Search Documents

By H. I. Aaronson, W. L. Winterbottom, G. M. Pound

On the basis of a statistical thermodynamic treatment of the data of smithz2 on the activity of carbon in austenite, a Darken and smith23 deduced that the interaction energy, wy, between carbon atoms occupying nearest-neighboring interstitial sites is repulsive. Aaronson, Domian, and pound 24 (ADP) have applied two different statistical thermodynamic analyses to the same data. One analysis, a composite of the treatments of Darken and Smith,23 Speiser and Spret-nak," and Kaufman, Radcliffe, and Cohen,26 primarily takes account of the positional entropic effects of wy in dilute solutions. The other, due to Lacher 27 and Fowler and Guggenheim," is also applicable to more concentrated solid solutions. The equations which both analyses produce for a,, can be rearranged so that, when In a,, is plotted against the appropriate function of the carbon content of the austenite, the plot will have a slope of unity when the correct value of wy is employed. Since no other constant need be simultaneously evaluated in order to make this determination, ascertaining the most probable value of wy from Smith's data on the bases of these analyses was an elementary problem in least-squares statistics. ADP demonstrated that the wy's obtained from both analyses vary with temperature in a statistically significant manner. McLellan, Gerrard, Horowitz, and sprague 29 (MGHS), on the other hand, have recently made a new statistical thermodynamic study of a,, and have concluded from this study that wy is independent of temperature. The equation which they derived for a,, is: where 0 = ratio of the mole fraction of carbon atoms to that of iron atoms, z = number of sites from which occupancy is excluded by the presence of a carbon atom and the repulsive character of its interaction with nearest-neighboring carbon atoms (z = zb in Ref. 24), and x = a geometric parameter taking account of overlapping of the exclusion shells of nearby carbon atoms. z is 1 when wy = 0 and 13 when wy = Q. For a given value of z there is a definite value of X . In the absence of an equation connecting z and X, MGHS computed geometrically the value of x at several integral values of z; x increases from 0.47 to 8.67 as z is increased from 2 to 5. MGHS fitted Eq. [I] to the a,, data of Ellis, Davidson, and Bodsworth30 at 925° and 1050°C and to the data of smithz2 at 1000°C. Confining z to integral values in the range 4 to 6, and also somewhat restricting AG, the values of z, X, and AG were sought which would minimize the average root mean square percent deviation, D, of the calculated a,, values from those obtained experimentally. Finding that D was almost always smallest when z = 5, they concluded that z is independent of temperature. Since:23, 26 where R = gas constant and T = absolute temperature, and w,, was considered to be similarly invariant, this statement cannot be strictly true. The temperature range employed, however, was small and the interval between the values of z tested was sufficiently large so that the results could still be consistent with a constant The statistical treatment of the a,, data applied by MGHS is clearly quite approximate. Since more than three values of a,, are available at each temperature, z, and X, and AG have actually been over deter mined, rather than underdetermined as their treatment implies. In order to make more complete and exact use of the a,, data, we shall employ the Legendre Method of Least Squares, as described by Whittaker and Robinson. This technique permits conversion of the overdetermined system of equations produced by the substitution into Eq. [I] of the available pairs of a,, and 0 data at a given temperature into an even determined system. Solution of the latter system yields the most probable value of each of the three constants. This procedure will allow a statistically rigorous test to be made of the conclusion drawn by MGHS in respect of the temperature dependence of In order to obtain linear iiequations of conditions" from Eq. [I], the exact values of the three unknown constants are replaced by G/RT = =/RT + y, where z, i, and aG are estimated values of the constants. This allows the conditional equations to be written in the form:'l where fi -f6, i, =/RT) = the right-hand side of Eq. [I] for a given pair of ayi and values. When applied to Eq. [I], these relationships become: The i equations of condition are reduced to three "normal equations" in the manner discussed by Whittaker and Robinson. The normal equations are then solved for a, ß, and y. Both of these operations are most conveniently performed by means of the computer technique of Winterbottom and Gjostein.32 This technique was used iteratively until the value of 0 (the most sensitive of the three correction factors) became 10.01. (Until they became small, a, 8, and y

Jan 1, 1969

By L. D. Jaffe

IT is now well established that quenched and tempered titanium alloys have much better ductility when the quenching is from a two phase a-B structure, rather than from an all B structure. The corresponding microstructural differences, however, have not been shown in previous publications. Accordingly, specimens were cut from a % in. rod of commercial RC-130A, containing 7.9 pct Mn and 0.12 pct C, which had been previously hot rolled, heated 1 hr at 1100°F, and air cooled. (The same heat has been studied by others." 7 Samples about 1/4 in. cube were heated in helium 1/2 hr at 1450' or 1700°F, quenched in brine, tempered in helium 1 hr at various temperatures up to 1250°F, and quenched in brine. They were then sectioned and metallo-graphically examined, using an etchant of HF-HNO, in glycerine. As quenched from 1700°F, the microstructure observed was clear /3. (Probably also present was U, as the hardness was 400 Vhn, but w is not yet reliably revealed by any metallographic technique.) When the /3 quenched alloy was tempered at a high temperature, a precipitated as a grain boundary film

Jan 1, 1957

By J. M. Stewart

Mining fatality rates in many countries have not changed substantially over the past ten years. This demonstrates not only that there is an inherent risk in mining, but also that current approaches to improving safety need to be rethought. An analysis of productivity and fatality data in the United States, United Kingdom, and South 4frican coalmining industries shows that the impact of legislation on safety is overlain by other significant factors. Although improvements in safety and productivity usually occur together, the data warn that safety legislation can sometimes cause a significant reduction in productivity. Based on the data and experience considered, it is concluded that legislation should be aimed at creating a framework within which a positive attitude towards the implementation of more productive and safer mining methods, work practices, and technology can flourish, rather than attempting to enforce excessively prescriptive provisions. This later approach is even more problematic when safety standards and legislation are transferee from well developed to less developed countries. A legislative framework in which the mine manager is required to take al reasonably practicable measures to procure safe working conditions in accordance with mine-specific codes of practice is outlined. Within that framework, the value of adopting widely accepted standards is recognized. A performance-based external audit arrangement is outlined as a basis for ensuring that detailed attention is focused on those areas most needing improvement.

Jan 1, 1995

THE area of the State of New South Wales is not great, nevertheless it has very large and important Mineral Resources. This is the more noticeable when the values of the annual mineral production from the individual States of the Commonwealth arecompared with the value of the New South Wales production. The principal minerals mined now are not gold, copper, and tin, as they were in the early years following the gold rush of 1851, the centre of gravity of commercial mineral activity having moved to coal and "oil-shale," water, limestone (with cement), silver-lead-zinc cadmium, sulphur, slate and other building and ornamental stone, road materials, and clays.From small areas totalling only 650 sq. miles, coal to the extent of 311,000,000 tons, valued at £151,000,000, has been won.The estimate of actual and probable reserves by the Mines Department within an area of less than 1000 sq. miles is about 14,000,000,000 tons, while the potential reserves within the remaining 15,500 sq. miles of concealed coal fields must be enormous. Even taking into account only the actual and pI:obable reserves in the 1000 sq. miles known, and assuming a depletion at the rate of 350,000,000 tons a year, or somewhat greater than that of the British Isles at present, and assuming an average value of £1 a ton, with money at 5% compound interest, then the present value of this coal (40 years of depletion) would be £5,575,000,000 approximately: truly an enormous present value for a business of 40 years, dealing only with 1000 sq. miles of country. The location of the main coal basin in New South Wales is one of great strategic importance. It lies almig and near a seaboard, with excellent facilities for anchorage; the coal is of very high quality, and is readily accessible; the climate is admirable. Were this same coal at Port Darwin, its commercial importance would not be be pronounced.

Jan 1, 1926

By J. L. Boyd

The mining and processing of basic metals relies on water as a medium for transport. Metallurgical ores are ground, concentrated, leached and refined in an aqueous medium. Water is used for temperature control during processing and in air pollution abatement during smelting. All of these process steps result in liquid wastes. Many of the aqueous wastes from ore processing areas become the raw product for a second stage and water recycling may begin. The point at which water recycling or reuse has been initiated in the past, rather than water discharge, was where water conservation was manditory due to a shortage, where process conditions would allow or benefit from reuse, and where economic considerations demanded reuse. The Fontana, California plant of Kaiser Steel Corporation is an example of an integrated steel plant that was forced to practice water conservation and reuse due to its location in an arid environment.1 Only a small amount of water required to maintain the water reuse system in balance with respect to dissolved solids and product quality is discharged. The Butte, Montana copper ore processing plant of The Anaconda Company obtains 66% of the water required for production by recycling, after clarification and chemical treatment, 30 MGD of wastewater from its tailings ponds. This operation is estimated to save the company about $1200/day over a once through water system.2 Here plant location and economics favored water reuse.

Jan 1, 1975

By Pathan AG

This research work is concerned with an investigation of the fracture toughness of sandstone, siltstone, and coal. Tensile failure trades have been examined with three different specimen geonetries, i.e; rectangular bar, round bar (in three point bending), and diametral compression discs. The Stress intensity approach, and J-integral methods were used to evaluate fracture toughness. Results from both approaches are discussed. True crack length was determined after pre-cracking, using the compliance calibration technique. Fracture toughness results of sandstone are independent of crack length and the size of the specimen. Fracture toughness may hence be regarded as a material property for sandstone. In cxnntrast fracture toughness values for !siltstone and coal are dependent on crack Length.

Jan 1, 1986

By S. -Y. Hwang

An ongoing problem for industry in Korea is effective removal of heavy metals from and safe disposal of spent power plant fly ash. This research endeavor attempts to develop selective separation of Ni from leach liquor using a selective chemical precipitation method. The research was conducted by changing two variables, the pH and the concentration of ions in solution. The effect of other ions present in the system on the separation efficiency of Ni species was also investigated by adjusting OH and NH3 concentrations. In the pH range of 7-9, the chemical precipitation method produced a high yield of Ni by precipitation from the fly ash leach liquor.

Jan 1, 2010

By Gillies A. D S, Lee A. H

Water is an integral component of a mining operation. To-date water management has received a low profile in the overall management of mining operations. To cost effectively meet the requirements of government environmental legislation the man

Jan 1, 1994

By Anestis Vlyssides, Elli Maria Barampouti, Sofia Mai, ?postolos Vlyssides

"A new anaerobic reactor variation, the UASB/CO2-stripper reactor was conceived. It consisted of a conventional UASB reactor that recirculated the biogas produced. The sludge characteristics of this system were examined when treating high strength wastewater. From the data collected, it was obvious that the UASB/CO2-stripper system can satisfactorily operate at higher loading rates (25 g COD·L-1·d-1). A pronounced effect on the quality of the granular sludge was observed. The VSS/TSS ratio decreased sharply. A considerable decrease in the mean granule diameter was observed, while the specific gravity of the granules increased. The sludge bed porosity increased significantly leading to a considerable expansion of the sludge bed. These changes in the sludge properties led to a gradual shift of the system towards a fluidized bed process as far as its hydraulic characteristics were concerned.IntroductionIn recent years energy considerations and environmental concerns have increased the interest in direct anaerobic treatment of industrial wastes. The anaerobic method of waste treatment offers, under the present circumstances, a number of significant advantages with trivial or more serious drawbacks over other treatment methods. The major obstacle to the application of the process for this specific purpose is perhaps the difficulty of extending it to a stable and simple operational form. A number of reactor configurations has been developed leading to high biomass concentrations, e.g. the contact process, the filter reactor, the UASB reactor, and the fluidized bed systems, but the process stability problem still remains [1].A prime objective in the operation of anaerobic waste treatment process is the maintenance of a proper pH range. Thus, a possible solution to the process stability problem could be obtained by increasing alkalinity in the anaerobic systems. Therefore, the main objective of this paper is to present and evaluate the results of a system (UASB/ CO2-stripper) with increased alkalinity concentrations."

Jan 1, 2008

By B. Orberger

The fine fraction (< 2 mm) of the high grade Mn-ore from the world class Moanda deposit, Francevillan basin, in Gabon, contains up to 30 wt. % of manganese and about 0.4 wt. % phosphorous. A pilot study at laboratory scale integrating mineralogy and geochemistry before and after ultrasonic treatment was conducted on the fine fraction (< 2 mm) of oxidized Mn ore in order to reduce the phosphorous content and enrich this fraction in manganese. The fine fraction was dried, crushed at 2 cm and sieved at 2 mm. The two fractions (< 2 mm and 2 mm ? 2 cm) were investigated by X-ray diffraction and scanning electron microprobe ? electron dispersive spectroscopy analyses. Both fractions contain lithiophorite, cryptomelane and pyrolusite as Mn carrier, and goethite, muscovite, illite and quartz as contaminants. The Mn hydroxide nsutite was only found in the fraction 2mm ? 2 cm.The < 2 mm fraction is significantly richer in goethite, muscovite/illite, and quartz. Phosphorous carriers are mainly goethite (up to 2.8 wt. % P2O5), while the Mn minerals contain up to 0.8 wt. % P2O5. The Mn minerals are partly included in an agglomerate of goethite, muscovite/illite, and quartz. The < 2 mm fraction was treated by ultrasound for 30 s in normal water. Mineralogical and chemical analyses after ultrasound treatment showed that the Mn-minerals were largely liberated from the goethite-muscovite-illite agglomerate. Mass balance calculations show that after ultrasonic treatment the < 2 mm fraction was ? 50 % enriched in Mn and ?50 % impoverished in P.

Sep 1, 2012

By Yang Jun, Qu Mei, Zheng Yao-wu, Chi Li-yuan

Due to the necessity of the prediction of blasting seismic effect around strip mine bench blasting area, the paper provides a method to predict the blasting seismic effect by employing the superposition of seed waveform at different monitoring points. The method assumes that blasting vibration waveform per hole is similar to seed waveform at monitoring point. Therefore seismic wave consists of the superposition of the waves from all of blast holes. Firstly, via sensors multiple seed waveforms can be achieved at different distances from signature hole. Then, by using the given dose and the distance, the vibration waveform of a certain blast hole can be calculated by the corresponding seed waveforms. Finally, the initiation delay time interval per hole is added to the propagation time to the predicting point. The predictive waveform at the whole blasting area can be obtained by superimposing all of the single waveforms. Considering the vibration waveform of a single blast hole changes greatly with the distance, under different distances condition the seed wave employed to superimpose is achieved from the similar distance. The experiments demonstrate that based on the method the predictive vibration waveform and spectrum are basically consistent with monitoring results around near-field blast. Compared with single seed wave method, the superposition method of multiple seed wave is more reliable to predict the duration of blasting vibration, the peak particle velocity, dominant frequency and frequency distribution.

Jan 1, 2015

By Robert M. Becker

This report (part 3 of a five-part series) presents computer programs for evaluating moments and moment relationships of the generalized probability distributions extended or developed in parts I and 2. The principal program is for evaluating the first three moments and moment relationships of the compound-multinomial distribution for finite as well as for infinite populations. This is the generalized distribution for sampling to some amount of items per sample. Another program is for evaluating the first four moments, the moments of the mean, and the moment relationships of the multinomial and generalized hypergeometric distributions. This is a general moment program in sampling to some number of items per sample or for sampling to some number of samples. This program will accept either ungrouped data, frequency data, or probability data.

Jan 1, 1965

By Dave J. Porter

Si bien, los proyectos son el camino para que una organización minera cumpla con su estrategia, la gran mayoría de su historial de cumplimientos son un fracaso puesto que el impacto del proyecto no es tan rico en sus etapas y las organizaciones mineras no pueden cumplir con su visión y estrategía. En ese sentido, el presente texto señala la importancia de una adecuada gestión de proyectos para que la organización minera cumpla con su estrategia. Así, la madurez de la gestión de proyectos es un indicador de éxito continuo y requiere de visión, compromiso en las etapas iniciales, ya que sus ganancias son difíciles de cuantificar.

Apr 1, 2012

By S. M. Moore

Technological advances in underground coal mining have reduced fatalities but may not have reduced worker exposure to cumulative injury risk factors. The objective of this study was to evaluate the prevalence of cumulative injuries before and after the implementation of technological advances in underground coal mining and to make a general cost estimate for these injuries. A previously published algorithm was utilized to identify cumulative injuries within the Mine Safety Health Administration (MSHA) database for two data sets: 1983-1984 and 2003-2004. For both, the following were determined: the number and percentage of cumulative injuries, the average days lost, the average age at the time of injury, the average years of experience and the general cost estimate by body part. The percentage of cumulative injuries remained largely unchanged (37 percent in the 1983-1984 period and 33 percent in the 2003-2004 period). The average number of lost days due to cumulative injuries increased (36±55 days and 62±82 days, respectively), which may have been due to the increased worker age (seven years older in the 2003-2004 period), increased length of employment (seven years longer in the 2003-2004 period) or other factors such as changes in medical practices. Cumulative injuries to the back decreased by 10 percent, while cumulative injuries to the knee increased by 8 percent. The reduction in back injuries may be due to the implementation of assist devices, while the increase in knee injuries may be related to kneeling/crawling in low-seam mines. Cumulative injuries were found to remain a major financial burden on the industry. Recently, National Institute for Occupational Safety and Health (NIOSH) developed tools to assist mining companies with incorporating an ergonomics process into their existing health and safety programs. The participating companies have reported tremendous success. Therefore, it is recommended that ergonomics processes be implemented as a means to systematically identify and address the root causes to cumulative injuries and ultimately reduce costs.

Jan 1, 2008

By Baker EM

The Kidston orebody is a kilometre diameter breccia pipe of Permo-Carboniferous age&apos; assoc- iated with rhyolitic dykes and hosted by Proterozoic granodiorite and metamorphic rocks. Mineralization and alteration are associated spatially and temporally with brecciation and rhyolite intrusion. Three stages of alteration have been recognized: pre-brecciation, and early and late stage post-brecciation. Gold is known to be particularly associated with late stage post-brecciation cavity infill and sheeted veins. Fluid inclusion and stable isotope results show the importance of moderate-high temperat- ure, saline, magmatic fluids in the early stage mineralization and in the brecciation of the pipe. Later periods of alteration, accompanied by gold deposition, are associated with fluids only slightly depleted in 180 relative to mag- matic waters, unlike the strongly 180-depleted meteoric water typically found in hydrothermal Permian and Carboniferous deposits of eastern Australia. The 5180 values and low salinities in fluid inclusions suggest the fluid may have formed from vapour condensation from a magmatic fluid. Fluid inclusion data and alteration assemblages define the prevailing chemical conditions. Gold transport under these, conditions would have been primarily as a bisulfide complex.

Jan 1, 1987

By L. Gutierrez, M. Jeldres, R. J. Jeldres

"Clays are present in a large number of mineral deposits and are commonly found as gangue. Its complex chemical structure, characterised by anisotropic surfaces, makes its presence a permanent challenge for flotation operations, increasing the reagent consumption, decreasing the quality of the concentrate, and changing the rheological properties of the system. In this context, the main objective of this research is to improve the floatability of chalcopyrite minerals in the presence of clays by using guar gum, a low molecular weight organic polymer, which acts as a surface coating agent for clays. Clay Minerals Society provided the kaolinite sample and the chalcopyrite sample was purified from mineralized rock specimens obtained from Ward’s Natural Science Establishment. Micro flotation tests were carried out in a 150 cm3 Partridge-Smith cell, using compressed air as the gas phase at a flow rate of 80 cm3/min. Potassium amyl xanthate (PAX) and methyl isobutyl carbinol (MIBC) were used as a collector and a frother, respectively. The results showed that the use of guar gum improves the recovery of chalcopyrite in the presence of kaolinite because it induces the formation of clay aggregates that settle by gravitational effects, preventing the 'coating effect' and decreasing excessive collector consumption. pH played a key role in the guar gum performance, which was most effective at highly alkaline conditions (pH 11), where the copper recovery improved from 73% to 90%. The work has significant implications for the mineral flotation in the presence of clay minerals.INTRODUCTION The mining industry is continuously confronted with challenges that alert the sustainability of the sector. There is little availability of water, the grade of the deposits are getting smaller, and the gangue is becoming more complex. Usually, clays are part of the gangue in numerous systems, including copper ore, porphyry, nickel, platinum, etc. (Senior & Thomas, 2005). The structure is mainly composed of layers of tetrahedral silica (T) and octahedral alumina (O) that join in certain proportions: 1: 1 (T-O) and 2: 1 (T-O-T) (Theng, 2012). Also, they expose two crystallographically different surfaces: the faces, which tend to be negatively charged, and the edges, which carry a charge that changes from positive to negative depending on the pH (Van Olphen, 1977). One of the most common clays in copper deposits is kaolinite, whose structure is composed of an octahedral sheet of gibbsite bound to a tetrahedral silica sheet in the ratio 1:1"

Jan 1, 2018

By J. Leland Myer

IN a precise study of Pennsylvania anthracites, the research on European. anthracites is of little value to us because of their different physical and chemical nature. Likewise, there can be little correlation with the physical properties of bituminous and lower rank coals. Although all high-rank coals are thought to have had a common origin, microscopic examination revealing essentially the same kinds of organisms in similar .states of preservation, the different physical properties apparently arise from the degree or kinds of metamorphism of these coals. Representative samples from the Pennsylvania deposits have been selected for analysis, together with graphitic anthracite, bituminous coal, and some of the common forms of carbon. A complete list, with descriptions, is shown in Table 1.

Jan 1, 1932

By D. F. Scott

The purpose of this study was to determine if miners are at risk from exposures to chemicals used in the mining industry, and determine the nature and sources of the illnesses and injuries. The authors reviewed the Mine Safety and Health Administration?s (MSHA) Employment and Accident, Injury, and Illness database and identified 2,705 cases of chemical-related injuries and illnesses that were reported to MSHA from 1999-2006, involving 66 different chemicals. The main source (cause) of chemical-related cases was acids/alkalis (about 39%). The primary nature (effect) of chemical-related cases was chemical burns (about 57%). The job classification where workers incurred the most chemical-related injuries and illnesses was cleaning plant operator/media operator/boney preparation plant operator/crusher worker. The number of nonfatal days lost did not change significantly and overall, the incidence rate of chemical-related cases decreased by 36%. Chemical burns accounted for a large number of injuries; mining companies should carefully examine their personal protective equipment (PPE) requirements, training methods, and safety culture to insure that their workers are protected.

Jan 1, 2009

By Joo Hyun Park

A history of the research regarding the spinel in the community of the stainless steels has simply been reviewed, followed by the recent studies for the formation mechanism of the spinel in the ferritic stainless steel melts equilibrated with the highly basic slags and the crystallization behavior of spinel phase in the calcium aluminosilicate melts containing MgO and CaF2 during slow cooling cycles. It has been proposed that the content of aluminum and calcium in the steel melts as well as the basicity and the content of MgO and Al2O3 in the slags are quite important factors affecting the spinel formation in view of the formation mechanism based on the reduction of MgO (or CaO) and Al2O3 in the slags by the aluminum and silicon added to deoxidize the molten steel. The use of magnesia refractory was also recommended. The formation mechanism of spinel from the MgO inclusions readily formed in the steel melts equilibrated with the highly basic slags has newly been proposed on the basis of the ionic exchange reactions at the inclusion/metal interface and the crystal chemistry of oxides. The crystallization behavior of the spinel phase in the calcium aluminosilicate melts was enhanced by the Al2O3 based on the ionic reaction of spinel formation in the oxide melts, while the size of the spinel crystals in the oxide melts decreased by addition of CaF2.

Jan 1, 2006

By W. Dresler

Since 1900, smelters have produced in Canada over 10 million tonnes of iron silicate waste slag containing significant quantities of nickel, cobalt and copper. The slag is reduced with aluminum and calcium oxide additions to produce a copper, nickel, and cobalt enriched alloy and an obsidian slag. It was found that the obsidian slag contained very low copper, nickel, and cobalt contents, indeed below 0.06% of each the base metals. These metals have been collected in a type of ferroalloy with up to 1.6% Cu, 2.1% Ni, and 0.7% Co. These alloys can be recycled according to standard procedures in base metal smelters. Surprisingly, the obsidian slag was found to display good cementitious and pozzolanic properties, which is a requirement for cement production. The strength producing properties of the obsidian slag are considered to be exceptional at the 28 day standard test age. In most cases, the obsidian concrete is characterized by significantly greater strengths than control concrete tests and concrete containing fly ash or blast furnace slag. Compressive strength data at 365 days for the obsidian concrete is impressive.

Jan 1, 2003