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By J. L. Bowlby

Introduction In the following discussion, boiler-feed and mine waters will be considered from the point of view of the problems arising from the chemical nature of the mineral and gaseous impurities they contain. The theories underlying some of these problems will be reviewed for the purpose of getting a clearer concept of the problems themselves. Certain terms of a chemical nature, necessary to the discussion, will be explained on the assumption that they are not generally familiar to mining engineers. Finally, an attempt will be made to correlate theory and practice, with the abject of establishing certain limits to factors relevant to the problems, and to show that these limits are justified by practical experience. The general problems occasioned by the presence of mineral and gaseous impurities in boiler-feed and mine waters are: (1) Scale formation and corrosion in boiler systems. (2) Corrosion of mine pumps and pump fittings. These will be discussed separately. Boiler Scale Typical analyses of waters available for use in steam power-plants are given in the accompanying Table (Table I). All analytical data are expressed in grains per Imperial gallon. The bicarbonates of calcium and magnesium in the raw waters are shown as normal carbonates in the Table. Substances in the first five rows constitute the encrusting solids. All the waters listed in Table I would be classified as 'very good' in the schedule of classification for boiler waters adopted by the American Association of Railway Chemists in 1887. In spite of this classification, however, the waters contain sufficient encrusting solids to cause serious scale trouble after prolonged evaporation.

Jan 1, 1934

By Wignall. T. K., J. De Geoffroy

Statistical models are fitted to the observed distributions of eighteen characteristics of the population of commercial porphyry deposits of North and South America. The statistical base required for the formulation of the statistical models includes 58 commercial porphyry-copper-molybdenum deposits of the Cordilleran Belt from which geological, geometric and economic data were collected. Predictive and composite models are derived from the statistical study to assist explorat10n. planning, engineering studies and fmanc1al analyses as required for the development of new porphyry deposits in the Cordilleran Belt.

Jan 1, 1973

By W. Griffith

"While oxalic acid precipitation practices are commonly applied on purified rare earth elements (REEs) pregnant leaching solutions (PLS), few efforts have been reported using oxalic acid (OXA) to recover REEs directly from untreated PLS. High oxalic acid demand is the most significant issue in all these direct oxalic precipitation (DOP) practices. Preliminary research on DOP of REE from a dilute PLS originating from an acid bake followed by water leaching was conducted. At 75°C, the oxalic acid demand was between 12 and 18 times the stoichiometric requirement for complete REE precipitation. Conducting DOP at 25°C had superior REE recovery but the product purity and filterability declined. Between 75°C and 100°C, REE recovery increased with increasing temperature. When sodium hydroxide was used to adjust the pH during DOP, in the range of 0.5 to 1.5, higher pH benefited REE recovery. Using ammonium hydroxide in place of sodium hydroxide, the REE recovery was reduced by close to 5%. Sodium chloride addition to the PLS was also investigated and the results showed that at both 75°C and 25°C, the REE recovery was enhanced substantially. At 25°C, when the oxalic acid addition was controlled at 4.7 times the stoichiometric requirement, the overall REE recovery reached 95% with the addition of 240 g/L NaCl. Other reagents such as KCl, NH4Cl also showed significant enhanced REE recovery at the same oxalic acid addition. The addition of sodium sulphate appeared to largely enhance the precipitation of LREE but inhibited the formation of HREE oxalate. All results indicate the formation of rare earth double salts may play an important role in REE DOP sulphate media.INTRODUCTIONThe conventional routes for recovering rare earth elements (REEs) from a sulphuric acid pregnant leaching solution (PLS) involves an initial purification step for removal of iron, aluminium for example by precipitation through neutralization, followed by precipitation of REEs as hydroxide, oxalate or carbonate salts, or by bulk solvent extraction for REE recovery (Xia, 2013). Another route was used by Bayan Obo in their historical flowsheet, where the PLS was first subjected to double sulphate precipitation, then the remaining REEs, mostly heavy rare earth elements (HREE), were recovered by oxalate precipitation (Li, 2011)."

Jan 1, 2016

"During the development of a mining project, samples are taken for metallurgical tests. The sample can be a composite sample made of material from a selection of various drilling products or a sample from a mining test. It can be also a sample from an existing plant in order to investigate process enhancement. This sample can represent several tonnes of material which are analysed and split for use in various tests.In the current case, a composite sample of gold ore is dedicated to a Gravity Recoverable Gold (GRG) test. The properties of interest are the head grade of gold, the size distribution of the material, and the gold assay per size class. The sample is mixed and a sub-sample is taken to measure the feed properties: the size distribution and the gold assay per size class. The remaining material of the sample is subject to the first stage of concentration using the laboratory Knelson concentrator. The concentrate is analysed in its entirety, while a sample of tailings is taken for the same analysis. The remaining part of tailings is subject to grinding to feed the second and third stages of concentration. Similar sampling is performed at each stage.The concentration performances are analysed in light of these measurements. But what is the accuracy of the measurements of the properties? Pierre Gy’s theory of sampling, associated with a heterogeneity model built using the GRG test results, will answer this question. The current paper presents, through a real example, the calculation of the errors of the measurements of size distributions and gold assays performed during the GRG test. The uncertainties of the concentration performances and liberation size estimate are then calculated and their impact on the results interpretation is analysed.INTRODUCTIONDuring the development of a mining project, samples are taken for metallurgical tests. The sample can be a composite sample made of material from a selection of various drilling products or a sample from a mining test. It can be also a sample from an existing plant in order to investigate process enhancement. This sample can represent several tonnes of material which are analysed and split for use in various tests. In order to take into account the ore variability in terms of gold deportment, it is recommended to perform variability studies (Dominy, Murphy, & Gray, 2011, Dominy, 2013) using samples representing various horizons or years of production. But for a given ore type, it can be necessary to perform many tests with different operating conditions (Brochot, 2012a). In that case, the variability of the samples is not due to the heterogeneity of distribution of the deposit, but only on the heterogeneity of constitution of the primary sample. The level of confidence associated with the estimated performance parameters is directly linked to the overall error (including sampling error) of the measurements performed during the tests."

Jan 1, 2016

By Song Mao, Local Joint Engineering Lab of Efficient Util of Dominant Mineral Resources from Karst Regions, Guizhou Key Lab of Comprehensive Utilization of Non-metallic Mineral Resource, Xianhai Li, Qin Zhang, unjian Ye, Guizhou University, Wei Cheng, Zhihong Liu

"Phosphate tailing is a kind of industrial waste that emitted from separation processing of phosphate ores, which is usually discarged to the tailing pond without treatment. Recovery of phosphorus from tailings is of great significance for comprehensive utilization of phosphorus resource. Chemical composition of a micro-fine cryptocrystalline phosphate tailing was investigated by X Ray Fluorescence (XRF) and Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES), and mineral composition and occurrence of harmful elements were analyzed by optical microscope and Scanning Electron Microscope (SEM), X ray Energy Dispersive Spectrometer (X-ray EDS) and Mineral liberation Analyzer (MLA). On the basis of above, effects of those on mineral processing for phosphate tailing was analyzed. Chemical analysis results in combination with microscopy indicated that there is a certain amount of iron and aluminum and it should focus on the removal of them in separation processing. The cryptocrystalline structure, especially the micro banding structure and micro porphyritic structure indicated that there is quite amount of phosphate in fine particles and it should recovery the phosphorus as much as possible when designing the flotation technology for this difficult separation fine phosphate tailing. This study can provide theoretical guide for efficient phosphorus recovery of from fine phosphate tailing by flotation.INTRODUCTIONPhosphate rocks are vital nonrenewable resources and are essential components in agricultural fertilizers and phosphorous-based chemicals (Gharabaghi et al., 2009). About 95% of the phosphate produced around the world is consumed in the fertilizer industry (page 60 Abdel-Zaher, 2008; Jasinski, 2007). Froth flotation, a solid wettability based separation process is widely used in separation of phosphate rock and shown to be effective (Yehia et al., 1990; Singh et al., 1992; Elgillani and Abouzeid, 1993; Al-Fariss et al., 2013) .Poor selectivity and low recovery for micro-fine particles are hard issues in flotation of middle-low grade phosphate ore because Phosphate resources is becoming poor, fine and complex as the rich ores run out since the 1970s. The rapid depletion of high grade ores forces minerals industry to process low grade ores where finer grinding is required to achieve required liberation of the values, making the fine particle flotation inevitable. the performance of conventional flotation deteriorates rapidly as particle size decreases to below 10-20 µm, depending on the density of the particles (Feng and Aldrich, 1999). To date, fine particle flotation is still considered to be a challenge in mineral processing (Li et al., 2015) ."

Jan 1, 2016

By A. E. Boudreau

It has long been recognized that platinum-group-element (PGE) deposits in layered intrusions preferentially occur in intrusions that crystallized from high-Mg parent magmas. Recent studies suggest that evaluation of any given intrusion for economic PGE potential should also include assessment of the PGE, sulfur and chlorine concentrations in the cumulates and potential parent liquids. PGE: Magmas that contain relatively abundant Pt and Pd are the best candidates for forming economic deposits. Although analyses of coeval sills and dikes are the best indicators of primary magmatic PGE concentrations, analysis of the cumulates themselves is also valuable. For example, within the Stillwater complex, background PGE values in cumulates from the ultramafic sections of the complex contain, on average, several 10s of ppb Pt and Pd. Background concentrations of this order are suggestive that the magma was not depleted in the PGE. Sulfur: Conventional petrogenetic models for the formation of PGE deposits in layered intrusions require the PGE to have been concentrated during a magmatic sulfide-saturation event. In contrast, some hydro thermal models suggest that sulfur and the PGE were mobilized from footwall cumulates by upward-migrating, high-temperature hydrothermal fluids. Both models suggest that significant PGE deposits are likely to occur at and below the level where stratigraphic increases in whole rock sulfur concentrations occur. Chlorine: In both the Stillwater and Bushveld complexes the cumulate sequences below the major PGE-bearing zones contain anomalous Cl-rich apatite. The chlorapatite component of apatite in these rocks may exceed 40% and, in the Stillwater complex, typically exceeds 90%. It is stressed that pristine igneous mineral analysis and not whole rock data be used, as whole rock Cl concentrations may be affected by very localized (grain boundary), low-temperature alteration. Intrusions that crystallized from high-Mg, high-Cl magmas appear to have the best potential to host significant PGE deposits.

Jan 1, 1995

By M. Gauthier, A. C. Brown

"Monometallic zinc mineralization associated with marbles of the Grenville Supergroup in the Mont-Laurier Basin of Quebec is found to be stratiform and to occur (1) within limited zones of dolomitic marble and (2) more precisely along contacts between these marbles and adjacent metaclastic units. Massive sphalerite with accompanying pyrrhotite and pyrite is the prime exploration target, and commonly gives rise to good geochemical anomalies, but generally weak and ambiguous geophysical responses. Disseminated sphalerite in dolomitic marbles may signal proximity to interesting massive mineralization, although, due to weathering, this broadly disseminated mineralization may not be detected easily on outcrops. It is concluded that the western and possibly the eastern margin of the Mont-Laurier Basin constitute favourable areas for continued exploration.IntroductionThe Grenville Supergroup marbles of Ontario, Quebec and New York State host numerous occurrences of zinc mineralization (Fig. I) , several of which have been periodically mined since the beginning of this century (Fig. 2). The Balmat Edwards district of New York is the giant of this depo sit-type, with the production since 1915 of some 20 million tons of ore grading 10% zinc, and acknowledged current reserves of approximately equal tonnage and grade. At present, there is renewed interest in the potential for similar mineralization throughout the Grenville Supergroup, and this paper outlines some of the geological, geochemical and geophysical guidelines that may be employed in the search for new ore. The geologic guidelines are derived especially from lithologic and stratigraphic features which survived intense, multiphase deformation and metamorphism.Although major portions of the extensive Grenville Supergroup hold potential for zinc mineralization, the present study is confined to a known zone of mineralization in the Mont-Laurier Basin of Quebec. Concurrently, we are compiling information on the regional metallogeny of the basin so that our conclusions can be applied to areas of similar Grenville Supergroup host-rocks elsewhere."

Jan 1, 1980

By H. Nejati

Experimentally, the Semi-Circular Bending Moment (SCB) fracture toughness test results of Basalt Specimens Under Illumination (BSUI) have shown reduction in fracture toughness and failure force as a result of micro-cracking. The fractographic investigation of BSUI confirms initiation and extension of micro-cracks. Determination of a relation between strength reduction (herein fracture toughness reduction) and density, location and orientation of thermo-mechanical induced cracks due to microwave radiation is critically important. Numerical modeling can bridge strength reduction and the density of thermal microcracks generated due to microwave radiation. Discrete Element Modeling (DEM) is a power tool for simulation of micro-crack initiation, coalescence into macroscopic fractures and failure mechanisms in brittle rock specimens under different stress regimes (herein combination of pure tensile stress due to SCB testing, and thermal stress due to microwave radiation). For this purpose, a DEM modeling of SCB testing of basalt using EDEM (i.e., a DEM based software). DEM models are calibrated according to results of experimental SCB testing as reported in previous papers. This paper first reviews some background data on SCB fracture toughness, and experimental results of fracture toughness of microwave treated SCBs. Then it proposes a new methodology for simulation and validation of rock samples exposed to microwave illumination with regard to experimental results, and discusses the correlation between fracture toughness of BSUIs and density of micro-cracks, which is attributed to applied microwave power and duration of illumination.

Aug 1, 2013

By E. O. Reinbold, J. H. Johnson, D. E. Keski-Hynnila

A field laboratory for use in monitoring underground mine air quality has been developed and proven in underground service. The laboratory includes two separate monitoring systems and data analysis computer programs. One is the Mine Air Monitoring Laboratory (MAML). This is an enclosed trailer-mounted laboratory capable of monitoring CO2, CO, NO, NO2 particulate matter, S02, NH3, temperature and air velocity in the mine drift. The MAML can be up to 1000 feet away from the area being monitored. The second system is the vehicle data system, mounted on the load-haul-dump (LHD) vehicle, which monitors engine speed, engine fuel rack position, exhaust gas temperature, ambient temperature, vehicle speed, CO2 concentration near the operators' breathing zone and the mode of operation of the vehicle. The two computer data analysis programs and the two field instrument systems comprise a complete Mine Air Quality Laboratory (MAQL) for underground pollutant studies. Data from the systems have been used for studying vehicle duty cycles, ventilation systems, exhaust after-treatment devices, vehicle exhaust system design and portable instrumentation. Descriptions of the laboratory are presented along with a summary of some of the experiments performed. The capabilities of the lab are discussed, along with future potential uses.

Jan 1, 1981

By Michel G. Grenier

Compliance with Diesel Particulate Matter (DPM) exposure regulation is currently performed using timeweighted average (TWA) sampling on underground mine workers. These samples are collected in the span of an entire shift and the resulting concentrations are compared to a legislated exposure limit. While this is very useful to determine the exposure level of an individual to DPM, it fails to clearly identify causes of exposure and highlight opportunities that could help reduce the exposure of workers in the course of the work shift. Real-time DPM monitoring measures the worker?s exposure as a function of time and helps identify circumstances where corrective actions can be taken or design changes can be made by the individual or the employer to reduce the overall exposure of the worker and peers. This work focused on obtaining DPM concentrations using a real-time polycyclic aromatic hydrocarbon (PAH) monitor. The aim was to demonstrate that this instrument, while not a direct DPM analyzer, was able to provide a concentration profile that could easily be linearly correlated to standard TWA elemental carbon measurements. In addition, several instances of improvements that could be implemented to reduce the exposure of underground employees were demonstrated.

May 1, 2010

By K. Eklund, T. Ahokainen

The Flash Smelting process is the most used production method for primary copper in the world. The basic idea of the Flash Smelting is to utilize the thermal value of sulfidic concentrates and melt the reaction product, in controlled conditions, without a need for external energy. This basic principle is utilized both in matte smelting and in Direct-to-Blister Flash Smelting Processes. In this paper, the behavior of normal (CuFeS2) concentrate of FSF-process is compared to the behavior of high grade feed material produced by Outokumpu Concentrate Upgrade Process with the aid of computational fluid dynamics (CPD) simulation using add-in subroutines developed by Outokumpu Technology. Results consist of the information concerning the behavior of the suspension, reaction efficiency and other parameters concerning the reactions of the feed material. It will be shown that, using the Upgrade Process, the throughput of copper from the Flash Furnace can be almost tripled.

Jan 1, 2007

By Laxman M. Amaratunga

Laboratocy flarmnability tests were perfonned on dust samples from Fraser Mine in a 1.2 L Lindenburg horizontal tube furnace to detennine the percentage of sulphur oxidized during ignition. The explosion pot ential of sulphide dusts depends on their degree of spontaneous oxidat ion, which was measured by the quantitative analysis of so2 gas released during ignition. Test results indicated that dusts with low sulphur content could exhibit a higher degree of oxidation than a sample with high sulphur content. txlst characterisation using image analysis techniques suggests that the structure and the texture of dust are important factors influencing the explosibility of sulphide dust at ignition temperatures. Therefore for safe mine operations% sulphur content cannot be considered as a reliable single index that could be used to predict the potential of a sulphide dust explosion. Physical, chemical and mineralogical characterisation of dust plays an important role in the detennination of suitable indices for the prediction and prevention of sulphide ore dust explosions.

May 11, 1988

By K. Bruce Hodgins

The North American mining industry faces challenging emissions regulations in coming years with the introduction of new standards for off-road diesel engines. In order to remain competitive, industry stakeholders must invest in new technologies that are economically and environmentally sustainable. Westport Innovations Inc., of Vancouver B.C. has developed high pressure direct injection (HPDI) technology that allows diesel engines to run primarily on natural gas with no intrusive engine modifications, reduced emissions of NOx, PM, and CO2, with no loss in performance. This is accomplished through late-cycle high-pressure injection of natural gas directly into a diesel engine combustion chamber. The natural gas is injected at the end of the compression stroke. A small amount of diesel fuel is injected first to initiate combustion, followed by the main natural gas fuel injection. The diesel cycle and its operating characteristics are fully retained including high combustion efficiency, low speed torque, high-power output, no engine knock and fast response to load changes. Natural gas has not been an attractive fuel alternative in mining operations due to reduced performance associated with spark ignition engines and the added weight and space required for compressed natural gas tanks. However, liquefied natural gas (LNG) can be stored in a similar manner and volume to diesel fuel by virtue of its increased energy density over compressed natural gas. Cummins, Inc. of Columbus, Indiana and Westport have formed a joint venture, Cummins Westport Inc. (CWI), under which agreement the HPDI technology is being applied to a Cummins QSK engine series for high horsepower applications such as mine haul trucking. CWI, along with Komatsu Mining Systems, ENRG Fuels, Placer Dome, and Cortez Joint Venture are performing a feasibility study for the development and demonstration of an LNGfueled HPDI QSK engine in a large mine haul truck. The goal would be to demonstrate low emissions consistent with EPA ?Blue Sky? standards, high efficiency based on HPDI technology and good economics resulting from the high fuel consumption of 2,000+ hp trucks.

May 1, 2002

By I-H. Jung, J. Kim

"Mg alloys are extensively used as light structural materials in modern industry. Mn and RE (rareearth) metals are effectively used as alloying elements to enhance the properties of Mg alloys. Therefore, the thermodynamic database of those alloys is important in the Mg alloy design and processing. Critical evaluation and optimization of all available literature data for the Mn-RE systems were conducted to obtain reliable thermodynamic functions. The Mn-RE systems shows systematic changes in the phase diagrams and thermodynamic properties with increasing atomic number in the lanthanide series. This systematic approach for all RE elements allows to resolve inconsistencies in the available experimental data. INTRODUCTIONRare Earth (RE) metals are widely used in many industrial fields including permanent magnet, electronic materials and structural materials. As a small addition of RE can enhance magnetic, electronic, optical and mechanical properties of numerous materials, the usage of the RE is still expanding regardless of the strategic control of their supply.Magnesium alloys are getting great scientific and industrial attention as the lightest structural materials. One of the drawbacks of Mg alloys is their poor formability at room temperature due to the limited slip system with hcp crystal structure. Recently, several studies (Farzadfar et al., 2011; Sandloebes et al., 2010; Stanford, 2010; Stanford et al., 2008; Yan et al., 2010) show that the additions of small amounts of RE can considerably enhance the ductility of Mg alloys. Therefore, a lot of research on Mg-RE alloys is undergoing to clarify the role of RE on the enhanced deformation mechanism and to find out the most optimum Mg alloy compositions. In order to respond to the need of Mg-RE alloy development, a large thermodynamic database for Mg alloys containing RE has been developed with critical systematic analysis and optimization of the entire RE series data. This includes the thermodynamic database of the Mg-RE (Kang et al., 2009), Mg-RE-RE (Kang et al., 2009), Mg-Al-RE (Jin et al., 2011; Jin et al., 2010), Mg-Zn-RE and Mg-Mn-RE systems."

Jan 1, 2012

By J. C. Kingston

Introduction The sliding-form method of erecting concrete structures was first devised and used in the early part of this century by the Sante Fe Railroad Company for the erection of a grain elevator at Santa Fe, New Mexico. A somewhat related principle has been employed for a number of years in shaft lining work and, to our knowledge, was perfected in Butte, Montana, but until the building of the concrete headframe at the Jeffrey mine of the Canadian Johns-Manville Company, Ltd., at Asbestos, Que., the method, as applied to surface structures, was quite foreign to the mining industry in Canada. The current shortage and cost of structural steel shapes has no doubt contributed more than any other single factor to the investigations that have led to the use of reinforced concrete as a headframe building material. Mining men in western Quebec and northern Ontario have shown a great deal of interest in the design and construction of the headframe at the East Sullivan mine in Bourlamaque township, Que., and we have had many queries regarding the methods used and, in particular, for an explanation of the sliding-form principle. This article is written in an attempt to set forth the conditions which were to be met; to explain the construction methods used, and to discuss the economy of concrete headframes as compared with the conventional steel structures with which the mining fraternity is familiar.

Jan 1, 1949

Arguably the SMC Test® has become the most popular laboratory hardness test in the world with over 17,000 tests having been completed to date, covering over 650 different ore bodies. It is now routinely used in design, optimisation and orebody profiling projects. The test is unique in that from relatively small amounts of drill core it simultaneously provides parameters that are used in simulation modelling of AG/SAG and crushing circuits as well as work indices that are used in power-based equations for predicting the specific energies of AG/SAG/Crushing and HPGR circuits. The very large data base that has been accumulated has provided the opportunity to study the differences in variability from deposit to deposit. This paper describes and discusses the trends that have become apparent from the study of this data base. Recommendations for appropriate selection of sample numbers are also made which are based on these trends.

Jan 1, 2012

By F. Parada, R. Parra

"The neutralization process of SO2 from coal burning plants is a well-defined technology using limestone to form CaSO4 according to the following reaction: CaCO3 + SO2(g) + 1/2O2(g) = CaSO4 This paper presents the results of a study carried out to validate the option of capturing SO2 using gases from a non-ferrous smelter; SO2 content was up to 12% using a three-stage fluidized bed reactor. The difference in SO2 content affects equilibrium conditions and kinetics, rendering a direct extrapolation of the high efficiency achieved for low SO2 content impossible. The R&D program consisted of a laboratory study using a semi-pilot operation of a one-stage fluidized bed reactor and the construction and operation of a three-step reactor prototype. Results show that the reaction proceeds according to the unreacted core model that imposes a compromise between CaCO3 conversion and SO2 capture. For high SO2 capture, the calcine from the reactor contained CaSO4 and CaO. A complete capture of SO2 from gases with 8 vol.% can be achieved with a mean reaction time of two hours at 800°C."

Jan 1, 2007

By Yasuo Iizuka

We have had studied CO oxidation on unsupported Au powder (mean particle size, ca.100nm) manufactured by evaporating ultra high purity gold metal (>99.99%) in inert gas and reported that it showed some activity after oxidizing pretreatment in O2 at 423 K?453 K. However, recent XPS analysis of the Au powder revealed that it contains much amount of impurity metals such as Ag and In at levels which far exceed those expected from the impurity level of raw gold metal in the bulk. Several samples of Au powder containing different amount of impurity metals were prepared to examine whether the activity depends upon the existence of surface impurity or not. Activity measurements were performed at 273 K after undergoing the powder under various pretreatment conditions. Although the activity of Au powder varied to some extent according to the pretreatment condition, it is strongly correlated to the surface concentration of Ag. Such dependence was not found for In, indicating that the activity of unsupported Au powder is mainly due to the existence of Ag in the surface layer. The activity attributable to ?particle size effect? was not recognized for Au powder with a mean particle size larger than 80 nm.

Oct 1, 2003

By V. G. Papangelakis, T. Clark, G. Kolliopoulos

Sustainability of the hydrometallurgical industry requires the development of processes for effective water recovery; if process water is recovered and recycled, fresh water intakes will be reduced. Forward osmosis (FO) is an innovative membrane process that promises to recover water from industrial process aqueous streams or seawater with less energy input compared to reverse osmosis (RO) and evaporation; the energy efficiency relies on the spontaneity of the process (no energy input required). The driving force of the process is the osmotic pressure gradient between a dilute feed solution (process water) and a concentrated draw solution. The draw solution is an engineered aqueous solution that contains a highly soluble chemical reagent that is able to osmotically "draw" only water from the dilute stream, through a semi-permeable membrane, leaving behind a small volume of concentrated brine. The draw solute is separated and recovered for reuse, leaving behind water. The main energy requirements of the FO process arise from the separation and the regeneration of the solute chemicals from the diluted draw solution. This work focuses on the evaluation of aqueous carbonated trimethylamine (TMAH:HCO3) as the draw solution and reports recent findings on the separation efficiency of TMA and CO2 from the solution.

Jan 1, 2015

By Eric D. Marks

Fatalities resulting from ground workers colliding with objects and construction equipment accounted for approximately 18% of the total construction fatalities experienced in 2010. Current injury and fatality measuring methods have proven to be inadequate due to their use of passive measures of safety rather than a more active approach, such as the use of leading indicator data (also called near misses) of hazardous proximity situations between ground workers and heavy equipment on construction sites. The objectives are to create and evaluate the effectiveness of a reliable algorithm for collecting and analyzing the resulting leading indicator data from hazardous proximity situations. Numerous experiments emulating typical interactions between workers-on-foot and heavy equipment are used to evaluate the proximity sensing and detection technology. Safety leading indicator data (also called near misses) generated by the proximity sensing and detection technology during the experimental trials are used to create and assess the resulting algorithm. Results from the experiments indicate that leading indicator data generated from these systems can be processed and analyzed to identify hazardous proximity situations and incidents on construction sites.

Aug 1, 2013