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By Adil Aledresse, Louis Mercier, Laxman Amaratunga

"The development of high capacity adsorbents with uniform porosity denoted, MP-HMS (Mercaptopropyl – Hexagonal Mesoporous Structure) using nanotechnology, and their ability to extract gold from solution, is presented. The preparation of highly effective heavy metal ion adsorbents by the incorporation of thiol moieties into the pore channels of mesoporous silica molecular sieves has been the subject of many nanotechnology research investigations. The unique feature of these nanoporous adsorbents is their ability to adsorb gold ions from ultra-low concentration solutions like mine effluent as well as from leached solutions in gold mills. The preliminary studies from laboratory simulated gold solutions show that the adsorption capacities of these materials are also among the highest reported. MP-HMS has shown the capability to adsorb 370 mg gold per one gram of the nanomaterials from Tetrachloroaurate solution (up to 37% of their weight). Experimental studies indicated that the maximum adsorption of gold (as high as 99.9% recovery). The current studies will be extended to investigate the interaction of ionic gold complexes with nanomaterials. Future development of this work may lead to either to replace the conventional CIP/CIL processes or use nanomaterials in tandem with the former, suggesting plausible use of mesoporous material in pulp, MIP or in leach, MIL, as a novel gold extraction process.INTRODUCTIONGold typically occurs at very low concentrations in ores less than 10 g/t or 0.001% (mass basis). At these concentrations the use of aqueous chemical (hydrometallurgical) extraction processes is the only economically viable method of extracting the gold from the ore. Typical hydrometallurgical gold recovery involves a leaching step followed by the separation of the gold bearing solution from the residues, or adsorption of the gold onto activated carbon adsorbent. After elution from the activated carbon the gold is further concentrated by precipitation or electrodeposition."

Jan 1, 2008

By R. Bridge

Mining companies are progressively finding themselves having to develop operations for more complex, deeper ore bodies, which require the use of more complicated mining and mineral processing methods. This coupled with the generally increasing trend of higher capital and operational costs have led to a need in the industry for improving ore body knowledge, mining and mineral processing. Geometallurgy is a relatively new concept that can link the three aspects, and when used effectively it is a method that can produce the necessary information for designing and building operations for reliable and optimum performance. Geometallurgy not only involves the integration of geological, mining, and metallurgical fields, but it can also be expanded to include environmental and economic information to produce a block model that can be used to obtain the best outcome in terms of plant response and plant sustainability. The geometallurgical program should not end once the block model has been populated. A detailed geometallurgical approach should be applied to all stages of the operation encompassing sample selection, through to equipment sizing and production forecasting. It can also become a useful optimisation tool thereby allowing the operation to be proactive rather than reactive against changes in the ore characteristics. With the development of metallurgical performance predictors it is possible to quantify how the ore will behave in the process plant in terms of throughput, recoveries, reagent consumption, etc. Therefore, in terms of responsible mining and sustainable resource development, a geometallurgical approach to operations is the logical step for plant development. In this paper we describe the state of the technology with respect to the application of geometallurgical modeling and its utilisation in the fields of design, forecasting and optimisation of mining operations.

Aug 1, 2013

By Harry Wilton-Clark

Introduction Coal cleaning may be taken as meaning the separation of coal-as-mined into two or more fractions. Coal cleaning includes coal washing, together with any other means used in the ultimate preparation of coal prior to shipment (as coal) . The method of coal cleaning devised for any given mine must be one which is based entirely on the economic results obtainable. The installation of a high-cost and complex washing plant, designed to produce a low-ash dean coal, at the highest possible recovery, may be unsound practice. A crude 'roughing' washer may be the best result of sound engineering and operating consideration, and in some cases coal cleaning should be confined entirely to preparation at the face. Consideration of complete costs, to the point where the coal is actually sold, may show that certain seams are workable or not workable. Of the seams found workable, extraction of the whole or parts of the seam may be decided on. The portion to be extracted may contain rock or bone partings, which must be removed. It may be good practice to mine the extra portion and remove the objectionable materials by surface washing; or it may be that such materials should be removed underground, even at an increased mining cost. For instance, in some of the steeply pitching seams of the Alberta Crow's Nest Pass district, the removal of bone and rock at the face may be almost impossible under the usual 'up the pitch' or 'angle' mining methods, but possible by mining across the pitch so that the material to be rejected can be removed and gobbed. Again, if a complete seam is being extracted, investigation may show marked differences between top coal and bench coal, and if sufficient mine cars are being loaded from a chute at one time, the fact that such a place is working top or bench coal at the time may be reflected by peaks in ash content or size proportions at the ripple. It may be very effective coal preparation to smooth out such peaks.

Jan 1, 1934

By H. R. Manouchehri

"It is well understood that, apart from particle hydrophobicity, the flotation process is strongly influenced by the cell hydrodynamics. Once the chemical conditions were optimized and fixed, the flotation rate is essentially determined by impeller speed and the air flow rate.The collection efficiency in flotation is a product of collision, attachment and stability/detachment efficiencies. The collision efficiency for a given particle diameter is increased by decreasing the bubble size and bubble velocity as well as increasing the power input to the cell. The attachment efficiency, however, is defined by bubble size and its velocity. The detachment/stability depends on the relative magnitudes of the attachment force between the bubble and particles and the detachment force acting on the bubble-particle aggregates. For the particles having specific contact angle, the stability decreases as the energy input increases. Therefore, there must be an optimum energy dissipation to maximize recover of defined size fraction.A comprehensive laboratory study was devoted to determine the effect of power input in recovery of finely grind Cu-Ni bearing ore. Several flotation tests were conducted to define the hydrodynamic parameters for a laboratory scale Runge cell under different impeller speeds. An increase in flotation recovery of finely ground ore was observed when the impeller speed was increased from 450 to 1,200 rpm. The experimental results have shown increasing in water recovery and improving in flotation kinetics of fines by increasing the power input to the flotation cell. Implementation of the Wark flotation model to the experimental data revealed a good correlation between the experimental data and the model. For the particles having enough hydrophobicity the flotation rate increases by increasing the impeller speed due to a higher value for collision efficiency within the cell."

Jan 1, 2016

By J. P. Mogan, E. D. Dainty, A. Lawson

"The toxicity reduction of emissions from two diesel engines by the emulsification of water into fuel oil was investigated to determine the applicability of such systems to underground mining machinery. . The engines studied were: 1) the Deut; F6L7J4, four-stroke, air-cooled, 6-cylinder, V-configuration, indirect-injection (IDl) engine, and 2) the Detroit Deisel Allison Division 8V7JN, two-stroke, water-cooled, 8-cylinder, V-configuration, direct-injection (Dl) engine.The application of emulsified fuel treatment to the two-stroke engine did not prove to be practicable. In the case of the Deutz engine, however, substantial benefit resulted. For a modest J5 per cent water content in the fuel and an injection timing of24° BTDC, approximate reductions of40 per cent in the concentrations of both particulate matter and nitric oxide (NO) were produced. These reductions were accompanied by insignificant changes in other toxic constituents. The net result was an approximate 30 per cent reduction in the over-all exhaust toxicity for typical LHD operation as assessed by the Health Effects Index criterion. This toxicity reduction represents a significant advance from the points of view of an improved underground environment and/or reduced ventilation costs."

Jan 1, 1981

By A. B. C. Stothart

"IntroductionIn the past four years Ontario Mines have made great progress in the development of reliable mine conveyance safety dogs. History shows that, prior to 1945, a rope failure on a descending conveyance was usually followed by unsatisfactory safety dog operation.It is proposed in this paper to discuss briefly;The history of this development. Progressive .development of one type (E. Long).Free fall testing of safety dogs. Anti-trailing rope device.HistoryOn February 2nd., 1945, a hoisting rope broke at the Paymaster mine. The safety dogs proved ineffective and permitted the cage to crash through to the bottom of the shaft, with disastrous results.Following this accident, the Ontario Government appointed a Technical Committee to investigate The Safety of Hoisting Equipment and Hoisting Practice in Ontario Mines. This Committee consisted of Dr. C. R. Young (Chairman) and Professors T. R. Loudon, E. A. Allcut, V. G. Smith, and Lloyd M. Pidgeon. The Ontario Mining Association (at the request of the Ontario Government) also appointed a Committee consisting of Messrs. R. E. Dye, R. D. Parker, and R. L. Healy."

Jan 1, 1950

By John G. Ayttes

"The following is a review of the advance of raise boring and its current position. The viewpoint presented is that the mining industry, through its worldwide acceptance of raise boring, has acknowledged the success of the method in general. Acceptance, however, does not imply complete satisfaction with either the equipment or current operating costs. Therefore, a brief review of how boring costs are being r educed is presented, citing examples. Recent raise borer applications of special interest are presented to show adaptability of current equipment, and some special projects in the planning stage are highlighted."

Jan 1, 1972

By J. G. Ross

A DESCRIPTION of the block-caving system of mining as practised at the King mine of Asbestos Corporation, Limited, Thetford Mines, Que., was presented. at the Annual Meeting of the Institute held in Quebec city, in April, 1934. The paper was published in the Transactions of the Institute for 1934. There has now been recovered, by this method, one million tons of ore, and a review of experience indicates that the method was well planned and has been executed smoothly. In approaching the problem of selecting the type of mining best adapted to this deposit, the method had to be one which would be low in cost, use no wood, and not disturb the surface immediately bounding the ore-body on two sides. Prior to 1931, block-caving had been considered but rejected, as it en-tailed disturbance of the surface area which lay within a 45° angle of the lowest contemplated workings, if the practice of such mines as Ray, Miami, Inspiration, and Morency, where this type of mining has been used extensively, was followed. At these properties there have been mined large tannages at outstanding low costs, but an extensive surface area has been disturbed in each case. In some instances, townsites in the mining area have had to be abandoned, and dwellings, not considered worth moving, have been allowed to fall into the depression. A study was made of the principles involved in the various types of block-caving, the existing information on ground movement, subsidence, etc., also being carefully analysed. Toward the end of 1931, a plan was conceived whereby the country adjoining ground being caved might be held permanently in place and undisturbed. The success of such a scheme was essential to the application of block-caving at the King mine on account of property boundaries, the Quebec Central Railway right-of-way, and expense of moving buildings. Study of existing data on caving and movement of rock, caused by sub-surface excavations of sufficient unsupported area to result in failure of the backs, indicated, in practically every instance, that such movements followed certain definite laws of mechanics.

Jan 1, 1936

By M. Lebeuf, A. Dumais, C. Farsangi, N. Singh

The Nunavik Nickel project began ramp-up of a new ore body (Expo) in November 2014. This new deposit is significantly more competent than the previous ore type milled (i.e., the plant moved from a feed with a BWI of 12.2 kWh/t to predominantly material with a BWI of 19.6 kWh/t). Despite circuit changes made in advance of the Expo ore ramp-up (grinding media size, mill loading/power draw, and cyclone configuration) the throughput of the plant was bottlenecked at 90% of targeted throughput with multiple stoppages to grind-out the primary mill due to excessive circulating loads. During this time, the secondary milling circuit was under-utilised: therefore the focus for debottlenecking plant production became increasing the product size of primary milling. Given the scope of changes already made to the circuit, it was decided to test the mill in open circuit. The milling changes were modelled using the Molycop Tools package to identify potential problems. In the modelling and plant trial it was apparent that the ball size in the secondary grinding circuit was inadequate, resulting in pebbling. The power draw of the secondary mill was brought up to minimize pebbling and the average ball size was increased. The switch to open circuit primary milling permitted a significant augmentation in plant tonnage. While the overall grinding efficiency decreased using the open circuit configuration, the ability to increase throughput made it the clear operating choice.

Jan 1, 2016

By C. W. Reno

"THE LORNEX MINING PROJECT is one of several large-tonnage, low-grade operations recently placed in operation in British Columbia. It is located in the Highland Valley in the south central portion of the province. This area is described as a divide valley at an elevation range of 4,000 to 6,000 feet and is situated on the divide between two drainage systems. The major drainage to the west flows into the Thompson River and to the east and south the drainage enters the Nicola River system. This open-ended valley lies between low, rounded mountains in fairly heavily-wooded country. Prior to the commencement of copper mining activities, the first by Bethlehem Copper Corporation Ltd. over ten years ago, the valley was only sparsely settled. A few small ranches were in existence on the several Indian Reserves located along the valley bottomland. There has also been a small amount of logging activity in the valley, although much of the area is covered by dense lodgepole pine which has little or no value to the loggers. As the mining interest mounted with further discoveries of the disseminated copper ore typical of the district, much of the valley was covered with mineral claims and exploration drilling was carried on by several companies at various times. At the time Lornex was preparing to commence major construction work in early 1970, there was very little activity of any kind in the Highland Valley outside of the Bethlehem operation and a small amount of ranching."

Jan 1, 1973

By Sebastian Siebert

Unmanned Aerial Vehicles (UAV) as a data acquisition platform and as a measurement instrument have become attractive for many surveying applications in civil engineering. However, their performance is not well understood for these particular applications. The specific scope of the presented work is the performance evaluation of a UAV system that was built to rapidly acquire mobile 3D mapping data for large earthmoving construction sites. Details to the components of the developed system (hardware and control software) are explained. A novel program for photogrammetric flight planning and its execution for the generation of 3D point clouds from digital mobile images is explained. A performance model for estimating the position error was developed and tested in several realistic construction environments. Results to these tests are presented as they relate in particular to large excavation and earth moving construction sites. Results and experiences with the developed UAV system are in particular useful for researchers or practitioners in need for successfully adapting UAV technology for their application(s).

Aug 1, 2013

By T. E. Warren, K. W. Bowles

"IntroductionTHE PROBLEM of producing synthetic liquid fuels from coal and other raw materials is of increasing importance in Canada as well as in the United States. This is due, to a large extent, to the continually increasing demand for gasoline and other liquid products which are now obtained solely from petroleum. The United States has reached a position where domestic supplies of crude petroleum must be augmented by imports and Canada is still a long way from self-sufficiency. In the event of war, there might well be an immediate need to find supplementary sources of liquid fuels. It is, therefore, expedient to consider alternative sources of production now -well in advance of the time when supplies of petroleum may prove inadequate to meet requirements.The purpose of the present paper is to give a short review of the history of liquid fuel production from coal, to describe briefly the research sponsored by the Federal Government on the coal hydrogenation process, and finally to evaluate the present status and future trend of the synthetic fuel industry, with special reference to necessary research work.History of the Oil-From-Coal IndustryThe history -of coal liquefaction began in 1913, in Germany, with the work of Frederick Bergius. His first approach to the subject was not deliberately planned."

Jan 1, 1952

By Keith C. Hendrick

"Metal prices are frequently the most critical and least predictable element in determining the profitability of mining operations. Short -term fluctuations can be offset in varying degrees by hedging or other market actions. Such solutions are not practical for the longer term, The paper investigates the nature and extent of metal price risks and evaluates methods to reduce them.IntroductionIt is management's responsibility to improve the odds by managing the-risks by identifying them clearly, assessing them accurately, minimizing them where possible-and, then, timing decision s success fully.In determining the profitability of current operations, preparing forward plan s or developing feasibility studies for new projects or expansions, pr ices are usually the most critical input. Being market determined rather than cost based, they can also be the most unpredictable As a result, commodity prices are frequently the greatest of all risk factors.Nature of Commodity PricesThe cyclical nature of commodity prices is well known. They are stable only when supply is in balance with demand and forecast to remain that way. An imbalance on either side of the equation can lead to a price reaction completely out of proportion to the actual or perceived surplus or shortage.This exaggeration arises through the cumulative effect of market forces. When the market senses an uptrend, consumers buy for the expected increase in activity. They also seek additional quantities for inventory before price s rise. Merchants defer spot sales anticipating higher price s, speculators go along for the same reason, and producers raise prices in response to demand. Events tend to confirm the expectation of each party and strengthen their reaction causing prices to move higher."

Jan 1, 1983

By U. Dillon, G. Blackwell

"Geographic information systems (GIS) provide an efficient means for the recording, manipulation, revision, display and analysis of spatially referenced data. GIS are widely used at the exploration stage of mine development, and are increasingly used for reclamation planning. The ability of a GIS to perform spatial searches and query spatially referenced data make it a powerful tool for use at all stages of mine development. As the amount of data available for analysis increases, so does the power and flexibility of GIS as a planning tool.Starting from the exploration database, this paper describes how a GIS can be used for the development of mining plans based on topography, geology and mineralization information stored in a relational database. Planning decisions approaching the optimal can then be made for a wide range of parameters, including stockpile and waste dump locations, the location of potentially acid generating and neutralizing material for dump design, profitable and risk-controlled mine extraction sequencing, and haul road locations. This is made possible by the overlay and buffer analysis capabilities of a GIS which are explored and exploited to produce a continuous mine production planning program, as well as site remediation and reclamation using a successful case study. IntroductionGeographic information systems (GIS) are a relatively new tool in the mining industry. Although they have existed for a number of years, the potential of GIS for mine management and planning is only beginning to be investigated and exploited. The unique spatial capabilities of GIS make them particularly wellsuited for use in mining, where spatial information is fundamental to the processes of mineral exploration, mine development, and environmental reclamation. A number of potential applications for GIS in the mining industry have been identified, and they are widely used for exploration and reclamation. The use of a GIS as a platform for the development of mine planning routines and software remains an interesting, but as of yet unexplored, application of this technology."

Jan 1, 2003

By Eduardo R. Rodrigues, Ankur Narang, Roberto Federico Ausas, U. T. Mello, Jose Maria Segura Serra, M. R. Lakshmikantha, Ignacio Carol, Kamal C. Das

"Modeling of big faults or weak planes of strong and weak discontinuities is of major importance to assess the Geomechanical behaviour of mining/civil tunnel, reservoirs etc. For modelling fractures in Geomechanics, prior art has been limited to Interface Elements which suffer from numerical instability and where faults are required to be aligned with element edges. In this paper, we consider comparative study on finite elements for capturing strong discontinuities by means of elemental (EFEM) and nodal enrichments (XFEM) for Geomechanical applications. For general fracture scenarios, Oliver et al. (2008) have demonstrated advantages of EFEM over XFEM for including: (a) ease of modeling in any standard finite element code due to the possibility of static condensation, (b) higher accuracy in some cases for coarse meshes, and, (c) a reduced computational cost. However, there has been no work that considers cohesive fractures in Geomechanics. We present a numerical analysis based on a linear constitutive model and linear triangular elements for the bulk and a linear constitutive behaviour for the fault for a representative set of fault planes in a circular tunnel made in rock mass. In the numerical examples we consider both well-traced and bad-traced meshes. We focus on traction profile analysis for both EFEM and XFEM, since that is crucial to understand the cohesive fracture behaviour specially rock joint. Therefore in each case, shear, normal and stress ratio are compared across the two methods along the fault plane. This is the first such work that compares XFEM and EFEM behaviour for Geomechanics problems.For the considered class of problems and the sharp penalization approach without regularizations adopted, it can be observed that accuracy and robustness of EFEM may strongly depend on the fault orientation with respect to the element edges, while, XFEM is independent of fault alignment with element edges. It has been also observed that, with mesh refinement model, stress oscillation completely removed with XFEM however EFEM fails to provide oscillation free results with finer mesh in case bad-traced model. We also performed error analysis and found that in case of bad-traced mesh the average error in the XFEM is 84% smaller than of EFEM and for XFEM the error goes to zero with increasing mesh resolution, while for EFEM the error increases with mesh resolution. Thus, we experimentally demonstrate that, XFEM performs better than EFEM in terms of accuracy and rate of convergence with marginal increase in computational cost. This work hence provides novel insights on the application of XFEM and EFEM in Geomechanics."

Jan 1, 2015

By P. K. Kaiser, F. Amann

"Rock mass characterization for deep underground construction and mining offers many challenges. This paper first describes some of the key challenges when characterizing highly stressed brittle rocks and then offers some guidance on how to arrive at reliable rock mass strength parameters for deep mining applications. Focus is placed on characterization for rock mass strength determination. It is illustrated how the common use of currently available rock mass characterization systems tend to underestimate the strength of rock at depth. Modifications to currently adopted approaches, i.e., the use of Geological Strength Index GSI for rock mass strength determination, are presented.INTRODUCTIONFor green fields projects, the first challenge of rock mass characterization stems from a lack of access to examine the rock mass at scales larger than typical core sizes (i.e., ~63mm in diameter) until late in the mine design when the flexibility for making changes is constrained. Hence, rock mass characterization often has to rely on information derived from boreholes alone (e.g., core, logs, etc.). This challenge is lessened when mines are expanded from existing operations. A second challenge is related to changing rock mass behaviour with increasing depth and stress. At depth, the rock is highly stressed, thus closer to failure, and often highly confined which leads to a higher interlocking with elevated strength but more brittleness. The goals of rock mass characterization are to be tailored to the technical goals of an investigation. For example, for cave engineering, the workflow includes the assessment of five key engineering aspects (Brown, 2007): Caveability; fragmentation; cave performance; extraction level stability; and mine construction (rock support). Each engineering aspect has to address specific engineering questions and each design component is influenced by different rock mass behaviour aspects and thus is dominated by different rock mass properties, e.g., the vulnerability to stress fracturing (spalling), the bulking characteristics for flow control and support selection, and the confining stress impact on pillar or support design. An effective rock mass characterization program, including logging, mapping and laboratory testing, thus has to collect and interpret features that are relevant for the above listed purposes. Some of the predominant factors are: block volume of defected and non-defected rock; spalling strength; tensile strength of defects; rock mass modulus; and rock mass strength parameters for application to low and high confinement design aspects."

Jan 1, 2015

By A. J. Rigby

Computer generated, actual-scale furnace models have been imported into a rendering software application to provide for impressively realistic surface features and lighting. When these models are imported into a 3D engine framework, it is possible to create content-rich virtual environments allowing for complete interactivity and could provide for a powerful tool to conceptualize refractory lining designs. This technology has been applied to illustrate the optimized design concept of an anode-refining vessel, which can be expected to be completely relined in six days and to last for 4-5 years with minimal partial relining. This technology could easily be applied to other smelter furnace, converter and refining vessel designs.

Jan 1, 2007

By M. Veiga, L. Lavkulich, R. Pakalnis, M. Ghomshei, S. Baldwin, J. A. Meech

"On July 26, 2000, the Canada Foundation for Innovation announced an award of $1.3 M dollars for The Centre for Environmental Research in Minerals, Metals and Materials, CERM3, at The University of British Columbia. Additional funding was also provided by the British Columbia Knowledge Development Fund ($1.3 M) and the UBC Stewart Blusson Fund ($0.7 M). Annual industrial grants and contracts are providing support funding for the on-going research projects. Corporate membership in CERM3 entitles each participant to a seat on the technical advisory committee (TAC) as well as access to the five laboratory facilities currently under construction. Both the federal and provincial governments will also participate in the TAC through NRCan-CANMET and the BC Ministry of Energy and Mines, respectively. CERM3’s mission is:• to develop innovative methods to deal with environmental problems created by mining activity;• to promote sustainable development as a hallmark of management decision-making; • to produce mining and processing engineers with the required environmental skills; and• to enhance the image of mining in society as a vibrant and necessary component of a modern economy and society which disturbs the environment for the benefit of mankind.CERM3 brings together a multi-disciplinary team of researchers from over 12 departments at The University of British Columbia (UBC) to work on mining-related environmental problems. These include: chemistry; soil sciences; chemical and biological engineering; earth and ocean sciences; microbiology; civil engineering; electrical engineering; metals and materials engineering; mechanical engineering; mining and mineral processing, the Westwater Research Centre; the Institute for Resources and the Environment; and the School of Occupational and Environmental Hygiene. The centre intends to interact with scientists from industry, governments and other universities across Canada and around the world. CERM3 aims to become Canada’s leading environmental research facility for the mining industry. This paper describes the evolution of CERM3 and its coordinated multi-disciplinary approach to mining and the environment. Some of CERM3’s research projects include:• developing new protocols for environmental analyses to provide consistent and reliable assays;• isolating a natural virus for Thiobacillus ferrooxidans and other bacteria responsible for acid rock drainage (ARD);• designing bio-remediation and adsorption techniques for mine effluents;• promoting and enhancing the use of hydrometallurgy to reduce environmental pollution;• examining new approaches to comminution to decrease energy consumption;• developing a magnetically levitated hoisting system to reduce the footprint of a mine operation;• building a state-of-the-art supercomputer network laboratory for mine/mill simulations; and• designing intelligent bulkheads to seal tunnels following mine closure to survive for 1000 years.This latter project involves the establishment of a research station at the Britannia mine site, 45 km north of Vancouver, which will provide a full-scale facility to design the “Millennium Plug” and contribute directly to the solution to one of North America’s worst ARD-contaminated sites."

Jan 1, 2003

By L. Mercier, R. Narendrula, F. Desmarais, L. Amaratunga, A. Aledresse

Thiosulfate is recognized as a promising alternative lixiviant to cyanide for the extraction of gold from ore bodies. Gold thiosulfate ([Au(S2O3)2]2), however, is not well-adsorbed by activated charcoal, making industrial scale use of thiosulfate for gold leaching impractical at present. Because of their high specific surface areas (500-1000 m2g-1) and uniform open-framework nanoporosity (pore channel diameters in the range 3-10 nm), functionalized mesoporous silicas are widely recognized as highly effective materials for the selective, rapid and high capacity uptake of mercury, gold and platinum group ions. In the present work, the efficient and rapid adsorption of gold thiosulfate by thiol-functionalized mesoporous silica (hereafter designated MP-HMS) is demonstrated, whereby the thiol groups in the materials bind with the gold complexes by ligand displacement. The adsorbed gold could be leached out using cyanide, regenerating the adsorbent for further uptake cycles. Functionalized mesoporous silica is thus a promising candidate for the preconcentration of gold from thiosulfate leachate solutions.

Jan 1, 2011

By Andrew Barnes

The adsorption capacity of peat collected from a proposed mine development in northern Sweden has been determined using laboratory column experiments in which peat was irrigated with a simulated (acidic) waste rock dump leachate. The simulated leachate was made using a hydrogen peroxide leach of composite waste rock from the proposed mine development. The waste rock samples were composited in proportion to their predicted extractable tonnage for the mine development in order to generate a more representative leachate solution for the waste rock facility. As expected the test revealed that the peat material shows a very high affinity for attenuation with greater than 70% of Co, 90% of Ni and 95% of Cu removed from influent solutions through the majority of the tests demonstrating the potential benefits in mine water treatment. In contrast, it was found that Fe is initially released from the peat at concentrations up to 100 mg/L and can mean potential problems for the water released depending on the receiving environment. The exact mechanisms for Fe release is uncertain, though it is suspected that ion exchange / competitive desorption is responsible. Inspection of the laboratory results and drainage data from the natural peat wetland receiving drainage during overburden prestriping and mine development at the mine site are comparable, confirm the validity of the experiments, and further emphasize the potential for future use of pre-stripped peat material in managing water quality.

Aug 1, 2013