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By J. E. Nesset, S. R. Rao, J. A. Finch

"For base metal sulphides, iron rejection starts in mineral processing. This review focuses on changes in plant practice specifically to improve iron sulphide rejection by control of contaminant ion effects and discusses selected general innovations in mineral processing that can be expected to play a role. One group of changes to control contaminant ions is in size reduction (the use of stage grinding and inert stirred milling) and another is in system chemistry (order of reagent addition and exploitation of the flexibility of sulphoxy reagents). Plant examples illustrate the successes, indicating that there are several options available. The general innovations start by considering the new tools for measuring gas dispersion properties and quantifying froth characteristics by imaging. Examples of their application to improve concentrate quality illustrate the potential. Other innovations stress adapting geostatistics to model variation in milling and flotation response to provide feed forward control and rigorous application of statistical experimental methodology in plant test work. An example from one concentrator shows improvements in concentrate quality from application of basic principles can be impressive.INTRODUCTIONThe more iron control (rejection) that can be accomplished in mineral processing the lower the subsequent metal extraction costs and environmental implications of iron disposal, particularly in hydrometallurgical processes. Iron rejection has been a contributing target to periodic attempts to apply mineral processing to nickel laterites and bauxites but the prime application is control of pyrite and pyrrhotite (iron sulphides) in the treatment of sulphide ores by flotation. In this paper some new concepts and innovations introduced in sulphide flotation plants over the past ten years or so (i.e., since a previous review [1]) will be outlined with examples of how they have contributed to improved “iron control”.To increase rejection of iron minerals, first the recovery mechanism should be understood. There are four principal ones, two physical in origin: 1, via locked particles (i.e., flotation of composite particles due to insufficient size reduction to liberate the minerals) and 2, through entrainment in the water reporting to the float product (an unselective process); and two originating from a response to the system chemistry: 1, true flotation (i.e., iron sulphides becoming hydrophobic) and 2, as a result of iron sulphides forming aggregates with hydrophobic particles (e.g., ”slime” coatings). There has been considerable effort to diagnose which of these dominates iron sulphide recovery; in many cases it is due to “chemistry”, in particular true flotation. The flotation effect often appears related to contamination by metal ions [1]. This can reduce selectivity in two ways: 1, metal ion species may activate iron sulphides, or 2, cause general depression which demands more vigorous flotation conditions (e.g., additional collector) with consequent loss of selectivity. This is where the review will start, by considering ways to control contaminant ions."

Jan 1, 2007

By M. Pelegrin Rodríguez, J. Castellanos Suarez, R. Causse Miyares, A. Mosqueda Martínez, Rubén Aja

"This paper will describe the methods and the results of studies to integrate polymetallic nodule extractive metallurgy methods into existing and operating technologies or plants with the aim of reducing the capital cost of deep-sea mining challenges and to streamline the supply chain of raw materials where such opportunities exist (Moa Bay and others). It will also assess the possibility to carry out pre-industrial processing operations with productivity corresponding to pilot mining operation in the Clarion Clipperton Fracture Zone (5–10% of assumed annual production) with the use of existing facilities. The present study shows the results of high pressure acid leaching of polymetallic nodules (PN) mixed with laterite non-commercial ore. It also presents PN processing in the presence of ammoniacal tailings obtained from the Caron process. The experiments were carried out according to 24 full factorial design. The regression equations were determined for extractions of Ni, Co, Cu, Zn, Fe and Mn. The obtained results show that increasing temperature, the acid/ mineral ratio and the leaching time have a positive and significant effect on extraction of all the studied metals. However, increasing the tailings addition favors the extraction of the Co, Zn and Mn. The extraction of Fe diminishes, while the extraction of Ni is not affected. In the following conditions; 180 min, 260°C, 0.5 kg acid /kg minerals and 2.5 kg PN/kg tailing; the following extractions were achieved; 96% Ni, 90% Co, 97% Cu, 99.9% Zn, 43% Mn and 26% Fe."

Jan 1, 2017

By Stephen van Duin

As productivity in coal extraction demands increase in underground coal mines, the industry is faced with finding new ways to support production without jeopardising safety. In modern mines the capacity and scale of longwall coal extraction has steadily increased to a point that support processes are failing to keep pace. In particular, roadway development is continually placed on the critical path of activities which maintain mine production, so any inefficiency in this area is quickly exposed. Original equipment manufacturers are under immense pressure to modify their machines to be more interconnected with each other, with machine communication and logistical sharing of space becoming a known requirement. This paper looks at the changing trends in mining practice, analysing available technology as well as currently emerging research into hard automation and discusses the need to integrate machinery and processes in order to see increases in productivity and safety.

Aug 1, 2013

By A. Bendada, P. Servais, X. P. Maldague, C. Ibarra-Castanedo, C. Mohr

Infrared (IR) thermography is a nondestructive, non-contact and non-intrusive technique that allows the fast inspection of large and complex structures with limited accessibility. Pulsed thermography is particularly interesting for the inspection of aerospace materials such as composites given that, after submitting the specimen surface to a thermal front, the most common types of subsurface discontinuities (e.g. porosity, de laminations, dis bonds, fiber breakage and inclusions) can be detected with an IR camera as regions showing abnormal temperature patterns. We present first the case of an aircraft door with water ingress and surface repairs on its honey comb structure. We also highlight the advantages and limitations of thermography for the inspection of aircraft composite parts, such as edge flaps, rotor blades and speed breaks. Finally, we expose some results from a Kevlar® non-planar specimen with Teflon® inclusions at different depths and locations.

Jan 1, 2006

By Mayumi Ito

Mineral processing of rare-earth ore from the Dong Pao deposit, Vietnam, was investigated. The ore contained bastnaesite, (REE (rare earth element)) CO3F, as the valuable mineral and barite, quartz, and fluorite as gangue. To establish a mineral processing flowchart, selective comminution, size classification, and magnetic separation were tested. Bastnaesite shows brittle properties and selective comminution was applied to improve the purity of products. The crushed products were classified by decantation, and the overflow product showed high purity of bastnaesite indicating that bastnaesite becomes fines by crushing and that selective crushing can be used to concentrate the bastnaesite. Magnetic separation for the sink product was carried out and the mag-product showed high recovery rates of bastnaesite, indicating that the combination of size classification and magnetic separation is effective.

Aug 1, 2013

By H. Stutchbury

Alberta is labouring, and has laboured, under serious difficulties in the marketing of ?her coals, due to a number of conditions which now obtain, but all of which appear capable of solution, and their elimination would insure a very largely increased market for the vast coal resources of that province. It is perhaps necessary to again mention the fact that 15 per cent of the world's coal resources are to be found in Alberta; 21 per cent of that of North America; 72 per cent of that of the British Empire, and 87 per cent of that of all Canada. While we talk largely of the great wealth of Canada, the immensity of her vast natural resources, it is axiomatic that the mere presence of any natural product in a country does not in itself constitute wealth for that country, unless these raw materials can find a market, either in their raw state, or by the process of manufacture. There are many factors, however, which enter into the marketing of any commodity. The chief of these, in my opinion, is price competition. High costs of production materially reduce the radius in which any product can be marketed, and this applies particularly to coal. Mining costs in the province of Alberta are necessarily high at the present time, due in a large measure to the ease with which the 'gopher hole' mine can be opened with small capital.

Jan 1, 1925

By P. A. Peach, W. H. Gross

The modern economic geologist in Canada is well equipped to apply geological, geochemical or geophysical techniques in the exploration for ore. Recently, great advances have been made in geophysics and geochemistry, and a large number of new orebodies have been discovered by these methods. An attempt is made in this paper to show that there has also been a considerable advancement in geological knowledge and that the most effective application of geophysics and geochemistry often occurs in areas already considered geologically favourable for the occurrence of ore. Ali exploration methods sooner or later suffer from diminishing returns. Therefore, as time goes on, one can expect to see the application of some of the more subtle or refined geological techniques that are presently being developed.

Jan 1, 1967

By Marius Jacobs

"Safety performance in many companies and even industries has stalled in the few years. Accidents rates are at a "plateau" and yet, serious accidents and fatality rates are not. In more dramatic cases, such as in the BP Texas disaster, organizations that have "exemplary" safety statistics, suddenly have a catastrophic or multi-fatality event occurring. Other classic examples are the Piper Alpha disaster and NASA’s Challenger and Columbia disasters and even the Chernobyl nuclear reactor. Looking into the root causes of these accidents provides an insight into the events and deficiencies that led up to the accident, but what are the common features in the organization’s mindset? What characterizes these organizations’ decision-making, their approach to safety and to risk and are there specific cultural features that can be delineated? The research and review presented in this paper covers a period since 1994, which started in the Australian resource industry and since then covered international events. The features of these organizations are summarized as the seven deadly delusions, based on extensiveresearch since 1997 of organizations that suffered unexpected disasters.The Piper Alpha Oil Rig disaster in the North Sea, on the 6 July 1988, was one of the most pivotal events in safety around the world. It changed the thinking and focus of governments, whole industries and led to numerous books and papers. It resulted in new legislation, textbooks and a critical self-examination by the oil and gas industry.In short, an explosion and fire occurred when a pipe started leaking gas and ignited. A temporary flange, with no safety valve, was used to block off this pipe during a maintenance operation the previous shift. The permit to advise operators not to start the pumps on this line was misplaced and lost. Several deficiencies, problems and system failures coincided. A key factor was that the water deluge system was inoperable at the time and failed to extinguish the large fire that erupted, followed by an even larger gas explosion. The accommodation unit, situated on top of the oil rig, was the main "killing field" - most men gathered here to await instructions (which never came) and where they died from smoke inhalation. Later, a large explosion of the gas pipeline from an adjoined rig exploded and killed more people.The line of events and the associated system failures are all very relevant in the analysis of the accident, and provide the only insight into what caused the accident. But much "further back", inside the organization’s culture, lurks more dark matter. The first inclination is to ask what was "deficient" in the culture. Did they not care enough about safety, or about their people? Did they have a culture where production decisions were more important than safety considerations? Did they ‘coerce’ supervisors and employees to ignore safety precautions or did they just "fly by the seat of their pants"?Not surprisingly, it is very difficult to identify the true nature of the culture in that business because in such an aftermath of death and destruction, no one dare say that the safety culture was a ‘positive one, focused and caring’ or that the company was doing well in safety and that this is only a freak accident. Indeed, there were many deficiencies in the organization’s systems and procedures, such as the permit to work system.But there are some niggling questions: How is then that the Piper Alpha Oil Rig was actually considered the company’s most productive and safest oil rig in the North Sea? Why would this rig win a safety competition, 6 months before the disaster, with the deficient permit as its most outstanding successful system?"

Jan 1, 2014

By Fatemeh Pourakbari, Mohammad Reza Yarahmadi, Abbas Sam

Pyrite is the most abundant sulfide gangue mineral in copper porphyry ores. In spite of addition of lime in large quantities to depress pyrite in flotation, considerable amount of this mineral is reported to concentrate, particularly in rougher and scavenger stages. With the Sarcheshmeh pit advancing to a greater depth and reaching to the hypogene zone, the amounts of pyrite and chalcopyrite in the feed are increased. Hence, a reduction in the copper grade and increase in the sulfur content of the concentrate are observed. In this study the effective factors on the pyrite floatability at the circuit flotation was considered at Sarcheshmeh Mine. Mineralization zones in the pit were firstly identified. Then, sampling points were located using GPS system. On the basis of mineralogical composition and morphology, the ore was categorized into five main classes. In this classification the amount of lead and zinc and also pyrite locking with other minerals were analyzed. The study of polished section indicated that inclusion in pyrite was very frequent in all classes, mostly composed of the floatability of pyrite. Flotation tests were performed on the samples of different classes at pH of 11.8 after conditioning time. It was shown that, pyrite floatability was decreased with a decrease in the lead content of the feed samples except for the second class, while for all classes an increase in zinc content contributed to a decrease in pyrite floatability and recovery. It was found that, the lowest pyrite recovery (1.89%) was corresponding to pyrite–molybdenite dominant mineralization with Zn of 0.33% and the highest recovery (86.89%) corresponding to pyrite vein dominant mineralization with Zn equals to 0.9%.

Jan 1, 2016

By J. A. H. Church

My paper entitled "Spontaneous Combustion of Coal in Mines;" read some time ago before this Branch, consisted chiefly of extracts from the British Blue Book dealing with the same subject. Fallowing my article, Mr. de Hart submitted a paper dealing with the application of existing methods of working in Alberta to the conditions obtaining in our bituminous mines. I must confess that the perusal of his paper did not enlighten me either as to what might be a method preferable to those in vogue or even to Mr. de Hart's ideas on the subject, nor did the ensuing discussion of Mr. de Hart's paper afford any great clarification of the problem. The outstanding idea, supplied by Mr. Dick, seemed to be that a retreating system could not be employed, as no operator would feel justified in risking the capital necessary to driving to the boundary when the whole might be jeopardized by a fire breaking out in the waste. That a fire would break out in the waste of any adit-level working seemed to be conceded by all, and with that I agree; that an ignited waste could not be safely sealed off by means of stoppings in a coal barrier-pillar appeared to be the contention of Mr. Dick, or perhaps he attributed this idea to the Mines Branch-anyhow, it seemed to loom over the discussion like a miasma. With this aspect I do not agree, as ? reliance is placed wholly on stoppings in the thick seams of South Staffordshire, even in fiery mines. In the thick coal at Exhall colliery, or elsewhere in Warwickshire (34 feet 4 inches) containing hard and soft coal in layers, a fire assuming serious proportions is sealed off. By the way, retreating long-wall methods are employed. In Fifeshire, sealing off fire in the Dysart mine has been accomplished successfully. The seam averages about 20 feet thick.

Jan 1, 1924

By O. A. Ojo, E. Anisimov, A. K. Khan

Electro-spark deposition (ESD) has recently generated a great deal of interest in processing aerospace materials. This is due to its potential for joining and repairing difficult-to-weld precipitation strengthened nickel-based superalloys without having problems of welding cracking that often plaque these materials. The short duration of current pulses involved in the process combined with the intermittent contact results in extremely rapid thermal cycle that produces nearly no heat affected zone in the substrate material. The microstructure of electro-spark deposited superalloy was meticulously studied in this work by scanning electron microscopy (SEM) and analytical transmission electron microscopy (TEM). The results show that in contrast to general assumption, the extreme rapid cooling rates involved in the ESD process did not produce partition-less solidification that is devoid of second phase microconstituents in the material. The secondary microconstituents were found formed along the intercellular regions of the solidification microstructure. The nature of these particles and the possible implication of their formation on mechanical properties of ESD processed material are reported and discussed.

Jan 1, 2015

By W. E. Oching, M. M. Ghomshei

Attracting and retaining workers in mining industry has become an uphill battle to many mining companies. As workers with significant experience retire, it is getting more difficult to attract not only new workers but also top talent to the mining industry to replace professionals exiting the workforce. To make matters worse, students’ enrolment in the post-secondary mining programs in Canada and USA is continuously declining year after year for reasons not directly linked to job market. This raises a question of how can the future needs of mining be met? This paper focuses on avenues for collaboration of industry and educational institutions to meet the current and future needs of mining. It provides effective approaches that mining institutes can engage with program advisory committees, role of the mining industry in supporting both faculty and students, how to harness the benefits of diverse workforce in the country and use of innovative technologies to attract young workers in mining. This work presents Human Resources (HR) professionals with tools that they can use to hire and retain skilled workers with strong interest to work in the mining industry. It also provides HR professionals with an opportunity to re-evaluate their restructuring practices during economic downturns as they reduce number of employees on temporary or permanent basis. The paper stresses the need of working together of the mining stakeholders including mining industry, academic institutions, First Nations’ communities and provincial(state) and federal governments to meet the current and future demands of mining as the industry experiences shortage of labour and low students’ enrolment in post-secondary mining programs. It is shown that mining educational institutes can enhance their programs and recruitments through establishing a better communication with all stakeholders. This communication can be facilitated by creating a national advisory board, to work with all mining programs at the national level for sustainable mining.

Jan 1, 2023

By G. W. H. Norman

"The La Corne molybdenite-bearing veins, discovered in 1915, lie halfway between Amos and Val d'Or near the southwest corner of La Corne township, Abitibi county, Quebec. The Molybdenite Reduction Company, which carried on operations during 1927 to 1930, sank a 200-foot inclined shaft to develop the property and produced about 22 tons of concentrntes from a 30-ton mill during 1929. Hollinger Consolidated Gold Mines, Limited, carried on further underground exploration in 1930. The Molybdenite Corporation of Canada drilled a part of the property in 1938 to 1939 and produced 1 ton of concentrates in 1938. Wartime Metals operated the property from 1942 to July 15, 1945. At this time the mill was enlarged to treat 200 tons daily. Molybdenite Corporation of Canada since July 15th, 1945, have continued the operation of this property and have revised the mill flow-sheet in order to produce both a bismuth and a molybdenite concentrate.The production for the period 1942-1946 is as follows:Total molybdenite production from the mine in the 1942 to 1946 period was about 4,127,400 lb.The La Corne deposit occurs at the northwest contact of a small mass of biotite granite with biotite schist. The form and extent of the biotite granite mass is concealed by a wide sand plain that extends northwest and west from the deposit and overlies bed-rock except in four small outcrop areas. These are spaced 1,000 and 2,000 feet apart along a narrow strip extending 5,000 feet south from the mine. The outcrops suggest that the granite must be at least 1,500 feet wide and 3,000 feet long northeastward. Where exposed in the mine workings the contact dips 70°N.W., but is not a sharply defineable feature due to the presence of numerous granite dykes and tongues in a zone of biotite schist 100 feet wide along the margin of the granite. The biotite schist in the few outcrops that flank the north and south sides of the granite strikes northeast and dips 60° to 70° S.E."

Jan 1, 1954

By E. A. Hart, J. E. Gill

"The property of Arntfield Mining Corporation, formerly Arntfield Gold Mines, Limited, covers an area of 2,110 acres and lies in Beauchastel township, western Quebec. The Francoeur mine lies to the west, and to the east are the West Wasa and Wasa Lake properties.The property was staked in September, 1923, by the late F. S. Arntfield. The early surface work was concentrated in the west part of the property along the Francoeur-Arntfield shear zone. The zone was opened by No. 1 shaft, which was sunk for an inclined depth of 250 feet. A series of silicified lenses were discovered farther east, where No. 2 shaft was later raised to the surface. A third shaft explored a shear zone about 1,900 feet to the east, where No. 3 shaft orebodies were developed.The mill was built at No. 3 shaft and production commenced in July, 1935, at 125 tons a day. This was increased to 280 tons by 1938, and later to 350 tons. The mine continued operations on this scale until April, 1942, when the exigencies of war necessitated closing. The Company was reorganized in 1944 and underground development was resumed in June, 1945. The total value of gold and silver produced to April, 1942, was $2,011, 755 from 529,987 tons of ore.ROCK TYPESThe area is underlain by highly deformed and altered Keewatin volcanics overlain by little deformed Cobalt sediments along the south boundary. The lavas in the vicinity of the mine workings are rhyolite, trachyte, andesite, and a flow breccia of intermediate composition. The fragmentals range from fine, well-bedded tuffs to coarse agglomerate in which acidic and basic horizons can be distinguished.The intrusive rocks are diorite and quartz-feldspar porphyry in the form of stock and sills, and narrow dykes of mica lamprophyre and syenite porphyry."

Jan 1, 1954

By A. F. Banks

"IntroductionThe typical potash processing plant recovers and/ or upgrades from 10% to 20% of its production through the recrystallization process. The feed to the recrystallization section consists of preconcentrated slurries of fine crystal size that cannot be raised to the required product grade by flotation and fine dusts also of low grade and too fine for compaction feed. It produces high grade white potash crystals that can be marketed as a high grade product or blended into the flotation products to raise their grade. In this chapter, a typical leaching (dissolving) and recrystallization operation will be discussed.The crystallization process makes use of the three phase system chemistry of NaCl, KCl, and H,O. The normal potash process operates on a temperature range of 75°F to 95 °F. A three phase slurry feed to the dissolving circuits will be within that range. The potash (KCl) is dissolved by heating the slurry in the presence of sufficient brine to a temperature of 190°F to 200°F. As the slurry is heated, the potash (KCI) dissolves and the salt (NaCI) precipitates. The potash rich brine is then clarified and the salt and other undissolved solids removed by thickening. Clarified brine becomes the crystallizer feed.The hot brine is cooled in evaporative cooling crystallizers. In cooling, the potash precipitates as a high grade white crystal. Crystallization is done in multiple effects to permit energy recovery and control of the process. In a four effect crystallizer the cooling is done by recycling mother liquor counter currently through the first two effect condensors and using brine pond brine for the cooling of the last two.The crystallizer product is removed from the last effect as a slurry at normal process temperature and is fed either to its own centrifuging and drying circuit or blended with the flotation product for centrifuging and drying."

Jan 1, 1989

By Fernando Romero Lage

"Crushing and screening theory and application has remained fairly consistent in the last 50 years. The application of such equipment is guided by varied formulaic conventions and rules that due to the entropic nature of the process, remains more an art than a science. The variability of conditions creates an environment in which trial and error becomes the principal means of process balance and control. This paper illustrates some of the theories behind the process, plus other assumptions, postulates, myths and misconceptions that exist within the crushing and screening industry.INTRODUCTIONContinuous material balance calculations are habitually performed in the design of new comminution circuits as well as in the valuation of existing circuits. A continuous material balance calculation is one in which the input rate of material is equal to the output rate for each unit functioning in the circuit. At continuous analysis, there is no accumulation or losses of material within the system, as it is when performing a discrete event analysis.In order to produce viable and manageable mine-to-mill material, whether it is ready to leach or ready to mill, we must reduce the material in a series of stages. The power demand increases as the material size decreases, as it is when folding a piece of paper successively. As with the paper, there is a crushing size limitation that is a consequence of the mineral properties such as work index, moisture, viscoelasticity, etc. Comprehensive knowledge of crushing plants in both the aggregate and the mining industries show that, after three stages of crushing, a particle size distribution originating from a blasted deposit can be reduced from an nominal maximum size of 500 mm to a nominal maximum size of 12 mm. if the last stage of crushing is set in closed circuit, the screen openings will be able to yield a smaller top size.Achieving steady and continuous material balance poses major difficulties as crusher lose their settings, screens blind or peg, and material characteristics change geographically or seasonally. Overloading conditions in crushers and screens are nothing but counterproductive, and the net losses of an unbalanced circuit can be overlooked when mining operators are paying a lot more attention to the evermore complex systems downstream.It is not simply the crushing of the mineral but achieving the right size for the downstream milling process that will yield the maximum amount of energy savings."

Jan 1, 2010

By E. S. Moore

"The Centre of the silver-producing section of the Gowganda area lies about 55 miles northwest of Cobalt, and the village of Gowganda is 71 miles by road from New Liskeard. The geological similarities of the Gowganda and Cobalt areas led prospectors westward from the rich Cobalt field, first to Elk Lake and then on to Gowganda, where mineralization was found in 1907. A year later many showings were found, and rich hand-picked ore was shipped. Most of the ore has come, however, from two mines, both of which are still operating; the Miller Lake-O'Brien, which was purchased by Siscoe Metals of Ontario Ltd. in 1945, and the Castle-Trethewey. The annual production of these two mines runs over one and one-half million ounces of silver and considerable cobalt. The total production of the camp has reached about 32,000,000 ounces of silver and a large amount of cobalt, the total not recorded.General GeologyThe general geology of Gowganda is in many respects much like that of Cobalt. There are areas of Keewatin basic and acid Javas mixed with tuffs and basic intrusions. These rocks are deformed and partly altered to schists, and have been intruded by some Haileyburian basic and ultra-basic rocks and by Algoman granite. These were followed by a large number of porphyritic Matachewan quartz diabase dykes. After a period of extensive erosion the Huronian sediments were deposited on a pene-planed surface over all the older rocks; these sediments include large quantities of conglomerate (partly tillite), quartzite, and greywacke. The Keweenawan rocks include the Nipissing quartz diabase sill, later quartz diabase dykes, and one long olivine diabase dyke, the latest Precambrian rock. The area has been extensively glaciated.Structural FeaturesThere has been little folding in the area since the Algoman batholiths were intruded, and the Huronian sediments lie nearly flat, with dips of 10, 15, or rarely 25 degrees. The Matachewan dykes show a remarkably uniform, nearly north strike, indicative of east-west tension when they were intruded. On the other hand, the dykes later than the sill strike nearly east, tangentially to the northeasterly and northwesterly strikes of the Miller Lake basin."

Jan 1, 1949

By W. Graham

"IntroductionEFFLORESCENCE is herein considered to be any deposit of salts on the surface of a masonry structure that is brought from within or through the structure by capillarity and deposited by evaporation. Usually, efflorescence is white although green, yellow, and brown efflorescence is sometimes observed.The common white efflorescence almost always consists of sulphates of the alkali and alkaline earth metals and calcium carbonate, although sodium chloride is frequently present in structures erected near the sea shore.The first and most obvious result of the presence of soluble salts in masonry is the unsightly accumulation of these salts on the surface. This is particularly noticeable early in its life and is frequently fugitive ( 1), as much of the salt is soluble and is gradually washed away by rain. This removal can usually be facilitated by scrubbing; the structure with dilute hydrochloric acid.A more serious effect is the continuous accumulation of soluble salts as a result of ingress of sulphur acids in rain water or water from the ground. This may eventually cause spalling and disintegration by crystallization of salts in the pores of brick and mortar. An example of this type of failure, resulting from the crystallization of calcium sulphate, is discussed by Hardesty (2). Butterworth (3) describes similar failure resulting from •crystallization of magnesium sulphate."

Jan 1, 1954

By Yongbao Zhu

The Ag2O-mediated reactions of cycloaurated compounds with a general formula Au(L)Cl2 (L = bi-dentate C?N ligand) with thiosalicylic acid, N-acetyl cysteine or 1,2-benzenedithiol in DMF proceeds via ligand substitution of the Au?Cl bonds to afford the S-O and S?S adducts all in good yields. The reactivity of the dichloro, S-O and S-S adducts towards thiols were examined by reacting with cysteine in an aqueous medium, revealing that all of Au-Cl, Au-O and Au-N are labile for thiol displacement. The measurement of the inhibitive activities of these compounds against human cathepsins B and K showed that the dichloro and S-O adducts are effective inhibitors with IC50 values ranging from 0.1 to 2.6 -M, and that the S-S adducts are inactive.

Oct 1, 2003

By I. H. Warren, F. A. Forward, A. Vizsolyi

"Observations are reported on the pressure leaching of material produced by subjecting chalcopyrite to two types of heat treatment. Calcination of the mineral at 825°C, in the absence of oxygen, induces some sulphur loss by volatization, producing a material from which copper can be leached more rapidly than from chalcopyrite. Treatment of the mineral with elemental sulphur at 475°C leads to sulphur uptake accompanied by a change in mineralogical structure of the chalcopyrite. Copper is prefer-entially and rapidly leached from the sulphur-treated material. A tentative explanation of the sulphur-chalcopyrite re-action is presented."

Jan 1, 1968