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By Nitin Bhavsar, Kaushik Vakil, Lakshmikanth Reddy, Sanjay Sarkar, Tathavadkar. Vilas, Bhavin Desai, Raghavendra Adiga

Gold and platinum group metals (PGM) do not dissolve in sulfate electrolyte from anode during electro-refining of primary copper. The PGM form solid ‘slimes’ which accumulates at bottom of the electrolytic cell. Typically, 8 to 10 ppm silver is present in copper cathodes, which is equivalent to almost 2% of silver loss during electro-refining. The silver can be cemented with cathode copper as soon as it is dissolved into the electrolyte from anode or during entrapment of slime particles in cathode. Over a period of time, the concentrates grade has deteriorated and change in type & amount of impurities in concentrate has resulted in higher silver loss during refining process. Therefore, an in-depth investigation was carried out in both fire- and electro-refining processes to understand the root causes of higher silver loss in copper cathodes. The detailed characterization and the plant data analysis were carried out. The results of study revealed that higher silver loss in 3rd crop cathodes as compared to 1st and 2nd crop cathodes from same anode. In anode silver was present in two forms, dissolved in copper (solid solution) and in slime phases such as Cu2-xAgxSeTe. SEM-EDX study of anode cross section confirmed higher silver and oxygen content in central region (core) of anode as compared that in both air and mold sides. This is due to non-uniform cooling of anode which was confirmed by the solidification modeling. Higher concentration of oxygen & silver at core of anode rised Ag+ concentration in electrolyte and slime particles during 3rd crop. The results of study were used to optimize the anode cooling process and also electrolyte chemistry to reduce the silver loss. The details of study carried out are discussed in this paper using the results of modeling, characterization and experimental studies. INTRODUCTION In the electrolytic refining of copper, fire refined copper anodes are used as raw material. Anodes contains copper of the range 99.5 to 99.6%, rest being the impurities. Hence, the purpose of the refining is (1) to remove the impurities so that final cathode conforms to the LME specifications and also (2) to recover the precious metal from the anode copper. When anode is dissolved, most of the impurities reports to the anode slime settled at the bottom of the cell, and rest dissolves in the electrolyte. Dissolved impurities remains in electrolyte and are removed during electrolyte recycling. However, sometime dissolved impurities and slime particles get entrapped in cathode due to disturbances in operational conditions. Metals dissolving in the electrolyte are the elements such as Ni, Co, Fe, Zn. The electrode potential of As, Sb and Bi being close to that of copper, these elements partly dissolve in the electrolyte. Noble metals like Ag, Au, Pt and Pd are generally insoluble and are thus expected to report to the anode slime. A small amount of the sliver content from the anode is dissolved in the electrolyte. Because the dissolved silver electroplates on the cathode at a smaller applied potential than copper, the cathode typically contains up to 8 ppm of silver. This is referred to as ‘silver loss’ in cathode (Cooper, 1987). Fortunately, silver is a rather benign impurity in copper due to its electrical conductivity being higher than copper. However, higher silver loss in cathode is loss of revenue for Copper smelter due to significant difference in their LME price.

Jan 1, 2019

By R. S. Adhikari

This paper presents an innovative computer vision method for condition assessments of bridges with multiple defects in bridge elements using digital images. This work utilizes 3D model of existing bridges and overlays digital images on 3D model to simulate on-site visual inspection. The analysis of element condition index (ECI) of bridges requires information about the severity and extent of defects in elements. In general, ECI is evaluated manually during routine bridge inspection considering the severity of dominant defects. The evaluation of ECI with multiple defects needs to be addressed with consideration of dominant defect as well as the interaction among defects. However, Image-based quantification techniques largely depend on geometry of objects (i.e. shapes). Shape vectors of a given object change as they are translated, rotated, and scaled with different magnitudes. This work considers shape preserving algorithms such as, affine and projective transformation for proper image alignment. Semi-automated approach for detection and quantification of concrete distress such as cracks and spalling are considered for the defects analysis. The proposed methodology ensures the consistency in reporting ECI and eliminates the shortcoming of traditional approaches.

Aug 1, 2013

By R. S. Adhikari

The changes in defects patterns or in element condition index during visual inspection of bridges are primary concerns for inspectors. This paper presents a new approach for change detection of defects in bridges by identifying changes in texture patterns through spectral analysis of digital images. The commonly used method for change detection is image differentiation. This subtraction method requires images to be of same size, scale, and rotation. However, no two images are same in real practices. Thus, image registration is required to align images and to produce change maps. This process is tedious and it is difficult often to achieve a good registered image. But, the change detection task can be readily modeled in frequency domain for texture patterns discrimination and also for quantifying their properties. This paper proposes a novel approach for change detection by transforming digital images into Fourier spectrum. In new coordinate system, 1-D signature functions can be drawn which facilitates easy comparison of textures in different directions. The proposed methodology provides useful tools for comparison of inspection history graphically and quantitatively. In practice, expensive sensors are used to detect subtle change in defect patterns. The proposed method can be used to detect any subtle change in defect patterns using digital images at much lower cost.

Aug 1, 2013

By J. Lammers, D. Adams

Most pressure oxidation operations introduce oxygen through a large multi-use nozzle in the vapour space of the autoclave. Sparge pipes extend inside the vessel to the point of discharge below the compartment agitator. However, two zinc pressure leach operations have successfully used a bottom entry oxygen sparge system for a number of years. Recently, the concept has been used in a whole ore gold pressure oxidation operation as well as a copper pressure leach plant. Both of the latter operations also introduce cooling water for temperature control through the same sparge pipe. This paper addresses the benefits of the bottom entry system with regards to autoclave performance and the positive effects on agitator performance.

Jan 1, 2004

By Michael R. McPhie

Topics of Discussion 1. The Global Mining Initiative (GMI) and MMSD North America (Brief) 2. Task 2 of MMSD North America ? A Test for Sustainability 3. The Seven Questions and their Application 4. Key Recommendations and Next Steps GMI = Global Mining Initiative Significant international collaborative effort supported by more than 30 of the world?s largest mining/minerals firms which sought to involve all communities of interest. Three major streams of activities: 1. Mining, Minerals and Sustainable Development Project (MMSD) ? 4 regional Process (North America, Southern Africa, South America, Australia) 2. Creation of ICMM (formerly ICME) 3. Major conference in Toronto in May, 2002

May 1, 2002

By H. O. Ghaffari

A complex network approach on a rough fracture is developed. In this manner, some hidden metric spaces (similarity measurements) between apertures profiles are set up and a general evolutionary network in two directions (in parallel and perpendicular to the shear direction) is constructed. Also, an algorithm (COmplex Networks on Apertures: CONA) is proposed in which evolving of a network is accomplished using preferential detachments and attachments of edges (based on a competition and game manner) while the number of nodes is fixed. Also, evolving of clustering coefficients and number of edges display similar patterns as well as are appeared in shear stress, hydraulic conductivity and dilation changes, which can be engaged to estimate shear strength distribution of asperities.

May 1, 2009

By J. Duriez, L. Scholtès, F. V. Donzé

"Fracture propagation process in brittle rock is investigated by means of numerical simulations performed with an adapted formulation of the discrete element method. The progressive failure mechanism is simulated through the breaking of the bonds making up the cohesion between the elements constituting the simulated medium. The use of appropriate contact laws associated to a near neighbor interaction feature provide the model the ability to reproduce fundamental characteristics of brittle rock behavior such as, for example, high values of the tensile to compressive strength ratio. Great attention is given to accurately describe the properties of the pre-existing joints or faults in the model. A specific joint model gives the possibility to define a tailor-made behavior of the discontinuity surfaces without suffering from discretization bias.Compression test simulations are performed on pre-flawed samples and compared to experimental results in order to validate the numerical approach for describing the initiation and propagation of fractures in brittle rock under mode I+II loading. It is shown that the crack mechanical parameters can greatly influence the fracturing pattern, in particular its frictional properties. Overall, the numerical simulations reproduce fairly well the failure patterns that are obtained experimentally.The discrete model is then used to study mode I+III loading to give an insight into fracturing problems occurring at the scale of the continental crust. The ability of the model to support mechanically the physical modelings performed with wet clay or sandbox is shown. As an example, the model is used to track the development of a twist crack system (wrench fault) through the nucleation and coalescence of microcracks."

Jan 1, 2015

By Joseph Carlston

With environmental regulations continuing to restrict the discharge of phosphorus from wastewater treatment facilities, traditional methods of phosphorus removal are proving inadequate. To achieve the phosphorus control necessary, a new coagulant used for phosphorus removal, cerium chloride, has been studied in several municipal and industrial wastewater treatment facilities that must meet a phosphorus discharge limit of 0.5 mg/L or lower. These studies demonstrated the high phosphorus removal capabilities of cerium chloride, with the results illustrating the ability for cerium chloride to reduce phosphorus to low concentrations in the effluent using a lower volume of product as compared to traditional coagulants, such as ferric chloride. This reduction is due to the unique ability of cerium chloride to remove phosphorus as cerium phosphate, whereas iron- and aluminum-based coagulants rely on adsorption and co-precipitation.

Jan 1, 2014

By Fred G. Hewett

Cassiar Mine in northern British Columbia began development in 1952. The deposir is found on rhe west limb of rhe McDame Synclinorium in a Mississippian serpentinite body. The serpenltntte, one of the McDame l ntrusives, imrudes Sylvester Group . rocks, which comprise a Lare Devonian to Early M1ss1ss1pptan eugeosync/inal sequence of argillites, quarrzires and volcanics. The foorwall conracr berween Sylvester Group rocks and rhe serpenrinire is a marked zone of broken and incomperent argillite and graphitic schist. The less marked hang- 111gwall contacr 1s a band of indurated argillite. The JurassicCretaceous emplacemenr of the Cassiar Graniric Barholilh is responsible for mosr of the numerous )aims, faulrs and shear zones found in the serpentinite body. Faulting occurred borh before and after asbestos formation. Asbestos is mined from an open pit ar rhe rate of 4,535 ronnes daily. It passes from the pir along a rramline to the mill, where it is concen/rared into nine direcr milling grades. Packaged fibres travel ro over 40 counrries around rhe world for use in the texrile, cemenr and other industries.

Jan 1, 1984

By Dwayne D. Tannant

This paper presents a summary of results from a questionnaire sent to surface mines in western Canada seeking information on haul road design, construction, and maintenance. There has been a marked increase in the size of the trucks used over the last decade with some mines now using trucks with a payload capacity of 360mt. Consequentially, geometrical elements of haul roads, such as width, have been enlarged to accommodate larger trucks. Most haul roads are constructed on the basis of past experience without use of formal design procedures. With the introduction of larger haul trucks, problems related to rolling resistance, deterioration, and maintenance of the haul roads have become more important. This has lead to adoption of more rigorous design methods for roads at some mines, most notably for the oil sand mines operated by Syncrude Canada Ltd. A summary of the evolution of haul road designs implemented at Syncrude Canada Ltd. is presented.

May 1, 2001

By Michel Dostie

Un séchoir à vis chauffé par induction électromagnétique a été développé et implanté chez Mines Niobec pour le séchage d?un concentré de niobium. Ce séchoir a permis une réduction des émissions de poussières et des gaz à effet de serre de l?usine. Il offre une grande souplesse de contrôle, une meilleure efficacité énergétique et peut être utilisé pour le séchage de granulats, de poudres ou autres substances habituellement traitées dans un four rotatif ou à l?aide de vis chauffées par un caloporteur. Le principe de fonctionnement du séchoir est simple. Trois inducteurs opérant à la fréquence du réseau électrique assurent le chauffage des parties métalliques du séchoir, dont des vis qui servent à convoyer le matériel. Le contact du matériel avec les parties métalliques chaudes permet le transfert de l?énergie requise pour le séchage. La conception de ce type de séchoir requiert un équilibre adéquat entre les besoins associés au chauffage par induction et ceux liés au transfert de chaleur par contact et au transport du matériel dans le séchoir. Cette première implantation industrielle a nécessité des efforts de développements importants et une collaboration des différents intervenants. Une revue des principes de conception, des difficultés rencontrées et des performances obtenues sera présentée.

May 1, 2007

By Robert B. Parsons

"The 1994 Quebec Budget included a significant overhaul of the mining duties sys-tem in that province: broadening the base and lowering the rate, all in the name of “ensuring the integrity of the taxation system"" and ""enabling the State to collect fair compensation "". The reforms hit hardest on the small, lightly-capitalized producer, by repealing the basic annual exemption, limiting the refund for losses, and significantly reducing the investment and processing allowances. There is some relief provided in the form of faster depreciation rates and a lower nominal tax rate, but the thrust of the overhaul is clear -higher taxes on the mining sector.IntroductionAlthough Quebec's mining tax regime represents under 10J0 of the province's revenue base, and was significantly reformed in 1979 and 1985, the May 13, 1994, provincial budget introduced further significant changes to the Mining Duties Act, The hope (on the part of the province) is to reduce the provincial ""subsidy"" for mining by $20 mil· lion per year by 1996."

Jan 1, 1995

By L. Zeng, Q. Feng, Z. Qiu, L. Ou, Central South University

It is well-known that the use of nanobubbles can significantly improve the flotation efficiency of ultra-fine particles. However, this is mainly focused on coal and phosphate rock flotation. In the field of nonferrous metal processing, the related research is few. In this paper, a small laboratory mechanical cell associated with a specially-designed nanobubbles generator was used to investigate the effects of nanobubbles on enhancing ultra-fine scheelite flotation. Nanobubbles were created and based on the hydrodynamic cavitation principle through Venturi tubes. Comparative flotation tests were performed using different tubes to evaluate the nanobubbles impact on the ultra-fine scheelite particle flotation recovery. In order to better understand the nanobubbles enhanced ultra-fine scheelite flotation, nanobubbles potential and size distribution were measured. The effect of nanobubbles on the particle aggregation and scheelite particles potential were also studied through the turbidity tests, microscope tests and zeta potential measurements. According to the results, the mean size of nanobubbles was about several hundred nanometers, and the surface of nanobubbles was of highly negative charge in alkaline conditions. The flotation recovery of ultra-fine scheelite particles was increased in the presence of nanobubbles. The zeta potential measurements indicated that the repulsive forces between scheelite particles decreased when nanobubbles existed. Through the turbidity tests and microscope tests, the promotion effect of nanobubbles on particle coagulation could be verified more directly. The existence of nanobubbles in flotation system promotes the particle aggregation, thus increasing particles apparent size and particles capture by bubbles, which may be the fundamental reason why nanobubbles enhance ultra-fine scheelite flotation.

Jan 1, 2016

By M. L. Jeremic

"Hydraulic mining consists of coal erosion by powerful jet s of water from hydraulic monitors operated by remote control. The broken coal is crushed and mixed with water and then transported from the face to the surface using gravity whenever possible. This is a simple, safe and productive method. It will easily satisfy North American productivity standards if the structural features and coal properties are favourable for water jet cutting technology (Kaiser Resources Ltd. , hydraulic mine). General ConsiderationIn open-pit mines, placer mining (Fig. I) and hydroelectric construction projects, hydraulic earth moving techniques have been successfully applied. The stripping and transporting of the overburden has been accomplished by means of large monitor jets augmented by slurry pumps and pipes. An extension of this technique has led to the underground extraction of coal and ores. To date, the method has been most successfully used in undergrond coal mining, because the coal can be easily cut and flushed away by water jets, and the rocks of the roof strata can be left behind. Due to this favourable situation, the hydraulic mining definition only relates to the underground coal mines.At present, there are four basic types of hydraulic mining, which can be defined according to the coal breaking technique used in each case. The methods are briefly discussed below:(1) Coal excavation may be carried out by conventional techniques, but the mine is designed and equipped for the hydraulic transport of the mineral from the working place to surface. Under these circumstances, the coal breaking may not be influenced by the water jet, however it may be indirectly involved. For example, pre-loosening of the coal may be done by water infusion-hydraulic fracturing. Water may also be used to flush the broken coal, which has been excavated either by drilling and blasting or by mechanical cutting, into the transport flumes. In other cases, a mechanical loader may load the coal directly into the hydraulic transport system, without using any water for the extraction process. This hydraulic mining concept is primarily used for hard and impermeable coal, such as anthracite."

Jan 1, 1980

By William Shaw

Conditional simulation is now an accepted tool for managing ore block design at a number of operating mines. It provides a way to consider the quality of data, local continuity and economic risk in defining ore and waste across the cut-off boundary. In addition a computer based system can ensure consistency in making decisions to meet multiple criteria such as cut-off grades, minimum ore-block size and contaminant grade limits. The development of a procedure for using multiple criteria allows ore blocks to be defined using alternative strategies depending on the specific production requirements. This has introduced the opportunity to define ore blocks for different destinations based on their material types and opens the way for geometallurgical modelling to be incorporated into grade control.

Oct 1, 2009

By J. Flemming, R. O. Burt

"The Tanco pegmatite is located in the Bird River greenstone belt of southeastern Manitoba approximately 160 km northeast of Winnipeg (Figure 1). This pegmatite body was discovered in 1929 and subsequently attempts were made to exploit it for tin by Jack Nutt Mines Ltd. and later in the middle 1950's by Montgary Oil Ltd., who extensively developed but did not produce from, its lithium deposits. In 1966 systematic investigation of the pegmatite as a potential source of tantalum led to the founding of Tantalum Mining Corporation of Canada Ltd. (TANGO) in 1967 and production of tantalum concentrates from the Bernie Lake mine commenced in 1969. Tanco is currently jointly owned by Hudson Bay Mining and Smelting Co., Cabot Beryl co Inc. of Boston, and the Province of Manitoba. (Williams and others 1978, Burt 1979, Burt and others 1982), continued until the end of 1982, when, due to falling demand and prices, operations were suspended.During the 1970's Tanco had investigated the potential of the lithium orebody; carrying our research into both the concentration of the ore and into the production of lithium chemicals. However lithium chemicals were in an over-supply situation, due in part to the production from Chilean brine deposits (Buckley, 1983), and Tanco' s own plans were put into abeyance. The potential alternative market, the direct use of concentrates in the glass and ceramics industry, did not at the time justify the cost of constructing a new plant."

Jan 1, 1986

By F. Melo, M. Pawlik

Fine coal aggregation in concentrated coal-water suspensions was studied through steady-state rheological measurements. The wettability of coal particles was modified by dry oxidation of a bituminous coal. The degree of hydrophobicity was monitored using film flotation. The rheological measurements revealed that hydrophobic coal particles aggregate in aqueous suspensions, over a wide pH range, and produce slurries with high yield stresses. As the degree of coal oxidation increases, the coal particles become more hydrophilic and such suspensions exhibit lower yield stresses values. The yield stress values for suspensions prepared from oxidized/hydrophilic coal become a strong function of pH and correlate well with the surface charge as determined through electroacoustic measurements. These results indicate that the yield stress of aqueous suspensions of coal, and hence coal particles aggregation, is strongly affected by the wettability of coal particles.

Jan 1, 2004

By Steve Hubbard, Brad Marchant, Rolando Cuadra

"Triton Mining Corporation acquired the rights to Mina El Limon in Nicaragua in 1993 by international bid. The bid included the gold operations at Limon and an exploration concession of approximately 4000 km2. Triton assumed control of operations and exploration in May 1994.The Limon mine is located in west-central Nicaragua, approximately 100 kilometers northwest of Managua. The climate is tropical, characterized by a wet season from May through October, and a dry season November through April. Gold at Limon is associated with both banded quartz and silicified breccia veins in Tertiary volcanic rocks, belonging to the lower Coyol Group. Mining is from two open pits and one mechanized underground operation. A second underground mine is currently under development for production during 1997.This paper describes the expansion of the milling facility at El Limon from a nominal capacity of 400 tonnes/day, producing approximately 20,000 ounces of gold annually, to the existing 900 tonne per day mill operation. Engineering of the new mill facility was initiated in September 1994 and construction was completed a year later."

Jan 1, 1997

By N. H. J. Freire, D. Majuste

In this paper, the effects of some organic compounds on the current efficiency, cell voltage and specific energy consumption during nickel electrowinning, and on the deposit features (morphology, crystallographic orientation and nanohardness) were described. The organics tested here (extractant, diluent, flocculant, lubricating oil and acid mist suppressant) are currently used in industrial plants. The results indicated that only the flocculant and acid mist suppressant exhibit relevant negative impacts on the current efficiency and energy consumption. The current efficiency dropped from 93.6 % (organic-free solutions) to 86.0 % and to 92.8% in electrolytes containing 100 mg.L-1 of acid mist suppressant and flocculant, respectively. At this concentration, their addition to the electrolyte led to increases of the specific energy consumption in the order of 18 % (acid mist supressant) and 2 % (flocculant). Cyclic voltammetry showed that Ni nucleation occurs at more negative potentials at 50 and 100 mg.L-1 of these organics in the electrolyte, thus indicating an inhibition of the deposition process. The deposit quality decreased at the higher concentration of all organics, when more hydrogen pitting was observed. The acid mist suppressant caused delamination of the Ni deposit at 50 and 100 mg.L-1. The addition of 100 mg.L-1 of flocculant and acid mist suppressant to the electrolyte increased the nanohardness of the deposit around 31 and 72%, respectively. The increase in Ni deposit hardness may lead to a decrease in the material ductility, thereby affecting the stripping and cutting of Ni sheets. Our findings may be helpful since strong adverse effect of some organics that may be present in the electrolyte were identified, thus the industry can control and optimize the organic´s dosage in the corresponding operations.

Jan 1, 2016

By J. H. Archibald

"In mines employing cut-and-fill stoping (sand fill), ore passes are built as mining progresses upward. These ore pass raises are generally made from timber and form a vertical ""chimney"", like a very tall log cabin. Traditionally the chimney, or raise, is square in shape and is constructed from square timbers with stepped ends as shown in Figure I. The timbered raise is thus surrounded by sandfill on its outside, leaving the centre open for passing ore down through it. Each layer consists of four timbers and rests flush on the layer below. The corners are frequently pinned or spiked.Under certain conditions in sandfilled stopes large horizontal loads may be transmined to the raise cribbing timbers, or the ""chimney's"" walls. In deep mines, where rock bursts are a problem, it can be shown that one of the conditions for rockbursts to occur is that the burst zone be stiffer and weaker than the surrounding rock(l). This allows a strain energy build-Up in the rock surrounding the burst zone, and the rate of release of this strain energy is known to be related directly to the over-all strength and stiffness of the rock in the burst zone. In stopes that are sandfilled, attempts are, therefore, usually made to increase the strength of the sandfill by the addition of large-sized waste rock and Portland cement. These measures usually achieve the desired strength of the sandfill and, consequently, the severity and frequency of rockbursts can be reduced.Problems may arise when the now chunky sandfill transmits high loads to the raise cribbing along with relatively large move- merits. This leads to heavily stressed and strained cribbing timbers the Coeur d'Alene district in Idaho, raise cribbing failures are common. A typical mode of cribbing failure is shown in Figure 2. One learns in statics that a structure shaped like the crib in Figure I is inherently unstable , at least from a structural standpoint. The crib has pivoted, in Figure 2, into a rhombi c shape and supports very little load. Soon the four-foot square raise cribbing made from 5 in. by 5 in. timbers will no longer pass ore."

Jan 1, 1991