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By V. Caps

Gold has been often used as an alloying component in order to increase or modify the catalytic properties of an active metal. For example, in the hydroconversion of methylcyclopentane, Riahi et al [1] shown that the addition of gold to palladium or platinum enhances the activity which becomes greater than that of the pure metals whereas the selectivity towards products resulting from ring expansion increases. Molenbroek et al [2] presented a detailed study on Ni-Au catalysts which exhibit activity for steam reforming and have been proved to be more resistant toward carbon formation than the pure Ni catalysts. Blocking of highly reactive Ni edge and kink sites by Au atoms is assumed to be the reason for the increased robustness of the Ni-Au catalyst. Nevertheless, the own catalytic properties of pure gold have been almost ignored up to the pioneering work of Haruta et al [3] which demonstrates the high activity of gold for CO oxidation at low temperatures. Other reactions such as WGS reaction, propylene epoxidation or benzene total oxidation have then been shown to be catalyzed by gold [4]. This discovery induced the publication of papers devoted to analyze the different factors controlling the activity of gold catalysts. Among them the most relevant appears to be the gold particle size, the nature of the support [5] and the preparation methods [6]. Clearly distinguish between support and size effect is not straightforward. Indeed, the calcination step often needed to synthesize supported catalysts on different supports, leads to different particle sizes showing that particle size and support are interdependent. To circumvent this difficulty, Au-based supported catalysts have been synthesized by using laser vaporization and low energy cluster beam deposition. The as prepared catalysts have then been characterized and tested in CO oxidation reaction.

Oct 1, 2003

By A. P. Yovanovic, P. Bonadia, M. N. Moraes, C. F. Matos

"The magnesite flotation operation of Magnesita Refractories, in Brumado – Brazil, has four parallel ball mills working in closed circuit with hydrocyclones to grind the ore for the reverse flotation of silicates in mechanical cells. The modification proposed here opens the circuit for three of the ball mills so that their products are collected together to feed a high frequency screen. The oversize of the screen feeds the fourth ball mill in closed circuit for secondary comminution. The product reports to dewatering and flotation. The undersize undergoes desliming and subsequent flotation operation. According to pilot tests performed, the modification on the magnesite flotation operation will promote a 20% increase in the productivity, 8.5% increase in mass recovery and a 26% reduction in water consumption. The gains are due to the fact that the silicates in the feed are concentrated in the smaller particles (<100µm) with over grinding in the existing closed comminution circuit, making it impossible to take advantage of this natural selectivity. The combination of open circuit, more selective milling, and the high frequency screen, ensures high efficiency particle size classification. This renders the process more effective, both to the screen undersize with its high contents of silicates and fines, and to the screen oversize, which is almost without fines and has a higher magnesite grade. This situation allows for the setting of specific parameters for the flotation of both the primary milling undersize and the secondary milling product.INTRODUCTIONMagnesita Refractories, with its operations site in Brumado, is the largest producer of high purity dead burned magnesia (DBM) in Latin America. The magnesite ore is extracted from an open pit mine, named Pomba, after which it is crushed and handpicked. Due to the presence of disseminated silicate the ore has to be ground and concentrated by means of reverse flotation, before feeding the high temperature kilns for sintering and conversion to DBM.The magnesite flotation unit has an impact crusher to reduce the size of the feeding ore, which is transported to the mills by conveyor belts. The milling operation is composed of four ball mills in closed circuit with hydrocyclones. The closed circuit generates a high circulating load with excess fines, which is detrimental to the selectivity of the desliming and flotation operations, reducing both mass andmetallurgical recovery.In the current scenario, the capacity of the flotation plant is insufficient to meet the demand of the DBM kilns, forcing the operation to work with high purity ores in order to attain the highest possible mass recovery in the concentration process. This is not an ideal situation as it requires the mining site to work with higher stripping ratios.The objective of this work was to improve the magnesite flotation unity to increase its productivity. After a detailed analysis, the milling was identified as the limiting process, which made the authors to focus on this operation."

Jan 1, 2016

By P. MacPhail, G. S. Dobby, I. M. Flint

"The objective of the laboratory work described in this paper has been to develop a method f or producing small gas bubbles at moderate to high gas rates in a flotation column. Small bubbles are particularly important for attaining reasonable flotation rates of fine particles. An ultrasonic aerosol generator has been employed to add frother solution directly to the gas stream. Using porous glass and filter cloth spargers, aerosol frother addition has produced bubbles at 1/2 to 2/3 the diameter of those produced by conventional frother addition to the liquid, at a lower frother consumption.IntroductionGas bubbles are generated in a flotation column most commonly by forcing gas through a porous medium called a sparger. Typical sparger material includes rubber (pierced with small holes) , fabric (such as filter cloth), fritted glass, or porous metal (steel or bronze) . Solid sparger material is suitable for laboratory use; however, for industrial applications a flexible sparger such as rubber or fabric is necessary to prevent the eventual plugging of orfices with solid particles and/ or precipitates. An exception to this is the use of a gas liquid contactor external to the column in combination with pressure release of gas in water, a method that has been demonstrated to produce very small gas bubbles. The typical objective of bubble generation for flotation column purposes is to produce bubbles with diameter of about 0.1 cm (and less) at a gas superficial velocity of 1 cm/s to 3 cm/s. In general, the smaller the bubble, the better. In man y cases, though, there is little , or nothing, gained by generating bubbles less than about 0.05 ern in diameter.Several factors affect bubble size when generated by a sparger: gas rate, orifice diameter, sparger surface area, surfactant type, surfactant dosage, and static head. At very low gas rates bubble diameter is independent of flow rate and is proportional to orifice diameter. At the moderate gas rates encountered in flotation columns bubble diameter, db&apos; is related to gas flow by: db oc vg n, where vg is superficial gas velocity (rate of gas flow per unit column area). For porous steel and filter cloth, n has a value of about 0.25 for vg between 0.2 cm/s and 2 cm/s(2). The magnitude of the effect of orifice diameter at these gas rates is unclear. The effects of frother type and concentration on bubble size issuing from a single orifice have been measur ed by Miagkovaru , shown here in Figure I(IS). The reduction in bubble diameter upon surfactant addition is due to the lowering of interfacial tension created by adsorption of surfactant at the gas liquid interface."

Jan 1, 1988

By James F. Archibald

Testing has been accomplished to substantiate recent laboratory trials which have demonstrated that thin liner membranes, applied to rock core samples, can significantly enhance the structural performance of such rock materials. A range of Canadian polymer liner materials (MineguardTM, RockguardTM and RockWebTM) have been tested side-by-side to evaluate strength and other physical property improvements generated for two highly homogeneous, though differently sourced, granodioritic rock materials. Tests were conducted on physically similar core materials, utilizing 104 to 113 samples of each respective rock type. For both rock sample populations, cores were coated using linings at thicknesses varying between 1 and 7.3 mm, typical of the application range currently used underground by mines contemplating use of such membrane agents. Results of rock failure tests, following application of passive lining covers upon the very large sample populations of each rock type, have indicated that noticeable strength improvement and enhancement of post-yield failure characteristics can be developed by the entire range of spray-on liner materials evaluated. It is shown that all of the tested liner agent materials currently available can and do act to positively reinforce rock support capabilities of modeled core pillars. Where liner materials can be effectively placed underground, it is anticipated that they may provide similar benefit and be successfully used in partial replacement for either screen or shotcrete to provide advantageous area support for rock.

May 1, 2001

By D. G. Cerigo

"INTRODUCTIONAn interim report covering an uncompleted project on revenue mill optimization was presented at the invitation of Mr. C.S. Stevens, the Secretary of the Canadian Gold Metallurgists. The work described summarizes the preliminary work carried out at the Noranda Research Centre on computer mill optimization and is an attempt to arrive at a model of a circuit using the ""black box"" approach and hence by using economic factors related to concentrate dollar value to maximize revenue. The help and cooperation of Mr. J.D. Wild, Mr. M.J.S. Bennett of Noranda and Dr. A. Bobkowicz of McGill University is gratefully acknowledged.DERIVATION OF MODELHistorical data from the Normetal mill were used for the study. Normetal ore contains chalcopyrite, sphalerite, gold, silver, pyrite and pyrrhotite. For simplicity, data were chosen for days when only two concentrates had been derived, a copper concentrate which also contains the gold and silver, and a zinc concentrate. In these periods when pyrite concentrate was not produced, its circuit was used as an extra zinc scavenger unit. Figure I is a schematic drawing of the circuit and Table I explains the nomenclature.The mill had been operated to obtain a fixed grade of copper and zinc in the copper and zinc concentrates respectively, at the same time insuring acceptable recovery levels. The target grade for the copper and zinc concentrates had been derived by manual calculations based on past experience. The data used were 170 sets of daily mill reports, a sample of which is shown in Table II. The data consist of daily tonnages of feed, concentrates and tailings and their average compositions obtained by taking samples every twenty minutes from each stream and analyzing the daily composite samples."

Jan 1, 1967

By A. M. Girodo

"Dorbyl Heavy Engineering has been manufacturing winders since 1949 mostly for the South African mining industry.Table 1 shows that the vast majority of winders have been double drum winders. At the greater depths with larger ropes being employed, it became apparent that multi-rope winders would be needed. The high stress variation in Koepe winder ropes at great depths especially beyond 2000 m, ruled out this possibility. Thus the original concept was borne for the Blair multi-rope winder where the stress level variations in the rope would be as per the well known, tried and tested double drum winder. The Blair multi-rope was also devised to increase payload by using multiple ropes.With the increasing costs of transporting men and material coupled with fact that orebodies are getting deeper, various feasibility studies have been carried out by South African mining houses. For this reason Dorbyl Heavy Engineering has done conceptual design work of both double drum and Blair multi-rope winders with diameters up to 8.5 m dia (still well within our manufacturing capabilities). These feasibility studies have looked at depths approaching 4000 m*.This paper covers the typical duties leading to the choice of single drum, double drum, Koepe and Blair multi-rope hoists on South African gold mines. A brief synopsis of Dorbyl hoists in use in the South African mining industry, with some indications of future trends, will be discussed.With current installed depths of wind approaching 2500 m, the Blair multi-rope hoist has been used extensively for the heavier payloads.Some of the main considerations pertinent to the design of the Blair multi-rope hoist are illustrated together with the implications of using this type of hoist to winding depths of3000 m to 4000 m in the foreseeable future."

Jan 1, 1995

By M. Honarmand, Z. Moezifar, H. Ranjbar

Abstract - The Sar Cheshmeh area covers an area of 640 km2, and is located in the southern part of the Iranian Volcanic-Sedimentary Belt. ETM+ images have been used for alteration mapping. The Crosta method was found useful for enhancing exposed areas containing hydroxyl and iron oxide minerals. However, field checking has shown that this method is not able to identify all the known areas of hydrothermal alteration. Many of these altered areas are also not clearly resolved in the geophysical data. In order to improve resolution of such areas, integration of remote sensing and geophysical data may be helpful. The Darrehzar Cu deposit was chosen as a control area. The data have been divided into two sets: explanatory and target variables. The explanatory data are Landsat hydroxyl and iron oxide images and airborne geophysical data (K, U, and Th total counts, and total magnetics). The target variables are rock geochemistry and ground geophysics. Data analysis and integration of geophysical and remote sensing data were performed using directed principal components. This technique is found to be useful for the delineation of hydrothermally altered areas with more confidence.

Jan 1, 2002

Material scheduling, sequencing planning and execution are the core tactical mine plan for achieving production targets that maximize the objective function of any mine production entity. This objective function is constrained by several exogenous and endogenous constraints including geological, operating, technological, marketing, financial, political, social and local field constraints. Linear and dynamic programming techniques have been used to formulate algorithms to solve the problems associated with scheduling and sequencing operations. These algorithms possess the mathematical rigor for dealing with the fundamental problems but they fail to provide adequate answers to random and dynamic process problems. Materials scheduling and sequencing are carried out within the bounds of random and dynamic fields. The functional relations between the output and dependent variables are random, and thus, current algorithms are limited in their abilities to address the problems arising from these random field processes. In this study a production simulator is developed to capture the random field process associated with materials scheduling and sequencing in an open pit environment. The algorithm incorporates a geometric pit evolution model, using solid geometry of an ellipsoidal frustum to capture material displacement dynamics. Taylor series expansion about the dimensions of the initial frustum is used to provide numerical solutions to the resulting partial differential equations governing the pushback dynamics. A production simulator, derived from the stochastic and dynamic models, is developed, validated and used to simulate the changes in the pit volume resulting from periodic incremental pushbacks and the random field process. The hybrid stochastic-optimization algorithm provides a powerful tool for addressing the random field and dynamic process problems. Combined with a hybrid stochastic-optimization dispatch system, tactical production planning and execution will be efficient and economic for achieving desired.

May 1, 2004

By B. R. Neufeld, M. G. Heximer, S. J. Roach, W. G. Van Luven, D. G. Reynolds

"Teck Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. In the zinc plant, zinc concentrates are roasted to produce calcine, which is then processed in the leaching circuit for zinc recovery. Calcine is first dissolved at pH <2.0. This is followed by a precipitation stage using additional calcine that removes iron as a ferric hydroxide precipitate which is recycled to the lead operations. It is during this pH adjustment that impurities, notably arsenic, antimony and germanium, are co-precipitated with ferric hydroxide which is the primary removal phase for these elements. Recent processing conditions have resulted in lower iron inputs to the leaching circuit and this has resulted in insufficient co-precipitation of key impurities. This paper summarizes the influence of iron concentrations on impurity removal using laboratory and plant scale surveys, and emphasizes key specification limits for the primary iron removal circuit.INTRODUCTIONThe Sulphide Leach Plant (SLP) at Teck Metals Ltd., Trail Operations produces a zinc sulphate electrolyte from three different zinc bearing streams:1. Calcine, primarily containing zinc oxide, from the roasters2. Zinc electrolyte from the Oxide Leach Plant (OLP) is produced by leaching zinc oxide fume from the pyrometallurgical lead smelting operations3. Zinc slurry from the Zinc Pressure Leach (ZPL) autoclaveThe feed sources are blended and introduced to the iron removal process to precipitate iron in the form of a hydrolyzed iron precipitate which is recycled to the lead smelting operation. Along with iron, impurities, namely arsenic, antimony, germanium and silica, also co-precipitate; this process acts as the primary removal step for these elements. Following iron removal, the electrolyte is further processed in the zinc dust purification circuits. Cadmium and copper are removed in the cold stage circuit via zinc dust cementation, followed by cobalt cementation in the hot stage circuit."

Jan 1, 2016

By Murray W. Grabinsky

This paper considers thickening mine tailings to dense non-segregating slurry or paste for surface disposal. The driving motivation for this initiative is the elimination of ponds, reduction in containment dams and significant decrease in water being sent to the tailings basin. This inherently reduces risks of environmental and structural failure. Some of the engineering challenges in creating a stable stack of thickened or paste tailings are identified, and possible field and laboratory testing techniques in support of design are discussed. Finally, the integration of monitoring activities into the ongoing management of the surface disposal site is considered.

Nov 1, 2002

By Hossein Aminian, Daniel Hodouin, Claude Bazin, Claude Jacob

"Solvent extraction followed by electrowinning (SXEW) is an economical option for the processing of low grade and oxidized copper ore. Phenomenological models were developed to simulate the copper solvent extraction and the electrowinning processes. The two models were linked together to make a SX/EW simulator. The simulator is used to predict the operation of the mines Gaspe pilot plant put in operation in 1996. Results confirm the potential of the simulation that would subsequently be used for student training, process optimization and to assess the performances of control strategies.INTRODUCTIONSolvent extraction followed by electrowinning (SXEW) has become in the last two decades a key process for the recovery of copper from solution obtained by leaching low grade copper ore. Several operations have been commissioned in North and South Americas in the last decade (Arbiter, 1994). In Canada, Gibraltar Mine (Scott, 1991) operates a SX plant followed by electrowinning (EW) to produce copper cathode from leached low-grade ore dumps. From 1996 to 1997 Mines Gaspe operated a pilot plant to test the economical feasibility of leaching an oxidized copper ore, followed by solvent extraction and electrowinning of copper. Despite copper SX/EW processes have the reputation of being low cost operations, plant engineers should always look at way to make the plant more efficient. Process models provide an economic platform to learn, control and ultimately optimize the operation of a plant.Several models have been independently proposed to simulate the SX process (Cadman and Hsu, 1970; Medina Gomez, 1980; Wilkinson and Ingham, 1983; Garcia et al., 1988; Aminian et al., 1997) and the EW process (Bryson, 1981; Barton and Scott, 1992; Barton and Scott, 1993). However few papers, if any, deal with the integration of the two process models into a single simulator of a SX-EW plant. This paper describes the development of an integrated simulator for the SX-EW process and shows some steady-state simulation runs of an actual SX-EW pilot plant. The paper consists of four sections. The first section shows the general layout and principles of operation of a SX-EW plant.The second section describes the SX model while the third section deals with the process model used for the copper electrowinning process. The last section shows how the two process models are linked to simulate the operation of the Gaspe pilot plant."

Jan 1, 1999

By S. Sakurai

"Gravitational force is an external body force acting on underground structures. It should be noted that gravitational force cannot be replaced with the surface traction vector (Cauchy stress) which is an internal force. This fact should be properly taken into account in a numerical analysis of underground structures, particularly for structures such as vertical shafts, tunnels, and caverns constructed at great depths. It is obvious that the gravitational force must be conserved at all times.In conventional numerical analyses, the initial state of stress of the ground medium is firstly calculated under the gravitational field. This means that the gravitational force is replaced with stress (surface traction vector), and after that only the initial stress is considered in the calculation of the stresses and displacements of the structure. It should be noted that the initial stress is Cauchy stress consisting of a surface traction vector, while the gravitational force is a body force acting on the mass of the materials. This computational approach may be acceptable for elastic problems because the principle of superposition is valid for elastic materials. However, this approach becomes questionable for elasto-plastic materials because there is no guarantee that the principle of superposition is valid for them.Furthermore, another problem exists in elasto-plastic analyses: The stress state in a plastic zone must satisfy a yielding criterion such as that of Mohr-Coulomb. In order to make the stress state satisfy the criterion, an excess stress beyond the yielding criterion should be transferred to an elastic zone existing outside of the plastic zone. This seems to always be possible, because an elastic zone always exists, no matter how large of a plastic zone appears. In some cases, however, the excess stress cannot be transferred to the elastic zone because the gravitational force must be conserved. Therefore, it is obvious that the magnitude of stress around underground structures may become large and surpass the yielding criterion at great depths where a large gravitational force exists.In this paper, it is demonstrated that in a conventional elasto-plastic numerical analysis of a vertical shaft at a great depth, all the stress components around the shaft become very small, even though a large gravitational force exists. This strange result may be due to the fact that the gravitational force is not properly taken into consideration in the numerical analysis."

Jan 1, 2015

By Bertrand Wolfman, William E. Stanley

"This paper reviews the traditional mine accounting systems, including ""custodial accounting"" and unit costing, and then suggests that the use of flexible budgets represents a more suitable method of reporting costs in order to assist the mine manager in improving productivity. Examples of various applications are given to show that the result is a clear reporting structure.Custodial Accounting is Emphasized in Traditional SystemsTraditional mine accounting has been mainly concerned with the accuracy of financial reporting to ""head office"" for the use of the directors and the company&apos;s bankers and shareholders. This is often called custodial accounting and it represented the main purpose of accounting when first developed in Europe hundreds of years ago. This important development permitted the establishment of enterprises which were separated from their owners because they could rely on accurate financial reports of management&apos;s stewardship.As custodial accounting is fairly broad and historical in nature, it is often not very useful to the mine manager for ongoing monitoring of performance of mining, milling, maintenance, and other support and staff groups. In spite of the considerable investment in accounting staff and computer support, many accounting systems have not been upgraded so that they accurately reflect workplace performance on a weekly or monthly basis.Budgets are Often FixedMany mines today also still emphasize fixed budgets. Thus, the mine plan which is set in the fall of one year is converted to a monthly tonnage and detailed dollar budget for periods of up to sixteen months in the future. The only certainty in this plan is that actual events will differ; timing, mix of mining methods and production volumes will differ on a monthly basis.Unfortunately, the fixed budget has no capability to reflect these operational changes. It is frozen for the full year. The result is that actual results will inevitably be compared to an outdated target."

Jan 1, 1982

By A. Wright, P. Lacombe, R. del Villar, D. Hodouin, C. Sepulveda

"The data acquisition from industrial plants is a fundamental step for process modelling in process optimization, process analysis and automatic control.The introduction, some years ago, of modern distributed control and data acquisition systems in concentrators imposes a new approach in designing experimental schemes for data acquisition campaigns and new criteria for the treatment of the obtained discrete information.This paper presents the methodology applied to sample a zinc flotation circuit at Les Mines Selbaie, Joutel, PQ. Values of 85 process variables were obtained form the Distributed Control and Data Acquisition System (Bailey Network 90) and transferred to the DOS environment. Another 11 variables (flowrates and valve positions) were directly sampled using an IBM-PC compatible computer equipped with a data acquisition card and a signal processing circuit.All variables, under the vector form, were processed in the PC-MATLAB environment to either filter or eliminate the non-linear disturbances and noises, producing useful data for model development. The filtering algorithms are also presented.INTRODUCTIONProcess control does not need to be justified. Whether manual or automatic, any processing plant requires some form of control to accomplish its main objectives: a good quality product and a target throughput. Process control of mineral processing plants has steadily evolved from manual control, where the operator skills and/or experience play an important role, to some level of automatic control, usually considered better, as less human subjectivity is involved, at least when actions have to be taken.The design of these control systems requires the knowledge of the dynamics of the process it is deemed to control. Process modelling is therefore an essential step in the assessment and the design of a control strategy. The choice of model will depend on the available resources and manpower."

Jan 1, 1991

By John A. Allan

The subject chosen for this paper is not a new one, but the subject matter is so extensive that something new can always be said .about it. We are just beginning to realize how little is actually known about the character of Alberta coal, except for a few general facts. The object of this paper is not to explain that our previous information, in whole or in part, on the coal resources of Alberta, has been incorrect, but rather to present some new facts obtained as a result of recent study in the field and in the laboratory. As field investigation continues the problem of determining the character of a coal seam for any great distance laterally becomes more and more complex. Our present knowledge of Alberta coal deposits should not be discussed before due reference is made to those great pioneers who blazed the trails for later geologists, by recording their observations on the general geology of Alberta. Geologists, to-day, particularly those of us who are striving, year after year, to unravel the mysteries of stratigraphy, palaeontology, and structure, in so far as these are related to the coal resources of Alberta, fully realize our indebtedness to those three trail-makers, Dawson, McConnell, and Tyrrell. Had these geologists not recorded their observations correctly, nor interpreted the broad geological facts contained in Nature&apos;s book, with still uncut pages, how much slower would have been the progress of our coal knowledge in the succeeding years. It is true that many of the interpretations given to observations by these pioneers have had to be changed as a result of closer studies, but we must also expect that the geological interpretation from present day observations will be changed by future workers, as Nature&apos;s book is read and re-read.

Jan 1, 1925

By Simon B. Blancher, Malo Rousseau, Renato Contessotto, Thomas Wallmach

The Manganese division of the ERAMET group extracts manganese ore in Gabon and produces manganese alloys for the steel industry. ERAMET has an economic interest to maximize the ore throughput without reducing the lifetime of its manganese mines. This can be achieved by means of research and development leading to innovative ore beneficiation processes. For this purpose, the ERAMET research center has designed and constructed a new pilot plant for ore beneficiation by physical separation processes. This pilot facility was erected within an infrastructural and synergetic framework, including competencies in hydrometallurgy, pyrometallurgy, numerical modelling, analyses and mineral characterization that provide ideal research conditions. After laboratory scale tests, a pilot operation of beneficiation of low grade Mn ore (around 35% Mn) was carried out by jigging of the 1-10 mm fraction. This gravity separation process exploits density differences between the various Mn-bearing minerals such as pyrolusite and lithiophorite as well as gangue minerals such as silicates and iron-hydroxides. Enrichment leads to the production of a marketable product associated with a high mass recovery (53% for the jigging step). However, 20% of pyrolusite and 30% of lithiophorite are lost in the waste. Mineral characterization has shown microtextural complexities, but grinding the ore to approach the liberation mesh was not an option due to commercially defined constraints given by the ferro-alloy industry. Recovery of the Mn-bearing minerals or adjustments of the feed grain size (6.3-10 mm) are two potential areas of process improvements identified by means of Qemscan® mineral characterization. This paper details the process tested on a pilot scale (0.5 t/h), which has led to a significant increase in the beneficiation of a low grade Mn ore.

Jan 1, 2016

By G. C. McKerrow

"Mr. G.C. McKerrow, Assistant Manager of Noranda Mines and formerly Smelter Superintendent attended the meeting to answer questions as to why smelters imposed penalties for too much zinc in a copper concentrate or too much copper in a zinc concentrate, etc.D.W. Bridges -Mattagami Lake MinesWhat limits do you set on zinc and lead in a copper concentrate?G.C. McKerrow - At Noranda, we allow 5% zinc free and charge 25 cents for every unit above that. For lead, it is 1% free and 25 cents per unit above that. Lead is a much more harmful impurity than zinc because it tends to recycle more in the smelter circuit and creates a greater health hazard in the plant.E. Thornton - Sullivan GroupWHat harm does fluorine do in the smelting process?G.C. McKerrow - Fluorine usually does not occur in harmful concentrations in non-ferrous smelters. Fluorides are present in exhaust gases in the aluminum and phosphate industries. If these fumes escape into the atmosphere, they may settle out on forage grasses in concentrations that are harmful to livestock.Thorton - Sullivan GroupI have asked this question other places and have been told that it is hard on brick linings and causes gold and silver to be lost up the stack.G.C. McKerrow - Almost any volatile constituent in a smelter charge will aid in carrying other metal values. To this extent it may be harmful.E. Thornton - Sullivan GroupMr. Tait mentioned before a smelter where they have a copper-tin ore and they pay for copper, tin, bismuth and silver but object strongly to indium in the concentrate. Why would this be?G.G. McKerrow - 1 can't see why indium would be a serious impurity. It does tend to concentrate in flu dusts and if you get enough of it you can recover it and sell it but I have never heard of anyone putting a penalty on it.Question - I once ran into a small copper mine in Peru that had cadmium in the copper concentrate but no zinc. The copper smelter charged a penalty for the cadmium. Why would this be?"

Jan 1, 1971

By John Monhemius

Looking back over the past half century, it can be seen that the growth in the importance of hydrometallurgy for the production of non-ferrous and precious metals almost exactly parallels the rise of the environmental movement and its principal NGOs, such as Greenpeace and Friends of the Earth. The paper will review important landmarks in the development of the science and technology of hydrometallurgy and show how many of these have been influenced by pressures on the industry brought about by environmentalists. Successful innovations as well as commercial failures will be considered and reasons for the success or failure will be analysed and lessons drawn to guide future developments.

Jan 1, 2014

By Barbara H. Scott Smith

"During the last two decades lamproites have joined kimberlites as the only two known primary sources of economic quantities of diamonds. This paper contrasts the petrography, primary and xenocrystic mineralogy and pipe geology of these petrogenetically separate rock types. The petrographic discrimination of kimberlites and lamproites from each other, as well as other rock types found during diamond prospecting, is discussed. Kimberlites and lamproites can be classified texturally and mineralogically. Such classifications highlight the differences between, and among, lamproites and kimberlites. The implications of these differences for diamond exploration programs are discussed, with particular emphasis on the application of petrography. IntroductionKimberlite was the term coined in the late 19th century to describe the host rock of diamond at the type locality, Kimberley, South Africa (Lewis, 1887, 1888). Innumerable kimberlites are now known worldwide; some of them contain economic quantities of diamond (e.g. South Africa, Botswana and Russia) while many are barren. Jennings (1989) suggests that less than 3% of the known kimberlites can be considered to be commercial. Kimberlite was thought to be the only important primary source of diamond for approximately a century. Until the late 1970s, lamproites were thought to be only academic curiosities. Some workers (e.g. Wade and Prider, 1940), however, did comment on certain similarities between lamproites and kimberlites and, hence, inferred a potential for lamproites to carry diamonds.The term lamproite was introduced by Niggli (1923) for leucite-bearing rocks from southeast Spain and Wyoming which had some unusual geochemical characteristics. Wade and Prider (1940) used the term lamproite (as defined by Troger, 1935) to embrace rock types found in the West Kimberley area of Western Australia. All the lamproites described by Wade and Prider (1940) form distinct topographic features. Subsequently in the late 1970s, additional pipes, which have little or no relief, were discovered in the same area, but only as the result of a major diamond exploration program (Atkinson et al., 1984; Jaques et al., 1984, 1986). Some of these bodies are diamondiferous. In 1979, the Argyle pipe was discovered in the East Kimberley area which, in terms of grade, is the richest known primary diamond deposit in the world with some parts of the body having grades greater than 500 carats/100 tonnes (Madigan, 1983; Boxer et al., 1989). All the initial new discoveries in Western Australia resulted from classic stream sampling for ""kimberlite indicator minerals"" (Atkinson, 1989)."

Jan 1, 1992

By J. Zollinger, J. R. Kennedy, E. Bouzy, B. Rouat, D. Daloz

"Ni-based superalloys have been replaced in the last low pressure stage of jet turbines for aircraft by titanium aluminides. In order to improve the properties of these Ti-Al alloys and extend their usage deeper into aircraft engines grain refinement by inoculation has been investigated. Borides are the most common inoculants for Ti-Al alloys, however they form brittle particles which are detrimental to the final properties of the alloy. Inoculants manufactured from a Ti-Al alloy with refractory metal additions were proposed to alleviate the issues arising from inoculation with brittle particles. An alloy was chosen which had less than 10% lattice mismatch with the alloy of interest (Ti-46Al) to maximize efficiency. Initial experimentation showed a decrease in as-cast grain size by a factor of 2 between the inoculated and non-inoculated samples along with an absence of the brittle particles found with boron inoculations. Investigations into the interaction between the inoculants and the melt were also carried out to better understand the inoculant size distribution and efficiency upon solidification.INTRODUCTIONTitanium aluminum alloys are an interesting material for aerospace applications. Their high temperature oxidation resistance and high specific strength make them particularly promising (Kim & Dimiduk, 1991). Recently, titanium aluminides have replaced nickel based superalloys in the last low pressure stage of the GEnx turbine engine. In order to increase their usefulness in turbines their properties must be improved for high temperature (>800oC) applications. Grain refinement is one method to improve the properties of a material, however current methods of grain refinement of Ti-Al alloys by inoculation have significant drawbacks. A new method of inoculating Ti-Al alloys by using Ti-Al alloys with small refractory metal additions (Nb, Ta) has been developed to avoid the drawbacks of current methods while still being effective grain refiners."

Jan 1, 2016