Search Documents

Discussion of the paper of F. C. NEWTON, presented at the New York meeting, Feb-ruary, 1915, and printed in Bulletin No. 9S, February, 1915, pp. 473 to 477. H. 0. HOFMAN, Boston, Mass.-The results of these large-scale experiments, which were carried on at Perth Amboy, show that there are many differences between theoretical conceptions and their applications to work on a large scale. The author has given reasons why the results of bringing a desilverizing kettle to the high melting point of the zinc-silver alloy, Zn3Ag2, melting at 665° C., are not satisfactory. In all probability the alloy is dissolved in the lead; it may also be decomposed by the lead; the practical result is that this high temperature does not work. It remains now for the laboratory man to carry on systematic experiments

Jan 5, 1915

By Heinrich Ries

Fullers' earth is a clay-like substance, which has the property of decolorizing or clarifying oils. An ultimate chemical analysis shows it to differ from most ordinary clays in having usually a high percentage of combined water and a low amount of alumina. There is probably a large amount of hydrous silica present. Fullers' earth possesses little or no plasticity, and in order to work properly has to be ground very fine. A chemical analysis is of little value at present in determining its quality; only a practical test suffices. Up to about two years ago all of the fullers' earth used in this country was imported from England; but about that time deposits were discovered in Florida, "† and since then rumors of its occurrence have been coming from all parts of the country. Next to the Florida deposits of fullers' earth, those of South Dakota are the most extensive thus far discovered in this country. The earth was first discovered near Fairburn, Custer county, and other deposits have since been prospected at Argyle, Minnekahta and other localities. Fairburn.—One of the first deposits located and opened up is five miles southeast of Fairburn, Custer county. The mine is a mile from the Fremont, Elkhorn and Missouri Valley Railroad, and the section exposed shows, beginning at the top: Feet. Micaceous sandy clay,......... 6 Fullers' earth,..........9 Micaceous sandstone,......... The fullers' earth passes upwards into the sandy clay, but in its purer portions it is a yellowish, gritty clay, with a somewhat

Jan 1, 1898

The regular activities of the Institute are financed mainly by income derived from members' dues, from advertising in MINING AND METALLURGY, and from the sale of publications to the public. In addition, collateral activities and special projects are financed each year by means of income from endowed funds controlled and administered by the Institute. In the aggregate, the amount of these endowments totals more than $684,000. An active effort is being made to increase the endowment funds of the Institute through a standing committee, of which Henry Krumb is Chairman, and of which the other members are: George D. Barron, Cleveland E. Dodge, John V. N. Dorr, Howard N. Eavenson, D. %. Jack- ling, Harvey S. Mudd, Wallace E. Pratt, Milnor Roberts, and Wilfred Sykes. This committee believes that there exists a tremendous opportunity for the Institute to be of evergrowing service to the public, to the mineral industries, and to the profession. It welcomes suggestions as to names of men of means who are vitally interested in the mineral industries, and to whom the opportunity to make a contribution or bequest might appeal favorably if presented in the proper light.

Jan 1, 1946

By Lloyd B. Underwood

Dr. Gardener, in Chapter 2, has presented a comprehensive state-of-the- art review of site investigations For tunneling. Nearly all of the techniques he discussed will also be required for future site investigations. Therefore, this chapter will be devoted to a few rather new exploration techniques plus ideas for improving some of the present-day methods. In March 1962, the first symposium on "Remote Sensing of Environment" was held at the University of Michigan.l Since that time, four additional symposiums have been held at the same University. Also, the technical Literature has recently included a number of articles on remote sensing techniques. A recent one appeared in the February 1968 issue of Materials Research and Standards.Vt was entitled "Developments in Remote Sensing Applicable to Airborne Engineering Surveys of Soils and Rocks," and was written by Dana C. Parker. Mr. Parker predicts that aerial reconnaissance will someday supplant soil augers, rock drills, surface reconnaissance, and geophysical surveys as the engineer's primary means of obtaining information about soils and rocks. He states, "The engineer wishing to survey a route or a site or to locate rock and soils suitable for construction projects will be able to push some buttons in an airplane and record all the data required for determining the relevant conditions. In a short time after he returns to earth with his rolls of film and charts, he will be able to reduce and analyze the data by partially computerized techniques and to compile a concise and comprehensive engineering report that gives all the relevant information about rocks, soil, water, and vegetation in the area he surveyed. Most important he will feel as confident with his recommendations, derived primarily from image characteristics and spectral power distributions, as his predecessors did with recommendations based on more tangible evidence obtained from drill cores and surface reconnaissance." The airborne sensors for engineering surveys of soils and rocks are those that sample some electromagnetic property of the materials that com- prise the terrain and cover its surface. In addition to cameras, these include

Jan 1, 1970

By AIME AIME

A CERTAIN area in the State of Indiana seems to be a breeding place for presidents and near president about eighteen miles southeast of Elwood is the little village of Daleville, and there, on April 9, 1890, John Robert Suman, newly elected President of the A.I.M.E., was born. It was not long before he migrated to California, however, where he went to the Los Angeles High School, then for two years to the University of Southern California, after which he went up to Berkeley

Jan 1, 1940

By Charles McElroy White

IT is indeed an honor to have been asked to participate in the program which celebrates the seventy-fifth birthday of the American Institute of Mining and Metallurgical Engineers. This great organization has occupied an important place in the professional and industrial life of this country-of the world. Its members have explored the far reaches of our globe and have played a great part in the discovery, extraction and utilization of the mineral resources upon which our civilization so largely depends. These engineers, together with the restless prospectors, on the one hand, and the scientists, on the other, have literally been the advance scouts of our modern way of life. As such, we owe them a deep and lasting debt of gratitude. May I, therefore, wish many happy returns to the American Institute of Mining and Metallurgical Engineers and express the hope that it may long continue to be of great service, as it has been in the past. The subject assigned to me-Iron Ore and the Steel Industry-is, indeed, important, as one considers the future of our world. I shall give as few figures as possible. Pertinent statistical data are included in the tables in this chapter, which, I think, will prove interesting. Many studies of iron-ore reserves have been -published and are available; hence I shall limit myself mainly to an interpretation of these figures. The statistics data are from standard sources, including the Lake Superior Iron Ore Association, the American Iron and Steel Institute, the United States Bureau of Mines, the United States Geological Survey, the United

Jan 1, 1947

President MRS. REED W. HYDE 84 Mountain Ave. Summit, N. J. First Vice-President MRS, WILLIAM A. SCHEUCH Trent St. Great Kills, S. I., N. Y. Second Vice-President MRS. THORNS E. LLOYD Box B Netcong, N. J. Third Vice-President MRS. H.. T. HAMILTON 24 Ridge Rd. Summit, N. J.' Fourth. Vice-President MRS. R. A. PALLANCH 1342 Laird Ave. Salt Lake City, Utah

Jan 1, 1939

By McDowell Graves, Joseph Jensen, W. D. Goold, M. L. Gwin

During the present year the Santa Fe Springs field has proved to be the most important oil field under development in the United States. Its production will exceed that of any other field. Without it, production within the United States would have been almost in even balance with consumption. The field has forced to the fore and compelled, more than any other single factor, serious consideration of the need of conserving the gas resources of the State of California. It has also contributed much to the development of new drilling equipment and important features in petroleum engineering, and has required the development of a new cement for use in deep wells because of high temperatures. It is the only oil field in the country where wells 8000 ft. deep have become so common that they are no longer given special attention. The field covers a little less than 1400 acres of land. In it 196 producing deep-zone wells have already been drilled since August, 1928, and 224 wells are still drilling. More wells may be drilled. This indicates that probably more than 450 wells will be drilled in the present campaign. In hardly a year's time it has caused the outlay of nearly $50,000,000 for drilling, and within the year 1929 it will have returned practically an equal amount of revenue. In contrast to conditions during 1923, when this field was once before an important and disturbing factor, the California oil industry has not been forced to refinance to meet the situation presented by such a large production of oil. There has been practically no unit selling and no stock selling, nor any unnecessary development far beyond the limits of the field. Production is now about 275,000 bbl. per day and gives every promisc of remaining at this figure or increasing to nearly 300,000 bbl. Six months from now the field should still be capable of producing more than 200,000 bbl. per day. Obviously, the need for conserving gas that would be blown to the air, incident to the production of so large a volume of oil, represents a problem in conservation deserving of the most serious attention of the oil industry and of the State of California.

Jan 1, 1930

One of the newest and most modern surface mining operations in the East is gathering steam at Mapco Inc.'s Martiki mine in anticipation of yielding 2.7 million tons (3 million st) of coal annually.

Jan 10, 1977

By T. A. Rickard

The use of the verb in this mood is not as common as formerly: at the time, for' example, when the Bible was translated and the plays of Shakespeare were written. Nevertheless it is an essential part of literary English. In editing the `Mining and Scientific Press' I do not insist upon the use of the subjunctive in articles that are contributed from the outside, but it is deemed proper in all our editorial writing. To speak plainly, the subjunctive is I a mark of scholarship; it is ignored by those that are not particular in such matters, and unfortunately it is a source of perplexity to many that are entirely unfamiliar with the use of it. Therefore, as an editor, I think it well to allow the indicative mood to be used by contributors in sentences in which, to be strictly correct, the verbs .should be in the subjunctive mood. The fact that most subjunctives are indistinguishable in form from indicatives is another cause of trouble to the uninitiated.* For example, the verbs in such phrases as "Suffice it to say ", "So help me God ", and "God save the King" Fare in the subjunctive. One reason why the subjunctive is becoming uncommon is the growing habit of expressing the subjunctive meaning by aid of auxiliary verbs that are coupled with the infinitive; thus: "It will suffice' to say" and "May God save the King". The subjunctive is common in subordinate clauses, and that is how it obtained its name, `subjunctive', meaning * The student is referred to `A New English Grammar', by E. A. Sonnenschein, published by the Clarendon Press, Oxford. This textbook (see pp. 60-71 in Part III) discusses the subject luminously.

Jan 1, 1931

Plans for the Petroleum Division during the ensuing year are in process of development, in contemplation of the usual fall meetings in the Mid-Continent and California areas, as well as the annual meeting to be held in New York in February, 1936. Houston, Texas has been suggested as the place for the Mid-Continent fall meeting, the exact date to be announced shortly. During the past year, the Division's technical programs, as in former years, have emphasized the wide fields of engineering endeavor in the petroleum industry yet remaining for more thorough investigation and discussion. An effort has been made to bring an international interest into the proceedings of the Division by inviting the participation of prominent foreign technologists. This viewpoint should promote a continuation in 1935 of past high standards, afford a more thorough understanding of problems throughout the membership, and maintain the Institute's position among the various technical organizations functioning particularly in the oil-producing and refining areas. In the list of subjects proposed for the fall meetings is the problem of estimating petroleum reserves. Various factors requiring study will include productive sand volume, porosity, average permeability, saturation, and types of recovery. Research papers are proposed dealing with energy consumption per unit of oil recovered, reservoir pressure or energy loss relationship to the usual volumetric method of estimation, and the study of oil and gas segregation within the reservoir. Other subjects tentatively suggested include new casing practice in relationship to wells producing from several productive zones, progress in lifting methods, repressuring, advanced methods in drilling economies, and the economics of conservation. Although the threat of overproduction yet remains, to a lesser degree than during the past few years, intensive activity is now being directed towards the discovery of new petroleum reserves. This situation undoubtedly will influence, in some considerable degree, the channels through which technical activities will be directed. A continuation of the commendable work on production statistics for the various oil-producing states and foreign countries has been effected. The usual papers dealing with the general economics of the industry will be reserved for the annual New York Meeting. The Stabilization Committee maintains its membership of nationwide authorities, and interest is manifest in new developments to meet the changing requirements of the industry.

Jan 1, 1935

By J. L. Smith, A. L. Albee

This article presents a series of guidelines by which the geologist can evaluate the likelihood of surface faulting and its probable extent at any given site in Southern California and Nevada. The information is intended primarily for geologists concerned with establishing design criteria for proposed nuclear plants. The geologic problems involved in the location of a nuclear power plant are fundamentally no different from those for other types of installations. They fall into four main categories: foundation stability, landslides and slope stability, shaking due to earthquakes, and surface faulting. For problems in the first three categories the foundation engineer, the geologist, and the seismologist can provide criteria for plant location and design, and these problems can generally be economically handled by appropriate design measures for a project of the magnitude of a nuclear plant. However, problems in the last category — surface faulting — are more difficult to handle and require a unique evaluation. Accordingly, this paper will deal primarily with the problem of establishing design criteria for surface faulting, particularly as it affects nuclear facilities. A nuclear reactor is a power source that for greater safety is contained in a heavy, air-tight structure, just as gas, oil, water, and other power sources must be contained. Surface faulting is significant in that it may reduce the integrity of the containment by affecting critical exterior piping or by breaching of the containment. A similar significance exists relative to dams or tanks for the storage of water, gas, or oil, except that in these latter examples the breaching of the container automatically releases the fluids to do their damage. This is not necessarily the case with the rupture of a reactor containment structure because the function of the containment is totally protective, i.e., it is necessary only in the event that radioactive products are released from the reactor, and there are many other safeguards to pre- vent this release even if the containment is ruptured. At the present time, nuclear power plants must be located near large sources of water for cooling the steam generated. The construction of an industrial facility of any kind on the coast line is esthetically distasteful to most people since, unfortunately, there is not enough coast to fulfill all the needs and all the desires of all the people. In most cases where industrial facilities encroach on the lives of citizens, there is no mechanism other than zoning laws by which a person can effectively protest. But in the case of a nuclear facility, the public hearing required by the Atomic Energy Commission provides a forum for dissent, as in recent case histories, and the question of safety provides objectors with a weapon for fighting the construction of the plant. The nature of a public hearing for a nuclear plant is such that the prospective owner and operator must prove that there is no undue hazard, whereas the objectors need only demonstrate that there is a reasonable doubt. It is in this situation that geology becomes the Achilles Heel of nuclear power plant location. For his investigation, the geologist has natural exposures of rock at the ground surface and a limited number of trenches and drill holes to give him a fairly complete picture of the distribution of the various rock types. From the surficial data, he must infer three more dimensions — depth below the surface, past time, and future time. Unlike many problems faced by engineers, the geologist has only this one set of data from which to reach a conclusion — he is unable to reproduce the natural sequence of events in order to obtain another set of data for comparison. Hence, by the very deductive nature of a geologic conclusion, it is difficult to prove a geologic conclusion beyond a reasonable doubt even to other geologists — and perhaps one should say especially to other geologists because the experience and background of a geologist will strongly influence his conclusion, and no two geologists have exactly the same experience and training. The engineer and the public official would like the geologist to conclude that faulting cannot occur at a given site or to assign a numerical value to the probability of its occurrence — but no responsible geologist can do either of these things. Since government officials and others must make decisions that affect the public safety, it would seem that the geologic profession must attempt to establish criteria and

Jan 1, 1968

By Thomas, J. Elmer

WHEN the price of crude oil was advanced on July 26, 1928, with some 4,000,000 bbl. daily of potential production shut in under proration regulations, and with as much more new production shortly available from semi-proved undrilled reserves, students of the oil industry were made to realize that a new order of things now prevailed in petroleum economics. A new interpretation of the law of supply and demand had taken the place of the archaic method of influencing current production by changing crude price levels. Proration had caused the change. The long period of over-production just experienced, the prospects of a potential over-supply far into the future, had set up certain forces which brought about some fundamental changes. Their cause, effect and future influence can best be developed by a detailed study of the history of the period since war-time regulation

Jan 1, 1928

By A. M. Gaudin

Activation of sphalerite with silver ions results from the exchange of two Ag ions for one Zn ion in the sphalerite lattice. The exchange is proportional to the logarithm of time and proceeds until either of the reactants is consumed. Sodium cyanide prevents the activation of sphalerite by controlling the ratio [Zn++]/[Ag+]' in solution. If sphalerite has already been activated with excess silver, cyanide ions can deactivate sphalerite provided oxygen is present. SOLUBLE: silver salts are effective activators for flotation of sphalerite with potassium ethyl xan-thate as collector.* Since sphalerite takes up large quantities of silver ions rapidly,2-4 investigation of this system appeared fruitful for studying the mechanism of sphalerite activation and deactivation. Experimental data presented here comprise studies of the mechanism and rates of activation and deactivation of sphalerite with silver and cyanide ions. A 20-lb sample of sphalerite from Ottawa County, Oklahoma, was handpicked, crushed, screened, hy-drosized to produce a 65/100-mesh fraction, and purified by electrostatic separation. The sphalerite was then leached with benzene and absolute ethyl alcohol to remove possible organic contaminants and with 0.1 M NaCN to remove any copper that might have been picked up during screening. The benzene had been specially purified by grinding with fine sphalerite for 12 hr to remove trace impurities that might have had a specific affinity for sphalerite. Ii'inally, the mineral was washed, dried in flowing nitrogen, and stored in large ground-glass stoppered weighing bottles under a small nitrogen pressure. The specific surface of two samples from the 65/100-mesh sphalerite stock, measured by krypton gas adsorption," was 420 cm2 per g. Compared with spheres of the same size and specific gravity, the prepared mineral had five times as much surface. Results of a wet chemical analysis and of a spectro-graphic study are given in Table I. Manganese, nickel, tin, indium, thallium, cobalt, and magnesium were not detected spectrographically. All solutions were preparid by -adding reagent-grade chemicals to conductivitv water. which had been previously saturated with the desired gases. Nitrogen and oxygen were purified, but no attempt was made to purify the laboratory air. Radioanalysis was carried out with prepurified Ag110 tracer obtained from the Oak Ridge National Laboratory. The complete decay scheme for Ae is complex. Its primary emissions are 0.09 and 0.55 mev ß rays and 1.48 mev y raysB and its half-life is believed to be 270 days. In preparation of solutions of AgNO3, the amount of Ag110 added was negligible compared to that of the inert silver. Abstraction of silver from solution by sphalerite was measured after agitation of 1.5 g sphalerite with 20 ml of solution in 50-ml pyrex flasks. All sample preparations were carried out in a dry box so that the proper atmosphere could be maintained. After the mineral had been agitated in the silver nitrate solution, an aliquot of the solution and a sample of the wet mineral were transferred to separate counting vials and weighed. The solid sample was dried and re-weighed and the activity in both vials measured by means of a scintillation counter. With scintillation counting it is possible to count y radiation from the solid and liquid, a distinct advantage over the older ß-ray counting techdiques.4 All measurements of silver activity were made using a sodium-iodide well-type scintillation counter. The amount of zinc in solution was measured colorimet-rically by the monocolor method of Sandell.7 Activation Studies Exchange Between Zinc Ions and Silver Ions During Activation: The increase of Zn++ in solution during activation with Ag+ is shown in Table 11. These data indicate a replacement of one Zn++ by two Ag+. Analysis of a separate two-month agitation test indicated that the replacement of Zn++ by Ag+ was, as expected, in the molar ratio of 2.0.

Jan 1, 1958

IN comparing the living conditions of the worker or peasant of the past with those existing today, his-torians might point out many strange contrasts. From the Doomsday Book we learn that at the time of Wil-liam the Conqueror the 1,375,000 inhabitants of Eng-land and Wales owned less than 1000 horses and 5000 oxen. Even as recently as 1871 when England and Wales had a population of 31,845.000, the total number of horses in the country was estimated at 1,110,000. Compare the necessary drudgery of labor in those days with conditions in Canada today where a population of less than ten million people own 3,500,000 horses. Re-member that there is also a turbine installation in` this country of more than four million horse-power, besides steam boilers and locomotive and automobile engines which reduce the traction and hand labor of the farm and factory. Frequently, poetic license has glossed over the poverty and hardship of the common people in the "good old days," and the imagination has created an idyllic world, far from being justified by the condi-tions which actually prevailed. Simon Patten's de-scription of the Middle Ages as "A Thousand Years Without an Ice Box" came nearer portraying the true situation. No one is likely to forget that the discovery of America was an incident in Europe's attempt to find a short route to the Indies, but the fact is usually for-gotten that the summer diet in Europe in 1400-an ice-less age-was such that spices were more precious than gold. Though the glamor of the Indies may never sur-round the modern refrigerator, certainly the modern housewife is likely 'to feel that the applied art called "cookery? may attain to higher levels with the assist-ance-6f such an adjunct. Those who have spoken slightingly of the uniformity of the modern apartment and have eulogized some of the exceptional hand-made furniture which has been bequeathed by former generations, have failed to com-pare modern house furnishings with those in the typical peasant's hovel. Machine-made furniture, though with-out particularly good lines, contrasts quite favorably with the pile of rags in the corner, and the poorest gas or oil stove is better than an open fire on a dirt floor. The scientist's application of the theories of physics, chemistry, biology and mathematics .to practical prob-lems has brought about a series of kaleidoscopic trans-formations in agriculture, industry and commerce. Large scale production, improved means of communica-tion and the prevailing higher standard of living are terms which imply a very human meaning when in-terpreted as actual changes in individual living. Though the student and the teacher may deprecate the influence of commercialism upon science, humanity as a whole has received great benefits from the close relationship which has developed between science and industry, and industry in turn has done much for science through the building and endowment of laboratories and by supply-ing funds to maintain research workers.

Jan 11, 1927

* A demonstration pipeline for transporting coal will be constructed by Pittsburgh Consolidation Coal Co, at the Georgetown strip-mining operation near Cadiz, Ohio, The 12-in., 17,000-ft line, special crushing and preparation equipment, and pumps especially designed for the operation will cost about $550,000. A slurry of fine coal and water will be fed into the line and moved through it under pressure. * Sulphur resources in the U.S. are being rapidly exhausted with no new major deposits being found, This common mineral may become one of the most strategic items during the next five years. Recovery of sulphur from pyrites is being considered in case of an emergency. Already the British have adopted stringent measures to conserve sulphur supplies.

Jan 3, 1951

By B. Haimson, C. Fairhurst

A criterion is Proposed for the initiation of vertical hydraulic fracturing taking into consideration the three stress fields around the wellbore. These fields arise from (1) nonhydrostatic regional stresses in earth, (2) the difference between the fluid pressure in the wellbore and the formation fluid pressure and (3) the radial fluid flow through porous rock from the wellbore into the formation due to this pressure difference. The wellbore fluid pressure required to initiate a fracture (assuming elastic rock and a smooth wellbore wall) is a function of the porous elastic constants of the rock, the two unequal horizontal principal regional stresses, the tensile strength of the rock and the formation fluid pressure. A constant injection rate will extend the fracture to a point where equilibrium is reached and then, to keep the fracture open, the pressure required is a function of the porous elastic constants of the rock, the component of the regional stress normal to the plane of the fracture, the formation fluid pressure and the dimensions of the crack. The same expression may also be used to estimate the vertical fracture width, provided all other variables are known. The derived equations for the initiation and extension pressures in vertical fracturing may be employed to solve for the two horizontal, regional, principal stresses in the rock. INTRODUCTION Well stimulation by hydraulic fracturing is a common practice today in the petroleum industry. However, this stimulation process is not a guaranteed success; hence, the deep interest shown by the petroleum companies in better understanding the mechanism that brings about rock fracturing, fracture extension and productivity increase. Geologists and mining people became interested in hydraulic fracturing from a different point of view: the method may possibly be employed to determine the magnitude and direction of the principal stresses of great depth. Numerous articles in past years have dealt with the theory of hydraulic fracturing, but they all seem to underestimate the effect of stresses around the wellbore due to penetration of some of the injected fluid into the porous formation.1-4 Excellent papers on stresses in porous materials due to fluid flow have been published5,6 but no real attempt has been made to show the effect of these stresses in the form of a more complete criterion for vertical hydraulic fracturing initiation and extension. This paper is such an attempt. ASSUMPTIONS It is assumed that rock in the oil-bearing formation is elastic, porous, isotropic and homogeneous. The formation is under a nonhydrostatic state of regional stress with one of the principal regional stresses acting parallel to the vertical axis of the wellbore. This assumption is justified in areas where rock formations do not dip at steep angles and where the surface of the earth is relatively flat. This vertical principal regional stress equals the pressure of the overlying rock, i.e., S33 = —pD, where S33 is the total vertical principal stress (positive for tension), p is average density of the overlying material and D is the depth of the point where S33 is calculated. The wellbore wall in the formation is considered to be smooth and circular in cross-section. The fluid flow through the porous elastic rock obeys Darcy's law. The whole medium is looked upon as an infinitely long cylinder with its axis along the axis of the wellbore. The radius of the cylinder is also very large. Over the range of depth at which the oil-bearing formation occurs, it will be assumed that any horizontal cross-section of the cylinder is subjected to the same stress distribution, and likewise that it will deform in the same manner. STATE OF STRESS PRIOR TO DRILLING OF WELLBORE At a depth D from the earth surface within the oil-bearing strata, it is assumed that the following are 1References given at end of paper.

By N. S. Stoloff, R. G. Davis

It is concluded from an X-ray stztdy that the formation of the hcp Mg3Cd superlattice is a nuclea-tion and growth reaction. A two-phase, ordered-plus-disordered, region is observed between 153" nnd 141"C. A maximum in the flow stress is observed both at temperature and in quenched specimens within the two-phase region. The peak arises fro112 the extra energy required to create antiphase boundary upon cutting the ordered regions. Hardening during isothermal annealing in Mg3Cd has been shown to be similar to the domain hardening in Cu3Au-type alloys in that up to the maximum the structure is ordered domains growing into a short range ordered matrix. The hardening is due to a combination of short range order strengthening and the strengthening produced when antiphase boundary has to be created. In a recent study1 of the effect of long-range order upon the mechanical properties and deformation modes of hcp Mg3Cd a comparison was made be- tween quenched (disordered) and slow-cooled (fully ordered) specimens. The most striking observations were that the disordered alloy yields at a much higher stress than the ordered alloy, and that there is a change in slip mode from primarily (_0001) ba_sal slip in the disordered state to (0001), {1010}, {1122}, and {l011} slip in the ordered state. The main purpose of the present work is to extend these observations to determine whether MgsCd exhibits a peak in flow stress at an intermediate degree of order, or at a critical domain size, as do other orderedstems. However, disagreement exists about the Mg3Cd order transformation with respect to: 1) the location of the critical temperature for order, 165°C or 153"~,' and 2) how the degree of order varies with temperature. Welber et a1.5 concluded from specific heat measurements that the formation of Mg3Cd is a second-order reaction with the degree of order a continuous function of temperature, while Moore and Raynor concluded that it is neither a first-order reaction, with the degree of order a discontinuous function of temperature, nor a second-order reaction. Consequently it was considered necessary to undertake an X-ray investigation into the change in degree of order and structure in the

Jan 1, 1964

By Ta M. Li

Expanded mine-mill capacity and greater operating flexibility are part of the dramatic changes taking place in the Tennessee mining operations of Asarco, Inc. Climaxed by the recent start-up of the $6.3 million Young mill in September 1975, Asarco has pushed Tennessee back into number one position as the leading zinc mining state. Furthermore, start-up of the Young mill is expected to insure a much-needed and continuing domestic zinc supply, at a time when US mines can only supply one-half of 1975 domestic consumption.

Jan 5, 1976

By K. E. Nelson

The effect of thorium and zinc variations on the strength and 100-hr creep characteristics of Mg-Th-Zn-Zr alloys was investigated. Optimum resistance to creep at 650° and 700°F are attainable within a certain range of thorium and zinc contents. This range does not conform to that which develops maximum tensile properties. RAPID advances have been made during the last few years in the development of magnesium alloys for elevated temperature applications demanding high resistance to creep. The beneficial effect of rare-earth metals on the creep resistance of magnesium alloys has been emphasized by a number of publications1-13 and such alloys are now in commercial production. The use of thorium as an alloying ingredient in magnesium was mentioned by McDonald and also in two Alien Property Custodian patent applications.10,17 The initial observation of Sauerwald that thorium contributes still higher creep resistance to magnesium than is attainable with rare-earth metals has recently been substantiated.'" " In fact, it has been demonstrated that the useful temperature range of magnesium alloys is appreciably extended by the use of thorium. In all cases, it was observed that zirconium must be included in the alloys in order to render them fine grained and more readily castable. Several recent publications:2-27 indicate that a still further improvement in creep resistance and a further extension of the useful temperature range can be realized by the addition of zinc to alloys. The primary purpose of this paper is to present the results of a comprehensive study of the effect of zinc on the strength and creep characteristics of Mg-Th-Zr alloys. Compositions covering the range of thorium content from M to 6 pct and zinc content from 0 to 5 pct have been investigated. The creep characteristics at 650" and 700°F reported in this paper are based on results of tests of 100-hr duration. It is appreciated that creep tests of 100-hr duration might not yield adequate data for design purposes for parts with much longer expected life. However, for the purposes of the present discussion, it is felt that the combination of stresses and temperatures used in the 100-hr creep tests have yielded a clear representation of the compositional variation of creep resistance at the temperatures investigated. Creep tests of 1000-hr duration are now in progress on a few of the most promising alloys. Preparation and Testing of Alloys The alloys studied in this intensive investigation were prepared in 25 lb capacity mild steel crucibles. The thorium, zinc, and zirconium were alloyed and poured as described in earlier publications The thorium was introduced into the melt in the form of a Mg-Th hardener," the zinc added in the metallic form, and the zirconium alloyed in the form of the commercial hardener containing magnesium and 30 to 50 pct Zr.10, 26 Fluxing practices for melting and refining were the same as for magnesium-rare-earth metal-zirconium alloys. The melts were sampled for analytical determinations and poured into separately cast 1/2 in. diameter standard tensile bars. The test bars were given a precipitation treatment of 16 hr at 600°F in laboratory furnaces. It has been shown by other tests that a high temperature solution treatment followed by an aging treatment is unnecessary for the development of optimum properties in Mg-Th-Zn-Zr alloys. The selection of 600°F as the aging temperature was based on an attempt to achieve metallurgical stability without coalescence of the undissolved phases and the attendant loss in strength. The thorium, zinc, and zirconium contents of each melt were determined chemically. The zirconium contents are reported in two parts, "soluble" and "insoluble," referring, respectively, to the portions present in the alloy which are soluble and insoluble in dilute HCl acid. Distinction is being made between these two components of the zirconium content in the alloys because it has been found that only that portion of the zirconium content which is soluble in dilute inorganic acids affects the structure and properties of the alloys. The usual impurities consisting of copper, iron, manganese, and nickel were determined spectroscopically. The analysis for each melt is listed in Table I. A description of the methods of tension and creep testing has been detailed in earlier papers. The tests were performed with the cast skin re-

Jan 1, 1954