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By J. L. Rodrigues Bravo

The aim of this paper is to show the results of the study that relate the variations of the bismuth content in the Caraíba Metais' electrolytic copper with the main electrolysis' process variables as electrolyte flow rate and temperature, anode's impurities content, electrolyte composition, current density, etc and their combinations and factors like cathode washing, blend of materials entering rod plant's furnace, analytical methods, shot-circuit inspection, etc. Also, the methodology considered arsenic, bismuth and antimony mass balance in the electrolysis and their electrolyte's molar ratio relations as well as bibliographic references of refineries that operate in similar conditions. The results showed the circumstances with the major probability of causing bismuth content increasing in the electrolytic copper and the main operating conditions that have to be fixed for having less bismuth variation and lower content in the electrolytic copper.

Jan 1, 2007

By L. Zeka, I. Ndala, J. Frenay, S. Gaydardzhiev

"Reductive leaching of cobalt (III) from a heterogenite bearing ore has been performed. Pyrite was added to the system and simultaneously bioleached in order to provide ferrous iron as reducing agent. Within such arrangement the iron ions are continuously re-circulated inside a Fe 3+ / Fe 2+ loop. As a result Co(III) is solubilized in the presence of Fe 2+ ions in concentrations well below the stoichiometric requirement. The ore has been initially subjected to acid pre-leaching in order to guarantee that the available Co (II) has been entirely removed. Two technological parameters have been studied to show influence on the degree of cobalt leaching: concentration of ferric iron in the inoculum and the presence of bacteria. The bacterial role could be mainly viewed in supplying ferric ions in the system which chemically react with the pyrite to generate ferrous ions used as Co(III) reducing agent. Co(III) dissolution has been less efficient when the concentration of total iron in the system was low, but also when microorganisms were absent. SEM observations on leached heterogenite have evidenced bacterial attack on the mineral; however the precise role of bacterial presence on cobalt (III) leaching is still to be elucidated.INTRODUCTIONCobalt accompanies quite often copper in secondary oxidized ore deposits (Rumbu, 2013). In such associations cobalt is found both as CoII+ as well as CoIII+ (Deliens, 1974). In contrast to cobalt (III), cobalt (II) is leached relatively easy in sulphuric acid solutions. Cobalt (III) when present in mineral form belongs to the heterogenite mineral group with a simplified chemical formulae Co2O3.H2O or CoOOH. In order to be brought in solution, heterogenite should capture two electrons, likewise shown in reaction 1 below:"

Jan 1, 2016

By A. Dolatmoradi

Nanocrystalline structure formations produced by severe plastic deformation in Fe-0.15C with initial ferritic-pearlitic and IF steel with ferritic microstructures have been studied through microstructural observation and microhardness measurements. It was found that the nanocrystalline region first forms near the surface of samples due to localized severe deformation. It was also observed that the nanocrystallization rate of Fe-0.15C and IF steels and the deformed layer thickness in these two materials are different with similar milling conditions. The crystallite size and structural evolution of the samples during milling was studied by employing XRD and SEM.

Jan 1, 2010

By W. G. Davenport

Methods of extracting copper are evaluated in terms of innovations during the 1970's, and predictions to the end of this century are made. It is concluded that between one and two new smelters and refineries will be needed per year until the turn of the century, and that most of these smelters will be of the oxygen or oxygen-enriched flash furnace type. For converting, the Peirce-Smith converter will still predominate, but the Hoboken converter will play an increasingly important role. Five Japanese pollution control systems are described and it is suggested that much of this technology will be included in future smelting installations. Further growth of hydrometallurgy is predicted, especially for oxide ores, based on improved product metal quality and low plant cost. A n increased level of scrap resmelting is also expected.

Jan 1, 1980

By R. M. Graves, C. B. McKenzie, D. Barbour, D. W. Desnoyers

"The prospective Tulks volcanic belt hosts five significant massive sulfide deposits, Tulks Prospect, Tulks East, Jack's Pond, Daniel's Pond and Victoria Mine, as well as numerous showings and indications throughout its 70 km outcrop length. Regionally, the 498 Ma sequence consists dominantly of felsic pyroclastic rocks and flows with interbedded mafic volcanic units and finegrained sediments, commonly graphitic. Contemporaneous granitoid rocks occur in the south half of the belt. Rocks usually display a strong NE-SW, steeply dipping, penetrative foliation and other shear-related high-strain fabrics. Facing directions are normally northwest, although there is local evidence of folding. Sulfide bodies and their alteration systems are deformed and shape-modified in the style of ambient strain.The Tulks, Tulks East and Jack's Pond prospects appear to occupy a similar stratigraphic level, on or near the contact between a thick felsic pile and an overlying broad, conductive package of graphitic sedimentary rocks. All are pyritic deposits with well-developed footwall alteration systems. The Tulks prospect comprises four polymetallic lenses totalling 750 000 t. Three lenses constituting more than 6 000 000 t of sulfide mineralization are indicated at Tulks East but only the 210 000 t ""B"" lens contains significant base metals. Jack's Pond consists of a very extensive, zoned alteration complex in which four lenses of massive to semi-massive pyrite + chalcopyrite are known. The central part of the system, characterized by Mg chlorite and carbonate, is enveloped by pervasive sericitization and capped by intensely silicified and pyritized volcanics. The sulfide lenses are interpreted as part of the footwall zone and are beneath that part of the system most likely to hostpolymetallic massive sulfides.Daniel's Pond differs from the other prospects in such fundamental ways as metal content, associated alteration and structural setting. The deposit comprises strongly tectonized, Ag-rich, Zn-Pb mineralization distinguished by a pronounced Ba-As-Sb signature. Mineralization is confined to a narrow, north-south high-strain zone which separates unstrained mafic volcanic rocks to the east from well-foliated felsic rocks. The deposit lacks an extensive alteration halo and at its north end is associated with a lens of barren, undeformed massive pyrite.The Victoria Mine deposit, the most cupriferous of the five, is related to a moderately dipping structure that separates well-foliated Tulks volcanic rocks from an overlying, less deformed volcanic sedimentary sequence that may be as young as 462 Ma. The structure is also the locus of black chlorite, dolomite and quartz alteration. Structurally remobilized precursor sulfide mineralization is one possible source for the deposit."

Jan 1, 1993

By A. M. Girodo

"Dorbyl Heavy Engineering has been manufacturing winders since 1949 mostly for the South African mining industry.Table 1 shows that the vast majority of winders have been double drum winders. At the greater depths with larger ropes being employed, it became apparent that multi-rope winders would be needed. The high stress variation in Koepe winder ropes at great depths especially beyond 2000 m, ruled out this possibility. Thus the original concept was borne for the Blair multi-rope winder where the stress level variations in the rope would be as per the well known, tried and tested double drum winder. The Blair multi-rope was also devised to increase payload by using multiple ropes.With the increasing costs of transporting men and material coupled with fact that orebodies are getting deeper, various feasibility studies have been carried out by South African mining houses. For this reason Dorbyl Heavy Engineering has done conceptual design work of both double drum and Blair multi-rope winders with diameters up to 8.5 m dia (still well within our manufacturing capabilities). These feasibility studies have looked at depths approaching 4000 m*.This paper covers the typical duties leading to the choice of single drum, double drum, Koepe and Blair multi-rope hoists on South African gold mines. A brief synopsis of Dorbyl hoists in use in the South African mining industry, with some indications of future trends, will be discussed.With current installed depths of wind approaching 2500 m, the Blair multi-rope hoist has been used extensively for the heavier payloads.Some of the main considerations pertinent to the design of the Blair multi-rope hoist are illustrated together with the implications of using this type of hoist to winding depths of3000 m to 4000 m in the foreseeable future."

Jan 1, 1995

By M. H. Moys, C. Bhondayi, Eric Tshibwabwa

"The relationship between froth bubble size as represented by intra-bubble impact distances (IID) and flotation performance is investigated. Experiments using an artificial ore comprising of limestone as the floatable component and silica as the gangue material were carried out in pseudo-steady-state circuit. A method to measure IIDs developed by Bhondayi and Moys (2014) was then used to measure froth bubble sizes as a function of froth height, superficial gas velocity and feed rate (pulp residence time). Samples for flotation performance evaluation were also taken. Results indicate that as froth height increases, the average IID values increase resulting in a decrease in limestone recovery while the grade increases. Increasing gas rate results in lower IID values that are accompanied by high recovery and low limestone grade. The effect of feed rate on both flotation performance and average IID values depended on froth depth and gas rate. Average IIDs largely remained the same at the two feed rates investigated.INTRODUCTIONIt is regarded as obvious that froth bubble size distribution (FBSD) will have an effect on plant grade and recovery. As the average FBSD decreases, the bubble surface area flux will increase making possible an increase in recovery and a decrease in grade. The opposite trend will be involved if average FBSD is increased. However: no method for measuring FBSD has been available, so these trends have not been studied in any detail. Bhondayi and Moys (2014) developed a novel technique to measure or estimate froth bubble sizes. Although they established a potential to use this method in understanding froth performance, no data have been presented to assess the correlation between the estimates of bubble sizes and actual flotation performance. In this work experiments are done to establish how the change in froth phase bubble sizes affect flotation performance. Flotation performance will be evaluated using recovery and grade. How water recovery to the concentrate changes with changes in bubble sizes will also be evaluated. It is known that water recovery is approximately inversely proportional to the square of the overflowing bubbles sizes. It will be interesting to establish how the rate of change of bubble sizes changes with water recovery."

Jan 1, 2016

By M. Walmsley, D. Maynard

"This paper describes the use of terrain and soil information in the planning of mine developments, particularly in satisfying many of the existing provincial regulatory requirements. It is also noted that, if properly used, this will provide a solid data base for cost-efficient and environmentally acceptable land use.IntroductionIn planning the development or expansion of a new or existing mine, engineering alternatives are judged on many factors, one of which is the environmental influence. Ecological investigations, ensuring consideration of a rational approach to managing land use and environmental impacts, should be carried out prior to a final decision being made on mine development. The Pit Slope Manual (CANMET, 1976) suggests that both baseline aquatic and terrestrial data be collected and interpreted in such pre-mining surveys. In British Columbia, planning procedures now exist which incorporate biophysical studies to help identify, assess and manage major environmental impacts associated with mine development.Methods outlined in the Guidelines for Coal Development (E.L.U.C., 1976) have been successfully applied in recent years. Following this example, the Inspection and Engineering Division of the B.C. Mineral Resources Branch prepared guidelines to help expedite the development of new base metal mines (Procedures for Obtaining Approval for Metal Mine Development; Ministry of Energy, Mines and PetroleumResources, 1979).The metal-mine guidelines require the proponent of a new mine development project to prepare a two-stage assessment proposal which systematically moves from a preliminary feasibility study (Stage I) to a final project design (Stage II), including application for regulatory approvals. One purpose of the Stage I report is to provide a description of the existing environmental conditions that could be affected by the proposed development. A preliminary environmental impact assessment should also be reported. The Stage II report will contain detailed assessment and management of environmental impacts."

Jan 1, 1981

By Z. S. Abisheva

The Zhezkazgan copper sulfide ore deposit in Kazakhstan contains both rhenium and the rare osmium isotope "osmium-187" (187Os) in the high isotopic purity of 99.4 ± 0.2%. This isotope is believed to have originated as a result of the disintegration of one of the rhenium isotopes, according to the reaction: 187Re75 ?> 1870576 + B- + v~ (where B is a 13-particle, v~ is a 3-disintegration antineutrino). The distribution of osmium and rhenium in metallurgical byproducts produced during the recovery of copper from these ores has been studied and process flowsheets for the processing of rhenium and osmium-containing byproducts have been developed.

Jan 1, 2007

By Henri-Loui Jacob, Suzie Nantel

"Depuis la fin des annees 1800, la province de Grenville represente pour Ie Quebec une source importante et diversifiée de minéraux industriels. Le Ministère de l'Énergie et des Ressources du Québec, dans Ie cadre de I'entente auxiliaire Canada-Québec, et les compagnies minieres y ant multiplié, surtout depuis 1983, leurs travaux d 'exploration, de cartographie, et d'évaluation pour les minéraux industriels. Ces travaux ant conduit ala découverte et ala mise en valeur de gisements de granite architectural, de graphite, de dolomite et ant aussi permis de repertorier des gîtes et des indices prometteurs de wollastonite, de silice, de calcite. de dolomite, de silicates d'alumine et de terres rares. Les gisements récemment découverts sont actuellement exploités au sur Ie point de l'être et les gîtes et les indices les plus prometteurs ant été jalonnés.ABSTRACTSince the late 18oos, the Grenville Province in Québec has been an important and diversified source of industrial minerals. The Ministere de l'Énergie et des Ressources du Québec, under the Canada-Quebec Mineral Development Agreement, and the private sector have put an emphasis on exploration, mapping and evaluation programs in the Grenville Province for minerals, particularly since 1983. These programs have led to the discovery and the development of deposits such as architectural granite, graphite and dolomite, and have also led to inventories of occurrences and prospects of wollastonite, silica, calcite, dolomite, alumina silicates and rare earths. The deposits discovered lately are presently being quarried or will be in the near future. The most promising occurrences and prospects have been claimed."

Jan 1, 1990

By J. C. Roy, S. Couture, C. Barbeau

The chemical composition of the asbestos tailings from different mines in the Eastern Townships of Quebec are fairly uniform in composition. The serpentine minerals antigorite and chrysotile form about 85 to 90 per cent of the total. Iron oxides add another 7 to 10 per cent; magnetite represents about 70 per cent of the oxides. Chromite is present in amounts of about 0.5 per cent. The average contents of elemental magnesium, iron and nickel are 23, 6 and 0.25 per cent respectively.

Jan 1, 1972

By Robert B. Parsons

"Canadian income tax legislation contains a number of provisions which serve to facilitate the structuring of business arrangements, including mineral resource ventures. These rules are often fairly complex and not easily understood. This article attempts to explain in plain and understandable language the mechanics and benefits of one of the more frequently encountered provisions, the ""Section 85 election"".IntroductionThe Canadian resource industries are probably singled out for more special attention under this country's tax legislation than any other industry. This special treatment is, of course, not always welcomed by the industry, such as where unnecessarily restrictive taxation is perceived to exist or where agonizingly complex tax legislation must be dealt with. On the other hand, certain provisions in the tax legislation treat the industry in a relatively favourable manner, including a number of rules which, in recognition of the high risk and capital requirements of the resource sector, serve to facilitate the structuring of resource ventures."

Jan 1, 1984

By Stuart J. Schofield

Introduction The study of the ore deposits of British Columbia is one of fascinating interest not only from a scientific but also from a commercial standpoint and certain wide problems in connection therewith have interested me for some years. Several of these problems have been set forth in papers presented before this Institute on previous occasions. In 1918 it was pointed out that the commercial ore deposits of British Columbia, with one exception, were associated with the granodiorite batholiths of upper Jurassic age. This was followed, in 1922, by a discussion of the ore deposits of British Columbia in which the mineral belts of the province were defined and named, showing a zonal arrangement of ores in which the Pacific coast deposits are characterized by the presence of copper, while the interior belt is marked by the presence of silver, lead, and gold. Methods Of Investigation In reading various reports on the economic geology of British Columbia one is struck with the fact that the mineral veins may be arranged as a system and further examination will show that such a system follows two main directions, one northeasterly and the other northwesterly, both related in origin to the same force.

Jan 1, 1925

By M. Pelser, H. Gous, J. H. W. M. Brits, K. Voogt

The effect of impurities; iron and selenium, on current efficiency and deposit quality in copper electrowinning was investigated using an at-line cell at the Rustenburg Base Metals Refiners’ Copper Tankhouse. The tankhouse is a direct leach, starter sheet electrowinning operation with a unique electrolyte composition. The effect of iron on the current efficiency in the at-line cell was found to be less severe than reported in literature. However, the distinction between the chemical impact of iron on current efficiency and the physical impact of iron on a starter sheet operation needs to be realised. The effect of selenium on current efficiency and deposit quality is also reported. INTRODUCTION Anglo American Platinum’s Rustenburg Base Metals Refiners’ (RBMR) Copper Tankhouse serves a unique function in the refinery flowsheet in that its primary functions are the removal of copper and production of acid for the leach circuit. This function needs to be performed to specification in order to keep the leach circuit operating optimally. Current efficiency is seen as an indicator of tankhouse performance and efficient energy use. The tankhouse plates starter sheets onto titanium blanks which, after stripping and preparation, return into the production cells for further plating. Approximately 78% of tankhouses surveyed (Robinson et al., 2013) use permanent cathode technology whereas older, smaller operations still use starter sheet technology. Drawbacks of the starter sheet technology are that the starters are thin and bend easily leading to increased shorts, they need to be removed after two days of plating to be manually straightened and are then returned to the cells. In addition, the electrolyte levels in the cells need to be adjusted during the plating cycle to improve loop adhesion to the cathode and reduce loop corrosion. The starter sheet technology is therefore very labour intensive and the final quality of the product is dependent on the quality of the starter sheets produced. In comparison, permanent cathode or direct plating technology lends itself to automation, allows for higher current densities and better cathode quality due to more robust geometric stability in the cell. The present barrier to implementation of permanent cathode plating at the RBMR Copper Tankhouse is the capital cost required to convert the tankhouse, i.e. blanks and stripping machine. At present, alternatives to titanium blanks, such as LDX 2101, are being investigated for the unique electrolyte composition of this tankhouse.

Jan 1, 2019

By Wengui Su, Qi Zhang, Junce Wang, Zhijun Ma, Xingyuan Weng

"Mesoporous materials with large specific surface area, pore size, and pore volume have been widely used in many fields such as ion exchange, gas separation, adsorption, and catalysis. Mesoporous materials prepared using natural zeolite have the advantages of both acid and alkali resistance. In this work, mesoporous materials were prepared using natural zeolite as the starting material and diethylenetriamine (DETA) as a template. The resulting samples were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and N2 adsorption-desorption experiments. The influence of the crystallization temperature and crystallization time on the specific surface area, pore volume, pore size, and morphology of the resulting mesoporous materials are also discussed. Our results show that for an increase in both the crystallization temperature and time, the average pore size first increases then decreases, while the specific surface area first decreases then increases. Based on this work, we concluded that the optimal crystallization temperature was 2003 and the optimal crystallization time was 60 h. These conditions gave an average pore size of 17.93 nm, a pore volume of 0.048 cm3g-1, and a specific surface area of 16.48 m2g-1.INTRODUCTIONMesoporous zeolite, as the name implies, is a highly porous crystalline zeolite. This material is of interest due to its high hydrothermal stability, its adsorption and diffusion properties for macromolecules, and its excellent selectivity and activity as a catalyst. In recent years, it has become a hot spot among research of porous catalytic materials and has been widely used in petroleum and natural gas processing, fine chemical processing, various adsorption and separation tasks, and other uses (Carvalho & Urquieta- Gonzalez, 2015; Teh, Triwahyono, Jalil, Mukti, Aziz, & Shishido, 2015)."

Jan 1, 2016

By H. Rafiei Renani, C. D. Martin

"The Cohesion Weakening Friction Strengthening (CWFS) is adopted in numerical analysis to capture the observed progressive failure of hard rock pillars. As a case study, pillars at the Elliot Lake mines with width to height ratios of 0.5 to 3 were analyzed in FLAC3D. Pillars with width to height ratios of 0.5 and 1 show a very similar strain softening behavior while with width to height ratios of 2 and especially 3 indicated prolonged strain hardening. The CWFS model successfully captured the mechanism of progressive failure observed in hard rock pillars including initiation of spalling at the corners, progress of spalling towards the centre and formation of hour-glass shaped pillar, and eventually shearing through the width of pillar. Both the CWFS model and site specific empirical formula successfully separated the stable and failed cases in the Elliot Lake mines. While both models are in reasonable agreement for width to height ratios of less than 2, the empirical formula gives increasingly lower strength values for wider pillars which may result in excessively conservative and uneconomical design.INTRODUCTIONPillars are the portion of in situ rock left between the adjacent openings to maintain the stability of excavations. Conditions of equilibrium require that the loads previously carried by the excavated rocks be transferred to the pillars resulting in elevated stresses within the pillar. Hence, prediction of the behavior of pillars under these loads is important for underground design. Determination of the strength of pillars is a classic subject in underground mining. In conventional mining methods such as room and pillar operations, economic incentives point towards higher excavation ratios i.e., leaving smaller pillars between the mined excavations, while safety and stability requirements favor wider stronger pillars. In some mining methods such as caving operations, the problem is even more challenging. On one hand, the whole operation is directly dependent on the proper continuous flow of caved ore between the drawpoints which requires optimizing the spacing between drawpoints and thereby often leaving narrower pillars. On the other hand, the pillars should be wide enough to ensure the safety of mining operation. Both the blockage of drawpoints as a result of wide pillars and uncontrolled failure of narrow pillars can jeopardize the investments and mining operation.Therefore, design of pillar poses a somewhat unique challenge to rock engineers where simple conservative approaches frequently used in other design methods are no longer acceptable. The behavior of pillar under elevated loads should be predicted accurately."

Jan 1, 2015

By Michael Schindler

Uranyl mineral dissolution appears to be complex, affected by factors such as solution pH and the presence of various cations in solution, and sometimes involving formation of secondary surface precipitates. Such secondary precipitates potentially could armor the underlying uranyl mineral surfaces from further dissolution. A detailed understanding on the formation of secondary precipitate is therefore essential for predictive modeling of radionuclide fate and transport in the subsurface. Several types of secondary precipitates on the surface of uranyl minerals were examined using Atomic Force Microscopy, Scanning Electron Microscopy, and, Xray Photoelectron Spectroscopy.

Aug 1, 2010

By D. R. Schmitt, Q. Jia, R. Kofman

"Tests were carried out on clear glass blocks containing borehole aligned with and at an angle to applied principal stress states in order to study the growth of drilling induced tensile fractures. The samples were illuminated such that photoelastic fringes could be video recorded during the measurements; this was useful in assessing states of stress and in determining fracture initiation. Axial drilling induced fractures were observed at the azimuths of the applied uniaxial stress as would be expected from the concentrated stresses. En echelon fractures were observed from the borehole deviated at 45° to the direction of the compression. These preliminary and currently qualitative results show that glass blocks serve as a useful test medium for studies of stress concentration and drilling induced fracture creation. INTRODUCTIONWith the increasing exploitation of unconventional oil/gas reservoirs using deviated drilling in recent years, the effects of the in-situ stress on the success of energy production have become more critical than ever before. Knowledge of the state of stress in the earth enables us to determine well trajectories, well locations, hydraulic fracturing design and production rates, but knowing the crustal stress is always challenging. Strictly, it can only be obtained to varying quantitative degrees by accessing the earth through drilling. Failure of the rock at the borehole wall produces borehole breakouts (e.g., Bell & Gough, 1979; Haimson & Herrick, 1986; Zoback et al., 1985) and drilling-induced tensile fractures (DITF) (e.g., Aadnoy, 1990; Aadnoy & Bell, 1998; Barton et al., 1997; Brudy & Zoback, 1999; Davatzes & Hickman, 2010; Peska & Zoback, 1995). Thus, it is important to understand the failure mechanism of the rock in the vicinity of the borehole. A number of closed-form expressions have been developed that allow the stress concentrations to be calculated in the vicinity of a borehole including Kirsch’s (1898) 2-D plane strain solution and 3D formulae for elastically isotropic (Hiramatsu and Oka, 1962) and anisotropic (Lekhnitskii, 1981; Amadei, 1983) continua. These solutions have been applied in numerous studies (e.g., Ong, 1994; Ong & Roegiers, 1996; Vahid & Ghassemi, 2011; Jia & Schmitt, 2014; Ito et al., 2001) to analyze the failure mechanisms of drilling-induced tensile fractures (DITF) on the borehole wall."

Jan 1, 2015

By A. Abadías Llamas, N. Bartie, M. Stelter

Evaluating the economic viability as well as the sustainability of the Circular Economy (CE) system requires a deep understanding of the distribution of all elements, compounds, alloys, materials etc. in flows. In this paper, the circularity of the copper value chain, including primary and secondary processing, is rigorously evaluated. The studied system comprises the metallic copper production from primary sources (from mineral to metal), copper-containing commodity production (copper is mixed with other metals) and copper recycling through secondary smelting to close the loop. This is linked to photovoltaic (PV) panels and battery storage. A simulation model of this system is created using HSC Sim, considering more than 30 elements (and its various compounds), 180 unit operations and 800 flows. From the mass and energy balances obtained through the simulation, an exergy analysis is conducted to evaluate the resource consumption from a second law (entropy) perspective. Additionally, these results are complemented through a Life Cycle Assessment (LCA), the recovery of technology elements and by-products is discussed, while quantifying the losses through the value chain. Through the digitalization of the complete system, a better CAPEX and OPEX understanding of the metal recovery and losses can be obtained, as well as the associated resource consumption and environmental impacts. New flowsheets and technologies can be evaluated. Several scenarios show how the resource consumption and the environmental impacts are affected by the recovery of different materials to produce different products. INTRODUCTION A key challenge of the circular economy (CE) is the linkage and optimization of both resource and energy efficiency of the (renewable) energy infrastructure and the resource cycle depicted by Figure 1 simultaneously. In addition, the CE requires the linkage of all stakeholders as shown by Figure 1. This has been discussed in some detail by Reuter and Bartie (2019) and Reuter et al. (2019). Copper and all its associated technology elements is one of the key enabling metals that is an economical copper colored thread through CE society (Reuter & Kojo, 2014). The Metal Wheel (Figure 2) shows the linkage of and recovery of various elements associated with copper and other carrier metals. This reveals that copper acts as an important carrier metal because of its properties i.e. the wealth of technology elements it carries from geological ores, but also its capacity to act as solvent of valuable elements and thence a key closer of various complexly connected element and material cycles when these technology elements are released during copper refining. The same applies to all other carrier metals of modern CE society as shown for example recently in a lead policy brief (Blanpain, Reuter & Malfliet, 2019).

Jan 1, 2019

By Liguang Wang

The froth phase in flotation has received much less attention than the pulp phase despite the fact that froth stability plays an important role in determining flotation performance. Froth stability is largely determined by the stability of thin foam films, which in turn has a strong correlation with the critical rupture thickness (Hcr) of the films. In the present work, a new approach to predicting the Hcr values of thin foam films in flotation froth phase was proposed and examined. The Hcr values were calculated using an advanced capillary wave model with input parameters being surface tension, film radius, capillary suction pressure, and intersurface force. The intersurface force was estimated by using the Stefan-Reynolds lubrication approximation to fit the measured thinning rates of single foam films formed in a Scheludko ring cell, where the film radii were less than 50 microns and were kept constant during the film-thinning process. A comparison between the predicted and experimental Hcr values was made for the films with the use of sodium chloride as background electrolyte and in the presence of various frothing reagents such as methyl isobutyl carbinol (MIBC), polypropylene glycol with an average molecular weight of 400 (PPG400), and sodium dodecyl sulphate (SDS), at different concentrations and film radii. It was found that the model correctly predicted the trends of Hcr-versus-concentration and Hcr-versus-film radius curves. Moreover, the predicted Hcr values matched well with the experimental ones of the foam films containing either SDS or PPG400. For the foam films containing MIBC, however, the model overpredicted the Hcr values. The reason for this discrepancy was discussed.

Jan 1, 2016