Search Documents

By I-H. Jung, J. Kim, B. Konar

"The usage of FeNdB permanent magnet, containing Rare earth elements (REEs), is steeply increasing with its demand for wind-turbine and electrical vehicle. The improvement and recycling of the permanent magnet require good understanding of chemistry of all constituent elements. In order to understand the chemical interactions between REEs and Fe, all Fe-RE binary systems have been critically assessed and optimized based on reliable literature data. The Modified Quasichemical Model and Compound energy formalism is employed to model the liquid phase and the solid solutions present in the binary systems respectively. The enthalpy of the liquid and the intermetallic phases showed a systematic trend along the lanthanide series. This helped to mitigate the discrepancies in literature data and also to predict the binary interactions between some less well investigated Fe-RE binary systems. INTRODUCTIONRare Earth elements (REEs) are a group of seventeen elements (including Scandium, Yttrium and the lanthanide series) that exhibit same characteristic chemical and physical properties. These properties make them valuable to the electronic, appliance, green technology, weapon and medical device manufacturing industries. Compounds of REE with other metals (like Co, Fe, Ni etc.) have unique properties of luminescence, thermal and electrical conductivity, magnetism and ability to act as catalysts and polishing compounds (Gschneidner ,2011).They are not only indispensable for some electronic gadgets of today, like computers, music systems, mobile devices, televisions and MRI machines, but also holds a key to more greener technology of the future. They contribute to the development of more efficient and environment friendly version of everyday products such as cars and light bulbs. REE compounds revolutionized the magnet industry by making them smaller and more powerful with increased longevity, and high temperature workability, which are used in motors and generators that power electronics, telecommunications, electric automobiles and turbines(Humphries, 2011)."

Jan 1, 2012

By J. Koponen, K. S. Stadler, A. Fuerst, S. Gaulocher, Th. von Hoff, R. Veldsman

"Gearless mill drives (GMDs) are the workhorse in the mineral processing industries, more specifically when it comes to grinding crushed ore and cement (in various production stages) in semiautogenous (SAG) mills and large ball mills. They are renowned for their excellent reliability and robustness, long lifespan, and little need for maintenance, and thus yield a low total cost of ownership (TCO).A GMD represents a major investment for a mineral processing plant, and its availability is pivotal for the grinding process. As a basic rule, shut-down periods are to be minimized, but even much more important is that unscheduled shut-downs be avoided. In this contribution, we will present a portfolio of innovative remote diagnostic that consist of the following three key components:1. Trouble shooting is a form of corrective maintenance and is based on state-of-the art remote access technology, thus enabling highly skilled engineers to access the current sensor readings anytime and from anywhere in order to resolve urgent problems together with the GMD user.2. Periodic maintenance reports are a form of preventive and predictive maintenance and aim at continuous improvement based on long-term historical records and analyses of multiple measured signals. These detailed reports highlight the health and operational status of the GMD and are periodically (e.g. 3 months) submitted to the customer.3. Remote condition monitoring spans across preventive and predictive maintenance and is based on continuous recording and automatic analyses of relevant signals using advanced algorithms. The main issue is how to handle the enormous flood of data in an intelligent manner. The results of these analyses are made available to both the GMD user and supplier in real time in order to increase the availability and reliability of the GMD.In this paper, we consider various parts of the GMD, e.g. the cycloconverter, the ring motor, the auxiliary devices (e.g. cooling and lubrication systems), and also phenomena related to the mill itself (e.g. state and quantity of charge). The signal analysis techniques range from simple threshold-based analyses to complex time and frequency domain analyses. We will illustrate the benefits of the proposed approaches with some selected examples."

Jan 1, 2012

By L. C. Johnston, J. N. Gills

This paper reviews the basic reactions of the blast furnace and the open hearth furnace, and then discusses the quarrying and sizing requirements of the limestone feed for each. Particular emphasis is placed on the lime-stone at Irish Cove, now being mined under an agreement between Scotia Limestone Limited and Dosco Steel Limited. The drilling and blasting operations are described, along with loading and haulage, plant flow, water supply, power supply and transportation facilities.

Jan 1, 1967

By Balmer Neilly

We are regularly told that before making a new investment one should seek the advice of his banker. If we were to place the subject matter of this paper before bankers. other than those who have experience in our mining camps, their reply would probably be evasive. However, if for example: a mining company asks them for a loan and offers as security certain mining investments, they are, in most cases, explosively candid. The idea is preposterous, unless, under Section 88 of the Bank Act, the mining company is able to deposit with the bank, gold or silver bullion, to an amount sufficiently in excess of the loan, to provide for what the banker describes as a reasonable margin of safety in case of contingencies. In addition the directors of the mine personally must jointly and severally guarantee payment of the loan. With any of these conditions missing the banking atmosphere becomes chilly. The local manager explains that the general situation, and particularly European conditions, are so unsettled that head office has warned him that his discretionary powers must not be exceeded under any circumstances.

Jan 1, 1924

By P. Ramirez

"To achieve an optimal metallurgical performance in the flotation process the bubble diameter should be between 0.5 and 2.5 mm. To control bubble size, frothers are added, reducing bubble size and conferring bubble stability against coalescence. However, the bubble generation mechanism determines predominantly the bubble size distribution produced. In mechanical flotation cells, bubbles are produced by the shear stress generated by a rotating blade on a gas stream. This mechanism produces a log normal bubble size distribution. In contrast, in column flotation, jetting gas injectors are commonly used in Chile and the bubble size distribution is bimodal with small and large bubbles. Bubbles larger than 2.5 mm mean a loss in surface area, while bubbles smaller than 0.5 mm move with the pulp stream and therefore collide less frequently with particles. In this paper, a new device based on a jetting sparger and a deflector disc (impinging jetting) is evaluated as an alternative sparger for column flotation.The new device was tested in a rectangular acrylic cell 1 m × 0.5 m × 3 m. High-speed cinematography was used to compare bubble generation with jetting and impinging jetting at different gas velocity in the nozzle (5–50 m/s). From the image analysis, it was observed that the deflector induces a shear stress, in analogy to a rotating blade but in this case the shear results from a high velocity gas hitting a static surface. The device was evaluated in a 0.5 m diameter 3 m high column. The McGill bubble viewer technique was used to compare the bubble size generated by jetting and impinging jetting. It was found that the Sauter mean bubble diameter reduced from 7.4 mm to 2.8 mm, when the jetting sparger was modified with the deflector. In the case of the impinging jetting sparger, 70% of the bubbles were in the effective range for flotation, while for the jetting sparger, only 10% were in the effective range."

Jan 1, 2016

By R. M. T. Raja Ismail

Shipping and stevedoring industry is going to witness a massive increase in the amount of containers to be handled while land constraints become more critical. Offshore transfer operations hence offer a preferable solution to deal with the surge in cargos rather than to expand the port outwards. Recently, there has been increasing research interests on offshore crane automation. Suspended cargos in a ship-mounted crane system are caused to swing due to the vibratory motion of the ship induced by ocean waves, which can lead to collision between cargos and deck. Therefore, it is vital for offshore crane systems to satisfy rigorous requirements in terms of safety and efficiency. This paper presents the modelling and control development for offshore boom crane systems. A second-order sliding mode control law is proposed for trajectory tracking and sway suppression control, making use of its capability of actuator chattering alleviation while achieving high tracking performance and preserving strong robustness. The asymptotic stability of the closed-loop system is guaranteed in the Lyapunov sense. Simulation results indicate that the proposed controller can significantly reduce the effect of disturbances coming from gusty waves and other dynamic loadings.

Aug 1, 2013

By C. L. Popp

The scope is to address issues confronted by parties in the mining industry such as: Mine planners, survey and engineering departments, field teams and subcontractors. Describing approaches and best practices for assembling a project team to identify and create modeling requirements and to implement beneficial results. 3D Machine Control and Guidance tools continue to reduce project risk and attract quality resources with skill sets new to the earthmoving industry. These tools increase production, reduce rework and help with government permitting.

May 1, 2013

By S. Bantubani, I. Mc Dougall, S. Arjun, H. Joubert, R. Hansraj

The requirements determining the design of the Söderberg electrode columns used in base metal applications are different to those of other industries. There is a strong trend to position the contact shoes above the furnace roof in order to reduce the risk of water leakages directly onto the furnace bath. Tenova Pyromet has adapted its proven electrode column design for application on base metal electric furnaces based on these requirements. The design modifications implemented as well as considerations regarding the overall electrode-roof-furnace arrangement are discussed. Equally important is the management of the Söderberg electrodes to prevent over or under baking. Tenova Pyromet has developed the AutoFurn™ furnace controller to not only optimise furnace operations, but to improve electrode management. An overview of the electrode management control philosophy implemented by AutoFurn™ is provided, focusing on intelligent electrode regulation, slipping and baking. INTRODUCTION Tenova Pyromet has developed an electrode system for use in base metal furnaces, which builds on the experience that Tenova has gained during the past 30 years with electrodes in the ferroalloy and base metals industries. In base metals applications, an important safety consideration is the minimization of water within the furnace and on the furnace roof. In addition, direct contact between copper equipment such as contact shoes and pressure rings and the contents of the furnace is discouraged. In a 3 phase AC furnace, three electrode columns transfer the electrical energy to the furnace bath. Both Söderberg and prebaked carbon or UHP graphite electrodes are in use in base metal furnaces. In each column, the electrode is held in position by a hydraulic slipping and regulating device, a pressure ring and contact shoes. The electrodes can operate in a submerged-arc or brush-arc configuration, where the electrode is immersed in the slag or a short distance above the slag (Mc Dougall 2013). The electrode equipment is divided into an upper and a lower electrode assembly. The self-baking Söderberg electrode is made from lengths of steel casings that are added to the top of the electrode column and welded into place. Carbon electrode paste is added to the inside of these casings and is baked to form a solid tip in the region of the contact shoes. The working platform that surrounds the area where new electrode casings are added, is electrically isolated from the building and each electrode is isolated from the others to ensure the safety of the personnel who perform the electrode casing additions.

Jan 1, 2019

By H. Link

"The extremely low permeability of the water-carrying beds in the nevonian formation of the potash district of Saskatchewan does not permit the injection of cement or chemicals to seal off sufficient water from the shafts to guarantee the safety of the mine. Based on many years of experience with wet shafts in the German and French potash mining industry, Alwinsal Potash of Canada Ltd. decided to have their potash mine shaft near Lanigan, Sask., which was completed in September of 1967, lined by means of an absolutely watertight lining of combined concrete and steel-plate construction.This shaft lining, consisting of two steel shells of welded construction with concrete filled in between, has proved itself before in the German coal mining industry. It guarantees a permanently dry shaft. With this type of lining, time-robbing and very often abortive injections are superfluous and the regular repair and adjusting work as well as the corrosion of conveyances and ropes can be avoided. Above all, however, the danger of a water inrush into the shaft is abolished completely."

Jan 1, 1971

By D. Song

In this paper, the differential equations governing the mass transport and the electrochemical reaction in a cathode catalyst layer of polymer electrolyte membrane fuel cells are solved based on the polynomial series expansion method. Explicit expressions for the polarization curve as well as for the distributions of oxygen, current density and overpotential are obtained when a quadratic, cubic or quartic polynomial is employed to approximate the oxygen concentration distribution. These kinds of explicit solutions are desirable for MEA design and diagnosis purposes. The comparison between the conventional numerical approach and the explicit solution approach proposed here shows that satisfactory accuracy can be reached by the first four terms of the polynomial series. The effect of the catalyst layer thickness on the accuracy of the obtained explicit polynomial solutions is also discussed.

Jan 1, 2005

By W. J. D. Stone

Discussions with people knowledgeable in the insulating material field revealed that materials on the market would be considerably improved if there was a greater meeting of certain very desirable criteria. Such criteria include: (1) the material should not burn, even at higher temperatures; (2) at an elevated temperature, the material should not give off toxic gases or produce smoke; (3) the material should have a low energy input; and (4) vermin would find the material unattractive. Theoretical discussions led to the conclusion that an insulating material made by foaming a mineral, preferably of a platy nature, with an inorganic binding system that could be converted to a rigid structure at low temperature would likely meet all the above requirements. It was also theorized that the use of microwaves in the converting stage would be beneficial in the creation of a cellular structure by aiding the foamer through creating vacules of steam. Talc was selected as readily meeting the theoretical mineral requirement and the material of Baker Talc Limited was used as the basic filler. The early results obtained led to an agreement between Americ Mines Limited and Baker Talc Limited pertaining to commercial production in a specific geographic area. It was recognized that due to the economics of shipping, the availability of the basic filler material should be geographically widely spread. Samples of materials were requested and many received from all over North America and one from Britain. Enough work has been done to show that they respond to the basic process in a similar manner as the Baker Talc material. From the data acquired, it is considered that the process is applicable for the production of loose fill insulation, moulded insulation for pipes and structural steel, ceiling tile, batts, sheet and for incorporation into other products such as various roofing board materials. Sufficient development has been done to enable a budget to be prepared for the construction and operation of a loose fill insulation plant.

Jan 1, 1979

By A. R. Farkoosh, K. Korgiopoulos, McGill University, O. Rodop, L. A. Villegas Armenta

"New generation of Al-Mg-Si alloys with thermally stable dispersoids that prevent recrystallization and grain growth during hot deformation are currently used in automotive components requiring good formability. Alloy chemistry controls the phase formation especially age-hardening precipitates, dispersoids, and primary intermetallic which have pronounced effect on grain structure, strength and formability. In this work, thermodynamic calculations have been used to predict the effects of varying levels of Si (0.5-1.5wt%), Mg (0.5-1.5wt%) and Mn (0.1-2.5wt%) on phase selection. Thermodynamic calculations have been performed in equilibrium and non-equilibrium conditions via the FactSage™ software using the FTlite database. Selected compositions have been cast, heat treated, extruded and characterized through scanning electron microscopy with energy dispersive spectroscopy and electron channeling contrast imaging techniques. The calculations showed that at the hot deformation temperature of ~540 oC, exceeding certain Mg and Si levels would lead to retained *-Mg2Si intermetallics and Si particles at the grain boundaries in addition to a-Al-(Mn,Fe)-Si. It was found that retained *-Mg2Si phase which adversely affects formability can be avoided for Si+2Mg levels lower than 2.3wt%. FactSage calculations also showed that increasing Mn from 0.5wt% to 1wt% leads to an increase in the amount of dispersoids (from 1wt% to 2wt%) that can potentially slow down recrystallization and grain growth during hot deformation and improve formability. Calculations at room temperature also show that for an alloy with 0.7wt% Mg, excess Si beyond 0.7 wt% promotes the precipitation of Si clusters in the Al matrix that accelerate natural age-hardening. Results were confirmed by experimental investigation.INTRODUCTIONAluminum alloy 6082 (Al-Mg-Si) is used in the automotive industry because of its high strength, and good weldability (I. J. Polmear, 2006). The alloy is age-hardenable through the precipitation of ß-Mg2Si and its precursors, and the recrystallization is usually inhibited by Mn- and Cr-containing dispersoids formed through high temperature heat treatments (I. Polmear & Couper, 1988). However, it is known that minor changes in alloy chemistry (Mg/Si ratio) can have significant influences on the ductility and formability of these alloys by altering phase selection and the resultant microstructure (Gupta, Lloyd, & Court, 2001; McQueen & Celliers, 1997; Zajac, Hutchinson, Johansson, & Gullman, 1994). For automotive applications where wrought alloys (usually extrusions) are cold-formed to produce suspension components, the chemistry of the alloys and the extruded structure are of crucial importance as they determine the formability at room temperature (Asensio-Lozano, Suárez-Peña, & Vander Voort, 2014). In this study, thermodynamic calculations along with experimental investigations were carried out on the Al-Mg-Si system to understand their phase formation and precipitation hardening as a function of alloy composition."

Jan 1, 2016

By Catalin Florin Petre, Elahe Ghasemian Langeroudi, Abdelaaziz Azizi, Éric Proulx, Caroline Olsen, Paul Blatter, Faïçal Larachi, Claude Gagnon

"The recovery of gold from ores is often accompanied by the release of other species in the leach solution. This state of affairs leads to depleted free cyanide levels in the slurry. Therefore, separation and quantification of these cyanicides and free cyanide at different stages of the cyanidation process as well as in waste solutions is crucial to provide mitigation tools by preventing leaching of deleterious metals for environmental considerations.COREM and the research group of Prof. Larachi have been working together on the control of gold passivation and cyanicides during cyanidation for several years. Previously, a first capillary electrophoresis (CE) protocol for the speciation of sulfur and cyanicides (SCN-, Cu, Fe) during cyanidation of gold complex sulfide ores was developed and validated for assessing industrial process water.The separation of zinc cyanide complexes used to be confronted with a number of difficulties due to the weak and/or undetectable cyanocomplexes in formally available CE protocols. Moreover, according to our knowledge, no direct CE protocol exists to separate free cyanide. Therefore, a new study aimed at developing a second CE protocol for the detection and quantification of cyanide complexes of zinc and nickel as well as of free cyanide in the cyanidation process water.To achieve this goal, six common carrier electrolytes such as pyridine, trimellitic acid, 4-methylbenzylamine, sodium chromate, phthalic acid and tris base were studied, using an indirect UV detection method. The best results were obtained using sodium chromate for which all ions were successfully separated and quantified. In addition, the effect of electric field strength, injection volume, electro-osmotic flow (EOF) modifier and background electrolyte (BGE) concentration were examined, while peak height, peak area and noise were considered for optimization.As a result, the new protocol is expected to complete the initial CE protocol by detecting cyanide complexes of zinc and nickel as well as free cyanide. Moreover, analytical determination of free cyanide in the presence of weak cyanide complexes achieved by the new protocol was also compared to conventional titration using silver nitrate solution. This new CE protocol will contribute to applied research and help plants to better understand and eventually control the behaviour of cyanidation circuits."

Jan 1, 2011

By E. Haccuria

Due to the growing share of electrical cars, the use of lithium ion batteries significantly increased. Recycling of these batteries is essential to safely dispose hazardous materials as well as to recover valuables (Cu, Ni, Co, etc.). In order to optimise the recycling process, accurate information is required on the slag phase equilibria for battery smelting. The slag is a multi-component system containing alumina from the battery cases, silica and lime from fluxes, and manganese and lithium from the electrode materials. The present study accurately determined the phase equilibria in the "MnO"-Al2O3-SiO2 sub-ternary system at metal alloy saturation. Particular attention was given to the accuracy and reliability of the final results by highlighting the different reaction pathways, mass transfer- and reaction mechanisms taking place in the system during experiments. This attention enabled improved experimental methodology and measurements. Based on the present study, further measurements will be undertaken in the quaternary "MnO"-Al2O3-CaO-SiO2 system at low "MnO" concentrations, which closely represents the future recycling industrial slags.

Jan 1, 2014

By Jinsuo Zhang

Investment in coal resource development is affected by a variety of uncertain factors. Investors can make a flexible, strategic decision to achieve the value of risk implicated in those uncertain factors. Therefore, based on real-option theory, we identified key uncertain factors that affect a coal resource investment project, and revealed the formation mechanism of option value in coal resource developing investment project. Then, a multi-factor decision making model was established for a coal resource development investment project with random changes of coal price, interest rate, convenience yield and production cost. Finally, we tested the model and analyzed relevant parameters by applying living data. Our results indicate this model reflects the value of risk implicated in uncertain factors for coal resource development investment, and is able to determine a critical point of decision making change when coal price and production cost varym respectively. By means of parameters analysis, the convenience yield has a positive effect on the project value. The interest rate has a negative effect.

Aug 1, 2013

By R. Barbaroux, B. Dubreuil, D. Lemieux, K. Nasrallah, G. Garcia Curiel

"As conventional, base or precious metal ores are being depleted worldwide, the mining industry is being faced with an increasing exploitation of arsenical sulfidic ores. Enargite is a common example. The downstream processing of these ores poses several problems ranging from high smelter penalties to finding economical and environmentally acceptable means of disposing of the arsenic. Several hydrometallurgical processes have been proposed for extracting arsenic from enargite concentrates, notably using alkaline sulphide leaching (ASL). However, few alternatives exist for removing the arsenic from solution and stabilizing it in an approach that is both economical and environmentally acceptable.Dundee Sustainable Technologies (“DST”) has developed a technology for the sequestration of arsenic by vitrification. Originally optimized to cost-effectively stabilize arsenic trioxide (As2O3), DST has shown that vitrification could be successfully extended to the stabilization of other arsenical products, such as calcium arsenate (Ca3(AsO4)2) and sodium arsenate (Na3AsO4). In this paper, the vitrification of arsenic in the context of an enargite leaching was newly explored and demonstrated successfully.Two processing routes are being proposed by DST for the removal of arsenic from enargite concentrates and their stabilization by vitrification. In one route, arsenic is extracted by ASL and is then precipitated under atmospheric conditions and with minimal use of reagents and time. The resulting precipitate is an unstable hydrated ferric arsenate (FeAsO4•2H2O) that is then vitrified in a non-dilutive method, significantly increasing the stability of arsenic and meeting the TCLP guideline. Unlike is required for scorodite, stabilization was successfully achieved without concern for the crystallinity of the precipitate."

Jan 1, 2017

By K. E. Harley, M. J. Whiting, T. J. Sabin, E. M. Ryan, J. F. Watts

"Wire and Arc Additive Manufacturing (WAAM) has the potential to enable a very significant reduction in buy-to-fly ratio compared to conventional manufacturing through the ability to build near-net shape components. Components manufactured from AA 2319 by WAAM can exhibit significant levels of porosity. There is also a variation in the physical appearance of the surface deposit sometimes found on such components. This deposit is similar to those observed on aluminium joined by MIG and TIG welding processes. It has been suggested that both the bulk porosity and the surface deposit are caused by hydrocarbon-based lubricant on the feedstock wire. An established correlation between surface deposit and porosity would offer valuable insight into WAAM products and enable early interventions in quality control or process monitoring based on visual examination. The relationship between the nature of the surface deposit and porosity has been studied for AA 2319 WAAM components manufactured using different wire batches. Evidence is presented to support the assertion that (i) there does not appear to be a relationship between surface deposit coverage and porosity, (ii) batch-to-batch variability in feedstock wire affects porosity. This study has led to a better understanding of the cause of porosity in WAAM components.INTRODUCTION There is a high cost associated with conventional, subtractive manufacturing because of the high ‘buy-to-fly’ ratio, a measure of the initial material bought compared to the material found in the finished part (Allen, 2006; Yilmaz & Ulga, 2016). A typical aerospace product may have up to 90% of the purchased billet of forging machined away which is cost inefficient and high in material waste. Wire and Arc Additive Manufacturing (WAAM) has the potential to reduce costs and lead time. Robotically controlled weld torches rapidly deposit feedstock wire in layers to build large near-net shapes with mechanical properties similar to those of conventional manufactured parts (Sequeira Almedia & Williams, 2010; Martina et al., 2012; Ding et al., 2015; Williams et al., 2015). A high level of porosity variation has been observed in aluminium WAAM parts (Cong, Ding & Williams, 2014; Gu et al, 2016) which can result in a range of material properties (Rudy & Rupert, 1970). This leads to difficulties in regards to standardisation and qualification of process and parts. In order for WAAM to be used commercially, porosity will need to be understood, monitored and reduced to a reproducible acceptable level or eliminated."

Jan 1, 2018

By A. Oja, M. Lahtinen, P. Salonen, B. Saxen

Most of the secondary and low grade zinc raw materials cannot be treated successfully by either conventional roasting - leaching - electrowinning (RLE) process or even by atmospheric direct leaching process. The problems arising especially from high impurity content of these raw materials can be effectively solved by implementation of the solvent extraction process. The utilization of solvent extraction process has been demonstrated by Outotec with raw materials like Waelz oxide, crude zinc oxide and zinc containing concentrator tailings. Based on batch and continuous test work it has been shown that SHG quality zinc can be produced even from the lowest grade raw materials. Impurity control in the solvent extraction process has been examined. The solvent extraction process is the key feature of the whole zinc plant for such raw materials. However, design of the entire zinc process including neutralization and bleed treatment is important for optimization of investment and operation costs of the plant. Very careful evaluation of the zinc process with modern simulation tools is essential. The optimized Outotec zinc process ensures a sustainable and profitable process containing minimal effluent and requiring little residue treatment.

Jan 1, 2014

By J. Gebhardt, D. McBride, C. R. Bennett, Croft. N., M. Cross

A comprehensive model of solution flow through heap leach systems requires a numerical solution with the ability to predict variably saturated-unsaturated flow through porous media domains that contain materials with spatially variable properties. The types of flow associated with stockpile leach processes lead to flow problems, such as infiltration into dry soil, drainage, perched water tables and flow through heterogeneous materials. Computational methods for modelling this class of flow behaviour are conventionally based on the classical Richards' equation. However, the governing equations are highly non-linear, difficult to solve, and require iterative numerical solution methods. The pressure-based form of the Richards' equation suffers from poor mass balance, while the mixed form can possess convergence difficulties. An adaptive transformed mixed algorithm is described, which reduces the non-linearity of the problem, optimizes the time step size, and provides a fast, numerically robust scheme that significantly reduces computation (or CPU) time. This method is shown to give fast, accurate solutions on a number of complex flow problems. The utility of this algorithm is illustrated through its implementation within the PHYSICA computational modelling software, which incidentally, provides a framework for a comprehensive heap leach model.

Jan 1, 2005

By S. Kelebek, E. Yalcin

"Diethylenetriamine (DETA) and/or triethylenetetramine (TETA) are reagents that can generally be categorized under ""flotation modifiers"". These polyamines are known to be effective for the deactivation/depression of pyrrhotite that is present in Canadian nickel-copper sulphide ores in large quantities. Recent bench scale testing on some of these complex ores indicated that chalcopyrite flotation can also be adversely affected under certain conditions involving polyamines, which may be taken to be an evidence of their specific affinity towards chalcopyrite. In general, DETA shows no significant depressant action on chalcopyrite while TETA's promotion of hydrophilicity for this mineral has been observed even in the presence of xanthate. This prompted an investigation on thermodynamic equilibria involving these polyamines and copper ions. Results serve a useful purpose to identify conditions for deactivation phenomena. CuDETA2+ and CuTETA2+ chelates as products of sequestration have large predominance areas covering a wide range of redox and pH conditions, where copper xanthate species are not stable, especially in the presence of TETA."

Jan 1, 2009