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By J. S. Phipps, D. R. Skuse

"Aqueous slurries of fine particle size calcium carbonate are used in a diverse range of end-use products. In many cases, the end use performance is governed by the fineness of the particle size distribution. In turn, the maximum fineness of the particle size distribution is primarily determined by the efficiency of the dispersants used during the production process. Here we report the sodium polyacrylate mediated dispersion of calcite and kaolin. Firstly, we report a colloid chemical description of the dispersant behaviour and attribute the stabilisation to both steric and electrostatic mechanisms. Secondly, we describe how the understanding developed in the first part of the study can be utilised to produce more effective dispersant systems which allow the preparation of, added value, higher solids and finer particle size calcium carbonate slurry products.INTRODUCTIONConcentrated aqueous dispersions of fine, particulate kaolin and calcium carbonate are used extensively in the coating of paper. Currently more than 10 million tonnes of such dispersions are used annually in North America and Europe alone, and worldwide consumption is growing at around 3% per year.Generally, paper is coated to enhance its visual appearance. Firstly, coatings improve the optical properties of the blank sheet, i.e. its brightness (or whiteness), opacity and gloss. Secondly, they improve the physical properties of the sheet that will influence the quality of the final printed image, such as surface smoothness, porosity, and ink absorption. In order to achieve these aims economically, paper coatings must be applied at high speeds and with minimal drying costs.Kaolin and calcium carbonate pigments are the major components of most paper coating formulations. Particle size distributions are chosen to maximise the optical benefits that they confer, and to allow the production of formulations that can be easily pumped, handled and coated. Coating pigments are generally produced and transported as slurries, and so it is important to obtain dispersions with the highest possible solids content, both to minimise drying costs and the quantity of water transported. This paper examines the dispersant technology that is currently used in the industry and the mechanisms by which it functions, and illustrates ways in which this technology has developed and could be further improved in the future."

Jan 1, 2003

By G. A. Davidson, P. G. Williams

"New developments in centrifugal slurry pump technology are discussed in relation to their importance for improving pump operation and reliability.Experimental data obtained by measuring the velocity of liquid flows in a slurry pump casing using Laser Doppler Velocimetry are presented. This demonstrates the importance of selecting pumps with the proper hydraulic design to provide optimum efficiency, maximum part life and minimum operating cost.The paper also discusses the use of new wear resistant materials, such as ceramic/metal composites, which can significantly improve the life of parts exposed to abrasive media. The results of laboratory attrition tests are presented. IntroductionCentrifugal slurry pumps are of primary importance for the hydro transport of abrasive and corrosive media in the mineral processing industry. As for all process equipment, slurry pumps must be carefully selected and operated to provide optimal performance. To achieve this, it is necessary to select equipment which will provide efficient and reliable operation for the specific service conditions and incorporates the best materials available to obtain maximum parts life.Abrasive wear of liquid end components is the most important aspect that distinguishes the design and application of slurry pumps from other types of pumps. It is therefore necessary to have a fundamental understanding of the mechanical interaction between pump components and the media being handled, as this will impact significantly on hydraulic design, mechanical reliability and selection of wear resistant materials. Recent advances in computational approaches'» have greatly improved the prediction of wear rates in pump casings by facilitating the solution of complex equations which describe the wear mechanisms mathematically. In conjunction with this, new experimental techniques allow researchers to measure flow fields in pump casings using non-invasive devices such as Laser Doppler velocimeters."

Jan 1, 1992

By P. P. Sinha, D. N. Bhatia, B. R. Ghosh, R. K. Gupta

Medium carbon, low alloy, high-strength steels containing Ni, Cr, and Mo are used for the fabrication of various types of high-strength fasteners required for launch vehicle structures. Cold heading properties and response to hardening and tempering are the essential requirements of the material for fabrication and application, respectively. Combining these two requirements is essentially warranted in high-strength fastener-grade steels. Cold heading properties require ductility, which can be achieved through spheroidizing treatments. In the absence of a suitable spheroidizing cycle for medium carbon 3.8 Ni, 1.8 Cr, 0.3 Mo steel, experiments were carried out with a theoretical understanding of the alloy system. This paper presents the experiments and results obtained after a spheroidizing treatment, which was carried out to optimize the process. Hardness measurements were carried out and microstructural studies were conducted to assess the spheroidization process and to determine the optimal spheroidization parameters.

Jan 1, 2007

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter has been developed to predict the molten temperature. The primary assumption of the model was that all matte, slag and gaseous phases in the converter were in thermal and chemical equilibrium. In this model, the matte components were considered only as copper, iron and sulfur elements. In the slag making stage, all the reacted iron was converted to fayalite. The reaction rate of iron and oxygen in this stage was considered to be constant. The converter temperature was calculated by heat balance over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depends on process parameters such as oxygen efficiency and molten emissivity.

Jan 1, 2007

By W. B. Timm

Introduction In preparing this paper on Recent Developments in Gold Milling Practice, the idea occurred to me that possibly the best way to deal with the subject would be to take you in thought on a visit to the principal gold mining camps of the Dominion, starting at the east and finishing up in the west, and noting, as we go, the outstanding improvements that have been made in the last few years in the practice of gold milling. Before beginning this tour, I desire to emphasize the debt this country, and particularly our mining industry, owes to that body of trained and experienced men, little heard of, but who, working quietly on their problems, are responsible for these improvements. The metallurgists, to whom I refer, have solved many difficult problems for the mining industry, in connection with the treatment of our complex ores; for instance, the silver-cobalt ores of the Cobalt district, the gold ores of the Porcupine district, the gold-telluride ores of the Kirkland Lake? district, the copper-gold ores of Noranda, the arsenical-gold ores of the Beattie mine, the copper-zinc ores of Flin Flon, and the lead-zinc ores of Kimberley. In doing so, they have maintained the high technical standards of the profession, and the practices thus evolved are noteworthy for their high degree of efficiency. When the price of gold increased from $20.67 to $35.00 an ounce, what had formerly been thought to be a low tailing became almost an ore, so that the metallurgists are now busily engaged upon the problem of putting this railing back in its proper place of being a tailing once more, or from its value, at the present price, of anywhere from 50 cents to a dollar or so per ton, to a few cents per ton. Owing to the changing prices of the metals in the world's markets, still greater improvements in metallurgical practices are imperative. An important contributory factor towards improvement in ore dressing is the aid furnished by the microscope in the examination of ores and mill products. By making possible the determination of the mineral constituents of the ore, their association, and grain size, it gives the investigator a knowledge of his problem, before he does any actual test work. In the Mines Branch laboratories at Ottawa, its use has enabled us to predict how an ore should respond to various methods of treatment.

Jan 1, 1935

By G. P. Gu

The in-service 90/10 cupro-nickel tubes in a water-chiller system suffered from severe corrosion damage during their relatively short service life causing unexpected down time. In addition to downtime, the environmental risk associated with losing refrigerant was also a concern that initiated this investigation, Microstructural investigation using SEM and electron microprobe indicated that pitting corrosion had resulted in local nickel depletion, During the corrosion process, copper appeared to have re-deposited around the corrosion pits accelerating the local corrosion.

Jan 1, 2005

By R. Salimi

Tricalcium aluminate hexahydrate (TCA) is used as filter-aid for security filtration in the Bayer alumina process. TCA is typically produced on-site by mixing Bayer liquor with slaked lime. Specific properties are required from the TCA to ensure adequate filter throughput, lifetime and importantly effective reduction of solid/colloidal impurities from the solution. The effect of reaction time on morphology and particle size distribution of tricalcium aluminate was studied for a batch experiment at simulated process conditions. It was found that reaction time plays a critical role on the morphology, crystal structure (diameter and crystallinity) and particle size distribution. In the early stages of the reaction, nucleation dominates the crystallization process followed by growth dominated by agglomeration up to a mean particle size of 10 µm. The particle morphology shifted from an irregular shape to more spherical throughout the course of the reaction.

Jan 1, 2014

By Jose Alberto Gonzalez, Said Sharif Mahboob, Jeffrey L. Shepherd

"During the industrial electrowinning of zinc, uneven growth can cause short-circuits and make the deposits more sensitive to the presence of impurities that can significantly impact current efficiency. To produce levelled zinc deposits, additives such as glue, licorice and sodium silicate are often added to the electrolyte. Even in the presence of additives, uneven zinc growth still takes place because of the combination of hydrodynamic and electrolysis conditions in the cell house. Recent advancements in imaging spectroscopy and scaling analysis have opened an avenue to further study the effects of additives on zinc growth morphology. In this study, Atomic Force Microscopy (AFM) and scaling analysis have been used to monitor zinc growth characteristics including roughness, periodicity, aspect ratios and growth mechanisms as a function of electrolyte composition as well as deposition time. Zinc was electrodeposited from an industrial electrolyte containing a host of additives onto an aluminum cathode with a platinum wire serving as the anode. AFM images of the samples were collected to obtain 3D topographical information on which scaling analysis was performed to extract details on root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. This analysis provided information on the mechanism by which the previously mentioned variables can impact short term growth and also provided a prediction of expected growth at long deposition times.INTRODUCTIONElectrowinning is one of the final stages in the industrial production of zinc metal. It is during this process where dissolved zinc ions undergo electro-reduction from an acidic electrolyte onto an aluminum cathode and are later recovered by stripping the zinc metal from the substrate. However, due to the nature of zinc growth as well as the various operating conditions, zinc deposition may occur unevenly, sometimes causing short-circuits that can cause electrode damage and reduced zinc production."

Jan 1, 2016

By A. Warczok

Chalcocite concentrate obtained by magnetic separation and flotation of Bessemer matte is processed in the Inca top blowing bottom stirring MK reactor into semi-blister copper. The semi-blister is then converted into blister copper in the multi-purpose vessels (MPV) by oxidation of iron, nickel and sulphur. High melting point NiO and Fe30 4 are formed inside the MPV s, which together with Cu20 and smaller amount of fayalite are the major constituents of the solid mush. The accumulation of solid mush and buildup requires periodic MPV cleaning by adding reductant and copper-nickel matte, a unique process called "washout". Various reductants and their combinations, such as pig-iron, 15%Si Ferro-silicon and 50%Si Ferro-silicon, have been used for the reduction of solid mush and buildup. The possibilities of using calcium carbide as a reductant and slagging flux were examined experimentally at the crucible scale. The rate of reduction of MPV buildup was determined by continuous measurement of CO and C02 contents in the offgas and the flowrate of argon carrier gas. The rate of the buildup reduction with calcium carbide was approximately five times faster than the rate of reduction with coke. Additionally, the formation of CaO results in the melting of reduced buildup and formation of a slag at 1300°C and higher temperatures. It was found that simultaneous silica addition enhanced the melting and slag formation. The results showed the strong dependence of the reduction rate on temperature. Activation energy is approximately 225 kJ/mol. Expected benefits of using calcium carbide are related to cost saving on reductant, significant acceleration of solid mush reduction, and reduced amount iron input from reductant.

Jan 1, 2007

By N. Yamazaki

The supply of clean copper ores, which have high copper concentration and low impurities like arsenic, has declined year by year. Therefore, both mine and smelter sides have to consider how to remove impurities like arsenic. We focus herein on arsenic as an impurity because it is an extremely important issue from the environmental point of view. Approximately 150,000 t of arsenic is input into the copper industry every year. A small part of it is mainly treated in the smelting side. For instance, Ministro Hales Limited, which is a mining corporation in Chile, has performed the calcination process to remove arsenic from ore with high-arsenic content. In the process, flue gas is washed by water, and the final residue is treated by a hydrometallurgical process. Many processes for arsenic removal in various stages have been proposed, and several bottlenecks exist to achieve it. One of the difficulties encountered is getting an assessment of the process, which depends on the countries and/or areas of operation. The standardization of the assessment procedure will be desired in the near future to keep the same environment standards all over the world, and now is the time to start making discussions on this matter. This will be the first step in making an international assessment procedure for arsenic treatment in the copper industry. INTRODUCTION Using the term “sustainable development” without any scientific basis can give people a false sense of security. Engineers and scientists must analyze the total mass flow of energy and materials and estimate local drain on the environment as well as the global impact of a particular industrial activity to ensure sustainability on this planet. The operations of the mining and smelting industries have a strong effect on the environment even if they provide useful materials for human beings. The copper mining and smelting industries have brought about serious environmental problems in the past. For example, the Ashio mine pollution caused big damage to the agricultural sector near the Ashio area in Japan in the late 19th century. One of the most serious problems at that time was SO2 emission because copper ore is sulfide, and the smelting process basically results to sulfur oxidation. The resource balance from a copper smelter in a year, assuming a total production of 16 million tons, can be summarized as follows: discarded minerals, 30 billion tons; sulfur, 16 million tons; iron oxide, 8 million tons; additional smaller amounts of other metals, electricity, and fuel.

Jan 1, 2019

By K. Forsberg, A. Rasmuson, R. Rodriguez Varela, J. Martinez De La Cruz

"This study analyzes the separation of rare earth elements by means of a supported liquid membrane (SLM) with the final objective of recovering REE from an apatite concentrate (Alemrajabi, Forsberg, & Rasmuson, 2015; Mohammadi, Forsberg, Martinez de la Cruz, & Rasmuson, 2015). In this study, the feed phase consists of an aqueous phase containing REE, the membrane phase contains the organic solvent and carrier (D2EHPA and EHEHPA), and the stripping phase is a hydrochloric acid solution. An evaluation of mass fluxes, separation efficiency, and membrane performance is conducted. In order to analyze the suitability of liquid membranes in the extraction of REE, a deeper insight into the mechanisms causing instability is needed. In this study, surface tension is considered as the key factor of Marangoni instabilities and spontaneous emulsification.INTRODUCTIONThe demand of REE and their compounds has increased considerably due to their special physicochemical features that make them crucial elements for numerous high-tech applications, including wind turbines, hybrid cars, mobile phones, and defense technologies. They are also extensively utilized in traditional industries such as nuclear energy, petroleum, metallurgy, agriculture, and textiles (Xie, Zhang, Dreisinger, & Dyole, 2014; Zhang, Wu, Bian, & Zeng, 2014).Solvent extraction is widely used for the separation of REE (Xie et al., 2014; Zhao, Huo, Pan, Li, & Liu, 2014). Di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHEHPA) are two of the most effective extractants for the separation of rare earth elements among organophosphorus extractants (Gupta & Krishnamurthy, 2005). However, the difficulty in stripping loaded D2EHPA extractant, especially for heavy REE, has limited its utilization. Yttrium can be stripped at lower acidities in EHEHPA systems compared to D2EHPA systems (Gupta et al., 2005), but the extraction efficiency is lower. Conventional solvent extraction by mixer-settlers is restricted by its large solvent inventory and loading limits, and suffers from phase disengagement, emulsification, loss of solvent, and flooding problems (Swain, Jeong, Lee, & Lee, 2007). In this context, supported liquid membranes (SLMs) present a potential alternative due to their advantages, being low solvent inventory, process simplicity, low energy and operational costs, great enrichment ratio, and combination of extraction and stripping into one single step. A SLM is a system in which two aqueous phases are separated by an organic liquid membrane suspended in the pores of a porous support by capillary forces. One of the aqueous phases is the feed solution with the solute and the other is the stripping or receiving solution. The solute diffuses through the liquid membrane and then is extracted into the stripping solution (Kislik, 2010)."

Jan 1, 2016

By H. A. Hamza

An experimental study of the settling characteristics of a washery effluent originating as tailings from a froth flotation circuit was undertaken by using a systematic approach to select the most appropriate flocculant(s) under predetermined conditions. Selection and evaluation procedures which greatly reduce the effort required to select flocculants are described. The results show that, although different flocculants display superiority at different ranges of dosage. Separan MG 700 (Dow) is the most suitable on absolute economic grounds. Flocculant evaluation is based on a Cost Performance Index (CPI) which expresses the cost of flocculant (¢/ton) required to produce a unit settling rate (in./hr). From experiments carried out with a number of flocculant aid and flocculant combinations, it was concluded that the use of flocculant aids can be economically justified only if the settling rates required are higher than those obtainable at the optimum flocculant dosage. Otherwise, the value of the flocculant aid appears to be limited largely to the reduction of supernatant turbidity.

Jan 1, 1979

By Anand Raman, Steve Dixon

"Industry practice for defining acid consumption is based on column tests. Freeport-McMoRan (FCX) has adopted a practice of leach operation using a defined pH or gpl acid in the raffinate based on the column test program. The acid consumption can be easily calculated using the leach operating parameters of SX-EW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate. The column leach test results and a column to heap efficiency factor are used to define the copper extraction. The maximum acid consumption will occur when zero acid is contained in the raffinate. The term Net Extracted Value (NEV) is to define the maximum extracted value relative to acid consumed.This paper presents the operating logic and method used to calculate acid consumption based on column tests and operating parameters.INTRODUCTIONIndustry practice for defining acid consumption is based on column tests. This may result in lower economic value if the tests are not designed to account for operating variables. A test program is described to assist in defining lift height and the influence of gangue on solution chemistry. A simple spreadsheet is presented that will use the leach operating parameters of SXEW efficiency, lift height, bulk density, irrigation rate, primary leach cycle time, acid cure dose and acid concentration in the raffinate to calculate the acid consumption for a proposed operation.A review of current leach operations solution chemistry will help to define acid consumption. This is recommended for all current leach operations.DISCUSSIONThe current practice at Freeport-McMoRan (FCX) is the use of column test results to define operating parameters. The monitoring of operational solution chemistry and copper production addresses any changes needed in operational parameters. This practice maximizes the value extracted from each tonne of ore leached."

Jan 1, 2008

By K. Peake, A. Dalvi, V. Hernandez, S. Chang, M. Oliazadeh

"Ironstone Resources Ltd. is developing the Clear Hills oolitic iron ore deposit in northwest Alberta, Canada. Sources of oolitic iron ore worldwide are abundant and ubiquitous, but there is currently no commercial technology to extract iron from oolitic iron ores. Mineral processing of the ore to generate a commercial iron ore concentrate is very challenging due to the nature of these ores. Accordingly, Hatch and Ironstone are developing a new pyrometallurgical process (Hatch Ironstone Chloride Segregation) to produce metallic iron from high silica and high phosphorus oolitic iron ores. Following the chloride segregation process, the treated ore is subjected to fine grinding. The iron is then separated by magnetic separation. The iron grade and phosphorus content of the final product shows a strong dependence on the separation methodology and the grind size. The pyrometallurgical process has been developed and tested at a lab-scale pilot plant. The commercialization of this technology could provide an opportunity for the development of a new alternate iron making technology. This paper presents the results of test work done on the raw iron ore to create a concentrate and also on the products of the pyrometallurgical process for the production of a high grade 90% metallic iron product.INTRODUCTION Oolite is a sedimentary rock formed from ooids – spherical particles with concentric layers. There are a number of large oolitic iron deposits where the mineralogical form features a low iron content and high concentration of impurities making them presently impossible to exploit on either a technical or economic basis. The fifteen largest oolitic iron ore deposits in the world are estimated to contain approximately 337 billion tonnes of iron ore, which would be a significant source of supply for worldwide steel production. A viable process that can economically recover iron from these oolitic iron ore deposits could become an important new technology to meet future demand in the steel industry. Hatch and Ironstone have demonstrated that oolitic iron ores can be exploited to produce direct reduced iron (DRI). Direct reduction ironmaking is a method for producing solid metallic iron using different techniques compared to the blast furnace process, which is the more conventional ironmaking route. The demand for the construction of direct reduction ironmaking plants has increased in response to the increasing demand for crude steel. It is viewed as a method of providing low-residual iron sources to scrap-based steelmaking in electric arc furnaces."

Jan 1, 2014

By C. H. Buck, A. J. Taylor

"In 2015 Vale’s Clarabelle Mill began the process change to enable a higher degree of Cu separation. The flowsheet modification was part of a complete divisional flowsheet change being implemented in Vale’s Sudbury Operations. This paper will centre on some of the Operational Readiness (OR) work, culminating in the commissioning of the circuit in March 2017. The emphasis will be on the implementation of an integrated test plan to prepare for the process flow change through the mill.BackgroundClarabelle Mill (CBM) began making a saleable Cu concentrate in 2006 with the installation of the Cu separation circuit. Typical separation rate was 35-40% of Cu in feed reporting to Cu concentrate based on a target Ni concentrate Cu:Ni target of 0.7-0.8. The remainder of the recovered Cu (55-60%) reported to Ni concentrate and was smelted through the Copper Cliff Smelter.In 2013 a capital project, Surface Facility Upgrade (SFU), was implemented to focus on matching the surface plants capacities with the future mine plan to maximize revenues. This was to be achieved by redistributing the metal flow, specifically Cu, through CBM to increase metal unit content through the Smelter. The amount of redistribution of Cu was determined to be based on maintaining a stable Cu to Ni ratio (Cu:Ni) in the Ni concentrate.The change in Cu:Ni ratio in the Ni concentrate would affect the Sudbury divisional flowsheet, and required process changes across the all of the surface plants. The detail that surrounds the flowsheet changes as a whole will not be discussed, but the outcome of the decisions plays a large role in the operational readiness interactions between the mill, its suppliers and its downstream customers."

Jan 1, 2018

By Botao Lin, Yan Jin, Hongjuan You, Jingjun Pan, Huiwen Pang, Mian Chen, Sen Chen

"Steam Assisted Gravity Drainage (SAGD) has become the mainstream technology for ultra-heavy oil recovery in Xinjiang oilfield, the success of which depends heavily on shortening of preheating period as well as forming homogeneous and highly permeable zone in land-facies oilsands layer. Towards this aim a special hydraulic fracturing process is required, which is accomplished through controlled water injection to a pair of horizontal wells in order to create homogenously distributed microcracks in the zone between the two wells. The associated mechanical response, however, is unclear for land-facies Karamay oilsands that is loose in texture. In this regard, this research utilizes a triaxial test system on cylindrical specimens extracted from field-collected oilsands cores. Isotropically consolidated drained triaxial compression tests are conducted on both saturated and unsaturated specimens so as to investigate the mechanical response of oilsands at different spots relative to the wellbore. Moreover, acoustic emission and fast pulse-decay permeability are performed to monitor fracture development and permeability evolution. Based on these experimental studies, the mechanism of dilation in oilsands is comprehensively analyzed. The findings reveal distinctive behavior between the saturated and unsaturated specimens as respect to dilation, porosity/volumetric evolution and change of permeability. It is also found that shear bands can be created upon shearing on triaxial specimens, rendering porosity or volumetric strain the factor that is more proper for evaluation of stimulation efficiency in the field.INTRODUCTIONXinjiang oilfield is widely known for its abundant deposit of heavy and ultra-heavy oil that has been estimated to be several hundred million tons. The ultra-heavy oil deposit located in Fengcheng region of Karamay at the northwestern part of the Junggar Basin, Xinjiang, China, has over 360 million tons of resource (Yuan et al. 2013). The resource is deposited in depths from 180 to 450 m and has viscosity over 100, 000 mPa•s at a temperature of 50ºC, bringing technical challenges to recovery activities."

Jan 1, 2015

By H. Arima

The Akita Zinc Company is the only refinery which produces hematite from the iron content in the zinc leach residue. The Akita Hematite Process consists of five stages, which are SO2 pressure leaching, the first neutralization stage, the de-arsenic process, the second neutralization stage and pressure hematite precipitation. In order to strengthen its cost competitiveness and stabilize its operation, the Akita Hematite Process has been modified continuously. Most recently, two process modifications were carried out. The first was an improved ability to maintain a lower arsenic concentration in the de-arsenic process, and the second was an increased throughput in the hematite precipitation autoclave. The details of these recent changes in the Akita Hematite Process are presented in this paper.

Jan 1, 2006

By C. R. Julian

THE large pyrites ore-bodies, the underground mining of which is to be described, are situated at Rio Tinto in the Province of Huelva in Southern Spain. The situation of the different ore-bodies with relation to one another is shown in Figure 1. It will be seen on the plan that the strike of the ore-bodies is approximately east and west. The geology of the district has been very fully described by Dr. D. Williams (1), so that for the purposes of this paper it will be sufficient to give briefly the salient features o each of the two larger ore-bodies which are being mined by underground methods at the present time. (a) San Dionisio.-This ore-body is the largest single deposit in Rio Tinto, having on its upper levels a length of 3,500 ft. On the upper levels the average width is approximately 200ft. but in places on the lower levels there is a width of 900ft. of un broken pyrites. Diamond-drill holes, without running out of ore, show the ore-body to persist to a depth of at least 1,600 ft. The ore-body in the upper part lies between slate and porphyry walls, but in depth is enclosed in porphyry walls. (b) South Lode.-Faulting is considered to be responsible for the break in the solid ore between South Lode and San Dionisio. On the upper levels, the South Lode ore-body has an unbroken length of 4,000 ft. The massive pyrites has a maximum width of 300ft. and an average of about 100 ft. Ore has been proved to a depth of 1,000 ft., at which depth the ore-body is much reduced both in length and breadth. This ore-body, to the depth at which it has been proved, lies entirely between slate and porphyry walls. The South Lode and the San Dionisio ore-bodies are mined both by open-cast and by underground methods. There is evidence that these mines have been exploited intermittently during the last 3,000 years; but, as is to be expected, no records are available of the tonnage mined prior to the time of purchase by the present company.

Jan 1, 1940

By L. H. Thorleifson

Demand for both gem and industrial diamonds is very strong. Synthetic production supplies industrial uses, but synthetic gems remain inferior and expensive, so the large gem market is supplied by mining. Several major mines have been depleted, and the market is receptive to new sources of high quality gems. Canada's Precambrian terrane, extending across the Canadian Shield and under the Phanerozoic cover of the Plains and Hudson Bay, has excellent potential for diamonds, but exploration conditions are difficult due to recent glaciation. Early world exploration relying on recognition of diamond in alluvial sediments was adequate to launch pre-1900 production from India, Brazil, and Africa. Exploration success in Canada, as was the case in Russia and other more recently discovered sources, however, had to await large investments in effort supported by advanced science and technology. Canadian exploration in many ways is similar to that in other regions, relying on analysis of tectonics, indicator minerals, geophysical surveys, and multiple stages of drilling and sampling. Very different from other regions, however, is Canada's surficial environment, in which recent glaciation has caused fresh indicator minerals to be transported hundreds of km. Exploration accelerated in Canada after 1960, first in Ontario and the Arctic Islands, then in Saskatchewan in 1988, and most importantly after the Chuck Fipke - Stew Blusson discovery at Lac de Gras, Northwest Territories, in 1991 that led to the billion-dollar BHP - Dia Met Ekati Mine that opened in 1998. In 2003, production from Ekati is expected to be supplemented by that from the similar and nearby Diavik Mine of Rio Tinto and Aber, currently under construction. These mines will bring Canadian output to over 10% of world supply, and will position Canada with Botswana and Russia as world leaders in production of high quality gem diamonds. There could be other mines as well, as sites across the Arctic and in the south from Alberta to Québec are being explored by an array of companies, including De Beers, other majors, and several juniors.

May 1, 2001

By Maurice Morton

THE use of organic and inorganic stains has found wide application as a means of detection and estimation of organic fibres. Such stains have enabled the analyst to distinguish between organic fibres of different type and even between wood fibres produced by different processes. Among these stains, aqueous iodine solutions have figured prominently, as in the case of the well-known Sutermeister and Herzberg stains. At the Johns-Manville laboratories, the idea of applying a stain to asbestos fibres was first considered solely as a visual aid in the microscopic examination of such fibres. The staining medium used in this work consisted of a 1 per cent solution of iodine in C.P. glycerine, the latter being used extensively here as a dispersing and mounting liquid for asbestos fibre. This iodine solution was found to have distinct staining properties when used on the local chrysotile fibres, and to improve greatly their visibility under the microscope. It was soon revealed, however, that this staining is apparently limited to the chrysotile variety of asbestos, as against other varieties. It can be readily seen that, if such were the case, the staining test would become a very useful tool in differentiating between chrysotile fibre and the other mineral fibres, without recourse to a lengthy chemical analysis. Hence this investigation was launched, with the purpose of obtaining more information as to the selectivity of this stain as well as its mechanism. The only previous work of this nature that could be found in the literature was that of Van Winsen and Graham (1, 2, 3) on the adsorption of erioviolet dye by serpentine and related magnesia minerals. However, these authors did not refer to any specific behaviour of chrysotile as against other types of asbestos fibre.

Jan 1, 1941