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By S. H. Logan

Mr. B. Neilly: A week or so ago the Secretary was good enough to forward me an advance copy of this paper by Mr. Logan and it was suggested that I comment on it at this meeting. At that time I was not very certain that I would be here, so I committed my thoughts to paper. As a matter of courtesy to Mr. Logan, I sent him a copy of my proposed remarks and I would like to give you just what I sent to him. Appreciating fully Mr. Logan's ability and many sources of information, one naturally hesitates to question anything seriously set forth as his considered opinion. Neither does one of my political stripe like to accuse him of being too 'conservative.? However, in places his paper reminds me of another general manager of a Canadian bank. While I was still Secretary of the Ontario Mining Association, this general manager wrote asking for our forecast on the current year's mineral production, stating that he proposed to refer to such production figures in his annual address to his shareholders. The request was considered very complimentary to the Ontario Mining Association and, in my opinion, justified a great deal of serious study and effort. Finally, the estimate was prepared and forwarded, showing a modest increase over the previous year's total. Picture our surprise and chagrin on reading his address to find that he predicted not an increase but, if you please, a decline of over $10,000,000. Before I cooled off I wrote asking the basis of such a prediction and got a reply to the effect that men in his position had to be ultra conservative in picturing the future.

Jan 1, 1931

By M. K. Gangal, M. A. Stoakes, A. E. Hall

"The major features of the CANMET thermodynamic mine ventilation network program, developed by the Mining and Mineral Process Engineering Department of the University of British Columbia for the Canada Centre for Mineral and Energy Technology (CANMET), are described.The program is designed for use by deep Canadian mines in planning ventilation flows where the effects of auto-compression of air, moisture lift work and natural ventilation are significant. Routines to simulate stalled fans and give an optional cost printout have been included in the program.A supplementary plotting program used to simplify data interpretation is also described.The program is described with a test data example of a deep mine. It is a valuable analytical tool which can assist ventilation engineers to simulate many alternative ventilation strategies at a low cost in a very short time.IntroductionCanadian underground mines are becoming deeper and more extensive. The use of more and larger diesel-powered equipment increases the amount of air required to be circulated in these complex systems. These effects, coupled with the increasing unit cost of the energy required for mine ventilation, require that the air is used with maximum efficiency.Optimum airflow distribution can be obtained by using network computer programs enabling engineers to plan future ventilation systems based on quantitative assessments. The programs used for deep mines must make allowance for the change of air density with depth, as the assumption of incompressible flow leads to serious errors. Natural ventilation effects may vary with depth and from part to part of the mine; this must be catered for by the program. The air moisture content changes throughout the circuit and a significant portion of the fan work may be used in removing moisture from the mine; as this work varies directly with the flow, a suitable relationship must be utilized in the program."

Jan 1, 1982

By Jonathan Peck, Jim Gray

"While the mine developer looks for bigger and better orebodies in countries offering lower risks to development capital, the opera-tor of existing mines is looking for bigger and better ways to use his existing resources. Mining operations today utilize a variety of stand-alone systems for planning and managing their operations. In both small and large mines, payroll, accounting, inventory, planning, and engineering requirements are met using a combination of manual and computer-based systems.Technical advances and new enabling technologies are changing how mines are doing business. PC-based systems are allowing small operations to join the larger mines in using advanced computer-based systems. Advanced monitors are being used in maintenance to track, predict and correct the health of production equipment. Production monitoring systems are used to measure the performance of operating equipment and personnel in real time. This detailed information on how much, where, when, and by whom is being used for proactive management and planning. Ultimately, this information can be used to optimize and control the machines’ activities, eventually leading to robotic and autonomous operation of mining equipment.As the use of technology increases in mining, specific information objectives are being met but other problems are being created. The life cycle of technology is small, and as current systems are replaced by newer ones, integration problems and additional end-user training are created. In addition, onboard monitoring systems can create large volumes of data, data which are frequently archived without being analyzed. Mine operators are also duplicating efforts applying new technologies in an effort to be more competitive, but in doing so are creating interfaces which are only compatible with their own facilities. As system development moved from the centralized mainframe computer to the PC environment, the fragmentation of these systems became more pronounced.To efficiently continue in adapting and utilizing advancing technology, the mining industry needs to develop a system architecture that readily integrates as many sub-systems as possible. This will provide a framework for existing system integration and design guide-lines for future development. The Total Mining System (TMS) concept will allow a network of stand-alone functional modules to be readily integrated with minimal effort. This paper will discuss some of the current technologies cur-rently in use in some surface mine operations.In addition, a description of the information system and communications requirements that will be needed to integrate these components in the future, will be discussed."

Jan 1, 1996

By Dart Wantland

"AbstractThe scope of geophysics in civil engineering and the nature of exploration geophysics are briefly discussed. Engineering problems amenable to geophysical attack are illustrated by specific examples. The various methods available, accuracy of results, and costs are treated. The possibilities of new uses of geophysical techniques are pointed out.IntroductionTHE SCOPE of geophysics in engineering is different than in oil or mining exploration. In civil engineering, geophysics solves specific problems; as for example, what is the depth to bed-rock along the axis of a proposed dam? The area to be surveyed is of limited extent, and the subsurface information .sought is relatively near the surface. The engineering geophysicist is not called upon to investigate geological basins or extensive mineralized areas or to probe for data to thousands of feet in depth. The geophysical tools employed in the three fields are, however, quite similar; the differences are mainly in the objectives.The Natural Geophysical ExplorationThe terms geophysics and geophysical exploration have been used heretofore and will .be employed in what follows. The question is, therefore, What is geophysical exploration?Geophysical exploration is a line of field work where measurements are made at the ground surface with special instruments to get geological subsurface information. Briefly stated, geophysics is a form of exploration that supplements geological work. It is a blend of physics and geology since physical measurements are made •at the surface of the ground that can be interpreted in terms of subsurface conditions."

Jan 1, 1953

By E. Peek, L. Becze, K. Reading

"Gallium oxide is an important semiconductor material used in optoelectronic devices (flat panel and solar cell) catalysts and sensors. One of the methods to produce ?-Ga2O3 is the so-called hydrothermal route. It is practiced by Neo Gallium Compounds and comprises of two steps: (1) the production of mainly gallium-oxy-hydroxide in a pressure vessel by reacting metallic gallium with water at 200-220 ºC and (2) the calcination of gallium-oxy-hydroxide at 700-750 ºC to convert it into ?-Ga2O3. This paper describes this pressure hydrometallurgy process supported with relevant thermodynamic data and presents the characteristics of the ?-Ga2O3 powder produced for commercial purposes. INTRODUCTIONGallium is a relatively new metal, having been predicted by D. Mendeleev in 1871, discovered by P.E. Lecoq de Boisbaudran in 1875, and first commercially produced in the USA in 1943. Gallium is not rare, being more abundant in the earth crust than antimony, bismuth, molybdenum, silver and tungsten. However, few gallium minerals exist in nature, and the dispersion of gallium within other minerals add to the complexity of its recovery. In practice, gallium is found in dispersed state primarily in bauxites and in some sphalerites, and, to a much smaller extent, in some coals. At present, a very large proportion of the primary gallium in the world is recovered as a by-product of aluminum plants, mostly Bayer plants, where gallium is extracted from a bleed of the Bayer liquor (Roskill, 2011). In 2011, world production of primary gallium was estimated at 200 metric tonnes. In addition, there is a significant contribution of recycling to the overall yearly availability of the metal.Gallium exhibits fairly remarkable properties: it is liquid above 29.76 ºC, can be supercooled, and with its high boiling point (2204 ºC), is the metal with the widest liquid range. Gallium is magnetic, and is an excellent conductor of both heat and electricity. Gallium also displays a marked anisotropic electrical conductivity (Roskill, 2011). All these properties render gallium almost irreplaceable in the semiconductors (GaAs, GaN, GaSb, GaP wafers) and the optoelectronics industry (flat panel, solar cell)."

Jan 1, 2012

By E. G. Joe

"Recent trends in Canadian mineral processing were reported in seven areas of interest covered by seventeen technical papers at the 1976 Annual Meeting of the Canadian Mineral Processors, held at Energy, Mines and Resources' Camsell Hall, Ottawa. New milling equipment included the Enviro-Clear thickener, large-volume Outokumpu flotation machines and abrasion-resistant polyurethane screens. Grinding experiences from a variety of milling operations were reported. Opportunities for increased sizing and grinding efficiency were presented. Flotation control by digital computer and by chemical additions were described in two mill operations. Slurry pumping and sampling techniques were described for various operations. Environmental control in milling was reported concerning dust suppression, arsenic removal and tailings disposal. Several aspects of gold milling were described by the most recently commissioned gold mine and by CANMET. Potash operations were reported showing the similarity of processing and process control to that of metallic minerals."

Jan 1, 1976

By R. H. Chambers, L. Alderman

"The paper is introduced by an examination of the factors which have led to the present world-wide interest in charging preheated coal to coke ovens. Various possible methods of preheating and charging the coal are considered and reasons are given for the adoption of the methods chosen. The design of the pilot preheating plant for the British Coke Research Association is discussed and its influence on the design of the commercial units for the South African Iron and Steel Corporation's plant at Pretoria and the British Steel Corporation's plant at Beighton are explained. Operating procedures on the pilot plant are described, particularly with regard to the charging of the preheated coal. Design features of the commercial installations, engineered by Simon-Carves Ltd., are explained with emphasis on the built-in safety of the control system of the preheating plant, and the particular problems associated with the erection of such plants on working coke oven batteries. Commissioning and operating procedures are described and the problems associated with the integration of the preheating plant into the normal pushing schedule of the plant are discussed. Preliminary operating results with regard to the effect of preheating on coal throughput on the commercial plants and on the properties of the coke produced are given."

Jan 1, 1972

By The Mill Staff

Introduction The Hollinger cyanidation mill commenced operating in June, 1912, and 49,779,978 tons of solids had been discarded by the end of 1950. The present tailing disposal plant has been in operation since 1924 and holds 39,762,250 tons. The tailing disposal plant is on the property of Kayorum Gold Mines, Limited, about a mile and a quarter south of the mill. The area available for tailing covers 640 acres and is roughly l ¼ miles long by ¾ mile wide. Tailing was first deposited on the McKay veteran claims, l mile long by 1/2 mile wide, which were later included in the Kayorum property. This site sloped from northeast to southwest, the slope amounting to 106 feet between the northeast corner and the low land to the southwest. The low land was wet and a considerable area was covered with muskeg up to 17 feet deep. It was drained by a brook running across the property in a southwesterly direction. Later, when more ground was needed, the low-lying mining claims adjacent to the south and west boundaries were acquired to allow for the extension of the plant. This entailed some extra difficulties and expense that would not have been encountered had the whole of the present site been acquired with the original purchase. At the present time, the top of the tailing deposit stands at two elevations, but eventually the tailing deposited on the extension to the original plant will be raised to the same height as the older deposit. Previous to 1924, all of the tailing was deposited on Low land and in lakes near the mil1. Between 1924 and 1926 an increasing tonnage was sent to the McKay claims until, in 1926, all of it was being sent there. In 1936, the area of the deposit was extended and shortly afterwards all of the tailing was deposited on the new site.

Jan 1, 1951

By C. A. Pickles

Microwaves are being applied industrially in a number of fields and possess a number of potential advantages that could be applied in extractive metallurgy. Microwave heating has a number of unique characteristics, which distinguish it from the conventional heating methods. In microwave heating, the absorption of energy occurs at the molecular or atomic level and therefore the heat is generated within the material itself. In conventional heating, the exterior temperature is usually higher than the interior, but with microwave heating, the temperature gradient is inverted and thus the interior temperature can be much higher than that of the surface. The energy densities in microwave systems can be relatively high and this in combination with the low thermal conductivities of oxide ores, can lead to very high internal heating rates. In this research, the application of microwave energy for the reduction of a nickeliferous silicate laterite ore has been investigated. The real and imaginary permittivities are the two fundamental properties which determine the microwave absorption characteristics of a material and these were measured for the ore, both with and without carbon additions using the cavity perturbation technique. The microwave heating and reduction experiments were performed in a 0 to 2 kW CTC microwave system. The effects of power input, processing time, sample mass and charcoal additions on the microwave absorption were investigated. Then reduction experiments were performed and the nickel grade of the magnetic concentrate and the nickel recovery in the concentrate were determined.

Jan 1, 2005

By O. Leuangthong, E. Schnetzler

"The McMurray formation in the Athabasca oil sands deposits of northern Alberta is part of the world’s second largest proven crude oil reserves. The formation is characterized by stratigraphic layers that correspond to three different depositional environments: Marine, Estuarine, and Fluvial facies. Resource estimation for oil sands has traditionally relied on polygonal and inverse distance schemes. These techniques are simple and straightforward in practice, but they do not permit reliable uncertainty assessment. This paper describes the modelling of the McMurray formation using modern geostatistical techniques.Geostatistical modelling should be performed within homogeneous geological facies. The methodology for geostatistical simulation within each of the identified facies involves: 1) assessing the most appropriate stratigraphic transformation for optimization of the correlation structure; 2) determining representative distributions with declustering and debiasing techniques; 3) modelling spatial continuity of the bitumen grade, fines grade, water saturation, and other petrophysical variables; 4) performing estimation and cross validation as checks against simulation results; 5) performing simulation for uncertainty quantification of bitumen and fines grade; and 6) model checking of simulation results against the input data, and comparisons against the kriged models. These steps are described in detail. The application of these models for uncertainty quantification in support of resource classification is also discussed."

Jan 1, 2006

By R H. Hallam

The Mattagami mining district encompasses a favour-?able belt of folded Keewatin-type rocks, with intercalated sediments and intrusives of late Keewatin age. This environment has been subjected to periods of basic and acidic intrusion. The orebodies lie within the fold structure and are associated with faulting and shearing of considerable magnitude. The No. 1 orebody contains 60 to 70 per cent massive sulphides. The minerals, in their order of abundance, are generally: pyrite, sphalerite, pyrrhotite, magnetite and chalcopyrite. It is evident that the broad geological structure of the district is amenable to ore deposition. There are two ? prominent linear expressions which comprise this broad structure. Both strike directions lie at the edge of, or are related to, a complex gabbro-anorthosite-peridotite zone. The fact that eleven of the ore zones discovered to date coincide with the broad structure indicates its over-all importance. It is estimated that the production from Mattagami Lake Mines will be in the range of 600 to 700 tons of zinc concentrate and 70 tons of copper concentrate per day.

Jan 1, 1964

By Pierre Buteau

Peat/ands distribution in Canada is widely spread thoughout the country and corresponds to a wide spectrum of wetland habitats which overlay peat deposits. The development and the evolution ofpeat/ands and peat deposits are closely linked together, since the vegetal remains of the peat deposits originate from the peatland habitats, and the peatland habitats constitute a response to many factors, including the properties of the substrate, which are the peat deposits. Peat/ands are defined as waterlogged terrains where the production of plant materials usually exceeds the rate of decomposition. The underlying peat deposits consists of organic residues associated to peatland vegetation, more or less decomposed, built up and kept under anaerobic conditions. Peat/ands evolution and distribution are determined primarily by climatic factors, but also by the geomorphology and edaphic conditions. All of these create particular hydrodynamical environments which will vary according to different regional settings, and sequentially to an evolutive time frame.

Jan 1, 2001

By C. Anderson, H. Huang, P. Miranda, E. Dahlgren, I. Chandra, M. Jeffrey

The latter part of the 20th century saw great advances in the treatment of refractory gold ores coupled with increased reliance on the use of cyanide for gold processing. Now, in many parts of the world, there is social pressure to limit or eliminate the use of cyanide. As well, treatment of some refractory ores or concentrates which have excessive cyanide consumption, gold cyanide pregrobbing or significant sulfide content remain difficult. This paper will outline the history of the development of alkaline sulfide leaching as an ancillary process to nitrogen species catalyzed (NSC) pressure leaching. Electrochemical fundamentals and the applicable thermodynamics of the alkaline sulfide hydrometallurgical system will be outlined. As well, examples of refractory gold recovery with alkaline sulfide hydrometallurgy such as an arsenopyrite gold concentrate application, a chalcopyrite gold concentrate application, a pregrobbing gold ore application, and a cyanide consuming gold ore application will be delineated in this paper.

Jan 1, 2005

By W. Evans, C. E. Ells

Nuclear power reactors using zirconium alloy pressure tubes generate electricity in several countries. Such reactors are particularly important in Ontario, where CANDUs* generate about 30% of the total electricity produced in the Province. Starting with the commitment of NPD-2 in 1956, the pressure tubes of the first five CANDU reactors were made of coldworked Zircaloy-Z, an alloy of Zr and Sn. This alloy was developed by the US Navy, but the decision to use it in a cold-worked condition was based on AECL work. In 1958, the USSR published information on a new alloy, Zr-2.5 wt% Nb. The Nb promotes stabilization of the (3-phase in the material, thus presenting opportunities of exploiting metallurgically strong pressure tubes analogous to the heat-treatable cx-{3 titanium alloys. After construction of two reactors using Zr-2.5 wt% Nb in a quenched and aged condition, an extensive development program on cold-worked Zr-2.5 wt% Nb pressure tubes resulted in them becoming the reference tubes for all CANDU reactors committed since 1966. Anticipating the future needs of the domestic and export markets, AECL have pressure tubes of Zr-3.3 wt% Sn-0.8 wt% Nb-0.8 wt% Mo (Excel) in an advanced state of development. These tubes will be used in an annealed condition; our projections show that they will have improved dimensional stability over the lifetime of the reactors. These improvements result from experimental programs leading to an understanding of the relationship between microstructures and fabrication variables and effects of the environment during service in nuclear reactors.

Jan 1, 1981

By Jeanne B. Percival, Paul Ramaekers, Charles W. Jefferson, Pat A. Hunt, Eric G. Potter, Katherine E. Venance, William Davis, Sean A. Bosman

"A 10-cm thick clay-rich layer near the top of the Manitou Falls Formation of the Athabasca Group is unusual in its breccia texture, alteration, and detrital mineral composition relative to the adjacent overlying and underlying sedimentary beds. This layer is composed of angular quartz grains set in an illite >> kaolinite + dickite matrix. Deformed clay-rich fragments within the layer have very similar mineral assemblages. The presence of euhedral accessory minerals including Ti-oxides and aluminophosphatesulphate minerals points to a diagenetic/hydrothermal origin. The presence of individual grains of Kfeldspar and amphibole is unusual relative to the typical Athabasca quartz arenite; originally, these minerals were probably included in detrital quartz and subsequently liberated during fracturing. The textures and alteration characteristics suggest that this layer is a hydraulically-fractured unit, which has experienced hydrothermal fluid alteration - a possible pathway distally related to uranium mineralization Une couche argileuse de 10 cm d’epaisseur pres du sommet de la Formation de Manitou Falls du Groupe d'Athabasca est remarquable par sa texture brechique, son alteration et la composition de ses mineraux detritiques qui different de ceux des couches sedimentaires sus- et sous-jacente. Cette couche est composee de grains de quartz angulaires dans une matrice composee d’illite >> kaolinite + dickite. Des fragments deformes riches en argile dans cette couche presentent des assemblages mineraux tres similaires. La presence de mineraux accessoires idiomorphes dont des oxydes de titane et des aluminophosphates-sulphates suggere que ces derniers ont une origine diagenetique / hydrothermale. La presence de grains de feldspath-K et d'amphibole est inhabituelle comparativement aux arenites quartziques typiques de l’Athabasca; initialement, ces mineraux constituaient probablement des inclusions dans le quartz detritique qui ont ete subsequemment liberees pendant la fracturation. Les textures et les caracteristiques de l'alteration suggerent que cette unite a subi une fracturation hydraulique et a ete alteree par un fluide hydrothermal - possiblement en lien avec les effets distaux de mise en place de la mineralisation en l'uranium."

Jan 1, 2013

By D. Sediako

Excessive residual stress in Al engine blocks may result in cylinder distortion which reduces engine operating efficiency. As such, neutron diffraction was used to measure residual strain along the Fe liners and Al, in the hoop, radial and axial orientations with respect to the cylinder axis, at the cylinder interbore region. Residual stresses were subsequently calculated using generalized Hooke's law and related to the microstructure along the cylinder bridge. The results suggest that the residual stresses in the Al interbore region are tensile and increased with depth in the axial direction of the cylinder. The increase in residual stress at the bottom of the cylinder coincides with a finer and more uniform microstructure in this region of the cylinder. The refinement in microstructure at the bottom of the cylinder likely increased alloy strength, thereby decreasing this section's susceptibility to distortion. This study successfully quantified the residual stress profiles in a heat treated engine block and related the stress profiles to an as-cast engine block.

Jan 1, 2011

By D. F. Kidd

Introduction In a companion article, Surveys at Great Bear Lake, 1931, R. C. McDonald has described the general character, topography, and climate of the Great Bear Lake-Coppermine River area and the main means of access (l). The present paper will largely be confined to the geological features of the district. In the last two years, the rocks of the region have received considerable attention, and papers including references to .the geological succession have been written by Knight(2), Duncan(3), Norris( 4), Reid(5), Cameron(6),and Kidd(7). The writer confined his field-work during the 1931 season to the district between LaBine point and Hunter bay and northwest to the head of McTavish arm. Brief trips were made down the Sloan river from McLaren lake, 25 miles northeast of Hunter bay, to that place, to Dowdell (Sixty-six) point, the south point of Echo bay, and to the region north of the Dismal lakes and west of the Coppermine river. The inner part of Echo bay, which is the area discussed by Reid and Cameron, has not been seen by the writer and the geology there will not be discussed.

Jan 1, 1932

By Brad Bjornson, Geoff Stevens, Mike Ashar, Cliff Britch

"LocationThe facilities are located 30 km north of Fort McMurray, Alberta (or 470 km northeast of Edmonton, Alberta).Brief Description of OperationThe operation includes the mining of oil sands, extraction of bitumen from the oil sands, and upgrading of the hydrocarbon fraction prior to shipment via pipelines to refineries.HistorySuncor was initially called Great Canadian Oil Sands. It was started by Sun Oil of Philadelphia. Construction began in 1965, with the first production coming on September 1967.Details of Present Milling Practice (Plant 3)Plant 3 recovers bitumen from the oil sand using the Clark hot water process. The basic steps in the process are conditioning, primary recovery, secondary recovery and tailings oil recovery.Oil Sand Feed SystemThe oil sand feed from the mine is transferred to the feed bin in extraction by two conveyor systems. Oil sand analyzers on each conveyor system measure the amount of bitumen and fines in the ore. Cones at the bottom of the feed bin distribute the oil sand to five process lines. Feed flow from each cone is regulated by an apron feeder which transfers the oil sand to conveyors that discharge into the conditioning drums. Weightometers on each of these five conveyors measure the rate at which the oil sand is delivered into the drums. The oil sand feed rate to each drum can be adjusted by varying the speed of the apron feeders."

Jan 1, 2000

By Ken McIntyre, Trodel Wolf-Dieter

"Sirius Minerals is a UK based fertilizer development company focused on advancing into operation its polyhalite project in North Yorkshire, England. The operation is known as the Woodsmith Mine which has an estimated 2.7 Billion Tonnes of reserves and is currently in the construction phase. DMC Mining Services was selected to carry out the construction of four shafts for the project, a production shaft of 6.75m diameter to a depth of 1594 m, a ventilation shaft of 6.75 m diameter to a depth of 1565 m, and two additional shafts to support the construction of the material transport system (the MTS and Lockwood Beck intermediate) to 360m in depth for servicing the underground conveyor network for transport of product from the mine site to the costal port facilities located at Teasside. This paper will review the status of the project to date and the innovative approaches that DMC is utilizing to ensure a safe and successful shaft sinking project. INTRODUCTION The Woodsmith Mine in North Yorkshire is a Sirius Minerals-owned deep potash and polyhalite mine located near to the hamlet of Sneatonthorpe, Whitby in North Yorkshire, England, approximately 75 km east of York. The area of interest is more than 700 km2. The £3.2 billion project is to develop the Woodsmith Mine to extract polyhalite, and a tunnel system to transport it to a materials handling facility and harbour at Teesside. The site is the world's largest and highest-grade deposit of polyhalite and is expected to produce 20 million tonnes of polyhalite, potash and POLY4 per annum, as well as create over 1,000 direct jobs and many more indirectly. It has the potential to generate over £2 billion of annual exports for the UK. As the project will require mining to be undertaken in the North York Moors National Park, many objections were raised about the mine. Sirius Minerals has gone to great lengths to ensure that the project is sensitive to the local landscape, including: mineshaft head frames that will be positioned below ground to reduce their visual impact; surface buildings will be kept to a minimum; and the entire site will be landscaped and screened by existing woodland to blend in with the surrounding area. The project will also abide by strict environmental limits which govern our activity during the construction phase."

Jan 1, 2019

By K. Kawagishi, J. Ang, A. Sato, H. Harada

"We have recently proposed a new ""EQ Coating"" bond coat system to solve the problem of secondary reaction zone (SRZ) formation caused by bond coats applied on the hot section components of modem jet engines. A viable EQ coating alloy was previously found for a representative znd generation superalloy, TMS-82+. It would be ideal if the same could be done for a representative 5th generation superalloy, TMS-173. In this paper, we will show that the coating with the best oxidation resistance in the EQ system of TMS-173, although possessing considerably better resistance than TMS-173, did not have sufficient oxidation resistance. In order to improve the oxidation resistance of the EQ coating for TMS-173, we have ventured into ""Pseudo-EQ coatings"". A diffusion couple between the Pseudo-EQ coating and TMS-173, after 300hrs at 1100°C, had a 0-15µm IDZ, but no SRZ. A diffusion couple between a conventional coating and TMS-173 formed a 80-150 µm SRZ. After a 1 hr oxidation test at 1100°C, the PseudoEQ coating formed a thinner oxide layer than the EQ coating, but still contained NiO and spinel. Aerospace"

Jan 1, 2006