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By M G. Aylmore

Thiosulphate is an attractive alternative reagent to cyanide for processing gold ores. It is relatively cheap and non-toxic, forms relatively strong gold and silver complexes, and readily leaches gold ores in ammoniacal solutions, catalysed by Cu(II). It is particularly suited to carbonaceous ores where the recovery of gold by cyanide is poor. However research over the past 20 years has identified a number of issues and impediments that must be understood or overcome before an overall process can be demonstrated as practical and economic for typical oxidised gold ores. This paper reviews our current understanding of thiosulphate chemistry and mechanism of gold dissolution, and discusses the stability of thiosulphate and polythionates. It then reviews the results of leaching various gold ores that have been reported in the literature, discusses gold recovery options, and considers environmental and toxicity issues. Some of the issues that require further research include decreasing the oxidation of thiosulphate by Cu(II) or other oxidants, increasing the extraction of gold compared to cyanide, and understanding the variation in gold recovery between ores. More work is also required to minimise the effect of polythionates on gold recovery using resins or alternative absorbents, to improve the elution of copper and gold from resins, and to recycle or minimise the concentration of reagents.

Jan 1, 2002

Agglomeration Drum Selection and Design A model has been developed by for drum agglomeration which allows selection of geometry and power input. Specific aspects considered are: calculation of total operating volume, solids residence time based on drum geometry and operating parameters, selection of the drum aspect ratio, selection of proportion of critical speed, calculation of rotating power requirements. The model uses solids total residence time to calculate the required operating volume. The burden density is calculated from the solids bulk density, agglomerate packing and the fluid density. Power is calculated using a modified Liddell and Moys correlation for burden position and shape, and the operating drum speed. A further power allowance is made to allow for accretion drop off during drum rotation. Results from the model (especially power and per cent operating fill) have been verified from industrial installations of significant size. Predicted and observed power draws are within five per cent when burden slip and bypassing are not significant. When these are significant (at fills above 15 per cent) the actual power draw will be less than the model prediction. Under these circumstances the quality of the agglomerates will be poor.

Sep 13, 2010

IN all wet concentration processes it is of primary importance to determine to what degree the crushing must be carried in order to obtain the maximum profit per ton of ore milled.To effect a clean separation, either by gravity or flotation treatment, between either one valuable sulphide from another, or a sUlphide from the gangue, the ore must have been subjected to grinding to such an extent that the particles to be separated are completely liberated from each other.Insufficient crushing will result in either an incomplete separation of the sulphides from each other, and thus a loss of the one sulphide in the other, or else a loss of the valuable sulphide in the gangue.This being so, the question arises whether the added cost of extra crushing would be economically warranted by the increased recovery consequent on such a step.

Jan 1, 1927

In the face of intense global competition and other business pressures on coal miners, ongoing quality initiatives and continuous process improvements are needed to enhance business performance. By viewing a minesite in terms of key processes, rather then departments, and employing innovative technologies and better applying organisational resources, there exists enormous potential to achieve reductions in process cost and time.

Jan 1, 1998

By Nicol S. K, Firth B. A

Much effort over the years has been put into the task of devising parameters which adequately assess the metallurgical efficiency of mineral processmg operations. One of the most celebrated of these methods is the so-called "release analysis" method of Dell (1953) which tackles the problem in terms of an ideal separation based on sequential retreatment of the products and tails of a given separation process. Other methods have also been proposed by Jowett (1969) and by Holland-Batt (1971 ). While these procedures are appropriate to multi-component mineralogical separations, they perhaps do not lend themselves to the much more simple two-component systems encountered in coal preparation. However Dell (1962) has suggested the use of the term "specific profit" in coal preparation in order to assess the conditions that give maximum economic gain. Specific profit is derived from data relating washability data with equipment performance and operating costs. The procedure for using this criterion for comparative purposes is therefore somewhat cumbersome as is illustrated by its lack of widespread acceptance in the coal preparation literature.In contrast, an efficiency index, E, which is both simple and meaningful from the utilitarian standpoint, has been proposed by Tsiperovich and Evtushenko (1959a). This index is defined by the relation, E = Yield X Tailings ash/Product ash (1) A cursory examination of this parameter shows that it increases when yield and tailings ash increase and also when product ash decreases; all of which are desirable circumstances in coal cleaning operations.Further, it will be shown that slight variations in operation are amplified by this function which makes comparisons simple and direct.While the use of this index is quite extensive in the Soviet coal preparation literature for some reason it has not received wide usag~ elsewhere.

Jan 1, 1978

Based on relative CO2, N2, and 3He contents, geothermal systems of the Taupo Volcanic Zone, TVZ, can be subdivided into two major groups: arc-type systems, associated with andesitic magmatism along the eastern boundary of the TVZ, and rift-type systems over its western parts. The highly increased N2/3He, CO2/3He and CO2/Cl ratios of the former are ascribed to entrainment of large proportions of volatiles of subducted, marine sedimentary origin. The largely rhyolitic, rift-type magmas are assumed to have formed from volatile-depleted, residual melts. Correlations of Cl and CO2 with heat contents suggest that formation of the two types of source magmas involves mixing of two end member components: a low-volatile melt with a heat/Cl ratio of 25 Ml/mol (0.7 MJ/g), and a low Cl vapor with a heat/CO2 ratio of 5 Ml/mol. On the basis of these values, the heat associated with andesitic magmas is found to be carried in close to equal parts by both vapor and melt; for the rhyolitic melts the proportion contributed from the vapor is only about 2%. The heat/He ratios of the rhyolitic source magmas for the rift-type geothermal discharges from the TVZ of 0.12¦0.05 Ml/pmol is within the range of 0.05 to 0.2 Ml/pmol of the upper mantle. The higher heat/3He ratios for the arc-related magmas of 0.4¦0.2 Ml/pmol are likely to be due to the high proportions of heat carried in the form of a separate, low 3He vapor phase derived largely from subducted sediments.

Jan 1, 1995

By D A. McCallum

With depth, many gold ores become sulfidic with minerals such as pyrite, pyrrhotite and arsenopyrite becoming prevalent. In addition, many underground gold mines use tailings backfill to bind and store the waste. In these cases, acid mine drainage (AMD) can become an issue. One approach to the control of AMD is desulfurisation whereby the sulfide minerals are removed prior to disposal. Four sulfide tailings samples, representing different ore types and gold and base metal operations, were selected for assessment and testing using simple physical beneficiation techniques. The aim was to determine the extent to which mineral processing methods were suitable for separating sulfides from non-sulfides and for extracting potentially marketable by-products from the tailings. In order to streamline the testing procedure a simple diagnostic separation technique was developed to enable quick screening of bulk sulfide tailings for suitability for reprocessing. The testing procedure involved detailed characterisation and a sequential set of testing regimes based on simple unit processes including water washing, classification, gravity concentration, magnetic separation and bulk flotation. The preliminary test results indicate each unit process can play an important part in producing effective sulfide/non-sulfide separations and in generating useful by-products from the tailings. Potential valuable products identified include coarse, benign silica sands, bulk iron sulfide products rich in pyrite and/or pyrrhotite, high-grade iron products (magnetite) low in silica, low-volume bulk sulfide concentrates and low-grade molybdenite and talc products. The work presented shows how sulfide tailings can be viewed as a resource rather than a waste stream, and identifies a pathway for developing a more sustainable approach to the environmental management of sulfide tailings for the future.

Jan 1, 2007

It is proposed to deal with those raw materials which are produced in South Australia to meet the needs of the country's steel industry. They are chiefly, iron ore, limestone and quartz.Iron ore and limestone are fed to the blast furnaces of Newcastle and Port Kembla together with coke to produce the hot metal charge for the open hearth steel furnaces.They are also qsed in the raw state in the steel furnaces to assist in the conversion of the hot metal to steel. The iron ore is quarried from' Iron Knob and shipped from Whyalla to Newcastle and Port Kembla, whilst the limestone is supplied from the deposits at Rapid Bay and shipped in the same manner.Quartz is used in the manufacture of ferro-silicon, an alloy which is added to the ladles of molten metal tapped from the open hearth furnace in the case of almost every grade of steel. It is obtained from a quarry situated between Iron Knob and Whyalla, and shipped to Newcastle.IRON OREWith the exception of several small quarries situated at Breadalbane, Cadia, Cowra, Crookwell, Michelago, Jerrawa and lerraama in New South Wales, the iron ore requirements of Australia's steel industry to date have been met from Iron Knob and the Middleback Range in South Australia.Several of the small deposits in New South Wales were worked during the war years of 1941-44 during the shipping emergency and produced 1,355,417 tons, compared with an output of approximately 43,000,000 tons from Iron Knob between 1901 and 1949.

Jan 1, 1951

By J L. Mauk

 Broken Hills is an adularia-sericite epithermal Au-Ag deposit, hosted in flow-banded rhyolites and overlying rhyolitic pyroclastic rocks in the eastern Hauraki Goldfield. The 7.1 Ma deposit was the largest producer of gold in the eastern Hauraki Goldfield, and was one of very few economic deposits hosted in Pliocene rhyolites. This paper presents the results of a recent study in the upper levels of the deposit. Maps and cross-sections constrain structural and lithological relationships, and the lateral and vertical extent of a breccia pipe û the major feature of the upper levels.   Previous studies in the upper levels of Broken Hills have shown that gold and silver values are concentrated around and within a large breccia pipe, mined by a series of æcaveÆ stopes and in veins. Contour diagrams of Au-Ag data from channel samples indicate that the breccia pipe was a major fluid channel-way for mineralising solutions.   The breccia pipe deposits are part of the dynamic geothermal system that formed the Broken Hills ore bodies; they developed as a result of hydrothermal brecciation in areas of structural weakness within a rhyolite pyroclastic unit that overlies a massive rhyolite lava-flow unit. The main breccia pipe begins near the rhyolite/pyroclastic contact, having the shape of an inverted, inclined cone, and consists of silicified breccia, stringers of quartz, and irregular patches of clay-altered country rock. Smaller zones or pockets of hydrothermal eruption breccia are silicified and contain low grade gold in the matrix and in the adjacent silicified wall rocks.   Quartz has been classified according to its physical characteristics as seen in situ and hand specimens indicate that vein definition decreases upwards, perhaps as a result of changing lithological conditions and/or increasing proximity to the paleosurface. Hydrothermal quartz is widespread as veins and as a replacement mineral, or lining fractures and cavities and overgrowing rock fragments. Breccias contain vein quartz, but some quartz veins cross-cut breccias, indicating that vein and breccia formation was relatively synchronous and overlapped in time.   Disseminated gold-silver mineralisation is associated with vein quartz and silicic alteration of the wall rock within the breccia pipe. The auriferous zones are highly irregular and erratic, and sampling results show a wide range of gold-silver ratios, suggesting that highly volatile physiochemical conditions prevailed during mineralisation.

Jan 1, 2005

The following brief observations on the mineral composition of the Mt. Oxide copper ore are intended to supplement the geological description of that ore-body recently published by Blanchard (2).'" The Mt. Oxide copper mine is situated about 45 miles W.N.W. of Dobbyn, in the Cloncurry district of Queensland (Fig. 1). A representative suite of specimens from the mine was obtained through the kindness of Mr. P. B. Nye, Executive Officer of the Aerial, Geological and Geophysical Survey of Northern Australia, and Mr. Jack Hall, the tributor of the Mt. Oxide mine. The specimens, as shown in Fig. 2, were nearly all from the sulphide zone, between the l04-ft. level and the 300-ft. level. Several additional specimens, together with information which will be referred to later were kindly sent to me by Mr. Roland Blanchard.MINERAL COMPOSITION OF THE COPPER OREThe mineral composition of the ore is relatively simple. It consists essentially of chalcocite, with varying, but minor figures...

Jan 1, 1940

By P Fines, D J. Williams, G W, S Miller

This paper presents the results and findings of geochemical and mineralogical testwork conducted on samples collected from waste rock dumps at two mine sites, located in South Carolina, USA (Site 1) and Sudbury Ontario, Canada (Site 2). Important aspects of the relationship between the physical and geochemical aspects of the dumps are also presented. The overall aims of the project were to 1. determine if the physical and hydrological nature of the waste-rock dumps had any impact on the geochemical and mineralogical characteristics of the dump materials; and 2. to identify key implications for dump construction for ARD control. The results of geochemical and mineralogical tests indicate that the waste rock at Site 1 had undergone significant in-dump weathering and was relatively advanced with respect to ARD evolution. In contrast, the waste rock at Site 2 had undergone some weathering, however still contained a considerable amount of sulfide minerals. Testing also suggested that flushing of oxidation products at Site 2 had been limited, which therefore promoted the storage of oxidation products at the site. In addition, materials that had a D50 particle size in the range of 5 mm to 30 mm appeared to be more readily flushed than samples that had a D50 particle size of 30 mm. This suggested that preferential water pathways may have developed within the dumps at both sites.

Jan 1, 2003

By A R. Proudman, A H. Purvis

The Granites Gold Mine Callie gold deposit is located 550 km northwest of Alice Springs in the Tanami Desert. Gold mineralisation occurs due to a complex interplay of geological factors which include but are not limited to favourable lithology, structure, alteration and quartz veining. High-grade mineralisation, while pervasive under favourable conditions, is highly variable over short distances and is very nuggetty. In contrast, the lithology and geological structures that host the mineralisation are very continuous. Orebody modelling techniques have evolved over time because of a growing understanding of the mineralisation controls. Modelling issues such as sampling and assaying accuracy, modelling method, data density, gold population statistics, geological interpretation and domaining, grade boundary and calculation conditions, and model block size are constantly being reassessed in an effort to increase understanding of the mineralisation controls and modelling accuracy. The evolution of the modelling process in response to increasing data levels and a growing understanding of the mineralisation controls has resulted in changes to the perception of the orebody size and style. This has caused the choice of underground mining method to be revised several times and the process to final mining method selection to take longer than usual. In order to achieve the planned production start-up date of July 1998 the process has been allowed to progress in parallel with development of the underground mine. This paper describes the resource modelling and mining method selection process applied to the Callie underground mine and some of the issues which have contributed to its evolution. Some conclusions that are relevant to the efficient planning and development of new mining projects in general are presented.

Jan 1, 1998

By B Ekberg, R Salmimies, T Kinnarinen, A HSkkinen

The regeneration of the ceramic filter medium used in iron ore dewatering is often done by combining backwashing, ultrasonic cleaning and chemical regeneration. Of these three, the first two are applied more frequently, whereas chemical regeneration is done only when needed, eg once a day. Chemical regeneration of the ceramic filter medium in iron ore processing can involve the use of oxalic acid to dissolve the iron oxide particles. Even while performing simple chemical regeneration, meaning no ultrasound to assist the cleaning, the changes in the performance and in the structure of the filter medium could not be explained solely based on the dissolution or the removal of particles from the surface. Good regeneration results were obtained at 35 and 50¦C, meaning that the final permeability of the filter medium corresponded to that of unused filter medium. Permeability of the medium after regeneration at 15¦C was also good after 12 h, but did fall short of those regenerated at higher temperatures. Changing the acid concentration did not seem to have a significant effect on the regeneration.CITATION:Salmimies, R, Kinnarinen, T, Ekberg, B and HSkkinen, A, 2013. Particle dissolution in the chemical regeneration of the ceramic filter medium used for magnetite dewatering, in Proceedings Iron Ore 2013 , pp 473-478 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By Wilson A. F

The use of stable isotopic measurements as a technique for elucidating the origin and history of the water in hydrothermal fluids is relatively new. Recent studies have emphasized the importance of meteoric water in the formation of many hydrothermal ore deposits including many epithermal gold-base metal deposits which occur in faulted volcanic terrane. Other vein-type gold ores are be- lieved to have formed from fluids of magmatic or metamorphic origin and exhibit characteri stic 6180 values. These values also give information regarding temperatures and the degree of equilibrium. Preliminary oxygen data for some important gold deposits of eastern Australia are evaluated in the con- text of styles of mineralization.

Jan 1, 1980

These may be of interest to members examining the collection of ores, etc., from Mount Lyell, which is a feature of the Victorian Gold Jubilee Exhibition, and may have some value as geological records. No. 7 and No 8 are analyses of samples of footwall rock from the Lyell Tharsis mine. No. 7 is hard, crystalline, fine-grained, and of homogenous structure. It has a dark-red colour, due to ferric oxide (Fig 1); and was taken from a place eight feet east of the ore body and about half way between the 50 feet and 100 feet levels. No. 8 is from the same excavation and from four feet east of the ore body it is softer than No. 7, being easily scratched with a knife-blade, of a deeper dark-red colour, and has a slaty cleavage.

Jan 1, 1902

Gold was first discovered on the Shotover by Thomas Arthur in 1862, and soon there were over 3000 miners working on the river. It has often been called the richest river in the world. Most countries probably have one of these, but it was certainly the richest in New Zealand. In the early days some miners collected as much as 200 oz/d from a sluice box, and the early river gravels must have been extremely rich before the gold bearing terrace gravels were sluiced into the river. Otago produced about 10 Moz out of the NZ total of over 30 Moz. Most of this was alluvial and possibly one third or more came from the Shotover. The extremely cold winter and danger of flooding made it a dangerous river to work. During 1863 when heavy rain melted snow in the high country, the river rose 35 ft overnight and drowned many miners camped on the banks. These hazards still exist and dominate the method of working. The early hand miners cleaned out much of the riverbed, and the advent of the hydraulic elevator enabled deeper parts of the river to be worked over. Extensive sluicing of high terraces also took place particularly around Skippers. Several companies have attempted operations on the Shotover. Many of these were distinctly unsuccessful, such as the suction dredge at Maori Point about 1930 and the Skippers Limited fluming in about 1934. At least two attempts were made to divert the river with the Sandhills cut above Skippers and the Oxenbridge Tunnel down near Arthur's Point.

Jan 1, 1983

By Jensen B, Ofori P, He Y, White E, Stanmore B, Brien M, O&apos

As part of a large AMIRA project, an on-line moisture meter was installed at two mine sites in Central Queensland. This project investigated the factors which control the moisture content of coarse (>0.5 mm) coal from the centrifuges used in conventional coal preparation plants. It was placed immediately after the first centrifuge to isolate the factors pertaining to one machine and its feed.The meter was found to be accurate and precise when compared with manual and mechanical sampling methods. The Grubbs estimator technique indicated that its precision is better than 0.3 per cent at the 95 per cent confidence limit.It has been identified that:1. the variability of the measured moisture contents of coarse coal can be described by normal distributions. Standard deviations of about 0.6 per cent are common; and2. the treatment of the coarse coal on the drain and rinse screens immediately prior to the centrifuge can affect the final moisture content.

Jan 1, 1995

By J Kinal, I Mitchell

Many flotation plants use pH to adjust the pulp chemistry of their system to achieve optimum separation. For example, in a sequential lead/zinc circuit the pH during sphalerite flotation is increased to 10.5 or greater to depress galena and pyrite, thereby improving selectivity for sphalerite. However, maintaining a pulp at a particular pH value does not necessarily provide the operator with an abundance of information regarding the chemistry changes occurring within a plant. This paper provides the reader with a number of pulp chemical observations in several plants, showing that the same trends are noted over time; however, the magnitude of the measured values do change. Further, the changes in magnitude are invariably associated with a change in mineralogy. Thus, is measuring pH enough? Can the Eh, dissolved oxygen and temperature be measured at the industrial scale reliably? And, are these measurements useful?

Jan 1, 2006

A survey has been undertaken of the petrography of North Island greywackes with a particular focus on the occurrence in them of smectite (swelling clay) and chlorite, two minerals that are closely associated, chemically similar, and commonly interlayered with each other. Smectite is the mineral which is a major cause of greywacke aggregatesÆ poor performance. Smectite occurs in post-metamorphic shear zones and in surface weathering profiles over greywackes. This study focuses on the petrography of fresh greywacke rocks.   The occurrence and abundance of smectite and chlorite and their relationship in greywackes is largely a function of the chemistry of the sediment and the maximum temperature that the sediment has been subjected to during diagenesis and/or very low grade (anchizone) metamorphism. Rock chemistry, particularly total iron and MgO, determines the smectite and/or chlorite content in fine-grained greywackes (argillites and siltstones) but chemistry is less influential in sandstones, where at low grades of metamorphism much of the Fe and Mg of the rock is held in unreacted detrital minerals and the mineral constituents of lithic grains.   Four zones which represent different levels of diagenesis and very low grade metamorphism, based on the crystallinity of illite and chlorite in the greywackes, and the proportion of smectite interlayered with chlorite, have been mapped in the North Island. In the anchizone smectite does not appear as a discrete mineral, it is always interlayered with chlorite. In the upper anchizone chlorite contains approximately ten per cent of smectite interlayered with chlorite. In the lower anchizone about 30 per cent smectite can occur in chlorite.   In addition to the smectite and chlorite inherent in the greywackes as the result of the thermal overprint, smectite as a discrete mineral and smectite-chlorite interlayered minerals with high levels of smectite, occur in abundance on shear zone surfaces and in alteration zones adjacent to shear zones; these are the main contributers to the high levels of smectite recorded in many greywacke aggregates.

Jan 1, 2006

The current drill-and-blast method of tunnelling is cyclic and, for this reason above all others, has a future application potential which is lower than that of continuous methods. There is scope for progress in several facets of today's drill-and-blast tunnelling. But even if each of its unit operations and the synthesis of these were to be optimised, this conventional method will, in the long term, fail to be a serious competitor for tunnelboring machines (TBMs), roadheaders and the like. If its role in tunnelling is not to decline at an increasing rate, drill-and-blast will need to be transformed into a continuous system. Boring and cutting machines consume considerable energy (and expenditure) in creating rock fragments which are smaller than those required by muck-handling equipment. In this respect, blasting is more efficient. Mechanical methods are also less versatile and flexible and, when planning proceeds on a basis of meagre or inadequate geological data, cannot be costed as accurately. Currently, research gains for TBMs and roadheaders are greater than those for conventional tunnelling. If (as is likely) the disadvantages of mechanical methods continue to be reduced at a greater rate, the swing away from drilling and blasting will gain momentum.

Jan 1, 1987