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By J. Gotor, C. Frias, E. Delgado

The Iberian Pyrite Belt (IPB) is one of the world's largest reserves of primary sulphides containing base metals (Cu, Zn, Pb), precious metals and some special metals such as indium. Estimated resources are over 1,500 million tonnes of volcanogenic massive sulphide ores. From 1980´s Europe lives the decline in its mines mainly motivated by the low price of the metals. One aspect that contributed equally to this was the ecological disaster produced by the discharge of more than seven million tonnes from the tailings dam of Boliden-Apirsa (Aznalcollar) in 1998. Today the situation is different; the companies present in the IPB have given evidence that it is possible to reconcile mining projects and care on the environment, and the regional authorities are opening a public tender to re-start Aznalcollar mine. A new challenging era has been started at this Spanish/Portuguese mining area. This paper presents the results and preliminary economics of a project devoted to IPB primary sulphides processing through different technology approach, e.g. conventional selective flotation against bulk flotation or mixed metals flotation combined with hydrometallurgical processing.

Jan 1, 2014

By W. G. Hubler

History The Aldermac mine is situated on the Nipissing Central railway near the ' centre of the township of Boischatel, Quebec, and is about ten miles west of Noranda. Aldermac Mines, Limited, is a subsidiary company of Towagamac Exploration Company. The property was staked by Messrs. Alderson and MacKay and McMartin, during the winter of 1922-23. During October, 1925, a copper discovery was made by K. W. Fritzsche, who was in charge of exploration work at that time, the first trench on this discovery averaging 8 per cent copper over a width of ten feet. This led to the discovery of another body 200 feet to the north, with an average of 3 per cent copper over fifteen feet in width. A magnetic survey was then carried out which led to the location of the large pyrite ore-bodies which have been developed in the past few years. Development work was carried on to a depth of 1,125 feet, and approximately three million tons of massive pyrite ore was indicated. Extensive metallurgical tests were conducted in the laboratories of the Mines Branch of the Department of Mines at Ottawa to determine the proper metallurgical treatment and the economic possibilities of the ore. Owing to the comparatively low copper content, and the uncertainty of the copper market, it was doubtful if the mine could be profitably operated for the production of copper alone. Messrs. Alderson & MacKay, however, realized the possibility of utilizing the large tonnage of pyrite as a substitute for native sulphur, 'which in past years has been imported into .Canada for the manufacture of acid and sulphate pulp in paper mills. They therefore organized the Sulphite Research Corporation with the object of developing an economical process of utilizing the pyrite.

Jan 1, 1932

By D. Kong, A. Klyashtorin, L. McGilp, I. Wilson

This work reports on applying iron oxide coated sands media in an experimental permeable reactive barrier to remove uranium species from uranium containing water. A field experiment was conducted at the legacy Gunnar uranium mine & mill site that was abandoned in the 1960s with limited to no decommissioning. The flooded Gunnar mine pit presently contains about 3.2 million m3 of water contaminated by dissolved U (1.2 mg/l), Ra-226 (0.4 Bq/l), and minor concentrations of other contaminants (As, Se, etc.). The water is seeping over the pit rim into Lake Athabasca posing environmental and health concerns. Iron oxide coated sands can be used to immobilize uranium species through an adsorption process. Methods for preparation of hydrous ferric oxide sorbents and their supported forms onto silica sands are described. Fourier transform infrared spectroscopy (FTIR), and powder X-ray diffraction (pXRD) were used to characterize the physical-chemical properties of the sorbent. The monolayer uranium uptake capacity (Qm) was estimated through the Langmuir adsorption isotherm. Adsorption kinetic experiments were performed in a lab environment before moving to a field trial. Based on these lab results and the input on field-scale appropriate geometries, a pilot permeable reactive barrier was fabricated and a field test conducted near the Gunnar pit in June 2019. This pilot test provided technical data and information needed for designing a full-scale permeable barrier based on the iron oxide coated sands, which may be applied for in-situ water treatment at Gunnar and other legacy uranium sites.

Jan 1, 2020

By G. A. McGuffin

"IntroductionWITH the increase in quantity of sour gas reserves in the Province of Alberta, and the wider market for sulphur brought about by mounting world demand and restrictions placed on the principal supply, it was inevitable that this important source of sulphur would be .developed. In the light of these facts, it seems timely that a general paper on sulphur recovery from petroleum gases be presented. This, then, is the purpose of the following text. A short discussion of each of the following subjects is presented:(1) Properties and uses of sulphur(2) Existing sources(3) Market research(4) The recovery process in Turner Valley(5) Hazards of sulphur productionNo pretext of originality of material is made since innumerable reports have been prepared on this and related topics and information contained in these has been used quite liberally.Properties and uses of SulphurSulphur is a non-metallic element having an atomic weight of 32.06. The stable crystalline form at atmospheric temperature is referred to as 'rhombic' sulphur. It is bright yellow and has a specific gravity of 2.05, equivalent to 129.2 lb./cu. Ft. Above 204°F. sulphur has another stable crystalline form, referred to as 'monoclinic'. This is reddish-brown and is slightly less dense than the rhombic variety (122.4 lb./cu. Ft.). Sulphur in bulk form weighs 84 to 90 lb. per cu. Ft. Sulphur melts at approximately 240°F. to a straw coloured liquid which is quite viscous."

Jan 1, 1952

By B. Ignasiak

Laboratory studies suggest that improvements of coke strength brought about by pre-heating caking coals before carbonization accrue from inadvertent oxidation rather than from other low-temperature changes in the coal mass. Controlled oxidation of highly caking coal, followed by laboratory carbonization, produces cokes which, in terms of a laboratory scale tumble test index, are equivalent to those obtained from prime metallurgical blends. Appropriately formulated blends of exhaustively oxidized and fresh caking coal similarly yield cokes with strength indices comparable to those of cokes made from the same coal after oxidation under optimum conditions.

Jan 1, 1979

By Garnet T. Page

"ABSTRACTThese societies •can help in such aspects of a vocation.al guidance program in secondary schools as: provide vocational and technical information, and assist with vocational exploration, such .as plant visits, films, etc. -as .an aid to the student in making a self-inventory. Evidence is increasing that employers' needs for engineers and scientists will not be adequately met in the future. Therefore, the E.I.C., C.I.M., .and C.I:C. recently revised and extended the activities of the Canadian Counselling Committee on Engineering and Science. This co-•operative .action is to be integrated with the educational system, nationally .and locally, and with provincial associations •of engineers and other groups interested in the provision of vocational information in engineering and science.DEFINITIONTHE scientific treatment of any subject requires consistent use of carefully defined terms. The National Vocational Guidance Association of the United States studied the problem of the definition of vocational guidance for .about 16 years, and in 1937 finally arrived at:""Vocational guidance is the pro-cess of assisting the individual to choose an occupation, prepare for it, enter upon and progress in it. It is concerned primarily with helping individuals make decisions and choices involved in planning a future and building a career -decisions and choices necessary in effecting satisfactory vocational adjustment.""RANGEAs a school enterprise, vocational guidance begins at that point in the individual's life when he finds it necessary to make choices that have a definite significance for his future vocation."

Jan 1, 1952

By E. Herrera, L. Mariscal

"Ilo Copper Smelter operates since 2007 with an ISASMELTTM furnace as a single smelting unit (1,200,000 tpy) associated with two Rotary Holding Furnaces for separation of matte and slag, and which directly produces a discard slag. Southern Peru continually has been improving the slag chemistry of its ISASMELTTM furnace in order to reduce copper losses, given its big economic impact due to large slag mass generation. The present paper describes the influence of the CaO, Al2O3 and magnetite content in the slag of the ISASMELTTM furnace correlated with the SiO2/Fe ratio and its liquidus slag. Also it defines the best slag chemistry and operating practice in order to reduce the copper losses without compromise the bricks life of the furnace.INTRODUCTIONIlo Copper Smelter of Southern Peru (Grupo Mexico) is located on the southern coast of Peru, and treats mainly copper concentrates produced in its own mines (Toquepala and Cuajone).The modernized smelter was commissioned in 2007 and operates with an ISASMELT™ furnace as a single smelting unit (1,200,000 tpy), which is associated with two Rotary Holding Furnaces (RHF) for separation of matte and slag. This slag is directly sent to the dump. Figure 1 shows the smelter flow diagram.The ISASMELT™ process is a bath-smelting process using a single lance. The lance tip is immersed into a molten slag bath contained within the stationary, vertical, refractory-lined ISASMELT™ furnace. The injection of oxygen-enriched air, through the lance into the slag results in a highly turbulent molten bath. Feed material falling into the turbulent bath from above reacts rapidly, resulting in extremely high productivity for a relatively small bath volume."

Jan 1, 2012

By X. (Mike) Yao

Rock mechanics engineers must provide ground support designs that ensure a safe underground working environment. Unexpected falls of ground are unacceptable while ground support systems must be adequate. Ground support must be economic for the area supported and the time frame the opening is in use. While numerical modeling can be used for ground support design, empirical models are still the common useful design tools. Empirical models are best developed and improved from local experiences although some models, such as Stability Graph (Potvin et al, 1992), are in extensive use by the Canadian mining industry. To determine the adequacy of ground support practices at HBMS, a database of 50 fall of ground case histories between 1985 and 2001 was compiled. For each failure, the recorded data included: location, rock type, rock mass conditions, opening and failure geometry, installed ground support and failure mechanism. An analysis of the database was done to obtain an understanding of failure frequency association with rock types, stope geometry and installed ground support, and to assess what support design changes were necessary. The paper describes changes made to ground support and mining practices during the last five years, and the formation of new ground support standards and practices which have been successful in reducing ground falls while providing improved, efficient and economical ground support.

May 1, 2002

By G. Morin, S. Amira, F. Chiesa, B. Duchesne

"The effect of heat treatment on the stress corrosion cracking (SCC) resistance of A206 aluminum alloy was studied using the breaking load test according to ASTM G139 standard. This method uses the residual strength measurement from tensile test specimens previously stressed axially while exposed to the 3.5% NaCl alternate immersion test according to ASTM G44 standard. The residual strength after exposure is used as a measure of SCC degradation. The performed heat treatments were conventional natural aging T4 and artificial over-aging T7 tempers in addition to artificial aging T6 temper added for purpose of comparison. These tests showed that A206-T4 has a good resistance to SCC at pre-loads up to 100 MPa while A206-T7 was prone to SCC for pre-loads of 0 and 50 MPa, and showed total loss of ductility for pre-load of 100 MPa. Both A206-T4 and A206-T7 pre-loaded at 150 MPa showed poor resistance to SCC. A206-T6 showed the worst susceptibility to SCC as it lost all mechanical resistance at the end of the alternate exposure to 3.5% NaCl solution, even without any applied pre-load. Metallographic analyses showed that the resistance of A206 alloy to SCC is mainly affected by the transition from pitting to intergranular corrosion attack. The initiation and the propagation of intergranular corrosion attack might be assisted by high stress concentrations in the pits, particularly for pre-loads higher than 100 MPa. The transition from pitting to intergranular corrosion can also be promoted by hydrogen evolution from growing pits, which supports crack propagation by hydrogen embrittlement.INTRODUCTIONA206 aluminum-copper casting alloy offers ones of the best mechanical properties among the aluminum foundry alloys. This alloy belongs to the 206 alloy family developed in 1970s as an alternative to the highly resistant and ductile but more expensive Ag containing 201 alloy (Tiryakioglu, 2009). A206 showed also good low cycle fatigue strength (Sigworth, 2002). These properties made A206 alloy a strong candidate for some vehicles lightweighting applications. In spite of its interesting properties cited above, A206 alloy was rarely used in critical applications due to its tendency for hot tearing and stress corrosion cracking (SCC). Studies of A206 hot tearing behavior showed that this tendency can be reduced by improving castability and by grain refinement (Sigworth, 2002). The optimisation of the casting design can also prevent the tendency toward hot tearing. The SCC of aluminum-copper alloys arises from their susceptibility to localised corrosion, especially in chloride containing media. The localised corrosion in Al-Cu alloys is caused mainly by their heterogeneous microstructure, where the presence of many phases leads to the formation of micro-galvanic coupling with the matrix. However, most of the studies aimed at investigate the SCC of Al-Cu alloys concerned the wrought ones, especially the AA2024 alloy tempered in the T3 (or derivative) condition and few studies concerned the 206 and cast alloys in general (Alexopoulos, 2009 and 2016; Campestrini, 2000; Vogt, 1998; Talamantes-Silva, 2008; Zhang, 2003). Jean et al. (Jean, 2009) studied the effect of heat treatment on SCC behavior of B206 alloy using alternate immersion technique and grain boundary attack method and did not find direct correlation between the two methods. Another study showed that aging of 206 alloy may make a casting susceptible to SCC (Sigworth, 2002). However, these studies did not provide detailed information about the mechanisms of SCC of 206 alloy, as well as the effect of the stress intensity. The present work investigates the effect heat treatments and the stress intensity on the morphology of the corrosion attack and the SCC behavior A206 aluminum alloy. This study uses the breaking load test according to ASTM G139. This test utilizes direct tensile specimens and was developed to give a more quantitative measure of the SCC performance of resistant aluminum"

Jan 1, 2016

By G. Avramovic-Cingara, H. J. McQueen

The microstructure of commercially pure aluminum was investigated by using polarized optical microscopy (POM), orientation imaging microscopy (OIM), and transmission electron microscopy (TEM) techniques. Specimens were deformed in torsion at 400°C and equivalent strain rate of 0.1 s-1, to various strains of 0.2, 0.5, 1, 4, and 6. The results indicate that POM can usefully reveal grain and subgrain structures over a large field in aluminum. TEM is most suitable to study dislocation substructure and evolution of subgrains. While TEM microscopy and OIM are capable of resolving individual subgrains, OIM can not reliably distinguish subgrains with small misorientations, particularly in samples with low strain. On the other hand, the OIM technique is very useful in the analysis of many regions surrounded by high, medium, and low angle boundaries (HAB, MAB, LAB). Various misorientation maps were studied using different data processing methods. The analysis revealed that the subgrain size is relatively insensitive to strain. The fraction of low LAB ( < 5°) decreased and HAB (>15°) increased conversely with increasing strain, whereas MAB (5-15°) remained stable. The development of an increasingly bimodal grain boundary misorientation distribution is consistent with the predominance of dynamic recovery (DRV) in the evolution of microstructure, combined with geometrical dynamic recrystallization (gDRX), now called grain-refining DRV.

Jan 1, 2006

By T. C. Murphy, W. Taciuk

In 1966, the Iron Ore Company of Canada commissioned a wet magnetic scavanging plant for the recovery of fine magnetite values p.resent in spiral tailings discharged from a spiral gravity separation process. The plant includes dewatering, grinding, classification, thickening, mini-wedge screening, and primary, secondary and tertiary wet magnetic separation stages. The source of feed varies in quantity and quality, so the original design included variable operational procedures to deal with these conditions.

Jan 1, 1972

By A. Musschoot

"The paper will review general types and designs of vibratory feeders, describing briefly the design features and characteristics that apply to the application of specific types. Control considerations for selecting types will be dis• cussed, such as fixed or adjustable, manual or automatic, individual or multiple bank, and process requirements. Design parameters for hopper openings and installation geometry will be discussed, including consideration of material size distribution, segregation, moisture content and other characteristics, based on practical applications and experience as well as theory. Pan designs and the selection of pan materials will also be discussed with reference to wear, corrosion, impact and practical economic factors."

Jan 1, 1972

By T. G. Joseph, M. J. Bolster

ABSTRACT This paper explores passive seismic measurement as an alternative, nonintrusive approach to conducting annual brake testing on surface mine sites. Dictated by the test site location, this evaluation adhered to the brake testing procedure as per British Columbia occupational health and safety regulations. Results showed excellent correlation to those reported via conventional practice: Comparing stopping distance, time, and velocity for the proposed instantaneous passive seismic versus conventional approaches, less than a 0.5% variance was evident. A viable alternative, the passive seismic approach, allowed an entire fleet of trucks to be sequentially evaluated for annual brake testing without disrupting operations by installing mechanical testing equipment.

Jan 1, 2012

By W. S. Szolga, M. Moser, M. D. Soderstrom, L. Cohen

"CYANEX® 272 is a phosphinic acid-based solvent extraction reagent used commercially since the early 80’s to recover and purify cobalt from sulfate solutions. Historically, the design of CYANEX 272 circuits has involved the selection of an optimal pH profile during pilot-scale testing using mixbox pH control. The desired pH profile is required to be carefully controlled in the same manner during commercial operation. To assist operators in the design and optimization of their circuits, Solvay developed CYANEX 272-specific solvent extraction modeling software, which has enabled determination of the ideal pH profile and staging configuration. Solvay’s recent advances in modeling capabilities have allowed the simulation of circuits without direct mixbox pH control. Modeling has indicated that circuits operated without direct pH control can achieve the desired metal separation while simplifying the commercial operation significantly. This paper reviews a number of potential circuit configurations for the use of CYANEX 272 and demonstrates the separations achievable under the right design and operational conditions, some of which have historically been considered too difficult.INTRODUCTION CYANEX® 272 is a phosphinic-acid based reagent designed specifically for the separation of cobalt from nickel by solvent extraction from weakly acidic sulfate solutions (Rickelton, Robertson, & Burley, 1982; Rickelton, Flett, & West, 1984; Rickelton & Nucciarone, 1997). Following commercial introduction in the 1980’s, CYANEX 272 has been used in a number of hydrometallurgical flowsheets for cobalt purification and/or recovery. CYANEX 272 metal extraction occurs by means of a cation exchange mechanism. Extraction of a divalent metal ion M2+ is represented by the following equation where RH represents the CYANEX 272 ligand and MR2 represents the ligand-metal complex."

Jan 1, 2017

By J. J. Jonas, G. R. Stewart, N. Pokutylowicz, S. Yue, R. Varano, A. Elwazri

Differing thermal histories in and around a weld can lead to differences in grain size, phase composition and morphology of precipitates; mechanical properties will vary accordingly. Hardness testing gives limited information and the machining and testing of tensile and/or impact specimens that would reveal these variations (which may occur over very small distances) is not practical. Therefore, in this investigation, shear punch testing was applied to measure the variation in the room temperature mechanical properties of a welded pipeline steel.

Jan 1, 2005

By G. W. Harris, P. Mousset-Jones, J. Daemen

"To minimize ore dilution induced by blast movement in surface mines, it is necessary to quantify such movement. This will enable more accurate location of the grade boundaries beneath the surface of a blasted rock pile before excavation. A method has been developed and tested to accurately measure the direction and magnitude of subsurface blast movement. This technique uses a cesium vapour gradiometer and a real-time, differentially corrected GPS system to locate pre- and post-blast position of magnetically enhanced target objects placed within blastholes inside a bench. The procedure developed does not require the blasted rock to be disturbed, and the movement information is available within a sufficient time to allow for modification of the selective mining boundaries for each surveyed blast. It was found that the maximum depth of target detection was 18 m, with the overall accuracy being measured as ±1 m (horizontally) and ± 1.2 m (vertically). IntroductionOre dilution is a critical concern for many mining operations. In some instances, it may be the cause of considerable mineral loss. Where the mineralization is finely grained, sedimentary and disseminated in nature, and exhibits no clearly defined visual ore/waste boundary, there is a heightened possibility for ore grade dilution. In most modern open pit gold mines, it is economically desirable to minimize dilution in the production process through the practice of selective mining by defining pre-blast ore digging boundaries, called digging polygons, on the preblast bench area. The polygons’ positions are defined by sampling the production drill holes, with the resultant assay and survey data being used to estimate the areas of specified grade content within the bench. Once the ore is blasted in the bench, the pre-blast locations of these digging polygons are flagged as designated areas on the broken ore pile. The purpose is for the loader operator to be able to recognize which areas of blasted rock are to be sent to the appropriate processing facility or to the waste dump."

Jan 1, 2001

By D. R. Pyke

Many of the gold deposits in the Timmins• area show a close spatial association to ultramafic metavolcanics. Available analytical data suggest that ultramafic rocks contain significantly higher gold contents than other major rock types. In addition, recent analyses by Keays (1975) suggest that talc-carbonate alteration of ultramafic rocks releases significant quantities of gold. It is proposed that the ultramafic volcanics formed the principal source of gold for the deposits in Timmins, and that the gold was derived from the ultramafic flows when they were extensively carbonatized. Carbonatization of the ultramafic rocks and emplacement of the auriferous quartz-carbonate veins was probably coincident with the last major period of deformation in the gold camp. Delineation of hitherto unrecognized ultramafic volcanics could be an important guide to the discovery of further gold deposits.

Jan 1, 1976

By Ian Orford, Ken L. Boyd

"Can the ever-increasing tonnages of ore and waste being mined today be accommodated simply by using bigger and better crushers? This paper updates the principal author’s earlier publication, “Crushing Plant Design and Layout Considerations” (SME Mineral Processing Plant Design, Practise, and Control, 2002). It reviews the latest primary crushing and large cone crusher designs. Its goal is to help consultants and operators select the optimal equipment and custom-designed items in the material handling flowsheet from the mine to the mill, maximizing operating hours per year.INTRODUCTIONAre larger crushers the answer to meeting the demands of existing or new mining projects for increased tonnage? The principal author’s previous paper in the year 2002 on ""Crushing Plant Design and Layout Considerations"" provided a detailed design and layout review for the design of primary and fine crushing (Secondary, Tertiary, Quaternary) mineral processing facilities. Some of the conclusions in this previous paper had predicted that larger crushers for primary and fine crushing would be beneficial and contribute to the further development of mineral processing. Larger crushers for primary and fine crushing applications are now available.The rock size reduction process, from the mine to the selected milling process facility has not changed since man first broke a rock to get at the interesting mineralization within. The rock size reduction process circuit from the mine to the mill can be summarized into four (4) stages:• Stage 1: Mining ( Rock Breakage and Fragmentation)• Stage 2: Pre-Screening (Scalping)• Stage 3: Primary Crushing• Stage 4: Fine Crushing (Secondary, Tertiary and Quaternary; the crushers used in this stage are identified by the titles which usage has conferred on them)Plant throughput and ore delivery schedule will form the basis for flowsheet design and equipment selection. Once a project's design criteria and the mine plan has been established, the actual circuit's utilization percentage (percentage of hours when the circuit is being utilized) can be optimized for each of the four stages. The mining and process departments are the key stake holders in the selection of the final comminution circuit and both departments should be familiar with and contribute to the design of the circuit."

Jan 1, 2016

By Joseph Sawicz

By now, the concept of remotely controlling heavy equipment in underground mines has become commonplace. Personnel safety is the biggest justifier for remote control, followed by an inherent cost saving (in certain cases) when wireless video is added to the mix. There are a handful of vendors targeting this need, and for years the mines have remained loyal to their brand. But as the number of remote-control related accidents and maintenance costs increase it forces our industry to take another look at this commonplace concept. And as the blinders are taken off, the mines are getting the revelation that not all remote control systems were created equally. This paper highlights the differences between various remote control systems, and then moves into an in-depth look at HARD-LINE?s package which drastically cuts maintenance costs, and also provides a solid investment toward full Tele-operation.

Apr 1, 2005

By Eiichiro Mizushima

Catalyst systems comprising (Ph3P)AuCH3 and acid co-catalysts were found to be highly efficient for hydration of alkynes to give ketones. Methanol was the best choice of solvents. Introduction Hydration of carbon-carbon unsaturated bonds is one of the environmentally benign routes to the carbon-oxygen bond formation. Hydration of alkynes forming carbonyl compounds, an important variation in this category, is a well known reaction which has been extensively studied. The reaction by acid-catalysis is the most conventional method, while it is applicable only to electron rich acetylenes to obtain satisfactory yields (1,2). The hydration of simple alkynes usually requires another catalyst (co-catalyst), typically a mercury(II) salt (3), which is inconsistent with the guiding principle of Green Chemistry (4).

Oct 1, 2003