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By Benoît Plante

La mine Tio (QIT Fer et Titane Inc.) exploite à ciel ouvert un gisement d?ilménite massive depuis 1950, générant jusqu?à maintenant plus de 70 Mt de roches stériles potentiellement génératrices de drainage neutre contaminé (DNC), dont une partie est submergée dans le lac Petitpas, au nord de la mine. Si généralement l?ennoiement des rejets miniers a un effet bénéfique pour limiter la contamination des eaux, cela reste à prouver pour ce qui est des stériles générateurs de DNC. Des essais en réservoirs ont été réalisés afin d?évaluer la réactivité de trois différents types de stériles submergés, qui ont été choisis en fonction de leur teneur en ilménite. Afin d?évaluer l?impact de la matière organique sur la réactivité des stériles submergés, chaque type de stérile est étudié en immersion simple ainsi que combinée à des sédiments prélevés au lac Allard, à proximité de la mine, d?où l?eau utilisée dans les essais a aussi été prélevée. L?évolution des teneurs en Ca, Mg, Si et Ni durant les 8 premiers mois d?étude démontrent que les stériles immergés sont réactifs, mais l?impact de la matière organique demeure pour l?instant difficile à préciser. Tank tests on Tio mine waste rock The Tio mine (QIT Iron and Titanium Inc.) exploits a massive ilmenite ore as an open pit since 1950, producing over 70Mt of potentially contaminated neutral drainage (CND)-generating waste rocks. While the underwater disposal of mine wastes generally show a beneficial effect on water contamination, this method still needs to be approved for CND-generating waste rocks. Tank tests were realized in order to evaluate the reactivity in underwater conditions of 3 different waste rock types, chosen with regards to their ilmenite content. In order to evaluate the impact of organic matter on the reactivity of underwater waste rock, each waste rock type was studied in simple immersion and in combination with sediments sampled at Allard lake, located near the mine, where the water for the tests was also sampled. The evolution of Ca, Mg, Si and Ni during the 8 first months of testing show that the waste rocks are reactive underwater, but the impact of the organic matter is till hard to define.

Nov 1, 2008

By M. N. Brodie

"The ability to adjust the speed of a SAG mill offers benefits to the process and to equipment maintenance. It can be provided with some slight effect on availability ranging from somewhat enhanced to somewhat reduced, depending on the particular equipment that is used. Several techniques have been developed for monitoring the magnitude of the contained charge, and several algorithms have been used to control mill feed rate and mill speed. The various benefits and the means by which they can be realized are examined and compared. Reasons for Variable SpeedProcess RequirementsThe recovery of minerals from ore is dependent on particle size and residence time in process. Separation in a given plant is most efficient at a particular rate and a particular size (e.g., 80% minus 200 mesh). If the particle size increases, less mineral will be liberated. If the particle size is significantly reduced, the process of choice may not be able to effect separation, and power, media, and maintenance costs would be increased.If a SAG mill-ball mill combination delivers the desired throughput at the correct size for efficient separation when processing ore of the design hardness, some adjustment must be made to maintain this condition when the ore changes. The processing of ore softer than design will result in overgrinding, unless:• the throughput is increased inversely to the change in hardness which lowers recovery by overloading the separation facilities;• or the SAG mill feed rate remains constant, but the speed is reduced to feed coarser material to the ball mill for finish grinding to the desired size.There is also the effect of changing milldiameter to consider. A nominal 36 ft diameter SAG mill will have an effective diameter of 35 ft with new liners and 35 ft 6 in. with worn liners. A mill designed to operate at 0.76 p.u. (per unit) of critical speed with new liners (9.84 rpm) will be changed to 0.765 p.u. with worn liners. If 0.76 p.u. is the desired value, the mill speed should be reduced to 9.77 rpm."

Jan 1, 2003

By Jorgen Elbrond, Yve Lizotte

"A mathematical procedure for determining the underground mining level layout which minimizes the total costs of excavation and haulage is described. This procedure has the advantage over previous graphical procedures of being easily amenable to microcomputers. The paper demonstrates through examples how the procedure can be applied to minimizing discounted costs of level layout as well as providing the optimal location of a production shaft.IntroductionIn recent years there have been numerous publications in mining journals concerning the minimization of mine haulage costs. With the rapid escalation of energy costs during the last decade it is not surprising that several studies applying queuing theory, simulation and mathematical programming to mining related transportation problems have been successfully undertaken. Because of the increasing availability of various sizes of computers these techniques have gained considerable popularity as evidenced by the numerous commercial packages presently being marketed.The publications concerned with haulage cost minimization are generally concluded along the lines of ' ... haulage costs at production rate x will be minimized by assigning y units to location z...'. Details about the route followed and whether it guarantees a minimization of costs are seldom considered. Route data has to date been manually resolved and used for input to developed programs. It would appear that no program has been developed to date which simultaneously minimizes costs by both fleet assignment and routing network resolution.Another important factor in transportation problems is the investment cost associated with the routes; road construction costs or, in the case of underground levels, drift excavation costs. Except for special cases the transport network which minimizes haulage costs only will not provide a minimum excavation cost solution.Zarnbo(1) illustrates by graphical and mathematical procedures how central 'facilities' can be located to simultaneously minimize investment in the transport network and haulage costs. Unfortunately these procedures and others recently applied to mine haulage problems do not provide solutions to the generalized problem. Also because these procedures are geared to graphical solutions and hand computations whereby certain possibilities can be 'visually' eliminated, they can be tedious to program and present storage capacity constraints with current microcomputers."

Jan 1, 1985

By D. S. Flett

"The current state-of-the-art of chloride hydrometallurgy for treatment of complex sulphide bulk concentrates is reviewed. General considerations regarding the various flowsheet steps are examined and options discussed. Then, individual flowsheets are presented and discussed. Finally, the forward prospects for chloride hydrometallurgy for treatment of complex sulphide bulk concentrates is considered and conclusions drawn concerning the likely application of this technology in the future. IntroductionHydrometallurgical processes for treating sulphide concentrates, in general, have received considerable attention over the last three decades or more. Many flowsheets have been developed, many pilot-plant studies have been undertaken and several processes are now successfully operating. For example, direct ammoniacal pressure leaching has been used by Sherritt Gordon Mines since the 1950s to extract nickel from pentlandite concentrates, the roast-leach-electrowin route is widely used to recover zinc from sphalerite concentrates and direct sulphuric acid pressure leaching of sphalerite concentrates has been successfully commercialized. Also, Duval Corporation operated a direct cupric/ferric chloride leaching process (Schweitzer and Livingston, 1982) with electrowinning to recover copper from chalcopyrite concentrates, this process (now closed) being the only chloride process which has been commercialized for a sulphide flotation concentrate. Despite these developments, it has long been considered, particularly for copper sulphide concentrates, that direct hydrometallurgical processes are in the main unlikely to be able to compete successfully with smelting for large-scale operations of simple high-grade single metal concentrates. As long as such concentrates can be produced commercially, smelting is likely to remain the principal processing route (Flett, 1981). This view is being challenged nowadays through pressure leaching developments made by Dynatec and CESL in Canada and the recent start-up of the Western Metals Gunpowder plant at Mt. Gordon in Queensland (Flett, 2000). Complex sulphide ores offer even greater opportunities because of the ability to produce a bulk sulphide concentrate from the complex sulphide ore with considerably higher metal recovery than is often possible from the production of individual metal sulphide concentrates from differential flotation. Interest continues to focus on hydrometallurgical solutions to these processing problems, particularly with regard to chloride hydrometallurgy. This paper, therefore, reviews current state-of-theart with respect to chloride hydrometallurgy"

Jan 1, 2002

By Michel Dagbert

"This paper illustrates the different ways grade-tonnage curves can be generated f or a mineral deposit. It emphasizes systematic discrepancies between reality, estimates and actual production according to different estimation methods and grade control programs. It does not offer a universal solution to the prediction of grade-tonnage curves. Hopefully, it will inspire caution to mineral economists who use estimated grade and tonnage data in the establishment of an optimum cut-off grade for a mining operation.IntroductionThe value of a mineral development venture often depends on a grade-tonnage curve. Statistics can help. The idea is to divide mentally the orebody into small blocks called selective mining units or SMUs. A SMU is an idealized version of the quantity of rock the grade of which will be tested against the cut-off at the time of mining. It could be as small as a truck load or a shovel load in very selective operations like some uranium mines where radiometric probing of each truck or car is performed. More typically, in an open pit operation, it will be the smallest zone flagged as ore from blast hole data, e.g. a 5 m by 5 m by 10m block, if blast holes are on a 5 m grid and bench height is 10m. Having defined the SMUs, the grade-tonnage curve determination amounts to evaluating the grade distribution of all the SMUs that can be mined in the depo sit. If we know this distribution we simply apply the cut-off to it and we get the number of SMUs above the cut-off (i.e. ore tonnage) and their average grade. .Assessment of the grade distribution of SMUs from exploration drill hole data is not an easy exercise and much has been published on the subject (David, 1972; Marechal , 1972; Huijbregts, 1975; Marechal, 1975; Guibal and Touffait, 1982). In this paper, we use a gold mine example to illustrate the influence of SMU size on the results. With the same example we also show that ""common-sense"" methods of grade-tonnage curve determination can sometimes be misleading."

Jan 1, 1987

By J. Chlan

"Dryer DescriptionProctor and Schwartz Continuous Conveyor DryerThe Proctor and Schwartz Continuous Conveyor Dryer has been in operation since July 1958, and comprises six unit• - an 8• wide single conveyor with roller extruder, insulated housing, type 304 stainless steel circulating and exhaust fall system, steam heating coils, temperature controls and discharge crusher rolls. Entire dryer dimensions are 52’ x 12'0""weighing 53,000 lbs,Extruder rolls - setting is 1/8"" (Drive 3 HP 1800 RPM) clearance off the extruder screen.Conveyor - consists of 151 interlocking pans, measuring 8"" x 8' (2 HP 1200 RPM) One Exhaust Fan (5HP - 900 RPM)Steam Coils -- l"" steel pipe - with steel fins -- each coil measures 16' 2’’- 64 coils in the No, 1 Compartment- 64 coils in the No, 2 CompartmentDryer OperationThe yellowcake slurry at 28% solids is pumped to an 81 x 8' Peterson Filter. The filter media presently being used is a Neotex 4372 blanket, being 100% staple fibre nylon, 12 oz per square yard with air porosity of 9 CFM's. The cake discharge at 45 - 50% moisture falls into the roller extruder. Extrusions are formed by forcing the material by rolls through a perforated plate moving back and forth and depositing the spaghetti-like extrusion on onto the dryer-conveyor.The conveyor now carries the extruded material through the heating chamber•, The feed end of the dryer will be referred to as No. 1 Compartment, with temperature control set at 280""F. The circulating fans take the hot air off the coils and circulate the heated air through the perforated openings in the dryer conveyor pane, After passing through the set of steam coils and circulating fan in No, 1 Compartment, the material then goes through No, 2 Compartment where the temperature is set at 305'F, Final material then discharges through a set of crusher rolls set at ~"". Moisture of final dried product runs at less than 2%.The dryer conveyor load is usually run to a 3"" - 4"" depth load. Conveyor speed at approximately 90 minutes for load to pass through. Load onto the conveyor is controlled by boot level and speed of the 8' x 8' filter. The dryer steam coils are water-washed twice a month."

Jan 1, 1972

By Peter Heine

Diavik Diamond Mines Inc. (DDMI) has treated systems development as an integral part of the construction project when it built Canada?s second diamond mine. Fully aware that the proper collection and processing of operational data is needed to drive business decisions during production and planning, key Performance Indicators (KPIs) were defined to effectively manage operations when the mine went into production. The Production Information Management System (PIMS) allows KPIs to be measured, reported, and transferred to other systems in a reliable and convenient manner. PIMS provides a mechanism to collect real time production data from the various control systems around the site and acts as a tool to ?drill-down? and establish the important cause-effect relationships that impact the value of a KPI. Thus PIMS provides a data collection, storage, management, and an environment in which cause-effect relationships can be analysed and statistically verified. This understanding of the real cause-effect relationships, close to the source of the data and in the context of the operation, can be used to improve both operations and maintenance performance. The PIMS includes the PI Database implementation, its associated external interfaces with the various Control Systems, Cleaning Packaging Weighing System, Environmental System, Enterprise Asset Management (EAM) System, and Diamond Tracking System (DTS), as well as laboratory data collection, custom applications (downtime tracking, data reconciliation) and user clients. The interface with the EAM system provides material flow quantities and equipment availability on which the plant performance reports are based. The transfer of equipment usage to the EAM system is fed into the maintenance notifications and work orders functionality in the EAM. The environmental system interface provides the mechanism for capturing water consumption data required to generate the various regulatory reports. The interface to the cleaning-packaging-weighing system provides the mechanism for capturing batch data for transfer to the DTS for diamond product tracking at the production splitting facility in Yellowknife. The PIMS lab application provides a means of getting sample data into the system for critical metallurgical metrics, and the data reconciliation application provides a means of manually verifying the data before it is published or passed onto other systems.

May 1, 2003

By P. Amelunxen, E. Herrera, L. Hill, J. Vanderbeek

It is well-known that the particle breakage mode that occurs in a semi-autogenous mill is significantly different from that which occurs in a ball mill, enough so to warrant very different lab scale breakage tests and scale-up models. This phenomenon, at the plant scale, leads to changing process constraints depending on the particular properties of the ore. For example, hard or coarse ores might bottleneck the SAG/AG mill throughput, while the ball mills might constrain throughput when milling soft or fine ores. Because the power draw of a ball mill is fairly constant compared to that of a SAG/AG mill, periods of SAG/AG mill bottlenecks lead to increased ball mill circuit specific energy consumption and a finer grinding circuit product size, which together constitute a loss of efficiency of the overall process. Because HPGR circuit throughput is less sensitive to changes in ore hardness, this situation is less common or severe in those circuits. Furthermore, the ball mills are somewhat decoupled from the upstream crushing circuits through the use of surge bins, which also helps to mitigate this effect. As a result, ore hardness variability constitutes a significant cost penalty that should be applied to SAG mill/ball mill/pebble crusher SABC circuits when evaluating the relative economics of different grinding circuit configurations. Nevertheless, the issue is by-and-large ignored, because most current HPGR trade-off studies are based on averaged ore hardness parameters. This paper provides an estimate of the magnitude of this penalty for a typical operation by using Monte Carlo simulation methods and plant data from Freeport-McMoRan’s autogenous, semi-autogenous, and HPGR-based comminution circuits. A case study from an in-house 96K t/d sulphide project is presented to illustrate the concept. It was found that by including variability effects, the trade-off NPV of the HPGR circuit over that of the SAG mill circuit increases to $84 million from negative $33 million, effectively reversing the original decision of selecting a SAG mill circuit for the fixed hardness case.

Jan 1, 2012

By John Keay, Douglas R. Shaw, Gregory J. Olson

"The results are presented herein of on-going laboratory investigations of heap bacterial oxidation as a pretreatment method for the recovery of sulfide-encapsulated gold from ore samples of the Rhodes Mining Lahoca deposit, located in northern Hungary. The ore contains just over 2 g Ault and as much as 6% sulfide, mostly as pyrite. Laboratory aerated column tests conducted at Colorado Minerals Research Institute (CMRI) showed that mild to moderate biooxidation of the finely crushed ore occurred rapidly in approximately three months, with cyanide gold recoveries of up to approximately 60%. The results contrast cyanide gold recoveries of less than 30% from non-pretreated ore. Mineralogical examination of biooxidized residues indicated that the mechanism of biooxidation of crushed ore was related to microorganisms following pathways along structural anomalies in the pyrite grains. Such selective biooxidation is an important result to minimize the biooxidation and aeration time and effluent neutralization costs in a commercial operation.IntroductionThis paper describes the development of a heap biooxidation process for the Lahoca gold project The Lahoca deposit is situated in northern Hungary, at the site of a former copper mining area. Lahoca is a large tonnage, relatively shallow, deposit amenable to open-pit mining Lahoca has the potential to produce I 00,000 ounces of gold annually for at least ten years at its minimum reserve base.The laboratory test work conducted initially by Rhodes Mining NL demonstrated that the Lahoca refractory ore is amenable to whole ore and concentrate oxidative pretreatment and cyanidation. Capital and operating costs, however, for such milled ore treatments were considered relatively high. Rhodes Mining subsequently evaluated heap leaching methods, particularly heap biooxidation pretreatment, as a process route that promised superior economics suitable for exploiting lower gold grade refractory ores.This paper focuses on the laboratory column (simulated-heap) biooxidation test work, particularly the proposed mechanism of selective microbial oxidation, wherein only a small amount of the sulfides are oxidized sufficient to allow commercially acceptable gold recoveries by conventional cyanide heap leaching. Selective or minimal biooxidation of sulfides is considered important to minimize biooxidation time and aeration requirements, as well as acid effluent neutralization costs."

Jan 1, 1998

By T. Bhambhani, O. Yavuzkan, D. R. Nagaraj

"Cu ore bodies commonly contain oxide Cu at the surface, with sulfide Cu content increasing with depth. The recovery of oxide Cu minerals by flotation is a longstanding challenge in the minerals industry, especially for high acid-consuming ores which would not be economical for direct acid leaching. Current practice of oxide Cu recovery involves sulfidization (often using controlled potential sulfidization or CPS) using NaSH (or Na2S) followed by flotation using traditional sulfide collectors. CPS has shown to improve recovery of oxide Cu but has the following limitations: a) HSE issues with NaSH, b) high consumption of NaSH, and c) inability to recover certain oxide Cu minerals because they are refractory to sulfidization. The oxide Cu flotation is further complicated by the presence of certain non-sulfide gangue minerals which adversely impact both recovery and selectivity.Over the past eight decades, numerous collectors have been proposed and evaluated for the direct flotation (i.e. without sulfidization) of oxide Cu minerals, the most researched of which is alkyl hydroxamate. While there are numerous publications dealing with the fundamentals of interaction of alkyl hydroxamates with single minerals, there are few publications which discuss the practical aspects of alkyl hydroxamate use in ore flotation, particularly their use with sulfidizing agents. Case studies in this paper include methods to identify optimum combinations of sulfidizing agents and oxide collectors to maximize recovery for various types of ores. It was observed that some ores do not require any sulfidization, while others require at least partial sulfidization to improve efficacy of AHX. Depending upon the ore type and mineralogy, recovery improvement in the range of 5 to 15% units, over and above that achieved with CPS, has been observed with the use of AHX. For ores requiring high dosages of NaSH, it was shown that AHX can be used to reduce the NaSH consumption significantly. The challenges associated with the presence of non-sulfide gangue minerals in oxide copper ores are included, and the use of modifiers to alleviate the associated problems and enhance the performance of AHX is discussed."

Jan 1, 2016

By K. J. Brouwer, J. P. Haile

"Construction of the first stage of the tailings disposal facility for the Montana Tunnels Project was completed in October 1986. The project is located 37 km south of Helena, Montana, and involves mining of42 million tons of weathered diatreme are at a rate or 13 500 tpd to produce a gold/silver dore, as well as lead and zinc concentrates. The tailings disposal facility for the project includes a fully drained tailings impoundment for storage of the tailings solids, and a process waterpond for storage of all decanted water prior to recyling to the mill. The over-all facility is designed to achieve the basic objectives ofminimizing seepage to the environment in the short- and longterm, and achieving a fully drained stable tailings mass suitable for immediate reclamation on completion of mining. Specific features of the design include a soil bentonite seal and drainage system within the tailings basin, a free draining embankment with a design flow-through capacity of 4000 US gpm and an ultimate height of 230 ft (70 m), and a soil bentonite lined make-up water pond with a capacity of 420 acre-feet (530 000 m'). The tailings will be discharged in a rotational sequence through multiple spigot offtakes to achieve a thin-layer low energy laminar flow. This 'sub-aerial' deposition results in higher stored densities and maximizes liquid-solid separation on the tailings beaches. The over-all design played a major role in the successful permitting of the project, and was significantly cheaper than a conventional wet disposal system, with overall unit costs for tailings disposal of less than US$0.36 per ton.This paper outlines the site characteristics and the tailings material properties and their influence on the design. Extensive use was made of naturally occurring free draining materials as well as bentonite modified soil liners within the tailings basin, embankment and retention ponds. General construction procedures for the various components are described, as well as on-going construction requirements utilizing materials from the open pit. Finally, the over-all costs and unit costs for tailings disposal are presented."

Jan 1, 1988

By G. M. Ritcey, S. H. Lucas

"On the north shore of the St. Lawrence River, in Quebec, are located orebodies of low-grade titaniferous magnetite. The Quebec Mining Exploration Company (SOQUEM), who have an interest in the deposits, believed that beneficiation of the could generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility. A joint research project of SOQUEM and CANMET investigated alkaline roasting of a magnetic concentrate, followed by leaching of the calcine and separation and recovery of Cr and V by solvent extraction. Aluminum was recovered by precipitation.The present paper describes the roast-leach bench-scale and pilot-plant work leading to the development of the optimum conditions f or the integrated process.A plant flowsheet was developed for the treatment of 5 x 106 tons of magnetic concentrate per annum. Estimates of capital and operating costs were made.Based on a recovery of approximately 90% V, 85% Cr and 75% AI, the total hydrometallurgical plant fixed capital costs, including mining, concentration and shipping, are estimated at $1.021 x 109; the operating costs are estimated at $131.92/ton concentrate. Annual revenue from the Na2CrO4.H2O, V2O5 and A12O3 produced is calculated to be $421 x 106.IntroductionThe Quebec Mining Exploration Company (SOQUEM) acquired in 1968 an interest in four titaniferous magnetite orebodies located in Eastern Quebec. 85 miles north of Mingan on the north shore of the St. Lawrence River. The Mingan deposit, with an estimated tonnage of one billion tons, has a reported average grade of 43% Fe, 6.3% Ti , 1.60% Cr, 0.19% V and 6.1% Al with minor amounts of nickel. SOQUEM, on the basis of previous bench-scale data, believed that the recovery of chromium, vanadium and alumina by alkaline roasting would generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility on the coast. One of the approaches selected by SOQUEM for beneficiation of the ore consisted of a combination of magnetic concentration followed by alkaline roasting of the calcine."

Jan 1, 1980

By Deni Côte, Marcel Vallée

"The Guide to the Evaluation of Gold Deposits reviews the successive evaluation steps in the domains of geology, engineering, and economics. The Guide analyzes, in a systemic perspective, the sequence of exploration, development, and evaluation work required to bring a mineral deposit to production. The aim is to identify the metal/mineralization losses and ore dilution that each work step contributes to the evaluation and mining process. The procedure allows one to maximize the income and profits of a mining operation, and to reduce the risks of financial losses tied to investment decisions in the mining sector. For greater efficiency, the criteria of reserve estimation and classification should be integrated with the evaluation steps and methods. At earlier stages of deposit development, when quantitative knowledge is available mainly on the geological axis, the term ""delimited mineral deposit"" should be used. The term ""reserve"" should be used only in an operating mine or in a mining project, when information in the geological, engineering, and economic domains is adequate to ensure technical and financial feasibility. ""Reserves"" are by definition ""mining reserves"". Each category of proven/probable reserves and measured/indicated deposits should be subdivided into two classes to express better the many steps of mineral valuation. The category of ""possible reserves"" shall be replaced by that of ""inferred mineralization"". This system, derived from the Australasian Code, can easily be integrated into current practices of the exploration and mining industry within a short timeframe. The proposal to develop the use of the margins of error of the estimates at a confidence level of90% should be viewed in a longer timeframe. Establishing the precision of the mineral inventories and distinguishing between categories and classes by means of the margin of error will require more work and a longer break-in period.SOMMAIRELe ""Guide d’évaluation des gisements d'or"" analyse, dans une approche systémique, les travaux d'évaluation et de mise en valeur des gisements minéraux dans l'axe de la géologie, dans l'axée l'ingénierie et dans I ‘axe de l'économique. L’objectif est d'identifier la contribution aux pertes de métal et à la dilution du minerai des diverses étapes de l'évaluation et de l'exploitation du gisement. Ceci aid erra à maximiser les revenus et les profits, et ainsi, à réduire les risques départe financière que comportent les décisions d'investissements dans le secteur minier. Pour atteindre ces objectifs, iI est essentiel de relier les critères d'inventorie et de classification des réserves aux méthodes d'évaluation des gisements. Aux stades antérieurs du développement minéral, lorsque les connaissances quantitatives ne s'étendent qu’à l'axe géologique, le terme ""gisement délimite"" sera utilisé. Le terme ""réserve"" ne sera utilisé que dans une mine en exploitation au dans un projet minier, lorsque l'information dans les axes de la géologie, de l'ingénierie et de l'économique sera appropriée pour en garantir la faisabilité technique et économique. Chaque catégories des réserves, prouvée et probable sera subdivisée en deux classes pour mieux qualifier les niveaux d'évaluation du projet. La catégorie actuelle des réserves possibles sera remplacée par celle des ""minéralisations inférées"". Plusieurs essais démontrent que le système propose, qui s'inspire du Code australasien, peut facilement et rapidement s'intégrer dans les pratiques de l'industrie. II pourrait également contribuer à une standardisation des méthodes et des nomenclatures à l'échelle internationale. La proposition d'utiliser les marges d'erreur des estimes au niveau de confiance de90%pour caractériser les estimations se situe dans une plus longue perspective. Cette application demandera des développement méthodologiques additionnels ainsi qu'une période de rodage."

Jan 1, 1992

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

By M. F. Lopez, A. J. Mattus, S. B. Magid, D. B. Mobbs

"The use of Caro's acid as a replacement for hydrogen peroxide for the oxidation of vanadium prior to solvent extraction resulted in a 56% reduction in oxidant usage when compared on an equivalent hydrogen peroxide basis. Comparative oxidation tests, using two actual uranium mill raffinates, resulted in premature precipitation of an amorphous ferric vanadate when hydrogen peroxide was used to oxidize one of the raffinates containing a high iron to vanadium ratio. The use of Caro's acid eliminated the precipitation problem, thereby permitting the adjustment of the raffinate pH to a higher, more favourable level prior to solvent extraction.Potentiometric characterization of the raffinates revealed that vanadium is responsible for the inefficiency of hydrogen peroxide compared with Caro's acid, with the oxidation efficiency of iron being the same for both oxidants. A limiting potential between 720 and 740 mV was observed when using hydrogen peroxide, while, when using Care's acid, potentials approaching 1200 mV were achievable.A four-stage, countercurrent extraction performed on the oxidized raffinates did not reveal any operational problems. The extraction efficiency and the extraction coefficient were found to be higher when Caro's acid was used as the oxidant, as opposed to hydrogen peroxide.IntroductionMost vanadium is recovered as a by-product of some other process: leaching of Carnotite uranium ores, oil fly ash, phosphate rock or chromite processing. The major source of vanadium has been from uranium mills incorporating acid leaching of Carnotite ore s at elevated temperatures and pressures. The by-product recovery of vanadium from uranium ores of the Uravan Mineral Belt, located in the Colorado Plateau , is a common occurrence when vanadium recovery is economically viable."

Jan 1, 1983

By Hu Harries

WE RECENTLY completed a study for a client, who is an applicant to export gas from the Province of Alberta, on the effects of gas export on Alberta's economy. This study was part of the client's application ?before the Conservation Board, and, no doubt, some of you are familiar with it. Submissions by other applicants in earlier hearings before the Board and before the Royal Commission on Energy, as well as claims made by parties opposing export, have also brought forward a number of other opmwns regarding possible economic effects. Ali of these studies have been on a piecemeal basis. They have dealt with particular aspects of particular applications, and only indirectly and by inference with the overall question of gas ex-port. We have prepared this paper to review the overall picture and ex-amine, as far as time permits, all sides of the question. While the paper is entitled Economic Effects of Gas Export on Alberta, we felt that the area considered should in-elude northeastern British Columbia, not only because Westcoast, the first major gas export project, is essentially a northeastern B. C. project, but because this area has historically been, from the point of view of economic, if not of political, geography, part of Alberta. In this paper, when we talk of export, we mean export from the Province or, in this case, from Alberta plus northeastern B. C. Sales to other parts of Canada have exactly the same effect on the economy of this area as l1ave sales to the United States, provided, of course, they are made on equal terms.

Jan 1, 1958

By J. Desroches, J. Burghardt, B. Lecampion, A. P. Bunger

"We present detailed comparisons between theoretical predictions and experiments for the initiation of radial hydraulic fractures transverse to a wellbore. Most of these experiments provide a measure of the time evolution of pressure, length, opening and flux entering the fracture during the test. We compare all these measurements simultaneously to our theoretical predictions, thoroughly testing hydraulic fracture initiation theory, which is shown to be predictive. These comparisons notably emphasize the difference between the initiation pressure (the wellbore pressure for which the fracture initiates) and the breakdown pressure (a misnomer which simply corresponds to the maximum pressure recorded during the test). INTRODUCTION In this paper, we will compare hydraulic fracturing laboratory experiments performed in different tight materials (PMMA, cement, shale) with the predictions from a numerical solution of the governing equations of hydraulic fracture mechanics (e.g. Geerstma & de Klerk, 1969; Detournay & Peirce, 2014). We focus on transverse radial hydraulic fractures initiating from a radial notch at the wellbore wall (see Figure 1). In particular, we will clarify the difference between the initiation pressure (the wellbore pressure at which the fracture initiates) and the breakdown pressure (a misnomer which simply corresponds to the maximum pressure recorded during a test, usually carried out at constant pump rate). This difference stems from the strong viscous effects at play during wellbore pressurization, fracture initiation and early propagation (i.e. fluid entrance in the newly created fracture). It has been observed on a number of experiments (e.g. Weijers, 1995; Zhao et al., 1996) and has a strong practical application, first because the maximum pressure is the most obvious value to report and second because that maximum value is necessary to specify injection systems."

Jan 1, 2015

By G. M. Hughes, R. W. Dunn

"AbstractCurrently installed an analogue instrumentation devices at Sherritt 's Ruttan Concentrator control. and/ or measure mill tonnages, grind, pH, density , some reagent and slurry flows, and cell levels. On-stream analysis is used to assay the main process streams. The history of development of process control is reviewed from startup to the present stage of selection of a process control computer. A pragmatic approach has been taken to process control to ensure compatibility with the needs and resources of Ruttan. Emphasis is made of the need to have the mill performing well from a mechanical and instrumentation point of view and to have opera tor acceptance of the computer through training. Plans for the computer phase to achieve these objectives are outlined.IntroductionTHE COPPER-ZINC OREBODY at Ruttan Lake was discovered by Sherritt exploration personnel in 1969 and by mid-1973 a 10,000-tpd mine and concentrator were in operation. After a typical startup period , the major mechanical problems in the crusher and concentrator have been resolved. Metallurgical performance is now up to standards forecast in the feasibility study.The cost of the original instrumentation installations, including an on- stream analyzer, was about one million dollars or 4% of the cost of the milling complex. Although there was no intention of using a process control computer until the plant was operating smoothly, it was understood that all instrumentation was compatible with .a computer, but this did not prove to be correct. This paper cover s the development of the instrumentation loops to date and the control strategies that will eventually be implemented through a process control computer."

Jan 1, 1977

By F. R. Deluca

"ClassificationClassification is a combination of mechanical and hydraulic operation which separates a pulp into two portions according to their respective settling rate. The finished product, the overflow, is removed from the other product, sand, which requires further grinding.Pulp is the uniform suspension of solids in a liquid. Overflow is the fines and therefore the more slowly settling portion of the pulp which is carried over the top of the classifier by the flow of water; sand is the coarser and more rapidly settling portion of the original pulp which is discharged from the classifier by the mechanical action of the rakes or conveyed out by a ""screw"" .Selective classification is classification that has for its object the concentration of the heavy constituents of the original pulp in the sand product so that it may be ground finer than the lighter constituent.Classification is used as follows:I. To make a size separation, for example, a sand-fines separation so that each product may be given a different treatment.2. For closed circuit grinding so that the maximum size of particles entering the circuit is limited, and so that the useful work is increased by enabling the mill to operate mainly on the particles that require the reduction.3. For differential grinding of the heavy mineral constituent and the gangue. In this case, the heavy mineral is concentrated in the sand product and is reduced further, while the lighter gangue material overflows the classifier.The selection of the proper size and type of classifier is determined by the function required, the character of the ore, and the tonnage to be handled, the initial cost and the operating cost."

Jan 1, 1989

By D. G. Tisdale, W. Curlook, J. M. Toguri

"In this study, the vapour phase reduction of titanium tetrachloride conforms to the traditional Kroll chemistry, but employs argon as an inert carrier gas and requires a higher reaction temperature of 1150°C to 1250°C. A vapour phase reaction is advantageous because titanium is the only condensed phase present, and the metal can be collected free of magnesium or magnesium chloride, in marked contrast to the titanium sponge produced by the conventional Kroll process. The yield of metallic titanium from the reaction was determined as magnesium additions ranged from 36% to 168% of the stoichiometric requirement. Yields of over 99% were obtained when an excess of magnesium was present. Although the collection efficiency was low, metallic titanium was collected at the reaction site, where all other species were present as vapours. Magnesium and chlorine concentrations in the collected titanium were less than 0.3%.IntroductionA proposed method (Curlook, 1987) for titanium production has been investigated as an alternative to the conventional Kroll process (Kroll, 1940). The advantages of the new process include a simplified means of recovering the product metal, and a potential for lower overall energy consumption and greater product purity. A higher reaction temperature for the reduction of titanium tetrachloride results in a vapour phase reaction, rather than the conventional liquid phase reaction. This is the major conceptual difference between the proposed and the established (Kroll) processes.This study focussed on optimization of the process chemistry and briefly examined the issue of product deposition and collection. The reduction of titanium tetrachloride with magnesium, to produce metallic titanium and gaseous magnesium chloride:"

Jan 1, 1997