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By Willie Manfrey, Richard Klimpel

This paper describes the effects of slurry viscosity on the selection-for-breakage and breakage distribution parameters in the wet grinding of cres. A series of experimental tests were run on laboratory scale ball mills. Slurry viscosities were modified by varying the solids/water ratio with and without the presence of selected chemicals. Very consistent and predictable correlations are shown to exist. The grinding parameters were calculated using a computerized back -calculation technique developed by Klimpel and Austin. Industrial scale circuit calculations and preliminary plant trial data suggest that considerable increases in throughput and/or fineness of grind can he achieved through the judicious use of chemical additives.

Jan 1, 1977

By Wenbin Zhang, George W. Poling

"Prior or simultaneous addition of ammonium sulphate can, not only enhance the activating effect of hydrosulphide ions on xanthate flotation of malachite but it can also eliminate possible detrimental or depressing effects of excess residual hydrosulphide . Use of relatively inexpensive ammonium sulphate appears to reduce the consumption of the much more expensive sulphidizing agent for optimal flotation recovery INTRODUCTIONOxidized copper minerals float poorly with conventional thiol-type collectors. This is believed to be due to the nonadherent character of the collector coating, which is readily re- moved by particle abrasion. Rosas and Polingr reported emulsion flotation seemed capable of resisting abrasion during the flotation of non-sulphide copper ores. It appears that the most common flotation technique for oxidized copper minerals comprises sulphidization with Na .S and subsequent treatment by sulphydryl collector. The principles of this method are available . Malghan recently reviewed the studies on the role of sodium sulphide in the flotation of oxidized copper, lead and zinc minerals.It is well known that in the sulphidized flotation of malachite, the activation process depends strongly on the concentration of the sulphidizing agent, i.e., insufficient sulphide gives poor recoveries because of inadequate sulphidization; excessive sulphide also causes poor recoveries due to the depressive effect of the residual hydro-sulphide ions in solution. A major difficulty in sulphidization, especially with a varying feed nature, is to establish and maintain the optimum sulphide concentration in solution. In plant practice, vigorous control of sodium sulphide is required and stepwise addition of the reagent is recommended to improve the efficiency of the process. Soto and Laskowskim have found that malachite, depressed by an excess of sulphide ions, can restore its floatability if air or oxygen is introduced to the pulp. They attributed this to the oxidation of the HS - ions on the surface of the mineral. Jones and Woodcockuvi showed that a sulphide ion selective electrode could be used to optimize the conditions (e.g . amount of hydrosulphide, sulphidization time, flotation time) more readily and precisely than existing methods in the flotation of oxidized copper ores."

Jan 1, 1989

By L. D. Smith

"Those who submit competing proposals for projects seek to present senior management with complete and fully supported material that will not fail under questioning. Hopefully, misleading notions and omissions will have been minimized and there will have been testing of the assumptions regarding the economic, social and political environments.A capital project evaluation team can do management and itself a service by including a sound approach to the impact of inflation (and its twin problem, interest) on a project and a great disservice with an inappropriate approach to inflation.InflationHandled deftly, inflation can alter a project evaluation to show almost any result the handler desires. It must be a constant source of frustration for design people and cost estimators to spend weeks perfecting the technical aspects of a project in order to minimize costs, only to have all of their efforts set awash in a sea of financial and economic assumptions that submerge all of the detail. In all of this, inflation is perhaps the largest offender, with inflation criteria often being brought to bear at the last minute, almost as an afterthought. Perhaps this tardiness reflects the difficulty of the subject and the belief that senior management will take its own approach to the problems of inflation. Such a belief is unfair to senior management, for it is entitled to not being misled by omission. It is entitled to the full use of the skills of the evaluating team, including reasonable assumptions of the impact of inflation.Working in a consulting context, one has the opportunity to participate in the evaluation of a large number of projects."

Jan 1, 1990

By Cesar A. Urbano Jr., Gretchen T. Lapidus

A series of experiments examined silver extraction from a high-grade sulfide concentrate employing thiourea solution. Thiourea was initially oxidized with hydrogen peroxide (H2O2) to form formamidine disulfide (FADS) and used to extract silver from the as-received concentrate and after various pretreatments. Very low recoveries (~30%) were obtained with the as-received concentrate due to competitive cementation reactions by metallic iron and easily oxidizable copper phases. Over 80% Ag recovery was obtained when the concentrate was pretreated to remove this iron and copper. The results suggest that an oxidative acid pretreatment of this concentrates significantly improves silver recovery upon leaching with thiourea.

Jan 1, 2014

By L. C. So, S. Faucher, S. Mostaghel, D. Sauter, S. -Y. Oh, S. K. Lee

"Molten material from pyrometallurgical furnaces is tapped at high temperature, carrying a large amount of heat. Traditional handling methods of slow air cooling or water granulation do not allow for the recovery of heat from slag and matte. Furthermore, water granulation adds an inherent safety risk of explosions. Recently, there have been numerous studies into processes attempting to recover waste heat. However, most of them have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple dry atomization system that allows for heat recovery while eliminating the use of water. Comparisons of pilot and commercialized dry atomization and heat recovery technologies will be presented and challenges of these technologies will be highlighted.INTRODUCTION Slag has traditionally been regarded as an undesired waste product from smelting operations with slag management focused on removal and disposal of “waste”. Over 500 million tonnes of slag are produced per year, carrying with it ~220 TWh of energy (Barati, Esfahani, & Utigard, 2011). Depending on the process, the energy content of slag ranges from 10-90% of the total energy input (Barati, 2011, Rodd, 2010). There has therefore been great interest in recovering energy from slag. Slag handling methods can broadly be classified into three categories: (1) dumping and slow cooling, (2) wet granulation and (3) dry granulation. As discussed below, only dry granulation routes are amenable to heat recovery. Slag dumping involves the slow cooling of molten material and crushing of the resulting solid. In this process, slag is dumped on the ground directly from furnaces or transferred to slag pots that are moved by rail or haulers and then dumped on the ground. The molten material is left to cool and solidify until it can be broken and handled by heavy machinery."

Jan 1, 2017

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By Haruka Takeura, Tomoaki Murata, Kazunari Yoshida, Masato Adachi

"Pure magnesium is a material with high functionality, however, the cold drawing of this material is very difficult, that is why, until this day there are no optimal cold drawing conditions. Furthermore, cold drawing of pure magnesium wire shows a problem with internal defects that occurs under certain conditions. In this research, the aim is the suppression of internal defects, and final target is to create the optimal cold drawing conditions for pure magnesium wires. The first step is the investigation of the drawing limit by using 250°Cannealed wire. As a result, reduction of 10% per pass was chosen for stable wire drawing. However, in this case, it was found that internal defects occurred at total reduction of over 45% during drawing. Investigation of intermediate annealing conditions that can suppress internal defects, and influence on internal defect that the die half angle and reduction per pass. As a result, it was found that the drawing condition capable of suppressing internal defects most efficiently was 13% reduction drawing by using under 6°half angle die. Consequently, it’s possible to manufacture a cold fine drawn pure magnesium wire of 100µm, without defects in the center of the wire and hindering its mechanical properties.INTRODUCTIONMagnesium is a light and high functionality material that has high vibration absorbency, heat dissipation, electromagnetic wave-shielding and recycling efficiency (Conruy, 1989). However, proper cold wire drawing conditions haven’t been established, that is why warm or hot processing is commonly used (Oishi, Mori, &Kawabe, 2005). As a result, strength improvement of the wires is not possible, that is why the production of medical tools is disregarded. If it was possible to cold draw magnesium wires, the applications for material products would expand. Further, in wire drawing such difficult processing material, if appropriate processing conditions are not selected, defects will be generated inside the drawn wire."

Jan 1, 2017

By T. Warren, R. Pender

"Significant strides have been made during the past decade to integrate the traditionally separate administrative functions of financial management, materials management and maintenance management.In 1983, Key Lake Mining Corporation (KLMC) brought on-stream one of the most technologically advanced mining operations in North America. There was a requirement to support this new facility with state-of-the-art management information systems.This paper will discuss the development and evolution of the corporation's computerized information systems with specific emphasis on the utilization of computer systems to assist maintenance personnel in performing their work activities:Note: In August of 1989, the administration and operation of the Key Lake Mine was assumed by CAMECO - A Canadian Mining and Energy Corporation.IntroductionThe Key Lake Mining Corporation was incorporated in 1979 and operates a $500 million uranium mining and milling complex located in northern Saskatchewan.The feasibility study and environmental impact statements for the Key Lake Mine were submitted in 1979and in August of 1981, following a public inquiry, approval to proceed with construction was granted. Ore processing commenced in October of 1983 and during 1984 a total of 10.4 million pounds of uranium oxide (U3O8) was produced. In 1987, an annual production of 13.5 million pounds was achieved clearly establishing Key Lake Mining Corporation as the world's leading producer of uranium oxide. Current ore resources are expected to extend production of the Key Lake facility into the year 2000."

Jan 1, 1990

By T. G. Joseph, K. Barron

A strain-softening constitutive relationship is introduced that describes the post-failure stress-strain curve for rock regardless of whether the rock is intact or broken. The core of this relationship is an “apparent friction” concept that relates the post-failure apparent cohesive and frictional characteristics of the rock to the strain. The relationship can be determined for a given rock via a series of triaxial strength tests establishing the peak strength and corresponding strain for a range of confining pressures, together with the determination of the base angle of friction via a simple tilt test. The postulates and assumptions used in deriving this relationship are verified from results of tri-axial tests on both intact and broken rock. This strain-softening relationship is then applied to coal. Having determined the post-failure stress-strain curve for coal specimens, this information can then be used in a finite element program, such as Phase 2, to examine the post-failure characteristics of coal pillars. Using example data, the strength of coal pillars of different width/height ratios are estimated and compared with well-known empirical pillar size-strength relationships. In addition, the post-failure stress-strain behaviour of a coal pillar is compared with an empirical relationship reported in the literature.

Jan 1, 2003

By E. W. Johnson

"The title of my paper is ""I 'Wonder Where The Yellow Went"". As you can readily guess, it is not related to an old-fashioned ""Pepsodent"" sales pitch! Rather, it concerns a situation which arises all too frequently in some gold milling operations, namely when actual ounces of gold production do not come up to estimated or projected ounces. The boss man scratches his head and wonders where the missing gold has gone and how it has disappeared. The problem, if one exists, is amplified if one forgets that an estimate is just that - an estimate - and not a hard fact - even though the numbers are produced by computers. And yet, from the point of view of engineering; financial and production planning and security; it is most desirable to tie together all data relating to production estimates, losses and actual production.In the course of this paper reference will be made to the term ""variance psychology"", to a few of the physical properties of gold and to the nature of its occurrence in Canadian ores, in relation to the topic under consideration. Activities which have a bearing on production estimates will be reviewed. These include: weighing, sampling, assaying, estimating residual losses and, in cyanide plants, gold precipitate production. Mention will be made of apparent, unaccounted for and unknown losses. In conclusion, I shall draw from personal experience and relate three examples of ""Where the Yellow Went''."

Jan 1, 1986

By L. V. Chugaev

In the course of the hydrothermal refining of copper-nickel products containing covellite, oxidation of Fe2+ ions by the CuS?Cu2+ pair takes place, and iron is precipitated as hematite. Lower copper concentrations in the solution and higher solution acidity lead to the partial oxidation of sulphide sulphur, whereupon hematite is reduced by covellite causing iron to go back in solution. It is demonstrated that in the process of hydrothermal treatment of the covellite-containing solid product in pure water covellite oxidises millerite to polydymite (Ni3S4). Formation of polydymite during the process of refining seems to be due to millerite oxidation both by covellite and the CuS?Cu2+ pair.

Jan 1, 2007

By Kenta Suzuki, Toshiya Anami, Daisuke Shimosaka

"In an Al-Mn alloy heat exchanger fin stock, the effect of annealing conditions for as-cast and 0.1%Zr addition on recrystallization behavior is investigated using metallurgical analysis. Refinement of post-brazed recrystallized grains in fin stocks with Zr addition are suppressed for long-time annealing. In 0.1%Zr fin stocks, there was a decrease in the number of fine a-Al(Mn,Fe)Si dispersoids for pinning of sub grain and grain boundary. In addition, relatively homogeneous distribution of Al3Zr dispersoids was observed with increasing annealing time in as-cast. Homogeneous distribution of Al3Zr dispersoids can have a major effect on pinning of sub grain and grain boundary during brazing heat treatment. The homogenous distribution of fine dispersoids prior to brazing heat treatment is effective in causing the suppression of refinement of post-brazed recrystallized grain structure in aluminum alloy fin stocks.INTRODUCTIONAl-Mn based alloys are widely used as fin stocks in automotive heat exchangers because of their superior mechanical properties, braze ability, sagging and so on. In particular, coarsening of recrystallized grain structure is beneficial to avoid erosion, and achieve excellent sagging resistance (Lee, Yoon, Kim & Jung, 2002). For resisting grain coarsening, the alloys should contain a dense and homogeneous distribution of fine dispersoids to retarder crystallization (Humphyreys& Hatherly, 2004). It has been demonstrated that addition of Zr to Al-Mn alloys can shift recrystallization to higher temperatures because of the distribution of fine Al3Zr dispersoids in matrix(Pokoba, Cieslar& Lacaze,2012). According to Tohma, Asanoand Takeuchi (1987), coarsely recrystallized grain structure was obtained in 3003alloy with Zr addition after heat treatment. However, fine Al3Zr dispersoids are usually heterogeneously distributed because of segregation during casting and low diffusion rate of Zr in aluminum. Therefore, a homogeneous distribution of Al3Zr dispersoids can be achieved through long-time precipitation annealing(Jia, Hu, Forbord& Solberg, 2008)."

Jan 1, 2018

By M. Sengupta

International trade in minerals plays a very important role in the economic growth of many nations. Several less developed countries a1•e heavily dependent on their mineral exports for earning foreign exchange, which is needed for industrialization. Mineral exporting nations experience many problems in international mineral markets; the most important are tariff barriers, deteriorating terms of trade, instability in metal prices, etc. The formation of international mineral cartels to raise prices can be successful only to a limited extent and only for a short period of time.

Jan 1, 1976

By L. A. Homeniuk, R. Bonnar

"The Fond-du-Lac uranium deposit is located on the northern rim of the Athabasca Basin. The uranium mineralization is, for the most part, confined to the Athabasca Group, which is underlain by pre-Helikian metamorphic rocks of the Western Craton.The deposit is characterized by a remarkable train of mineralized glacial erratics which led to the original discovery. The mineralization is present as a ""high-grade"" core and a diffuse ""low-grade"" aureole. The ""high-grade"" core occurs as a stockwork of steeply dipping pitchblende veins which strike N 50°E. Hematite, siderite and secondary silicate are also abundant. The ""low-grade"" aureole contains uraniferous goethite, argillaceous material and rare carbon buttons. Recent alteration to coffinite has taken place along the margins of pre-existing ore minerals.The ""high-grade"" core is 390 m long and 10 to 40 m wide, and is surrounded by an irregularly shaped zone of ""low-grade"" mineralization with a similar length and a width of up to 350 m.Comparing the Fond-du-Lac deposit to other unconformity-type deposits, several important differences can be noted:1. Ninety per cent of the ore is above the unconformity, in the Athabasca sandstone.2. The deposit is not associated with underlying graphitic rocks or a major structure.3. The clay-rich alteration zone is not extensive around the Fond-du-Lac deposit.Although there are differences with other Athabasca unconformity-type deposits, the high-grade portion below the unconformity suggests a common origin.The ore deposit is postulated to have been formed from uranium-bearing solutions which entered the stockwork of fractures. Following the reduction in part of these solutions by pre-existing carbonaceous matter and pyrite and/or chemical reaction with pre-existing hematite, deposition continued as a result of decreasing temperature and pressure. Subsequently, minor supergene redistribution of the uranium has taken place."

Jan 1, 1982

By M. du Plessis, G. More O’Ferrall, A. Hartzenberg

"Lonmin Platinum has experienced several cases of large-scale hangingwall instabilities during the extraction of the Upper Group 2 Chromitite Layer (UG2) at a number of the Marikana operations along the Western Limb of the Bushveld Complex. These instabilities were all attributed to the presence and interaction of prominent geological features and highlighted that assumptions made in the design of the stable pillars and stable span were potentially overly simplistic in these areas. Investigations into the various case studies over the past ten years have resulted in the identification and classification of the rock mass characteristics of the geological structures causing the instabilities.In order to get a better understanding of these instabilities, it is important to understand the structural geology in general, and the sequence of events that led to the formation of the Bushveld Complex in particular. The tectonics involved in the formation of the various layers around the economic mineralized layers has been investigated, and the influence of these tectonic events on the stability of the UG2 stopes hypothesized.Following this investigation, the behaviour of the various layers in the hangingwall of the UG2 is better understood. This paper presents a description of the ground conditions being experienced in the underground stoping environment, the possible source of the associated structures and the resultant behavioural mechanism of these structures causing the rock mass instabilities."

Jan 1, 2015

By M. Boodman, E. Gertner

"At first glance, the activities related to mining and mineral exploration appear to be local or domestic, rather than international, in nature. Minerals, as corporeal or tangible property, form an integral part of the land in which they are found until extracted and exploited commercially. Even in the latter phase, the tangible nature of minerals gives the impression that the law governing the commercialization of minerals is the law of their situs at any given time. The nature of minerals appears to negate the international aspect of mineral enterprises.The fundamental flaw in the above analysis is its focus upon the nature of minerals, rather than the role of persons in mineral enterprises. The high costs of mineral exploration and commercialization invariably require the involvement of international consortiums or joint ventures. Governments may not have access to the funds necessary to exploit the mineral resources that they control. Local or domestic enterprises may not have sufficient expertise for mineral exploration. Further, markets for various types of minerals are far from localized or static. For these and other reasons, the tangible and localized nature of minerals belies the fundamentally international nature of mineral exploration and commercialization."

Jan 1, 2004

By A. Rajan

"Drawing upon the experiences of a gold extraction plant startup in the Southern Pacific, this paper will describe the importance of the commissioning phases to the project outcomes to achieve early target production despite an overall time compression to attain full plant production. Some of the highlights of the paper include: impact of roles played by the Owner’s construction and operations representatives during project commissioning, the formation of a capable and competent “Mod Squad,” availability of trained operating personnel, control over work priorities and the scope of work needed to bring the plant to safe initial operations. The commissioning team comprised subject matter experts skilled in process technology supported by “generalists” thoroughly conversant in overall plant operations. The merits of a structured team approach to brainstorm and resolve commissioning challenges as opposed to direction from individual subject matter experts is discussed. IntroductionStartup or commissioning is a unique period in the life of a project. Each stage of a project-exploration, feasibility, design, construction, commissioning, initial operations and continuing operations-requires special talents, know-how, and practices. Each stage makes particular demands of the people involved. Initial operations are no exception.Having experienced the 1997 startup phases of oxide and sulfide facilities for a gold extraction plant at a remote island in the Southern Pacific, I can attest to the many challenges and rewards. Commissioning for both facilities was extremely successful and brought the entire project on line well ahead of the targeted completion dates. Using this specific project as an example, this paper will highlight some of the key features of project commissioning. In this paper, the term “pre-commissioning” denotes all activities that lead to mechanical completion; “commissioning” occurs when feed is introduced; and “initial operations” are defined as the duration when operations accepts the system/facility and takes over."

Jan 1, 2000

By X. Z. Yuan

Contamination introduced by the impurities from the feed stream can impact the PEM fuel cell performance dramatically. The presence of these unwanted trace species such as CO, H2S, NH3, can adversely affect the fuel cell functioning. It has been reported that the major impact of CO and H2S contamination on the fuel cell performance is kinetic while the effect of NH3 contamination is speculated as membrane conductivity reduction only. In this paper, a model regarding the NH3 contamination is described and the mechanism of the NH3 contamination is illuminated by the model calculations.

Jan 1, 2005

By M. A. Keogh

This paper reviews the physical properties that make low-density polyethylene the most practical and economical material for launder• fabrication in the majority of mine and mill applications. The basic design features and use of other launcher• materials are also discussed.

Jan 1, 1976

By T. Sugawara, H. Sekimoto

Electrorefining of low-grade copper alloys containing various amounts of nickel, lead, antimony, bismuth, arsenic, selenium, silver, and gold in sulfamic acid media was demonstrated. The copper concentration of the alloys used as an anode was 70–90 wt%. The electrolyte contained 100 g L-1 of free sulfamic acid and 40 g L-1 of cupric ion. Galvanostatic electrolysis was conducted at 200–300 A m-2 in the electrolyte using a low-grade copper alloy anode and a stainless steel cathode at 25C. The terminal voltage was approximately 0.8 V at the start of the electrolysis, although it increased periodically to approximately 2.0 V and then shortly returned to its initial value. Nickel, lead, and arsenic from the anode dissolved in the electrolyte and were removed. Antimony, bismuth, selenium, and silver were removed as solids. Consequently, a dense copper cathode was obtained, and the concentration of copper was evaluated by inductively coupled plasma – optical emission spectrometry to be 99.82–99.99 wt%. INTRODUCTION Electrorefining of copper is conventionally carried out in a sulfuric acid electrolyte using crude copper assaying at 99.5 wt% Cu as the anode (Biswas & Davenport, 1994). Elements more noble than copper do not react anodically, and consequently, they are distributed in anode slimes. Elements less noble than copper dissolve from the anode. Nickel and arsenic are stabilized as aqueous species. Lead, antimony, and bismuth react with water, sulfuric acid, or arsenic acid to form barely soluble compounds; thus, they are distributed in anode slimes. An emerging issue in the electrolytic refining of copper is an increase of impurities in crude copper used as the anode (Moats et al., 2013). This is due to an increase in the content of impurities in copper concentrates as well as an increase in the types of secondary copper feedstocks (e.g., E-Scraps, automotive shredder residues, and smelting residues) treated in the copper pyrometallurgical process. An extreme case is a copper smelter that does not use copper concentrates as feedstocks. In such a process, copper-bearing feedstocks are smelted in a top submerged lance furnace to prepare low-grade copper alloys assaying at 80– 90 wt% Cu (Sekimoto et al., 2013). Such low-grade copper is not acceptable as an anode in the conventional copper electrolytic refining process because it is easily passivated during electrolysis. Consequently, electrolytic copper is produced by leaching the atomized low-grade copper in a sulfuric acid solution with oxygen, followed by electrowinning. However, electrowinning should be avoided whenever possible because the electrical energy consumed in electrowinning is 5–10 times higher than that consumed in electrorefining. Therefore, the development of technologies for electrorefining of low-grade copper alloys is desirabl.

Jan 1, 2019