze, which is typically along grain boundaries (Wenzl & Filzwieser, 2007; Wenzl, Filzwieser, Mori & Pesl, 2008).

Jan 1, 2019

By Y. X. Li, L. R. Xiao, S. Gong, S. S. He

Porous copper and porous copper based alloys with controllable pore structure have been manufactured successfully by sintering evaporation process. This process consisted of mixing copper or copper based alloys with NaCl powders, hot pressing and final high-temperature sintering to evaporate the filler material of NaCl powders. NaCl was eliminated completely during vacuum sintering, and strong metallurgical bonding in the walls was achieved. The pores’ structural parameter (pore size, shape, and direction) and porosity can be controlled effectively. These porous copper and porous copper based alloys with controllable pore structure have great potential in many fields. Including heat dissipating materials, heat absorbing materials, chemical catalyst carriers, electromagnetic shielding materials, filtering materials, damping materials, silencing materials, battery electrode materials. INTRODUCTION The development of porous materials began in the 1960s. The research of activated carbon with high specific surface area made porous materials enter the stage of material research (Belyakov et al., 2008; Ferey et al., 2008). With the rapid development of science and technology, porous materials play an important role in material research, and gradually become an indispensable part of the material research field (Wu et al., 2012). The research of porous materials has gradually extended to metal, ceramics, plastics and glass and other fields. It has been successfully applied in many fields, such as functional materials, industrial production, aviation, medical materials, biochemistry and electronics, which fully shows that porous materials have considerable development prospects. Porous silicon, plastic porous materials and glass porous materials are the most widely used in the field of non-metallic porous materials (Capelle et al., 2012). Compared with non-metallic porous materials, metal porous materials have developed rapidly in the late 1980s and become new materials with good mechanical properties and excellent physical properties. Porous metal materials have many advantages, such as large specific surface, small specific gravity, good silencing effect, high stiffness, high electromagnetic shielding performance, good shock absorption performance, etc (Li et al., 1999; Ferey et al., 2008). Among its many applications, metal porous materials can be used as both functional materials and structural materials. In some cases, metal porous materials have dual functions and structures. It is a multi-purpose engineering material with excellent performance. At present, porous copper, porous aluminium and porous nickel are the most concerned materials (Chen et al., 2002; Yang et al., 2017; Liu et al., 2018). The preparation methods of porous copper and copper-based alloys mainly include self-propagating high temperature synthesis (SHS), capsule-free hot isostatic pressing (CF-HIP), spark plasma sintering (SPS) (Kvanin et al., 2008; Takahashi et al., 2008; Zhang et al., 2014). However, these methods can not accurately control pore structure parameters (including pore size, shape, orientation, distribution, etc.). In porous materials, pore structure plays an important role in the overall performance of materials. In order to control pore structure parameters accurately and optimize material performance, it is necessary to explore and develop new preparation technology. In this paper, the sintering evaporation process (SEP) was introduced for the preparation of porous copper and copper-based alloys. The core process of the preparation method is hot pressing and evaporative desalination. Hot pressing can make the pore orientation consistent. Evaporative desalination can ensure the complete removal of NaCl in the form of vapor in a short time, thus eliminating the corrosion of residual NaCl on the matrix metal (Gong et al., 2011).

Jan 1, 2019

By S. K. Kawatra, S. Valluri

With increased CO2 emissions from steel and coal industry, there is great opportunity to capture CO2 and utilize the captured CO2 for economic advantage. The primary goal is to develop energy-efficient processes that reductively couple CO2, an abundant and renewable carbon source, for the production of value-added chemicals such as methanol, ethanol, and oxalic acid. These chemicals can be used elsewhere in the refining process or sold as valuable by-products. Geological sequestration, in comparison, has no economic return. Current CO2 utilization research at Michigan Technological University focuses on electrochemical reduction of CO2. Electrochemical reduction of CO2 to hydrocarbons and other chemicals is a complex multistep reaction with adsorbed intermediates. The exact reaction mechanisms leading to various products are not clear from the literature to date and will likely change over the range of conditions like pH, electrode potential, electrolyte medium, catalyst, etc. This paper will present different ideas and their viability to utilize CO2 as a feedstock to produce several value-added compounds. INTRODUCTION Carbon dioxide (CO2) emissions into the atmosphere will need to be drastically reduced to curb the various undesirable effects of climate change. The large contribution in total CO2 emission originates from coal or natural gas power plants, and a considerable amount from steel plants. Average CO2 emissions in the US from steel industry is 2.9t CO2/t steel (Global CCS Institute 2013). Capturing the available CO2 from the steel and coal industries for economic advantage is a win-win situation for the industry. This technology is not only important scientifically but is also vital for a sustainable future. The various ongoing investigations can be categorized as biochemical, thermochemical, photochemical, and electrochemical approaches. Among these, the electrochemical method shows the most promise as an efficient form of CO2 conversion technology, because of its many advantages like high reactivity under ambient conditions and good extensibility from small- to large-scale processes1 BACKGROUND Extensive research has been done on the chemistry of transforming carbon dioxide into more useful products. Methods are known to convert carbon dioxide into a wide variety of substances, including methanol, isobutanol, carbohydrates, methane, carbonates, urea, formic acid, oxalic acid, carbon monoxide, epoxides, formaldehyde, and so on. Several of these (carbohydrates, formaldehyde, isobutanol etc.) are primarily results from biological processes. The rest are results of strong reduction reactions or electrolytic reduction. In short, electrolytic reduction can be used to form methane, methanol, formic acid, oxalic acid, carbon monoxide from carbon dioxide2. CO2 reduces at the cathode in an electrolysis cell. These processes have the general form of generating the carbon dioxide anion radical (2⋅−) and allowing it to react with itself or the electrolyte3. Catalysts can be added to influence the formation of the anion radical or to suppress side reactions3. The electrolyte, catalyst, voltage, electrode material and CO2 content are all known to effect the reaction pathway. Table 1 shows the overall reactions and energy requirements for electrochemical conversion of CO2 to chemicals

Jan 1, 2019

By Kalyani Devabhaktuni, Mike Minton, Mark T. Howe, Yan Zhang

During the procurement phase of a Design-Build (DB) project, design-build contractors must often commit to a fixed price based on limited or incomplete geotechnical information. This lack of information can result in an inaccurate assessment and allocation of project risk to either the contracting authority or the DB contractor. This paper presents a case study of an elevated water tank supported by mixed ground improvement techniques, including Vibro-Compaction (VC), Aggregate Piers (AP) and Compaction Grouting (CG) in East St. Louis, Illinois. An adaptive design and contracting approach provided the best value solution for a complicated set of geotechnical problems, including static bearing capacity and settlement concerns as well as liquefaction induced settlement. Close cooperation between the owner, the tank contractor, the geotechnical engineer and the ground improvement contractor was essential to produce an effective solution. Ground Improvement techniques resolved the geotechnical challenges at the site through adaptive design methods, utilizing progressive rounds of verification and real time data acquisition to achieve performance objectives. This paper details the evaluation of geotechnical criteria, the selection of ground improvement techniques, the adaptive design and implementation of ground improvements, as well as contracting methodologies used to ensure that the best value was provided. PROJECT INFORMATION In November, 2016, CB&I Storage Tank Solutions (McDermott) submitted a design/build proposal for an elevated water tank for Illinois American Water Company (IAW) in East St. Louis, Illinois. The purpose of this tank was to have backup water capacity for power generation. In the RFP, IAW requested two alternate styles of tank: Option 1, a 1250 Million Gallon (MG) Composite Elevated Tank or Option 2, a 1250 MG Waterspheroid tank. Option 1 consisted of a steel tank supported on a concrete tower. Option 2 consisted of a steel tank supported on a steel shaft. The height (determined by IAW) was 140 feet to the top capacity line measured from top of floor slab.

Jan 1, 2019

By Brian Koch

Michels installed 242 drilled shafts to support the piers for a new basket-handle, true-arch twin bridge across the Mississippi River from Moline, IL to Bettendorf, IA. The installation of the drilled shafts was completed with the simultaneous use of two Liebherr LB36 and one IMT 300 drill rigs. Utilizing barges, 233 drilled shafts were installed in the river. Michels crews also installed 7-ft to 10-ft permanent steel casing into the bedrock, and drilled to depths of 60 feet for each shaft. Despite working in strong currents, freezing temperatures and on rocking barges, Michels crews placed the shafts within 3 inches of plan position. Since the drilled shafts are the key piece in supporting the bridge structure, Michels provided cross-hole sonic logging to verify the integrity and strength of the concrete within the shafts and to add another level of quality control for the owner/customer. Extensive planning took place each day to ensure that tugboats, the linchpin of the project, were being efficiently utilized to shift the barges and materials daily. On any given day, Michels transported five concrete trucks by barge from shore to shaft sites to pour between 40 and 240 cubic yards of concrete. The Michels environmental team was diligent with preparing, discussing and implementing a water treatment plan that was accepted by all state and federal agencies and adhered to strict environmental regulations. Grain hopper barges were rented to control and treat the water that was used in the drilling operations. Another challenge crews ran into was the discovery of caverns when drilling into some parts of the bedrock. Michels worked with the engineer to develop a plan to construct the drilled shafts that encountered the caverns.

Jan 1, 2019

By Piotr Kozlowski, Stanley L. Worst, Matthew J. Niermann

Circular secant pile shafts were installed along the tunnel alignments for both the Ohio Canal Interceptor Tunnel project in Akron, Ohio and the Ohio River Tunnel project in Louisville, Kentucky. The diameters ranged from 34 to 51 feet and the depths ranged from 49 to 107 feet. Verticality and concrete volumes were measured on all piles to verify compliance with the design, which for some shafts consisted of a finite element model with multiple openings using unreinforced concrete secant piles. All secant piles were drilled into rock to seal off the groundwater. This paper will discuss the design, construction and quality control of the secant piles for these projects. INTRODUCTION Many Midwest and Northeast cities have Combined Sewer Overflow (CSO) systems which discharge pollutants into waterways during wet weather events. One way to remedy this issue is to provide a temporary overflow tunnel. A temporary overflow tunnel connects to the combined sewer system and collects the overflow during wet weather events, storing the wastewater until the event has subsided. After the storm event, the stored wastewater can be pumped to the treatment facilities and processed as normal. Project Background – Akron, OH The Ohio Canal Interceptor Tunnel (OCIT) project was performed as a result of the Environmental Protection Agency’s (EPA) Consent Decree with the City of Akron, Ohio. This Consent Decree required modification of the existing Combined Sewer Overflow system. The resulting project consisted of a 27- foot diameter tunnel with multiple points of entry to capture the sewer overflow and prevent it from entering waterways. The tunnel is over 6,000 feet long and is as deep as 150 feet below the ground surface; see Figure 1 below.

Jan 1, 2019

By David S. Graham, Paul J. Axtell

Crosshole Sonic Logging (CSL) non-destructive integrity testing identified anomalous readings near the base of a 6.5-foot diameter drilled shaft rock socket. The anomaly was confirmed to be a defect by subsequent coring and core hole camera inspection. A large void and exposed rebar were visually observed in one of the core hole camera inspections. The center of the shaft was then excavated initially with 3-foot diameter tooling and subsequently with 4-foot diameter tooling as part of the remedial actions to address the defect. While excavating with 3-foot diameter tooling, the shaft defect was not encountered. Excavation with 4-foot diameter tooling revealed the defect, a significant void around the majority of the shaft circumference. The void extended radially from the circumference of the 4-foot diameter excavation to beyond the reinforcement cage to the exposed wall of the rock socket around approximately 80 percent of the shaft circumference. CSL results and observations made during remedial shaft investigation and excavation are in good agreement. The shaft defect, located primarily outside of the reinforcement cage, was effectively identified by CSL testing. Although the defect was confirmed by investigative coring, the remedial excavation demonstrates how the investigative coring could have easily missed the defect. This paper shows how CSL results compare to physical observations made during a rare opportunity to characterize the full extent and nature of a drilled shaft defect originally identified as an anomaly by CSL testing. INTRODUCTION The case history presented here pertains to a drilled shaft for a multi-shaft bridge pier in the Midwestern United States. However, the observations presented in this paper are not a result of unique site conditions or the particulars of the project. The lessons learned from this case history are applicable to almost any drilled shaft constructed in the wet. The overall length of the subject shaft is 22 feet including approximately 12 feet of permanently cased, 7-foot diameter shaft extending to bedrock and approximately 10 feet of uncased, 6.5-foot diameter rock socket. The shaft is designed to resist axial and lateral loads and considers the contributions of side and base resistance in the axial design. Six, 2-inch diameter steel Crosshole Sonic Logging (CSL) tubes are include in the shaft. The bedrock at the shaft location includes beds of sandstone, shale, and limestone. The shaft was drilled using conventional drilling equipment and tooling, and water was used as the drilling fluid. Conventional drilled shaft concrete appropriate for underwater tremie-placement was placed via a 10-inch diameter open hopper tremie.

Jan 1, 2019

By Karl A. Higgins, Michael D. Venezia

The South Capitol Street Corridor Project is one of the District Department of Transportation’s (DDOT) largest projects, and is currently under construction. This case study will focus on the design of the foundation piles for the main spans of the iconic Frederick Douglass Memorial (FDM) Bridge, and will include a discussion of the foundation design evolution from an originally designed alternative foundation system (i.e. coffer dams and drilled shafts), to the current use of driven Large Diameter Open End Pipe (LDOEP) Piles. The paper will provide a discussion of the design methodology used during preliminary engineering and final design, and will highlight insight gained from the extensive load testing program completed to date. The load testing program consists of a combination of high strain dynamic testing (PDA), as well as Statnamic Load Testing on select sacrificial, pre-production test piles. Specifically, data gathered during the nearly-completed load testing program suggests the development of significant internal shaft frictional resistance within the tested LDOEP Piles. This paper will also discuss limitations of currently accepted industry design methods for predicting the capacity of LDOEP piles, a subject that is also currently being researched by FHWA. The data from this test pile program will help design assumptions for future projects. INTRODUCTION The Frederick Douglass Memorial (FDM) Bridge carries South Capitol Street across the Anacostia River in Southeast/Southwest, Washington, DC, and is owned and maintained by the District Department of Transportation (DDOT). The existing FDM Bridge is nearly 70 years old, serves as a major artery into the city, and has been classified as functionally obsolete. As a result of the condition, age and limitations of the existing bridge structure, DDOT deemed it necessary for complete replacement of the bridge. The replacement project consists of the construction of a new bridge traversing the Anacostia River, as well as the reconfiguration of the Suitland Parkway and I-295 interchanges located at the eastern terminus of the FDM Bridge. Final design and construction services for the replacement project were procured by DDOT through a Design-Build contract. This paper will focus on the driven Large Diameter Open End Pipe (LDOEP) Piles used for support of the main span of the new FDM Bridge which is currently under construction. Discussion regarding the LDOEP Pile design methodology has been included, along with commentary regarding currently available industry guidance related to design and construction of LDOEP Piles. Much insight has been gained during the mostly-completed and extensive load testing program which consists of a combination of high strain dynamic testing (PDA), as well as Statnamic Load Testing on select sacrificial, pre- production test piles. Specifically, data gathered during the mostly-completed load testing program suggests the development of significant internal shaft frictional resistance within the tested LDOEP Piles.

Jan 1, 2019