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By Paul E. Mather, Matthew J. M. Krane

Anode or fire refining is the final pyrometallurgical step in the production of copper anode. Part of this process purifies liquid copper by reducing its dissolved oxygen with a natural gas-steam mixture. Until now there have been no transient models of this process coupling the injected gas jet mass transport with its chemical reactions. A transient, 1D flow, chemical reaction model was made to estimate the time-dependent behavior of anode copper composition, soot formation, and the transient gas jet composition along its height. Model estimates were made for reduction rate, soot emission rate, and exergy loss and destruction distributions for two melt temperatures and a range of steam addition rates. It was found that increases to melt temperature and steam addition rate increased reduction rate and decreased soot emission, while having little effect on exergetic performance. Estimates for reduction histories were compared to industrial data. INTRODUCTION Anode/fire refining is the final pyrometallurgical step in the production of copper anodes; it is essential for removing dissolved gases which cause porosity in cast anodes. Despite its significance, the open literature appears devoid of any transient models of the entire process; furthermore, there are very little published process data with which to validate any models made. This dual dearth of modelling work and process data inhibits studies of the tradeoffs between process and performance changes, desirable for decreasing reduction time and soot formation as well as quantifying changes in the exergy losses and destructions of the process. This work introduces a reduced-order, transient model of reduction during fire refining, examines performance trends with operating conditions, and compares model estimates with industrial data. Overview of anode refining The purpose of anode refining is to produce liquid copper which can be cast with minimal gas porosity, which disrupts the downstream electrorefining process. Dissolved sulfur is removed first, then oxygen, by reactions with different injected gases. The removal of oxygen (the reduction step) is the subject of this proceeding and is effected by the bubbling of natural gas, typically mixed with steam, through the melt from tuyeres. A typical refining run reduces dissolved oxygen from 3000 ppm to 300 ppm in 2–3 hours (Schlesinger, King, Sole, & Davenport, 2011). The refined copper is then cast as anodes. Figure 1 shows a schematic of the furnace vessel.

Jan 1, 2019

By Damian Connelly

The metallurgical heart of the majority of copper oxide processes is the heap leaching operation. Fresh low grade sulfide ores is a far greater challenge.The success of this unit operation is so important that operators need to understand the ramifications of their decisions or non-decisions and how they could affect the downstream processing. Heap leaching is an operation that can be described as a scientific art whereby principles of science can be used to guide experienced personnel in attaining their goals. Recent advances have been made based on better understanding the ore characteristics. The success of a heap leach operation, or otherwise, is dependent upon a number of factors, notably: The type of ore to be treated The extent of testwork completed to define the process The interpretation of the testwork results Ore preparation prior to stacking Agglomeration and curing requirements Other issues are: Compliance with the ’smaller’ requirements of environmental authorities Adequate and timely drainage of solution from the base of a leaching lift The degree of saturation in the pads Heap porosity – coarser or finer ore, which is better? Higher or lower irrigation rates – which would produce a better result? Laying out irrigation pipework for ease of operation and maintenance The addition of water, raffinate during agglomeration where needed The heap leaching of sulfide ores, including chalcopyrite, via enhanced bacterial leaching is discussed. INTRODUCTION Over the last twenty years, production of extremely pure copper from solvent extraction and electrowinning (SX/EW) has become more common in a market of real declining prices for copper metal. This paper touches on a number of heap leach operations and experiences. These projects were subjected to extensive engineering design and resulted in low capital cost, efficient operations with a number of lessons learned. The key to these operations was the performance of the heaps and associated fluid collection systems rather than the plants themselves.

Jan 1, 2019

By B. R. Maas

Processing material at a consistent rate through the continuous countercurrent decantation (CCD) thickeners presented a major bottle neck to unlocking additional value from one of the post-flotation streams at the Kansanshi processing plant. The manual operation of the thickeners making up the CCD train resulted in frequent imbalances and process upsets across units. The automation of CCD trains is notoriously tricky as the available manipulated variables are outnumbered by the parameters requiring regulation. The implementation of an advanced, auction-based, control philosophy to manage the movement of both slurry and solution inventory through the train addressed this parameter imbalance and lead to the stabilisation of the circuit. Since the commissioning of this control strategy: an additional 7 200 dmt/day (+36% throughput) of material can reliably be processed through the train, the number of monthly downtime events has reduced, and a saving of $354 000/month in reagent cost has been achieved. INTRODUCTION CCD operation Agitated leaching is a common method used in hydrometallurgy to extract a metal from its host ore. The host ore is initially finely ground to liberate the surfaces of the valued minerals and improve the kinetics of the leaching process. The ore is then contacted in an agitated tank with a lixiviant to dissolve the desired metal into the aqueous phase. The resultant slurry from the leaching process comprises of a solution pregnant in the metal salt and a barren ore. The first purification step taken after leaching is to wash the pregnant liquor solution (PLS) from the depleted ore. On the industrial scale, a set of between two to ten thickeners arranged in a countercurrent configuration is often used to carry out this separation (Perry & Chilton, 1973). The slurry is introduced at the head of the train and a wash solution at the tail. The two streams are pumped through each thickener countercurrent to one other. At each stage the residual PLS in the slurry is mixed and diluted down with the countercurrent overflow solution from the downstream thickener. The diluted slurry is fed into the thickener where the solids separate out through gravity sedimentation. The settled solids are channelled towards the underflow of the thickener by a rake mechanism and pumped downstream to the next thickener in the train. The outcome is the recovery of a PLS from the overflow of the lead thickener and a slurry of washed solids from the underflow of the tails thickener.

Jan 1, 2019

By M. G. Beukes

"In South Africa most of the large gold mines operate between 1500m and 4500m below surface where reef is accessed initially through a vertical shaft system then via a network of tunnels and mined in either a longwall, sequential grid or scattered mining configuration. Due to the complexity of the ventilation networks used to ventilate these mines and the potential disastrous consequences associated with underground fires, it is of utmost importance that these mines are managed in such a way that underground fires are prevented. However, if they do occur the fires are managed to firstly prevent the loss of life and secondly protect the infrastructure and viability of the mine. The aim of this paper will be to: • Discuss current SA mining legislation regarding underground fire prevention and control. • Examine these fires from a risk management perspective by means of a bowtie assessment. • List and discuss the major Threats and Consequences as determined by the bowtie assessment. • Discuss the various prevention and consequence controls for deep level underground fires. • Examine how to effectively run an emergency control room. From this, a practical way of designing, implementing and managing an underground fire management system is explored. Lastly, the paper identifies new technology and ways of thinking and how these can be used to combat underground fires. INTRODUCTION The orebodies of South African gold mines are generally narrow tabular structures that vary in thickness between 0.8m and 1.2m with an inclination of between 200 and 700. This, coupled with depths of between 1500m and 4500m, as well as the unpredictable geology, creates unique challenges and significantly impacts on mine designs and mining methods. In general, gold bearing reefs are accessed initially through a vertical shaft system then via a network of tunnels and mined in either a longwall, sequential grid or scattered mining configuration (Figure 1). Mining is very labour intensive with very limited mechanisation opportunities and this increases the risk to human life if an underground fire occurs. On 16 September 1986, one of the worst mining disasters in SA mining history took place when 177 mineworkers were killed at Kinross Mine. An acetylene tank sparked flames that swept through the mining tunnel igniting plastic covering on the wiring and the flames also set fire to polyurethane foam. The burning plastic combined with polyurethane and the toxic fumes that filled the shafts caused the miners death. This incident was a stark reminder of the serious consequence that underground fires can have on human life as well as the crippling financial and asset impact for the mining companies. Over the past thirty years, the SA mining industry reduced the number of mine fires significantly by replacing normal timber support with fire retardant treated timber, alternative support systems such as backfill and elongate support and many other fire prevention initiatives. Although the number of fire incidents and number of fatalities due to fires does not show a direct correlation because of various factors, the controls put in place against fires has had an impact on the number of fire and explosion fatalities (Figure 2)."

Jan 1, 2019

By Beatrice Pierre, Juan Carrasco

Altonorte began as a concentrate roasting operation in 1988 under the name of Refimet. In 1993, a copper smelter was built with a design capacity of 203,000 tonnes per annum of concentrate. Since 2001, many technological advances have been made in Altonorte, where the biggest Noranda Reactor in the world is installed being the first Noranda Reactor reaching above one million tonnes of copper concentrates processed per annum. In 2013, Altonorte was acquired by Glencore. Recently due to various new environmental regulations in Chile, Altonorte has evolved to new standards of operation in order to reach the vision of becoming a World Class Smelter. This paper describes the path followed to improve safety, environmental performance, process capacity, reliability, and productivity. The foundation for the growth and success in Altonorte is our People. Employee engagement and branding of our cultural journey is what allows Altonorte to face the future with the certainty of becoming a World Class Smelter. INTRODUCTION Altonorte is located in Antofagasta, the mining capital in the north of Chile and is the last smelter built in Chile practically completed with second hand equipment. The biggest technological change in Altonorte occurred during the phase 3 expansion in 2003, where the old Reverberatory furnace was shut down and replaced by the biggest Noranda Reactor installed in the world. The vessel measures 5.3 m × 26m. ºAdditionally, this project contemplated a new rotary dryer, three (3) new Peirce Smith converters, new anode furnaces and a new Acid plant. The nominal capacity was to treat 816.000 tons of new concentrate per year. In 2008, a new expansion phase was implemented where a new double absorption acid plant replaced the oldest acid plant. Bottlenecks such as blowing capacity and oxygen availability were solved installing a new air blower and a new contract was negotiated with our oxygen supplier to increase oxygen availability up to 683 tpd. This improvement defined the current nominal capacity of 1.100.000 ton of new concentrate per year. Current process description All concentrates are received by trucks directly from domestic mines or from the Antofagasta international port in cases of imported concentrates; the concentrate warehouse has a capacity of 25 kt where the blend is prepared to feed the smelter.

Jan 1, 2019

By C. Hudson, D. Tremblay, A. Frey

"A discussion of the design, challenges and successes associated with the commissioning of the gravity recovery circuit at Canada’s newest open pit gold mine - Atlantic Gold’s Moose River Consolidated Project in Nova Scotia, Canada is presented. An overview of the project, its historical significance and overall flowsheet is provided with special focus given to the design and selection of the gravity circuit equipment including the scalping screen, gravity concentrators and the novel intensive leaching technology selected for the project. The performance of the gravity circuit is benchmarked against the feasibility study process design specifications and the outcomes are discussed. Challenges encountered during commissioning are also presented, including the use of third-party automation and the effects of screen sizing on overall gravity circuit performance. Mechanical modifications made to the Sepro Leach Reactor for the Moose River project are also discussed. A detailed technical review of the mechanical and operational aspects of the Sepro Leach Reactor is provided with key operational data on leach times, recoveries, reagent usage, solid-liquid separation, pregnant solution quality and its influence on bullion purity.INTRODUCTION Atlantic Gold Corporation’s Moose River Touquoy Mill in Nova Scotia, Canada was commissioned in the fourth quarter of 2017 with commercial production declared in March of 2018. The 2 Mtpa process plant uses a conventional, gravity-CIL process. This site was previously mined in the 1870s. Interest waned in the early 1900s but resumed in the 1930s and the mine was brought back into production in 1935 until an underground mine collapse in 1936. This mining district became famous after CRBC radio commenced a ground breaking, around the clock, broadcast of the rescue operations. Over 100 million people listened to the broadcast from Canada, the United States and the United Kingdom. These broadcasts changed radio, transforming it from a medium for music to on the spot, breaking news reporting. The mill was constructed by Ausenco on a fixed price EPC contract in the historic Moose River gold mining district, 95 km north-east of Halifax by road. The mill will process ore from the adjacent Touquoy pit for the first 5+ years of operation; after the Touquoy reserves are exhausted, the mill will process ore trucked 37 km from the Beaver Dam deposit for an additional 5 years."

Jan 1, 2019

By A. A. Wessels, D. P. Allison

"Mine hoists are built to handle a certain nameplate capacity; they are specified and designed according to the required duty. However, as production capacity increases in other parts of an operation, the hoist capacity can become the critical constraint. Such a situation occurred at Lundin Mining’s Neves-Corvo operation. This paper examines how each component of the existing hoisting system was examined and optimized. Through a combination of engineering study and hoist simulations, the annual hoisting capacity was improved by 24% through increases in payload capacity and available hoisting time combined with a reduction in cycle time, while no changes were made to the hoist motor, drum or headframe. The additional payload capacity was achieved by reducing the mass of the hoist ropes and skips, and improving load monitoring systems. The cycle time was reduced through the shortening of the creep distances and increased availability through the installation of a shaft collar safety platform, alternative guide rope bushes, and superior liners for both the skips and underground measuring flasks. Enhanced cooling of the hoist electrical system was also incorporated to increase hoist availability by reducing downtime during hot summer months. The changes will increase the capacity from the current 4.5 mega tonnes per annum (Mtpa) to a planned 5.6 Mtpa and are being implemented over a 2-year period whilst maintaining the mine production during the upgrade work. INTRODUCTION Neves-Corvo Mine Neves-Corvo is primarily a copper and zinc mine producing copper, zinc and lead concentrates. The operation is owned and operated by Somincor, the Portuguese subsidiary of Lundin Mining. Located in the Alentejo district of southern Portugal, the operation is situated approximately 15 km southeast of the town of Castro Verde, where summer temperatures can reach as high as 45ºC, and approximately 220 km southeast of Lisbon. The principal means of mine access is via a ramp from surface, with the vertical shaft used to hoist ore and waste from the 700 m level, while conveyors descend from the 700 m level to transport ore and waste up from the deeper levels of the mine. The mine is highly mechanized and several different stoping methods are employed, with the most significant being bench-and-fill and drift-and-fill. The Neves-Corvo mine currently exploits five orebodies: Neves, Corvo, Graça, Zambujal and Lombador for copper and zinc-lead ores which are processed in one of two plants. All the orebodies are currently exploited over their full elevation with the exception of Lombador which is only mined down to the 220 m level, approximately the top 50% of the orebody, known as Lombador Phase 1."

Jan 1, 2019

By A. Esterhuizen, S. Essack, H. Joubert, N. Fowler

Tenova Pyromet has developed innovative technologies for copper smelting and electric slag cleaning furnaces. Based on client feedback and requirements, innovative designs have been developed to address key design areas and improve furnace reliability, operability and hygiene. These developments include the NovaLance™ lance system to prevent lance bending on top submerged lance furnaces, the SlagFlo™ slag tapping flow control device to better control bath levels and tapping rate for granulation, and an electrode seal for improved sealing directly onto the electrode casing to allow water-cooled electrode components to be located above the furnace roof. The potential application and benefits of these innovative designs are discussed. INTRODUCTION Tenova Pyromet has a long history in the engineering and supply of innovative electric furnace and related equipment for the base metals and platinum industries. Recently Tenova Pyromet has used its furnace equipment design experience to engineer innovative solutions for top submerged lance (TSL) furnaces, and potentially other furnace technologies. These equipment design solutions are developed to address specific operating challenges and operator requirements. Three of these innovative equipment developments are discussed in this paper. First the NovaLance™ lance technology to prevent lance bending during operation in TSL furnaces, such as used for primary copper smelting, is described. Lance bending has been identified as a significant problem for TSL furnace operators as it causes down time and affects furnace availability. The SlagFlo™ device to control the slag flow rate during tapping has been developed based on specific requirements in the mineral wool industry. The SlagFlo™ device can be used to control slag bath levels in primary smelting, converting and slag cleaning furnaces for base metals including copper. In addition, it can be remotely activated for the safe closing of slag tapholes located upstream from a water granulation system. Finally, Tenova Pyromet developed an electrode seal that seals directly onto an electrode surface. This is a special requirement related to base metals and platinum electric smelting and slag cleaning furnaces where furnace operators prefer to keep the water-cooled electrode equipment above the furnace roof. The seal can be used to seal directly onto the potentially hot and uneven surface of Söderberg, pre-baked and graphite electrodes.

Jan 1, 2019

By A. Ghahreman, M. Oliazadeh

"Heap leaching is an attractive process for low grade deposits where the metal content of ore does not justify the high cost of milling and agitated leaching. In general, the heap leaching capital cost is low, construction is rapid, and production costs are low. The primary disadvantage of heap leaching is low recoveries (typically 65% of agitated leach recovery); thus, recovery improvements could convert more lower-grade deposits into minable reserves. This will also allow to process primary sulfide ores and result in a dramatic expansion of the technology, as ~80% of total ore types are sulfidic in nature. The old gold operations tailings are another massive source of low-grade gold material that can be retreated by the heap leach process. The major parameters affecting the recovery rates are ore characteristics (mineralogy, particles size of metal and host minerals, ore permeability), and operational conditions (segregation of ore, compaction, leach cycle time, lift height, and solution application rates). The design of a percolation leach process is based on a limited number of coarse ore bottle roll and/or column tests under ideal conditions. The economics of the projects and engineering design of the process facilities are developed based on the bench scale test work results and the application of the conventional engineering scale up factors. This paper will deal with the parameters affecting the HL efficiencies and focus on the potential improvement of gold heap leach recoveries. This would include design of heap leach operation and evaluation of processes such as fine crushing and bioleaching.INTRODUCTION Gold heap leaching is a hydrometallurgical process designed to treat amenable low-grade gold ores that contain typically 0.5 to 1.5 g/t gold (Marsden and House, 2006; Wong Wai Leong and Mujumdar, 2010). Ore is stacked by various types of equipment on an impermeable barrier, and a sodium cyanide solution is applied to the surface of the stacked ore. Gold, silver, and other metals contained in the ore are dissolved to various degrees by the cyanide application, as it percolates downward through the stack of the ore. The pregnant leach solution (PLS) is then collected at the bottom of the heap. The PLS is then sent to the gold recovery plant where the metals are extracted. The barren leach solution (BLS) is then reapplied to the top of the pad. Ore is placed on a pad or previously leached lift by various means, including ramp conveyor belts, radial-arm and self-leveling stackers, and trucks. Once trucks are used to construct the pads, the pad can be compacted and hence the pad should be graded and ripped or scarified (roughened up) with wheeled or tracked equipment to produce shallow cuts to increase surface area exposure to the leachate."

Jan 1, 2019

By E. Vesely, A. Saxena

"SAG mill liners are designed for protecting the mill shell and providing lifting power for ore charge and grinding media. Due to the impacts from the charge and the grinding media, the liner experiences dimple, plastic deformation, strain hardening, fatigue, peening and final failure. Because of the collisional environment directly measuring such dynamical loads is extremely difficult if not impossible. In this study we tried to evaluate the liner failure risk by simulating the collisions of solid particles with mill liner using Discrete Element Method (DEM). DEM simulation has been proved to be a very useful tool in evaluation of granular flow and its impacts on the solid structure. But there are certain limits in DEM coherently, such as the number of solid elements, the computer runtime, etc. Here we first present the general feature of the particle-liner collision in terms of impact force and collision energy. Then the effects of parameter selection is discussed. Our simulations show the fatal collisional event of huge impact force is very rare and the collisional events of low impact is much more frequent. The fatal event may contribute most to the liner failure. The rarity of the fatal events may be missed in a short runtime simulation. This technical challenge combined with lacking of criterion to evaluate varying impact loads in fatigue problems may further complicate the evaluation. Should we use the largest impact force alone or we should use the more frequent events is an open question and requires more effort. In order to evaluate the quality of liner design, we proposed a relative comparison method. In the end we show the implication and application of this method in liner optimization by a work example. In particular, the effects of the charge level of grinding balls and their size on the operation performance is presented.INTRODUCTION Grinding is one of the most important and expensive steps of mineral processing. A variety of grinding mills such as rod mills, ball mills, semi-autogenous (SAG) mills and autogenous (AG) mills are being utilized for comminution of mineral ores (Gupta & Yan, 2016). Up to today, SAG mills and AG mills have been widely used to reduce operation costs and increase throughput. In an AG mill, a rotating drum throws larger rocks of ore in a cascading motion which causes impact breakage of larger rocks and compressive grinding of finer particles. Unlike AG mills, SAG mills use steel grinding balls to break ores of size quite small such that they cannot be easily broken in AG mill. SAG mill liners are designed for protecting the mill shell and providing lifting power for ore charge and grinding media. Due to the impacts from the charge and the grinding media, the liner experiences dimple, plastic deformation, strain hardening, fatigue, peening and final failure. Quality and performance of SAG mill liners play a fundamental role to enhance efficiency of grinding mills, because failure of liners is the major cause for unexpected breakdown (Banisi, Hadizadeh, Mahmoudabadi, & Eilkhany, 2006)."

Jan 1, 2019

By Arsenio Enriquez, Adrian Deneys, Ryan Walton, Jenny Esker

NOx emissions at the Rio-Tinto Kennecott Copper (RTKC) smelter, near Salt Lake City, Utah, are regulated to a compliance emission limit at the Main Stack of 15.9 kg/hr on an annual rolling average. The paper discusses RTKC efforts and improvements, particularly related to the anode furnace operations, since the Smelter modernization in 1995 to comply with the air quality approval limit. This includes replacement of gaseous ammonia to Steam-Gas Refining (SGR) system during the copper reduction stage, upgrade anode furnace oxygen-fuel burner from Praxair’s Stabilized Jet (S-J) to Jet Lance (J-L) technology, development and implementation of operational best practices and continuing to investigate and evaluate NOx control technology and strategy in the industry. In early 2016, changes to Praxair J-L Burner technology on both anode furnaces, utilizing wider lance spacing, was adopted and further improved NOx emission levels well below the compliance limit. INTRODUCTION Since the establishment of the Clear Air Act in 1970, the Environmental Protection Agency (EPA) has been regulating emissions of nitrogen oxides (NOx) to reduce impact on public health and the environment (USEPA, CAA, USEPA, NAAQS). As a requirement of the Clean Air Act, the EPA evaluates the standards for NOx and criteria pollutants on a periodic basis and as a result, standards have been revised and ultimately reduced over time (USEPA, CAA, USEPA, NAAQS, UDAQ, SIP). To remain competitive with changing regulations and in conjunction with Rio Tinto environmental standards for continuous improvement, the RTKC smelter has been motivated to research and implement NOx control strategies. NOx health and environment impacts NOx refers to a group of seven compounds including the most common, nitrogen dioxide (NO2). (USEPA, NO2). The EPA enforces both short-term (1-hr average) and long-term (annual average) standards for NO2 to protect against associated respiratory system impacts. Short-term exposure of elevated NO2 concentrations can aggravate respiratory diseases and lead to symptoms such as coughing, wheezing or difficulty breathing while longer exposures may contribute to the development of asthma and potentially increase susceptibility to respiratory infections. (USEPA, NO2) Additionally, NOx is necessary in the formation of ozone and particulate matter less than 2.5 microns (PM2.5). Ozone concentrations can negatively impact lung function and in some cases, contribute to chronic obstructive pulmonary disease. (USEPA, Ozone) The particles associated with PM2.5 can reduce lung capacity and aggravate heart conditions. (USEPA, PM2.5) For all NOx related pollutants, children and the elderly are generally at greater risk for the health effects. (USEPA, NO2, USEPA, Ozone, USEPA, PM2.5)

Jan 1, 2019

By D. R. Hatton

To obtain sufficient material on which to perform copper-molybdenum separation testwork a variability set of drill hole reject samples amounting to several tons was put together to include the different ore types proportions expected in the copper circuit. The samples were treated in a copper circuit pilot plant and enough mass of bulk concentrate was recovered to conduct copper moly separation tests in the laboratory. Tests consisted of stage flotation reactor (SFR) rougher pilot plant tests, conventional laboratory rougher, cleaner and 4 stage open circuit cleaner tests. The mineralogical liberation analysis of the feed and concentrate was used to model the effect of liberation on the grade-recovery relationship of the different samples. Mineral kinetic parameters for the various samples were determined by calibration to the test data. The copper concentrate results as simulated from previous studies on the same deposit were used to simulate the variability in head grade and throughput expected for the feed to the copper molybdenum separation circuit for each of the first 10 years of production. This variation in feed was then simulated through the separation circuit to obtain optimised molybdenum grade recovery curves to forecast the circuit production for each of the first 10 years. INTRODUCTION Incorporating Geometallurgy into the design for a copper molybdenum separation is especially challenging due to the low mass of final concentrate typically produced during testwork. This is due to the low molybdenum head grades and high overall molybdenum upgrading expected. With molybdenum head grades of around 300 ppm, 1 tonne of copper circuit feed is expected to produce around 300 g of molybdenum concentrate in the plant. In the laboratory however, this may end up only resulting in a few grams. Obtaining sufficient mass for laboratory testing therefore requires starting with a large initial sample and careful testwork planning to maximise the utilisation of this mass. A testwork program was designed to investigate the effect of ore variability on the copper molybdenum separation circuit (here after referred to as the molybdenum circuit). Composite samples were selected to represent the various ore types, copper content, moly content, pyrite content and clay contents expected in the copper circuit feed. These samples were run through a bulk copper pilot plant to create the feed for the molybdenum testwork. The molybdenum testwork consisted of rougher kinetic flotation tests, rougher cleaner kinetic tests, rougher cleaner kinetic tests with regrind, stage flotation reactor (SFR) pilot plant tests, open circuit cleaner tests. These tests were used to calibrate the ore kinetics in the IGS-FLEET model for simulation of the molybdenum circuit performance.

Jan 1, 2019

By K. Trapani

"The study undertaken aims to investigate an ice stope heating and cooling system for its potential to be implemented in sub-arctic mines, as a low carbon alternative to conventional natural gas and refrigeration chiller systems. Its performance was simulated for a years’ worth of data, taking into consideration hourly temperature data. Results showed that to supply the required heating and cooling loads, the ice stope system had to supplement its heating with natural heating. The techno-economic performance of this system was compared to that of a conventional heating and cooling system in a mine, with the ice stope thermal storage system hawing the lowest annuitized cost and significantly lower carbon emissions.INTRODUCTIONConventional heating and cooling, in a mine is implemented using natural gas heaters and chiller refrigeration systems respectively. This results in a significant portion of energy consumption in underground mines attributable to ventilation (De Souza, 2015), including the conditioning of the air to ensure that temperatures do not exceed work comfort standards (ACGIH, 2011). Especially at depth where heat could become a significant issue. An ice stope thermal storage, using ice as the storage medium is being proposed as an alternative to provide the heating and cooling—with the ice creation resulting in heating and the ice melting providing the cooling required. A techno-economic investigation of the two systems is undertaken to identify the capital and operating costs for the two systems, and to assess the ice stope’s potential to be considered a low cost and carbon solution for heating and cooling of mines in sub-arctic climates.NATURAL STORAGE SYSTEM – CONCEPT DEVELOPMENTThe concept for the natural storage system is developed from the ice stope at Frood-Stobie Mine, ON, Canada (Stachulak, 1991). The ice stope was developed for mine air heating, with the heating occurring by spraying warm return service water onto the cold intake air—resulting in the air temperature increasing and ice being created in the stope. In summer this ice was melted by passing warm air on top of it, resulting in slight cooling of the air but no significant temperature difference which could allow effective cooling. A schematic of the Frood-Stobie Mine ice stope is provided in Figure 1."

Jan 1, 2019

By A. Majumdar, B. Servière, H. Persson

The CCR refinery, which was built in 1931, treats both internal and third party copper anodes to produce 325,000 mt of copper as cathodes. These anodes contain high levels of impurities, such as Ni, As, Sb and Bi, that reports to the electrolyte during the refining step and need to be removed in order to maintain cathode quality and operating efficiencies. In the purification plant, the electrolyte is de-copperized via electrowinning in three stages. In the last stage, the copper content of the electrolyte is reduced to below 1 gpl in order to maximize the co-deposition of As, Sb and Bi with the Cu. This is accomplished with minimum arsine gas generation by using periodic reversal of the current and by controlling the final copper content of the electrolyte. Nevertheless, the possibility of exposure to arsine is treated as a major risk and controls have been implemented to reduce this risk. This paper describes the controls in place at the purification plant, which are being continuously improved through periodic risk assessments and audits. INTRODUCTION The CCR Refinery, which is a part of Glencore Canada Corporation and located in Montreal-East, Quebec, is a custom copper and precious metal refinery, with a capacity to refine 325,000 tonnes of copper anodes per year. Copper anodes are received from the Horne smelter in Rouyn-Noranda, Quebec, Altonorte smelter in Chile and other 3rd party smelters. CCR anodes are produced using the spent anodes from the tankhouse along with purchased spent anodes and copper scrap. The precious metal plant treats the tankhouse anode slime, purchased anode slime, precious metal ingots and Doré anodes from Glencore’s Brunswick lead smelter in Belledune, New Brunswick. CCR products include copper cathodes, silver and gold bullion, a platinum-palladium concentrate, selenium, tellurium dioxide and nickel sulfate. In 1975 an accident occurred at CCR where two employees were exposed to fatal levels of arsine emitted from the then existing purification cells. This process was therefore shut down immediately. Research and development work was then initiated to determine the optimum electrowinning conditions whereby arsine gas generation would be minimized while maintaining high copper and impurity removal efficiencies. It was found that the application of periodic reversal of current (PRC) during the last stage of electrowinning retarded the onset of arsine formation while at the same time allowing the copper concentration to be reduced to less than 1 gpl (Houlachi & Claessens, 1978). A new purification plant was designed based on the PRC technology and was started up in 1976. In addition to the use of PRC electrowinning, the new plant is located in a fully enclosed section of the tankhouse. A special effort was made to design a ventilation system to evacuate the acid mist in addition to any arsine gas. Arsine monitors were installed to measure the emissions from the stack along with arsine levels in the workroom. The arsine monitors and the ventilation system were interlocked with the rectifiers (Thiriar et al., 1983).

Jan 1, 2019

By P. Rosario

"Industry practice for high-pressure grinding roll (HPGR) assessment and sizing relies on tests using pilot-scale machines with 0.7–1.0 m roll diameters. Typically 1–10 t of sample are required, depending on the level of study and resource complexity. This is challenging during early-stage development, which hinders incorporating HPGR into designs. With support from the Canadian Mining Industry Research Organization, researchers at the Norman B. Keevil Institute of Mining Engineering at The University of British Columbia developed bench-scale piston–die press tests (PPTs) that correlate to pilot- and full-scale HPGRs. This paper describes a new regression model to estimate the HPGR-specific throughput rate using both PPT results and an HPGR database. A case study is presented to show how the current PPT method is used for engineering studies. ¦ KEYWORDS Empirical modelling, High-pressure grinding roll (HPGR), Piston–die press test (PPT), Sizing and scale upRÉSUMÉ La pratique en vigueur dans l’industrie concernant l’évaluation et le calibrage d’un cylindre de broyage à haute pression (HPGR, de l’anglais high-pressure grinding roll) dépend d’essais menés à l’aide de machines à l’échelle pilote dont les diamètres de bobine sont de 0,7 à 0,10 mètre. On a généralement besoin de 1 à 10 tonnes d’échantillons en fonction du niveau de complexité de l’étude et des ressources. C’est une pratique difficile durant les premières phases de développement, qui empêche l’intégration du HPGR dans les plans. Bénéficiant du soutien de la Canadian Mining Industry Research Organization (CAMIRO, l’organisation de recherche de l’industrie minière canadienne), des chercheurs du Norman B. Keevil Institute of Mining Engineering (l’institut Norman B. Keevil de génie minier) de l’université de la Colombie-Britannique (UBC) ont mis au point des essais en laboratoire sur des presses à matricer à pis¬ton (PPT, de l’anglais piston–die press tests), qui mettent en corrélation les HPGR aux échelles pilote et réelle. Cet article décrit un nouveau modèle de régression qui évalue le taux de production spécifique aux HPGR à l’aide des résultats tirés des PPT et d’une base de données dédiée aux HPGR. Une étude de cas est présentée afin de décrire l’utilisation de la méthode actuelle des PPT dans les études techniques. ¦ MOTS CLÉS calibrage et mise à l’échelle, cylindre de broyage à haute pression (HPGR), essai sur presses à matricer à piston (PPT), modélisation empiriqueINTRODUCTION It is widely accepted that high-pressure grinding rolls (HPGRs) are a viable, energy-efficient solution for modern comminution flowsheet design. Table 1 summarizes select examples of HPGR applications in the mining industry. The main benefits of HPGRs are energy savings, which leads to lower operating costs, and stable operating characteristics that can better cope with variations in ore hardness compared to the conventional autogenous (AG) or semi-autogenous (SAG) mill-based comminution circuits."

Jan 1, 2019

By T. G. Joseph, M. Bolster, M. Curley

"High tirerim loading on haul trucks operating on rough ground frequently manifests as mechanical separations and rim base cracking caused by cyclic fatigue. This paper provides an understanding of the impact of high loads on rim component life and tire footprint, bulge, and deformation behaviour; and develops a maintenance planning tool to predict strain implications of high g loading for a given rim location. Loading tests and analyses were conducted for a tirerim arrangement under increasing load and internal tire pressure. Graphical models were developed, allowing higher g load extrapolation predictions for specific rim components.KEYWORDS g load, Mining, Model, Prediction, Rim, Strain, Tire bulge, Tire footprint, Ultra-class vehicleRÉSUMÉ L’application d’un chargement élevé sur le système pneu/jante de camions de transport rou¬lant sur des terrains accidentés se manifeste fréquemment par des séparations mécaniques et une fissure à la base de la jante engendrée par une fatigue cyclique. Cet article nous permet de mieux comprendre l’incidence de l’application de charges élevées sur la durée de vie des composantes de la jante ainsi que sur l’empreinte, la hernie et le comportement de déformation des pneus. Il développe également un outil de planification de l’entretien visant à prévoir l’incidence des contraintes en cas d’application d’un chargement g élevé sur un endroit donné de la jante. Des essais et des analyses de la charge ont été effectués pour un agencement pneu/jante soumis à une charge et une pression interne du pneu croissantes. Des modèles graphiques ont été développés, ce qui a permis d’établir des prédictions sur la base d’une extrapolation du chargement g plus élevé appliqué à des composantes spécifiques de la jante.MOTS CLÉS charge g, contrainte, empreinte du pneu, exploitation minière, hernie du pneu, jante, modèle, prédiction, véhicule ultralourdINTRODUCTION The purpose of this paper is to report on a proposed and trialed tire performance test based on data obtained from controlled testing that is used to predict the impact of high g loading on hauler rims and tires with greater accuracy. For example, for many years oil sand mining operations have expressed qualitative beliefs that an impact load of the magnitude experienced by a rim and tire arrangement is not detrimental to a rim as a stiff component; however, mining equipment components are subjected to cyclic loading where failure can result from repeated load/unload activity, truncating the peak region of a stress–strain response and resulting in fatigue failure at a stress value that is less than the peak value. The outcome reported by oil sand haul truck maintenance groups indicates they have realized that most high g impacts—such as those experienced by hauler tires and rims operating on poor ground conditions—can result in failure due to cyclic loading, where higher loads require fewer cycles for failure. This high-level loading and the resulting strain transmitted to the rim is evident in the results of the laboratory testing presented in this paper."

Jan 1, 2019

By A. de Ville d’Avray, G. Guezennec, P. Wavrer, E. Braak

The aim of the European CEReS project was to develop an innovative copper recycling route based on the coprocessing of coal production waste by bioleaching and printed circuit boards (PCBs) from Wastes of Electrical and Electronic Equipment (WEEE). Coal waste is processed by bioleaching in stirred tank reactors, and the resulting bio-lixiviant solution is used to extract copper from PCBs pre-treated by catalytic cracking. Copper is then extracted using solvent extraction, stripping and electrowinning. The whole process flowsheet combines thermal, biotechnological, physical and hydrometallurgical operations. Once the process concept has been validated at laboratory scale, a simulator of the whole process has been built in the USIM PAC software platform. The tool enables to improve the analysis of the results of the lab-scale experiments and to design industrial-scale scenarios by simulation. The results of such simulations allow to estimate the economical interest and to perform environmental impact assessment. After presentation of the CEReS project objectives and main results, the paper describes the methodology used to build the simulator and define the scenarios corresponding to feasible process routes. The main results of the simulations are then presented with technical, economic and environmental point of views. INTRODUCTION Because of rapid technological innovations in the electronics industry, electronic waste represents the fastest growing waste stream in the world, especially in developing countries (Işildar et al., 2018). Meanwhile, the global copper demand is expected to go on rising in the future. As significant amounts of copper are present in end-of-life printed circuit boards (PCBs), it becomes a necessity to develop efficient copper recycling routes. Metal refining from e-waste is traditionally performed by pyrometallurgical processes. However, the hydrometallurgical processing of PCBs, which has been shown to be technically feasible at laboratory scale with a wide range of leaching reagents, could be a less energy intensive and more flexible alternative (Tuncuk et al., 2012). However, a large amount of leaching reagent is required to leach the metals from PCBs.

Jan 1, 2019

By Alexander Levran

The main thrust of this presentation is to illustrate the growing contribution of solar energy to the mining industry by replacing existing mechanical and pneumatic tools and equipment with more effective and efficient electrical tools due to the increased efficiency and lower cost of solar energy generation. LCOE (levelized cost of energy/electricity) for solar energy is becoming highly competitive with other conventional sources of energy. The distributed architecture of solar power plants allows the supply of energy to highly remote and abandoned geographies. We will focus on the trend for this contribution to the mining industry over the next three years. Water desalination and delivery to the mining area will be topic of discussion regarding the contribution of solar systems in Latin America (LATAM) and other geographies. INTRODUCTION Increasing price pressure on the mining industry has generated a strong interest for mining companies to investigate energy costs and consumption. Currently, energy costs in mining economics contribute15% to 25% of the total commodity cost. In the past, most mines were operated by diesel gensets. Very high logistics costs for diesel supply, high and fluctuating diesel prices and theft led to very high energy prices. To overcome this problem, the mining industry has turned to solar energy, employing two main solutions: (i) adding a small scale (single level MWp energy supply) solar to an existing diesel system to create a hybrid solution operating as a microgrid environment; and (ii) replacing the existing diesel system with a large scale grid connected photovoltaic system financed by utilities or private IPP owners that signed a long-term power purchase agreement (“PPA”). In both applications, the near-term trend is to add storage and weather controls to optimize the electrical performance of the system. Use of concentrated solar solution (CSP) in the past was employed in a few remote sites to provide electrical energy to the mines. Currently this technology is not competitive with the photovoltaic (PV) systems. In some installations we have seen usage of a small hybrid system that is designed as relocatable, containerized and delivers scalable electrical power. In addition to the evolution of electrical energy sources, we see the trend of reduction of energy consumption in the mines by optimizing energy efficiency and generating load shifting solutions. Many studies of electrical energy in the mining industry support the growth of this trend in the mining industry.

Jan 1, 2019

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

In this study, the dissolution behavior of copper and arsenic from five different copper concentrates containing 21-34.7 %wt. of Cu, 1.3-7.3 %wt. of As and 15.6-27.5 %wt. of Fe were investigated under high pressure oxidative leaching conditions. Leaching experiments were conducted using different leaching reagents such as ferric sulfate, sodium chloride, deionized water, sulfuric acid and ferric sulfate-sodium chloride mixture in order to compare the effectiveness of each on the dissolution of copper and arsenic from copper concentrates. The effects of ferric sulfate (0.1-1 mol/L), sodium chloride (0.1-0.5 mol/L) and leaching temperature (100-180C) were investigated under 1 MPa autoclave pressure , particle size >45 m, pulp density of 100 g/L, stirring speed of 750 rpm and leaching time of 60 min. Results showed that the most effective leaching reagents for the dissolution of copper are 0.34 M NaCl and a mixture of 0.1 M Fe2(SO4)3 - 0.34 M NaCl, in which As extraction did not exceed 7%. The copper concentration in the pregnant leach solution obtained after leaching using 0.1 M Fe2(SO4)3 - 0.34 M NaCl was 13-30 g/L, while the concentration of As and Fe were in a range between 0.3-1 g/L and 0.2-10 g/L at 160C. INTRODUCTION Copper sulfide minerals, such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and covellite (CuS) are used for the production of copper in mining and metallurgical industries worldwide. The conventional pyrometallurgical processing followed by electrorefining is a common process for the production of high purity copper (Moskalyk, & Alfantazi, 2003; Padilla, Aracena, & Ruiz, 2012). However, the degradation of copper content and an increase in the amount of metal impurities, especially arsenic (As), antimony (Sb) and bismuth (Bi) in copper concentrates cause serious problems to the production of copper and environmental pollution (Basha, Selvi, Ramasamy, & Chellammal, 2008; Long, Peng, & Bradshaw, 2012). Hydrometallurgical processes are used to recover metals from refractory ores, concentrates and tailings by leaching (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018). During the last decades, hydrometallurgical processing for the recovery of copper from enargite-bearing copper ores and concentrates has been extensively investigated due to its relatively more environmentally benign and less capital costs than the conventional pyrometallurgical processes (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018; Choubey, Lee, Kim, & Kim 2018). However, several issues facing the hydrometallurgical processing are incomplete extraction of copper associated with the coprecipitation of iron compounds, difficult stabilization of toxic impurities and production of a contaminated copper product (Dreisinger, 2003; Safarzadeh, Moats, & Miller, 2014). Hence, a number of studies have been conducted on the selective dissolution of copper from copper ores and concentrates or selective removal of arsenic leaving a clean copper residue using various leaching reagents or lixiviants (Safarzadeh, Moats, & Miller, 2014; Mihajlovic, Strbac, Zivkovic, Kovacevic, & Stehernic, 2007; Tongamp, Takasaki, & Shibayama, 2009). More extensive studies on the selective extraction of copper from enargite- bearing copper ores and concentrates are much needed to improve copper recovery.

Jan 1, 2019

By H. Huang, H. M. Chen, W. B. Xie

Cu-0.8Cr-0.1Zr alloy were prepared by atmospheric melting. the microstructure and properties of the CuCrZr alloy after first cold rolled, solid solution, second cold rolled and aging treatment were analyzed by using optical microscope, electrical conductivity analysis and Vickers hardness tester. The results show that with the increase of the first cold rolled deformation, the grain breakage becomes more serious, and the cold hardening becomes more obvious and the hardness increases. The conductivity and peak hardness of the first cold rolled (reduction of 30% and 60%) alloys after solution, secondary cold rolled and aging treatment reaches 81 %IACS and 187 HV, respectively. However, the conductivity in the CuCrZr alloy with a higher rolling degree (reduction of 90%) after solution, secondary cold rolling and aging treatment is significantly higher, and the conductivity and peak hardness is 85.8 %IACS and 178 HV, respectively. INTRODUCTION CuCrZr alloy has been widely used in domestic industry for its excellent comprehensive properties such as high strength and high conductivity, especially in the contact wire and lead frame of high-speed railway (Sun, Tao, & Lu, 2015; Mishnev, Shakhova, Belyakov, & Kaibyshev, 2015; Zhang et al., 2016; Fu et al., 2017). In recent years, a lot of research has been done on how to improve the strength and conductivity of CuCrZr alloy. However, the high strength and high conductivity of copper alloys are contradictory characteristics. On the one hand, the addition of alloying elements is conducive to solution strengthening and aging strengthening; on the other hand, too much alloying elements in copper alloys cause defects in the lattice of copper matrix, resulting in a serious decline in the conductivity of copper alloys (Martienssen & Walirmont, 2005). How to obtain high strength and high conductivity at the same time is the main problem. At present, the main research methods are adding microalloying elements, thermomechanical treatment and severe plastic deformation to study the electrical conductivity and mechanical properties of CuCrZr alloys. For example, Xie et al. (2011) added trace Ag to the Cu-0.26 wt%Cr-0.08 wt%Zr alloy, and the size of precipitated phase Cr and Cu4Zr became smaller and the mechanical properties of the alloy were improved. Su, Dong, Liu, Li, & Kang (2004) found that the addition of trace Mg in CuCrZr alloy inhibits the growth of precipitated phase and reduces the internal stress around the precipitated phase. At the same time, the size of precipitated phase becomes smaller and the peak aging strength of the alloy is improved. Pang et al. (2013) found that adding trace Ni and Si to the CuCrZr alloy could improve the peak hardness, softening resistance and precipitation morphology of the alloy. Experiments shows that the grain size was significantly refined by equal channel angular extrusion combined with aging treatment, while the strength of the alloy was increased, and the electrical conductivity of the alloy did not decrease (Vinogradov, Patlan, Suzuki, Kitagawa, & Kopylov, 2002; Saray, 2016); Kermajani, Raygan, Hanayi, & Ghaffari (2013) showed that the strength of CuCrZr alloy can be improved by rolling at 500 °C. After 150 minutes of aging treatment, the strength and conductivity of the material increased to 431 MPa and 81 %IACS, respectively. Takata, Ohtake, Kita, Kitagawa, and Tsuji (2009) noted that the strain hardening, uniform elongation and tensile strength of the nano-precipitates produced by the mechanical heat treatment process can be notable enhanced. The mechanical and electrical properties of CuCrZr alloy can be improved by combining large plastic deformation with aging treatment in the test process (Gao, Huttunen-Saarivirta, Tiainen, & Hemmila, 2003; Huang et al., 2003; Xia et al., 2012; Zel’dovich et al., 2014).

Jan 1, 2019