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By James M. Stapleton

It has long been recognized by blastfurnace men that correct top distribution of materials is very important in efficient and economical furnace operation. Thousands of experiments on top design, filling, sizing, and other operations have been carried out to improving furnace performance by securing uniform distribution. Many of these experiments have worked out satisfactorily and have been passed along to the industry. Many of them have been discarded and forgotten. It has been the custom to judge the results of such experimentation by the results shown in improved or lowered furnace efficiency. While the effect on furnace practice will have to continue to be the final criterion of experimental changes, it has always been a desire of blast-furnace men to ascertain the reason for failure or success. Efficiency in the blast furnace approaching the maximum can be measured in several ways: (1) by actual operating results as revealed in the coke rate and tonnage figures, and (2), in the degree to which the top gas approaches the limiting ratio of CO/CO2 for the reduction of iron oxide by CO gas. This ratio is shown in the equilibrium curve in Fig. I for the system Fe-O-C and CO2-CO-C. The closer the top gases approach this limiting ratio (set at 1.08 by Martin1 because of the effect of limestone calcination) the more efficiently we may expect a furnace to operate. The fact that low CO/CO2 ratios parallel eficient operating performance caused us to investigate the cause of good or poor distribution and the effect of filling and other changes on furnace operation. Heretofore it has been possible to take a sample of furnace gas (usually from the dust catcher) and from it determine how closely the reducing gases were to the ideal or limiting value as set by the equilibrium diagram. However, to find just where in the top area the distribution was distorted and the top-gas CO/CO2 ratios were distant from equilibrium values has been a difficult and expensive investigational procedure. In an effort to overcome this difficulty, apparatus was designed to take gas samples and temperatures across the top radius of the furnace. It was hoped that with the aid of this apparatus traverse sampling of the ascending gases could be simplified, and the cost of sampling substantially lowered. Routine experimenting could then be maintained and results checked with furnace operation. It must be emphasized that a traverse sampling is necessary for a true picture, as single samples at any one point are unreliable. This statement can be verified by an examination of Tables 3 to 6, showing results obtained at our furnaces in a large number of tests. Apparatus The design of the equipment for taking the samples was governed by the need for providing a simple, routine test that could be performed fairly quickly without adversely affecting normal furnace operation.

Jan 1, 1943

By James M. Stapleton

It has long been recognized by blastfurnace men that correct top distribution of materials is very important in efficient and economical furnace operation. Thousands of experiments on top design, filling, sizing, and other operations have been carried out to improving furnace performance by securing uniform distribution. Many of these experiments have worked out satisfactorily and have been passed along to the industry. Many of them have been discarded and forgotten. It has been the custom to judge the results of such experimentation by the results shown in improved or lowered furnace efficiency. While the effect on furnace practice will have to continue to be the final criterion of experimental changes, it has always been a desire of blast-furnace men to ascertain the reason for failure or success. Efficiency in the blast furnace approaching the maximum can be measured in several ways: (1) by actual operating results as revealed in the coke rate and tonnage figures, and (2), in the degree to which the top gas approaches the limiting ratio of CO/CO2 for the reduction of iron oxide by CO gas. This ratio is shown in the equilibrium curve in Fig. I for the system Fe-O-C and CO2-CO-C. The closer the top gases approach this limiting ratio (set at 1.08 by Martin1 because of the effect of limestone calcination) the more efficiently we may expect a furnace to operate. The fact that low CO/CO2 ratios parallel eficient operating performance caused us to investigate the cause of good or poor distribution and the effect of filling and other changes on furnace operation. Heretofore it has been possible to take a sample of furnace gas (usually from the dust catcher) and from it determine how closely the reducing gases were to the ideal or limiting value as set by the equilibrium diagram. However, to find just where in the top area the distribution was distorted and the top-gas CO/CO2 ratios were distant from equilibrium values has been a difficult and expensive investigational procedure. In an effort to overcome this difficulty, apparatus was designed to take gas samples and temperatures across the top radius of the furnace. It was hoped that with the aid of this apparatus traverse sampling of the ascending gases could be simplified, and the cost of sampling substantially lowered. Routine experimenting could then be maintained and results checked with furnace operation. It must be emphasized that a traverse sampling is necessary for a true picture, as single samples at any one point are unreliable. This statement can be verified by an examination of Tables 3 to 6, showing results obtained at our furnaces in a large number of tests. Apparatus The design of the equipment for taking the samples was governed by the need for providing a simple, routine test that could be performed fairly quickly without adversely affecting normal furnace operation.

Jan 1, 1943

By R. B. Hoy, Stanley J. LeFond, K. Reckling

World production of natural diamonds prob¬ably exceeds 50,000,000 carats a year. The Republic of Zaire is the leading producer, with an output which is primarily industrial rather than gem grade. The USSR ranks second, and the Republic of South Africa third. Diamonds are also mined in South-West Africa, Angola, Ghana, Sierra Leone, and other African coun¬tries. In the western hemisphere, Brazil and Venezuela are the principal producers (Fig. 1). A very small output of diamonds is mined today in India, which was the first source of commercial production. In the U.S., efforts at commercial diamond mining have been con¬fined to a small area near Murfreesboro, Ark. The first diamond was found in a kimberlite pipe there in 1906. Small-scale trial mining has not, however, proved economical. Since diamonds were first discovered over 2000 years ago, only about 130 tons have been mined. In order to obtain 1 g (5 carats) of diamonds, it is necessary to remove and process approximately 25 tons of rock. Recovering this small percentage involves a combination of highly developed techniques in mining, quarrying, and earth-moving, and extremely sophisticated recovery processes. End Uses Diamonds are used for two unrelated end uses; gem diamonds are jewels of great beauty while industrial diamonds are essential ma¬terials of modern industry. Although imitation stones are substituted for the gem diamond, none of these matches its properties sufficiently well to offer real competition. Synthetic indus¬trial diamonds are now of a quality that per¬mits wide substitution in the fine-grained sizes. Gem Diamonds A diamond is a natural prism. It has the ability to bounce light rays (reflection), to bend them (refraction), and to break them into all colors of the rainbow (dispersion). This ability to "modify" light gives the diamond three characteristics for providing beauty. First is brilliance, the reflection of light back to the eye. Second is fire, dispersion of light into the colors of the spectrum. Third is scintillation, the "twinkling" that occurs when the diamond is moved (Bauer, 1969). The skill of the diamond cutter is required to unlock the brilliant, fiery beauty of a gem dia¬mond (Fisher, 1966). Diamond-cutting skills have gradually developed over the centuries. The first cutters, in India, learned how to grind one rough diamond against another to remove their "skins" and to give them various shapes. This revealed some fire and beauty, but little compared to that of the diamonds that are cut today. About 1475, a Flemish cutter named Van Gerquem discovered that diamond dust on an iron wheel would polish facets on a diamond to provide more brilliance and fire. Cutters continued to experiment with facets, and shortly before 1700 a Venetian cutter named Peruzzi developed the 58-facet brilliant cut. With the development of the science of optics, cutters have learned more about the behavior of light within the diamond. Early in the 20th century, they learned how to angle Peruzzi's

Jan 1, 1975

By M. King Hubbert

In 1856 Henry Darcy described in an appendix to his book, Les Fontaines Publiques de la Ville de Dijon, a series of experiments on the downward flow of water through filter sands, whereby it was established that the rate of flow is given by the equation: q= - K(h2- h2)/I1 in which q is the volume of water crossing unit area in unit time, I is the thickness of the sand, h1 and h2 the heights above a reference level of the water in manometers terminated above and below the sand, respectively, and K a factor of proportionality. This relationship, appropriately, soon became known as Darcy's law. Subsequently many separate attempts have been made to give Darcy's empirical expression a more general physical fornzulation, with the result that .so many mutually inconsistent expressions of what is purported to he Darcy's law have appeared in published literature that sight has often been lost of Darcy's own work and of its significance. In the present paper, therefore, it shall be our purpose to reinform ourselves upon what Darcy himself did, and then to determine the meaning of his results when expressed explicitly in terms of the pertinent physical variables involved. This will be done first by the empirical method used by Darcy himself, and then by direct derivation from the Navier-Stokes equation of motion of viscous fluids. We find in this manner that: q = (N4(p/p)[g - (l/p) gradPI = WE, is a physical expression for Darcy's law, which is valid for liquids generally, and for gases at pressures higher than about 20 atmospheres. Here N is a shape factor and d a characteristic length of the pore structure of the solid, p and IL are the density and viscosity of the fluid, a = (Nd2)(pip) is the volume conductivity of the system, and E = [g - (l/p) grad p] is the impelling force per unit mass acting upon the fluid. It is found also that Darcy's law is valid only for flow velocities such that the inertial forces are negligible as compared with those arising from viscosity. In general, three-dimensional space there exist two superposed physical fields: a field of force of charucteristic vector E, and a field of flow of vector q. The force field is more general than the flow field since it has values in all space capable of being occupied by the fluid. So long as the fluid density is constant or is a function of the pressure only, curl E = 0, E = - grad F where F = gz + dp/p The field of flow, independently of the force field, must satisfy the conservation of mom, leading to the equation of continuity div pq = — f ap/at , where f is the porosity, und t is the time. For steady rnotion ap/at = 0. and div pq = 0 .

Jan 1, 1957

By R. P. Carreker, R. W. Guard

True stress-true strain data are given for nominally pure molybdenum (99.95 pct) over the temperature range -196° to 1540°C (0.027 to 0.63 T/T). Strain rate sensitivity was determined by rate change tests and stress relaxation tests. Inhomogeneous yielding and strain aging effects were observed. The yield stress and tensile strength depend markedly on temperature below 400°C and are insensitive to temperature in the range 400' to 800°C. The ductile to brittle transition range is +25O to -25OC. Strain rate sensitivity and stress relaxation effects are very large near room temperature. THIS report presents data which were obtained as a part of a continuing program designed to document the deformation behavior of nominally pure metals over a wide temperature range.'" This research program is rooted in the conviction that sufficient tensile and creep data of appropriate quality and detail does not exist to provide precise phe-nomenological descriptions of the deformation behavior of pure metals as a function of temperature, strain rate, and grain size. Such knowledge is needed to provide a firm base for alloy design and an experimental framework to which theories of deformation must conform. These data also complement a parallel exploratory program investigating the properties of refractory metals, including molybdenum, and their alloys. Several important reviews and research reports dealing with the tensile properties of molybdenum as a function of temperature have appeared."-lo To a great extent the work to be reported in the present paper parallels that of Bechtold and of Pugh. The authors' results are in general agreement with those of Bechtold and Pugh. The principle differences be- tween the present experiments and those published previously are as follows: 1—Wire specimens prepared from arc cast molybdenum were used in the present experiments, bar specimens were used by others. Pugh used arc cast material while Bechtold's most extensive results" were obtained on powder metallurgy specimens. 2—Several different grain sizes were tested in the present experiments. 3—The testing range was extended to cover from -196°C to 1570°C (0.027 to 0.63 T/Tm). 4—The combination of wire specimens, high speed autographic recording, and a stiff testing machine permitted more detailed study of initial yielding. The principle contribution of the present paper is the demonstration of the relatively consistent mechanical properties of nominally pure arc cast molybdenum specimens of differing metallurgical history. Bechtold and Scotts have shown that arc cast and powder metallurgy molybdenum samples have comparable tensile properties in the range —75" to 200°C when processed to have the same re-crystallized grain size. Material The molybdenum used in this investigation was supplied by the Climax Molybdenum CO. Its metallurgical history is outlined in Table I; the final products were 0,030 in, diam wire specimens annealed at 1100' and 1375°C and 0.060 in. diam wire

Jan 1, 1957

By H. T. Clark, S. Feigenbaum

The importance of measuring the temperature of molten steel in the open-hearth furnace has been recognized for many years. Poor temperature control may be costly to steelmaking operations and lead to a lowered quality of the steel. Low or excessive temperatures may shorten the life of the furnace, ladles and molds. Rates of reactions in the furnace and efficiencies of deoxidizers are known to change materially with a change in the temperature of the metal and slag. Ladle skulls and mold and stool stickers cause steel to be scrapped instead of being converted into useful products. Finally, the structure, segregation and surface condition of ingots are affected by the teeming temperature. Mill investigations of the effect of bath temperature upon steelmaking operations have been largely qualitative in character, based upon observations by practical melting men. The physical chemist has used the empirical information available and has reached reasonable and useful conclusions with respect to the various melting processes. The introduction of a reliable direct-reading pyrometer will permit accurate quantitative evaluation of the effects of temperature and should furnish a more rational basis for study of the thermochemistry of steelmaking. The problem is not merely one of making a small numbcr of temperature measurements in the open-hearth furnace. This has been done by several methods to a * Assistant Manager, Research and Development, Jones and Laughlin Steel Corporation, Pittsburgh, Pennsylvania. Issued as T.P. 2031 in MEtals Technology, June 1946; also in Open Hearth Proc., 1946. † Open-hearth Metallurgist, Jones and 1aughlin Steel Corporation, Aliquippa. Pennsylvania. degree of precision that was apparently satisfactory. Considerable effort by a number of investigators has been directed rather to the development of an open-hearth bath pyrometer that would be both accurate and practical for routine measurements. To be practical, the pyrometer should be inexpensive to operate; that is, the installation, operating and maintenance costs should be exceeded by the tangible benefits to the open-hearth operator. Temperatures from 2800' to 3100°F. are. encountered in the open-hearth furnace. The surface of the molten metal is covered by several inches of slag, which prevents direct observation of the metal surface for optical or radiation measurements. Both slag and metal are highly reactive at these temperatures and will attack to a greater or lesser extent any material immersed in them. Adequate protectioil of thermocouples, which of necessity must be brought to the temperature of the bath, has generally resulted in a large, heavy assembly made up of brittle materials, unsuited for handling on the open-hearth floor. The life of the equipment was short and maintenance was an important consideration. Earlier Work Any of a number of Physical Properties of liquid steel could conceivably be used a a basis for temperature measurement. Efforts to the present time, however, have been confined largely to measuring either the thermal electromotive force generated between two dissimilar materials immersed in the steel or the intensity of radiation from the surface of the steel. These

Jan 1, 1947

By H. T. Clark, S. Feigenbaum

The importance of measuring the temperature of molten steel in the open-hearth furnace has been recognized for many years. Poor temperature control may be costly to steelmaking operations and lead to a lowered quality of the steel. Low or excessive temperatures may shorten the life of the furnace, ladles and molds. Rates of reactions in the furnace and efficiencies of deoxidizers are known to change materially with a change in the temperature of the metal and slag. Ladle skulls and mold and stool stickers cause steel to be scrapped instead of being converted into useful products. Finally, the structure, segregation and surface condition of ingots are affected by the teeming temperature. Mill investigations of the effect of bath temperature upon steelmaking operations have been largely qualitative in character, based upon observations by practical melting men. The physical chemist has used the empirical information available and has reached reasonable and useful conclusions with respect to the various melting processes. The introduction of a reliable direct-reading pyrometer will permit accurate quantitative evaluation of the effects of temperature and should furnish a more rational basis for study of the thermochemistry of steelmaking. The problem is not merely one of making a small numbcr of temperature measurements in the open-hearth furnace. This has been done by several methods to a * Assistant Manager, Research and Development, Jones and Laughlin Steel Corporation, Pittsburgh, Pennsylvania. Issued as T.P. 2031 in MEtals Technology, June 1946; also in Open Hearth Proc., 1946. † Open-hearth Metallurgist, Jones and 1aughlin Steel Corporation, Aliquippa. Pennsylvania. degree of precision that was apparently satisfactory. Considerable effort by a number of investigators has been directed rather to the development of an open-hearth bath pyrometer that would be both accurate and practical for routine measurements. To be practical, the pyrometer should be inexpensive to operate; that is, the installation, operating and maintenance costs should be exceeded by the tangible benefits to the open-hearth operator. Temperatures from 2800' to 3100°F. are. encountered in the open-hearth furnace. The surface of the molten metal is covered by several inches of slag, which prevents direct observation of the metal surface for optical or radiation measurements. Both slag and metal are highly reactive at these temperatures and will attack to a greater or lesser extent any material immersed in them. Adequate protectioil of thermocouples, which of necessity must be brought to the temperature of the bath, has generally resulted in a large, heavy assembly made up of brittle materials, unsuited for handling on the open-hearth floor. The life of the equipment was short and maintenance was an important consideration. Earlier Work Any of a number of Physical Properties of liquid steel could conceivably be used a a basis for temperature measurement. Efforts to the present time, however, have been confined largely to measuring either the thermal electromotive force generated between two dissimilar materials immersed in the steel or the intensity of radiation from the surface of the steel. These

Jan 1, 1947

By I. M. Roberts

The war emergency has affected every phase of industry. The gas and coke-oven companies have sought faithfully to discharge their responsibility in this critical period and have willingly modified their operations where possible to meet the ever increasing demands made upon them. Our company made commitments for blast-%urnace coke for war purposes which necessitated a reduction in coking time in order to produce the amount required to meet the new demands. At the same time there were certain customers of long standing, who had been supplied with foundry and egg-sized coke produced on fairly long coking periods, who also were engaged in war work and whose patronage we desired to retain. Coke produced on short coking rates from the coal mixture we were then using would not have been satisfactory for these customers. The average width of our ovens is 19¾ in., which is a little wider than the more modern ovens of the present day. They were originally designed to give somewhat cool tops in order to produce a rich gas. This necessitates carrying the heats a little on the warm side so that the tops will be fully carbonized. A reduction in coking time, as is generally known, is accompanied by a reduction in the average size of the coke produced. This is due to the greater shrinkage that takes place at the higher temperatures required to carbonize the charges in a shorter time. The net result is that the coke is more cross fractured and longitudinally fractured and breaks up into small sizes on handling. The cokes produced from the better coking coals seem to be more susceptible to fracture at high temperatures than those from poorer coking coals. A coal mixture that produces a beautiful foundry-sized coke at 30 to 36 hr. may yield a product at 18 hr. that would be so badly fractured as to be unsatisfactory for foundry practice. Coking Characteristics OF Coals Our problem was to find some economical innovation and develop a method that would enable us to reduce the coking time and still produce a coke satisfactory to our foundry trade. However, before discussing the results of our present operations, it might be well to present a few observations on the coking characteristics of coals in general. Most coke-oven operators carbonize a blended mixture of coals. It may consist of a single high-volatile coal with a single low-volatile coal, or of a combination of several high-volatile and low-volatile coals. Medium-volatile coals of the Eagle seam are used for the production of high-grade foundry coke. Medium and high-volatile coals are often blended with one or more low-volatile coals. The possibilities are almost infinite, but the combinations are limited by such factors as cost and facilities for handling multicoal mixtures, and by other practical considerations. Every coal has characteristics that make it blend better with a particular coal or coals in preference to others. This property has

Jan 1, 1944

By I. M. Roberts

The war emergency has affected every phase of industry. The gas and coke-oven companies have sought faithfully to discharge their responsibility in this critical period and have willingly modified their operations where possible to meet the ever increasing demands made upon them. Our company made commitments for blast-%urnace coke for war purposes which necessitated a reduction in coking time in order to produce the amount required to meet the new demands. At the same time there were certain customers of long standing, who had been supplied with foundry and egg-sized coke produced on fairly long coking periods, who also were engaged in war work and whose patronage we desired to retain. Coke produced on short coking rates from the coal mixture we were then using would not have been satisfactory for these customers. The average width of our ovens is 19¾ in., which is a little wider than the more modern ovens of the present day. They were originally designed to give somewhat cool tops in order to produce a rich gas. This necessitates carrying the heats a little on the warm side so that the tops will be fully carbonized. A reduction in coking time, as is generally known, is accompanied by a reduction in the average size of the coke produced. This is due to the greater shrinkage that takes place at the higher temperatures required to carbonize the charges in a shorter time. The net result is that the coke is more cross fractured and longitudinally fractured and breaks up into small sizes on handling. The cokes produced from the better coking coals seem to be more susceptible to fracture at high temperatures than those from poorer coking coals. A coal mixture that produces a beautiful foundry-sized coke at 30 to 36 hr. may yield a product at 18 hr. that would be so badly fractured as to be unsatisfactory for foundry practice. Coking Characteristics OF Coals Our problem was to find some economical innovation and develop a method that would enable us to reduce the coking time and still produce a coke satisfactory to our foundry trade. However, before discussing the results of our present operations, it might be well to present a few observations on the coking characteristics of coals in general. Most coke-oven operators carbonize a blended mixture of coals. It may consist of a single high-volatile coal with a single low-volatile coal, or of a combination of several high-volatile and low-volatile coals. Medium-volatile coals of the Eagle seam are used for the production of high-grade foundry coke. Medium and high-volatile coals are often blended with one or more low-volatile coals. The possibilities are almost infinite, but the combinations are limited by such factors as cost and facilities for handling multicoal mixtures, and by other practical considerations. Every coal has characteristics that make it blend better with a particular coal or coals in preference to others. This property has

Jan 1, 1944

By G. E. Warner

This paper presents a review and analysis of a highly stratified Burbank sand waterflooding project in Osage County, Okla. Permeability values in this reservoir range from less than 0.1 md to nearly 3 darcys, and 90 percent of the permeability capacity is contained in approximately 26 percent of the reservoir volume. To date, the project has recovered 103 bbl/flood-acre-ft since waterflood initiation, which represents 50 percent of the total preflood cumulative and 12 percent of the original stock-tank oil in place (OSTOIP). The outstanding feature of this project has been the economical recovery of a sizable quantity of oil at water-oil ratios higher than those normally considered prohibitive. Nearly 70 percent of the recovery to date has been achieved at water-cut values greater than 95 percent. An ultimate waterflood recovery of 138 bbl/flood-acre-ft, or 67 percent of the preflood recovery and 16 percent of the OSTOIP, is predicted. The ultimate primary and secondary recovery will be 302 bbl/acre-ft and approximutely 40 percent of the OSTOIP. The actual performance is compared with the predicted performance by both the Stiles and the Dykstra-Parsons methods, and applicabiliry of these methods to this particular reservoir is evaluated. The performance of this project indicafes highly stratified reservoirs can be successfully and economically waterflooded when either reservoir or economic conditions preclude the use of mechanical and chemical means of mdbility control. Introduction The concept of the stratified reservoir has been used by reservoir engineers for many years to describe the vertical variations in permeability within a reservoir. Numerous techniques have been advanced to predict the expected waterflood performance of the stratified reservoir, and in most cases they prove reasonably accurate. The advisability of undertaking a prospective waterflooding project is determined, based on these predictions. This paper presents a review of a waterflood project in a highly stratified reservoir that normally would be considered a marginal prospect, at best, when evaluated with any prediction technique properly adjusted for reservoir conditions. This kind of project can be successful if the predictions are used to design a waterflooding system capable of economically recovering an oil cut of 1 to 2 percent. Experience gained in the early stages of the project's development was profitably applied in the later development of the entire reservoir and could prove beneficial to other projects with similar reservoir stratification or fracture characteristics. The East Burbank pool waterflooding operations have been developed in three separate stages, each of which has been a separate project: Mid-Burbank Unit, Flood A, and Stanley Waterflood. When referred to collectively, these projects will be called the Composite Project. The Skelly Oil Co.'s Barber lease — the only portion of the pool not included in the three projects — is operated as a separate facility with a cooperative injection-well agreement. It contains less than 80 productive acres and would not significantly affect the over-all performance picture.

Jan 1, 1969

By H. G. Doll

The S.P. log is shown to be a measurement of the potential drop along the drill hole, caused by ohmic effect in the mud. The notion of static S.P. is brought forward, and its relation to the S.P. log is discussed. Other factors influencing the shape and amplitude of the log are considered; attention is given to conditions encountered in practice. Numerous figures are given illustrating graphically the results; these figures are of particular interest for comparison with field examples. The S.P. log, although indicating permeability, is not an absolute measurement of permeability, nor of porosity, of the formations traversed by a drill hole. It is affected by several parameters, such as resistivity of formations and mud, thickness of formations, and others, which should be appraised carefully. Simple rules have been established for a better distinction of the boundaries of permeabl: sections, particularly in difficult cases, such as those encountered in highly resistive formations. A systematic application of the established principles will assist in obtaining more information from the S.P. log than was possible thus far; for instance, under favorable conditions, presence of oil may be detected, or amount of shale in sands may be estimated. Introduction The S.P. log, or spontaneous potential log, has been known and widely used during the last 15 years for the location of permeable beds traversed by drill holes.1,2 In electrical logging practice, the S.P. log is shown on the left hand side track of the record (as may be seen in later examples) where it can be easily correlated and interpreted with the resistivity curves located to the right. Usually, the S.P. log consists of a base line, more or less straight, having excursions or "peaks" to the left. The base line frequently has been found to correspond to impervious beds, while the peaks are usually found opposite permeable strata. Measurements which will indicate positively the presence of permeability in the formations, and which will give accurately the boundaries of the permeable zones, are of great importance in oil-field practice. Thus far, the S.P. log is the best approach to such determinations; unfortunately, its interpretation is not always evident. With respect to the base line of the S.P. log, it may be noticed that this line is not always at a definite location on the chart. Sometimes it may shift abruptly, while other times a gradual drift is apparent. As far as the peaks are concerned, their shape is not uniform; some are rounded while others are sharp. Also, from other data, it may be found that occasionally the peaks extend appreciably beyond the boundaries of permeable zones into zones which are not everywhere permeable. A comparison with permeability measurements made on cores has often confirmed that there was no definite correspondence between the magnitudes of the peaks and the permeability values. In the same geological horizon, it generally will be found that most of the thick and permeable for-

Jan 1, 1949

By J. L. Bruce

AFTER six years of war-enforced idleness, Cyprus copper mines are operating again. This relatively long shutdown seems infinitesimal when compared with something like seventeen hundred years of inactivity that followed the important operations of the ancient Romans, and continued until the twentieth century. The historical records of the ancient operators are scarce but full of interest to those who realize that Cyprus copper production was important more than two thousand years ago. This paper, however, will give only a brief review of the ancient history and the evidence of ancient mining which have been quite fully covered in other publications.1-6 The purpose of this paper is to give a general sketch of the Cyprus Mines Corporation's enterprise in the Island of Cyprus, with special emphasis on those conditions and practices which are unusual. The picture is not intended to be complete, and many interesting details will be omitted. Some of these may be described in subsequent papers covering departmental practices. The principal operations of Cyprus Mines Corp. are in Cyprus, where it has leasehold concessions from the Cyprus Government covering about 50 square miles. It holds additional areas under "Prospecting Permits." The consideration for the concessions is a royalty on production, coupled with minimum annual rentals. Cyprus is a British Colony in the Eastern end of the Mediterranean with an area of about 3000 square miles and a population of about 400,000, of which 65 pct may be classed as Greeks on the basis of language, religious training, and traditions. About 25 pct are Moslems, principally of Turkish extraction. Prevailing languages are Greek and Turkish. A large proportion of the supervisory and administrative staff and practically all of the skilled and unskilled craftsmen and laborers are drawn from the native population. The "overseas" staff constitutes not more than 2 pct of the employees. The majority of these are from the United Kingdom, the British Dominions and Colonies. About one-third are from the United States of America. The topography of the Island is rugged, with mountains and foothills covering more than two-thirds of the area. Between the Kyrenea range rising to 3000-ft elevation, along the north coast, and the Troodos range (maximum elevation 6400 ft) occupying the southwest half of the Island, lies a cultivated rolling plain, the "Mesaoria," dry in summer and watered only by the winter rains and by scanty irrigation from small mountain streams and wells in the spring and summer. Climate and natural vegetation are characteristic of semi-arid conditions. The "urban" population, about one-fourth of the total, lives in the five port towns, Famagusta, Larnaca, Limassol, Paphos and Kyrenia, and in the capitol Nicosia, near the center of the Island. The suburban population lives almost entirely in villages or small towns, with very few people residing in isolated country homes.

Jan 1, 1947

By I. M. Roberts

THE war emergency has affected every phase of industry. The gas and coke-oven companies have sought faithfully to discharge their responsibility in this critical period and have willingly modified their operations where possible to meet the ever increasing demands made upon them. Our company made commitments for blast-furnace coke for war purposes which necessitated a reduction in coking time in order to produce the amount required to. meet the new demands. At the same time there were certain customers of long standing, who had been supplied with foundry and egg-sized coke produced on fairly long coking periods, who also were engaged in war work and whose patronage we desired to retain. Coke produced on short coking rates from the coal mixture we were then using would not have been satisfactory for these customers. The average width of our ovens is 19 ¾ in., which is a little wider than the more modern ovens of the present day. They were originally designed to give somewhat cool tops in order to produce a rich gas. This necessitates carrying the heats a little on the warm side so that the tops will be fully carbonized. A reduction in coking time, as is generally known, is accompanied by a reduction in the average size of the coke produced. This is due to the greater shrinkage that takes place at the higher temperatures required to carbonize the charges in a shorter time. The net result is that the coke is more cross fractured and longitudinally fractured and breaks up into small sizes on handling. The cokes produced from the better coking coals seem to be more susceptible to fracture at high temperatures than those from poorer coking coals. A coal mixture that produces a beautiful foundry-sized coke at 30 to 36 hr. may yield a product at 18 hr. that would be so badly fractured as to be unsatisfactory for foundry practice. COKING CHARACTERISTICS OF COALS Our problem was to find some economical innovation and develop a method that would enable us to reduce the coking time and still produce a coke satisfactory to our foundry trade. However, before discussing the results of our present operations, it might be well to present a few observations on the coking characteristics of coals in general. Most coke-oven operators carbonize a blended mixture of coals. It may consist of a single high-volatile coal with a single low-volatile coal, or of a combination of several high-volatile and low-volatile coals. Medium-volatile coals of the Eagle seam are used for the production of high-grade foundry coke. Medium and high-volatile coals are often blended with one or more low-volatile coals. The possibilities are almost infinite, but the combinations are limited by such factors as cost and facilities for handling multicoal mixtures, and by other practical considerations. Every coal has characteristics that make it blend better with a particular coal or coals in preference to others. This property has

Jan 1, 1944

By H. Y. Bassett

THIS paper attempts to show the various major operations used in nonferrous tube mills and does not necessarily represent the current practices at the two plants of the Wolverine Tube Div., of Calumet and Hecla Consolidated Copper Co. Inc. The operations now utilized in the production of tubing are quite varied and show the continual interest and advance metallurgically and mechanically to produce the best quality at the lowest cost. Naturally, any advance or lowering of cost is dependent on large production runs, which mean longer machine running time with maximum worker productivity. Standardization of tube sizes and elimination of unnecessary alloys are therefore very necessary, otherwise the development of costly new production machines would be of little benefit to the consumer as a whole. It should be noted that in such a short presentation it is impossible to describe in any detail the major operations. The short descriptions, it is hoped, will enable all who are interested to obtain a general idea of present, day practices in the copper tube producing field. Fig. I is a flowchart or sequence of operations showing the steps usually employed in tube production. RAW MATERIALS Quality starts with the raw material, and it is absolutely necessary that raw material be controlled and held to rigid specifications. Little need be said, however, regarding the raw materials for the casting of bars or billets, as the material always is purchased and checked against the various governing A.S.T.M. specifications. CASTING Casting, as is indicated in Fig. I, is quite varied and for convenience can be classified into two groups: The casting of solid billets, and the casting of hollow tubes, each of which is the base for subsequent operations. In the melting of the raw materials various types of furnaces are used, and the selection of any one is dependent on many factors outside the scope of this paper. However, as of general interest, a short description will be made of each. Induction Furnace (Low Frequency) This is popular in the melting of copper-base alloys, Fig. 2. In the induction furnace the principle of an inefficient transformer is used for the production of the necessary melting heat. The primary coil is.arranged around a transformer core made of high permeability silicon steel sheet. The secondary circuit is through a melting channel around the primary coil and opens into a hearth which contains the main charge. The heat is generated only in the melting channel, but because of the stirring action there is a constant flow of metal around the channel, which when mixing with the charge causes very rapid melting. The volatilization losses are very low as the furnace atmosphere above the charge is heated only by the heat from the melting metal. The stirring action, however, makes the use of any slag cover difficult. Such furnaces- must be started with molten

Jan 1, 1951

By R. P. McNitt

TITANIUM hydrides have received considerable study in recent years because of the adverse effects of the hydrides on mechanical material properties such as ductility and tensile strengths. Generally speaking, as the hydrogen content increases, ductility and strength levels decrease. While the amount of hydrogen present in commercial titanium is negligible, hydrogen may enter the material during welding, electroplating, and so forth. The hydrogen will then precipitate, in the form of titanium hydride. If the material

Jan 1, 1968

In December, 1927, the Institute published two papers on the Brad-ford pool, which were presented at the New York meeting in 1928. Pamphlet copics may be obtained by writing to the Secretary's office for: Oil-field Waters of the Bradford Pool, by Paul D. Torrey. Technical Publicalion No. 38. Some Factors Influencing Production of Oil by Flooding in the Bradford and Allegany Fields, by Paul D. Torrey. Technical Publicaliol No. 39.

Jan 1, 1928

By Stanley C. Suboleski, J. Richard Lucas

Simulator I, a program to simulate production in room and pillar mining systems containing up to six face operations, was developed at Virginia Polytechnic Institute under sponsorship of the Office of Coal Research. Since its inception, several hundred analyses have been run, with over thirty companies using the program. This paper describes the simulation technique used in this program, the output achieved from an analysis, and reviews the experience gained in working with Simulator I.

Jan 1, 1969

Unitization—in some form from simple agreements among operators to complete consolidation of ownerships—is a means of obviating the wastes of unrestrained competition among owners in extracting oil and gas from a common reservoir, as well as of adjusting its output to the current needs of its owners. It offers opportunity for application of improved production methods which are expected to increase recovery, decrease developing and operating costs, and assist in stabilizing output.

Jan 1, 1930

By J. J. Spencer

IT has been found that, during any particular period of operation or in mining any particular area of the Castle Dome mine, there appears variation between mine grade and mill grade, thus Ear always in the plus direction. It would be interesting to know if this condition obtains at other properties, and, if possible, to alter the sampling methods or computations in order to get better agreement between mine and mill figures.

Jan 4, 1951

This consolidated index covers all publications of the Institute for the years 1926 through 1935. The following list indicates subjects of volumes and gives numbers or abbreviations used to designate them. TRANSACTIONS VOLUME *G26. Petroleum Development and Technology in 1925 (Published in 1926). *G26. Petroleum Development and Technology in 1926. *E27. Institute of Metals Proceedings. 73. Nonferrous Metallurgy, Milling and Concentration, Nonmetallic Minerals, Institute of Metals and Iron and Steel. [ ]

Jan 1, 1936