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By D. Brion, J. J. Prédali, J. Hayer

The need to grind volcanic-sedimentary ores very finely (d80 < 20 µm) so as to liberate Pb, Zn, and Cu sulfides from their pyritic gangue causes difficulties in selective flotation. The pyrite, which accounts for 70-80% of the mineral content, is insufficiently depressed by the usual pH and NaCN techniques. To determine better depressing methods, the surface evolution of pyrite during flotation was followed by ESCA spectroscopy to compare the stability range in the Eh-pH diagram. Surface iron hydroxide was formed, which is the main pyrite-depressing factor. NaCN appears to play a more restrictive part, since no ferricyanides were detected, except for very small amounts at pH 7.

Jan 1, 1980

By O. A. E. Jackson

Pebble milling has been practiced in the reduction works of South Africa gold mines for well over 50 years. Originally flint pebbles were imported from Denmark to grind stamp-mill amalgamation- process tailing, which contained a good deal of extractable gold, but local operators soon found that large pieces of ore could be used for the same purpose. The ore is a hard, tough conglomerate in which quartz pebbles are cemented together by a matrix of redeposited silica interspersed with pyrite crystals. The gold, rarely visible, occurs as fine particles mostly segregated at the interface of the pebble and matrix, although a small fraction occurs within the pyrite crystals. There is seldom any gold in the pebbles themselves.

Jan 11, 1959

By I. Iwasaki, R. Titi-Manyaka

Thermogravimetric analyses were used to formulate the chlorination and chloridization behaviors of such metals as iron, manganese, copper, tin, nickel, and zinc and their oxides; of lime and magnesia; and of such minerals as calcite, siderite, rhodochrosite, rhodonite, and apatite- all commonly encountered in ironmaking raw materials. Complexities of the reaction steps involved were indicated by plotting thermogravimetric analysis curves and the possible mechanisms were discussed based on the theoretical weight changes and thermodynamic considerations. The relative effectiveness of chlorine and hydrogen chloride as chloridizing agents was considered in the light of the experimental results.

Jan 1, 1973

By William Kent

I DESIRE to place on record in our Transactions a recent innovation in blast-furnace practice, namely, the introduction at the Lucy Furnaces, in Pittsburgh, of four water-tube steam-boilers, of the Babcock and Wilcox pattern, aggregating 832 horse-power, builder&apos;s rating, or 9,568 square feet of heating-surface, utilizing the waste gases of the furnaces as fuel. The boilers are set in two batteries, each of 416 horse-power, and each battery occupying a ground-space of 22 feet 7 inches by 20 feet 4 inches. The accompanying dram-

Jan 1, 1885

By V. P. Yashin

Modern trends in the use of autogenous grinding of minerals have been investigated by Mekhanobr Institute. The conclusions drawn are based on experimental and theoretical investigations by the author and his coworkers. A method is suggested for determining the efficiency of converting from ball milling to autogenous grinding. A qualitative interpretation is given for comminution theory using both methods. This interpretation is used as a basis for considering both the principal trends in increasing use of primary autogenous grinding and the results of such in industrial application. Data are given from testing some ores from USSR deposits for the effect of the ore Preparation step on subsequent metallurgical treatment. Autogenous grinding is shown to be widely used in various USSR industries.

Jan 1, 1980

By E. J. Dulis, A. Kasak, R. C. Westgren

The potential of uirought tungsten- and tantaluw-rich alloys of the W-Ta-Mo-Cb system was investigated for high-strength structural applications above 2500° F. Appreciable strengthening of tung-sten and tantalum—essentially attributable to solid-solzction effects—was obtained with binary, ternary, and quaternary alloys. Tensile strengths as high as 67,000 psi were achieved at 3000 OF. ThE quest for wrought structural materials which possess good strength properties at temperatures above 2000°F has led to a considerable research effort during the past decade. In addition to exploring the potential of various high-melting-point refractory metals (such as molybdenum, columbium, tantalum, and tungsten) for very high-temperature structural applications, alloy-development programs have been undertaken to achieve greater strengths than could be achieved with unalloyed refractory metals. The methods of strengthening refractory metal alloys have included both solid-solution and dispersion strengthening. General relationships among the relevant properties (melting point, recrystallization temperature, and high-temperature strength) of refractory metals indicate that the highest strengths at temperatures of 2500°F or higher would be obtained with tungsten-or tantalum-base alloys. Therefore, the present investigation was undertaken to determine the high-temperature strength potential of solid-solution strengthened alloys based on the binary system W-Ta; to effect further strengthening, minor additions of molybdenum and columbium (at the 6 and 12 pct levels) were made. The portion of the W-Ta-Mo-Cb quaternary alloy system of interest is shown schematically in Fig. 1. The component metals—W, Ta, Mo, and Cb—have a bcc structure at all temperatures, and their binary systems are mutually completely soluble.&apos; Complete solid solubility in the W-Ta-Mo and W-Ta-Cb alloy systems has been demonstrated,&apos; and, therefore, it was expected that the quarternary alloys of the system would also exhibit complete solid solubility at all temperatures. In the virtual absence of contamination by interstitial elements, all the alloys would be truly solid-solution strengthened. Twenty specific compositions of this investigation included binary, ternary, and quaternary alloys of the W-Ta-Mo-Cb system as well as unalloyed tungsten and tantalum. The compositions are shown in Table I. EXPERIMENTAL PROCEDURE Consumable-electrode vacuum-arc melting with ac power was used to produce small laboratory-sized, cylindrically shaped ingots (1-1/4 in. in diameter and 2 to 3-1/2 in. long) of the twenty compositions. A furnace was specially constructed to melt as many as four electrode rods simultaneously into molds lined with tungsten or tantalum sheet. High-purity rods of tungsten, tantalum, molybdenum, and columbium were used for consumable electrodes; the diameter of each rod was determined by the desired weight percentage of the component metal in a given alloy. The details of the construction and operation of the melting furnace will be discussed in another p~blication.

Jan 1, 1964

By A. M. Gaudin

TEN years ago Taggart, Taylor and Ince1 described a workable, convenient apparatus for the measurement of contact angles be-tween cleaved, ground or polished particles and captive bubbles. Wark and Cox2 and Wark and Sutherland3 have done an im-mense amount of experimental work with this apparatus. Their work has had as principal object the determination of "con-tact curves." Contact curves are Cartesian charts in which pH (or some other variable) is plot-ted against quantity of modifying agent. The rectangular area is broken into two or more curvilinear areas separated by the contact curve. The curve indicates that a sharp demarcation exists between condi-tions that bring about sticking of particles to bubbles and conditions that do not pro-duce sticking, The type curve appears in the TRANSACTIONS as Fig. 1, page 248, volume 112. Wark and Cox offer data to show that the contact angle has a value determined by and characteristic of the agent used. Wark and Cox also make the statement that they believe this value is independent of concen-tration (ref. 2a, p. 209), They say: It is suspected that, given sufficient time and provided that there are no disturbing factors. the full ethyl xanthate angle (corresponding to a complete xanthate film) would be obtained in every case where contact occurs.

Jan 1, 1940

By G. R. Leverant

RECENT investigations1,2 of the low-cycle fatigue behavior of pure copper under strain cycling conditions have shown that a unique saturation stress level is eventually attained for each value of applied plastic strain amplitude. The dislocation substructure of copper at the saturation stress level is in the form of cells whose diameter decreases with increasing saturation stress level, i.e., plastic strain amplitude. In addition, both the saturation stress level and the cellular substructure are completely reversible. That is, the saturation stress level and accompanying cell size are determined solely by the present conditions of testing and are, therefore, independent of any previous cyclic history. The mechanical and substructural reversibility observed in pure copper, which has a relatively high stacking fault energy, is not observedz for Cu-7.5A1 which has a much lower stacking fault energy. This implies that easy cross slip (wavy slip) is a prerequisite for reversible fatigue behavior. A dispersion of fine, nondeformable particles of a second phase in a metal matrix tends to stabilize substruc- tures introduced by forming operations during subsequent elevated-temperature heat treatments.3 This raises the question as to whether a finely dispersed second phase can induce an element of irre-versibility into the cyclic deformation behavior of a wavy slip material at room temperature, due to partial stabilization of the initially introduced substructure. Since nickel has a higher stacking fault energy than copper,6 pure nickel should be characterized by cyclic reversibility. Therefore, TD-nickel* (Ni-2ThO.r) was

Jan 1, 1968

S. LE FEVRE, Forest Glen, N. Y. (communication to the Secretary*).¬F. L. Nason thinks I could not have studied Mr. Witherbee&apos;s paper and doubts the arithmetic used, but in his discussion arrives at practically the same conclusion. He says 10 ft. thickness of ore over a square mile should give 27,878,400 tons, allowing 10 cu. ft. per ton of ore. This is correct, but if he reads carefully he will see that this depth of ore was figured as covering one-tenth of the surface, which reduces the figures to those used by Mr. Nason. I did not say, however, that there were 2,300,000,000 tons of ore in New Jersey, but that applying the same method of computation as used by Mr. Nason, to the area of the iron ore-bearing gneisses in New Jersey, we would get a total of 2,300,000,000. I did say, "In this area are located 366 magnetite mines that have been worked more or less. These lenses may easily be capable of producing (on an average) 1,000,000 tons each, and there are probably double the number listed not opened up." Thus my estimate for New Jersey, as far as any was made, would be: Probable ore 366,000,000 Possible ore in addition 732,000,000 1,098,000,000 Mr. Nason&apos;s final conclusion of his personal estimate was one-half of what he erroneously read to be the estimate given in the paper, or half of 2,300,000,000, which equals 1,150,000,000. So the two estimates seem to differ less than 5 per cent., and we have the two sister States of New York and New Jersey on an equal footing of productive possibilities in magnetic ore.

Jan 6, 1917

The General Committee met in the Treasury Building at Washington on Oct. 6 and 7. At the first meeting, Cornelius P. Kelley was appointed chairman, and Paul Armitage, secretary. Sub-committees were ap-pointed on Invested Capital, Mine Valuation, and Depletion and De-preciation. On Oct. 7, the reports of these committees were submitted to the General Committee and were referred to the Executive Committee. A motion was carried that the Executive Committee he constituted a permanent committee to continue the work of the Committee, with full power to acid to and increase its membership, that. as thus increased, it should constitute a permanent organization to act- and cooperate with the Treasury Department in matters of mining taxation under the Federal Income and Excess Profits Tax Laws. Thereafter the Executive Com-mittee met and formed a permanent committee as follows: Cornelius F. Kelley, chairman, 42 Broadway, New York City. J. L. Darnell, office of the Commissioner of Internal Revenue, Wash-ington, D. C. J. Parke Channing, 61 Broadway, New York City. Walter Douglas, 99 John St., New York City. R. V. Norris, 542 Second National Bank Bldg., Wilkes-Barre, Pa. J. E. Spurr, Engineering and Mining Journal, 10th Ave., and 36th St., New York City. W. G. Swart, 808 Selwood Bldg., Duluth, Minn. J. P. Finley, 45 Cedar St., New York City. W. A. Williams, Bartlesville, Okla. F. S. Peabody, Peabody Coal Co., McCormick Bldg., Chicago, Ill. Matthew C. Fleming, 71 Broadway, New York City. H. B. Fernald, 54 Wall St., New York City. William G. Mather, Cleveland, Ohio. Walter Fitch, Eureka, Utah. Arthur Thacher, 900 Security Bldg., St. Louis, Mo. John P. Gray, Coeur d&apos;Alene, Idaho. Paul Armitage, secretary, 233 Broadway, New York City.

Jan 12, 1919

By Charles P. Williams

The successful production of zinc white or oxide on a commercial scale in this country dates from the issue of the patent of Samuel Wetherill, for the preparation of the material (November, 1855), and

By Frank L. Nason

RECENT explorations with a diamond-drill, originated and conducted by Mr. J. A. Van Mater, Superintendent of the Lehigh Zinc and Iron Company, have revealed some very important geological facts, which, it is believed, will be of special practical interest to mining engineers. During these explorations the writer was frequently called in consultation, and hence the facts here recorded are almost entirely the results of personal observation. The franklinite-deposit upon which the explorations were conducted has a long continuous outcrop. Figs. 1, 2 and 3 give a map and sections. Beginning at the extreme southern point,

Jan 1, 1895

By Ludwig Thomas, Klaus Detert

Klaus Detert and Ludwig Thomas (Westinghouse Electric Gorp.)— The results of C. Panseri and co-workers are quite important. The authors came to the same conclusions about the occurrence of zone formation in A1-Mg alloys as was outlined in previous papers.31&apos;32 Because of the sensitivity of their measurements, it was shown that zone formation could also occur at a much lower range of mag- nesium content than previously observed.31, 33 The idea of strong interaction between magnesium atoms and vacancies, as stressed by the authors, so that all of the quenched-in vacancies are kept in solution at lower temperatures but anneal out completely at 150°C, is in disagreement with our results which clearly indicate that zone formation and annealing out of vacancies occur simultane-

Jan 1, 1964

By M. Cepak, K. Donovan, W. G. Pariseau

This paper examines the difficulties of applying the finite element (FE) method of analysis to quantitative design of cable bolt systems. Cable bolt systems are in general use for ground control in VCR (Vertical Crater Retreat) topes throughout the world. However, despite their widespread use and importance, design of cable bolt systems is highly subjective. Two difficulties with the FE approach are examined: (i) the use of standard elements with a high aspect ratio (slender elements) to represent bolts, and (ii) the influence of cable bolts on hanging wall stability of a VCR study stope. Analysis results indicate that the use of slender elements for bolts is practical in large scale finite element analyses of VCR stopes. There are significant advantages in this approach to the engineering design of cable bolt systems in underground mining.

Jan 1, 1984

By A. A. Schweizer

A method to improve the quality of Magmont zinc concentrates to become acceptable feed to an electrolytic zinc refinery is described. The magnesia content of zinc concentrates produced was too high due to particle locking with sphalerite in coarse fractions. Regrinding the concentrates to a very fine particle size and then refloating the sphalerite was chosen to eliminate a sufficient amount of the magnesia to make the concentrates acceptable.

Jan 1, 1984

By Stephen L. Bolivar, Susan H. Balog, Thomas A. Weaver

A data-classification scheme was developed to detect potential uranium mineralization in the Montrose l º x 2º quadrangle, Colorado. The methodology developed is a rapid and efficient method of resource evaluation on a reconnaissance scale. The necessary techniques were developed and refined to digitize, integrate, and register various large geological, geochemical, and geophysical data sets for the Montrose quadrangle, Colorado, using a grid resolution of 1 km. All data sets for the Montrose quadrangle were registered to the Universal Trans- verse Mercator projection. The data sets include hydrogeochemical and stream sediment analyses for 23 elements, uranium-to-thorium ratios, airborne geo- physical survey data, the locations of 90 uranium occurrences, and a geologic map (scale 1:250 000). Geochemical samples were collected from 3965 locations in the 19 200 km2 quadrangle; aerial data were collected on flight lines flown with 3-5 km spacings. These data sets were smoothed by universal kriging and interpolated to a 179 x 119 rectangular grid (each grid block is 1 km2). A mylar transparency of the geologic map was prepared and digitized. All possible combinations of three, for all data sets, were examined for general geologic correlations by utilizing a color microfilm output. Subsets of data were further examined for selected test areas. A classification scheme for uranium mineralization, based on selected test areas in the Cochetopa uranium district, is presented. Areas favorable for uranium mineralization, based on this scheme, were identified and are discussed.

Jan 1, 1982

By Cyril Stanley Smith

BETA brass (consisting of approximately equal atomic proportions of copper and zinc) exists as a random solid solution at high temperatures, but at low temperatures [ ] an ordered structure is stable, with the copper and zinc atoms occupying alternate sites on the body-centered-cubic lattice. On cooling, ordering commences at a temperature of 450° to 470°C., depending on the composition. The degree of ordering progressively increases at lower temperatures until it becomes virtually complete at about 100°C. The electrical resistivity of the alloy illustrates the changes clearly (Fig. I). This type of reaction has been a favored subject for study by physicists. An [ ] excellent summary of the theory is to be found in a paper by F. C. Nix and W. Shockley.1 All published data on electrical conductivity, specific heat and other properties agree in indicating that the ordering reaction in beta brass takes place so rapidly that it cannot be prevented or even retarded by quenching. With most ordered alloys, cold-working induces disorder and

Jan 1, 1942

Prof. Mathesius analyzes the running of Howland&apos;s furnace No. 19, according to the method described by him in Stahl and Eisen, 1916, Nos. 30 and, 31, and in his work "Die physikalischen und chemischen Grundlagen den Eisenhüttenwesens" (Spamer, Leipzig). By assuming 500 Cal. lost from the hearth by radiation and cooling water per kilogram of pig iron made, a throat-gas temperature of 600° C., and taking the ratio of C02/CO as 0.64, he finds that his diagram would show 0.68 kg. of carbon oxidized per kilogram of pig iron, while Howland gives 0.66 kg. He expresses himself as well satisfied with this test of the accuracy of his theory. Making the further assumption that the heat losses from the shaft are 1,000 Cal. per kilogram of pig iron (twice as

Jan 5, 1917

By F. J. Cuddeback

For low-head pumping of small quantities of water, the water jet, or hydraulic educter, has been used to advantage by Eagle-Picher Mining and Smelting Co. in the Tri-State district. Water-jet pumps are used for draining sumps and pockets up to 15 ft. in depth. They have been used very successfully when only moderate amounts of water are encountered in taking up bottom. A small, easily handled unit is desirable in this work, especially while opening and deepening a new stope. Small air pumps are convenient but can be used only on the day shift, when air is available. Obviously, a jet pump of smaller capacity but operating 24 hr. prevents lost time at the start of each shift. No tests have been made on their power efficiency, but admittedly it is low. However, for certain kinds of work this is offset by their handiness, low initial cost, low upkeep, and reliability. They will handle slime and sand without ill effect, and will continue to pump indefinitely on air. This foolproof 24-hr. performance has led to their continued use at some places even after electric pumps with better power efficiency could have been installed. The success of jet pumps depends largely upon a cheap source of high-pressure water. Owing to mine depths in the Tri-State district, pump pressures range from 100 to 150 Ib. per sq. in. In many mines it is common practice to handle the normal inflow water with triplex pumps ranging in size from 3 to 8 in. The pumps operate 24 hr. per day, and, in order to handle emergency conditions, are speeded slightly faster than necessary to pump the normal inflow. The sump level is governed by controlling the by-pass water with a butterfly valve and float. This method is somewhat wasteful of power, but permits the pumps to operate with a minimum of attention. Such an installation is visited once a day to check lubrication. Hence, if some of this water, normally by-passed to the main sump, were used to operate a jet pump, the power cost could be considered low regardless of efficiency. Figs. I and 2 show two water jets that have done satisfactory work. The one in Fig. 2, made up entirely of pipe fittings, may be of interest partially because of its novelty, but does better work than its appearance indicates. The pipe fittings for this jet as shown cost $2.20. Some improvement in its design may be made by cutting out the 135 by 1¼-in. reducer to a smoother taper as shown by dotted lines. A 3-in. suction pipe is sometimes used in order that the discharge may be as straight as possible. A 2-in. discharge line has been used frequently, but 3-in. pipe is used where several hundred feet of discharge is required.

Jan 1, 1946

By P. E. Price, N. J. Grant

DURING the course of creep studies in iron-chromium-nickel alloys, it became necessary to establish the limits of the two-phase ferrite-austenite field at 1300°C. The shape of this region, predicted from the iron-chromium and chromium-nickel binary

Jan 1, 1960