Search Documents

By C. Dorfling

Experimental work was performed using a bench scale autoclave to evaluate the effects that leaching temperature, pressure, initial acid concentration, and the solid to liquid ratio have on the behaviour of base metals and platinum group metals in a high-pressure sulphuric acid oxygen leaching system. The concentrations of metals in the leach solution were measured over time at different leaching conditions. At the conditions investigated, the initial acid concentration had the largest influence on the copper leaching kinetics, while the leaching rates of the other precious metals (OPMs: rhodium, ruthenium, and iridium) were highly dependent on the leaching temperature. A set of chemical reactions that can be used to describe the leaching chemistry was proposed, and the associated reaction kinetics were quantified. As a first estimation, the rate expressions were considered first order, and the rate constants were determined using the method of least squares, considering the experimental and predicted concentrations obtained for the different leaching conditions. Of the OPM compounds, the sulphides showed the fastest dissolution rate, followed by OPM alloys, and finally the OPM oxides. During the initial leaching stages, base metals and OPMs competed for the available dissolved oxygen, with oxygen being preferentially used for copper leaching. Precipitation of OPMs during the initial leaching stages can be ascribed to copper and nickel dissolution according to exchange reactions between dissolved OPMs and copper present as digenite or nickel present as polydymite. Control of the autoclave residence time is of particular importance to enhance the selectivity of this leaching step, given the dependence of the PGM leaching rates on the extent of copper dissolution.

Sep 1, 2012

By Cuim R., M. L. Li

Fankou Lead-Zinc Mine produced pyrite concentrate (P.C.) from the zinc tailings by rougher and scavenger flotation before 2010, with the averaged S grade of 40.54% at recovery of 79.34% ( to the feed of S circuit). On the one hand, the economic value of P.C. increases with its purity, on the other hand, when the S grade of P.C. feed to sulfuric acid manufacturer is over 47%, the pyrite cinder can reach a high Fe grade of 62% which can be directly sold as iron concentrate. On this background, engineers in Fankou Mine set the P.C. with S grade of 47% as target. The direct way to reach that goal was to clean the rougher P.C.. Lots of cleaning flotation tests were conducted and the compromised strategy was to produce two ranks P.C. with the S grade of 47% and 38% at the recovery of 44.20% and 36.17%, respectively. The dual-product flowsheet was successfully industrialized in 2010. In order to further improve the quality of P.C., gravity separation was introduced into the flowsheet. The numerical simulation and separation tests were performed to evaluate the beneficiation and classification performance of hydrocyclone as it treated the rougher P.C.. It was shown that the underflow of hydrocyclone could addressed the S grade of 47%, and the finer size overflow could also be enriched to P.C. with S grade of 47% by flotation, due to the contained pyrite with well liberation. That is to say, with the ingenious addition of hydrocyclone to treat the rough P.C., single P.C. with S grade of 47% could be achieved. The new flotation-gravity separation flowsheet was commissioned to produce the high quality P.C. at the end of 2013. The averaged S grade is 47.20% at recovery of 82.26% in 2014. The two steps flowsheet improvement maximizes the enterprise benefits and leads to simple utilization of Fe in pyrite in downstream industry.

Jan 1, 2018

By Yuhua Wang, Huilan Yang, Yanqing Jiang, Dongfang Lu

"Generally, the concentration of bauxite flotation tailings is around 10%, a large amount of water in tailings needed to be recycled in the flotation process. Sedimentation and dewatering properties of tailings were investigated under different conditions. Surface high negative charges on mineral particles are the key factor to destroy the settlement of tailings when the pulp pH is around 8.9. Hence, the modification of pulp pH around 7 is necessary to the diminution of the repulsive force between mineral particles and then the acceleration of sedimentation of tailings. Anionic polyacrylamine with molecular weight of 14 million is the best flocculant for the settlement of tailings in all tested polyacrylamines. P-toluene sulfonic acid shows better properties than hydrochloric acid for pulp pH adjustment when anionic polyacrylamine with molecular weight of 14 million is used as flocculant. Although the flotation of diaspore is depressed in the presence of polyacrylamine using sodium oleate as collector, but the recycling water traded by the combination of ployacrylamine and p-touenesulfonic acid does not show the depression effects on the flotation of bauxite ore. The lower residual content of polyacrylamine in recycling water treated by the combination of ployacrylamine and p-touene sulfonic acid plays an important role. INTRODUCTION Generally, the waste water generated from mineral processing plant is usually treated by sedimentation, oxidization, electrodialysis, ions exchange, active carbon adsorption and flotation technology, and the treated water is also used again in the industrial process. Flotation was adopted widely to improve the quality of bauxite from low grade diasporic bauxite in China. For flotation, the grinding fineness of bauxite is over 90% -0.074 mm, sodium carbonate and sodium hexametaphosphate were used as regulators, so the tailings pulp is very difficult to settle and be dewatered (Y. Wang et al., 2004; Y. H. Wang et al., 2007; Wang Yu-hua et al., 2008; Wang Yuhua et al., 2011). The water recycling of bauxite tailings are becoming the highlight for the industrial application of the flotation process for bauxite ore. Researchers in China shift their attentions onto this topic."

Jan 1, 2018

By B. Das

The processing of banded iron ore by direct anionic and reverse cationic flotation to produce pellet grade concentrate is investigated. This low-grade iron ore, known as banded hematite quartzite (BHQ) contains 41.8% Fe, 41.5% SiO2, 1.2% Al2O3, and 0.5% LOI. The flotation behavior of BHQ is studied by varying the effect of concentration of collector, frother, dispersant and pH. Oleic acid and dodecylamine are used as the anionic and cationic collectors respectively. The parameters that gave the best results in cell flotation are utilized in 100 mm diameter flotation column. All the results are compared with regard to the iron grade and recovery in concentrate. It is observed that, anionic collector with dispersant dosage of 220 g/ton, at pH ~8.5 is selective and yielded a high-grade iron concentrate with low silica as impurity. Also, it is possible to achieve an iron concentrate with 64% Fe at 30-37% weight recovery. The characterization studies of the BHQ ore using X-ray diffraction (XRD) technique and liberation analysis with QEMSCAN® are carried out. The sample contains 58.8% hematite and 37.7% quartz and the liberation of hematite particles are found to be 90.3% in -25 µm size. An alternative statistical modeling approach called response surface methodology was also undertaken to optimize the operating parameters in order to maximize the iron grade and recovery. The predicted results by the model are in agreement with the experimental values.

Sep 1, 2012

By Chris A. Fleming

"Interest in the recovery of cyanide from gold and silver plant tailings has heightened in recent years. This interest has been spurred by several factors:Increasingly stringent regulations throughout the gold producing world, governing discharge limits for free and total cyanide to tailings ponds and the environment.The increasing cost of active chemical treatment versus passive (natural degradation) treatment of tailing, to bring them in line with environmental regulations.The worldwide trend to processing of more complex gold ore bodies, which is usually accompanied by higher levels of cyanide consumptions and greater concentrations of cyanide (particularly the copper cyanide complex) in tailings.The growing negative perception of the general public for the gold mining industry, due to several highly publicized cyanide spills in recent years (breaches of tailings dams, accidents involving trucks carrying cyanide to gold plants, etc.).The ability to recover cyanide from gold plant tailings has been known almost as long as the cyanidation process has been practiced, but there has been little incentive to process tailings in this way in the past. With the development of technologies that make it possible to recover and recycle free or complexed cyanide directly from gold plant slurry tailings, which indicates, on paper at least, the potential for significant cost savings compared to cyanide destruction, coupled with the introduction of legislation to seriously limit the discharge of cyanide to the environment in most gold-producing regions of the world, many companies are evaluating the cyanide-recovery alternative."

Jan 1, 2003

By S. Z. Shafaei

An experimental investigation has been carried out using a laboratory scale Denver flotation cell. For evaluation of cokeable coal of Alborze Sharghi coal washing plant, the full factorial method was used to statistically design and analyse the experiments. The 2 factorial interaction model were developed for combustible recovery and ash content as response and diesel dosage, conditioning time, feed percent solids and rotor speed as factors. Model validation and residual analysis were con-ducted and results indicated that the fitness, predictability power and residual distributions of models were good. The effect of parameters and interactions were examined and it has been demonstrated that rotor speed, solid percent and interaction between diesel dosage and solid percent were more important terms of all responses. A product with approximately 78% combustible recovery and 10% ash content was obtained at 4000gr/ton diesel fuel oil (high level), 30 sec conditioning time (low level), feed percent solids of 15% (low level) and 800 rpm rotor speed in appropriate condition.

Jan 1, 2014

By Milind Chikhale, Ranjeev Kumar, Keshav Tyagi

Ore characterisation including mineralogy and beneficiation testwork of an ore is very important for determination of possible products and their quality. The results of such study help in ascertaining the beneficiation process route for the ore. The present study deals with ore characterisation study and beneficiation testwork on the samples of hematite iron ore with goethite impurity. The characterisation study reveals that the hematite is under alteration stage to goethite which has become an integral part of hematite. High goethite/limonite content is enhancing the loss of ignition content of the ore and reducing its Fe content. The findings indicate that in case of hematite iron ore associated with goethite and limonite, it is difficult to achieve high grade of concentrate above 65% Fe. It depends on the amount of goethite and limonite minerals and their association with hematite. These minerals contain aluminous impurities and hence, their rejection becomes essential. Separation of limonite and of goethite to limited extent is possible. In case of goethite, effective liberation is not achieved where it occurs as surface alteration product of hematite grains. The gangue mineral reported are clay and gibbsite, and are closely associated with iron minerals. The test work results indicate the grade and recovery of Fe along with alumina and silica content in lumps, sinter fines and pellet feed fines that can be achieved for the different ore types vis-a-vis the percent of available hematite in the ore. The recovery of iron is dependent on the hematite available and the loss of iron values in tailings is more because of rejection of limonite and goethite.

Jan 1, 2014

By Chuanyao Sun, Zhenguo Song, Aijun Ren

"Lead-Zinc sulfide ore containing carbon is one of typical refractory resource. Because organic carbon has natural floatability, it has a great negative influence on flotation of lead-zinc sulfide ores. It is difficult to obtain qualified lead concentrate by flotation using conventional reagent system. In order to reduce the influence of organic carbon on lead and zinc flotation, two alternatives, i.e., removal carbon by pre-flotation or adding carbon depressant in lead and zinc flotation, can be adopted. If the flowsheet of removal carbon by pre-flotation is adopted, the lead and zinc recovery which are lost in the carbon tailings is often higher. If conventional carbon depressants are used in lead and zinc flotation, it has a certain depression effect on lead minerals. In the paper, the ore grading 1.49% Pb, 5.73% Zn, and organic carbon 3.14% has been carried out by flotation tests. In the bulk flotation of carbon and lead minerals, Pb concentrate is only about grading 21.00% Pb. In the pre-flotation of organic carbon, it’s hard to remove most of carbon, and the loss of Pb and Zinc recovery is too much in carbon tailings. New carbon depressant BK547 and three conventional carbon depressants including sodium lignosulphonate, Fe-Cr-lignosulfonate, and dextrin, are used in comparative tests of Pb flotation, and results show that BK547 have a good depression on organic carbon, and have almost no effect on Pb flotation. Using BK547 as carbon depressant, cycle test in flowsheet of two-stage Pb and Zn selective flotation and coarse concentrate regrinding have been carried out, and results show that concentrates grading 62.51% Pb and 41.33% Zn are obtained at recoveries of 70.24% Zn and 83.58% Zn.INTRODUCTION Lead and zinc mineral resources are still the main source of lead and zinc metal. For lead-zinc sulphide ore, lead concentrate and zinc concentrate are obtained by flotation. Minerals separation by flotation is a complex process and is dependent, along with other factors, on the relative distribution of hydrophobic (e.g. collector, polysulfide, elemental sulfide) and hydrophilic (e.g. metal hydroxide) species between different particles of the same mineral phase and between mineral phases (Piantadosi & Smart, 2002; Boulton, Fornasiero & Ralston, 2003). Organic carbon has natural floatability and is often associated with lead-zinc sulphide ores. If the content of organic carbon in the ore is more, the flotation index will become worse. The main problem is that the concentrates has too low grade to be qualified grade products for sale. At the same time, the consumption of reagents is more than ordinary ores without organic carbon. In order to solve the influence of organic carbon on the flotation of lead and zinc and other sulphide ores, a lot of research works have been carried out."

Jan 1, 2018

By Carina Ulsen

The existing construction and demolition (C and D) waste recycling technologies and standards have been essentially focused on the production and use of coarse recycled aggregates. Very few papers focus on the production of recycled sand, although some previous results show that fine aggregates fraction represents around 40 to 60% (in mass) of the Brazilian waste and it is usually used as road sub-base or disposed in landfills. The quality of the recycled aggregate is strictly related to the content of porous and low strength phases, mainly the patches of cement remaining on recycled aggregate surface. Some technologies have already been described in the literature, even though, to the moment none of these technologies has clearly succeeded in reaching the large market available. This paper presents a summary of the main properties of the sand produced from C and D waste by tertiary crushing at vertical shaft impact crusher (VSI). Additionally mineral processing technologies were applied on the attained product, such as gravity concentration by shaking table and spirals and removal of cement paste by attrition. The main properties of recycled sand are discussed and compared to the previous C and D waste, respectively: particle size distribution, particle shape, chemical composition, cement paste content and porosity. The results demonstrates that the crushing allowed producing a VSI-sand with low porosity and water absorption due to the increasing on the content of silicates from natural rock phases and increasing liberation between these phases and porous cement paste; the particles from the attained product presented also a better shape (sphericity and aspect ratio). The attrition tests assayed on VSI recycled fine aggregates accomplished a further selective disaggregation of cement paste and other porous materials - the porosity was reduced from 10% to 7%. The concentration by shaking table at narrow sieve fractions led to a product with low porosity and reduced content of cement paste, however, concentration on spirals did not succeed since separation was performed essentially by the size of the particles. The heavy product from shaking table represented almost 75% in weight and has less than 60% recovery of CaO+LOI, and expressive reduction on porosity. The aim of producing sand from construction and demolition waste through mineral processing unit operations changes the recycling approach and contributes for up cycling the recycled sand. The exhaustion of sand deposits on Brazilian large centers, the increasing price and the construction boom encourages the development of alternative materials as construction raw material. Keywords: recycled sand, construction and demolition waste, technological characterization

Sep 1, 2012

By E. Hulthén

Crushing plants are widely used around the world as a pre-processing step in the mineral and mining industries and as standalone processing plants in the aggregates industry. Despite automation and different advanced model predictive control, a lot of the process is still managed by operators. The operators affect a lot of the performance. The numbers of the improvement they can achieve are at least as big as the advanced control algorithms?, today. Therefore, it is also important to train the operators so they know how to behave in different situations. Models for crushers and other production units have been developed during the years and the latest add is the different units? dynamic behavior being brought in, which gives the crushing plants dynamic time dependant performance. This can be used as a simulator for operators training. By connecting a Human Machine Interface (HMI) to a dynamic simulator with the models incorporated, a training environment for operators can be achieved. In this paper, a dynamic crushing plant simulator implemented in MATLAB/SIMULINK has been connected to an HMI via a PLC. The HMI is placed in a control room at the university and complemented with monitors showing sequences from the process connected to the simulations, thus creating a realistic control room for training. In the created training environment, the operators can be trained under realistic conditions. Simple training scenarios and how they could be simulated are discussed. Apart from the increased level of knowledge and experience among the operators, the time is an important factor. While a real crushing plant is still being built, the operators to be can already be trained, saving a lot of the commissioning time. Keywords: crushing, cone crusher, simulator, control room, operator, training

Sep 1, 2012

By Hamid-Reza Manouchehri, Hassna Aitahmed-Ali, Stellan Sundberg

"In flotation practices as the particle size becomes fine, e.g., p<20µm, the process efficiency declines markedly. When flotation of fine particles is necessary, one method to improve the recovery is selective agglomeration of fines. Different agglomerating methods have been introduced and tested; however, one method which has recently received great attention is to aggregate fine particles by magnetic force. A selective aggregation of the fine paramagnetic particles, e.g., sulfide minerals, can be achieved by applying a high intensity magnetic field during flotation conditioning. The method is simple, selective and effective for fines, and has a low operation cost. However, a minimum magnetic susceptibility of fine grains is required for this process. This method has been demonstrated in different sulfide minerals flotation plants. The implementation of the magnetic conditioning device, ProFlote, in both the Cu-Pb and the Zn circuit of Boliden’s Garpenberg plant in Sweden, where a complex massive sulfide ore is treated, is discussed herein. The preliminary results have shown an increase in the recovery of value minerals, in particular Zn and Ag and considerable reduction in Zn deportment to the final tail. Increases in Cu grade and decreases in Pb grade in Cu-con have been achieved as well."

Jan 1, 2014

By J. D. Miller

The more efficient production and use of mineral resources is a major objective of our sustainability efforts. Resource characterization is a critical component for optimization of the mine-to-mill process, including innovative processing for sustainable growth. Such characterization is now referred to as geometallurgy, with advanced instrumentation including, for example, particle size analysis, XRF, XRD, NIR, automated SEM/EDAX analysis (QEMSCAN, MLA), and high resolution X-ray micro tomography. Geometallurgical information is important for exploration, deposit evaluation; mine planning, design and analysis of separation processes, etc. Characterization of mineral processing particles in 3D is now possible using high resolution X-ray micro tomography (HRXMT), and such HRXMT systems have been installed at several laboratories around the world. After review of principles, the features of such HRXMT analyses are presented including size/shape, damage state, mineral phase identification, and evaluation/isolation of trace mineral particles. With new algorithms for image analysis, quantitative data treatment is possible for construction of liberation-limited grade/recovery curves, for the determination of specific crack surface area, and for complex texture analysis including grain exposure. Finally, new tomographic characterization possibilities are discussed to provide the foundation for the development of advanced, innovative processing strategies for sustainable growth. Keywords: X-ray tomography, resource characterization, HRXMT, particle size analysis XXVI INTERNATIONAL

Sep 1, 2012

By Hans-Åke Häggblad, Bertil I. Pålsson, Jan Stener, Kent Tano, Andreas Berggren, Pär Jonsén

Numerical modelling of grinding in tumbling mills is traditionally done with the discrete element method (DEM). The grinding balls are then represented by DEM particles and the mill structure is considered rigid. To include more physical phenomena several numerical methods can be combined. One important improvement is to include the mill structure response, using the finite element method (FEM). The interaction between charge and lining can then be studied in detail. The pulp can also be included using a particle-based continuum method e.g. smoothed particle method (SPH). The strength of SPH lies in modelling of free surface flows and very large deformations and it is suited to model simultaneous fluid and granular flow. Still, the coarse particles (grinding balls) in the charge are suitable to be model using DEM. Each of these methods has their strength and weaknesses, but combined they can successfully mimic the main features of the charge movement. With these numerical tools the complex interaction between the different components of the grinding process; pulp, charge, lining and the mechanical behaviour of the mill, can be studied together. This work will present novel numerical approaches to model, simulate and validate charge behaviour in tumbling mills. These numerical models give possibilities to better understand the physical and mechanical behaviour of particulate material systems during grinding in a tumbling mill. This is important in order to develop and optimise future high-capacity grinding circuits and save energy.

Jan 1, 2014

By J. X. Zhang, F. S. Niu

"In order to accurately detect whether the collision occurs between particle and bubble in flotation process, a collision detection method of particle and bubble, which based on morphological image processing and Otsu method, is presented. First of all, it utilizes image pre-processing to optimize images, the target area and the background area are segmented by Otsu method. Then, particle and bubble are fitted to a circle combined with the least-square method. It’s convenient to obtain the coordinate information and radius. Finally, the position of all particles is extracted to an image, which achieves the particle tracking and avoids the complexity of the continuous frame image tracking.Experimental analysis shows that the relationship between the two ordinate difference d and the bubble radius r has a certain influence on the collision detection when the dripping particles are close to the bubble, when d>r, the detection accuracy is 92%;When d=1/2r, the detection accuracy is 97%;When d=0, the detection accuracy is 100%. The result indicates that this algorithm can detect the collision between particle and bubble quickly, and the working hours of manual test are saved effectively ,the best position of dripping particles close to the bubble which is taken with a CCD camera should be in the range of the particle and bubble’s ordinate difference less than half of the bubble radius.INTRODUCTIONFlotation is an important technical means to separate useful minerals from ores. The flotation process of ores and materials in the world is treated by flotation technology up to billions of tons every year, so the study of flotation process is particularly important. Raising the collision probability between mineral particles and bubbles in flotation process is one of the key factors to improve flotation separation efficiency[1]. The study indicates that[2-4] the collision probability between particles and bubbles is influenced by many factors, such as particle density, particle size bubble size, etc. The analysis of these influential factors requires a lot of experiments. Therefore, it is of great significance to design an accurate collision detection method for the research of this field."

Jan 1, 2018

By S. H. Lau

Rapid 3D characterization of multiphase mineral particles in a variety of mineral processing applications is described, including: mineral liberation analysis, grain size, mineral exposure analysis, particle damage, and pore network structure for fluid flow simulation in heap leaching. While micro X-ray computed tomography systems (microCTs) have been used for many years, industrial adoption is limited due to a variety of reasons, including insufficient resolution, the general lack of imaging contrast to differentiate different mineral phases within a multiphase mineral particle and the lack of automated 3D mineral processing software. For example, resolution with industrial CTs and desktop microCT is of the order of tens of microns to a few microns at best, depending on specimen size and CT configuration. We describe a novel lab-based X-ray microscope, XRM, which overcomes these resolution and contrast limitations, notably as the industry is going towards finer grains and more complex ore bodies. Using lens-based optics and detectors (similar to its XRM counterpart in synchrotron beam lines), resolution of the lab based system is in the submicron range with contrast better than conventional microCTs. Hence, visualization, differentiation and segmentation of most mineral phases of interest to the industry are now feasible. Coupling these high resolution and high contrast tomography images with a suite of customized 3D segmentation algorithms and analysis software, applications in mineral liberation analysis for process control, particle damage assessment and other mineral processing applications can be achieved. This non invasive 3D technique which requires relatively little sample preparation is currently being considered for coal, industrial minerals, and base/precious metal ores, complementing existing microscopy techniques such as QEMSCAN and MLA for a variety of applications

Sep 1, 2012

By K. Hori

In this study, the determination of optimal conditions for jig separation has been investigated with a TACUB jig separator. The TACUB jig, from which a Batac jig originated, is a useful gravity separator that is effective to separate crushed solid wastes as well as coarse ores. A mixture of crushed polyethylene (specific gravity 1.3) and polyvinyl chloride (specific gravity 1.5) was separated by a batch TACUB jig by varying the frequency (wavelength) and the amplitude (pulse stroke length). It was found that the sample particle layer in the separation chamber was fluidized without turbulence by the rising water pulse resulting in the separation. However, a too strong water pulse reduced the efficiency of the separation of the particles. The results indicate that the specific velocity of the rising water is necessary to fluidize the particle layer without turbulence to separate the particles. The expansion ratios of the thickness of the particle layer in rising flows were measured in a cylindrical column. The pressure losses by the particle layer were calculated from the expansion ratios and the velocity of the rising flows by Ergun?s equation. The curve of the pressure loss vs. the velocity of rising flow showed a maximum point corresponded to the point of fluidization. The velocity of a rising flow on the point of fluidization provided the optimal separation condition.

Jan 1, 2014

"This research represents a shift away from empirical models that lock the industry into 50-year old inefficiencies with little response to operating variability. The mechanistic and intrinsically dynamic mill model under development steps up to a new paradigm using the latest computing capabilities and physical understanding of breakage and transport to transform predictive capabilities for design, optimisation and on-line control with variable feed. The milling process is broken down into discrete sub-processes, each of which can be modelled as an object in the whole model and in the model code. These objects can be upgraded or exchanged without having to rewrite or restructure the remainder of the code. Sub-processes include: feed into mill; transport along mill; presentation to impacting events; range of impacting forces; probability of being impacted in different zones in the mill as a function of particle size and density; suspension in slurry; and discharge out of the mill. The unit and processes surrounding the mill (feed and recycle conveyors, slurry pump and pipe, cyclone and recycle crusher) have also been modelled, in order to incorporate the effect of recirculating load coming from a cyclone or a recycle pebble crusher, respectively for ball mills or SAG mills. Each unit is modelled dynamically and PID controllers have been added to control pumping flowrate from sump and water addition for cyclone feed dilution. The paper demonstrates the predictive capability of a dynamic, mechanistic model and is used to test the sensitivity to the sub-processes, comparing different formulations and highlighting the aspects that require further development. Validation on pilot tests and application to industrial data is presented. This approach is currently undergoing industrial trial on sites, for use in on-line model-informed process control. Considerable further development is required to incorporate the full mechanistic structure planned for this model."

Jan 1, 2018

By T. Wallmach, S. B. Blancher, A. Delaporte, P. Goncalves

"Fe-Ti oxides concentrates produced from heavy mineral sand deposits are widely used for the production of titanium dioxide pigments that are critical components of white paint, plastics and paper. According to mining industry, the Fe-Ti concentrates mostly consists of three phases: ilmenite, leucoxene and rutile. However, a few mineralogical studies have shown that the variety of Fe-Ti oxides found in sand deposits is far more complex, mostly due to alteration processes. The aim of this contribution is to characterize in detail by means of Qemscan analyses the mineralogy of the three main concentrates (ilmenite, leucoxene and rutile) produced by the Grande Côte Operation (GCO) mineralurgical plant in Senegal. The ultimate goal is to characterize the different products and textures formed during the natural ilmenite alteration processes, to localize the phases carrying the main impurities (Cr and P), and finally to determine the physical properties of each mineral component to improve metal recoveries. Along alteration processes, Ti content increase. Ilmenite (FeTiO3) is progressively transformed into pseudorutile (Fe2Ti3O9) particles which could also be altered and transformed into hydroxylian pseudorutile [FeTi6O12(OH)3.3H2O] or complex blends of anatase microcrystals (TiO2). These transformations are accompanied by significant changes in particle textures. Microporosity and fractures appear and the impurity content also increases. Anatase rich microcrystal assemblages, so far described as Leucoxene, could be identified to consist of grains with higher porosities, water contents and higher intrapore impurities. These particles are the main carriers of chromium and phosphorus. The observed mineral transition textures have a significant impact on the ore dressing processes. During these transformations, the physical properties of these phases change, the magnetic susceptibility as well as densities decreases, due to the increase in porosity. The separation of particles, especially those with high porosity will help improving the GCO mineralurgical plant performance and to reduce the impurity contents in finals products."

Jan 1, 2018

By l. Bokányi, T. Varga

"The recycling of waste car tyres is a very important environmental task. The waste tyres usually are re-used or recycled by thermal processes like pyrolysis, gasification or incineration. The main problem associated with these processes is the sulphur content of waste tyres originated from the vulcanisation process, which pollutes the environment and the valuable products (i.e. pyrolysis oil) as well. In our research the desulphurisation of waste, mechanically prepared tyre sample was systematically investigated by the biosolubilisation with Acidithiobacillus thiooxidans, strain Karitas. Parallel, the experiments with sterile 9K nutrient medium were also carried out. It was found that the vulcanisation sulphur can be solubilised due to both the bio- and the chemical leaching, although the bioleaching is more effective. The solubilised vulcanisation sulphur then forms precipitates. The precipitates are forming in the bulk solution, as well as on the surface of rubber particles. The origin of the precipitates was investigated using XRD and scanning microscopy with micro probe. The origin of the precipitates is different: while in the process of the vulcanisation sulphur solubilisation with 9K medium the jarosite (KFe3+3(SO4)2(OH)6) forms, the course of the biosolubilisation with Acidithiobacillus ferrooxidans Karitas is accompanied by the formation of the jarosite and the halotrichite (FeAl2(SO4)4 · 22H2O) as well. The formation of the latter is the biomineralisation. The mechanisms of the bio- and chemical solubilisations are rather different as it was found and experimentally proved by several tests, and depends on the retention time of the solubilisation. Special efforts were done to elaborate the proper separation of the precipitates from rubber particles. Combination of intense dynamic stirring and recycling flotation process to remove the precipitates was applied for this purpose. The surface properties of synthetic jarosite were revealed using zeta-potential measurements at different pH and in presence of collectors. The parameters of the flotation were chosen based on the revealed surface properties of the precipitates. Finally, the sulphur recovery of the recycled rubber was achieved as low as <0.5%, sulphur content of it 0.17%, 12-times lower than that of the waste tyre sample after mechanical preparation."

Jan 1, 2018

By Nicolás Caussade

"The IMPC 2014 slogan "Optimizing Water and Energy Usage for Sustainable Mining" refers to the ever decreasing availability of fresh water and energy, which has turned out to be a crucial aspect in assuring the competitiveness of the mining sector in Chile and the Andes region in general. The concern for sustainability and the supply of water and energy is nowadays part of the top priorities of mining countries and communities. This is also the case for Antofagasta Minerals. Several years ago its mining group implemented an energy policy based on intelligent, strategic and sustainable management, in order to successfully face the challenges imposed by the market. It is called an intelligent policy because it intends to provide energy through a diversified range of sources, which includes the development of in-house alternatives. It is also a policy focused on efficient energy consumption and one that is strategic. Because it is in line with the characteristics of the mining activity, it is developed for the long term. Finally, what makes the policy sustainable is that it gives priority to energy usage from renewable resources and as such, the required capacities have been developed to generate innovative solutions that respond to the restrictions that characterize the industry today."

Jan 1, 2014