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By Nicolás Luis, Qi Liu, Gonzalo Montes-Atenas

"The prediction of froth flotation performance is still an unresolved topic. Classic industrial models based on particle size, elemental and mineralogical information provides recovery results with deviations that may become significant. One possible reason for this deviation may be the fact that the current liberation analysis provided by electron microscope based techniques does not take into account the outmost surface layer composition of liberated particles. In order to complete the description provided by the liberation analysis, other spectroscopy techniques measuring the extreme surface of the minerals can be tested. For instance, X-ray Photoelectron Spectroscopy (XPS) is a technique which measures the first tens of nanometers providing elemental composition over the particle surface and allows resolving the elemental associations present at the surface sample. However, this information needs to be statistically robust, reproducible and most importantly representative of what is occurring in the process. The aim of this research work is to develop a statistical model based on particle population to evaluate the feasibility of turning the XPS technique into a metallurgical tool. The model consists of classic statistical population arranged in a bed of heterogeneous particles with a known grade and mineral liberation. The simulations showed that the XPS results statistically followed a well-defined pattern. The statistical results were confronted with pilot plant results obtained from a rougher bank when processing a copper sulfide ore from a Chilean mine site. It was observed that the probability function distribution was in agreement with the experimental data. Further analysis on how the XPS results provide valuable information improve the computation of froth flotation recoveries is also discussed."

Jan 1, 2014

By M. H. Moys, M. M. Bwalya

The use of the Discrete Element Method (DEM) to simulate the interaction of particles in dynamic environments is growing rapidly. This technique is also being applied in the study of milling extensively. However, to date more focus has been on the validation of the model. In spite of the advantages of the detailed information that is available from the simulator, appropriate application of this information remains a daunting task. In this paper a technique that combines particle breakage probability data with the energy spectra generated from the DEM is discussed.

Jan 1, 2003

By F. S. Hoseinian, K. Filho, D. Deglon, T. Souza, M. Safari

"This paper investigates the reverse flotation of hematite in three laboratory flotation cells with very different contacting environments. The main objectives are to investigate the recovery of coarse quartz by flotation and fine hematite by entrainment. The laboratory flotation cells used were the mechanical, oscillating grid and pneumatic cells. The effect of froth height and solid concentration were investigated in the mechanical and pneumatic cells. The effect of impeller speed and energy input were investigated in the mechanical and oscillating grid cells. Froth height results show that coarse quartz particle recovery decreases almost linearly with increasing froth height due to increased detachment of coarse quartz particles in the froth. Fine hematite particle recovery also decreases almost linearly with increasing froth height due to decreased water recovery and associated entrainment. Agitation/energy input results show that coarse quartz particle recovery increases with increasing impeller speed to an optimum, after which this decreases dramatically. The increase is due to improved gas dispersion, generation of smaller bubbles and increased bubble-particle collision and attachment. The decrease is due to significantly increased bubble-particle detachment at higher impeller speeds. The recovery of coarse quartz particles in the OGC is higher than that in the mechanical cell with an optimum at a much lower energy input. Solids concentration results show that both mass recovery and water recovery increase with increasing solid concentrations. The pneumatic cell achieves higher mass recoveries and lower water recoveries than those in the mechanical cell at equivalent solids concentrations and operating conditions. INTRODUCTIONFlotation is a selective process for separating different minerals from each other. The flotation separation efficiency depends on the recoveries of the mineral species by both true flotation and entrainment (Neethling and Cilliers 2009; Wang et al. 2015). Both chemical variables and hydrodynamic conditions within the flotation cell affect the recovery and selectivity of the flotation process. Cationic reverse flotation of hematite is a common method for selective separation of quartz from iron ores to produce pellet feed. The presence of coarse quartz particles in the tailings and fine hematite particles in the concentrate are two major challenges in the reverse flotation of hematite (Vieira and Peres 2007)."

Jan 1, 2018

By Gideon Chitombo

"Mining is a "continuous" process of dependent breakage and materials handling stages, from the initial breakage of the in-situ rock, extraction from the pit or underground, and finally to the surface stockpile and downstream processing. Over time, underground and in-pit mining activities diverged into two separate disciplines, each using a variety of in-situ breakage techniques and surface activities, with processing techniques dependent on mineralogy or grades. This artificial separation of underground and open pit activities was exacerbated when the two became increasingly managed as separate cost centres rather than as an integrated unit. Mass mining essentially began in 1903 when metallurgist Daniel Jackling initiated the world’s first open pit, mining system at the Bingham Canyon porphyry copper deposit in Utah. The term mass mining has since been construed to mean large open pits and cave mining methods, including their variants. These methods are largely non-selective, involving the mass extraction of a deposit irrespective of the uneven distribution of grade and mineralogy. The advantages of mass mining have historically applied mostly to low grade, large scale deposits. With the depletion of mineral reserves closer to the surface, however, new deposits are deeper, lower grade and mixed with more impurities. These and other factors make extraction more difficult and costly. Mass mining is moving rapidly into a new and less certain environment where revolutionary changes are required to effectively deal with future challenges which are technical, economic and environmental (licence to operate). This keynote address presents current initiatives being considered for the next generation of both underground and surface mass mining systems in order to significantly reduce lead times and mining costs (CAPEX and OPEX), substantially increase productivity and meet license to operate requirements. The address is designed to solicit discussion on how better integration of mining and processing can become a platform for these next generation of mass mining systems and can also help the industry deal with the future challenges."

Jan 1, 2014

By Glasswell K. Nkonde, Fredrick Chileshe, Steven Simukanga

Improving food security by increasing crop output is a primary objective for most countries in the sub- Saharan region. Most soils in the region are deficient in phosphorus an important nutrient after nitrogen in plant growth. Phosphates are therefore used together with nitrogen and potassium based fertilizers in improving crop production. Zambia like many other countries in the sub-Saharan region imports phosphate fertilizers for use by its farmers. However, indigenous phosphate deposits of igneous origin exist in Zambia of which the main ones are Chilembwe in Petauke district, Mumbwa sugarloaf in Mumbwa district, and Nkombwa Hill in Isoka district. If commercially exploited, these deposits could become a ready source of inexpensive phosphate for the local farming communities in the country. Previous research has shown that partially acidulated phosphate rock (PAPR) produced using Chilembwe phosphate rock is just as agronomically effective as the imported superphosphate fertilizers on food crops in most of the Zambian soils. PAPR is produced by reacting finely ground phosphate rock with only a fraction (usually 50%) of the stoichiometric quantity of the sulphuric acid required to fully convert the apatite in the rock to monocalcium phosphate thus making the process cheaper in terms of acid consumption than the poduction of single superphosphate where the apatite in the rock has to be fully converted to monocalcium phophate. The factors that affect the percentage of available P2O5 in the PAPR produced include particle size of phosphate rock, degree of acidulation, concentration of acid, process temperature profile, residence time and drying temperature. These factors were studied in a 25kg/hr PAPR pilot-plant in the School of Mines at the University of Zambia using Chilembwe phosphate rock. The PAPR pilot-plant consisted of a rotary drum granulator as the main reactor, a rotary drum dryer and a triple deck vibrating screen. Ground phosphate rock was reacted with sulphuric acid and water in the granulator to form a granular product which entered the drier. The dry product was screened into three size fractions. The 1 – 4 mm size fraction was the final product whilst the –1mm size fraction was recycled. The +4mm size fraction was sent to a crusher while the crushed PAPR was sent back to the screens.

Jan 1, 2003

By Brian Loveday, Sandile Nkwanyana, Indresan Govender

"Recent batch experiments by the authors in a pilot scale ball mill (Ø = 0.6m) have demonstrated that a partial replacement of the ball charge by pebbles (25 % pebbles; 75 % steel balls) optimally reduces the ball and power consumption without altering the rate of production of fine material (passing 75 microns). At higher pebble volumes, the production rate of fines was reduced progressively. With the 25/75 composite charge a saving of 13 % in power consumption was achieved, and a saving of 25 % in steel ball consumption is implied. A partial replacement of steel balls by pebbles reduces the overall density of the grinding media in the charge. Taking into consideration that the production rate of fines is usually proportional to the bulk density of the charge in the mill, it would be expected that a composite charge (e.g. 25/75) would coarsen the grind and consequently reduce the rate of production of fines. Pebble wear contributes a small proportion of fines and it doesn’t provide a full explanation of why the 25/75 composite charge has no (or minimal) adverse effects on the rate of production of fines. Clearly, the production of fines across the mill is directly related to the shear and compressive power dissipation density. Accordingly, we hypothesise that the spatial power dissipation distribution meeting the minimum requirements for fines production— at the so-called active regions—are equivalent, or minimally comparable, for both the 25/75 composite and 100 % ball charge operating conditions. To test the hypothesis, we performed DEM simulations to analyse power dissipation in the active regions. 1. INTRODUCTION Comminution remains to be the most expensive process in mining operations, particularly because the energy consumed in this process accounts for 30-70 % of the total cost of a mining operation (Nadolski et al, 2014). Optimization of comminution circuits has been focussed on reducing capital and operating costs and maximising throughput capacity. For existing operations, it is often a challenge if the optimization process recommends retrofitting new ‘major’ equipment. The challenge arises from new capital cost and the difficulty of retrofitting in an existing circuit, while maintaining production (Major et al, 2001). Thus, for existing mining operations, optimization of comminution (cost and throughput) is often limited to operating conditions and/or addition of auxiliary equipment (such as pebble crushers, additional screens and high pressure grinding rolls (HPGR)) (McIvor and Greenwood, 1996; Hart et al, 2001; Powell et al, 2015b)."

Jan 1, 2018

By Kazutoshi Haga, Atsushi Shibayama, Altansukh Batnasan

The objectives of this study were to propose a viable alternative method for recovery of precious metals such as gold (Au), silver (Ag) and palladium (Pd) from waste printed circuit boards (WPCBs) and to regenerate the spent lixiviant solution for reuse. The proposed method generally consists of several steps as follows: 1). iodine-iodide leaching for metals extraction; 2). separation and recovery of precious metals and metal impurities from a pregnant leach solution; 3). regeneration of the spent iodine-iodide solution/lixiviant. In this method, more than 99% of Au leaching was achieved in the iodine-iodide solution from the solid residue of WPCBs that was obtained via sequential processes including incineration at 800 ?C and high pressure oxidative leaching with a diluted sulfuric acid at 120 ?C, while the leaching of Ag and Pd was less than 1%, respectively. Besides Ca, Cu, Ni, Co and Zn as main metal impurities, leaching efficiency of other metals did not exceed 1%. The precious metals and base metals as metal impurities present in the pregnant leach solution were separated and recovered by precipitation using L-AA and NaOH solutions. About 99.8% Au, 81.7% Ag and 72.8% Pd were recovered from the pregnant solution at pH of 2 with the addition of 0.1 M L-AA as precipitating agent. The remained small amounts of precious metals and metal impurities were precipitated at pH 13 using 1 M NaOH. The spent lixiviant after sequential precipitation was regenerated in the presence of hydrogen peroxide, hydrochloric acid and potassium iodide. It was revealed that over 90% of gold could be extracted from the residue of WPCBs with the regenerated lixiviant solution.

Jan 1, 2018

By T. N. Alexandrova

Results of mineralogical-technological research of carbonaceous rocks of Kimkansky precious metal occurrence are presented, on their basis new typemorphic natural and technological microelement associations were revealed using mathematical statistics methods. Keywords: carbonaceous rocks, processing, microelements, flotation, statistical criteria

Sep 1, 2012

By Sashnee Raja, Mehdi Nemati, Ashley Sissing, Susan T. L. Harrison

"Extreme thermophiles, operating at 65 - 90°C, are finding increasing application in biohydrometallurgy. These micro-organisms have the advantage of exhibiting better oxidation kinetics in terms of reaction rate and extent of mineral solubilisation (Duarte et al., 1993; Norris and Barr, 1988; Konishi et al., 1995). These extreme thermophilic Archae, characterised by a different cell envelope structure (König and Stetter 1986, König 1988, Michel et al. 1980) perceived to provide reduced structural strength in comparison to bacterial envelopes, and customised metabolic pathwaysThe active tank bioleaching process, used for high rate leaching, is conducted in a slurry bioreactor. Here sufficient energy dissipation is required to ensure suspension of the mineral phase as well as to sustain high rates of gas liquid mass transfer. It is well known that subjection to hydrodynamic stress of sufficient magnitude may alter the physiological state of a range of micro-organisms through changed viability (ability of the microbes to grow), metabolic activity and integrity. While limited study on the influence of the solids phase on thermophilic leaching performance is reported, initial reports suggest that the thermophiles used for bio-oxidation appear to be sensitive to hydrodynamic conditions (Jordan et al 1993, Clark and Norris, 1996) and the presence of solids (Norris and Bar 1988, Le Roux and Wakerley, 1988, Escobar et al. 1993, Torres et al. 1995, Nemati and Harrison, 2000)."

Jan 1, 2003

By H. Pearce, A. E. Lewis, A. Ochieng

"Hydrodynamics and mixing are fundamental to the operation of mineral process systems such as flotation cells and metal precipitation reactors. Hydrodynamic conditions influence phase mixing and mass transfer in a multiphase system, and these affect the overall performance of such a system. Detailed information on the effects of the hydrodynamics on the performance of agitated systems is still required for the design and optimal operation of hydrometallurgical systems, which are always multiphase. Computational fluid dynamics (CFD) techniques have been employed to study the hydrodynamics and mixing, most of which have focussed on the performance of axial and radial pumping impellers in agitated tanks. However, very little has been reported on the influence of a draft tube on the flow profile in such systems.CFD simulation of a stirred vessel centres on the way the impeller is modelled. Some of the most recent approaches to modelling an impeller are impeller boundary condition (IBC), snap shot, sliding grid (SG), multiple frame of reference (MFR) and inner outer (IO). The accuracy, with which these models predict experimental results and the corresponding computational demands, form the basis upon which the choice of an approach is made. Most of these approaches (IO, SG and MFR) address the key problem of the stirred tank modelling, namely, the simultaneous meshing of the rotating impellers and the stationary baffles. The MFR is computationally cheap and has been found to give predictions that compare well with experimental data.The CFD technique (code CFX4.4) has been employed in the present work to study the hydrodynamics in a mixing vessel stirred with either a Rushton turbine or a pitched blade impeller. The multiple frame of reference (MFR) approach has been used to model both impellers. A draft tube was used only in the Rushton turbine stirred vessel. The flow profiles for the impellers have been studied in three regions; below the impeller tip, at the middle of the tank, and near the liquid surface. The simulation results were compared with literature data obtained using a laser Doppler velocimetry in the three regions of the vessel, and it was found that the model predictions were better in the impeller region. There was a poor prediction of the experimental results in the region closer to the liquid surface; however, this was improved when the turbulence parameter (C2) in the k-e model was set to a higher value. The value of the impeller clearance at which the Rushton turbine generates an axial impeller type flow has been determined and it has been shown that, at this clearance, a draft tube can be used to enhance axial flow in a Rushton turbine stirred reactor."

Jan 1, 2003

By S. Banisi, E. Arghavani, M. Pourkani, M. J. Rajabi, Gh. A. Mohamadian, H. Bidshahri, Gh. A. Parsapour

The Sarcheshmeh copper complex flotation circuit of plant No.1 consists of two identical north and south sections where each includes four rougher (each bank consists of 14 cells), two cleaners (each bank consists of 8 cells), two recleaners (each bank consists of 2 cells), and two scavenger banks (each bank consists of 10 cells). The reduction of feed grade along with a change in the mineralogical composition is the main reason of current lower concentrate grade (24%) compared with the design concentrate grade (32%). Because of a lower feed grade, the amount of rougher concentrate has decreased which in turn has significantly reduced the feed rate to the cleaner, recleaner, and scavenger banks. This has increased the mean residence time of the material in the cleaner section resulting in a lower final concentrate grade. A laboratory study showed that the final concentrate grade can be increased by 2-4% if one cleaner stage is added to the flotation circuit. In this research, based on the laboratory results, one cleaning stage was added to the current flotation circuit. In order to make this modification instrumentally possible in the plant, the final concentrate was gravity transported to the Mo-Cu thickeners. This released 2 pumps and associated tanks which made addition of one cleaning stage practicable. Finally, a part of the cleaner and scavenger cells were used as the third cleaning stage. This decreased the residence time in the cleaner and scavenger banks. After implementation of one cleaning stage in the south section of the plant, the performance of the circuit compared with the identical north section. It was found that at the same recovery, the concentrate grade of the south section increased by 2.5%. The promising results led to the implementation of adding one cleaning stage in all sections of the flotation circuit.

Jan 1, 2018

By Marko Hilden

"A stochastic model of mineral texture is discussed and used to demonstrate that grain association within the intact texture has a significant effect on the liberation characteristics of breakage products. The majority of previous models have simulated texture and liberation of binary systems. This new model is able to simulate complex multi-component (multi-mineral) aggregate textures and their breakage products. Grain size distributions can be defined for each of several minerals. Mineral-mineral associations can be controlled by inserting mineral grains within grains of another mineral. Repeated Monte Carlo sampling of the aggregate is used and the liberation properties of the fragments are calculated. These are analysed to generate data in a similar form as reported by mineral liberation analysis systems, including density distributions, liberation distributions, and particle class distributions. Simulations results are presented where the model has been fitted to complex sulphide ores with four minerals. Comparison of the simulated particles and experimental data show that the model is able to reproduce similar particle class distributions as measured by QEMSCAN. The texture of real complex ores can be simulated and fitted to conventional mineral liberation analysis data. The model should provide a useful and practical means of modelling the effects of mineral texture on separation processes and in geometallurgical models."

Jan 1, 2014

By Leon Lorenzen, Rodrick M. Lamya

"Leaching behaviour of nickel – copper matte in a CuSO4–H2SO4 solution during the repulping stage of a matte pressure leaching process has been studied. The base metal recovery process investigated in this study consists of a matte repulping stage prior to a series of pressure leach stages. The repulping stage is essentially an atmospheric leach stage in which the Ni-Cu matte, containing small amounts of cobalt and iron, is leached in copper spent electrolyte from the tankhouse, resulting in dissolution of the nickel with simultaneous precipitation of almost all the copper.Effects of various process parameters on the kinetics and extent of the leaching reactions, as well as on the cementation of copper from the solution have been quantified. The parameters investigated were temperature, particle size, pulp density, stirring speed, residence time, initial copper concentration and initial acid concentration.Leaching characteristics of the preleached matte during the subsequent pressure leach operation has also been studied. The effects of variations in the conditions in the repulping stage on the kinetics and degree of base metal dissolution during the pressure leach stage have been investigated. Any transformations that occur in the mineral phases of the matte during the leaching process have been studied, and a leaching mechanism proposed."

Jan 1, 2003

By Benoit Clermont, Jan Lux

"Magotteaux and Anglo Platinum started a co-operation program with the main aim of establishing the optimum milling configuration measured in terms of throughput, fineness and energy consumption.For this purpose, a fully instrumented pilot milling plant, supplied by Magotteaux (Pty) Ltd, and equipped with a 0.9 x 1.0 m ball mill, was erected at Frank concentrator (Merensky Pt ore). The primary ball mills at Frank concentrator were surveyed in order to set the conditions for the base case. This data was then replicated in the pilot mill under the same configuration. Thereafter, a series of different parameters were varied in order to attempt to optimize the milling system.Only grate versus overflow discharge and open versus closed circuit will be discussed in this paper.It should be noted that this paper does not attempt to give a universal solution as to what milling configuration is optimum in all cases. The conclusions apply for this particular case and probably most others, but it would be advisable to consider each case on its own.CONCLUSION• Overflow versus grate dischargeAn overflow mill has a “pool” of slurry around the toe of the ball charge, which creates a counter lever to the ball charge. This will reduce the absorbed power in the range of 10-15% (depending on the case) and will consequently result in a coarser grind. The tests found a 4% gain in grinding efficiency (Wio) with an overflow mill but this is probably not significant.This lower absorbed power and coarser grind can be counteracted by increasing the ball charge (if below maximum) and/or by increasing the mill volume when removing the grate discharge (a typical grate takes up about 300mm of the mill length).• Open versus closed circuit"

Jan 1, 2003

By Xiaojing Li, Yueyuan Zhou, Shengyao Ma

The paper presented the acnalysis of field intensity of rare-earth permanent magnet with high BH product and the research of magnet configuration with narrow pole pitch on open magnet surface, both using ANSYS. The possibility to separate micro-disseminated feebly magnetic minerals by improving the field intensity and the capture line distribution rate on open magnet surface were verified. The research on the method to pile up magnets to increase peak value of field intensity on the open magnet to 1.0T was done through correlation analysis between shape and dimensions of magnetic material and field intensity. And the research on technology method to improve capture line distribution rate in the separating field to 1.25×105/m2 was done through optimization design of magnet configuration of the open magnet with narrow pole pitch. Laboratory tests were performed with hematite sample from ore dressing plant such as Hainan mine, Qidong iron ore, etc. The separation results acquired were at the same level as using the electromagnetic separator, verifying the possibility to separate micro-disseminated feebly magnetic minerals with open magnet. The research suggested a new idea about the development of magnetic separator with high efficiency and low costs to separate feebly magnetic minerals and non-magnetic gangues.

Jan 1, 2014

By John Ralston, Stephen Grano, Yongjun Peng, Daniel Fornasiero

"A specially designed mill which allowed the control of pH throughout grinding was used to study the effect of rgrinding conditions on galena flotation and galena separation from pyrite. The various reactions occurring on the mineral surface were investigated by a range of techniques, including OH- addition to maintain the grinding pH, EDTA extraction, XPS and ToF-SIMS measurements.Galena flotation and galena separation from pyrite were strongly dependent on the metal oxidation species produced on galena and pyrite surfaces under different grinding conditions. Iron oxidation species depressed both galena and pyrite flotation, whilst lead oxidation species activated pyrite but had little effect on galena. Optimum galena flotation and galena selectivity against pyrite were achieved by selecting grinding conditions that enabled lead and iron oxidation production to be controlled."

Jan 1, 2003

By Arkady Senchenko, Yevgeny Zhagun, Yury Kulikov, John Starkey

"The paper contains description of a new project in Russia - gold-processing plant at Aleksandrovskoye deposit (start up in September, 2013). The paper includes a brief description of plant flowsheet, data for material composition and technological properties of ore, as well as information about the achieved parameters of ore processing over the first months of plant operation. The project is interesting because a new semiautogenous mill and a ball mill were purchased on the basis of SAGDesign Consulting Group recommendations after the testing of ore samples characterizing the deposit according to specific years of operation. The plant has relatively small design capacity - 750 000 tpa, but nevertheless is the biggest gold-processing plant in the territory of Zabaikalsky region. Major valuable component in the ore is gold, silver is recovered as a by-product. The ores are very hard to grind. The design grinding flowsheet includes a semiautogenous mill operating in closed circuit with a screen, and a ball mill operating in a closed circuit with hydrocyclones (SAB). Process technology includes gravity processing and flotation with subsequent cyanide leaching of concentrates. Mill operation analysis and conclusions about the compliance of the achieved values to target ones are shown, as well as the accuracy of SAGDesign method when applied to very hard ores of Aleksandrovkoye deposit are presented in this paper. Basic directions of technological flowsheet optimization are also given."

Jan 1, 2014

By Francisco Vicuña, Miguel Becerra, Gonzalo Montes-Atenas

"The optimization of the copper recovery from smelting slag by a process of comminution / flotation has been a widely discussed topic during the last few decades. Several studies covering the characterization of different types of slag, the impact of the slag cooling rate and of different flotation operating conditions on the flotation performance have been widely published. Currently, at El Soldado mine site (Angloamerican), there are large copper bearing slag deposits that can be a profitable alternative for the concentrator with capacity to treat this material. Under this process schema, the optimization of the flotation process to obtain better copper recoveries is a relevant topic of study. The aim of this study is to assess the efficiency of a sulfidation stage of a slag and to correlate that process with copper recoveries results in a flotation circuit. This article presents a detailed examination at both laboratory and plant scales of the slag sulfidation on the recovery of copper in the flotation process. The experimental methodology involves studying the effect of the sulfidation agent dosage, the pH, the particle size distribution of the flotation feed and the conditioning time. Furthermore, the performance of the sulfidation stage was analysed through the XPS analytical technique. It was observed that the sulfidation of particles in floatable size fractions correlated well with the increase in copper recovery. The results indicated that it is possible to increase between 2 to 4 points the total copper recovery with a sulfidation process implemented appropriately."

Jan 1, 2014

By A. Güney, G. Önal

"Karagedik Chromite Concentrator of the ETI Holding Co., which is located in Fethiye (south Turkey), has been producing chromite concentrate assaying 47-48 % Cr2O3 from the chromite ores containing 30-35 % Cr2O3 by using gravity separation methods since 1920. The tailings having 13-14 % Cr2O3, which had been removed from this plant, were accumulated at the stockpiles amounting about 1.2 million tons. In order to recover the ultra fine chromite particles from the Karagedik Concentrator tailings, the new process including Wet High Intensity Magnetic Separation and column flotation, was developed and the Karagedik Research Pilot Plant based on this process was commissioned in 2000. At this plant, the final concentrates assaying 46-48% Cr2O3 were produced and overall plant recoveries are about 60-65%.At the chromite concentrators using gravity separation methods, if their material size is about minus 1.0 mm, chromite particles especially pass to fine fractions according to their mineralogical structures and the ore-genesis (Önal and Güney, 1990). Generally, after crushing and grinding, the shaking tables and spirals are used at the chromite concentrators; therefore fine size chromite particles (-0.038 mm) are removed as tailings. Cr2O3 content of the -0.1 mm size fraction with 52.3% of the total amount is 19.58 % with Cr2O3 distribution of 82.6%.In order to upgrade the minus 0.1 mm size fraction of the tailings, assaying about 20% Cr2O3, Karagedik Research Pilot Plant (KRPP), which includes Wet High Intensity Magnetic Separator (WHIMS) and Column Flotation units, was installed by Istanbul Technical University (ITU), Mineral Processing Section in 2000.Feeding material of the KRPP having 5 tons per hour capacity is obtained from stockpiles amounting 1.2 million tons. After attrition scrubbing, the feed is sent to a screen with aperture of 1.0 mm. The screen overflow, assaying 5-6 % Cr2O3 is removed as tailings. Screen underflow is classified to –1.0+0.1 mm and minus 0.1 mm size fractions by using cyclone and sieve bend. –1.0+0.1 mm size fraction assaying 6-7 % Cr2O3, is sent to existing gravity separation plant. Minus 0.1 mm size fraction is firstly fed to WHIMS for pre-concentration and non-magnetic product assaying 10-11 % Cr2O3 consisting of serpentine, talc and olivine minerals are separated as tailings. Also magnetic product (25-30 % Cr2O3) obtained from WHIMS is fed to the two stages conditioners after dewatered to 30 % solid ratio."

Jan 1, 2003

By Douglas W. Fuerstenau

Some historical sketches of the early development of froth flotation are presented. Flotation technology involves several aspects: chemical control of mineral hydrophobicity, selectivity in flotation, flotation kinetics, flotation machines, and process optimization and control. However, only some aspects of the regulation of mineral flotability by the addition of chemical collectors in some selected cases are discussed. The early contributions to flotation science by Langmuir, Gaudin, Wark, and Taggart are briefly outlined. With a firmer understanding of surface chemistry, electrochemistry, and the electrical double layer, progress has been made in understanding the fundamentals of flotation chemistry, although sound theoretical underpinnings still are needed in these very complex systems. Flotation chemistry is related very directly to the type of mineral being floated since the systems depend strongly on the chemical and physical characteristics of the minerals. Full discussion of chemical reagent phenomena would be in terms of the behavior of naturally flotable minerals, sulfides, oxides, silicates and alumino-silicates, and salt-type minerals. At this time, citing a few cases involving salt-type minerals and oxides, the dependence of their flotation surface chemistry will be discussed in terms of the role of adsorption, surface reaction, and the hydrophobic effect.

Sep 1, 2012