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By R. Rumpold, J. Antrekowitsch

"The continued increase of the automobile production leads to a higher platinum, palladium and rhodium (PGM) demand. Due to the high value of the PGMs the recycle of these metals from automotive catalysts is of special interest. Pyrometallurgical processes, which are only focused on the PGMs, represent the state of the art of automotive catalysts recovery. However, hydrometallurgical recycling processes offer additional recovery of other valuable metals and compounds. The method presented in this paper is based on a combination of hydrochloric acid and hydrogen peroxide to dissolve the valuable metal fraction which can be precipitated afterwards.INTRODUCTIONPlatinum and the corresponding metals from the PGM group, especially palladium and rhodium are well known as catalytic active materials. They support chemical reactions which are inhibited. This effect is used to decrease the amount of harmful compounds like hydrocarbons, carbon monoxide or nitrogen oxides in automotive exhaust gases. The generation of these toxic substances is based on incomplete combustion, which in turn is caused by non-ideal conditions in the combustion chamber. Catalytic converters minimize the harmful compounds by supporting the following Reactions 1 – 3 (Votsmeier et al., 2009).CO + ½ O2 ? CO2 (1)CnHm + (n + ¼ m) O2 ? n CO2 + ½ m H2O (2)2 NO + 2 CO ? N2 + 2 CO2 (3)Platinum and palladium are very effective for the oxidation (Reactions 1 and 2), while rhodium supports the decomposition of nitrogen oxides by carbon monoxide (Votsmeier et al., 2009). The classical three way catalyst was a platinum – rhodium combination with a Pt:Rh ratio of 5:1 (Hagelüken et al., 2005). Today the platinum, palladium and rhodium ratio is highly variable and strongly depends on the engine type as well as on the car producer. Diesel engines are operated with a super stoichiometric air addition in comparison to spark ignition systems. Therefore the exhaust gas composition and off gas temperature is different. Based on the high oxygen amount, diesel engines produce less carbon monoxide and hydrocarbons but more nitrogen oxide in contrast to gasoline engines. This leads to various requirements for the catalytic converters."

Jan 1, 2012

By Lianjun Liu, Ying Li, Qianyi Zhang

"Photocatalytic reduction of CO2 by H2O for production of Cl fuels (CO and CH4) was studied using copper and iodine co-modified TiO2 (Cu-IffiO2) nanocomposites, with copper deposited on the surface and iodine doped in the lattice. The nanocomposites were prepared via a combined hydrothermal and wet impregnation process. All I-doped samples demonstrated visible light activity. Under UV-vis irradiation, co-modification of Cu and I significantly increased TiO2 photoactivity compared with bare TiO2 or those modified with only one species.IntroductionThe photoreduction of CO2 into fuels on photocatalysts such as TiO2 has been regarded as an important approach to solve both energy shortage and globe warming problems [1]. However, the wide band gap and fast recombination ofphotoinduced hole (h+) and electrons (e"") limited the application of TiO2 in CO2 photoreduction reaction. Extensive research has been conducted to improve the photocatalytic ability ofTiO2 by depositing or doping foreign ions that can enhance charge transfer and/or creates intra-band-gap states to induce visible light absorption at the subband- gap energy. Compared with mono-doping, co-doping of metal/nonmetal species has been reported to have higher photocatalytic activity for TiO2 [1-3]. Our previous studies showed that Cu deposited on TiO2 [4] or iodine doped in TiO2 [5] significantly enhanced the catalytic efficiency for CO2 photoreduction and increased the response to visible light. We hypothesize that there could be a synergetic effect if TiO2 is co-modified by both Cu and I species resulting in further improvement in CO2 reduction efficiency. In this work, we synthesized and characterized Cu-IffiO2 samples and investigated their activity toward CO2 reduction under visible and UV-vis illumination, respectively.Experimental MethodsMaterialsTitanium tetra-isopropoxide (TTIP, 98%) and isopropanol (C3HsO, 99.8%) were purchased from Acros Organic. Iodic acid (HIO3,99.8%) and Copper Chloride (CuCh, 99.9%) were purchased from Alfa Aesar. All other chemicals were analytical grade and used without further treatment."

Jan 1, 2012

By Tom Meikle

Long tendon support systems provide several challenges when used in-cycle as part of the secondary or primary support cycle. A two-component pumpable resin, Carbothix, has been in development for use with self-drilling rock bolts, but many of the attributes of this new resin system make it ideal for grouting long tendon support systems. While neat Portland cement grouts or polyester resin capsules have been used with long tendon support systems for many years, two-component pumpable resin systems overcome many of the shortcomings in these systems. The two-component systems dramatically improve the set-time to enable mining face advance with fewer delays, enable longer pumping distances, improve quality control, and enhance load transfer mechanisms. This paper describes the key benefits associated with a new pumpable resin and details the Australian Department of Mines and Petroleum department atmospheric testing results and cable load testing completed by Minova personnel to date. It also details the results of the Australian mine site trials and the introduction of these systems into production use.

Jan 1, 2012

By Jack Zhang, Chuck Edwards

"The versatility and specificity of rare earth elements (REEs) have led to their use in an ever increasing variety of applications in new technologies. Consequently, demand for REEs has increased significantly. However, to separate REEs safely and effectively is a complex and expensive process. While China has consistently invested in R&D of REE processing technologies, there have been only sporadic activities in REE mineral processing in North America in the past 20 years. This paper presents a review of REE mineral processing technology, providing an update on current capabilities in REE mineral processing. This paper reviews REE extraction from the major commercially valuable REE-bearing minerals such as bastnaesite, monazite, and xenotime, and also from the ion-absorption type of REE deposits. Currently, there are four major REE mining areas in China, one in the United Sates, and one in Australia. A review of the REE extraction processes in these major REE mining areas closes out the paper.INTRODUCTION The rare earth elements (REEs) include the 15 lanthanide elements, plus yttrium and scandium. The lanthanide elements are normally categorized in two groups: the light rare earth elements (LREEs), i.e. lanthanum through europium (atomic number (Z) = 57 through 63); and the heavy rare earth elements (HREEs), i.e. gadolinium through lutetium (Z = 64 through 71). Yttrium is usually grouped with the HREEs due to similarity in physical and chemical properties. Table 1 lists the REEs, atomic numbers, and abundances in earth’s crust (Taylor and McCleannan, 1985). Promethium is the rarest due to lack of stable isotopes. REEs with low atomic numbers are more abundant than those with high atomic numbers. More interesting is that the REEs with even atomic numbers are much more abundant than adjacent lanthanide elements with odd atomic numbers as shown in Table 1."

Jan 1, 2012

By D. G. Almond

Nkomati Nickel Mine in South Africa processes one of the world?s hardest ores in a 375k TPM autogenous grinding circuit. The plant employs an unconventional processing circuit, comprising a primary autogenous mill (AG or FAG) and pebble crushing circuit followed by a secondary hybrid pebble/ball mill and classification cyclone cluster. Advanced Process Control (APC) or Expert Control is now generally accepted as an advantage in most modern high capacity concentrator grinding circuits. This paper reviews the installation of model predictive control at Nkomati and examines the results and benefits of installation in an autogenous mill during plant ramp-up. The paper also demonstrates how predefining process control objectives together with good plant and supplier cooperation can achieve a robust and reliable APC implementation on a very short site program. The results conclusively demonstrate operational and economic benefits during circuit operation with the advanced process control system ON. Production performance and circuit stability were significantly better than during manual control.

Jan 1, 2012

By X. Yuan

"The processing behaviours of ores such as their liberation characteristics in comminution and their response in separation processes are affected by their mineralogical characteristics. Key ore characteristics which are relevant to processing, such as mineral proportions, mineral grain size, grain shape and mineral associations are routinely measured at the micro-scale in polished section using optical microscopes and SEM-based automated mineralogy systems. The application of X-ray micro-tomography to mineral processing provides the means to quantify these important micro-textural characteristics in three dimensions, removing the stereological issues encountered when measuring volumetric information in two-dimensional polished sections. In this paper we present several examples of ore textures to illustrate where X-ray micro-tomography can be applied successfully to obtain quantitative measures of ore characteristics which are useful in a variety of process modelling applications.INTRODUCTION X-ray tomography has been used as a tool in medicine for some years and is being applied in a wider range of fields including geology, palaeontology and mineralogy. In this paper we present some applications of X-ray tomography in mineral processing applications being developed at JKMRC. The availability of SEM-based automated mineralogy systems such as MLA and QEMSCAN has seen the increased use of quantitative mineralogical data measured in two dimensions in the design, operation and simulation of mineral processing plants. When the ore is amenable to measurement by X-ray tomography this technique can provide quantitative data for characteristics such as mineral grain size, shape, mineral associations and liberation in three-dimensions. The advantage of measuring these characteristics in three-dimensions is that the stereological issues which bias measurements made on polished sections are removed. X-ray tomography also quantifies the location of mineral grains relative to one another in space - a useful descriptor of ore texture. Like many measurement techniques X-ray tomography has advantages and disadvantages when compared to other techniques. One limitation is that the ability of the X-ray tomography system to discriminate between minerals is a function of the X-ray attenuation of those minerals. While the X-ray attenuation of many common minerals is sufficiently different for X-ray tomography to distinguish between them, there are some where the overlap in X-ray attenuation makes discrimination on the basis of this characteristic alone impossible. An example of this would be chalcopyrite and magnetite. However where the ore mineralogy is suitable to apply X-ray tomography, the technique provides some exciting opportunities to explore the relationship between texture and ore processability."

Jan 1, 2012

By D. R. Wilburn

his summary of international mineral exploration activities for the year 2011 draws upon available information from industry sources, published literature and U.S. Geological Survey (USGS) specialists. The summary provides data on exploration budgets by region and mineral commodity, identifies significant mineral discoveries and areas of mineral exploration, discusses government programs affecting the mineral exploration industry and presents [ ] analyses of exploration activities performed by the mineral industry. Three sources of information are reported and analyzed in this annual review of international exploration: 1) budgetary statistics expressed in U.S. nominal dollars provided by Metals Economics Group (MEG) of Halifax, Nova Scotia; 2) regional and site-specific exploration activities that took place in 2011 as compiled by the USGS and 3) regional events including economic, social and political conditions that affected exploration activities, which were derived from published sources and unpublished discussions with USGS and industry specialists.

Jan 1, 2012

By J. L. Louw

The utilization of centralized blasting systems is progressively becoming a feature of the South African mining industry, owing to increased pressure from the Department of Mineral Resources (DMR) to ensure safer blasting conditions. The purpose of a centralized blasting system (CBS) is to ensure reduced blasting-related incidents and to improve the underground working environment for the mine?s employees. The brief from Samancor Western Chrome Mines (WCM) pertaining to this study was to explore?at a conceptual level?all variables pertaining to the implementation of the CBS. Studies have indicated that Sasol?s SafeBlast? was preferred due to low overall risks and user-friendliness. Empirical observations, however, indicated that attention should be given to the current shaft-clearing procedure and to the installation of additional transformers. This is required to co-ordinate the power supply from 2 level to 10 level with the required supply of the network slave station. A cost analysis indicated that an electronically initiated CBS will result in a R24 cost increase per panel, which relates to a mere 1% cost increase per panel. This cost, in addition to the R1.1 million capital cost, proved to be negligible in comparison to the possible direct and indirect costs incurred by the mine in the event of a blasting-related incident. It was found that Samancor should conduct further studies incorporating the necessary requirements to ensure a successful transition, while considering all stakeholders on the mine. This study proved that the transition to a CBS would ensure safe and efficient blasting at Samancor?s Mooinooi Mine.

Jan 1, 2012

By B. Spigarelli

Carbon dioxide sequestration by conversion to carbonates has become a promising option for CO2 storage. Experiments were conducted to determine the feasibility of CO2 sequestration at ambient conditions using a Ca-rich industrial waste in a carbonate solution. The Ca-rich industrial waste used in this study was lignite fly ash. Fly ash was chosen because it is cheap, available near large CO2 point sources, already in powder form, and reactive due to amorphous properties. In the experimental set-up, CO2 absorption was inferred by monitoring feed and exhaust gas CO2 concentrations. The addition of an alkali to a fly ash-distilled water solution provided a 50% increase in CO2 absorption of the solution. Absorption time also increased by 50% compared to a fly ash-distilled water solution. TGA analysis was used to determine the extent of CO2 sequestration in the carbonate form. At a liquid to solid ratio of 20:1, the conversion of ?free? calcium to carbonates was 75%. A CO2 balance on the system concluded that at the current operating conditions 42% of the total CO2 fed to the system was sequestered in the carbonate form. SEM-EDS analysis of the fly ash particles before and after reaction with CO2 indicated that the carbonate compound being formed was calcium carbonate. The analysis identified rhomboidal structures on the surface of the fly ash particles after reaction with CO2, but not before. These rhomboids are characteristic of calcium carbonate formation and they had higher Ca, C, and O concentrations than the host spheres, suggesting calcium carbonate formation.

Jan 1, 2012

By S. Kahraman

The prediction of rock properties from indirect testing methods is important, particularly for preliminary investigations since indirect tests are easier and cheaper than the direct tests. In this study, we investigate the predictability of the uniaxial compressive strength (UCS) and Brazilian tensile strength (BTS) of rocks from the indentation hardness index (IHI) obtained using point load apparatus. Forty-six different rock types, 14 of which were igneous, 15 were metamorphic, and 17 were sedimentary were tested in the laboratory. The UCS and BTS values were correlated with the corresponding IHI values and the results were statistically analysed. The influence of rock classes on the relationships was also investigated. A strong correlation between UCS and IHI was found for all data. The correlation between BTS and IHI is not as strong as the correlation between UCS and IHI, However, it is in the acceptable limits. When the regression analyses were repeated for igneous, metamorphic, and sedimentary rocks, the correlation coefficients were generally increased. The results show the UCS and BTS can be estimated from IHI, In addition, the effect of rock classes on the relationships between IHI and both UCS and BTS is important.

Jan 1, 2012

By Raphael Trousselle, William Reisz

The blasting industry is now well into its second decade of commercial use of electronic detonators. As an increasing number of blasters are introduced to the technology, the benefits are becoming more widely monitored and accepted in many surface blasting operations. However, their use in underground applications is not yet as widely established. This is primarily due to the distinct cost dynamics and processes associated with underground lasting.

Jan 1, 2012

By M. Maley, S. Burling, R. Ring

ABSTRACT The numerous global uranium deposits vary significantly in mineralogy, grade, and textural characteristics; therefore, information from traditional (or conventional) sources on the fundamentals of leaching uranium and gangue minerals is not always applicable when studying particular ores. Empirical studies can be effective in understanding leach systems and can lead to improvements in process design but there remains a lack of fundamental understanding necessary for ongoing process optimization as ore bodies continue to vary. ANSTO Minerals has undertaken a work program to address several fundamental questions about uranium leaching, including the unexpected impact for some ore types of leaching at high oxidation potential.

Jan 1, 2012

In the last four years, 2007~2010, 9 out of 24 metal/nonmetal underground mine fatalities were caused by ground fall across United States of America (Mine Safety & Health Administration, MSHA). To reduce or eliminate incidents/accidents caused by ground fall, this paper clarified how to design and select ground support based on different ground conditions, how to use mine ground support standards, what geotechnical engineers and underground operators should do to keep mine production free of ground failures.

Jan 1, 2012

By Renxing Li, Yongyong Gong, Yufeng Cheng, Zhenxing Yin, Xin Cao, Qijie Zhai

"This paper investigated the refinement effect of pulse magneto-oscillation (PMO) on the solidification structures of medium carbon steel S45C in metal mould. The induction coil was positioned at the middle of ingot. The results showed that solidification structure of the treated ingots was remarkably modified with a transformation from well-developed dendritic structures to small dendritic structures or globular structures compared to the untreated ingot. The area fraction of modified microstructure regions reached more than 80 percent. A further experimental investigation had been done to understand the influence of refinement effect on the solidification structure under different mould size. Theoretical analysis demonstrated that the mechanism for the refinement of solidification structure was that PMO promoted nucleation near the mould walls and changed the interface temperature gradient and concentration gradient in liquid, eventually leading to a transition from the columnar crystals to the equiaxed crystals.IntroductionIn recent two decades, the electromagnetic processing of materials (EPM) has been widely used in many fields such as ironmaking, steelmaking, and solidification processing [1-6], where EPM can control melt flow, modify melt shape, reduce macro-segregation and refine microstructure. Pulse magneto-oscillation [7-9] (PMO), as a novel technique of EPM, has a remarkable effect on grain refinement and high potentiality to be used in industrial production. Compared with ultrasound refinement technique, PMO can be easily employed to metal solidification processing for long time in no contact with hot metal liquid by using a water-cooled coil. Another important advantage is that PMO needs smaller energy compared to pulsed magnetic field which needs a very high current to obtain a strong magnetic field to get a satisfactory effect. These advantages mentioned above are beneficial for industrial application, which make it potential to be widely used in future. Gong et al. [7] have studied the refinement effect of PMO on pure aluminum and find that PMO can significantly modify the solidification structure of pure aluminum. Li et al. [9] have reported the effect of temperature field on solidification structure under the influence of PMO. On the basis of these works, this paper has studied the effect of PMO on solidification process of medium carbon steel S45C in a metal mould, which can also provide some information for industrial application of this new technique."

Jan 1, 2012

By K. Oraee

Rate of penetration of Tunnel Boring Machines (TBM) has a significant role in the planning, measurement of productivity and performance of any tunneling project. In this paper, the application of Adaptive Neuro Fuzzy Inference System (ANFIS) in prediction of TBM penetration rate is evaluated. For this purpose, a database including Rock Quality Designation (RQD), Uni-axial Compressive Strength (UCS) of the rock, the Distance between Planes of Weakness (DPW) in the rock mass, and empirical data regarding rate of penetration of TBM from several tunneling projects are collected. The Rate of Penetration is then estimated by using ANFIS. These results are then compared with measured TBM penetration rates (actual data). It is concluded that ANFIS can be applied successfully for such purpose and result in high accuracy for prediction for the rate of penetration of TBM. The method provided in this paper can assist the mining engineer to estimate the performance of tunneling accurately.

Jan 1, 2012

By Cristiän Vargas, Jaime Simpson, Gerardo Cifuentes

"This paper presents a new process for the precipitation of Sb and Bi present in copper refinery electrolytes in the presence of Pb02 (Chilean Patent No. 45,037). To establish the conditions under which the precipitating compounds form, it was necessary to evaluate the amount of PbCh consumed, antimony extraction efficiency, precipitate stability, reaction kinetics, diffraction analysis and X-ray fluorescence, separation of size, plus observation of the precipitates in the electron microscope. Preliminary tests were carried with synthetic copper refinery electrolyte, and then the final testing was done with electrolytes from Chilean refineries. This process provides a real alternative for the treatment of copper refinery electrolytes for the control of Sb and Bi in solution; it is very simple to operate and is low cost compared with competing processes.Introduction.A high quality copper cathode implies a cathode free of impurities. The electrorefining process seeks to eliminate these impurities from the copper anode (99.5% purity) by its dissolution in an acid electrolyte using chemical and electrochemical reactions. As a result of this process, a cathode (99.99% purity) is obtained. If the concentration of impurities in the electrolyte, from the dissolved anodes, begins to increase; particularly if the antimony concentration in the electrolyte increases up 500 ppm, the formation of floating slimes which are a major cause of contamination of the cathode is favoured. The most important impurities from the point of view of their effect on the quality of the cathode copper, are Ag, As, Sb, Bi, Pb, Se and Te. Silver is necessary for the control of Se and Te. To control all of these impurities, it is necessary to establish different methods or parameters of control in copper electrorefining. These parameters are anode composition, additives, purification of the electrolyte, current density, acidity, etc."

Jan 1, 2012

By L. R. Herrmann

The most fundamental feature of fracture is that it involves separation. Such separation can arise by either separation of molecules, more or less along the line joining their centers (tension), or by d sliding separation roughly perpendicular to that line (shear). Theoretically, a perfect crystal could never be broken by the application of perfectly axial compressive stress (until some sub-molecular actions occur). In tension fields the calculated forces between molecules are extremely high. Consequently, calculations based on the forces known to exist in materials at the molecular and crystalline levels always lead to strengths which are two or three magnitudes higher than the strengths obtained in service or in the laboratory. It has been a major problem, therefore, to explain: (a) How fracture can occur in compressive stress states. (b) Why the observed strength of a material is always much lower than its calculated strength.

Jan 1, 2012

For the past two years, Cliffs Natural Resources in Minnesota has tried an experiment: it has staffed a booth at the Iron Range Earth Fest. ?It was a little unusual for a mining company to participate in an event that centers around preserving the Earth?s resources,? said Julie Lucas, environmental manager at Hibbing Taconite Company. ?But Cliffs is a sustainable company and we want to take every opportunity to share information about our practices. We found the response to be overwhelmingly positive.? Cliffs? outreach effort is just one of the surprising ways mining companies across Minnesota are reaching out to stakeholders and finding success. The 85th annual SME Minnesota Section Meeting (73rd Annual University of Minnesota Mining Symposium), held April 17-18 in Duluth, MN, demonstrated the Minnesota mining community?s commitment to connection and collaboration, and how that approach is bringing success.

Jan 1, 2012

By Denise Nascimento, Alice Barreto Bevitori, Felipe Perissé Duarte Lopes, Renan Carreiro, Sergio Neves Monteiro, Isabela Leão Amaral da Silva

"Natural fibers obtained from plants have increasingly been used as reinforcement of polymeric composites in engineering applications. This is the case of the fiber extracted from the piassava palm tree, a native of the southeast region of South America, which for a long time has been used in simple items like brooms and brushes. Recently it was reported that the tensile strength of the piassava fiber varied inversely with the equivalent diameter. Following that previous work, the elastic modulus and the density dependence on the diameter of stiffer piassava fibers of the Attalea fiinifera species was investigated. Precise measurements with a profile projector and Weibull analysis of the experimental results indicated that both the elastic modulus and the density of piassava fibers also follow an inverse correlation with the diameter. Scanning electron microscopy observations of the microstructure and fracture surface showed that defects and participation of microfibrils are responsible for this correlation.IntroductionIn the past decades, both the increase in the price of the petroleum and climate changes due to greenhouse gas emissions are motivating the use of renewable and low cost natural materials as a substitute for energy intensive and CO2 contributor synthetic materials [1]. A typical case is that of natural cellulose-based fibers extracted from cultivated plants in comparison to glass fibers, which are extensively used for composite reinforcement. In fact, these natural lignocellulosic fibers are increasingly being investigated [2-6] as possible reinforcements of polymeric composites, and in some cases, successfully replacing glass fiber composites in engineering applications [7]. The automobile industry has remarkable examples of lignocellulosic fiber composite substitutions [8-10]. Not only do some of these fibers display specific mechanical properties comparable to glass fibers but their composites also contribute to lower equipment wear and better finishing of molded components [6]."

Jan 1, 2012

By Maura Malone, Neil Gao, Daniel Liu

"Corrosion is the primary failure mode for aluminum cathode sheets used in Teck's Trail Operations electrolytic zinc plant. It was observed that the corrosion performance of Al cathodes from different suppliers varied considerably. This suggests that the material properties of Al cathodes have a strong influence on corrosion resistance. In the current study, various types of Al alloys, including 1050, 1060, 1070, HIS and 1090, were characterized through chemical analysis, corrosion testing, mechanical testing and metallography. The results are discussed with a focus on the effects of impurity elements and second phase particles on corrosion resistance. The findings were used to improve the Al cathode sheet specification and to develop a standardized screening procedure which details qualification steps for comprehensive evaluation prior to a plant trial.IntroductionAluminum (Al) cathode replacement is a major operating expense at Teck's Trail Operations zinc electrolytic plant. Currently, approximately 0.5% of daily stripped Al cathodes are removed from service because of failures caused mainly by corrosion. Edge corrosion and acid (solution) line corrosion are the most severe types of corrosion, resulting in more than 50% of cathode failures.Corrosion of Al cathodes has been intensively investigated for over two decades and the origins and mechanisms of Al cathode corrosion are well understood [1-4]. Halide anions contained in the electrolyte are the primary culprits for the corrosion and sticking problems of Al cathodes. Both fluoride (F') and chloride (Cl"") result in localized passivity breakdown on the surface of the Al cathode, causing pitting corrosion. Bouarzaiga investigated the corrosion of Al cathode samples partially immersed in electrolyte and found that the formation of Ch at the electrolyte/air interface was the primary contributor to solution line corrosion [2]. Because of the significant impact of F"" and Cl"" on Al cathode corrosion, it is imperative to maintain these concentrations as low as possible in the electrolyte."

Jan 1, 2012