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By Z W. Orndorff

Excavation through sulfidic geologic materials during construction activities has resulted in acid rock drainage (ARD) related problems at numerous (>40) locations across all five geologic regions of Virginia, USA. Potential acidities ranging from >100 to develop a statewide sulfidic materials risk map; document ARD impacts to soil and water quality and engineered structures; and develop methods to assess site-specific risk potentials within a given highway corridor. A statewide sulfidic materials GIS risk map was developed based upon the state digital geology map which assigned four levels of relative risk to all mapped strata based upon predicted lime requirements and probabilities of encountering highly reactive materials. Non-highway construction activities have also routinely disturbed sulfidic materials, and a recent airport project in northern Virginia resulted in over 150 ha of extremely acidic (pH 45 mg/L) run-off from this site heavily damaged a receiving stream, partially due to the fact that it dissolved the galvanised steel water control structures in stormwater detention basins, leading to direct discharge of run-off and sulfidic sediments. The airport area was treated and revegetated in 2002 with a combination of lime-stabilised biosolids, straw mulch, and acid-tolerant grasses. Water quality in a receiving second-order stream quickly responded to the treatment, but some release of N was also noted as a secondary effect. Collectively, these results point out the importance of accurately assessing the potential for excavation of sulfidic materials in construction environments, and the necessity of developing toxic materials handling strategies similar to those employed in mining environments.

Jan 1, 2003

By Ault A. R

The recent modernisation program at the Risdon electrolytic zinc smelter of Pasminco Metals - EZ (PMEZ) inyolved significant changes to the composition of cell electrolytes. The most significant were increased acidity and sulphate level, a reduction in Co level, and the replacement of 2-naphthol in the additive mixture with licorice. In determining acceptable operating ranges, a relatively large number of industrial deposition tests under controlled conditions was required. The cathode zinc deposits so produced were examined in terms of overall appearance, crystal structure according to X-ray diffraction, and a micro-roughness parameter. Beginning with typical deposits produced in the presence of an excess of one of the addition agents glue or antimony or a mist suppressant (licorice or 2-naphthol), a simple classification system was developed. In this system, the deposits are divided into the following types: Doughy, Pinholed, Compact and Stressed. There was a weak correlation between deposit type and crystal orientation. In terms of ease of stripping, observations in plant operations showed that only Compact and Pinholed were consistently acceptable. Current efficiency was normally maximised by producing a Compact deposit. Process variables such as zinc concentration, temperature and the use of strontium carbonate were found to cause changes in deposit type if the reagent mixture used was unchanged. From the knowledge gained, guidelines were developed to allow glue and antimony additions to be altered to fit new circumstances. The simple classification system was first used to expedite recovery from undesirable morphologies and then to optimise individual cell units operated under substantially different conditions. It is believed that finer control could be exercised by determining the micro-roughness of Compact deposits. However, difficulties can arise if sudden, large deviations occur and go undetected. Suggestions are given for an improved additive control system. The classification system developed has been compared with published information in the literature, and good correspondence was noted suggesting a predictable relationship between short-term, laboratory deposition tests and observable phenomena in industrial electrowinning cells run under steady conditions.

Jan 1, 1993

Integrated chemical thermodynamic software and computerised databank systems have evolved over the last 15 years. The extent to which these systems have automated thermodynamic calculations relevant to extractive metallurgy is examined. The scope for further automation and the role of the expert consultant is discussed.

Jan 1, 1991

By Forster I, Thilo A, Dean AK

A prototype production tool capable of operation in the hole sizes (

Jan 1, 1988

By Khosrowshahi S

The objectives of grade control remain unchanged but new methods are being developed to attain them. Since the early-1990s, an improvement in the power of mine site computers has made the geostatistical tools of conditional simulation more accessible. Optimisation of the grade control process on mine sites now involves two stages: optimisation of the sampling regime and optimisation of the interpretation of ore and waste boundaries. Optimisation of the sampling regime first requires an understanding of the nature of the mineralisation and in particular the impact of particle size on the sampling precision. This relationship, termed the Fundamental Error of sampling, enables an optimum subsampling protocol to be defined for the sample preparation and assaying. However, the actual sample collection method, whether drilling or trenching, must be correctly selected and the sampling grid should be optimised. The relative costs and benefits of various alternative sampling methods and grids can be determined using the method discussed. The use of the grade control data can also be optimised. In the past ore and waste boundaries were often defined using a linear interpolation algorithm that smoothed the data (such as polygonal, sectional, inverse distance squared or even kriging methods). Frequently the relative impact of ore loss and dilution could not be estimated. Conditional simulation to generate equiprobable alternative maps (realisations) can now be adopted to address these issues. A transfer function is then used to evaluate the similarities and differences between the maps. The Ore Block Optimisation (OBO¬) process is a transfer function that produces a three-dimensional model of the optimal ore block outlines. This provides a clear guide for the mining geologist to refine and mine. The nature of the transfer function and the inputs and outputs are discussed. In the past, reconciliation has been the `acid test' for any grade control system. Any ore blocking method based on conditional simulation can make use of the exhaustive data set to ensure that reconciliation between prediction and production will improve significantly. The OBO¬ method provides a guide to the mining geologist to ensure that the best ore blocks are mined. Misclassification between ore and waste is reduced, ore loss and dilution are minimised (and are measurable) and ore is optimally assigned to stockpiles of various cut-off grades. These advantages significantly enhance mine profitability and control of the mined grade.

Jan 1, 1997

By J H. Baker, P G. Beadle, J P. O&apos, Brien

In 1974 a preliminary study of the refractories industry in theRepublic of Indonesia was completed by Crown Lynn Consultants, a subsidiary of Cerarnco Ltd., on behalf of the Indonesian and New Zealand Governments. As a result of recommendations arising from that study the two Governments commissioned, in 1976, as a Bilateral Assistance project, an investigation into the potential of the refractories industry in Indonesia. Ceramco Ltd., was retained to carry out the study on behalf of the New Zealand Government. The Directorate-General of Chemical Industries, Directorate of Silicate Industries administered the project on behalf of the Indonesian Government. Indonesian counterparts to the New Zealand study team were provided by the Directorate of Silicate Industries.

Jan 1, 1978

By J Cook, S Pike, D Pridmore

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The application of high-resolution seismic reflection to map structure and/or mineralisation in hard rock environments has progressed significantly in the last decade. Improvements in equipment, field practice, processing and understanding has seen the seismic reflection technique emerge as a cost-effective tool for high-resolution three-dimensional structural and lithology mapping to depths far greater and with superior accuracy than other more conventional geophysical techniques.This paper outlines results and preliminary interpretation of 2D and 3D seismic reflection surveys aimed at defining fault zones and locations for quartz load development in favourable host lithologies at the Cracow low-sulfidation epithermal gold system in Queensland, Australia.As this is possibly the first time that high-resolution seismic reflection data has been used to define the structurally-controlled location of low-sulfidation epithermal gold mineralisation, an important aspect of this work was the derisking or due diligence steps taken prior to commissioning the full 3D surveys at each site. This included full wave sonic logging, vertical seismic profiling and trial 2D lines. Interpretation of the 2D profiles and the drilling of interpreted structure provided the confidence to proceed with the full 3D survey.The advantage of collecting 3D data extends beyond ensuring that the received reflections are located correctly in 3D space. The final 3D data cube can potentially map the entire fault network, thus highlighting flexures and changes in orientation of the structures both vertically and along strike, which is an important aspect in the deposition of gold and for direct targeting.CITATION:Smith, R, Cook, J, Pike, S and Pridmore, D, 2015. Application of high-resolution seismic reflection surveys to exploration for blind vein systems at the Cracow low-sulfidation epithermal field, in Proceedings PACRIM 2015 Congress, pp 77–84 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By G R. Hancock, W D. D P Welivitiya

is placed in a waste rock dump, which is usually later reshaped to be erosionally stable, initiate and sustain vegetation and ultimately integrate with the surrounding undisturbed landscape. However, it is unclear how this exhumed material will weather and evolve for most sites. Also, there is a lack of data on the weathering of post-mining materials. If weathering is better understood, then there is the potential to improve rehabilitation outcomes. To improve predictions of the evolution of soil properties and weathering-limited erosion, estimating the rate at which fine, transportable material is produced from the weathering of larger, non-transportable particles and the resultant fragment size distribution and how that distribution evolves over time is necessary. This study examines the weathering process for four different coalmine waste rock materials for a Bowen Basin, Queensland site. Materials obtained from various areas of the coalmine were subjected to cyclic wetting and drying and heating and cooling. Particle size distribution and other material properties were explored after each experimental cycle to ascertain how the material changes during the experimental cycles. The particle size distribution data of wet and dry cycles were used as input data in a numerical weathering model to explore the dynamics of the weathering process for each material sample. A Monte Carlo framework was employed to assess the geometry of the weathering products, weathering rate and the number of daughter particles produced within a weathering cycle. Then the SSSPAM Landscape Evolution Model was used to evaluate the influence of weathering on erosion and landscape evolution of a post mining landform. SSSPAM simulations with: (i) active weathering and (ii) without weathering were run for each material. The erosion rate and the overall landform structure were then compared between weathering and non-weathering simulations.

Aug 2, 2023

It is now 32 years since Walsh's classic publication (1) heralded the beginning of atomic absorption spectrophotometry (AA) as we know it today. During this time, AA has developed into the most widely used analytical techniques for the determination of the metallic elements. The years have seen progressive changes in instrumentation so that today it is a highly sophisticated technique. One area of development in AA that is experiencing renewed attention is in the area of electrothermal excitation. In this technique a flame is not used by the analyte solution is atomised by an electrically heated graphite furnace. For a large number of elements the graphite furnace atomic absorption spectrophotometer (GFAA) is considerably more sensitive than flame work. It is common to be able to detect concentrations one hundred times smaller than those possible by flame. Today's geochemists are finding that they can gain valuable information out of very low limits of detection. Electrothermal atomic absorption spectrophotometry (or GFAA) allows for low limits of detection and can be seen to be a valuable aid to geochemical prospecting Analysis.

Jan 1, 1987

By K Barbosa, G Wilkie, F Reyes, V Jokovic, C Evans

The idea behind Grade Engineering is to exploit the natural heterogeneity of an orebody (spatial, temporal) in order to divert low-value waste out of the mining value chain. Essentially, this involves rejecting material at relatively coarse particle sizes (10 mm to 200 mm). However, lack of knowledge about the inherent particle grade distributions in these coarse particle size ranges limits the opportunities for optimisation. Particle grade distributions are essential for quantifying and modelling gangue liberation and yield curves. These curves can then be used to predict the mass and value flows that will go towards the accept and the reject streams. Particle grade distribution information for particles coarser than 10 mm can be collected based on chemical assays of sufficient number of individual particles. However, for smaller particles (1 mm to 9 mm), a significantly larger number of particles is required for assays. Moreover, in some cases, the mass of individual particles is smaller than the minimum mass required for chemical assaying. Also, other quantification techniques such as automated mineralogy, eg Mineral Liberation Analysis (MLA), require extended measurement times to analyse statistically representative numbers of particles at these size ranges. This work investigates the use of 3D X-ray microtomography to fill this quantification gap at these size ranges (1 mm to 9 mm). In-house image processing algorithms are used to estimate the mineral/metal content in each particle. Particle grade distributions, as well as density distributions, are thus produced without a minimum mass requirement and with each scan providing information about tens to hundreds of particles at a time. Mineralogical data from MLA analysis, of finer size ranges, is used to inform X-ray microtomography, so a simpler 3D mineral map can be obtained using the image intensity. Chemical assay information of the scanned samples is used to validate and correct the mineral phase segmentation.

Aug 24, 2022

By L Lagoeiro

The samples studied in this paper were derived from the iron oxide facies of iron formations (IFs) of the Quadrilßtero Ferrffero, south-eastern Brazil. The rich-iron oxide varieties of the IFs can be regarded as Fe-O systems because they consist predominantly of aggregates of haematite and magnetite crystals. The study was based on carefully selected samples in which magnetite crystals occur as isolated large crystals set in a matrix of haematite grains. Optical microscopy and an electron microscope equipped with an electron backscattered diffraction (EBSD) system were used to investigate the microstructural and crystallographic relationships involved in the phase transformation between magnetite and haematite. The magnetite crystals in the IF samples are partially transformed to haematite and this process is also known as martitisation. This transformation occurs along the crystallographic planes {111} of the magnetite producing a characteristic triangular pattern of interlocking lamellae of transformed haematite crystals that are oriented parallel to octahedral plane {111}. This new generation of haematite is referred to martite because of the martitisation process. EBSD analyses show that the magnetite and the new haematite crystals, martite, share crystallographic planes of highest atomic density, eg {111} and (0001), respectively, possibly due to the ccp and hcp atomic arrangement of the two crystals. Stereographic projections of these two planes therefore coincide when the maxima of their poles are plotted. However, the crystallographic orientation of the haematite crystals in the matrix shows maxima of (0001) poles that do not coincide with those of {111} planes of magnetite. Consequently, it is concluded that the direct transformation to haematite crystals retains the crystallographic orientation memory of the former magnetite crystals, possibly due to the similar manner whereby their atoms are packed together in the crystal structures. On the other hand, no such relationships are observed between magnetite and haematite crystal in matrix. This suggests that haematite grains in the matrix may have been formed by other processes rather than those involved in the iron oxide transformation observed within the magnetite grains.

Jan 1, 2008

By Reid T. W

This paper describes the results of investigations into the relationship between specific gravity and chemical composition in the Cockatoo Island orebody, In the early investigations the samples were classified into groups according to porosity. This resulted in high, medium and low porosity groups, the latter being further subdivided into ore and waste. Whole number tonnage factors were assigned to each group. In the later investigations the reciprocals of bulk specific gravity and true specific gravity were ex- pressed as linear combinations of iron, silica and alumina using stepwise regression. The efficiency of the models as predictors was tested by dividing the data into two sets; one of which was used to calculate the regression equation and the other to test the efficiency of the equation as

Jan 1, 1976

By Neill B. K, Fander H. W, Wong K, Dunlop G, O&apos

Commercial interest in refractory gold is increasing rapidly. This trend is supported by the work patterns of Amdel, where, apartfrom routine process- ing of free-milling and refractory ores, the majority of testing now includes biological and pressure oxidation studies to enhance gold recoveries. Central Mineralogical Services have examined, among other ores, an apparently unique type of refractory coating. A summary is given of experience at Optimet Laboratories, Pty., Limited. Research into nitric acid pre-oxidation, underway at the South Australian Institute of Technology since 1987, has shown significant improvements in gold recoveries, and in some cases, large reductions in reagent consump- tions. Three final-year student research projects were undertaken in 1990, jointly between the University of Adelaide and the S.A. Institute of Tech- nology. These projects involved biological pre-oxidation, pressure leaching, and Scanning Electron Microscope examination of refractory ores, and the resultant pre-oxidation and cyanidation products.

Jan 1, 1991

By Khosrowshahi

A scientific approach to analysing grade control has been applied at a number of mining operations. By dividing the grade control process into the various stages of data collection and interpretation, errors can be identified using reconciliations of production against predictions. The merits of different mining styles in large and small open pit mines are examined.One factor in successful grade control is estimation of the expected ore loss and dilution. Empirical methods developed in two dimensions have been refined to enable 3D modelling of the effects on mineable grade and tonnage of varying the bench height, sampling orientation, and sampling Resolution.

Jan 1, 1992

By K S. E, S C. Parker, T K. Kundu

Understanding the fundamental principles governing the reactions at surfaces has always been the goal of theoretical surface science. The atomistic simulation techniques have been used to calculate the surface structures and the stability of quartz and wollastonite, and their adsorption behaviour in the presence of molecular and dissociative water, and the two widely used collector head group molecules of methanoic acid and methylamine. The dissolution behaviour of wollastonite has also been modelled. The calculated surface energy, hydration energy and reaction energy values have been examined and discussed in the light of flotation literature. These studies have given an insight into the interactions at atomic level, which indicate that modelling techniques should be capable of predicting the adsorption behaviour and to design the selective collector molecules, which is of central importance to the mineral processing technique of flotation.

Jan 1, 2005

By Stanley I. M, Brett D, Dickson R

The Mt Lyell Mine, situated in Queenstown on the west coast of Tasmania, has a production history of more than 100 years. Previous mining activities have resulted in substantial modifications to environmental conditions at Mt Lyell and disposal of sulphidic waste rock across the lease has left a legacy of on-going environmental impacts including acid drainage (AD). In 1995 Copper Mines of Tasmania (CMT) was granted a mining lease Irons the Tasmanian State Government for redevelopment of Mt Lyell and indemnity from actions concerning pollution from previous occupation and use of leased land. The Environmental Management Plan (EMP) for the Mt Lyell redevelopment committed CMT to be responsible for waste rock dumps generated from their activities and to ensure that management is in-line with best practice environmental management principles. CMT commenced commercial production in December 1995 with sulphidic material from development of the underground Prince Lyell mine reporting to a single waste rock dump constructed according to a management plan developed in July 1995 and superseded by a management plan for extension in May 1997. The CMT waste rock dump currently has a total capacity of 220 000 m- and approximately 120 000 m3 of rock have been placed to-date. Material reporting to the dump is placed in a densely compacted state to a controlled surface profile. The dump is clay capped and a final revegetated soil layer placed on top. A rock pitched drain extends down to a wetland area in order to remove stormwater and minimise possible soil erosion on the revegetated sections. An integral part of the management plan for the waste rock dump involves characterisation of waste rock to identify geochemical rock types according to acid forming potential with provision for selective placement within the dump. High-risk materials are selectively placed and covered within the core of the waste rock dump, where possible, to control sulphide oxidation. Monitoring equipment has been installed in the waste rock dump by the Australian Nuclear Science and Technology Organisation (ANSTO) and an on-going monitoring program has been established to demonstrate the integrity of the dump cover as a barrier to the influx of atmospheric oxygen into the dump. The overall objectives of this program of work are to control the oxidation of sulphidic waste rock in the waste rock dump, minimise the risk of AD, prevent pollution of the aquatic environment and thereby demonstrate the integrity of the CMT waste rock dump management Strategy.

Jan 1, 1997

By Fullagar P. K

In resource definition and mine development, major capital expenditures are committed on the basis of sparse information and even in production surprises such as bad ground are not uncommon. Drill holes constitute the principal source of information about the orebody and its environment and optimisation of drilling implies maximising the yield of useful information per dollar expended. Geophysical borehole logging provides new flexibility for optimising the drilling budget. Economic benefits can flow from geophysical logging at all stages of the mining cycle. The most commonly cited benefit is substitution of diamond delineation drilling with cheaper percussion or reverse circulation drilling in cases where geophysical logs can substitute for core. This approach can deliver an attractive direct saving in drilling costs (and time) if drill meterage is unchanged, or a potentially greater indirect benefit from better ore control if more holes are drilled within the original drilling budget. More ore contact intercepts per dollar can translate into lower dilution and enhanced ore recovery, thereby increasing revenue as well as reducing mining costs. Substitution of diamond drilling with percussion drilling is not always feasible. However, geophysical logging of diamond holes is often highly advantageous in its own right, both for geotechnical characterisation as well as ore delineation. Operational advantages of logging include data objectivity, speed of interpretation and reduced core handling and analysis costs. Geophysical logging assists mining engineers by providing a continuous measure of in situ rock strength, even over intervals with poor core recovery. The additional expense of geophysical logging in blast holes can be justified in terms of more accurate ore boundary delineation and rock strength evaluation. Precise ore boundary delineation permits refinement of charge placement, to minimise dilution and maximise recovery. Detailed knowledge of rock strength can enable optimisation of blast design. Rock strength can be evaluated in real-time via analysis of drill performance data recorded with measurement-while-drilling (MWD) technology. To successfully apply geophysical logging in mines, its technical, operational and economic viability must all be established. This entails verification of the existence of appropriate physical property contrasts, investigation of the best way to integrate the geophysical results with the mining method and an objective assessment of the value of the resulting mine performance benefit. Geophysical logging is already well established in many mining operations. The greatest impediments to its wider utilisation at mines are: lack of appreciation of geophysics by most mine geologists, engineers and managers; limited interpretational aids; and the necessity to re-enter completed drill holes. In this paper we endeavour to address these issues by informing mine geologists about potential applications of geophysics, by illustrating automated interpretation of geophysical logs and by highlighting the importance of emerging MWD and logging- while-drilling (LWD) technology.

Jan 1, 1997

In 1975, following a programme of solution characterization and small scale laboratory test work, a pilot plant was constructed to treat waste liquors from the Risdon works. The plant was designed basically to neutralize liquor to a desired pH, and to flocculate, thicken and then filter the resultant pulps. The primary objective was to purify waste liquors to stand- ards set by Tasmanian environmental regulations and at the same time to provide design data for construction of a full scale treatment facility. Waste liquors were divided into two groups, those from the Zinc Plant, and those from the Acid and Superphosphate Plants, and were treated independently. To satisfactorily purify Zinc Plant waste liquors the following reaction sequence was required: 1. Neutralization to pH 10.5 (with aeration for Mn removal). 2. Further reaction of neutralized pulp with Na2S at an addition rate of typically 5 mg of S2-/litre of liquor treated to remove Cd.

Jan 1, 1977

Carbothermal Reduction and Nitridation of Ilmenite Concentrates and Chlorination of the Reduced Samples

Sep 13, 2010

By P Dean, M Elmouttie

Radar monitors are now widely used in surface mining for monitoring slope deformations and predicting failure events. Their introduction has facilitated better management of risk associated with slope failure during mining and therefore protection of personnel and equipment. However, a wellrecognised problem is that radar monitors only measure deformation directed towards the detector (line-of-sight bias). This bias can lead to misinterpretation of deformation size, rate and failure mechanism, and therefore miscalculation of failure volume, which can significantly impact safety and productivity. This paper presents recently completed research and field trials into the feasibility of using low cost vision systems to mitigate this issue. It has been demonstrated that by integrating a computer vision system with an existing slope monitor, high precision tracking of features in the field of view can be performed. Combined with assumptions on the deformation characteristics, the true 3D deformation vector can be estimated. The applicability of using this technique for monitoring iron ore mine slopes is discussed.

Nov 8, 2021