Search Documents

The purpose of this work is to determine the equilibrium-state of the aqueous-solution which is produced by the leaching processes, including natural weathering of pyrite minerals. The latter can lead to acid-mine-drainage (AMD). The ferric iron species (Fe3+) resulting from bacteria-catalysed oxidation of ferrous iron (Fe2+), in the presence of water and air, is known to bring about steady-dissolution of minerals chalcopyrite (CuFeS2), sphalerite (ZnS), pyrite (FeS2), and so forth. Good-aeration, relatively high-porosity and sufficient bacterial activity tend to promote leaching in waste-rock-dumps. The composition of the aqueous-phase that accumulates in the pore-space (or in open-pits) is of practical interest as it would strongly influence the leaching of both sulfide and non-sulfide minerals. Since the reactions among the various ionic species occur relatively fast, the solution-phase may be regarded as approaching a state of virtual-equilibrium and it is possible to determine by computation the respective concentrations of the many dissolved species. For the Cu-Fe-H-O-S system, these species may include: H+, Fe2+, Fe3+, Cu2+, HSO4-, SO42-, OH-, CuSO4o, H2O, Fe(OH)+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, Fe(SO4)+, Fe(HSO4)+, Fe(HSO4)2+, and Fe(SO4)2-. The aqueous-system which may be constituted from appropriate mole-quantities of H2SO4, FeSO4, Fe2(SO4)3, and CuSO4 is in fact the result of various natural processes (reactions) and due respect must be accorded to the extents of these reactions. The present model computes the equilibrium molalities of the foregoing ionic and neutral aqueous species, using the iterative equilibrium constant method that ensures strict-adherence to charge-balance and elemental molar-balance constraints. The dissolving sulfide-minerals (FeS2, CuFeS2) consume Fe2(SO4)3, H2O, and O2 and yield FeSO4, H2SO4, and CuSO4 while the aqueous-phase tends to become progressively acidic (declining pH) reflecting the gradual increase in the extents of sulfide-dissolution reactions. The equilibrium-state of the solution-phase is computed for specific set of values for the extents of respective reactions. The temperature and pressure of the system are 25¦ C (298.15 K) and 101.325 kPa (1.0 atm), respectively. The mica-like minerals such as the biotite [H2K(Mg,Fe)3Al(SiO4)3] tend to consume much of the H2SO4(aq), with the extracted K+, Mg2+, Fe2+ and Al3+ ionic species accumulating in the solution. The precipitation of the jarosites (potassium, hydronium, or ammonium) contributes to the removal of ferric and ferrous species from the solution-phase. In the present work, the emphasis is on predicting the compositions of the aqueous- and condensed-phases with advancing time or increasing æextent of reactionÆ. The results of such calculations are compared to published data on raw AMD (acid-mine-drainage).

Jan 1, 2008

By D J. Bradshaw, E M. Wightman, C L. Evans, B Triffett

During the commissioning phase of Prominent Hill, periods of reduced recovery were experienced with higher-grade ore blends. This was unexpected and as part of the process to identify the cause, surveys were conducted in May 2009, with two different ore blends (copper grades: 1.94 per cent Cu (blend 1) and 2.49 per cent Cu (blend 2)). Metallurgical performance was assessed in terms of rougher recovery and grade with consideration of both pulp and froth effects. In addition, hydrodynamic measurements (gas hold up, bubble size, superficial gas velocity) as well as measurements of bubble load and top-of-froth grade were taken during the surveys and full mineralogical assessment of selected streams completed to characterise the nature of the differences. The metallurgical results showed that the lower performance was obtained with blend 2 which contained the higher amount of chalcocite and was higher-grade. Analysis of the survey data showed that for both ore blends more than half of the copper loss occurred in the +38 ¦m size fractions. Almost 30 per cent of the copper in the +38 ¦m fractions that reported to the rougher tails during processing of blend 2 was liberated compared to less than five per cent for blend 1. Additionally almost 60 per cent of the copper in the +38 ¦m fraction of blend 2 was chalcocite compared with approximately 20 per cent in blend 1. This paper discusses the sensitivity of the chalcocite-to-surface chemistry effects causing marked reductions in recovery either through reduced pulp recovery or froth phase (detachment) effects. The reagent suite and operating conditions were subsequently changed and the recoveries increased substantially and the sensitivity to ore changes eliminated. It should be noted that subsequent optimisation work, which focused on recovery improvement, has led to copper recoveries of over 90 per cent being achieved.CITATION:Bradshaw, D J, Wightman, E M, Evans, C L and Triffett, B, 2012. Characterising the reasons for the difference in performance of two ore blends in early processing at OZ Minerals Prominent Hill Operation, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 273-278 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

Indiscriminate surface disposal of coal waste in New South Wales has created a serious fire hazard and increased air pollution.A survey of numerous dumps, as well as particular investigations of one badly-constructed dump, showed that factors conducive to ignition and propagation of fires in waste dumps were high contents of combustible material (coal, pyrite, wood. paper. grease), size segregation leading to ready movement of air and moisture shape of the dump (e.g. protruding sections or porous junctions), high ambient air temperatures, bush fires, and even deliberate lighting.Control methods applied in the past tended to be haphazard and unsuccessful. Under Australian conditions the technique recommended for control of existing dump fires, based on experimental work, is to spray the dump with a chemical fire retardant (e.g. a 2 per cent solution of sodium tetra borate and ammonium phosphate), to cover the dump with a suitable soil, and to seal the surface with a I per cent solution of aluminium sulphate or sodium metasilicate. The recommended method of dump construction to prevent fires is to level and seal the site, to construct a firebreak around the dump area, and to build a rectangular dump with minimum size segregation and compacted surfaces.

Jan 1, 1971

By S C. Dominy

A high nugget effect and the presence of coarse gold characterises many vein-gold deposits. The effective sampling of these deposits is often difficult because of the relatively low concentrations involved and erratic nature of the gold. Geological complexity often compounds this effect. Underground development, in-fill drilling and bulk sampling/trial mining are often required to delineate Ore Reserves. Winzing is an historical technique that was used to gather geological and sampling data during underground exploration. It permits access to the mineralised structure below the current datum to help determine viability. Winzing has always been considered an arduous and dangerous task. Modern technology has led to the development of the Mobile Supersucker, essentially a giant vacuum cleaner. This system permits safe and efficient winzing activities, and allows the collection of bulk samples for grade estimation. Bulk samples from horizontal development have long been collected to help define mineable grade. However, when defining blocks below current development, there has been over-reliance on ineffective æsmall sampleÆ drill data. The Mobile Supersucker permits safe and cost-effective development of winzes and off-winze sublevels.

Jan 1, 2003

The Olympic Dam mineral discovery by Western Mining Corporation (WMC) in South Australia has been shown to contain one of the world's largest known deposits of copper and uranium; gold and silver are also present. Development of the deposit jointly by WMC and the BP Group is awaiting commitment, with planning based on initial production of gold in 1987 and copper and uranium in 1988.

Jan 1, 1985

By Higuchi K, Sekimoto Y

In this report,the results of the large diameter drilling tests in coal seams assisted with water jet are described. The stress relief in coal seams by this new method is as effective as by the conventional method and the penetration speed by this method is 1.5 times as fast as by the other method. 1 Introduction The average mining depth of Japanese coal mines has already attained about 700m from the surface. Almost all coal mines are suffered from occurrence of coal and gas outbursts. To prevent outbursts, some countermeasures are taken generally. In particular, large diameter stress relief borings have been carried out quite often at Akabira coal mine located in the northern part of the Ishikari coal field in Hokkaido,JAPAN. These borings have had successful results but the drilling work of such large diameter

Jan 1, 1987

The difference between a hypothetical and a theoretical approach is considered and the advantages in using a hypothesis is discussed. Virgin horizontal stresses play an important role in stabilising strata which bridge across an excavation, and reduces the tensile stresses which develop in a beam subjected to bending. Simple formulae are deduced for the bridging of a thick massive stratum under such conditions. At shallow depths, tensile failure on the upper side of the beam is the most likely cause of fracture, but below a certain depth this gives place to compressive failure on the underside, with the possible incidence of rock bumps. The presence of strong massive beds delay the onset of subsidence and may restrict the width of the subsidence trough. If the material involved in the caving is strong, this will reduce the final subsidence, especially at shallow depths. The British regulations for the control of aquifers and their dependence on the strain developed at the seabed are discussed. As an alternative, the concept of a disturbance factor is introduced to permit the consider- ation of aquifers at depth, leading to an explanation of the make of water on the first faces to be mined in the Selby Coalfield. 'Elie paper closes with a brief consideration of the different roles played by longwall face supports in the control of readily cavable strata, and the control of strong beds which hold up in the waste.

Jan 1, 1986

The non-metallic minerals, excluding the construc- tions and fuel materials have for long been the "poor relations" of the Mining Industry of New South Wales. The State is self-sufficient in only a few of the industrial minerals and is almost completely lacking in any of the essential fertilizers. The deficiencies must be met by imports from overseas and interstate and in fact New South Wales imports some quantity of every one of the non-metallics. For the year 1967 the value of non-metallic mineral production amounted to only $9,390,000 or less than 3.5% of the States total of $275,900,000 for all classes of mining and quarrying. In roughly the same period, the 1967-68 financial year, New South Wales imported non- metallic materials, valued at well in excess of $22,000,000 from overseas and over $2,000,000 from interstate sources.

Jan 1, 1969

By O Aydan, R Ulusay

Blasting is the most commonly used excavation technique in mining and civil engineering applications. Blasting induces strong ground motions and fracturing of rock mass in rock excavations. Particularly, high ground motions may also induce some instability problems of rock mass and structures nearby. Furthermore, it may cause some environmental problems due to noise as well as vibrations of structures near the populated areas. Furthermore, flyrocks is another major issue for the safety of people and damage to machinery and equipments when blasting is employed. In this study, the authors explore the ways how to estimate the ground motions as a function of distance, amount of explosive, number of holes. The ground motions were measured by stand-alone accelerometers developed by the first author and some empirical relations are developed. The effect of ground motions on the instability issues of benches such as sliding, toppling and rockfalls were investigated. Furthermore, the flyrock issue is investigated and some empirical relations to estimate the maximum distance of flyrocks from the blasting relations are compared and discussed. CITATION:Aydan, O and Ulusay, R, 2018. The ground motions induced by blasting in open pit lignite mines and its environmental effects, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 142–151 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By Ribicic M, Kocar F

Surface lakes or water accumulation present a possible threat for the flooding of the underground mining works. Therefore, the criteria that define the conditions under which no flooding of the mining works can occur are of vital interest to the miners. The authors present the criteria that they developed for the Velenje lignite mine, Yugoslavia, and that take into account the elastoplastic behaviour of the rocks and the natural stresses involved in the deformable strata between the bottom of the lakes and the mine works as well as the extent of the direct caving-in process resulting from longwall mining activity. Fi- nally a generalization of these criteria to the other rock and stress conditions is discussed.

Jan 1, 1988

By Sivell W

We discuss the origin of the Patuki ophiolite complex and the Dun Mountain ultramafics of Middle Permian age in Nelson, New Zealand. It is shown that the Patuki volcanics have strong affinities with tholeiites of mid ocean spreading ridges transitional to alkaline basalts similar to those from fracture zones and ocean islands. At D'Urville Island, typically pillowed alkaline basalts enriched in rare light rare earth elements (LREE) - ophitic spilites - are associated with LREE-depleted (N-MORB-like) tholeiitic spilites with intergranular textures. The metabasalts are associated with a wide variety of sediments, and with sediments are intruded by conformable sheets of serpentinite. Coarsely crystalline mafic and plagiogranitic rocks signify vents and magma chambers, and we propose that the group developed as ocean crust from a slowly spreading mid-ocean ridge, transform association, overwhelmed at intervals by volcaniclastic sediment. Detailed mapping at a scale of 1:5000, and stratigraphic and geochemical development and structural coherence, show that the group is not melange in the Franciscan sense. The Dun Mountain Group, of serpentinites, peridotites, dunites, gabbros and other rocks, intruded the upper Patuki Group as a linear series of aligned pods and sheets. They carried up with them tectonic inclusions of older rock, which were metasomatised, and altered wall-rock, and one low angle dike passed several hundred metres into overl~ing sediment, at moderate temperatures (500 C). The rocks did not act as a floor (and alleged source) for the Patuki, but partly post-dated and were emplaced into Patuki.

Jan 1, 1987

By M Camarda, A Pirson, F Vasconcelos, J Mesquita

ArcelorMittal Prijedor is a goethitic iron ore mine located in the north-west of Bosnia and Herzegovina, which mainly supplies ArcelorMittal’s European subsidiaries. Annual production of the asset stands at the level of 1.5–2.1 million tons of iron ore product which is sent to ArcelorMittal Zenica steelmaking plant. Two types of products with approximately 50 per cent Fe are generated in Prijedor through a process composed by crushing, screening, and magnetic separation stages. Within this process one of the tailings produced is called ‘ultrafines’. The ‘ultrafines’ product corresponds to the desliming hydrocyclones overflow in Prijedor plant, which is classified in a size fraction below 25 μm and corresponds to about 5 per cent of feed. This material is richer in iron than the coarser size fractions of the ore but do not present a good performance in concentration processes. In this way, several studies have been carried out during the last years to find solutions to use the ‘ultrafines’ material without success. In this context, the possibility of dehydroxylate the goethite contained in the material transforming the mineral into hematite and thus increasing the iron grade of the final product was investigated. During the research, several dehydroxylation tests with different temperatures and time of exposure were performed. Using dihydroxylation process at temperatures higher than 800°C it was possible to produce a material with 43 per cent Fe from the original 39 per cent Fe ‘ultrafines’ sample. In addition, the dehydroxylation tests confirmed that goethite becomes completely transformed into hematite at 400°C (with an exposure time of 60 mins) and material is completely sintered at 1200°C. A simulation study based on dehydroxylation tests results showed that it would be possible to use a ‘ultrafines’ product with Fe grade higher than 45 per cent to produce a material with 50 per cent Fe through a complete dehydroxylation process.

Sep 18, 2023

The Myally Beds, Surprise Creek Beds and Mount Isa Group form the upper part of the Proterozoic Western succession of rocks in northwest Queensland. The latter two units are partly equivalent, and are important for their base metal content at Mount Isa and elsewhere. The arenaceous Myally Beds lie unconform- ably or disconformably below the Mount Isa Group and Surprise Creek Beds; they contain four mappable units which were deposited on a broad, shallow shelf washed by east-trending currents. Emergence of the Myally shelf initiated a series of parallel, possibly intra- cratonic, troughs to the east and west. In the east, the Surprise Creek Beds were deposited between the emergent shelf and base- ment rocks, and consist of a shelf and trough facies divisible into 7 and 10 units, respectively. Trough sediments are continuous north-south, and show turbidite character- istics; algal dolomite characterizes the shelf facies. To the west in the Mount Isa trough, an orthoquartzite facies, the Warrina Park Quartzite, defines the base of the Mount Isa Group. Hinge zones between the shelf and trough environments are marked by east-west facies changes, and provide a focus for later major north-south faulting. However, some penecon- temporaneous faulting near Mount Isa is best explained as complex post-depositional faulting of a disconformable sequence. Subsidence and deposition in the Mount Isa trough continued for a longer period than in the Surprise Creek trough, allowing accumulation of lead and zinc deposits in the upper half of the sequence. The Surprise Creek Beds appear equivalent to the lower half of the Mount Isa Group, and are probably not prospective for lead and zinc. Turquoise and possible other secondary copper minerals are widespread in the Warrina Park Quartzite and equivalents in the Surprise Creek Beds, and further investigation of these formations seems warranted.

Jan 1, 1974

By Quintiliani G, Giordano V

A research field of interest and a topical subject with the aim to reduce a considerable amount of coke in ironmaking is the injection into blast furnace stack of hot reducing gas combined with use of auxiliary fuels at tuyeres. In recent years evaluation studies and prelimirfary industrial experiments have been carried out on this subject in Europe and Japan. Even if these experiments seem to confirm the advantages theoretically expected, it appears as useful to cast more light on new problems concerning the improvements of this technique. In this report some aspects are analysed on fluid dynamics of blast furnace process with two gas flows: the main flow coming from the bosh and cross flow of the reducing gas injected in the lower shaft. A research on a blast furnace physical model was made with the aim to obtain information about the phenomena which occur in the full scale blast furnace. This work was carried out on cold models IN and tridimensional) in which the radial gas distribution was experimentally measured. A mathematical model based on gas diffusion was implemented aimed at simulating gas distribution inside the reactor taking into account the number of injection tuyeres. A good agreement between experimental and theoretical data allows for extending results to industrial practice in order to determine operating conditions assuring good performance of blast furnace with high amount of auxiliary fuels.

Jan 1, 1975

Programmes of environmental investigations to identify and minimise impacts and satisfy government and community requirements have become an integral and rate determining component in the planning and development of new mines in Australia. This paper reviews the essential features of the environmental project management Function.

Jan 1, 1983

By P Yß±ez, G Ferguson

The El Teniente mine produces more than 340 000 tonnes of fine copper per year from an industrial complex of underground mine, concentrator and smelter. Mass caving methods are employed to deliver approximately 95 000 tpd of ore to the mill, from a number of sectors underground, each sector being in effect a large-scale mine in its own right. This mining activity has faced challenges over the course of the last century such as:the capacity of the underground mine has been expanded to maintain and increase output of fine copper; the increasing size of the ore fragmentation forced to change the mining method to achieve the high productivity and profitability required in the business; and to modify the mining methods to continue mining at depth with safety. Fundamental activities in these mining methods, for the successful initiation of caving and subsequent draw, are:undercutting the base of the block or panel by blasting; and excavating of drawbells. The undercutting design evolves mainly on the height of the blasting to manage the change on ore fragmentation. The methodology move away from incorporating massive areas, typical of the block caving method, to a continuos blasting, typical of the panel caving method. Drawbell design changes on geometry, dimensions and sequence of excavation to deal with a corse ore fragmentation and the resolution of mining difficulties in the form of major rock bursts and collapses of production facilities. This paper focuses upon the evolution of the undercutting and drawbell design used at El Teniente mine and techniques under consideration to deal with future caving operations to provide the bulk of the daily production for the foreseeable future.

Jan 1, 2000

By R T. A MacGillivray, S B. Curtis

Bacteriophage (phage) are viruses that infect bacteria. Protein coatings on the surface of the phage particle can be genetically engineered so that they bind to inorganic molecules. The filamentous phage particle is about 930 nanometres in length and 6.5 nanometres in diameter and consists of a single-stranded molecule of DNA surrounded by five different coat protein molecules denoted P3, P6, P7, P8 and P9. Peptide sequences in the P3 coat protein that bind to sphalerite and chalcopyrite have been identified. The binding is selective; phage with specific P3 peptide sequences bind to minerals but do not bind to silica or to pyrite. Two peptide sequences in the P8 coat protein that bind selectively to chalcopyrite and pyrite have also been identified. The amino acids in the P8 binding sequences are hydrophilic and thus a coating of a mineral particle with phage having these peptide sequences may render the particle hydrophilic. Experiments are underway to confirm this. Phage are relatively easy to grow and are not living organisms requiring an energy source to maintain life. Phage can also tolerate a range of pH and temperatures. Given this, and the ability to indentify phage coat proteins that bind selectively to a variety of inorganic molecules, phage have the potential to be useful tools in mineral processing and waste treatment.

Jan 1, 2008

British Coal's Selby Complex is the newest producing mine in the United Kingdom. The reasons behind its origins, planning and design are explained. Some detail is given of equipment used, with the emphasis being placed on the unique features of its layout. The entire project has been planned and constructed over many years and the design has consequently changed, principally in response to the geology of the coalfield and improving technology. In spite of many totally unexpected difficulties, the mine, which is not yet in full production, has the highest productivity in the United Kingdom.

Jan 1, 1991

This paper considers two particular empi- rical models for the processes of the generati- on of hydrochemical zoning and epithermal near- surface mineralization of mercury-antimony-arse- nic formation in the discharge area of the Uzon Caldera ore generating hydrothermal system in Kamchatka. Vertical and horizontal hydrochemical zo- ning is caused by mixture of infiltration waters of the surface formation with fluid of chloride- sodium composition which are supplied up the-zo- ne of deep fault. Ore formation is caused by simultaneous existence of two geochemical barriers, namely oxidizing and reductive. The first barrier is determined by the-level of ground waters. The second one forms under the clay-opal screen un- der the influence of two factors, namely the inflow of deep reduction sulphur compounds (which are transported together with arsenic, antimony and mercury) and the generation of hyd- rogen sulphide as a result of sulphur- and sul- phate reduction. X-ray-amorphous phase of orpi- ment composition and realgar phase are formed, respectively, on the oxidizing and reductive Barriers.

Jan 1, 1987

By Brennan D. J

The trend worldwide is for increasingly stringent control of sulphur dioxide emissions to the environment. It is therefore likely that Australian industry will be placed under increased pressure to restrict such emissions, and this will have implications for Australian smelters of mineral sulphide ores. Traditional outlets for sulphur dioxide emissions have been in sulphuric acid manufacture, but Australian demand for sulphuric acid has declined markedly in recent years. This paper examines the balance of supply and demand for sulphur and related products in Australia, the shifts occurring in that balance and the underlying causes of those trends.

Jan 1, 1994