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By Ltd Changsha Research Institute of Mining and Metallurgy Co., Shi Yunliang, Luo Yunbo, Chen Jun, Liu Miaohua, Xiao Jinxiong, Long Yan

"A refractory lead-zinc oxide ore located in Yunnan has hundreds of tons of metal reserves, which is hard to be recovered effectively by conventional oxide ore beneficiation methods. In this study, by sulfidation roasting of raw-ore, sulfide deposit is formed on the surface of the lead-zinc oxide ore, and then the roasted ore is processed with bulk flotation. The test results indicate that a bulk concentrate with grade of 7.85% lead and 34.24% zinc, recovery of 79.13% lead and 79.04% zinc, respectively, can be obtained by using conventional sulfide ore flotation method.The sulfidation process shows that pyrite in the raw ore releases S firstly, then S reacts with PbO and ZnO to transform into PbS and ZnS. When the mole ratio of sulphur:zinc is 0.59, the surface of smithsonite is covered with a layer of zinc sulfide. When the mole ratio of sulfu:zinc rate is 1.47, entire simthsonite particle is transformed into zinc sulphide. Thus the transformed particles can be recovered by flotation without complete sulfidation.INTRODUCTIONWith the increasing demand for zinc and decreasing of zinc resources, people pay more attention on development and utilization of zinc oxide ore. However, zinc oxide ore has wide range mineral kinds, complex mineral composition, disseminated fine-grained particle size, and high content soluble salt, so current study results about the zinc oxide ore with conventional flotation are not satisfactory. So far, process dealing with zinc oxide ore includes: sulfuration (Na2S)-flotation, direct flotation with fatty acids collectors, metallurgical methods, in which sulfuration flotation is the most widely used method. The basic principle of sulfuration flotation method is firstly roasting oxide ore with vulcanizing agent, and then recovering the sulfurated oxide ore with flotation, which is similar with recovering nature sulfide ore by using conventional collectors such as amines and xanthate."

Jan 1, 2016

By S. N. Aliferova, E. I. Afonina, S. N. Titkov, A. Ju. Bondareva, N. N. Panteleeva

"Potash ore is mainly processed using the method of cationic flotation. Potash ore deposits of the CIS, namely: at Upper Kama river, Gremyachinsk (Russia), Starobin (Belarus), Tubegatan (Uzbekistan) are characterized by relatively low KCl impregnation (1.0 – 1.5 mm) and contain up to 10% of waterinsoluble impurities (WII). Water-insoluble impurities are presented by aluminosilicate, silicate, carbonate (calcite, dolomite) minerals and anhydrite. In the process of milling the ore to a flotation size there are released and dispersed the insolubles impurities actively sorbing the cationic collector, i.e. aliphatic amines C16 – C22. In this regard there is carried out a preliminary desliming of the ore.Currently grinding the ore to a flotation size (1.5 mm or less) is carried out in rod mills along with forming of a large number of fine-grained ore fractions having the size under 0.25 mm, which results in the increased KCl losses with halite slime waste and reduction in the quality of finished product. There has been developed the technique for processing of potash ores with a high content of water-insoluble impurities (10 – 12%) containing, in different ratios, silicates, carbonates and anhydrite. The technology involves the use of the ore dry grinding to the flotation size and subsequent reagent activation of the processes for sludge removal and sylvite flotation.INTRODUCTIONCurrently there are being developed the potash ore deposits in the CIS countries, namely: at Upper Kama river and Gremyachinsk deposits (Russian Federation), Starobin deposit (Republic of Belarus) and Tubegatan deposit (Uzbekistan). Potash ores are a mixture of sylvite and halite and contain water-insoluble impurities of silicates, carbonates and anhydrite. The content of water-insoluble impurities (WII) reaches up to 10%, disseminated (impregnated) sylvite does not exceed 1.5 mm and in connection with that the ore is crushed to a particle size under 1.5 mm. Ore grinding is performed by wet process in rod mills with producing a significant amount of fine-grained mineral fractions and sludge, which are actively sorbing a cationic collector, i. e. primary aliphatic amines C16 - C22. The ground ore is deslimed and the slime product is directed to a sludge depot (pits)."

Jan 1, 2016

By P. Hajiani

"It has been shown that the economics of the hydrometallurgy of a rare earth process depend upon the amount of acid needed to extract the metal per unit mass of the ore. In this paper, we show how to save a significant amount of acid treating a low grade ferrocarbonatite and extracting +99% constituent REEs. In order to save the acid, the alkali earth metals, originated from gangue minerals were removed prior to REE leaching. Moreover, the operating conditions of leaching reactor are optimized to leave iron behind and to leach REE selectively and effectively. Consequently, the hydrochloric acid consumption per ton of ore drops significantly compared to other processes.INTRODUCTIONThe viability of an extractive metallurgy process of rare earth elements (REEs) to produce an intermediate mixed concentrate depends upon a low-cost simple flowsheet (Bogner, 2014). It has been known that regardless of the mineral, the acid consumption is intimately associated with the operational cost (OPEX) of any REE project, particularly when the initial REE grade is low. Besides acid, the other reagents consumed in the process impact the OPEX. This makes minimizing acid consumption in an REE method a critical priority. The acid consumption in different projects has been reported to be equivalent of 100 kg to 1000 kg HCl (100%) per tonne of ore (Average: 500 kg/t HCl 100%) (Bogner, 2014). This value is strongly correlated with the grade of REE in the ore and therefore in the pre-concentrate.Previously, it has been stated that the Montviel flotation concentrate requires about 300 kg HCl (100%)/t ore to attain +99% REE recoveries using direct leaching (Yu, Verbaan, Pearse and Britt 2013). Hence, for an ore feed rate of 2500 t/d ROM, a large acid production plant (744 t/d HCl 100%) would be required for acid leaching of such concentrate. The equivalent Chlor-alkali plant is estimated to cost M$ 150 (CAPEX) and may require 100 MW power. Therefore, there is a necessity to improve the extractive hydrometallurgy and to reduce the acid consumption significantly."

Jan 1, 2016

By M. W. Gilmore, J. Ndlovu, T. Sepoloane, Anglo American Platinum, L. R. Nelson, R. N. Varty, L. J. Bryson, B. Peyper, J. P. Hagemann

"As part of Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) expansion, a new Nickel Electrowinning Tank House, with a nameplate capacity of 32 400 tons per annum, was constructed. Commissioning of the new electrowinning technology, which involved world first full deposit plating, commenced in 2011.The old nickel electrowinning process at the RBMR used starter sheets which, along with a divided cell configuration, was very labour intensive and exposed operators to high levels of aerosols that contained both nickel and acid. To overcome this problem two key design intents of the new technology are aerosol abatement and minimising labour in the electrowinning cell environment, with a design target to reduce the nickel occupational exposure limit (OEL) to half the legislated limit of 0.1 mg.m-3.Commissioning of the new technologies adopted to achieve mist abatement is described, together with a review of technical and operational challenges relating to the titanium blank edge strips, blank roughness and sandblasting optimisation, blank quality control, electrode spacing, polyconcrete cell dimensional stability and cell top furniture. The impact of these on process performance is presented and the development of fault checking and rectification methods, to maintain high process performance, is explained.INTRODUCTIONThe expansion of Anglo American Platinum’s Rustenburg Base Metals Refinery necessitated the construction of a new Nickel Tank House to achieve two primary objectives, namely increasing the nickel electrowinning capacity from 22 500 tons per annum (tpa) to 32 400 tpa nickel, and a design to reduce the nickel aerosols to 0.05 mg.m-3 as a time weighted average over 8 hours, which is half of the legislated occupational exposure limit (OEL) of 0.1 mg.m-3."

Jan 1, 2016

By Mohamad Sabsabi, André Hamel, André Moreau, Paul Bouchard

"Laser-Induced Breakdown Spectroscopy (LIBS) is an atomic spectroscopy technique used to measure elemental concentrations. It is well-adapted to in-situ and in-line measurements during materials processing in general, and pyrometallurgy in particular. It is an optical non-contact technique and it can measure nearly all elements, including light elements. Our group has developed a mobile prototype system to measure molten metals. The system includes a tube, also called a lance, one end of which is immersed in the molten metal. An inert gas flows in the tube and bubbles out below the surface. The LIBS measurement is made through the tube and onto the bubble’s surface. This is done to avoid measuring contaminants, slag, or fluxes often found at the surface of the melt. An added benefit is that the molten surface is constantly renewed and thus, more representative of the bulk. An alternative to using our lance is to use a tuyère, such as a gas injection tuyère in a converter, as we did several years ago in a nickel matte converter. In this presentation, we will show various applications emphasizing more recent developments. This includes the simultaneous measurement of the concentrations of Cu, Ni, Fe, Co and S in molten matte at 1125 °C. The more obvious industrial applications of the technology include determining the best time to end oxygen blowing in the converter and elemental concentration measurement during alloying.INTRODUCTIONThe mining industry continually faces challenges in optimizing cost and productivity. Because of the large volumes of materials that are being processed, small improvement can have a big impact on benefits. Better real-time information can help improve this optimization."

Jan 1, 2016

By Akiyoshi Horiuchi, Manabu Kanno, Shigeki Sato, Taro Aichi

"AKITA ZINC Co., Ltd. (Iijima Zinc Refinery), jointly owned by DOWA METALS & MINING Co., Ltd.(DMM), has used the company’s own hematite process for iron control since the beginning of operations in 1971. The hematite process consists of reductive leaching with SO2 gas and iron removal in autoclaves by high temperature hydrolysis. This process enhances not only zinc recovery but also the recovery of gold, silver, copper, lead and rare metals, which is carried out at another DOWA metallurgical plant. All by-products produced in the hematite process are marketed and sold. This paper presents an overview of the hematite process and the recent process improvements made.INTRODUCTION DMM carries out mining and smelting activities for precious metals, PGMs, rare metals and base metals such as copper, lead and zinc. It owns KOSAKA SMELTING & REFINING, producing copper and lead, and the AKITA ZINC Co., Ltd. (AZC) in Akita Prefecture. DOWA is a specialized smelting company which has established a metallurgical complex for copper, lead and zinc, including a recycling business. AZC was established in 1971 at a production capacity of 72,000 t/y zinc; it is jointly owned by DMM and five other non-ferrous metal companies. AZC has increased its capacity continuously and now produces 210,000 t/y of zinc. Figure 1 shows the changes in zinc production and capacity at AZC."

Jan 1, 2016

By Georges Houlachi, Raynald Labrecque, Jean-Noël Cloutier

"Electrodialysis (ED) is an electro-membrane technology based on electrochemical process using electrical energy for the production of chemicals. The process can be used for concentrating, extracting, separating products, modifying molecules, purifying solutions, pH adjustment and regenerating salts into their base and acid. This paper reviews the principle of ED, present some of the different options and discuss applications that are relevant to the hydrometallurgy and mining industries for the treatment of effluents focusing on recovery of chemicals (acid and metals) and recycling of water minimizing the environmental footprint.INTRODUCTIONElectrodialysis (ED) is usually defined as an electrochemical separation process in which electrically charged membranes and an electrical potential difference are used to separate ionic species from an aqueous solution and other uncharged components [1]. ED technology consists of an electro-membrane technology based on an electrochemical process using electrical energy for the production of chemicals. It is a method combining electrolysis and dialysis was proposed for the first time in 1890 by Maigrot and Sabates [2]. In the late 1930s Teorell, Meyer and Sievers discussed membrane phenomena, revealed membrane potential, electric conductivity, transport number [3]. Meyers and Strauss introduced a multi-compartment ED apparatus consisting of two electrodes and a stack of ion-exchange membranes between them [1]. They succeeded to double the concentration of a KCL solution [3- Tarleton]. In general, ED consumes less energy than electrolysis to perform salt splitting. In that regard, one can expect an energy reduction of about 30% [4–5]. ED offers a great versatility in the domain of separation processes. Indeed, it can be used for concentrating, extracting, separating products, purifying by desalination, pH adjustment and regenerating a salt to acid and base components. This paper reviews the principle of ED, presents various options available and discusses potential applications relevant to the mining and metallurgy industries with economics of some successful industrial applications."

Jan 1, 2016

By Q. Shi, Q. Feng

"The influence mechanism of chlorite on the flotation of pyrrhotite was investigated through flotation tests, Zeta potential measurements, optical microscope photos, solution ion measurements and absorption measurements. It is observed that, the addition of chlorite influences the flotation of pyrrhotite seriously. The IEP (isoelectric point) of pyrrhotite and chlorite is 7.6 and 4.3 respectively, in the condition of slight alkalinity, both pyrrhotite and chlorite are negatively charged, and the hetero-aggregation will not occur. With the existence of oxygen in solution, the iron ions are dissolved from pyrrhotite surface because of the oxidation of pyrrhotite during pulp conditioning. The dissolved iron ions adsorb onto the surface of chlorite in the forms of iron hydroxyl and iron hydroxide, and the adsorption results in the opposite charge of chlorite surface. As a result, the hetero-aggregation between pyrrhotite and chlorite occurs. The adsorption of chlorite changes the surface property of pyrrhotite and restricts the adsorption of amyl xanthate onto pyrrhotite surface, and then decreases the flotability of pyrrhotite.INTRODUCTIONIn sulfide ores processing, magnesium silicate bearing gangue minerals often report to the concentrate causing downstream processing problems as well as increased smelting costs. Talc,chlorite and serpentine are gangue minerals commonly encountered in complex sulfide ores (Engel, Middlebrook, & Jameson, 1997; Pietrobon et al., 1997; Witney & Yan, 1997; Chen, Grano, Sobieraj, & Ralston, 1999a, 1999b; Bremmell, Fornasiero & Ralston, 2005; Senior & Thomas, 2005; Wang, Somasundaran, & Nagaraj, 2005; WieseHarris & Bradshaw, 2007). All of them are characterized with uniform crystal structures consisting of silicon-oxygen tetrahedron and magnesium-oxygen octahedron. The magnesium-oxygen octahedron layers are broken during the liberation of serpentine to expose the magnesium-oxygen bonds with strong ionicity and hydration, which results in natural hydrophilicity of serpentine. In water, the hydroxyl on serpentine surface ruptures and dissolves into the aqueous phase while the Mg2+ remains, resulting in surface positive charge (Tao, 2012). As serpentine has a positive potential at alkaline condition, it is therefore likely that it will attach through electrostatic attraction to the negatively charged mineral surface and reduce both the flotation rate and recovery of target minerals (Lu et al., 2011). For talc, characterized as good natural hydrophobicity, the liberation comes from the interlaminar fracture to remain molecular bonds on surface with weak hydration. Being naturally hydrophobic, talc easily reports to flotation concentrates, thus reducing concentrate grade (Shortridge, Harris, Bradshaw, & Koopal, 2000; Beattie, Huynh, Kaggwa, & Ralston, 2006). Meanwhile, both molecular bonds and magnesium-oxygen bonds are exposed on chlorite surface when liberation occurs, resulting in moderate natural hydrophobicity between serpentine and talc (Tao, 2012). And thus the mechanisms of influence of chlorite on sulfide ores are more difficult to study."

Jan 1, 2016

By Longjiang Li, Song Mao, Zhengyang Qiao, Qin Zhang, Guizhou University, Ling Wang

"After a study on the advantages and disadvantages of flotation column, according to the limitation of ordinary flotation column only is used for a flotation of microgranular minerals, the paper designed a new kind of layered convection coarse particle flotation column.Using a bauxite to test the rationality of the flotation column.The test results show that the new layered convection coarse particle flotation column is feasible.It has certain advantages about coarse particles flotation.INTRODUCTIONFlotation column has many advantages, for example,a simple structure, high efficiency and energy saving, the obvious advantage of fine particles flotation , the index superior and so on. The advantages gradually getting people's recognition. Research of flotation column has been a breakthrough, however, due to it only is used for the flotation of microgranular minerals, and the microgranular mineral particles will lead to a series of problems, and makes the processing cost is increased. Due to increase grinding fineness can save the grinding time and reduce the cost of grinding, also can avoid the disadvantage of fairly granular mineral particles cause a deterioration in the flotation. So it is necessary to research a kind of coarse particle flotation column.After a research on the advantages and disadvantages of flotation column, the authors designed and manufactured a new layered convection coarse particle flotation column, the flotation column both in theory and operation is better than flotation machine.DESIGN OF THE LAYERED CONVECTION COARSE PARTICLE FLOTATION COLUMNAdvantages and Disadvantages of the Traditional Flotation ColumnIn the field of mineral processing, as the increasing proportion of ore that has low grade, fine dissemination size, complex mineral composition characteristics. The limitations of traditional flotation machine is increasing[1],for instance, the high energy consumption, severe wear, inconvenient configuration , large amount of maintenance and so on. Compared with flotation machine, the flotation column with high separation efficiency, low investment and production cost, covers a less area low installation cost, less reagent dosage, more suitable for separation of fine particles and can automatically control, etc[2]. At present, the ore is facing the world energy crisis situation, and becoming increasingly difficult to flotation. So it is important to invent a coarse particle flotation column."

Jan 1, 2016

By B. MohammadSadeghi, S. Bakhshivash, M. Haghshenas, F. Rahimi

"Spring-Back/Forward in sheet metals is defined as recovery of elastic strain upon unloading in a deformed sheet specimen. Since this phenomenon can cause alternation in the dimensions of a part, leading to irrecoverable compensations, the operative parameters need to be investigated, thoroughly. To assess spring-forward and effective bending parameters, V-shaped bending dies are the most commonly used experimental approach. In the present research, the effect of bending angle and punch tip radius on the spring-forward behavior of an Al-Mg-Si alloy sheet specimen is studied. To this end, a V-shaped die with four bending angles (i.e. 30°, 45°, 60°, and 90°) was designed and fabricated. Specimens with thickness of 2 mm were cut with dimensions of 50 mm×10 mm. Results show that by increasing the bending angle, the spring-forward angle decreases. In addition, smaller punch tip radiuses lead to further spring-forward. The effect of these parameters on the amount of spring-forward angle, strain distribution and homogeneity along sheet thickness was assessed using finite element analysis (FEA). Simulation results show that as the bending angle increases, the strain is developed more homogenously. Finally, micro-hardness test was used to study the effect of strain hardening caused by bending operation on strength evolution. Results show higher hardness trends for the zones in which the maximum plastic strain occurs.INTRODUCTIONPrecise production plays a significant role in the durability of a part. When it comes to sheet metal forming, this issue should be taken into account as an important factor. In order to predict the alternations, bending dies with special geometric parameters (i.e. V-shaped, U-shaped and L-shaped dies) are commonly used (Wagoner, Lim, & Lee, 2013)."

Jan 1, 2016

By Douglas Brand

"The data that many mineral processing plants make use of, is provided by samples taken from sampling systems which are inadequately designed or improperly maintained, and therefore cause detrimental effects to plant operations, production planning and metallurgical accounting! Poorly designed or maintained sampling systems will likely produce low probability samples which give the operator a false sense of security of the product and the process. If data is the basis for action (Flintoff, 1992, p.2), then using the resulting suspect or bad assays by operators, control systems, or metallurgist and administration personnel will act and make decisions which may adversely affect the profitability of a processing plant. Here we will discuss some of the fundamental sampling problems, propagation of errors and a method to estimate what impact this has on an operations Net Smelter Return.INTRODUCTIONIn order to control a mineral processing plant at its best potential, it is necessary to obtain the best possible measurement results of the metal or mineral in question. The sample which is delivered to a measuring instrument, or lab, needs to be of the highest probability to be able to achieve this. This paper will discuss the effects of sampling errors on grade / recovery and grade / Net Smelter Return (NSR) and provide a method to estimate the monetary advantages of using probabilistic sampling in a processing plant.REVIEW OF SAMPLINGSampling, by definition, is the removal of a small representative portion from a total consignment, or flow, for the purpose of accounting or process control.• A sample can only be considered representative, if each and every increment collected, in each of the sampling stages, is representative.• Each particle of the sampling lot must have the same probability of being included in the final sample.• If both of the above conditions are met, then the final sample will be representative of the complete sampling lot.It is commonly known that in order to take truly representative and probabilistic sample, best practices indicate that:• The total stream should be sampled.• The sample cutter should intersect the sample at right angles to the flow.• The sample cutter should travel through the stream at a linear and constant speed and the speed deviations should be less than 5%."

Jan 1, 2016

By L. Vinnett, I. Panire, J. Yianatos, F. Ruiz

"The effect of operating variables on the flotation performance at steady-state has been extensively used for modelling and simulation of separation processes. However, the dynamic characterization of key variables such as gas dispersion (Sauter mean diameter of bubbles, D32, and bubble surface area flux, SB) and froth discharge rate is rather scarce. In this paper, an experimental design allowed identifying the dynamic response of the flotation process in a laboratory scale flotation cell, using a two-phase system, airwater. The installation included automatic control for the superficial gas rate, JG, and the pulp level. Gas dispersion was evaluated in terms of the Sauter mean diameter of a bubble population and the bubble surface area flux, SB = 6·JG/D32. The D32 was measured using the McGill Bubble Size Analyzer (MBSA) along with a semiautomated algorithm. In addition, the froth discharge velocity was measured in real-time using a Visiofroth system. The control variables were the superficial gas rate and the frother concentration (Teefroth). The dynamic characterization of the flotation process is useful to design algorithms that allow the direct or indirect control of metallurgical variables such as flotation rate, concentrate grade and mineral recovery.INTRODUCTIONGas dispersion indicates the way the gas entering a flotation machine is dispersed throughout the volume of the equipment (Schwarz & Alexander, 2006). The gas dispersion is typically characterized in terms of the bubble size (dB), gas holdup (eG), superficial gas rate (JG), and bubble surface area flux (SB =6·JG/dB) (Finch et al., 2000). All these variables have significant impact on the metallurgical performance of flotation machines. For example, Perez-Garibay et al. (2014) investigated the effect of the particle size, bubble size distribution, superficial gas rate and collector dosage on the flotation performance, for the separation of a sphalerite mineral. The authors observed that recovery increased with the superficial gas rate ranging from JG = 0.04 to JG = 0.08 cm/s and also a maximum recovery was obtained for bubble size close to 300 µm. Gorain et al. (1998) reported a strong correlation between the flotation rate constant and the bubble surface area flux in a zinc cleaner circuit. Both variables were directly proportional at three froth depths in the range of hF =7 - 45 cm. Dobby & Finch (1986) incorporated the effect of the superficial gas rate and the bubble size on the flotation efficiency by means of a kinetic model for the rate constants. Yianatos & Contreras (2010) developed a model to estimate the carrying capacity in large flotation cells by including the bubble surface area flux."

Jan 1, 2016

By Bahjat Khoshaba, Bern Klein, Haixing Yan, Libin Tong, Andrew Bamber

"When a conductive or magnetic particle was put into an electromagnetic field introduced by an electromagnetic sensor, the particle can influence the electromagnetic field which can be used to characterize this particle. The electromagnetic technology based on eddy current theory was explored to investigate its potential in both the separation of minerals and the pre-concentration of a base metal ore. Samples tested in the study included the minerals obtained from Ward’s Science and the low grade copper ore particles obtained from Mount Polley Mine. The effects of mineral type, sensor frequency, particle size, particle position on the sensor surface, and particle lift-off on the magnitude and phase of the electromagnetic spectra were investigated. The electromagnetic spectra of various minerals show that it is possible to separate chalcopyrite or magnetite from tested minerals, simply based on the magnitude of the spectra. The spectra of the ore particles were determined by the mineral in the particles with the strongest signal. The effect of the pre-concentration of the low grade copper ore is determined by the association of chalcopyrite with magnetite. Direct sorting is the mechanism in the separation of mineral particles, while indirect sorting is the mechanism for low grade ores.INTRODUCTIONSensor-based sorting technologies include radiometric, X-ray transmission, X-ray fluorescence, near infrared, photometric, inductive, microwave heating and so on. Sorting not only discards barren rocks away from the concentrator but also recovers metal bearing that would be lose to the waste dump. The benefits of pre-concentration using sensor-based sorting are achieved on reduced energy consumption for comminution and reduced water usage on a volume per weight of metal basis (Bamber, 2008; Gunson, Klein, Veiga, & Dunbar, 2012; Kleine & Wotruba, 2010; Knapp, Neubert, Schropp, & Wotruba, 2014; Kobzev, 2014; Lessard, de Bakker, & McHugh, 2014; Mazhary & Klein, 2015; Robben, Wotruba, Robben, von Ketelhodt, & Kowalzcyk, 2013). Amongst others, high frequency electromagnetic sensors were developed for ore sorting at MineSense Technologies Ltd. and are subject of this paper. Improving the understanding of ore heterogeneity is the basis for developing a successful semi-bulk or bulk sorting systems by incorporating the sensors in the material handling equipment (MineSense Technologies Ltd., 2016). The present study focuses on the bulk sorting potential and bulk sorting mechanisms of the electromagnetic technology in the pre-concentration of minerals or ores."

Jan 1, 2016

By Eric Poulin, Anthony Clapperton, Jocelyn Bouchard, Jaime Cristobal Rojas-Montes, Benjamin Legare

"Several grinding mill dynamic simulators have been developed in the last half-century. However, complete circuit simulations are mainly limited to academic investigations, and on-site applications for advanced control or real-time optimization are scarce. One particular issue that has certainly curbed a more widespread use is the time and efforts required for model calibration. This paper illustrates this challenge and presents a calibration method based on dynamic simulation using industrial data and laboratory testwork. The simulator models discussed originate from the work of Austin and Luckie (1972) for grinding mills, and Plitt (1976) for hydrocyclones. A two-stage approach based on a least squares minimization allows determining calibration parameters values. Firstly, laboratory testwork are required for characterizing breakage coefficients of the ore. Secondly, step change responses and their simulation— effect of ore and water feed rates on output flow rates and size distributions—allows identifying transport/mixing conditions. Simulation results are in agreement with actual process responses to variations of feed conditions obtained from a plant survey.INTRODUCTIONDynamic models for grinding circuits has been intensively studied since the 1970's notably by Austin and Luckie (1972b), Klimpel and Austin (1984), Rogovin and Hogg (1988), Napier-Munn et al. (1996), Liu and Spencer (2004), and King (2012) among others. The resulting models primarily serve in simulation applications for process equipment sizing, which incidentally also helps developing a better understanding of comminution operations. An obstacle curbing a more widespread and targeted use of grinding simulation for process control and optimization purposes is the time and efforts required for dynamic model calibration. It remains a cumbersome task that is typically not well detailed in technical papers. This could explain why dynamic process simulators are mainly confined to academic applications."

Jan 1, 2016

By R. G. McDonald

"High iron solution concentrations often result in the formation of basic ferric sulfate during the high temperature oxidation of sulfidic materials such as base metal and refractory gold concentrates. Consequently, the “Hot Cure Process” followed by limestone neutralization is required to facilitate subsequent processing and/or disposal of the leach residue. The present paper discusses strategies that can be employed to influence the composition and nature of the high-iron content leach residues produced during pressure leaching.INTRODUCTION Control of iron deportment in hydrometallurgical processing remains a key challenge for a range of reasons. Strategies generally relate to the control of conditions under which iron is optimally rejected (Demopoulos, 2009). Supersaturation provides the driving force for crystallization and this can be controlled by a number of factors that include (1) pH and/or Eh control, (2) the presence of matrix anions and impurities, (3) dilution, (4) complexation and dissociation and (5) manipulation of the rate at which the metal to be precipitated is released to solution. Each of these factors is impacted by temperature. Good control of crystallization is essential to the control of precipitate properties such as the degree of crystallinity, stability, particle size and quality which covers both the extent of impurity uptake and suitability of the precipitate for waste disposal. The quality and properties of iron precipitates in turn can impact downstream processing. It is the aim of this paper to discuss the generation of iron-containing residues produced during the pressure oxidation of sulfidic ores and concentrates and how the nature of these can be controlled to potentially facilitate further processing. A brief overview of several related topics will now be given and include, where relevant, discussion of work undertaken in our laboratories. In addition, brief discussions of selected process options that enable good control of iron rejection will be provided."

Jan 1, 2016

By G. Deschênes

"In 2013, as the prices of precious metals dropped, investors moved their positions to equity markets for higher returns. As a result, the price of gold dropped further to below US$1200 per ounce, prompting additional substantial outflows from gold investments. In response to lagging gold prices, major gold producers initiated large asset write-downs and cost-cutting programmes. In 2015, this trend continues and gold mining stocks are close to lows not seen since the global financial crisis (GFC) of 2008. In the current economic climate many projects have marginal economics, and the number of projects that have competitive development and production costs is declining. A competitive edge is particularly important with the decreasing grades of orebodies, increasing complexity of the mineralogy, and increasingly demanding environmental constraints. In addition, higher cost producers seek to optimize their process t o reduce operating costs.This paper presents some highlights of three case studies on optimization of gold leaching strategies that improved the economics of brownfield projects. Processing of sulphide-bearing ores was optimized by using the synergy between cyanide, lead nitrate, and oxygen. The outcomes were significant reduction of retention times while maintaining or increasing gold extraction and reducing cyanide addition and effluent treatment costs. A stirred tank reactor experimental programme led to direct implementation of reliable leaching strategies from laboratory scale to production. This approach resulted in savings of $2.2 million to $15.2 million on the three brownfield projects discussed in this paper."

Jan 1, 2016

By Robert S. MacPhail, Chilombo Henry, Arnold Kabamba, David Mukelebai, Suresh Thirunagari, Bukali Victor, Yoram Kapai, Chomba Leonard, Kanna Amarasingham

"FLEX 31 is a chemically enhanced sodium isopropyl xanthate. Developed by Charles Tennant & Co (Canada) Ltd and has shown improved collection properties over SIPX for sulphide minerals flotation. Improvement of recoveries, grades, faster kinetics, lower dosages, high pyrite and pyrrhotite rejection capabilities have all been exhibited by FLEX 31. Recent plant trial carried out in the copper circuit at one of the largest copper mine in Zambia shown over US $ 2.00 Million annual improvement on the bottom line over SIPX at current copper prices. Data produced also showed superior grade and recoveries from rougher concentrates that previously had not been attainable with other reagents effectively. Flex 31 has also shown positive outcomes with zinc, Copper/Zinc, arsenopyrite and copper/molybdenum ores.IntroductionSodium Isopropyl Xanthate (SIPX) is one of the most popular flotation chemicals on the market today. Somewhat more specific than amyl xanthate, SIPX is used in a variety of ores like copper/zinc, lead/zinc, arsenopyrite/pyrite, and many others (Melis et al., 1991). An investigation carried out by the research division of Charles Tennant & Company (Canada) Limited has produced a chemically enhanced SIPX. This product has shown all the advantages of normal SIPX along with improved recoveries of copper and copper activated minerals. The product was named “FLEX 31”."

Jan 1, 2016

By G. Danha, D. Glasser, D. Hildebrandt, N. Hlabangana

"In this work, we apply a method known as the attainable region (AR) technique in order to optimize the milling and leaching process of a low grade gold ore. No work on the application of the AR optimization technique has been done yet on a joint milling and leaching process. The advantage of the AR approach lies in its ability to simplify the optimization problem, as searching over a defined set for the maximum of an objective function is a fairly standard procedure. The objective function we selected was that of optimizing a linear function of the value of the recovered material minus the cost of both milling and leaching. Using the three variables (milling time, leaching time and recovery), we constructed a 3D plot and used it to obtain all the possible recoveries from the different milling and leaching times. The optimum for our chosen objective was then found by overlaying a contour plot of the objective function on the 3D plot. Our results show that the optimum was obtained at 90 % recovery with a profit value of 600, milling time of 30 minutes and leaching time of 1750 minutes.INTRODUCTIONAfrican countries are facing a general increase in demand for electrical power. In South Africa, the demand is now surpassing the supply from ESKOM, the main electric power provider of the country. This has resulted in load shedding strategies being implemented in many local communities in an attempt by ESKOM to cope with the high demand. A potentially better approach is to propose use of energy efficient technologies in the country’s largest power consuming industry; the mineral processing sector.In mineral processing, milling is the highest consumer of energy. The objective of carrying out milling is not merely to reduce the particle size of the feed material, but also to liberate the constituent minerals that make up an ore. This is done so that valuable minerals can be separated from the gangue, in downstream processes, such as leaching. However, the milling process is generally performed relatively poorly, and at a considerable expense in terms of electrical power utilization. Tomanec and Milovanovic (1994) estimated that milling accounts for more than 50 % of the total power used in the concentration process, but this can rise to as high as 70 % for hard or finely dispersed and inter-grown ores. Apart from being relatively wasteful of energy, the milling process is also inefficient with regard to mineral liberation because of the indiscriminate nature of the grinding force."

Jan 1, 2016

By J. Karonen, M. Tiihonen, J. Guentner, L. Haavanlammi, Outotec GmbH, E. Kolehmainen

"Rare earth elements have obtained significant attention during the last few years due to predicted increase in their demand. Several projects worldwide are at pre-feasibility or feasibility stage aiming to commence production. Deposits of rare earth elements are typically complex and multi-metallic of nature. This means that production processes are often also complex and therefore, various metallurgical unit processes are needed. Outotec’s equipment and technology portfolio is very comprehensive and includes hydrometallurgical and pyrometallurgical apparatus and processes applicable to the efficient exploitation of rare earth deposits. Outotec has gained useful experience relevant to the processing of rare earths through several assignments including those for Alkane Resources Ltd. (Dubbo Zirconia Project), Greenland Minerals and Energy Ltd (Kvanefjeld Project), Frontier Rare Earths Limited (Zandkopsdrift project), Tantalus Rare Earths AG (Madagascar), Quest Rare Metals (Strange Lake project) and Orbite Aluminae Inc. (HPA project). The hydrometallurgical test work of two process flowsheets is presented in the paper. A roasting or acid baking step is common to several proposed rare earth projects. In the past, rotary kilns have been used, but Outotec has developed a new process concept to handle the rare earth material in fluid bed reactors. The basis for this development is long experience in fluid bed technology of Outotec in Germany. One advantage of fluid bed roasting is the higher throughput per unit. In combination with the roasting and baking, Outotec offers the gas cleaning and acid plant and provides a complete and closed concept.INTRODUCTIONRecovery of rare earth elements (REE) has obtained significant attention during recent years. It has been estimated that their demand will be boosted because of their need in many technology areas. REE can be utilized in magnets, batteries, displays, catalysts, optical devices etc. (Jordens, Cheng, & Waters, 2013; Zhang & Edwards, 2013). The production of REE is focused in China, which means that production outside of China is very scarce. However, there are multiple active development projects worldwide working towards production of REE containing products outside of China (Chen, 2011)."

Jan 1, 2016

By M. Melashvili

"The SART Process was introduced to the gold mining industry in the late 1990s and several commercial plants were built over the following 10 to 15 years. Most of these plants have operated well and enjoyed plant performance in line with expectations based on the underlying chemistry of the process. However, two of the plants have consistently suffered from high reagent consumption and poor product quality, which has motivated a re-examination of the process fundamentals in the hope of understanding the reasons for poor performance when it occurs, and developing mitigating strategies.This testwork along with a review of the relevant literature has demonstrated that the amount of sulphide added to the primary reactor, relative to the copper concentration, is the most critical parameter dictating plant performance, with pH and residence time important secondary factors. The primary product in the SART Process is synthetic chalcocite, Cu2S, and the stoichiometric requirement for sulphide addition is therefore 0.5 moles per mole of copper in solution. Testwork shows that when sulphide is added in excess of this amount (generally with the express purpose of lowering residual copper in solution) it not only fails in its intended purpose, but can have a negative impact on the settling and filtration characteristics of the copper sulphide product, as well as the final product quality. Moreover, these problems are exacerbated the higher the selected operating pH in the pH 3 to 5 range, and the longer the residence time of slurry in this pH range.Freshly precipitated copper sulphide compounds are known to be very fine and slimy, with poor settling and filtration characteristics. It is therefore important to engineer the SART Process in such a way as to encourage growth in the average particle size of the precipitate crystals. This was the rationale for recycling a portion of the thickener underflow to the primary reactor when the SART Process was developed. The theory of crystallization predicts that compounds of extremely low solubility, such as chalcocite (Cu2S: KSP = 10-48), are likely to experience growth in crystal particle size through aggregation rather than heterogeneous nucleation. On this basis, the SART practice of recycling a portion of thickener underflow to the primary reactor in the commercial plants is unlikely to lead to crystal growth via nucleation, and could in fact promote breakage of the aggregates that formed in the thickener. Recycling thickener underflow could therefore have the opposite of the desired outcome. The result of testwork that is reported here lends credence to this theory and questions the wisdom of recycling in the SART process.There is evidence to suggest that operating the copper sulphide thickener in the SART Process without flocculants may be beneficial. Thickener underflow densities could improve from the current 10 - 15% range to 40 - 50%. This will not only reduce the flowrate of slurry to the filter, but the filtration properties of the slurry (filtration rate, filter cake moisture content) will also improve. This is one of the most critical engineering and design aspects of the SART Process, and the achievement of high solids density in the thickener underflow will not only improve the health and safety aspects of the operation, but also has the potential to lower capital costs and improve the quality of the final product."

Jan 1, 2016