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By Rakesh Kumar, Rajabrahma K., A. K. Verma, V. Mukesh

"In this study, laboratory investigation as well as numerical investigation is carried out to ascertain the transition from one mode to another for Semi-circular bend setup. Laboratory investigation is carried by varying the span length (s/2R); crack length (a/R); notch angle (a); and notch thickness (t). The specimen consists of cement, sand and water mixture in a ratio of 1:1:0.5 by weight and are prepared as per the ISRM standards (2014). Tests are conducted by a servo controlled universal testing machine at a strain rate of 0.2 mm/ min. The results are collected in terms of failure load, crack mouth opening displacement (CMOD) and images of crack initiation and propagation.Image analysis of laboratory tested samples shows that crack initiates at the notch tip when the notch inclination angle is 0°. As the notch angle increases (i.e. 30° and 60°) the fracture begins to initiate behind the notch tip. The direction of crack propagation in front and back side of the sample is same for notch inclination angle is 0° whereas it differs more and more as crack inclination increases. The transition represents the change in mode of failure from mode I (0°), mode II (30°) and mixed mode I/II fracture (60°).Finite element method used to find the transition based on MTS failure criterion. The inclination of notch is varied like 40, 42, 44, 45, and 50 deg and FEM analysis shows that the transition from mode-I to Mode-II take place at 49 deg. The same procedure can be extended to find the transition from mode-II to mode-III."

Jan 1, 2015

By Colin E. Dunn

Plants have a remarkable ability to select, use and store metals derived from the substrate. Each species is unique in its requirements for and tolerances to the full spectrum of chemical elements in the Periodic Table. Studies to define the chemical characteristics of common trees and shrubs of the temperate forest are providing insight to their use for exploration, i.e., biogeochemical exploration. Examples of surveys over gold deposits in British Columbia show the effectiveness of sampling various tissues from different species in a range of biogeoclimatic environments. At the Nickel Plate mine in the Montane-Spruce zone, outer bark of Lodgepole pine was effective in defining a large area of metal enrichment; at the Carolin mine in the zone of Coastal Mountain Hemlock, analysis of twigs of western hemlock and Pacific silver fir provided an exploration target considerably larger than that defined by lithogeochemistry; at the Mount Washington gold deposit in the Mountain Hemlock zone, twigs of mountain hemlock and rhododendron were used to outline the mineralization; and in the Interior Douglas-fir zone at the QR deposit analysis of Douglas-fir tops collected by helicopter provided a rapid and effective method of identifying a gold-rich area.

Jan 1, 1995

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

By M. Dupuis

In the present study, the heat balance of the Hirakud smelter aluminium reduction cell has been accurately assessed using only a surface thermocouple and a pyrometer, As it is well known that using a single linear or quadratic relationship to estimate the heat flux from the measured surface temperature does not provide the accuracy required to close the cell heat balance, this approach was not used in this study, Instead, the fundamental natural convection and radiation heat flux equations were used systematically for each measurement point, Practically, this means that the ambient air temperature and at least one ambient radiative temperature must also be known in addition to the surface temperature for each measurement point. Sometimes, the radiative heat flux could not be accurately estimated using a single ambient radiative temperature, In those cases, a more accurate estimation based on two ambient radiative temperatures and corresponding view factors has been used instead, It turns out that although at least three temperature measurements are required to estimate a single heat flux, it takes a lot less time to make those temperature measurements using a pyrometer than directly measuring the heat flux using an expensive heat flux meter, Furthermore, no loss in accuracy was detected when using this approach as the cell heat balance could be closed within 5%, the level of accuracy typical of cell heat balance assessment using heat flux meter.

Jan 1, 2004

By P Hulteberg

In this article, an integrated catalytic reactor design approach to produce PEMFC-quality hydrogen is evaluated. The design is based on a high level of heat exchanging perfonned internally, highly active noble metal catalysts and a woven wire mesh catalyst support system. It consists of an integrated steam refonner and a catalytic burner section, a water gas shift section and a preferential carbon monoxide oxidation section. The reactor design is described and experiments perfonned to evaluate the two reactors built are reported. The two reactors have a maximum output of 3 Nm and 10 Nm3 hydrogen/h respectively. In the larger unit, a total of six fuels, three gaseous (methane, natural gas and liquid propane gas) and three liquid (naphtha, ethanol and methanol), were evaluated. The larger unit was also used to investigate how variations of parameters such as steam-to-carbon ratio in the steam reforming part of the system and the relation between oxygen and carbon monoxide in the preferential carbon monoxide oxidation affect the reactor perfonnance. The smaller unit was used, after implementing automatic control, to run a system life time test for 480 h. The refonner system perfonned according to specifications on almost every aspect.

Jan 1, 2005

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present study the effect of using different grinding media, viz, ceramic balls, forged steel balls, 15% Cr steel balls, stainless steel and mixture of stainless steel and 15% Cr steel balls (50:50) on the flotation performance of a Platinum Group Mineral (PGM) UG2 ore was investigated. Test work was conducted using a laboratory scale horizontal tumbling mill and a batch flotation cell. Power draw to achieve a specific P80 was determined for each media type. Changes in flotation behaviour were evaluated in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. pH, Eh and DO levels were also measured. Grinding products of five different media produced similar solids and water recovery, which is indicative of the froth characteristics, but the grades and recoveries of PGE and chromite were different. The product obtained when using ceramic media showed the best flotation performance, producing the highest PGE recovery and the lowest Cr2O3 recovery. The products obtained when using stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery. The paper proposes possible reasons to explain these observations which may have significant importance for the operation of a PGM concentrator.

Jan 1, 2015

By S. M. Bulataovic, D. M. Wyslouzil

"The Martison Lake phosphate-niobium deposit is composed of unconsolidated residuum containing clay and silt-size particles of phosphate, niobium, iron and clay minerals. This paper deals with the laboratory and pilot plant development of the flowsheet and the reagent scheme to treat the Martison Lake ore. The ore, in addition to the complex gangue composition, contained several phosphate minerals including fluorapatite, francolite and florencite. The detailed laboratory and pilot plant evaluation resulted in the development of an effective flowsheet and reagent scheme for the selective flotation of phosphate minerals using a fatty acid circuit, followed by niobium flotation using amine collectors at acid pH. The developed flowsheet included des liming of ore, magnetic separation, and selective P 2 O 5 -Nb 2Os flotation. The main aspects discussed include characterization of the ore, step by step development of flowsheet and evaluation of dfferent modifiers and collectors for P20s and Nb20s flotation.INTRODUCTIONMartison Lake phosphate-niobium ore deposit, located 75 km north of Hearst, Ontario was discovered in the early 70's and has been the subject of extensive technical-economic evaluation in the late 70's and early 80's.The deposit is covered completely by 30 m to 90 m of glacial overburden and is composed entirely of unconso1idated material called residuum, that lies on top of a precambrian age carbonatite intrusive from which the residuum was derived by weathering and natural leaching in situ. The residuum is and irregularly-shaped horizontal lens, 2 km by 3 km in area, and up to 100 m thick, composed mostly of unconsolidated clay and silt-size particles of phosphate, niobium, iron, mica and clay minerals."

Jan 1, 1986

By E. Yan, M. Mankosa, E. Wasmund

"Rougher flotation in sulfide ore applications is typically performed using conventional flotation machines. The trend over the last 100 years has been for these cells to become larger in volume with cells reaching sizes of 600 m3 and in some cases even larger. The associated foundation loadings, transport and installation requirements along with building size have also increased. In an economic environment where projects must be executed with dwindling capital supply, bigger is not always better. More recently, industry is being challenged to identify new technology that allows for improved flowsheets and financial returns through efficiency gains. To meet this challenge, a novel high-intensity two-stage flotation system known as the StackCell™ was tested to potentially achieve installation volume and required retention time gains when compared to conventional flotation circuits. The results from on-site pilot scale work conducted on typical copper concentrator rougher flotation feed showed retention time gains on the order of 6 to 9 times when compared with conventional flotation equipment. This finding has the potential of reducing capital demands for rougher flotation circuit designs when incorporating the StackCell. The results from test work will be discussed in this paper showing comparative test data generated with a Denver bench batch test, pilot StackCell and large conventional cells, all receiving the same feed.INTRODUCTION Over the last few years, a number of flotation devices have been described as two-stage or multi-stage flotation units. The idea behind multi-stage flotation devices is that flotation performance can be improved by utilizing cells with multiple specialized units in series, but not all units of the same type, as is practiced in trains of multiple tank cells or columns. Instead, each unit is specially designed to provide the optimized fluid environment for each stage of the sequential flotation process. This idea has been proposed based on a study of the fundamentals of the flotation process, and the realization that the process consists of discrete sequential processes, that are each optimized with dissimilar process conditions (Finch et al, 1995), (Zhou, 1996). Instead of executing each step simultaneously in a homogeneous fluid environment, where the conditions would be a compromise between particle collection and froth recovery, the multi-stage flotation unit operates in a set of segregated process environments, each with a set of conditions optimized for that step."

Jan 1, 2018

By J. H. Crocket, J. Andy Fyon

"All gold deposits within the Tisdale Group are spatially associated with carbonate alteration zones; however, not all carbonate alteration zones are host to gold mineralization.Within the komatiitic and magnesium tholeiitic volcanic rocks at the base of the Tisdale Group, discordant and stratabound carbonate alteration zones occur throughout. The alteration zones consist of a ferroan dolomite - quartz inner assemblage which is enveloped by calcite-quartz and an outer chlorite-rich subzone. Factors which control the distribution of carbonate alteration include joint systems, flow contacts, synvolcanic faults and bulk composition of the host rock.Two environments of carbonate alteration can be recognized: 1) The subsea-floor alteration zones developed within the volcanic rock succession where hydrothermal fluids did not discharge directly onto the sea floor. Insignificant gold production has come from this alteration environment. 2) Seafloor zones, which represent points of hydrothermal fluid discharge into the hydrosphere, are spatially associated with felsic volcanic rock complexes and are host to syngenetic, auriferous cherty dolomite.Carbonatized, magnesium tholeiitic basalts, which are host to the auriferous, cherty dolomite, are enriched in antimony (>0.35 ppm), boron (>30 ppm), gold (>5 ppb) and lithium (> 35 ppm), but are depleted in copper ( < 70 ppm), with respect to carbonatized basalts not associated with gold. Orerelated, altered komatiitic flows can be screened using gold (>5 ppb), lead(> 10 ppm), arsenic(> 70 ppm) and antimony (>1 ppm).The habit, petrographic characteristics and certain geochemical characteristics of the altered volcanic rocks suggest that the hydrothermal fluid was of sea-water origin."

Jan 1, 1982

By A. -M. Cadieux

During the geological synthesis of the Réservoir Pipmuacan area (NTS 22E) by the Ministère des Ressources naturelles (Québec), several ilmenite-apatite occurrences, some well-known and some recently discovered, have been examined. These occurrences are hosted in the Lac-Saint-Jean and Labrieville AMCG anorthositic suites. The Lac-Saint-Jean Anorthositic Suite (1160-1140 Ma), composed of multiple intrusions covering an extensive surface area, is characterized by labradorite plagioclase. The Labrieville Anorthositic Suite (1010-1008 Ma) is characterized by andesine plagioclase. It was previously known as the Labrieville Anorthosite, which was composed of a small isolated pluton located east of the Lac-Saint-Jean Anorthositic Suite. However, new geochronological data and field observations indicate that the Labrieville Anorthositic Suite in fact includes several intrusive bodies, namely the La Hache Monzonite and the Mattawa Anorthosite. A series of major structures (Saint-Fulgence, Pipmuacan, and Chute-des-Passes deformation zones) and their conjugate faults played an important role in the emplacement of the Lac-Saint-Jean Anorthositic Suite. The Saint-Fulgence deformation zone appears to have been involved in the emplacement of the Labrieville Anorthositic Suite. Oxide mineralizations are abundant in both anorthositic suites. Ilmenite, magnetite (± titaniferous), and apatite assemblages are found mostly in the labradorite-type anorthosites, while hemo-ilmenite, magnetite and apatite assemblages are associated only with the andesine-type anorthosites. Field works has revealed ilmenite-apatite mineralizations in a variety of settings, with grades reaching 48% TiO2, 16.2% P2O5, and 71.7% Fe2O3 (tot). Numerous oxide-bearing gabbronorites, often accompanied by or located near massive apatite-oxide accumulations (nelsonites), were discovered. Among these oxide-rich zones, breccia zones with anorthosite enclaves in an oxide matrix (ilmenite-magnetiteapatite) have been observed. Locally, ilmenite-apatite mineralization occurs as cumulate concentrations in ultramafic rocks. Evidence has been observed for immiscible magmas, for magmas differentiated from a mangerite or jotunite parent, and even for late magmas differentiated from the anorthosite magma itself (apatite-bearing anorthosite). Finally, the northern part of the Lac-Saint-Jean Anorthositic Suite hosts sulfide and vanadium mineralizations associated with ilmenite-apatite enriched zones, with grades reaching 1.48% Cu, 1.22% Ni, 1.6% Cr2O5, 0.25% Co, and 0.52% V2O5.

May 1, 2003

By C. H. B. Leitch, T. N. MacAuley, R. L. Linnen, A. E. Williams-Jones

"The Trout Lake stockwork molybdenum deposit is temporally and spatially related to the emplacement of a late Cretaceous granodiorite-tonalite stock in southeastern British Columbia and contains an estimated 49 million tonnes grading O.I9% MoS2- No metal zonation patterns are apparent, with the exception of peripheral tungsten skarn, and exploration was guided largely by geological interpretation. It is typical of the granodiorite, or fluorine-poor type of molybdenum deposit. Molybdenite is contained within a quartz-feldspar vein stockwork and coeval dissemination in igneous (and less commonly metasedimentary) hosts. In general, molybdenite is strongly associated with alkali feldspars, but in detail it is intimately associated with incipient muscovite replacement of albite and K-feldspar; veins that lack feldspars are also typically barren of molybdenite. These textures suggest that fe/dspathic alteration (and precipitation in veins) was an important precursor to mineralization, and the occurrence of similar textures elsewhere (e.g. Henderson) suggest that early feldspathic alteration is important to the genesis of molybdenum deposits in general. Molybdenite deposition at Trout Lake was preceded by contact metamorphism, skarn and potassic alteration, and was overprinted by muscovite-ankerite (phyllic) alteration. Only moderate temperature changes are recorded by the metamorphic and alteration mineral assemblages (350°C to 450°C}; however, with time, fluids became increasingly more acidic and enriched in C02- In light of the intimate molybdenitemuscovite intergrowths, the decrease of pH probably exerted a major control on mineralization.IntroductionGranite-hosted molybdenum deposits can be classified in terms of the composition of the related intrusion, e.g., the granodiorite and granite types of Mutschler et a!. (1981), or the calc-alkaline, alkali-calcic, and alkalic types of Westra and Keith (1981). They have also been classified on the basis of their fluorine contents (Theodore and Menzie, 1984) with the fluorine-rich and -poor varieties roughly corresponding to granite- and granodiorite-type deposits, respectively. For economic reasons, most exploration and research has concentrated on the high-grade/large tonnage granite-type of deposit, exemplified by Climax. F1uorine-poor, granodiorite-type deposits are, however, the most common type in Canada and have been mined in the past (e.g., Endako). In this paper, the authors summarize the research that has been carried out on the fluorinepoor Trout Lake deposit (Boyle and Leitch, 1983; Linnen, 1985; Linnen and Williams-Jones, 1987; 1990) and use what has been learned to develop guidelines for the future exploration of fluorinepoor, granodiorite-type molybdenum deposits."

Jan 1, 1995

By K. C. Marsden, B. Pesic

"Interest in the efficient production and recycling of rare earth elements has increased in recent years along with the prices of these elements. The molten LiCl-KCl eutectic is one ionic solvent which can be utilized for these purposes. The LiCl-KCl eutectic has also been selected as the electrolyte for focused research for advanced pyrochemical recycling processes for used nuclear fuel in several nations. Rare earth elements are fission products with notable neutron absorption characteristics, and thorough understanding of the properties and behavior of these elements is critical to their successful partition from the electrochemically-similar actinide elements. The number of research papers investigating individual rare earth elements has greatly expanded in the approximately 35 years since the last review. These research papers are presented in a variety of languages and technical formats, making data difficult to compare, and are sometimes contradictory. A review and summary of diffusion properties of rare earths in LiCl-KCl eutectic was performed, and the data translated to a common format for evaluation. INTRODUCTIONThe rare earth elements have experienced growing importance in recent decades due to their application in high technology, including optical lenses, lasers, high-temperature superconductors, improved alloys, high energy-density batteries, and powerful magnets for compact electronic devices. Their historic production methods and uses are detailed in several texts (Hampel 1971; Bautista &Jackson 1992; Gupta & Krishnamurthy 2005). A s the p rice o f these e lements has r isen in r ecent years, so has interest in their efficient production and possible recycling options. Rare earth oxides are concentrated through hydrometallurgical techniques, but the high thermochemical stability of their oxides precludes production of rare earth metals in aqueous systems. However, the wide electrochemical window and better control of pO2- in fused salt systems allows the production of these reactive metals from their halides or oxides. The high ionic conductivity and diffusivity of the molten ionic electrolyte allow high currents with limited resistive losses (Fray 1980). Electrolytic methods in fused salts are commonly adopted for the production of bulk rare earths in a variety of molten salt systems. Fluorides are sometimes proposed for oxide electrowinning processes due to ability to dissolve the rare earth oxide, reduced hygroscopic behavior, and the wider electrochemical separation between O2 and halide gas evolution (Mohan Das, Damodaran et al. 1988; Gibilaro, Pivato et al. 2011). However, in most electrolytic production processes, such as that for mischmetal, the rare earth oxides are converted to chloride prior to electrolysis in a chloride bath (Gschneidner Jr. & Eyring 1978; Sharma 1987). Of the chlorides, the LiCl-KCl eutectic is one specific medium in which metal production and production-related investigations have been conducted (Gschneidner J r. & Eyring 1978; Driscoll & Fray 1993). L iCl-KCl eutectic has the advantages o f h igh conductivity, but relatively low viscosity and operating temperature. The low operating temperature allows simpler design, with reduced energy consumption, salt volatility and cell corrosion."

Jan 1, 2012

By G. A. Bezuidenhout, J. Davis, S. Lefume, J. P. T. Kapusta, D. K. Chibwe

"Although the centennial of the Peirce-Smith (PS) converting process has recently been celebrated, the technology has essentially not changed much since its inception. PS converting is used extensively in the Cu, Ni and PGM industry to remove iron and sulphur from a molten matte phase. A typical PS converting process would use low pressure air supplied by a blower to bubble air through the molten bath. This bubbling injection regime is inherently inefficient from a process and energy consideration. In the late 70’s and early 80’s, Brimacombe and co-workers demonstrated at both laboratory and plant scales that sonic injection (jetting regime) into copper or nickel converters could reduce or eliminate the above hindrances characteristic of PS converting. Since then, in spite of these successes, very little industrial applications have made headway in the converting process of non-ferrous metal mattes on a commercial scale. As part of its operational improvement and energy reduction program (process efficiency), Lonmin Platinum decided to conduct a full scale industrial evaluation of sonic injection using air only to establish if punchless, high efficiency sonic injection was feasible in its small 3.05 × 4.57 m converters (10’ × 15’). A plant trial was run for four weeks in one of its three converters. This paper discusses the plant demonstration with a focus on the experience acquired by Lonmin together with the key learnings from the trials. Reference will also be made to the commercial aspects of a full scale implementation of sonic injection in all three converters in the smelter. INTRODUCTION AND OBJECTIVESAlthough the centennial of the Peirce-Smith (PS) converting process has recently been celebrated (Peirce and Smith, 1909; Southwick, 2009), the technology has essentially not changed much since its inception. PS converting is used extensively in the Cu, Ni and PGM industry to remove iron and sulphur from a molten matte phase. A typical PS converting process would use low pressure air supplied by a blower to bubble air through the molten bath. This bubbling injection regime is inherently inefficient from a process and energy consideration."

Jan 1, 2012

By W. K. Smith, V. P. Krueger, D. C. Mulder

"AbstractThis paper describes the geological procedures used to evaluate two mineable high-volatile C bituminous coal seams at Coal Valley , located in the outer foothills belt of the Rocky Mountain Eastern Slopes in west-central Alberta. Lexco Testing Ltd., the exploration arm of Luscos: Ltd., owns and operates an all -weather geophysical logging system which provides gamma, focused density , single-point resistance and caliper logs in a single pass. A mathematical analysis for a theoretical interpretation of the single-point resistance log confirms empirical research that bed boundaries are located at a point 10% from the bottom of the curve. A unique and efficient triple-tube, wireline rotary coring system cuts an undisturbed 0.076m- diameter core in a plastic liner at recoveries exceeding 90% . Although only 10% of the total footage is cored, it provides vital analytical and geotechnical data, and, when integrated with the geophysical logs, improves the quality and extends the usefulness of interpreting both sets of data. All data are programmed to produce computerized structure contour, isopach, isoratio and isoquality maps, and volume calculations.General IntroductionTHE COAL VALLEY AREA is located in the outer foothills belt of the Rocky Mountain Eastern Slopes, 60 miles (96 km) by road southwest of Edson, Alberta. Luscar Ltd. holds leases which total 49,000 acres (19,830 ha) , of which 18,300 acres (7,410 ha) have been assigned to the Coal Valley mine area (Fig. 1 ) . There are two Paleocene high-volatile C bituminous coal seams initially developed for mining within a total stratigraphic interval of 750 feet (230 m ) (Fig. 2 ). These seams strike generally NW, and in the undisturbed areas generally dip westerly from 10 to 30 degrees."

Jan 1, 1977

By F. F. Roberto, E. Kirby, A. R. Marchbank

The application of biologically assisted methods for metal extraction in the mining industry has a long history, but development of modern techniques has been relatively slow. There is, however, a resurgence of interest in the industry with the recent development of methods to successfully treat base metals concentrates. Two major pilot plant programs for treatment of chalcopyrite concentrates have been initiated in the past year and results from one are beginning to be released. This paper provides an overview of methods that have been applied in the past, from the earliest deliberate applications of the technology, through the copper and uranium heap and dump leach applications, the more highly engineered agitated tank leach gold applications and the developments currently taking place in the industry.

Jan 1, 2003

By Lang Tao, Jun Wang, Wei Xiao, Wenqing Qin, Pan Cao, Guanzhou Qiu, Key Lab of Biohydrometallurgy of Ministry of Education, Central South University

"The effect of metal cations on the rutile flotation using styryl phosphoric acid (SPA) as the collector was investigated by micro-flotation test, bench scale flotation test, zeta-potential measurements and adsorption measurements. The micro-flotation results indicated that Fe (?) and Al (?) ions in low concentrations had obvious activation on the rutile flotation, and Pb (?) ions in low concentrations had smaller activation of rutile, but Fe (?), Al (?), Pb (?), Ca (?) and Mg (?) have strong inhibition of rutile flotation in high concentrations. The bench scale flotation results indicated ethylene diamine tetraacetic acid (EDTA), boracic acid, and sodium hexametaphospate can decrease the metal ions concentrations, and increase the recovery of rutile flotation. Adsorption measurements and zeta-potential measurements revealed that Fe (?), Al (?) and Pb (?) ions were adsorbed on the rutile surface, and had interaction with SPA. But when these ions concentration were over the largest adsorption capacity, residual metal ions could occur chemical reaction with SPA.INTRODUCTIONRutile is one of the favored minerals for production of titanium dioxide white pigment, primarily through the chloride manufacturing process (Stanaway 1994; Hou et al., 2013) However, the majority of rutile ores belong to refractory ores, while flotation is one of the most efficient methods to separate fine rutile from gangue (Dolbear et al., 1937). With the flotation development, many effective collectors were successfully applied in the oxide ore. Many reviews have indicated that organic phosphonic acid collectors showed good selectivity on oxide ores such as ilmenite and rutile (Bulatovic & Wyslouzil 1999; Liu & Peng 1999).It is inevitable that many types of metal cations are present in ore pulp. These metal cations significantly influence the flotation of minerals. Liu et al. (2015) showed that Ca2+ and Mg2+ could improve the floatability of spodumene at pH 12.5 and 10.0, respectively. The authors proposed that Ca2+ and Mg2+ ions readily form hydroxy complexes (CaOH(l) and MgOH(l)) and precipitates as (Ca(OH)2 and Mg(OH)2) in strongly alkaline solutions. Fan and Rowson (2000) investigated the effect of Pb(NO3)2 addition as an activator on ilmenite flotation and showed that it could improve ilmenite floatability. The addition of Pb(NO3)2 resulted in an increase of ilmenite zeta potential in both weakly alkaline and acidic aqueous solutions. Mehdilo, Irannajad, and Rezai (2015) studied three kinds of ilmenite of different origins and discovered that both Mg and V had a negative correlation with ilmenite flotation, while the Mn content seemed to correlate positively with flotation efficiency. A number of studies have also showed that Fe3+ can improve the floatability of ilmenite (Fan et al., 2009; Nuri, Mehdilo, & Irannajad, 2014)."

Jan 1, 2016

By C. Campero, C. Nicolau, L. Pagliero

The Chilean Congress has recently promoted desalination as a solution to meet the mining industry’s growing water demand. However, this rapid expansion of desalination infrastructure comes with trade-offs. This includes a significant energy cost for treatment, as well as socio-environmental impacts on indigenous communities, tourism, fisheries, and the marine ecosystem. This paper advances a regional-scale model for analyzing competing trade-offs through a case study in the Antofagasta mining region of Chile. Through geospatial data analysis in ArcGIS, new desalination infrastructure investments supplying water to mines are overlain with features of concern raised by communities during the environmental impact assessment (EIA) process, such as national parks, fisheries and exploitation areas for benthonic resources. The resultant model provides a test-bed for analyzing the cumulative effects associated with desalination expansion and for investigating scenarios to mitigate negative social-environmental impacts. The model simulates alternative scenarios for desalination locations and pipeline routes according to competing constraints (i.e. to minimize cost and energy constraints while also avoiding ecological and social hotspots). The ultimate contribution of the work is a demonstration of how the proactive adoption of a regional-scale infrastructure planning might have led to different desalination investment decisions. INTRODUCTION Chile represents the largest producer of copper globally, and holds approximately a third of the world’s estimated copper reserves. However, access to water represents a major constraint to industry expansion and creates conflicts with competing water users (Aitken et al., 2016; Côte et al., 2010). Recently, the Chilean Congress has promoted desalination as a solution to meeting the industry’s growing water demand, which is likely to lead to significant growth in desalination infrastructure to support large-scale mining projects that extract freshwater over a rate of 150 l/s1. By most recent projections, the Chilean copper mining sector is set to increase seawater use by 230% by 2029 (Faversham House Group Ltd, 2019). By the year 2015, Chile had 11 projects serving the mining industry and there are at least other 12 planned plants (Cochilco, 2015). While the use of seawater allows continued expansion of the sector without depletion of scarce underground aquifers, it is nonetheless accompanied with important socio-environmental drawbacks. One such challenge with desalination is the associated energy costs, expressed, both economic and environmental (e.g., CO2 emissions). This includes the energy required for reverse osmosis treatment facilities, as well as to pump water to inland regions at high elevations around 3.100 m.a.s.l in Chile. (Dixon, 2013; Knops et al., 2013). Additionally, the impacts of desalinated water use on flotation chemistry are generally poorly understood, necessitating the need for further research into the impacts, both positive and negative (Cisternas and Gálvez, 2018; Liu et al., 2011).

Jan 1, 2019

By S. Kahraman, K. Develi, E. Yasar

Four hydraulic top hammers, one pneumatic top hammer, and three down-the-hole drills were observed in several rock types at quarries and highway construction sites to measure the performance data. At the same time, drill cuttings from each drill hole were collected for the determination of the coarseness index (CI), which is the sum of cumulative weight percentages of a particular size-graded sample of debris, and for the determination of median particle size (MPS), which is defined as the particle for which the quantity of particles equals 50% of the total of the cumulative distribution. After the sieve analysis was carried out on the drill cuttings in the laboratory, CI values were calculated and MPS values were obtained from the plots of cumulative undersize vs particle size. The performance data of the drills, CI values, and MPS values were analyzed using the least square regression method. It was seen that strong linear relationships usually exist between penetration rates and CI values, and penetration rates and MPS values for both top hammer drills and down-the-hole drills. Penetration rates increase linearly when increasing the CI and MPS values.

Jan 1, 2004

By Norman Orr, J. W. Gregg, Jack Wahl

The Pembina Cardium pool is a low permeability, stratified, solution-gas drive reservoir. Water-flooding has proven to be an effective means of pressure maintenance for all areas of the pool in which an economic rate of water injection can be maintained. The majority of water injection wells in the pool are converted oil well~ with capacities greater than 100 millidarcy-feet. If the average injection rate per unit of capacity can be in-creased the lower capacity areas of the pool can be economically flooded. Theory, laboratory work, and two . early miscible-flooding projects with-in the pool suggested that average water injection rates for converted wells could be increased two to three-fold by the initial injection of natural gas liquids and natural gas. How-ever, these two early projects received volumes of natural gas liquid!:' and high-pressure natural gas which would be economically prohibitive for routine stimulation. Area D, one of the Five-

Jan 1, 1962

By H. Salamanca

Recently, the mining industry has become one of the leading target markets for the technology industry as they need to innovate in their productive processes in order to boost productivity, reduce operation costs, increase operation safety, and improve the quality of life of their workers. This work presents the technological developments that HighService has done in different stages of the mining productive processes to include robotic manipulators in their automation solutions as well as the development of new equipment and sensors. The robotic technology integration is presented in different applications such as handling and selection of cathodes in E-W machines, automation of base plate maintenance, automation of cathode stripping machine, and multi-tools handler for liner bolt replacement in SAG mill liner maintenance activities. The proposed solutions show technical and economical viability with low initial investment and short implementation period of six (6) to ten (10) months. The results have been validated in plant, obtaining higher production rates and availability.

Jan 1, 2007