Search Documents

Sequential and evolutionary changes through time are recognizable in many, perhaps most major families of ore deposits and their geological environments. These changes are additional useful indicators of the evolutionary history of the earth and its tectonic processes. They are important in mineral exploration because they involve consideration of time as a fourth dimension, thereby indicating the most favorable ages, rather than types of rock for investigation. Many of the changes are analogous to those recognized in faunal evolution. Some primitive, unspecialized types of ore deposits occur nearly unchanged through rocks of widely differing age. Others diversify into several, more specialized variants, whereas still others become extinct. The place of these is taken by new, younger types, some of which undergo sudden proliferations and later diversifications of their own. In Archean greenstone belts irrlportant iron, nickel, gold, and base metal deposits occur co-regionally, but in different stratigraphic positions in the same, thick volcano-sedimentary successions. Here their close temporal and spatial associations suggest common genetic exhalative hydrothermal processes. The massive base metal sulfide family of ore deposits provides an excellent example of evolutionary changes, exhibiting distinct variations through both time and space. Deposits belonging to this family span the entire range of time, occurring in rocks of ancient Archean to Recent age, and specific types within the family also span the entire range of spatial environments from ensimatic to ensialic. Moreover there are possible evolutionary metallogenic links between certain types of massive base metal sulfide deposits and other important base metal ores, noteably Mississippi Valley-type and porphyry copper deposits.

Jan 1, 2013

By Jeff Gore, Jack Dermody, David Gribble, Brett Macaulay, Bart Sharpe, Paul Klaric, Paul Thornley, Ben DeVries

Optimal Fragmentation in Block Caving is difficult to achieve as it is generally defined by the rock mass itself and the way in which the cave is initiated. The lower portion of the cave has even less chance as the material has little time for self comminution. Blast Preconditioning of the Block Cave is designed to engineer the lower section of the rock mass to produce material of a suitable size to assist in the initial cave propagation and improve initial drawbell productivity. At Cadia East a plan was developed to drill 150-metre long, vertical up-holes from the undercut level and blast them fully confined to produce fractures in the rock mass. The blast itself was a simple undertaking. However, in the year preceding the first production blast, all aspects of the process were designed, tested and refined across multiple trials. As this type of challenging application had not previously been encountered in Australia there were many unique situations to address. Products and systems had to be developed and adapted to overcome these challenges. These included: Formulating and manufacturing an explosive that is robust and of a high VoD; designing and manufacturing easy to use electronic initiation systems; and, designing pumping systems to combat high head pressures to allow for successful and safe loading of the holes. Close collaboration with the customer ensured that the trials culminated in successfully blasting a hole containing almost 3.3t of explosive. These trials have since led to the blasting of four holes instantaneously, which contain almost 13t of explosive. This paper describes the various components of the system, the challenges and the final result.

Jan 1, 2013

By Abraham Lindo

Panama’s current economical growth demands an increase in electric power supply; projected energy supply for 2012 exceeds the demand by as little as 2%. In an effort to comply with the demand, several different hydroelectric projects, promoted by the government, are currently under construction and each of them vary in generating capacity, construction design and complexity.

Jan 1, 2013

By P. Schloth, H. van Swygenhoven, N. Chobaut, J-M. Drezet

"In the current trend toward thicker aluminium plates, a major concern is the stress build-up during quenching which causes distortions during machining. Indeed, cooling rates are not high enough, especially at the core of such thick plates, to prevent any precipitation and quench induced precipitates lower the hardening potential. Multi-scale modelling is required when predicting macro-scale stresses after quenching for thick heat treatable aluminium components. The reason is the instantaneous strong coupling between phase precipitation at the nano-scale and material hardening due to precipitation or softening owing to solute depletion at the microscale. For thick parts, quenching intensities decrease when going from the skin to the core of the component, thus introducing a gradient of nanostructure and consequently a gradient of mechanical properties. In addition, large thermally induced deformations lead to high macroscale residual stresses although part of them is relaxed by plastic deformation. These stresses have been measured in water quenched thick plates of 7040 and 7449 aluminium alloys using neutron diffraction and layer removal techniques and the results when compared with a thermomechanical finite element model of quenching highlight the influence of precipitation.IntroductionIn the processing route of heat-treatable aluminium alloys (AA), a critical step is quenching from the solutionizing temperature. High cooling rates are desired, as they avoid formation of coarse precipitates, which reduce mechanical properties. Fast quenching, however, cannot be achieved in the centre of thick components, where the quenching rate can be more than one order of magnitude lower than at the surface. The existence of a thermal gradient between core and surface leads to a differential thermal deformation which is accommodated by elastic and plastic deformation to comply with the compatibility of deformation. Whenever the material yields, especially at high temperature when the yield strength is low, residual stress remains after quenching due to the irreversibility of plastic deformation. After quenching, the plates are in a state of residual stress that causes unacceptable distortions during machining and may reduce service life drastically. Since stress relaxation is negligible during ageing treatments [1 ], agehardened aluminium parts are usually stress relieved prior to ageing. This is typically achieved by applying plastic deformation: stretching from 1.5 to 3 % in the rolling direction (L) can reduce the internal stresses by a factor of approximately 10 [2, 3]. However, complex geometries or thicker components like thick sheets require other approaches. Reducing the quenching rate by using boiling water for instance leads to lower residual stresses [1, 4]."

Jan 1, 2013

By Jing Zhan, Chuanfu Zhang, Yonglin Yao

"The Ni/Co arbitrary ratios of fibrous precursor were investigated during coordinated coprecipitation by changing the precipitating medium. The results show that the original molar ratio ofNi2+ to Co2+ in reaction solution can be maintained in the coprecipitate at pH'.'05.0 and the coprecipitate is single phase solid solution using water and water-X precipitating medium. But the original Ni/Co ratios are no longer kept and composition of the coprecipitate is not uniform at pH>5.0 in water precipitation medium. In order to obtain the precursors with the required morphology and accuracy Ni/Co ratios, the optimum conditions of fibrous precursors were chosen as follows: ammonia used as complex agent and pH adjustor, water-X solvent as precipiting medium, oxalate as coprecipitated agent, 8.0-8.4 for pH value, 50-70°C of reaction temperature, 0.5-0.8 mol/L of initial nickel and cobalt salt concentrations and excesses of oxalic acid of 10% - 20%.IntroductionNi-Co alloy as an important transition metal alloy with high mechanical strength, good anti-deformation, corrosion resistance, thermal conductivity, thermal stability, electrical conductivity, electrical contact, and special magnetic properties indicates that it can be used as high-temperature catalyst, special magnetic material, high-temperature electrochemical devices, and so on [1-6]. An ideal composite powder should have an appropriate stoichiometric ratio, good uniformity of chemical composition, appropriate phase, low impurity content and small particle size [7]. Similarly, the composition of nickel-cobalt alloy powder has an important impact on its crystal structure, properties and applications. Guo[8] found that magnetisms of CoxNi1-x such as magnetic anisotropy, curie temperature, and the shifts of the spin steering are very sensitive to the composition of alloy powder."

Jan 1, 2013

By J. Sliwinski, J. Oliveira

"The application of geometallurgy and corresponding sample selection can take on several formats within industry. Current practice can range from a strictly geostatistical approach to one in which geological and metallurgical parameters are used in combination to create a representative sample selection strategy. The stage of a project and the level of information available at the time of sampling influences the methodology used to create a representative sample.A geometallurgical study of Carpathian Gold’s Rovina Valley Project in Romania is used to demonstrate a sample selection strategy that integrates geological, mineralogical and metallurgical data to maximize the relevance of the geometallurgical unit definitions. This approach, practiced by Xstrata Process Support for its’ clients, ensures that the results of the metallurgical program can be interpreted in the context of these units.INTRODUCTIONGeometallurgy is a cross disciplinary approach in which metallurgical performance of an ore is linked to intrinsic geological and mineralogical characteristics. The objective of a geometallurgical study is to characterize the range of metallurgical performance of an orebody. This allows the geoscientist or metallurgist to create a robust flowsheet able to treat the full range in variability and to develop production strategies to maximize financial performance. The standard approach is to individually sample and test a series of ore types or geometallurgical units. Several different approaches are used in industry to define what constitutes geometallurgical units and how to sample them.One current methodology is the use of multivariate statistics. Geochemical data along with available geological data are used to define multiple variability domains (Williams, 2004; Walters, 2009). There are risks associated with this methodology since the extent of the data set itself may not support a purely statistical approach at the time that metallurgical units need to be defined. The assay suite collected by exploration programs is often limited to pay metals while metallurgical performance is often affected by ore gangue components. Furthermore, in many cases metallurgical scoping and pre-feasibility studies take place prior to the availability of extensive geochemical data sets. Purely statistical methods can produce multiple populations which require extensive sampling, testing and validation prior to consolidation into a reasonable number of composites for metallurgical testing. Methodologies are therefore required that allow representative sampling and testing of consolidated geometallurgical composites to occur at various phases throughout the development of a mining project."

Jan 1, 2013

By Guohua Bai, Lin Zhang, Shan He, Xuling Chen, Min Gan, Xiaohui Fan, Yanbin Tang

"For reducing the dust content in flue gas during copper smelting in the Ausmelt, technologies and mechanism of strengthening the pelletizing of copper concentrate were studied. The results show that adding bentonite, organic binder or composite binder can effectively enhance the strength of green pellet and reduce the rate of shedding powder in drying process, and composite binder works best. When adding 1 % of composite binder, the drop strength of green pellet increased from 1.9 times/P to 4.5 times/P, the rate of damage dropping from 2 m reduced from 50.12% to 13.08% and the rate of shedding powder reduced from 60.28% to 25.13% at drying temperature of 400111. In addition, the mechanism of binder absorbed in the surface of mineral was investigated by infrared spectroscopy. The results showed that composite binder absorbed in the surface of copper concentrate was in the form of chemisorptions, which made hydrophilic enhanced, while bentonite absorbed in the surface of copper concentrate was physisorption.IntroductionWith the technologies of copper smelting developing, the equipment of copper smelting steps into a large-scale and efficient level in recent years. As Ausmelt smelting is characterized by being efficient, environmentally-friendly and energy-saving, it is generally recognized by the enterprises of copper smelting [l]. The process of Ausmelt smelting starts with materials mixing, and then pelletizing. From this point onwards, pelletized balls are charged to the top of the furnace, undergoing drying and smelting reaction[2]. Since copper concentrate is fine-grained, directly adding into smelting furnace can make it blown out of the furnace together with the airflow upwards, rendering flue gas high in flue dust, which can cause the loss of concentrate greatly, and make smelting environment poor as well. The concentrate transported into the furnace and smelted after disc balling is conducive to improve the capacity of melting furnace during copper concentrate smelting, reduce the powder shedding rate and improve enterprise benefits."

Jan 1, 2013

By Kyle S. Brinkman, Kenneth L. Reifsnider, Fazle Rabbi

"Mixed ionic and electronic conducting (MIEC) ceramic membranes are HeteroFoaM's which play an essential role in a number of energy conversion related systems including the solid oxide fuel cell (SOFC), oxygen separation and permeation membranes, partial oxidization membrane reactors for natural gas processing, and high temperature electrolysis cells. Dual phase oxygen membranes consisting of an ionic conducting phase Ceo.sGdo.z02 (CGO) and an electronic conductive phase C0Fe204 (CFO) were fabricated and characterized by structural (XRD), microstructural (SEM-EDS) and broadband dielectric measurement techniques. In-situ measurements of the dielectric properties of working oxygen separation membranes are presented which indicate that the material's dielectric behavior can be an indicator for MIECperformance.IntroductionCeramic membranes which transport oxygen ions play an essential role in a number of energy conversion related systems including the solid oxide fuel cell (SOFC) [l ], oxygen separation and permeation membranes in the commercial and nuclear arena [2, 3], partial oxidization membrane reactors for natural gas processing [4], and high temperature electrolysis cells [5]. For the electrolyte functions, the membranes must transport oxygen ions only. On the other hand, permeation membranes, typically used in combustion devices to support oxy-fuel combustion or for partial oxidation reactions involving the production of synthesis gases, require mixed oxygen ion and electronic conduction (MIEC). Traditionally the tailoring of the ratio of ionic conductivity to the materials electronic conductivity, measured as the transference number, has been accomplished by the introduction of aliovalent doping elements creating point defects in the material facilitating the diffusion of charged species. However, several decades of research have not yet produced single phase materials which possess the concomitant ionic and electronic conductivity required for use in membrane separation applications. It is clear that novel ""dual phase"" heterogeneous materials will be required and that the surface reactions of these materials will be of particular importance as the industry moves toward thin films membranes [6]."

Jan 1, 2013

By Peter W. Lipman

In the Rocky Mountain region, variations in Tertiary mineralization correlate with changes in tectonic setting and associated igneous activity that can largely be related to tectonics along the west boundary of the American plate. Successive settings include compressional tectonics and associated continental-arc igneous activity; transitional igneous types associated with intra- and back-arc extension; and basaltic or bimodal basalt-rhyolite assemblages associated with Basin and Range extension in- ward of a growing transform boundary between Pacific and American plates.

Jan 1, 2013

By G. Deschênes

The Eleonore property (James Bay district of Northern Québec), owned by Goldcorp, hosts gold within stockworks of quartz-tourmaline-arsenopyrite veins and veinlets contained within microcline (potassic alteration) and brown tourmaline replacement zones. The preliminary investigation to recover gold from drill core samples showed that flotation followed ultrafine grinding and cyanidation is the preferred option. Ultrafine grinding is used to liberate gold finely disseminated in sulphides. The flotation concentrate used in the investigation had a P80 of 11 microns and contained 75.5 g/t Au, 5.0 g/t Ag, 10.3% S, 0.07% Cu and traces of antimony (0.03%). The mineralogical characterization showed the presence of 65% gangue minerals, 23% pyrrhotite (hexagonal), 9.6% arsenopyrite, 2.2% pyrite and 0.08% chalcopyrite with trace amounts of galena (0.05%) and sphalerite (0.03%). Gold was in the form of native gold and electrum. A straight cyanidation conducted at pH 11.0, DO of 3-5 ppm, 2000 ppm NaCN, 20 C 72 hours extracted 97.0% Au and consumed 31.5 kg/t NaCN. The equilibrium was reached within 24 hours. Increasing the dissolved oxygen to 16 ppm reduced the consumption of cyanide to 22.0 kg/t with 96.7% Au extraction. A 16-h pretreatment with 2.0 kg/t lead nitrate, followed by a 24-h cyanidation reduced the cyanide consumption to 6.0 kg/t with a gold extraction of 97.5%. Increasing the lead nitrate addition to 6.0 kg/t reduced the cyanide consumption to 1.2 kg/t by passivating the surface of pyrrhotite. The gold extraction remained at 97.0%. It was possible to decrease the concentration of cyanide to 800 ppm NaCN without compromising gold extraction. The associated cyanide consumption was 1.2 kg/t NaCN. The passivation of gold grains was an issue when the cyanide concentration was decreased to 550 ppm NaCN. The gold extraction decreased to 92.2%. The average lime addition for all the tests was 7.4 kg/t and the average silver extraction was 80%. Efficient cyanidation of an ultrafine sulphide concentrate with only 800 ppm NaCN represents an advance in leaching of ultrafine sulphide concentrates.

Jan 1, 2013

By Paul Semple

"In 2007, Noront Resources Inc. discovered the high grade nickel copper PGE deposit in northwestern Ontario in a region now known as the Ring of Fire. Since the initial discovery, Noront has advanced the Eagle¹s Nest Project and in September 2012 released a feasibility study for the development of the Eagle¹s Nest Project. This paper summarizes the results of this recent study and outlines additional work planned in the next stages of project development. INTRODUCTIONThe following paper summarizes the findings of the recently completed feasibility study on Noront Resources Ltd.’s Eagle’s Nest Project. The feasibility study was compiled into a NI 43-101 report by Micon International. This paper is intended to summarize the major technical findings and for complete information, interested parties can find the entire NI 43-101 report at www.norontresources.com or on SEDAR.LOCATIONThe McFaulds Lake project area, which includes the Eagle’s Nest deposit, is located at approximately UTM 5844000 N and 547000 E, and between approximately 52º42’ and 52º50’ N latitude and 86º06’ and 86º24’ W longitude, approximately 250 km west of the community of Attawapiskat on James Bay and 575 km northwest of Timmins. The closest all-season accessible community to the McFaulds Lake project area is Nakina, 300 km to the south, where there is a paved airstrip, in addition to all weather road and railroad access (see Figure 1).The First Nations communities of Webequie and Ogoki/Marten Falls are located 90 km west and 120 km south southeast of McFaulds Lake, respectively. Both communities are served by regularly scheduled air service, primarily from Thunder Bay; both Thunder Bay and Timmins serve as support centres for the James Bay communities and the exploration projects in the area."

Jan 1, 2013

By Brain E. Gombos

The Allen Park Sanitary Sewer Overflow (SSO) Tunnel and relief sewer project, located in the city of Allen Park, MI, is a long-term corrective action designed to bring Sanitary District One?s sanitary system into compliance with its 2005 consent order and service contract with the Detroit Water and Sewerage Department (DWSD). The $20 million project is intended to reduce Allen Park?s wet weather discharges to DWSD, reduce bypass pumping to the Ecorse Creek and limit the future risk of basement flooding by providing storage during wet weather events and eliminating hydraulic bottlenecks in the sanitary sewer system.

Jan 1, 2013

By S. E. Cook

This article uses the case of the Royal Bafokeng Nation to argue that royalties and dividends from mineral resources, if managed well, can provide direct benefits to the surrounding community even while the state collects its share of mining revenues through taxation. The key to this model is the effective management of the resource income flowing into community coffers. Where some of this income may fund urgent interventions in the community, a portion of the income can also be used to establish an intergenerational wealth fund to meet the needs of future generations. As a depleting resource, minerals like gold and platinum are not a sustainable source of income, and must be replaced over time by more regenerative income streams. These strategies and dynamics are manifest in the Royal Bafokeng Nation?s status as both community and quasi-municipality, a labour hosting and a labour sending community, a mine operator and a mine owner. The Royal Bafokeng Nation also owns one of South Africa?s largest community-based investment companies, which channels revenue derived from platinum deposits into a broad investment portfolio that in turn funds an aggressive social development program for 150,000 people living in twenty-nine rural villages.

Jan 1, 2013

By Xing Jin, Dan Graffi, Glenn MacPherson, Dan Rioux

"The complexity of a modern flotation circuit makes it susceptible to disturbances such as changes in feed, ore mineralogy, equipment degradation, poor measurements and faulty instruments. Good measurements and a robust control system are critical to create and maintain a stable and optimum flotation process.This paper focuses on the development and implementation of process control applications in the flotation circuits at Xstrata Nickel’s Strathcona Mill ( referred to as the mill hereafter ) in Sudbury, Ontario. Following the path of ‘stabilize-improve-optimize’, basic controls to stabilize process variables such as flotation cell pulp level, air and reagent addition rates, cleaning-column feed and wash-water rates have been established. Factors such as best practice in pulp level and valve position measurement, feedforward control and the application of an appropriate control philosophy, have contributed to the significant reduction in process variability. For instance, standard deviation reduction of 79% for the Ni impurity in the column Cu concentrate grade was experienced and is shown. The variability reduction of the flotation circuits’ key process-variables paves the way to further improve and optimize flotation performance. A grams-per-metal unit reagent addition control scheme has been improved upon, particularly for different operating scenarios and better robustness. In addition, following significant stabilization of the primary controls and columns feedrates, Cu/Ni separation cleaning-column bias-control (cascaded to the wash-water rate) and hold-up control (cascaded to air flowrate) have been developed and tested. This strategy – from stabilization to optimization - is expected to achieve a more consistent control of final concentrate grades and improve recoveries.INTRODUCTIONFlotation is considered the most important and value-added process in the milling metallurgical plant and is still undergoing continuous evolution to treat greater tonnage and different ores (Wills, 2006). Starting over three decades ago, with the advent of on-line slurry content analysis devices, flotation automatic control has received persistent interest and a large number of applications have been reported (Thwaites, 1983, 1986 ; Mckee, 1991). Bergh and Yianatos (2011) reviewed different aspects of process control in flotation circuits and have evaluated the applicability of model predictive control to the process. Mckee (1991) analyzed the difficulty in developing lasting/robust process control applications for flotation circuits and stated that the path of stabilization-refinement-optimization would more likely lead to successful flotation circuit process control. Best practice on column process control was discussed by Bouchard, etc. where a multi-layered approach was proposed, provided that the measurement of column process variables ( i.e. bias, froth depth, hold-up, etc. ) are measured reliably (Bouchard & Thwaites, 2008). Wills (2006) stated that the best practice for flotation automatic control starts with fulfilling basic control objectives, such as stabilized flotation cell level, air flow, pH, reagent flow etc., before considering more advanced, or even optimal, control of metallurgical targets, which are more closely linked to economic performance."

Jan 1, 2013

By Kent C. Condie

Precambrian terranes in the Rocky Mountain region decrease progressively in age from the Archean Wyoming Province (> 2.5 b.y.) to the late Proterozoic in West Texas (figs. 1,2). Within the Wyoming Province, most dates fall near 2.7 b.y. although some are recorded at 2 3.8, 2.9, and 2.6 b.y. Although Penokean (- 1.8 b.y.) deformation and plutonism are recorded in southeastern Wyoming, most Precambrian rocks south of the Wyoming shear zone, which separates the Archean and Proterozoic provinces, are < 1.76 b. years in age. Supracrustal rocks in Colorado, western Arizona, and northern New Mexico fall in the range of 1.72-1.76 b.y., those in central New Mexico about 1.65 b.y., those in southeastern Arizona and southwestern New Mexico about 1.70 b.y., and those in West Texas 1.1-1.2 b.y. The Wyoming Province is comprised chiefly of 2.7 or 2.9 b.y. tonalitic gneiss terranes intruded by 2.6 b.y. granites in the central and southern parts of the province. Supracrustal rocks are minor and include greenstone belts comprised chiefly of pillow- ed tholeiites and graywackes and remnants of quartzite-shale successions. Metamorphic grade in greenstone-gneiss terranes ranges from upper greenschist to amphibolite facies and in quartzite-gneiss terranes from upper amphibolite to granulite facies.

Jan 1, 2013

By Shi Guan-Yong, Niu Li-Ping, Dou Zhi-He

"In the preset work, the viscosity model (named modified KTH model) proposed by Sichen Du and S. Seetharaman et al and extended by Shu Qi-feng was applied to the ESR slag systems. A correlation to predict the viscosities of CaF 2-(CaO)-Al203 slags using interaction coefficients of different cations in the presence of oz-and viscosity interaction coefficients between oz-and F in the presence of different cations has been developed. The interaction coefficient between oz- and F- in the presence of Al3+ was determined from the experimental data as shown in known literatures. The good agreement between the calculated viscosities and the experimental data in the CaF2-(CaO)-Al203 systems has indicated that this approach can be successfully employed to predict the viscosities of ESR slags.IntroductionReliable viscosities data of high-temperature slag melts are important for the modeling and design of high temperature metallurgical processes. Although a number of experimental measurements have been carried out, the available viscosities data is still scarce compared to the needs of today's technology, especially in the case of complex melts. In process simulations, the needs of viscosity descriptions for complex systems which could enable the extrapolation of the data as functions of temperature and composition is strongly felt today."

Jan 1, 2013

By Xinli Wang, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng, Byoung-Gon Kim

"The microwave dielectric properties of silicon dioxide at frequencies of 915 and 2450 MHz were characterized in the temperature range of 24 to approximately 1000 °C using the cavity perturbation technique. It is shown that the relative dielectric constant of silicon dioxide at both frequencies remains almost unchanged below 500 °C, above which there is a slight increase of 2%. The relative dielectric loss factor of silicon dioxide exhibits a strong temperature dependence above 500 °C and increases by approximately 7 and 5 times at 915 and 2450 MHz, respectively. The substantial increase in the relative dielectric loss factor is mainly attributed to the enhanced dielectric polarization and accelerated electrical transport in silicon dioxide at elevated temperatures.IntroductionSilicon dioxide (Si02) is usually considered a microwave transparent material due to its poor absorption capability at room temperature [1]. This characteristic has led to various applications of silicon dioxide in microwave processing of materials and communication. For instance, Si02 has been used to produce sample holders for microwave heating and substrates for electronic devices [2,3]. These applications generally require the material to withstand high temperatures under microwave irradiation. This indicates that microwave absorption capabilities of silicon dioxide at elevated temperatures are also important for its utilization.The microwave absorption capability of Si02 can be determined based on dielectric characterization (permittivity measurement) of the material at commonly used microwave frequencies, 915 and 2450 MHz, in a broad temperature range. To date, however, no detailed work on the dielectric properties (permittivity) of silicon dioxide at high temperatures has been reported. The present work is aimed to study the dielectric properties of silicon dioxide from room temperature to approximately 1000 °C at 915 and 2450 MHz. The results show that the permittivity of silicon dioxide has a strong temperature dependence above 500 °C, suggesting a substantial increase in its microwave absorption capability."

Jan 1, 2013

By Adam Gesing, Paul Marchwica, Jerry Sokolowski, Sharon Lackie

"Often referred to as SEM-EDX, energy-dispersive spectroscopic analysis of characteristic fluorescence x-ray is a standard technique for semi-quantitative elemental composition analysis in scanning electron microscopy. It is quick and extremely useful for identification of phases in the sample microstructure, as long as the constituents are significantly larger than the probe volume from which the fluorescence x-rays originate. The probe volume ranges from a few to several microns, depending on the electron beam spot size and the acceleration voltage. We report on a new variant of an EDX technique developed to overcome this limitation and allow quantitative elemental analysis of smaller phase constituents, down to a size of several nanometers. This variant involves the calculation of compositions of individual phases from multiple analyses of areas containing phases of interest. This significantly increases the usefulness of EDX for quantitative analysis of new nano-structured materials.IntroductionIn any elemental micro-analytical method, the sample material is illuminated by a probe beam that excites an interaction volume of a sample to emit a characteristic signal. This signal in turn interacts with the sample material through absorption and fluorescence mechanisms before a portion of it is collected by a suitable detector and analyzed for elemental composition. The spatial resolution of the method depends on the minimum interaction volume between the probe beam and the sample material.Laser light beams can be tightly focused to a spot size limited by the photon wavelength and can be used to sample the surface of any material. In micro-LIBS (laser-induced plasma spectroscopy) a focused laser beam ablates and vaporizes a small volume of material from the sample surface, creating a plasma spark. Spectral analysis of the light emission from the plasma spark allows the semi-quantitative determination of the elemental composition of the material removed from the sample surface. The smallest reproducible craters achieved are ~ 3mm in diameter and a few nanometers in depth. [l]Particle probe beams of ions or electrons can be focused to a diameter of a few nanometers at the point of impact on the sample. Ions sputter the sample atoms from the point of impact, and the sputtered ionized material is analyzed by mass spectroscopy in a secondary ion mass spectrometer (SIMS). [2] This gives SIMS resolution in a nanometer range. SIMS equipment, however, is expensive and not readily available."

Jan 1, 2013

By Yuanbo Zhang, Helei Zhang, Heng Yu, Guanghui Li, Zhengwei Yu, Tao Jiang

"Composite agglomeration process (CAP) is an innovative method for preparing blast furnace burden. For CAP, the classified raw materials of pelletizing feeds and matrix feeds are mixed, charged and sintered. The characteristics of these two kinds of feeds obviously affect the permeability of per-ignition bed, as well as the sinter productivity and quality. In this study, the Ergun equation is proposed to predict the pressure drop of CAP bed using the particle size distribution. The calculation process indicates that the Dv and the Em are the two tuning parameters. The results show that there is a gap between the calculated values by Ergun equation and the measured results by pressure drop testing facility. Eliminated this error by modified the Ergun equation and then validated it through experimental studies using simulated CAP mix and test facility. Therefore, the modified Ergun equation can be used to predict the permeability of CAP bed.IntroductionThe sintering process is one of predominant agglomeration processes for preparing ironmaking burden from iron-bearing materials. Sinter accounts for 70-80% of the blast furnace burden in China and the continuous improvement of sinter quality provides a guarantee to anterograde production of blast furnace. Sinter productivity and quality are strongly related to the permeability of the bed during sintering, which is dependent on the structure of the bed before ignition in the early stage [l]. The size distribution, the shape of granules and the bed voidage are the primary affecting factors to pre-ignition permeability."

Jan 1, 2013

By Peter C. Hayes

"The high temperature reduction of solids through the use of reactive gas atmospheres has application in a wide range of industrially important processes. Whilst significant advances have been made in understanding and describing these processes, some key aspects of the chemical reactions and reaction mechanisms operating in these systems, for example, the transformation from metal oxide to metal, remain poorly understood. A number of different product morphologies have been identified in these reaction systems and the reaction rates have been shown to be critically dependent on the product structure.Theoretical examination of the elementary process steps taking place in the region of the gas/metal/metal oxide interface, combined with electron microscope studies of the resultant product microstructures, have enabled the key process and material variables responsible for the development of the various product morphologies to be identified. By considering i) established criteria for the stability of moving interfaces in a thermodynamic potential gradient, ii) the relative rates of chemical reactions on the oxide and metal surfaces, and iii) key process phenomena and physico-chemical properties of the solid phases, the mechanisms and conditions for the formation of various product morphologies are identified. Interestingly the analysis points to direct analogies between these phase transformations and, the phenomena and microstructures observed in metal solidification, and the potential to develop generic models of these fluid/solid reaction systems."

Jan 1, 2013