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By Georgy Cherkashov, Tamara Stepanova, Anna Firstova

INTRODUCTION High tellurium contents in the ancient volcanogenic massive sulfides (VMS) and modern seafloor massive sulfides (SMS) have been reported by V.Maslennikov (Maslennikov et al., 2013). However findings of tellurium minerals in SMS are rather rare. The only reported coloradoite and bi-melonite, have been found in massive sulfides from Rainbow hydrothermal field (Fouquet, 2010). Here we present data about Te - minerals in sulfide chimneys of different ages (up to 84.7 kyr - Cherkashov et al., 2010 ) from Semyenov-2 hydrothermal field. The obtained results The Semyenov hydrothermal cluster was discovered and studied in the course of cruises 30 and 32 of R/V Professor Logachev (2007 and 2009) at 13º31´ N, MAR. This area is associated with an oceanic core complex and associated with serpentinized gabbro- peridotites and basalts. Plagiogranites and tonalites have been dredged on seafloor in the Semyenov cluster area (Cherkashov et al., 2013; Pertsev et al., 2012). In total, 25 sulfides samples have been studied. The major and minor mineralogical phases were identified using reflected light microscope. Major element compositions of ore- forming minerals were analyzed on a Hitachi S3400N scanning electron microscope at the Geomodel Center, St. Petersburg State University (St. Petersburg, Russia) with an AzTec Energy 350 (EDX) detector and an INCA 500 (WDX) detector.

Jan 1, 2018

By Ian Selby

Resource management is a key factor in the operation of a successful marine aggregates business; it is integral to the development of sustainability, satisfying increasing commercial, quality, and environmental performance standards. Resource management is based on the combination of; (i) a thorough evaluation and understanding of the resources on the sea bed and (ii) a dredging plan targeted to permit the effective and efficient extraction of the resources whilst mitigating impacts and leaving the sea bed ready for recolonisation.

Jan 1, 2004

By Raymond A. Binns

Exploration for undersea polymetallic sulfide mineral resources with high economic potential would be more effective given an ability to predict sites with particularly high gold contents (averaging say > 10 ppm Au). Herzig et al (1993) addressed this issue shortly after recognition that deposits in the back-arc Lau Basin (average 3.8 ppm Au) were enriched in gold relative to mid-ocean ridge sites (average 1.2 ppm Au). Small but significant numbers of hydrothermal sites with massive sulfide deposits averaging >10 ppm Au have since been discovered. The principal genetic factors underlying gold enrichment include depositional processes at and below the seabed, and the source of gold. It is timely to consider whether resolution of their relative importance can be translated into practical criteria for exploration strategies focused on especially gold-rich deposits. Comparing the ?grade? of seafloor deposits using analyses cited in research papers is fraught with difficulty, but there is no alternative at present to assuming that such averages provide an initial tenor guide. On this basis, four known polymetallic hydrothermal sites from convergent plate margins fit the exceptional-gold category with >10 ppm ?average? Au, while one from a divergent margin comes close: Sunrise (Myojin Knolls; 20 ppm ?average? Au) and Suiyo Seamount (28 ppm Au) in the Izu-Bonin Arc are frontal arc volcanoes dominated by rhyolite and dacite respectively, contrasting with more common mafic neighbor edifices (Iizasa et al., 1999). In both cases gold-rich massive sulfides occur in summit calderas with significant development of pumiceous volcaniclastic rocks, at depths around 1300 and 1370 m respectively. In the Eastern Manus Basin, PACMANUS (~1700 m; 14 ppm Au) and Suzette (~1550 m; 22 ppm Au) occur along the crests of volcanic ridges dominated by dacite/rhyodacite and andesite/mafic dacite respectively (Binns, 2004). Caldera structures are lacking. Although the Eastern Manus Basin is tectonically a rifted back-arc, its submarine volcanic edifices (picritic basalt to rhyodacite) have distinctly arc-style geochemical and isotopic affinities, differing from more typical back-arc basin basalts at the spreading axis further west (central Manus Basin). Probably as a consequence of transpression and a marked rupture in the New Britain subduction zone, submarine arc volcanism has here extended into the rifted back-arc region.

Jan 1, 2005

By Richard H. T. Garnett

On the western continental shelf of southern Africa diamonds derived from onshore sources are concentrated in gravels within drowned terrestrial and marine geomorphological features. First discovered offshore in the late 1950's, they are known to exist for about 1400 km along the Namibian and South African coast in water depths of up to 200 m. Shallow water operations yielded 1.5 Mct during the decade ending 1970 when De Beers acquired a majority of the offshore leases and commenced a 15 year exploration program. Deeper water and the prevailing sea conditions required the development of new, unique, marine mining equipment. The first large scale mining production of 22 kct was achieved by De Beers in 1989 with an output of 22 kct. Annual marine output from all sources now exceeds 0.6 Mct worth some US.$ 170 M, and rising to 0.7-0.8 Mct for 1998. Exploration has also been taking place in the waters of West Africa, Australia, and Indonesia. Exploration is by means of high resolution geophysics followed by sampling using a variety of drills, airlifts and seabed-mounted machines which imitate the eventual mining process. Surveying is now probing depths of 500 m. Smaller scale mining by several junior companies has traditionally involved diving and airlift systems. Increasingly, however, they are adopting different and improved techniques which to date have been employed only by De Beers Marine as contractor to Namdeb. Marine exploration and unit mining costs are high compared to those applicable to alluvial deposits onshore. By 1996 the total development costs incurred by De Beers alone reportedly had exceeded US.$ 500 M. However, the financial rewards are commen-surate because of the higher recovered grades. The operations are not without risk for the total of nearly 10 large and medium scale production vessels deployed by various organisations. The greatest shortfalls are experienced in the estimated throughput, not the grade.

Jan 1, 1998

By Charles L. Morgan

"In 2012 the International Seabed Authority (ISA) established nine “Areas of Particular Environmental Interest” (APEIs) for consideration as future Marine Protected Areas to help preserve the biodiversity of life on the seabed within the Clarion-Clipperton Zone (CCZ) between Baja California, Mexico, and the Hawaiian Islands. The CCZ is believed to have a high potential for future seabed mining operations. Areas under active exploration contracts in the CCZ, plus the areas currently reserved by the ISA for exploration by developing nations, comprise about 1.9 million km2 of seabed area. The currently designated APEIs consist of more than 1.4 million km2 of seabed. Each APEI includes a central primary conservation area of 200 X 200 km, surrounded by 100-km buffer areas on all sides. The 100-km buffers are intended as a very conservative spacing between the primary conservation area and potential mining activities in adjacent seabed. The selection of these nine 400 X 400 km APEIs, has been criticized as possibly not including sufficient representative habitat similar enough to the potential mining areas (identified currently as the exploration contract and reserved areas administered by the ISA within the region) to ensure protection of the biodiversity that might be impacted by mining.An area to the east of the existing exploration contracts and reserved areas is known to have substantial mineral deposits; it is very similar to the adjacent exploration contract areas in its geology, environmental setting, polymetallic nodule abundance and nodule metal content. Because it is located in the northeastern extreme of the CCZ, this area is also likely to have relatively high densities of benthic life, compared with benthic communities further westward within the CCZ. Many options for the designation of this APEI are possible, but the area designation must accommodate the boundaries of the Exclusive Economic Zones of Mexico and France.This paper discusses why the selected region in the eastern extreme of the CCZ is a good candidate for designation as a new APEI.Keywords: polymetallic nodules, Marine Protected Areas, Clarion-Clipperton Zone, Areas of Particular Environmental Interest"

Jan 1, 2017

By Raymond A. Binns

Drilling into an active hydrothermal system linked to convergent-margin felsic magmatism is a listed priority of the Ocean Drilling Program that addresses several fundamental geoscience issues. Solid and fluid products of felsic rock-water interaction, and the consequences for global chemical fluxes and for ore deposition, should differ from those in basaltic mid-ocean ridge environments already successfully tested by Legs 106, 139, 158 and 169. So, too, will fracturing controls on fluid pathways, and sources for metals and ligands. Researching the subsurface volcanic, structural/hydrologic, and mineralisation/alteration architecture of a drilled felsic-hosted system also has economic implications, especially for land¬based mineral exploration. A first-order hypothesis to be tested states that fluids derived from volatile-rich magmas are more important than recirculated seawater in convergent-margin hydrothermal systems - economic geologists increasingly appeal to this for creating "world-class" massive sulfide orebodies. Another hypothesis proposes "subhalative" massive sulfide deposition within hydraulically expanded volcanic products as a factor in generating large orebodies. Many second-order hypotheses such as leaching fractionated volcanics to cause gold enrichment in back¬arc systems also need testing. The thoroughly surveyed, active, PACMANUS hydrothermal field in the Eastern Manus back-arc basin of Papua New Guinea will be the site for ODP Leg 193 commencing in November 2000. It lies near the crest (1655-1750 m) of high-standing Pual Ridge, a 40 km-long edifice of dacite/rhyodacite with basal andesite all having geochemical and isotopic affinities with modern arc volcanoes of nearby New Britain. PACMANUS includes at least three focussed, high-temperature "smoker" sites with Cu+Au-rich massive sulfide deposits, and a field of diffuse, lower temperature venting through intensely altered dacite where modelling indicates significant subsurface mineralisation. Isotopic characteristics of deposits and vent fluids suggest magmatic contributions to the mineralising fluids.

Jan 1, 2000

By William Siapno

Manganese nodules, as metal ores, have for the most part been cast aside from further consideration within this century. However, in the decade of the 90s, rising demand at all levels of society, for clean air give nodules a new - lease on life as a stack gas cleaning agent. Further, the Clean Air act of 1990, mandates enormous outlays to bring systems into compliance with new stringent standards. Quick corrective actions are imperative. Research beginning in the 1960s proved nodules possess unique qualities to remove acid compounds from stack gases. Early this year, the National Science Foundation awarded General Electric an $83 million contract to design a system to extract oxides of sulfur and nitrogen from coal fired power plants. Environmental damage is abundantly evident on the ground, from the air as well as form space. A dirty pall of yellow-brown smog is smothering both animal as well as plant life around the globe. Losses run into billions!

Jan 1, 1991

By Se-Won Chang

This is a part of the joint KIGAM-GNS-NIWA 3-year study of ferromanganese nodules on the Campbell Drift, east of Campbell Plateau to determine age distribution, growth rates and geochemical evolution in relation to geographic setting. During the research voyage SAA3 by R/V Tangaroa (TAN 9909) in July-August 1999, seafloor sampling and camera towing were conducted along the two transects across the known flow path of the Deep Western Boundary Current (DWBC) perpendicular to the lowermost margin of the Campbell Plateau and Bollons Seamount. The four major nodule facies, SHH (slope hydrogenetic nodules with high density), AHH (abyssal hydrogenetic nodules with high density), ADH (abyssal diagenetic nodules with high density), and ADL (abyssal diagenetic nodules with low density) were identified. Two additional minor nodule facies, SIB (slope irregular nodules with ice-rafted boulders) and SHB (slope hydrogenetic nodules with boulders and crust), of localized distributions are also identified.

Jan 1, 2003

By Andrew E. Grosz

The United States is dependent on foreign imports for about 80 percent of its ilmenite, about 60 percent of its rutile, and virtually all of its monazite. Nearshore marine sand deposits and beach-complex sediments in the southeastern United States are important domestic sources of ilmenite, leucoxene, rutile, zircon, monazite, and a number of other less well known economic heavy-mineral (HM) species. Because global onshore reserves of placer titanium minerals may fall short of demand in as few as 20 years, offshore research in HM placers will become more important. The Atlantic Continental Shelf (ACS) defined by the shoreline and the 200-m isobath varies in width for the modern U.S. coastline from a fraction of a kilometer to about 150 km offshore of Cape Cod, Mass., and includes an area of about 3.91 x 105 km2. It probably contains 3-7 x 1011 m3 of sand and gravel which may locally contain commercially exploitable placer HM deposits.

Jan 1, 1986

By Michael J. Cruickshank

Marine minerals are more than an academic curiosity as they represent the most significant global source of mineral materials for economically and ecologically sustainable development for the future. Minerals research is traditionally carried out by industry and thus, in the United States at least, applied research in marine minerals may not get the share of government funding or attention that more exotic programs for space exploration or future global disasters engender. Two recent events have significantly changed the status of marine minerals. Discoveries made in the last thirty five years indicate that the potential for mineral occurrences in the oceans and seabeds, area for area, is as high as for terrestrial lands. On this basis the global mineral resource base has been recently increased by a factor of four of which three quarters is underwater. The recently enacted Law of the Sea has mandated what is probably the most far reaching re-distribution of natural resources in human history, and has resulted in a peaceful subdivision of seabed jurisdictions between the coastal nations of the world which should significantly affect future mineral markets and the balance of economic powers. Significant applied research efforts are ongoing for marine minerals as an adjunct to commercial production in southern Africa for diamonds; and in many other parts of the world for sands for beach and coastal protection. Forward planing, including research and development activities focussed on future commercial production of metalliferous oxides, continues in Korea, China, Japan, India, and with lesser activity, in the United States, United Kingdom, Germany and the CIS. Annual expenditures for this work amount to millions of dollars. In all cases the environmental aspects of commercial produc¬tion are a significant part of the research. Geologic studies on the occurence and distribution of metal sulfides at plate boundaries continue on a regional basis in the Pacific.

Jan 1, 1996

By Steinar L. Ellefmo, Thomas Kuhn

The deep-sea ocean floor offers a great potential for mineral resources. The evaluation of these resources is both time consuming and costly and require as any resource evaluation data; geodata. The collection of hard data, physical samples, is of course preferred because the associated uncertainty is low. However, the collection of soft data or image derived data can offer a valuable supplement. In this paper image derived nodule uncertain abundance data from an area in the Pacific is utilized. Implementing these uncertain data improves the estimation when the quality of the estimation is measured using the classification indicators like the kriging standard deviation, the relative prediction error, the slope of regression and the weight of the mean. It is concluded that uncertain data is better than no data. INTRODUCTION The deep-sea offers vast mineral resources (Cathles (2011), Hannington et al. (2011), Hannington (2013), Singer (2014)). A mineral resource can according to increasing geological confidence be classified as an inferred, an indicated or a measured resource. The classification is performed by a competent- or qualified person and is dependent on the amount, quality and characteristic of available geodata. The competent person must have at least five years of experience relevant to both the style of mineralisation, the type of deposit and the performed task. Typical examples of a “task” is for example resource estimation and classification or planning- and execution of exploration activities and presentations of the results. The competent person must also be a member or a fellow of a professional organisation and thereby be bound by reporting code (-s) that defines minimum standards, recommendations and guidelines for public reporting.

Jan 1, 2018

By John Parianos

"Seafloor mining provides significant potential economic benefits for many Pacific nations that may be “land poor” but “coastline rich,” meaning they have the potential to utilize and profit from the mineral wealth within their Exclusive Economic Zones that extend 200 nautical miles (360 km) out from their coastlines. Within international waters, mineral wealth is the “Common Heritage of Mankind” with additional benefits for sponsoring states and their people.The Solwara 1 Project build continues with significant progress over the last twelve months. The Seafloor Production Tools (SPTs), Subsea Slurry Lift Pump, riser pipe, launch and recovery systems and winches are now complete with delivery to test facilities and the vessel ongoing. Recent focus has been on submerged trials for the SPTs, but the vessel build continues to progress to schedule. Nautilus appreciates the great support thus far from our all our stakeholders.Our focus is to develop the world's first commercial high grade seafloor copper-gold project in an environmentally and socially responsible manner and to launch the deepwater seafloor resource production industry.Nautilus’s marine research continues, including a 3.5-month series of exploration cruises for Seafloor Massive Sulphides in the Bismarck Sea, as well as fabrication of purpose designed exploration equipment."

Jan 1, 2017

By Roger Amato

The 1982 United Nations Convention on the Low of the Sea includes provisions under Article 76 for extending a coastal State's jurisdiction beyond the 200-nautical-mile (nm) Exclusive Economic Zone (EEZ) and for establishing the seaward limits of sovereign rights over natural resources. Article 76 prescribes a set of methodologies for determining these outer limits based on physiography and sediment thickness. The methodologies were applied to each of the five continental* margin areas of the United States - Atlantic, Pacific, Gulf of Mexico, Alaska, and Pacific Islands-using existing digital hydrographic and geologic data. Figures 1 and 2 show the results of applying the methodologies to the Atlantic, Pacific, Alaskan, and Gulf of Mexico continental shelves. Figure 1 depicts the preliminary limits of each of the Article 76 determinations for the Atlantic and Gulf of Mexico continental shelves. The Atlantic limits were described by Carpenter, Thormahlen, and Amato (1995) at the 26th Underwater Mining Institute.1 The limits for the Alaskan continental shelves are shown in Figure 2. Additional areas beyond the 200 nm EEZ are highlighted. These include a small area north of the U.S. - Canada boundary, containing 7,000 km2, a large area north of Point barrow (395,000 km2), and a third area north of the Aleutian Islands (178,000 km2). The shelf between the first two areas appears to have sediments thick enough to qualify for the 1 percent method (Irish Formula); however, year-round ice cover has prevented acquisition of seismic or drill data. The entire northern Alaska shelf is prospective for petroleum The Gulf of Mexico (Figure 1) has two small areas beyond the EEZ known as "doughnut holes." One is south of Louisiana and includes part of the Sigsbee Escarpment, an area believed to have potential for oil and gas. Oil was found on Sigsbee Knoll in cores from Deep Sea Drilling Project's Leg 1 cruise in 1968. The Sigsbee areas contains about 6,000 km2. The second area is south of the Florida panhandle and contains about 12,000 km2.

Jan 1, 1996

By John Halkyard

Deep ocean mining is experiencing a rebirth following many years of low levels of activity. Large scale mining is being projected as just over the horizon. A lot has been made of the advances in deep water oil and gas developments over the last thirty years, and how this technology is directly applicable to ocean mining. The authors present their views on this from a perspective of a legacy of participating in the development of manganese nodule mining systems in the 1970s, followed by thirty years in the deepwater oil & gas arena. While it is true that great advances have been made in subsea technology, the differences between mining and oil and gas recovery should not be diminished. Fundamentally, oil and gas are stored in compact reservoirs under pressure. Any intervention leads to flow of the material up a pipe to the surface. The seabed hard minerals are stuck in place, either adhering to sticky pelagic sediment (nodules) or bonded together as hard rock (massive sulfides). The minerals require complex machinery in order to be extracted, sized, concentrated and lifted to the surface. Once at the surface the ore must be dewatered, de-fined and transferred to shore for processing. The overflow from this dewatered product must return to the sea in an environmentally satisfactory manner. These steps involve technology unique to mining that has to be addressed in a methodical fashion before commercial mining systems can be designed. The presentation will discuss the critical technical challenges of deepsea mining and thoughts on different routes to commercialization. The program will address the critical technical challenges, as perceived by the authors, and steps required to address them. Alternate development programs will be discussed focusing on nodules and sulfide. Keywords: manganese nodules, polymetallic sulfides, ocean mining

Jan 1, 2011

By Dennis Sánchez Mora, John Jamieson

INTRODUCTION Work by Humphris et al., (2002); Ondréas et al., (2009); Barreyre et al., (2012); and Escartín et al., (2015) has identified active and inactive hydrothermal sites along the Lucky Strike segment. The sites that contain the largest accumulation of known sulfides are located between the north and the southern zones (Figure 1), a vent site area that is referred to as the Main Lucky Strike hydrothermal field (Escartín et al., 2015). Hydrothermal fluid outflow has been linked to a shallow fault network (Barreyre et al., 2012). However, specific constraints on fault geometries have not been determined. Other off-axis sites at Lucky Strike, such as Capelinhos (high temperature vent), and Grunnus (inactive?), as well as a low temperature vent field (on-axis), Ewan, have been described by (Escartín et al., 2015). Given the spatial relationship between the Main Lucky Strike hydrothermal field (MLSHF), and the intersection of northern rift faults with the southern rift faults, a structural analysis of this area can provide insight into the fault controls on fluid flow that leads to hydrothermal venting and sulfide precipitation. METHODOLOGY Structural data (dip direction and dip) was determined using Leapfrog Geo 4.0 software. Bathymetric data was obtained from Escartín et al., (2015) and references therein. The bathymetry was imported into Leapfrog Geo (in UTM format) and, using the structural modelling tool, individual measurements with dip direction and dip data were collected with a focus on the northern volcanic rift and the southern central volcano (Figure 2a). All measurements were taken from what the authors consider as normal faults, and to aid the determination of individual measurements a “face dip” map was constructed, where the bathymetry is colored by slope angle (Figure 2b). All measurements are simultaneously plotted on a stereonet generated by the Leapfrog Geo Software. Data were divided into northern and southern, and western and eastern zones to determine the relationship between hydrothermal venting and the structural geometries at Lucky Strike (Figure 2c). Slip measurements for individual faults were determined along the dip of the fault with a measuring tool. Net slip, heave (horizontal displacement), and throw (vertical displacement) was calculated for each of the zones.

Jan 1, 2018

By Carl H. Hobbs

The beach at the resort city of Virginia Beach, Virginia has been and increasingly will be dependent upon artificial nourishment for maintenance and for hurricane protection. Both existing base-level maintenance operations and planned substantial enhancement programs out strip the capabilities of traditional terrestrial resources to provide the required quantities of sand. Our research program, an amalgam of projects from several funding sources, has located and defined suitable quantities of beach quality sand for use on the city's beaches. The work also has furthered our understanding of the region's Quaternary history. Initially, reconnaissance level, high-resolution, sub-bottom profiles and surficial grab samples taken on the basis of sub- marine geomorphology identified two geographically and geologically separate areas worthy of further exploration. Further profiling supplemented with some cores further defined the potential sand reserves. The Sandbridge Shoal site is a large and discrete Holocene sandbody atop late Pleistocene strata. The sands in region offshore of the commercial area known as the Resort Strip appear to be recent fill within fluvial(?) channels cut into the older subsurface. Each of these resources is within roughly 5 km of major sites targeted for beach nourishment and/or hurricane protection and contains sand with appropriate geotechnical properties. Ongoing work will better define the dimensions and limits of the sand bodies and provide data to enable determinations to be made concerning exploitation. Ultimately decisions concerning the overall beach enhancement-hurricane protection projects will involve economic, environmental, technical, and social considerations.

Jan 1, 1995

By S. Rajendran

Gas Hydrates (Methane Hydrates) are solid, ice-like substances composed of water and natural gas. They occur naturally in areas of the world where methane and water combine at appropriate conditions of temperature and pressure and are found in ocean bottom sediments and in some permafrost areas. Besides temperature and pressure, factors like bathymetry, sediment thickness, sedimentation rates, and total organic carbon content (TOC) also control gas hydrate formation in the ocean basins. The stability of gas hydrates depends on the critical combination of high pressure and low temperature (0 - 17 bars, 0 - 25°C), which in turn is dependent on the mix of gases from which the mineral is formed. As the critical parameters can be altered by deposition, erosion, slumping, formation or melting of ice cover, rise and fall of sea level, and sudden temperature changes induced by tectonic activities, current flow, or volcanisms, the gas hydrates tend to be very unstable. The Indian offshore is promising for the occurrence of gas hydrates in a total of about 80,000 km2 area in the bathymetry range of 700 to 3000 m as reported in earlier surveys. A gas hydrate stability zone thickness map was prepared using bathymetry and sea bottom temperatures along the continental margins of India. This map is expected to provide the depth window while searching for Bottom Simulating Reflectors (BSR). The study indicates that a minimum water depth of 750 m is required for the formation of gas hydrates, above which the chances for gas hydrate occurrence appear minimal despite other favorable conditions like organic-rich sediments, etc. Single-channel seismic analog records (Gupta et al., 1998) indicate that the Western Continental Margin of India (WCMI) offers a greater promise for gas hydrate occurrences, particularly with regard to the number of BSRs traced on the analog records as compared to earlier surveys.

Jan 1, 2005

By N. R. Ayupova

Several metallogenic zones including Sakmara, Magnitogorsk, and East-Ural zones were revealed in the Ural fold belt (Fig. 1). These zones are considered to be the paleogeodinamic sectors corresponding to marginal sea, island arc system, and uplift respectively. Ferruginous-manganiferous sediments in the Southern Urals are hosted by the basalt-rich volcano-sedimentary series of the Magnitogorsk paleoisland arc system with West- and East Magnitogorsk island arcs and Sibai inter-arc basin. The manganiferous mineralization occurs in association with the Middle Devonian stratabound hematite-quartz rocks and bedded red jaspers localized on the foot or handing walls of massive sulfide deposits. Fe-Mn nodules are widespread in jasper horizons on the flanks of manganese deposits. We have studied Fe-Mn nodules from the Faizulino and Yanzigitovo Mn-deposits formed in the Sibai inter-arc basin and compared them with well known Fe-Mn nodules from modern oceans.

Jan 1, 2010

By Gerald R. Dickens

Massive sulfide ores and Fe-Mn oxyhydroxide precipitates represent two extremes of a spatial continuum of hydrothermal deposition along oceanic ridges. Elemental variations across this continuum are of interest to economic geologists as a prospective geochemical exploration tool. Theoretical considerations suggest that certain physical and chemical parameters can be used to model compositional variations within the far-field (i.e., Fe-Mn oxyhydroxide) component as a function of distance from ridge axis; however, testing and verification of such models generally has been precluded because the few available distal hydrothermal sediment sequences have been sampled at low resolution and/or are highly diluted with biogenic components (e.g., siliceous and calcareous tests). Recent ocean drilling (ODP Leg 145; Sites 885/886) in the North Pacific successfully recovered an extensive record of "biogenic-free" distal hydrothermal precipitates from an area approximately 60 km south of the Chinook Trough at longitude 168.1 °W. Geophysical and geomorphological evidence suggests the Chinook Trough is the southern lithospheric scar marking initiation of late Cretaceous north-south rifting, implying that recovered hydrothermal materials record distal hydrothermal precipitation from the now-subducted Kula-Pacific spreading ridge. The Chinook Trough hydrothermal sequence is a continuous 15 my record of "biogenic-free" hydrothermal Fe-Mn oxyhydroxide precipitation mixed with eolian clays. It was deposited during the late Cretaceous, early Paleocene (80-65 Ma) as the perpendicular distance from ridge axis increased from 75 to 600 km. A high-resolution geochemical analysis of this hydrothermal sequence reveals distinct trends for the up-core (equivalent to increasing distance from ridge) distribution patterns of Fe, Sc, As, and rare earth elements (REE). Iron concentrations exhibit an S-shape distribution pattern with respect to increasing

Jan 1, 1994

By Timm Schoening, Greinert. Jens, Iason –. Zois Gazis

"Ferromanganese nodules are again of interest because of their high concentrations of Ni, Co, Cu as well as REE. With regards to an operational underwater mining industry, one of the main questions and important requests is to finding a method that can predict the abundance of nodules with high accuracy within reasonable time spans, without many requirements for ground truth data; and all these on an operational scale and ideally automated. In this regard, we present results of a study based on the combination of highresolution multibeam and optical data acquired by an AUV using specific machine learning techniques to reveal a detailed distribution of the Mn-nodules in correlation to the seafloor terrain. The accuracy of the method employed and results gained were validated and approved through comprehensive statistical analysis and by comparison to box-core data.Study AreaOur study area (AUV survey block G77) is located in the Clarion-Clipperton Zone (CCZ) (Eastern Central Pacific Ocean), an area that has been receiving international research and industrial attention for many years already (e.g. McKelvey et al., 1979; Bernhard and Blissenbach, 1988, von Stackelberg and Beiersdorf, 1991, Jeong et al. 1996). Block G77 covers an area of 9.5km2 in a depth between -4478m and -4536m. The area is characterised by gentle slopes 0-5° (0-3° in most of the area and only in the outer parts of the Block slopes can exceed 5°). The seafloor is characterised by moderate to low rugosity, the only exception being a small area in the eastern part, where sub-recent smallscale volcanic activity created 15 cone-shaped morphological features of up to 55m height and 150m width that are clustered in an area of 700 x 380m (Figure 1)."

Jan 1, 2017