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By B. MohammadSadeghi, S. Bakhshivash, M. Haghshenas, F. Rahimi

"Constrained groove pressing (CGP), as a severe plastic deformation (SPD) technique, is one of the applicable methods for sheet metal forming capable of producing ultra-fine grained materials (UFGMs). In CGP, processing and die design parameters can significantly affect the deformation response of sheet metal specimen. Having said this, in the present research the effects of die design variables and processing parameters (i.e. shear angle and friction) on the deformation behaviour of an Al-Mg-Si Alloy are studied thoroughly. Finite element analysis (FEA), was used to evaluate the effectiveness of mentioned parameters on the deformation homogeneity, strain distribution and pressing load variations. Also, mechanical properties of the deformed sample in term of micro-hardness was analyzed. It is observed that with increasing the shear angle, effective stress, strain and pressing load are enhanced. Moreover, by increasing the coefficient of friction, pressing load enhances. The color coded micro-hardness measurement showed a good agreement with the strain distribution obtained from FEA (higher hardness for the zones associated with higher shear plastic strain values).INTRODUCTIONWork hardening results in enhanced mechanical properties upon cycles of deformation (Hosford & Caddell, 2007). However, the formability of the processed products are affected by work hardening reducing the possibility of processing in subsequent deformation cycles. Therefore, many industrial processes cannot be performed on sheet metals to produce products with desired mechanical and physical properties (Valiev, Islamgaliev, & Alexandrov, 2000). Severe plastic deformation (SPD) is an effective grain refining technique which can impose large plastic strains through cold working on a metallic specimen (Bisadi, Rastgou, Payganeh, Zeynali, & Ghahremani, 2010). SPD techniques are mainly categorized into three types; sheet, bulk and tube forming. Among SPD sheet forming methods, Constrained Groove Pressing (CGP) (Shin, Park, Kim, & Park, 2002), Accumulative Roll Bonding (ARB) (Saito, Tsuji, Utsunomiya, Sakai, & Hong, 1998) and Repetitive Corrugation and Straightening (RCS) (Zhu, Lowe, Jiang, & Huang, 2001) possess potential applications in manufacturing industries."

Jan 1, 2016

By O. Alonso-Gonzalez, F. Nava-Alonso, A. Uribe-Salas, R. Pérez-Garibay, C. Jimenez-Velasco

A current problem in gold production is the presence of copper minerals which dissolve during conventional cyanidation practice. The dissolved copper causes several problems in the different stages of the process. This issue is the base for copper elimination/recovery methods such as the Sulphidization, Acidification, Recycling, and Thickening (SART) process, which is currently used in gold production plants around the world. Even though the process is well established, new challenges appear as the composition of the solution varies from ore to ore, in some circumstances affecting the performance of the SART process. This work presents a thermodynamic study and experimental tests performed to understand the role of the initial copper concentration and sulfur addition, on the efficiency of the copper removal. For a constant cyanide concentration, an increase in the initial copper concentration causes a decrease in copper removal; high sulfur/copper molar ratios favor copper removal. We demonstrated that the cuprous sulfide formed from solutions with high ionic strength, presents better sedimentation rates than solutions with less ionic strength. For solutions with low sedimentation rates, the use of some pretreatment is necessary to facilitate the sedimentation such as addition of flocculants, particle recirculation and the used ultrasonic pretreatment.

Jan 1, 2014

By N. Hmidi, T. Yalcin, M. Papadakis, B. Hilscher

Mill tailings, containing iron sulphides in particular, pose an environmental concern since they constitute a potential source of acid mine drainage which can damage vegetation, harm soil and living organisms, and contaminate groundwaters. Proper disposal of acid generating tailings is therefore an important issue that must be addressed and resolved in a satisfactory manner. Placer Dome Canada operates a 4000 t/d gold cyanidation facility at Musselwhite mine, in northwestern Ontario, where the mill tailings have been classified as acid generating. This study was conducted to explore the effectiveness of froth flotation in removing the sulphide minerals from these tailings and producing a low-sulphur, non-acid generating material that could serve as a capping material for previously deposited tailings. Laboratory semi-batch flotation tests were carried out in accordance with an experimental design procedure, and a computer simulation program was developed to facilitate the evaluation of flotation performance. In this investigation, pH, collector concentration, and airflow rate were considered as the relevant flotation variables, and their effects were examined both experimentally and by simulation. Results have demonstrated that flotation can successfully desulphurize the Musselwhite mine tailings and render them non-acid generating.

Jan 1, 2004

By Daniel D. M. Adams

In 2004, Rio Tinto started a major project to implement Mine Monitoring and Control (MMC) systems worldwide. A detailed selection processes was undertaken and migration to a standard system was started. Today systems are operating around the world and serve as the core of to many business processes. Implementations include highly union areas, large mines, centrally managed mines, and remote areas. Each implementation has unique challenges but all are working towards the common goal with common systems. This paper reviews two projects that Rio Tinto has deployed in diverse conditions. The projects are the Rossing Uranium upgrade from the original Wenco system to the common standard and Iron Ore of Canada?s general technology upgrade. Also discussed is the future of mining at Rio Tinto, specifically the drill automation projects, and how it is utilizing the common standard MMC systems.

May 1, 2010

By A. C. Hitchins, C. N. Orssich

The Eagle zone is a gold-bearing, sheeted, quartz vein porphyry deposit hosted by the Cretaceous Dublin Gulch biotite granodiorite stock, located in central Yukon, 50 km north of Mayo. The deposit occurs at the western end of the stock and has been drill tested over a 1000 m by 500 m area, to a depth of 150m. Mineralization consists of 1 cm to 2 Cm wide, parallel, grey and white quartz veins with accessory gold, arsenopyrite, pyrite, pyrrhotite, chalcopyrite, native bismuth, bismuthinite, and scheelite. Vein densities range from two to fifteen veins per metre and average approximately five per metre. The majority of the veins have potassic and or phyllic alteration envelopes. Alteration of the granodiorite becomes pervasive as vein densities increase. Mineralization outside of the Eagle zone, but spatially related to the Dublin Gulch stock, includes: (i) scheelite bearing sheeted quartz vein zones within the east-central portion of the stock; (ii) a swarm of gold-bearing quartz-sulphide veins up to a metre wide in a zone along the northern contact of the stock and extending 7 km further west; (iii) the Mar scheelite skarn located on the south side of the stock; and (iv) cassiterite-bearing breccias located 2 km north of the stock. A geological potential resource of 64.5 Mt tonnes at a grade of 1.03 g/t Au has been estimated for the Eagle zone from widely spaced core and reverse circulation drill holes. Mineralization is open at depth, on strike to the west and beneath the hornfels to the north.

Jan 1, 1995

By R. J. R. Schaller

NO. 3 winze, the sixth shaft to be sunk on the San Antonio property, is practically a duplicate of No. 3 shaft, which was the main shaft prior to the installation of the larger hoisting equipment in 1939. It is collared on the tenth, or 1,500-ft., level, and goes down vertically to the sixteenth, or 2,500-ft., level, with a loading pocket, spill pocket, and sump below this. It is 1,000 feet east of No. 3 shaft. All ore, men, and materials are handled through the latter. The winze location with reference to the rock formation is shown in Figure 1. (In plan, this section strikes N.30°E. and cuts most of the main orebodies of the mine normal to their strike.) It is collared eighty feet inside the footwall contact of the basalt and cuts through it before reaching the eleventh level. In this location there will be no ore tied up in shaft pillars, as the closest ore to the shaft is on the tenth level, and here it is eighty feet northeast of the collar. The winze headframe and hoist-room straddle the main haulage to the No. 3 shaft, on the tenth level (see Figure 2). At no time during the excavation for the headframe and hoist-room was the general routine work of this haulage held up.

Jan 1, 1941

By R. Elliott, C. A. Pickles, J. Peacey

As the nickel sulfide ore deposits become decreasingly viable as a source of nickel metal, increasing attention is being paid to the exploitation of the nickeliferous laterite ores. Attempts to produce a high grade ferronickel concentrate from these ores by pyrometallurgical methods face several challenges, in particular the selective recovery of the highly disseminated nickel from the reduced ore. The current work explores strategies for maximizing the size of ferronickel particles formed in order to improve the selective recovery of the ferronickel by magnetic separation. The effect of various coal, elemental sulphur, pyrite and sodium sulphate additions on ferronickel particle formation and size at 1000°C have been investigated. It has been observed that increased coal additions leads to a moderate improvement in the size of the ferronickel particles, while the presence of any sulphur bearing reagent leads to a significant increase in particle size. The retention of sulphur in the reduced material has also been studied, showing sodium sulphate has the highest retention, followed by pyrite and then elemental sulphur. An inverse trend was observed in the efficiency of sulphur retention on the basis of residual mass of sulphur per unit mass of reagent added.

Jan 1, 2015

By R. C. Beard

"Heap leaching, currently being applied in the treatment of low-grade ores in the south western United States, is shown to have potential for use in north western Ontario. The history and operation of the process are described, and cost comparisons are given.IntroductionHeap leaching is a simple, low-cost method of recovering gold from low-grade ore. Although it is not currently being used in Canada on a production scale, it is being used extensively, and successfully, in the southwestern United States as well as elsewhere in the world. Especially suited for large deposits of very low -grade ore, it also appears to be practical for use on small, high-grade deposits because it avoids the high capital costs of mills. Eveleth (1980) and others suggest that the capital and operating costs required for heap leaching are approximately 20% and 40% respectively of conventional milling methods.Northwestern Ontario is noted for its large number of undeveloped, small, high-grade gold deposits. Although there are a number o f larger and higher-grade deposits in the area as well, it is the relatively small undeveloped deposits which would benefit most from heap leaching, if it could be demonstrated to be a viable extraction method.To assess the significance of these small deposits, the Ontario Ministry of Natural Resources recently commissioned a consultants' study of the gold reserves in certain parts of northwestern Ontario. This report, titled ""Feasibility of Small-Scale Gold Mining in Northwestern Ontario"", by J.N. Neilson and R.C.E. Bray (1981, OGS Open File Report 5332), documents 106 known gold deposits having sufficient information to calculate gold reserves. A total of over 7.8 million tons having a weighted average grade of 0.19 oz of gold per ton were compiled in the proven, probable and possible categories, with an additional 8.2 million tons in the speculative category. Many of these deposits could be mined by open-pit methods."

Jan 1, 1983

By V. I. Lakshmanan, R. Roy

"Zinc is the fourth most widely used metal in the world after iron, aluminum and copper. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing the steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Process Research ORTECH Inc. has developed an efficient energy-saving sustainable technology for the recovery of zinc from secondary sources such as galvanized steel scrap, dross, dusts etc. The process consists of treating the zinc containing scrap in an alkaline solution to remove the zinc and thereby producing a zinc free steel scrap for recycle. The zinc containing leach liquor is subjected to a solvent extraction process to recover value added zinc oxide as the final product. In this paper, important industrial processes for the recycling of zinc including the PRO process will be discussed. BACKGROUNDZinc is the fourth most widely used metal in the world after iron, aluminum and copper. Global refined zinc output increased by 2.7 per cent to 13.16 million tonnes in 2011 and is expected to increase by an additional 2.4 per cent to 13.48 million tonnes in 2012 [1]. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Other major usages of zinc are in the production of brass and bronze, die casting and zinc-air batteries. The additional demand for zinc could come from its addition to fertilizers to increase crop yield.While the demand for zinc is increasing, many mines are scheduled to close in near future after being depleted of ore. The mines set to close between now and 2015 are Teck Resources’ Red Dog Mine in Alaska, Minmetals’ Century Mine in Australia and Vedanta Resource’s Skorpion Mine in Namibia [1]. The depletion of resources due to continued use and exploitation is becoming a great concern for the zinc industry. As a result, the sustainability of natural resources for continued societal care has become extremely important. Resource conservation and recovery by recycling with minimal environmental impact is a key element for sustainable development. In this paper, important industrial processes for the recycling of zinc including the PRO process are presented."

Jan 1, 2012

By Sibabrata Patnayak

A major problem during shovel excavation in oil sand mining is the variability of material diggability resulting in varying mechanical energy input, cycle time, energy consumption, wear, and stress loading of shovel dipper-andtooth assembly. This variability greatly influences the mining equipment performance. Different approaches such as empirical ground classification systems, analytical methods, and performance monitoring that are used to determine diggability of groundmass are reviewed. It is concluded that the existing empirical diggability classification systems are site specific and mostly based on rock and therefore, cannot be used for shovel excavation in oil sands. The O&K wedge test is a simple and useful index test for establishing correlations between cutting resistance and geotechnical properties of coal and other soft rock overburden material. But this test, when performed on small size unconfined oil sand samples, may not give reliable indication of diggability because of the boundary conditions on the specimens. Digging predictions made using analytical and laboratory digging models need to be verified with performance monitoring data to better understand the digging effort in oil sands.

Apr 1, 2005

By A. Azad

SAGD (Steam Assisted Gravity Drainage) is an in-situ oil recovery technique for heavy oil reservoirs. The technique has been successfully applied to many projects in the past 25 years and the process has been, now, well understood. It is now believed that geomechanics plays an important role in SAGD and should be considered in numerical or analytical modeling. Currently, geomechanics is numerically modeled through combining a multi-phase flow and a geomechanical simulator. Numerical modeling is, however, time consuming, need lots of input data, and could not be used for quick decision-making purposes. To decrease the modeling time, this study based on a new version of the Reis drainage model, proposes coupled mathematical model and reserves the effect of geomechanics in the process. Results showed a perfect match with the past experimental and numerical data.

May 1, 2009

By B. Jena, M. Rigaud, S. C. Panigrahy

"The influence of flux addition on the structure and properties of pellets produced from low silica specularite with peat moss and bentonite as binders was investigated. Specific pellets basicities in the range of 0.4 to 3.2 were obtained by the addition of limestone or a combination of dolomite and limestone as flux. A t basicities < 1.6, the bonding in the pellets was provided by a glassy silicate phase. At basicities =1.6, calcium ferrites were the predominant bonding phase. When dolomite was added as a flux, presence of magnesia-ferrite was noted. The reduction behaviour of pellets at different basicities was found to be influenced by the type of flux and binder. The pellet compression strength and swelling characteristics were improved with increased basicity.IntroductionThe properties of iron ore pellets are influenced by the type and nature of the ore or concentrate, additives and their subsequent treatment to produce pellets. The interaction between various constituents of the concentrate and additives, i.e. iron oxides, gangue and fluxes etc. result in the formation of various mineralogical phases which affect the degree and nature of bonding achieved in the pellet and the structure and distribution of pores. The pellet properties such as pellet strength and reducibility are influenced by the extent and type of bonding achieved between the ore particles. In view of the present emphasis on the production of high quality pellets to meet progressively stringent quality control requirements, it is essential to investigate the effect of additives on the bonding mechanism and properties of the pellets.In the past, the effects of additives on the bonding mechanism of pellets have been investigated. It is important to note that the conditions and parameters to be controlled are typical of a given concentrate/ore. In this paper, the results of the investigation on characterization of fluxed pellets produced from a low silica specularite concentrate are reported.This investigation was also aimed at assessing the suitability of peat moss for use as a binder for the production of low silica fluxed pellets. Peat moss is abundantly available in the vicinity of iron ore mines in Quebec and encouraging results have been obtained du ring the production of high silica acid and fluxed pellets."

Jan 1, 1992

By A. J. Williams

"Whenever a decision is made to bring a mineral deposit into production, the Owner in actual fact has decided to convert substantial sums of capital into productive capacity with the intenti6n of making a profit from such conversion.Escalating costs of construction, frustrating and costly delays in comp1etion, the increasing tempo of technological change and the increasing size and complexity of mineral processing projects have convinced Owners that the best way of implementing their capital must be sought and utilized. This requirement has stimulated a search for ways and means of applying modern management techniques to the design and construction of mineral processing plants.This search by consulting firms has resulted in the evolution of the concept of project management and the development of planning and con trolling techniques with the result that Owners can seek and obtain better assurance that their project objectives will be fulfilled.This paper will attempt to outline how a mineral processing plant can be brought into production through the implementation of project management techniques.Definition And Objectives Of Project ManagementThe design and construction of mineral processing plants is subject to the restraints of three inter-related parameters -Quality, Cost and Time each of which influences and is influenced by the other two.Project management is a technique where the Owner delegates complete responsibility to a single organization for all phases of a project (design, procurement, construction and commissioning) for the above parameters but retains freedom for major decision making. Normally, the consultant under-takes full responsibility for all phases, but partial project management services can be provided when the Owner so desires.The objective of project management is first to devise and define and then to implement a program in which the relationship between the three parameters of Quality, Cost and Time is optimized, i.e., the desired functional and other requirements are attained (but not exceeded) at the lowest practicable overall cost in the shortest practicable time. The measure of success of a project lies in the degree to which this objective is achieved."

Jan 1, 1974

By M. Bryson, S. Broom-Fendley, A. E. Brady, W. Dawes, G. Beer, N. Sehlotho, S. Al-Ali, F. Wall

The Songwe Hill Rare Earth Element (REE) Project in Malawi is a near surface carbonatite-hosted deposit with synchysite and apatite as the key REE bearing minerals. A strong focus has been placed on understanding the REE mineralogy of the Songwe Hill carbonatite as REE mineralogical characterization is a crucial component at all steps, ranging from exploration to production, in the development of REE deposits. Extensive mineralogical work has been completed at Camborne School of Mines (CSM), Natural History Museum (NHM) London, British Geological Survey (BGS), Nottingham, Aberystwyth University, Wales, Mintek, South Africa, and SGS Inc. Canada (SGS). The following analytical techniques were used: scanning electron microscopy (SEM), electron microprobe analysis (EMPA), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and QEMSCAN®. The detailed studies have demonstrated that while synchysite is light-REE enriched as expected, apatite, abundant in all stages of carbonatite emplacement at Songwe, is anomalously enriched in mid- to heavy-REE relative to apatite in other carbonatite deposits. The distribution of REE within synchysite and apatite at Songwe has had important implications for the direction of the metallurgical work with respect to the behaviour of light and heavy REE through the flotation and hydrometallurgical stages of the flow sheet.

Jan 1, 2014

By Jr. Blanchette, Claude Bazin, Paul Blatter

"Reporting of the gold production during a month implies to estimate the mass of gold that is processed by a mill, recovered as dorés, lost to the tailings and the change of gold inventory within the plant equipments. Carbon in pulp and/or carbon in leach tanks may contain gold inventory as large as 72 000 g (2 200 troy oz) of gold which needs to be estimated from measurements obtained from sampling the material contained in a tank. Sampling and analysis introduce measurement errors that could be systematic and/or random. This paper examines the effect of measurement errors on the estimation of the gold inventory and on the variation of the inventory in the carbon in leach tanks of the Agnico-Eagle Mines Limited Lapa concentrator. Results of the analysis demonstrate that the inventory is measured with ±10% reproducibility, while the variation of inventory used for mass balance is known with ±300% reproducibility.INTRODUCTIONThe preparation of a production report implies to reconcile measured data with the constraint of material balance over the considered period of production. The sampling and data reconciliation problems were recently reviewed by Morrison (2008) and Jansen (2009a; 2009b). Typically a production report is prepared to cover a period over which the mass conservation hypothesis can be considered valid. In gold processing plants, the change of inventory can seldom be neglected and plays a significant role in material balance calculations. This is particularly true for circuits using carbon adsorption, where the complete cycle of carbon is measured in days.In a 2000 t/d gold ore processing plant, the inventory can be as large as 140 000 g of gold in gravity concentrator bins, carbon in pulp tanks and in the electrolysis circuit. This is equivalent to the mass of gold that fed the circuit during 10 days of operation with 7 g/t feed assays. The change of inventory may therefore strongly impact the production figures and especially the plant recovery at the end of a week or a month. Despite the financial impact associated with gold inventory, few publications are devoted to the subject. Bruington (1991) and Morrison (2008) discussed the problem and stressed the need for the development of reliable methods to estimate the gold inventory in carbon in pulp or carbon in leach circuits."

Jan 1, 2011

By G. Avramovic-Cingara

Grain boundary characteristics and microstructural evolution are analyzed in a comparative study using orientation imaging microscopy (OIM/SEM) and transmission electron microscopy (TEM/SAD). The subgrain sizes and misorientations were determined by the OIM for aluminum deformed in torsion to equivalent strains between 0.2 and 4 over the temperature ranges of300-600°C and strain rates 0.01-1 s". The OIM gives clearer evidence of boundaries with high misorientation than does TEM, but it overestimates their frequency b y missing boundaries less than 1 0. T EM more clearly reveals low-angle arrays of widely spaced dislocations resulting in finer subgrain sizes than those indicated by OIM. The evidence supports a mechanism combining dynamic recovery (DRY), deformation band formation with permanent boundaries and geometric dynamic recrystallization (gDRX) in contrast to the hypothesis known as continuous dynamic recrystallization (cDRX).

Jan 1, 2004

By M. Leroux, J. A. Finch

"Sizing below 38 µm (400 mesh) is an increasing requirement in mill testing laboratories. The Cyclosizer is gaining wide acceptance in this role. A recent alternative is to use electro-formed sieves (micro-sieves), which are available with openings down to 5 µm. The advantage of micro-sieving is a cut size which is independent of mineral density, easier retention of the fi nest fraction and reduced purchase cost. A simple method of microsieving using an ultrasonic bath, which performs readily to 10 µm, is described.A systematic study of Cyclosizing and micro-sieving is reported for three samples; silica, copper oxide and a lead concentrate. Micro-sieving gave comparable results. Comparison with a standard sizing method, the Sedigraph 5000D, revealed misplaced material in each fraction by both methods. The range for micro-sieving was from 20% to 60% depending on the sieve and material; for the Cyclosizer it was a consistent 40-50% for all cones and all materials. The Cyclosizer can be sensitive to feed mass and particle size for dense materials. It is recommended that for minerals of specific gravity greater than 5, no more than 35 g of -38 µm be used.The disadvantage of micro-sieving is that it requires continuous operator attention and sieving time depends on sample mass. To fractionate 35 g-as used on the Cyclosizer and considered at reasonable mass for mill testing purposes-through 25-, 15- and 10-µm sieves requires about 80 minutes.IntroductionParticle size has a pronounced influence on mineral separation processes. Consequently, the measurement of particle size plays an important part in mill testing. By far the most common method is by screening. This, however, is usually limited to 38 µm (400 mesh) or occasionally 25 µm (500 mesh). Increasingly, mineral products are becoming finer than this limit and consequently finer sizing methods are required."

Jan 1, 1982

"RésuméDans la première partie de cet article on discute Ie mode d&apos;écail age aetueJJement en usage dans des mines souterraines. Par la suite, on presente la problematique d&apos;écaillage à l’aide de barres conventionnelles et on discute les plus recénts développements des outils d&apos;ecaillage portatifs et mécanisés ainsi que les techniques de détection des roches branlantes. Plus tard, on analyse la tâche d&apos;écaillage avec des barres conventionnelles. Dans les chapitres qui suivent on présente un concept d&apos;un outil d&apos;écaillage portatif et mécanisé développe à l&apos;Université Laval, ainsi que les résultats des essais de cet outil, effectués dans quelques mines au Québec. On constate que Ie nouvel outil d&apos;écaillage démontre un potentieJ intéressant tant au niveau de l&apos;effort requis pour effectuer la tâche d&apos;écaillage que de la sécurité des mineurs.On conclut que l’application de cet outil fera un pas important sur Ia voie d&apos;amélioration des conditions de travail dans les exploitations souterraines, tout en assuarnt une qualité accrue de l&apos;écaillage.AbstractThe first part of this paper discusses the type of scaling operations presently in use in underground mines and derma; a scaling factor which is expressed as the:: area necessary to scale to extract one ton of ore. Subsequently, the problems associated with conventional scaling methods are discussed as well as recent developments in mechanized hand-held scaling devices and methods of loose detection. The elements of the scaling process are further analyzed. In subsequent sections of this paper, the conception and design of a mechanized scaling device, developed at Universite Laval is described. The results of field tests conducted in Quebec hard rock mines are presented. The experimental findings show that the mechanized hand-held scaling device shows great potential in improving the productivity and safety of underground mining operations."

Jan 1, 1995

By Roland B. Hoag, Roger G. Webber

Sulphate concentration in groundwater is a good measure of the extent of oxidation of sulphides, provided that sulphide minerals are the primary source of the sulphate. A study was conducted near the Eustis Mine in Quebec to determine where and how the sulphate in groundwaters originated. Atmospheric precipitation is the only source of sulphate other than oxidation of sulphides, and in this study area it is equal to 0.01,. millimole per litre. The oxidation of sulphides can be divided into subsurface oxidation (mainly inorganic processes) and surface oxidation (including both organic and inorganic processes) . The maximum sulphate concentration due to subsurface oxidation of sulphides depends on the solubility of 0 2 in water and is 0.25 millimole per litre. Surface oxidation is, therefore, responsible for any amount greater than atmospheric plus subsurface contributions (0.29 millimole per litre). Surface inorganic oxidation occurs in waters with a pH greater than 15 and is controlled by the kinetics of the oxidation processes. Organic (bacterial) surface oxidation is dominant only in acid (pH< 1.5) waters. The bacterial action accelerates the oxidation of sulphides, and large quanttties of sulphate may be introduced into solution.

Jan 1, 1976

By M. Nakai, G. Itoh, R. Yamada, A. Kurumada

In order elucidate the mechanism for poorer fatigue properties of 7000 series aluminum alloys than those of 2000 series alloys, the effect of the test environment on the fatigue crack growth of the two series alloys was investigated, considering the relationship to hydrogen embrittlement. Two 7075-type and four 2024-type alloys were T6-tempered and T4-tempered respectively, and subjected to fatigue crack growth tests in moist and dry environments. When tested in moist air, fraction of intergranular crack path was higher in the 7075-type alloy with coarse equi-axed grains than in the 2024-type alloy with similar microstructure. This was in accord with the larger crack growth rate in the 7075-type alloy. Both the intergranular crack path fraction and the crack growth rate were decreased by changing the environment to the flow of nitrogen gas. Thus, the large fatigue crack growth rate of the 7075-type alloy is attributable to hydrogen embrittlement.

Jan 1, 2015