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By U. Erb, L. Monaco

"Electrodeposited nanomaterials are increasingly implemented in advanced industrial applications in the aerospace, automotive, defence, electronic and energy sectors due to their outstanding physical, chemical and mechanical properties, including increased strength and wear resistance, and superb magnetic properties. As with the development of any class of new materials, the corrosion behaviour of these electrodeposits requires considerable attention. This presentation reviews major developments in the understanding of the corrosion behaviour of nanocrystalline metals, alloys and metal-matrix composites over the last 20 years, with emphasis on how their intrinsically high density of intercrystalline defects does not compromise their corrosion resistance as initially expected.INTRODUCTIONOver the past 20 years there have been considerable advances in the understanding of the corrosion behaviour of nanocrystalline metals, alloys and metal-matrix composites. In this paper, the corrosion properties of nanocrystalline nickel, cobalt, zinc, and copper and some of their alloys are reviewed with emphasis on how a reduction in grain size affects their corrosion behaviour in different environments.It is possible to synthesize nanocrystalline material with microstructural refinement down to the range of 1 to 100 nm using a large number of processing methods. There are five basic synthesis methods that can be used to classify the different techniques: vapor-phase processing, liquid-phase processing, solid-phase processing, chemical synthesis, and electrochemical synthesis. Depending on the synthesis method, different microstructures (equiaxed, textured), shapes, and forms (films, particles, bulk material) may be produced. In addition, other factors may be introduced (eg. residual porosity or amorphous phases), aside from microstructural refinement, which can contribute to the observed properties (Erb, 2010). In order to interpret and categorize the resulting microstructures, a dimensional structure modulation scheme was introduced by Siegel (1996) in which zero-dimensional nanomaterials refer to individual particles, clusters, etc. One-dimensionality results from a layered (less than 100 nm thick) structure. Two-dimensional nanomaterials are thin, layered structures containing grains (less than 100 nm) within each layer. Finally, three-dimensional nanomaterials are bulk structures with an average grain size less than 100 nm."

Jan 1, 2012

By Jari Aromaa, Antti Kekki, Olof Forsén

"The deposition of copper on inert substrate depends on the number of active sites that will react at certain overpotential. The critical overpotential depends on surface morphology, surface film resistance and additives on cathode surface. The effects of surface properties on copper nucleation and growth rates were studied for used stainless steel blanks from several tankhouses. The surfaces of the blanks were characterized with electrochemical and mechanical methods. Electrochemical deposition tests were done at current density of 300 A/m2 for 10, 30 and 60 seconds. The nucleation density and copper coverage were estimated using image analysis. The surface film resistance did not correlate with copper growth. Increasing surface roughness correlated with lower copper growth.IntroductionStainless steel cathode blanks in copper electrorefming are usually made of AISI 3 I6L type steel. They have a typical lifetime over 10 years. During use the surface will collect deposits and become rough due to wear and corrosion. These factors can affect the nucleation and growth of copper. The nucleation and deposition of copper on inert substrate depends on the number of active sites that will react at certain overpotential. The critical overpotential can depend on surface film resistance, surface morphology, and additives adsorbed on cathode surface.The deposition potential of metallic ions on a foreign substrate is usually higher than the deposition potential on the electrode made of the same metal due to crystallographic substrate/metal misfit [I]. If the substrate has traces of the depositing metal they will be preferential growth sites. For a smooth deposit a large number of simultaneous nuclei is necessary. However, excessive nucleation density can lead to porous deposits [2]. Surface films of good conductivity are needed for dense nucleation and small nuclei. On cathode blanks the number of active sites increases with increasing surface film conductivity [3-5] and/or surface film porosity [6]. On AISI 3 I6 L stainless steel a more resistive oxide has been found to limit favourable sites for copper nucleation and more conductive film promoted high-density copper nucleation [7]. Also Urda-Kiel et al. have concluded that thicker oxide layers on AISI 304 stainless steel resulted in lower nucleation [8]. Increase in overpotential or current density activates more and more of the potential nucleation sites and this can be seen as higher number of nuclei [9] or smaller average distance between nuclei [10]."

Jan 1, 2012

By Jeffrey Shepherd, Scott R. Smith, Eduard Guerra

"Electrochemical and spectroscopic evidence for the dissolution of a Au electrode by meso-2,3- dimercaptosuccinic acid (DMSA) from an acidic LiCl04 electrolyte is presented. Near the potential of zero charge, DMSA was determined to form a stable layer on the metal surface but at more anodic polarizations, DMSA was displaced from the metal through an oxidative process. The anodic displacement of the layer from the electrode resulted in a small amount of Au that was detected in the electrolyte using atomic absorption analysis. The extent of Au dissolution, was monitored while holding the potential of the electrode for 24 hours at the thermodynamic Eo/H,O in LiCl04 electrolytes containing 10 mM DMSA. This routine resulted in detectable quantities of a soluble Au-DMSA complex in the electrolyte and the greatest leaching was observed at a pH = 2.0. At room temperature, the leaching rate was stable at 10.9 µg cm·2 hr·' however, upon increasing the temperature to 50.0°C, the rate of Au dissolution increased yielding an average rate of extraction of 40.1 µg cm·2 hr- 1. Interestingly, after the first 12 hours of leaching at 50.0°C, the leaching current decreased dramatically suggesting surface passivation which prevented further Au extraction. The implications of this process in the industrial leaching of Au will be discussed.IntroductionThe use of cyanide in the industrial process of leaching Au from ores has raised concerns regarding both operational safety and environmental issues surrounding the disposal of spent leaching eftluents in tailings ponds. Depending on the chemical nature of the processed ore, the spent solutions that are released into the tailings ponds can contain toxic cyanide, either dissolved or complexed with different metals and may pose serious risk to wildlife as well as freshwater contamination to nearby water systems. Because of these issues, some recent studies have focused on the exploration of more environmentally-friendly molecules to selectively leach Au with appropriate kinetics. However, to effectively leach Au into an aqueous solution, a suitable ligand that reacts to form a stable chemical bond with Au is needed to form soluble Au complexes that can be later recovered [I]. Recently several sulfur bearing alternatives have been shown to leach significant quantities of Au in aqueous solutions. These include thiourea [2], thiocyanate [3], and thiosulphate [4]. However, alkylthiols are also known to quickly form a stable covalent Au-S bond [5], but have been relatively understudied in term of their ability to leach Au in solution, even though some short chain thiols are water soluble and relatively nontoxic."

Jan 1, 2012

By D. Richers

When modeling predictive pit lake chemistry, groundwater chemistry is integrated with the affected portions of the wall rock and chemistry of the lake in a complex series of mixing. Fractions of the solutions impinge upon fresh, unaltered or fractured and oxidized zones of the wall containing sulfide materials and/or soluble metal/metalloid salts. Changing conditions over the short term (biannually) and long term (decades) can drive reactions allowing for dissolution or precipitation of acid rock drainage and metal leaching (ARD/ML) constituents. Local zonal variations can result in a portion of the pit releasing materials into solution; whereas other portions of the lake might favor the formation of colloids or precipitants. The proportions and character of groundwater can drive the chemistry of the pit lake provided sufficient buffering capacity is available to temper the generation of ARD in the system. For sulfide-rich systems, reduction of oxygen by rapid inundation and consumption by sulfides is key to reducing the ARD/ML. This paper presents several models of a sulfide-rich wall rock system using a range of groundwater chemistries to show these constraints.

Jan 1, 2012

By Raymond E. Sandiford

"The redevelopment of the World Trade Center (WTC) provided an opportunity for the Port Authority of NY and NJ to complete a long sought underground connection between all of Lower Manhattan’s transit lines, the World Trade Center and the World Financial Center (WFC) (Figure 1). Creating this connection was a challenge because the WFC lies west of the heavily trafficked Route 9A, also known as West Street. The previous connection was a bridge that required pedestrians to make significant level and directional changes to navigate the crossing. The positioning and elevation of the Route 9A pedestrian tunnel was established to provide pedestrians with a clear, single level, climate controlled corridor from the new WTC Transit HUB to escalators leading into the WFC Winter Garden.As the most direct link to the WFC, tens of thousands of people a day will use the pedestrian corridor. To accommodate this large number of pedestrians and provide an obstruction free passage, the tunnel has a clear width of 50 ft (15.2 m). Although only 250 ft (76.2 m) long, that short length presented many technical challenges.Here I describe how the challenges were overcome during the construction. However, some of the truly problematic issues arose from coordinating the phasing of this project with adjacent construction activities at the WTC, the reconstruction of Route 9A, and the WFC’s redevelopment program. The limited access to the excavation areas and confined site logistics were further complicated by having to maintain six lanes of traffic on Route 9A at all times. The efforts were so intertwined that, well into the underpass construction, the Port Authority Construction Department decided to merge a portion of that work into the WFC redevelopment."

Jan 1, 2012

By M. Sakata, H. Hata, K. Haiki

"Most of the secondary ZnO contains fluorine (F) in large quantities. Serious troubles at the zinc electrowinning are occurred by the cathode corrosion caused by F, therefore we developed iron compounds as F-adsorbents used in zinc sulfate solution. The iron compounds can be reused repeatedly as F-adsorbents because they can adsorb/desorb F alternatively depending on the pH. Moreover, if the adsorptive capacity decreases, we can dissolve and re-synthesize them easily. In this paper, results of the experimental process which consists of five steps (leaching, F removal, Cl removal, purification and electrowinning) to produce high purity electrolytic zinc from the secondary ZnO are reported. INTRODUCTIONThe recycle material for zinc, secondary ZnO, contains large amounts of fluorine (F) and chlorine (Cl) which are halogen elements, compared with calcine obtained by roasting of zinc sulfide concentrate. The halogen elements cause adverse effects in the zinc electrowinning process and particularly F causes corrosion of aluminum cathode plates and eventually sticking of electrodeposited zinc and therefore, F concentration in the electrolyte is controlled to less than approximately 20 mg/L. There are several methods to remove F from secondary ZnO, such as leaching with Na2CO3 or NaOH solution [1-2], vaporizing in a rotary kiln by roasting at 1000 to 1200 degrees C [3-4]. However, up to the moment, there has been no effective method for the removal of F from zinc electrolyte and it has been a big obstacle in treatment of secondary ZnO in electrowining of zinc.The authors, therefore, developed an iron compound used as an adsorbent of F in the zinc sulfate solution [5-8]. This iron compound is Akaganeite that has a crystalline structure of ß-FeOOH. Akaganeite is synthesized by neutralization of FeCl3 solution containing a small amount of SO4 2- with Na2CO3. When this iron compound is immersed into weak acidified zinc sulfate solution, F in the solution is adsorbed. F adsorbed in the iron compound is removed by immersing in weak alkaline solution and the iron compound can be reused as F adsorbent."

Jan 1, 2012

Significant advances have been made in the design of centrifugal slurry pumps that are used for pumping high-density viscous and paste slurries. This paper presents the results of a series of centrifugal pump performance tests that were conducted using an FLSmidth 6 x 4 Krebs millMAX centrifugal pump. The pump was fitted with a dry mechanical seal to prevent dilution of the slurry from gland service water, as the theology of the slurry is sensitive to small changes in slurry density. Tests were done using paste kaolin slurry with Bingham yield stress values between 578-1 120 Pa and plastic viscosities between 728 and 1491 mPa.s. The viscous properties of the paste during each pump test were measured using a rotational viscometer. Pump head and efficiency de-rating were measured and compared to the correlations of Walker and Goulas (1984). The test data shows the pump's best-efficiency point (BEP) changes and shifts to the left of the performance curve. The pump efficiency decreases as the slurry yield stress increases. The head de-rating data shows more head de-rating at the low flow rates compared to the high flow rates for the high viscosity slurry, which is in line with the findings of Walker and Goulas (1984). This paper demonstrates that it is possible to pump very viscous, high yield stress slurries with limited head and efficiency de-rating using centrifugal pumps, provided that positive suction conditions are maintained at all times.

Jan 1, 2012

By Baokuan Li, Fang Wang, Meilong Shan

"As the advantage of uniform bus loading, the electroslag remelting (ESR) furnaces with three - phase installation by delta or star connection are mainly used to produce the large or super large ingot. The electrical efficiency is significantly improved as the short circuiting through the molten slag. However, little is found about fiindamental research on the electromagnetic field of the ESR system with three -phase installation. A three-dimensional (3D) finite element model was developed to simulate the current density, magnetic field, electromagnetic force and Joule heating for a system of electrode, slag and ingot in the ESR system with three -phase installation.IntroductionThe metallurgical performance of the ingot is the fundament and precondition to obtain the large forging of high quality, which has a critical role in the producing of forging. The electroslag process (ESR) to product the metal materials of high homogenization and clarity become more and more popular[1].The electroslag process is a special smelting technology of producing small ingots, which originate in 1950[2].At present the three, four or six electrode is used in large scale electroslag furnace. It has been found that the deeper molten pool and the wider of the two-phase zone with only one large diameter of electrode to product large ingot effect the solidification microstructure of ingot[3]. However, the molten pool becomes shallow relatively with several electrodes producing the large ingot, which is benefit to the solidification microstructure of ingot. Three electrodes electroslag remelting furnace take the three phase equilibrium power supply to making the load and electric power network balance, avoiding the distortion phenomenon induced by single phase power supply and saving electric power. It also can uniformize the distribution of heat source."

Jan 1, 2012

By K. Mayhew, R. Bruce, A. Heidel, G. P. Demopoulos

"Teck and Aurubis are working together to commercialize a technology for the processing of copper arsenic sulphide concentrates that is economic and sustainable with regards to the environment and community. The pressure hydrometallurgical approach is a desirable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. A test work program was carried out where a range of copper concentrates with varying arsenic grades was processed under CESL leach conditions. This paper discusses the stability character (in terms of arsenic) of the resulting residues and their mineralogy. The basic ferric arsenate sulphate phase (BFAS; otherwise known as type 2) was identified as the main arsenic carrier. All CESL residues demonstrated high stability (<1 mg/L As) through a range of aggressive (pH and ORP) environmental leach conditions.INTRODUCTIONArsenic deportment and control in the copper industry needs an integrated approach involving each stage of the value chain, i.e. exploration, mine operation, refining process and mine closure. Teck Resources Limited (Teck), Canada’s largest diversified mining company and Aurubis, Europe’s largest copper producer, have formed a partnership to advance the application of CESL copper-gold technology for the development of high arsenic bearing copper resources (Bruce et al., 2011).Among the options for arsenic control in the metallurgical treatment of copper concentrates is the precipitation of ferric arsenate, which is widely accepted as the most suitable method for stabilizing arsenic (Ferron and Wang, 2003). The pressure hydrometallurgical approach to processing arsenic bearing copper concentrates is a favorable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. Under CESL pressure leaching conditions (150 °C, 1380 kPa) high copper extraction and arsenic (V) fixation is possible.Within the pressure leach autoclave, arsenate and ferric iron react to form scorodite type phases. The precipitate formed under CESL conditions is dependent on the Fe (III) /As (V) ratio and the tenor of cations and anions, particularly excess sulphate (Gomez et al., 2011a). Previous studies on CESL residues have found arsenic to be present as crystalline scorodite (FeAsO4.2H2O) (Bruce et al., 2011), basic ferric arsenate sulphate (BFAS: Fe(AsO4)1-x(SO4)x(OH)x·(1-x)H2O, where 0.3<x<0.7), and/or arsenate adsorbed on to hematite (Gomez et al. 2011b). Although not a focus of previous work, scorodite was the predominant precipitate formed when the concentrate Fe/As was <1.5 (Mayhew et al., 2010), and BFAS was the predominant precipitate when the concentrate Fe/As was >10 (Gomez et al. 2011b)."

Jan 1, 2012

By E. Sun

Tailings disposal is a significant consideration for the mining industry, with the majority of the ore processed in most mining operations ending up as tailings. Several tailings dam failure accidents have occurred during the past few years and mine tailings dam failures are occurring at relatively high rates. Tailings dam failure is disastrous with the serious damage and the loss of lives. To increase the tailings dam safety, a tailings dam monitoring and pre-alarm system (TDMPAS) based on the internet of things and cloud computing platform has been accomplished with the abilities of real-time monitoring of the saturated line, impounded water level, rain fall and the dam deformations etc. The TDMPAS has been applied in several mines in China and helped the mine engineers monitor the tailings dam safety and get warning information automatically and remotely in any kind of weather conditions. This work has been demonstrated the tailings dam monitoring and pre-alarm system (TDMPAS) is meaningful to monitor the tailings dam physical safety condition. The TDMPAS could be applied to monitor all the national tailings dams online in the future.

Jan 1, 2012

By Matthew S. Sanchez, Richard J. Lee, Matthew D. Zock, Drew R. Van Orden

"Current Environmental Protection Agency (EPA) risk models and asbestos fiber counting techniques for monitoring airborne exposures treat all fibers as being equivalent and ignore the effect of dimension on toxicity. While this may have been appropriate when modern analytical methods were not available, the measurement world is now fully capable of making the appropriate distinctions. The importance of width as a determinant of carcinogenicity has been recognized for nearly 30 years within the published literature. Stanton,1 in a landmark study of a suite of fibrous materials, found that durable mineral fibers with widths less than 0.25 mm and lengths longer than 8 mm were causally associated with the induction of tumors. Pott,2 in a later study, postulated a fiber toxicity model that agreed reasonably well with the Stanton findings, but extended the concept to include varying toxicity as a function of length and width. Wylie et al.3 reanalyzed samples used by Davis et al.4 and found that tumor generation was strongly and inversely correlated with fiber width. Crump5 testified increasing fiber length was correlated with disease occurrence. Lippman6 reviewed a number of studies and suggested that mesothelioma was closely associated with long, thin fibers. Berman et al.7 published a risk model, which found that disease was correlated almost exclusively with fibers longer than 40 mm and width less than 0.25 mm. Recently, Loomis et al.8 reanalyzed textile mill samples and found that aspect ratios greater than 40:1 were highly correlated with disease. Incorporation of width into risk models has been limited by the availability of data from operating asbestos plants and, in particular, the observation of an asbestos plant for which there is no observable mesothelioma. There have been only limited studies published on the dimensions of asbestos fibers, with a few serving as the primary references in other literature.9_13 A rare opportunity to collect detailed concentration and dimensional data of airborne crocidolite from an operating asbestos-cement plant using modern analytical procedures arose, providing a chance to supplement the existing literature on airborne fiber dimensions. The asbestos-cement plant is located in the eastern end of Cochabamba, Bolivia along Highway 4. Cochabamba is a relatively large city located in the Andes Mountains, approximately 250 km southeast of the capital La Paz. The city sits in a valley that runs east-west with mountains to the north and south. The crocidolite used in the products made at this facility is mined in central Bolivia, approximately 75 km northwest of Santa Cruz. The crocidolite is a fibrous magnesioriebeckite 14 (blue asbestos). Crocidolite fibers from Bolivia were the subject of prior reports suggesting the fibers are generally longer and thicker than crocidolite from Australia or South Africa.9 At the cement plant, the run-of-mine crocidolite was first pulverized using a hammer mill and then sieved on vibratory sieves to produce fibers of limited size ranges for use in the cement. The sieved crocidolite is mixed with other components, including recycled cement product, to produce a slurry that is vacuum filtered into sheet form. The sheets are then manually molded into a corrugated shape, air dried, and sawed (using circular saws) to accepted dimensions. The sawed sheets are cured in soaking pits for 28 days before being shipped to the consumer. Prior to shipping, the sheets are finished by a light hand sanding followed (at customer request) by applying one or more coats of paint. A detailed description of the cement plant and the industrial hygiene results can be found in Van Orden et al.15"

Jan 1, 2012

By Ry Stone

To maintain longwall continuity, NRE Wongawilli Colliery extracted the approximately 20-year-old Thompson Mains and in doing so, 20 roadways were holed into during longwall retreat. The orientation of these roadways with regard to the longwall face varied between (i) a parallel alignment where the entire roadway was simultaneously subjected to a significant increase in vertical stress on holing and (ii) a more favorable high angle of alignment, meaning that only a portion of the roadway was subjected to an increase in vertical stress on holing. In addition, the longwall holed into and was recovered in one of the existing roadways. The geotechnical environment presented several additional challenges during longwall retreat. The orientation of the stress field resulted in a major horizontal stress notch on the maingate and an elevation in the major horizontal stress in front of the longwall face during the retreat up to an adjacent goaf edge. The presence of geological structure zones also resulted in both swings in the major horizontal stress direction and increased levels of roof deformation. The gate road support designs were based on commonly accepted strata management techniques and principles. The support designs in the hole-through roadways were based on empirical design models generated from (i) aconceptual geomechanical model of pre-driven hole-throughand recovery roads and (ii) a worldwide database on pre-driven hole-throughand recovery roads. Imperative to the success of extracting the panel was a sitespecific strata management process. In this regard, consideration was given to the following: roof displacement monitoring in the gate roads (in particular, Longwall (LW) Acceleration Position), roof-to-floor convergence monitoring in the hole-through roadways, the ability of the mine to limit downtime prior to and during holing by utilizing an Authority to Mine (ATM) type process, and the use of Trigger Action Response Plans (TARP).

Jan 1, 2012

Acid heap leaching has been extensively applied to the processing of copper oxide ores, with recovery of copper by solvent extraction and electrowinning. Heap leaching has also been extended to the treatment of secondary sulphide copper ores, where oxidative conditions are generated in aerated heaps by the bacterially-assisted oxidation of ferrous iron to ferric iron. The treatment of low-grade chalcopyrite ores has recently been the focus of research, with Mintek playing a prominent role. When processing chalcopyrite ores, more complex column test work is performed, which incorporates the prediction and simulation of temperature behaviour in pyrite-containing heaps. Mintek has devised a trade-marked column leaching apparatus (SmartColumn?) for the simulation of the natural temperature profile development in pyrite-containing heaps. As heap leach applications are becoming more complex, the parameters that need to be built into the design and operation of heap leach plants are growing in number, and the amount of data to be collected and processed, and the number of decisions to be taken daily, are also increasing. Mintek has therefore developed the HeapStar® administrative advisory software, as a guidance system to ensure that the correct protocols are implemented at various stages of the leach cycle.

Jan 1, 2012

By R. F. Taberer

Within the technology field generally known as biological heap leaching or percolation leaching, lies a wealth of technological knowhow that is potentially patentable and therefore can form the subject matter of patent applications. An organization often overlooks the potential for generating intellectual capital during its research by dismissing the possibility that what it is working on may be novel and inventive and therefore patentable. The organization labours under the misconception that there is nothing patentable in its work mainly because the novel aspect is overlooked against the general background state of the art or, if identified, is not recognized as having sufficient inventive merit. In the field of biological heap leaching, patents have issued on inventions that extend across a large range of technology, including microbiological inventions-for example a particular strain of microbe used in a heap leach application, electro-mechanical inventions, for example a column simulator that simulates the heap leach environment, and thermodynamic inventions such as methods of generating and maintaining heat in a heap.

Jan 1, 2012

By M. Demuth, B. Holleis, M. Potesser, D. Spoljaric

"In 2005, Messer Group established a technology competence centre for metallurgy in Gumpoldskirchen (Austria), with the aim to develop oxygen burners which satisfy today's and upcoming standards of legislation as well as customer requirements. With the assistance of the Development Sponsorship Fund (FFF) of Austria, cooperation with the University of Leoben was agreed on. With the long term experience of the Gas-Warme-Institut ""GWI"" in Essen (Germany) and the University of Leoben, different new burners have been developed.The efficiency of industrial combustion processes can be increased in two ways (which can be seen in Figure 1 ), either by preheating the fuel and combustion air or by adding oxygen. Due to the high 79 % Nz ballast in air combustion, only low flame temperatures can be reached. This results in high heat loss in the exhaust gas, caused by the low combustion efficiency. Oxygen can be introduced into the combustion chamber using different techniques:• Oxygen fuel burners• Direct oxygen injection into the fuel air flame• Underlaying of the fuel air flame• Enrichment of the combustion airIn Figure 2, the theoretical flame temperature for the stoichiometrical combustion of natural gas is plotted as a function of oxygen enrichment. Therefore, it can be concluded that even low enrichment values produce higher flame temperatures and result in higher combustion efficiency."

Jan 1, 2012

By Huimin Lu, Qiang Li, Jingbo Xu

"The smelting reduction of V-Ti bearing beach placer by combined rotary hearth furnace and direct current arc furnace was studied in laboratory. It takes the aid of back propagation (BP) neural network theory to build the nonlinear mapping relations between the crucial process variables such as content of carbon, temperature and time and the degree of reduction. Then by the integrating BP neural network and genetic algorithm (GA), the optimized process parameters for the high degree of reduction were searched. The comparisons between experiment results and neural network simulation results show that GA-based on BP method can predict the degree of reduction with higher prediction accuracy. Calculations show that the integrated energy consumption of new technology is 580kgce/tHM, less than the current existing blast furnace.IntroductionThese V-Ti bearing beach placers (VTBBP) are secondary Fe-rich minerals formed by rivers, ocean waves, ocean tides and ocean currents on beach zones, their useful minerals are V-Ti magnetite ores. On Asia Pacific zone, such as Japan, China, Philippines, Indonesia, Australia and New Zealand, the VTBBP have large reserves and wide distribution. But so far, the VTBBP are not still comprehensively utilized. Therefore, in this paper, a combined rotary hearth furnace technology and arc furnace smelting method is studied for comprehensive utilization of the VTBBP. The main objective of this paper is to find optimum operation conditions for the production ofV-bearing iron and titania-rich slag from the VTBBP by means of the laboratory testing.Recently, neural network (NN) expected to be able to provide an effective tool because of its advantages, which describe nonlinear mapping relations. With the characteristics of strong selflearning, self-organization, robust error toleration and accurate nonlinear relation approximation, artificial neural network can be applied to nonlinear process modeling based on sufficient training. Back-propagation (BP) training algorithm is probably the frequently used one in practical application. Genetic algorithm has parallel search strategy and global optimization characteristics, which makes the trained neural network being higher classification accuracy and faster convergence speed. So it is necessary to combine neural network and genetic algorithm. The nonlinear relationship between input and output presented by NN and the global optimal function of GA are abroad applied in the engineering and scientific research [1, 2]. So these methods supply an efficient path to solve the above problems. At present, it is common to study the optimization of process parameters by orthogonal experimental design, the method combining neural network and genetic algorithm is a novel and better method than orthogonal experimental design. Tills study organized the above advantages to optimize the process parameters for comprehensive utilization of the VTBBP."

Jan 1, 2012

By Tim Robinson, Georges Houlachi, Michael Moats, Marco Ginatta, Michael Free, David Creber, Neale Neelameggham, George Holywell

"Electrolytic processing is used commercially to recover and/or refine metals such as aluminum, copper, magnesium, nickel, and zinc. There are also new and exciting opportunities to utilize electrometallurgy in the production of titanium, lead, and other metals. This paper reviews some of the main technologies that are used to produce and refine metals as well as some of the recent advances and future directions the electrometallurgy industry may implement to meet the challenges faced now as well as those that are likely to be faced in the future.IntroductionElectrolytic processing is used commercially to recover and/or refine metals that include large scale production for metals such as aluminum, copper, magnesium, nickel, and zinc as well as small scale production for metals such as gold and silver. There are also new and exciting opportunities to utilize electrometallurgy in the production of titanium, lead, and other metals. This paper will focus only on electrometallurgical processing of metals with relatively large production markets."

Jan 1, 2012

By D. Brady

There are many examples, historical and recent, from the underground coal mining industry where during emergency response the response and ultimately the outcomes, could have been significantly improved if adequate systems had been in place for the collection and management of relevant information preceding the incident, the acquisition of information during the incident and the use of the information for risk mitigation and decision making purposes. The subject and process of knowledge management is possibly the most critical for would be rescuers of endangered coal mine workers, as it has been demonstrated at numerous coal mine incidents that a lack of or mismanagement of crucial information can be fatal for both the rescuer and/or the endangered coal mine worker. This paper will underline the scope and importance of robust knowledge management systems for emergency response within the underground coal mining industry and the process by which it is being achieved within the Queensland Mines Rescue Service and the NSW Mines Rescue Service.

Jan 1, 2012

By W. Biermann

All industrial processes are economically driven, resulting in the ever increasing need for process optimization in order to stay competitive and profitable. Numerous models has been published depicting the optimization of the raw material usage in an arc furnace, as well as the thermal and electrical efficiency; however, to obtain a holistic view of the cost-effectiveness of the process one needs to expand the model to include the cost of all the operational variables. This project therefore aimed to not only include the raw material feeds and power consumption as input variables, but also the labour, maintenance, and environmental costs to generate an all-inclusive financial balance. In the end, the model was able to mathematically optimize the ferrochrome (FeCr) production process through evaluating the effect of a specified combination of input parameters. It could therefore be used as a tool to aid in managerial decision-making; to appraise and correspondingly adjust certain operational variables in order to achieve a maximum return on investment. This paper fully describes the reasoning behind the choice of the essential model components, the assumptions made during the models development, the calculation approach, as well as the advantages, limitations, possible applications, and areas for expansion of the final model. Through running simulations with plant data, it was found that the accuracy of final model remained fairly constant when applied to stable furnace conditions, but was met with a number of limitations when applied to more complex situations. These limitations could, however, be overcome through further development and expansion of the existing model to include a larger number of process variables.

Jan 1, 2012

By Xiaodi Huang, Matthew Andriese, Zheng Zhang, Jiann-Yang Hwang, Zhiwei Peng

"The thermal decomposition and regeneration behaviors of wüstite were investigated by in situ high temperature X-ray diffraction (HT-XRD) under non-isothermal condition at heating rate of 4 K min-1 in vacuum ranging from 294 K to 973 K. Wüstite on heating decomposes to magnetite and iron up to 823 K, above which it exhibits marked tendency to regenerate. Investigation of thermal stability of the reaction system shows that the decomposition proceeds under kinetic reaction control while the regeneration is under thermodynamic control. Kinetics study based on the Coats-Redfern integral approximation method indicates that the decomposition reaction follows a Komatsu-Uemura model-based diffusion-controlled kinetics with activation energy of 32.860 kJ mol-1. The thermodynamics analysis of regeneration reaction demonstrates that wüstite regenerates at lower temperature than stoichiometric ferrous oxide.IntroductionOwing to its importance in preparing various magnetic ceramic/metal nanocompostites or nanocrystals with high values of coercivity for the application as recording media, wüstite (non-stoichiometric ferrous oxide) has been attracting the attention of scientists over a long period [1-6]. The thermal behavior of wüstite was investigated by several researchers and phase transformations due to thermal decomposition and regeneration of wüstite during the heating in a specific temperature range was observed [7-9]. In spite of wüstite being found to dissociate to magnetite and iron at temperatures lower than 848 K and then regenerates at higher temperature, a clear understanding of the reaction mechanisms is clearly lacking [9]."

Jan 1, 2012