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By J Kokado, N Hatta, S Yabushita

A theoretical model is described for prediction of the capacity of fines from porous ores, such as cokes and sintered ores, to be removed by a pneumatic, horizontal-type classifier prior to charging into a blast furnace. First, the influence of variation in the apparent density and drag coefficient of porous ores on removal efficiency is analysed from a stochastic standpoint. The effect on efficiency of collisions between particles in the classifying region is then examined analytically in relation to the ratio of the mass flow rates of particles and air (the loading ratio). Finally, a theoretical model is constructed that takes these factors into account. Theoretical and experimental results are compared and classifying efficiency is discussed from both experimental and theoretical viewpoints.

Dec 1, 1993

By G. R. Doughty

It is shown that sodium can be removed very readily from molten aluminium by the use of a beta"-alumina, the more highly conducting form of beta-alumina, provided that the surface of the tube is wetted by a layer of salt. From current/time plots the theoretical amount of sodium removed has been calculated and excellent agreement obtained. The beta"-alumina tubes can be immersed directly in the Al without fracturing if they are pre-heated for a few minutes prior to immersion. According to its stability beta"-alumina should be attacked by molten Al at low Na contents, but in these experiments the salt acted as a protective layer. Magnesium chloride is a relatively cheap salt, whose Mg product can be used within a foundry. The only other product is NaCl, which can be used in-house as a flux or sent for disposal. No polluting gases are used or produced and no drosses created. The time for removal of sodium was quite short, comparable to that for chlorination

Jun 21, 1905

By G. G. Barbante

An understanding of the thermodynamics of smelting copper anode slimes is a prerequisite for improvements to the process. During slimes smelting, a silver-copper selenide matte is formed and subsequently oxidised to silver metal. As part of a series of investigations, molten silver selenide matte was oxidised at 1 100 degrees C with pure oxygen. The chemical potential diagram for the system was developed and used for qualitative prediction of the results of the experiments. A simple, computational thermodynamic model of converting is presented, the adjustable parameters of which were determined by matching the model with the experimental results. The practical usefulness of the model was demonstrated by predicting the effect on silver recovery of smelting temperature and of using either oxygen or air as the smelting gas

Jun 21, 1905

By R. T. Grant, C. Bazin, D. Hodouin

It is shown that most of the variation in the results of semi-batch flotation tests is related to the unavoidably stochastic nature of the flotation process. The preparation and analysis of flotation samples and, to some extent, operator error in performing the flotation test procedure are responsible for a small proportion of the observed variability of the calculated flotation performance indices

Jun 17, 1905

By D. H. Watkinson

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. Part of the contact of the 4b orebody with the enclosing Murray granite is characterised by the presence of recrystallised and biotitic Sudbury Breccia; in places the contact is faulted and sheared. In other areas of the contact partly silicified granite contains disseminated chalcopyrite and quartz-chalcopyrite veins with other minor minerals. Both ore and veins contain platinum group minerals (PGM); predominant PGM are michenerite, kotulskite, merenskyite and sperrylite with Au, galena and Bi-tellurides. At some silicified-granite contacts Mn-rich garnets, some containing inclusions of PGM and quartz, are associated with biotite + epidote + stilpnomelane + quartz. PGM and Au also occur within Cl-rich biotite and ferropyrosmalite in massive sulphide and in siliceous ore. Quartz, chalcopyrite and feldspar in the contact rocks and in veins contain abundant, highly saline fluid inclusions. Studies showed that the fluids were trapped at intermediate temperatures. The 4b orebody is surrounded by a sheath of brecciated granite but is close to the Contact Sublayer. During and after emplacement of sulphide magma, saline formational fluid that was resident in the breccia interacted with hot massive sulphides in and near the Sublayer and remobilised Cu, Au and PGE. This fluid reacted with cooler rocks and ore in footwall fractures, enriching the 4b protore and producing the adjacent Cu- and PGE-enriched quartz veins. Exploration for Cu and PGE enrichment in footwall rocks of the Sudbury South Range is warranted not only in zones of magmatic ore in the Contact Sublayer but also in fractures and permeable units within Sudbury Breccia

Jun 16, 1905

By G. I. D. Roach

The leaching, with hydrochloric, sulphuric and perchloric acids, of suspensions and massive specimens of different haematite and goethite samples has been studied. Both accelerating and constant types of leaching curves have been observed. It is concluded that the grain to particle size ratio of the oxide being leached determines which type of leaching curve is obtained, particles containing a large number of individual grains producing the accelerating type of curve

Dec 1, 1971

By Ruddle R. W.

Although copper has been smelted for many years, relatively small attempt has been made in the past to examine the fundamental physical chemistry of the processes involved. Therefore, technological developments apart, slow progress has been made with the development of improved or new principles of smelting. The methods at present in use in the majority of the world’s smelters are essentially those employed at the beginning of the present century; it is significant that many of the textbooks on copper smelting, written some 50 years ago, are still regarded as standard works. The book is divided into seven chapters. In the first the fundamentals of modern smelting processes are briefly outlined for easy understanding of the subsequent sections, while the next two chapters are confined to the more theoretical aspects of the constitution of mattes and slags. Some problems of considerable practical importance are discussed in the remaining four chapters; these are (1) magnetite formation, (2) copper losses during smelting, (3) the recovery of sulphur from the smokes produced during smelting, and (4) the elimination of impurities. A collection of thermodynamic data relevant to copper pyrometallurgy is presented in an appendix, and, for the convenience of readers not well acquainted with thermodynamics, a brief explanation of the thermodynamic terms and methods employed is given in a second appendix

Jan 1, 1953

By A. C. Dunham, Y. D. Drakapoulos, P. W. Scott

The Pt and Pd occur alloyed with copper in small, irregularly-shaped grains, 0.25-5.0 micrometers in maximum dimensions. Grains of unalloyed native copper are also present. The grains are completely surrounded by or marginal to magnetite with inclusions of Ni-Fe-Co sulphides and native Ni-Fe, which is apparently a product of the serpentinisation process. Crystallisation of the Pt-Pd-enriched copper probably occurred at the same time, at low temperature, but the previous form of the Pt and Pd is unknown as no earlier PGE phases have been found. While Pt and Pd minerals are usually important in early-magmatic base-metal sulphides, Pt alloyed with Cu is extremely rare and apparently occurs only very late in the paragenetic sequence. A Cu alloy with Pd dominant over Pt and only minor amounts of other elements appears not to have been reported

Jun 14, 1905

By A. Sutherland Strachan

Before regulations governing the work on the mines, it was not uncommon in the Rand for a miner to die within a period of 2-3 years as the result of exposure to dust. This paper considers mine and tunnel conditions promoting silicosis and measures to avoid dust exposure in the Rand, South Africa.The relationship between blasting and lung lesions is explored. Evidence is presented that improved working conditions and lowered dust levels reduce the incidence of silicosis.

Jan 1, 1947

By P. K. Kaiser, R. K. Brummer

Paper presented at the conference Risk assessment in the extractive industries, held in Exeter, 23-24 March 1994. A risk-based decision-making procedure has been developed for selecting rockburst-resistant tunnel support in burst-prone mines. The method is based on a risk-cost-benefit analysis and uses support cost data, costs associated with the risk of support failure or excavation loss, costs associated with accidents, injuries and deaths, and the benefits achieved by installing rockburst-resistant support. It takes into account the risk of damage to the support systems due to rockbursts, potential loss of production and the need to rehabilitate in the event of a damaging rockburst. A practical example is provided to illustrate the principles involved in the decision process

Jun 17, 1905

By B. Denby

Following an introduction to the symposium and its topics, including techniques such as expert systems, neural networks, genetic algorithms and case-based reasoning, the contents list of the 8 selected papers is presented

Apr 1, 1994

By M. J. Matos, W. Patruk

The correct version of Equation 1 is represented and Tables 3 and 6 are revised to consider all size fractions, including those coarser than 300 micrometres, in calculating the total liberation from King's fractional liberation

Jun 18, 1905

By J. H. E. Jeffes, K. T. Jacob

The activity coefficients of oxygen in liquid Pb-Sn alloys have been measured between 550 and 1100°C by use of solid oxide galvanic cells: Pt, Ni-NiO | Zr02 Solid electrolyte | O (Pb + Sn), Cermet, Pt; and Pt, Fe-FeO | Zr02 Solid electrolyte | 0(Pb + Sn), Cermet, Pt. Alcock and Richardson's quasi-chemical equation, with the coordination number of atoms set to 2, is found to predict successfully the activity coefficients of oxygen in these alloys. The relative partial molar enthalpy and entropy of oxygen at 1 atom per cent in the alloys have been calculated from the variation of the activity coefficient with temperature. The addition of Sn to an unsaturated solution of O in Pb is shown to decrease significantly both the partial molar enthalpy and entropy of O. As the measurements were restricted to a narrow range between 750 and 1100°C in Pb-rich alloys, however, the pronounced variation of the partial molar enthalpy of O with temperature at constant alloy composition predicted by the quasi-chemical model could not be verified.

Dec 1, 1971

By P. Seppanen

Cemented fill was first introduced at the Keretti mine in 1952, but entailed high cement costs, the need for stope preparation, slimes handling, clean-up and maintenance, increased mine dewatering, segregation of fill and long setting times. In the 1970s research began into the use of iron blast-furnace slag as a binding agent and by 1989 Pyhasalmi, Vihanti, Keretti, Vammala and Enonkoski had saved US $11 000 000 by using slag binders instead of cement. Viscaria in Sweden and Tara in Ireland also use slag as 90-100% of total binder, although their backfilling methods vary. The main area of interest in slag research is determining the activation methods for initiating the binding reactions; it is also important to achieve other characteristics such as resistance to corrosion by sulphuric ion. New backfilling techniques developed during the 1980s included the use of high-density cemented tailings fill at Vammala and porous cemented rockfill at Enonkoski and Viscaria. Future developments focus on concepts such as integration of mining and milling with backfilling and the achievement of total underground disposal of wastes

Dec 1, 1995

By J. Temporal

An introduction to the conference material in this issue is given together with the issue contents list, closing remarks by its chairman Dr. J. Temporal, the list of contributors and their companies, and the information that the 26th Sir Julius Wernher memorial lecture had had to be presented by the lecturer's wife, M. Biggart, in his absence due to site problems on the Storebaelt project

Jun 16, 1905

By A. E. Tercan, D. Mamurekli

Ordinary kriging on the assumption of a gaussian error distribution and indicator kriging were used to derive the probability that a given calorific value would or would not be exceeded by coal from an area of a deposit. The two techniques led to similar probability maps despite local differences; the lack of an absolute reference makes it impossible to judge which method is better for this particular application

Jun 19, 1905

By G. Zhan, P. Mousset-Jones, G. Danko, J. J. K. Daemen, C. Mezei

Paper presented at the conference Risk assessment in the extractive industries, held in Exeter, 23-24 March 1994, and first published London: IMM, 1994, preprint volume. 18pp., 12 refs. (Originally entitled: Tunnel roof diagnosis using a robotic sensor test bed.) An integral roof diagnosis method is proposed to assist in assessment of risk regarding the stability of an excavation. A Robotic Sensor Test Bed (RSTB) is being developed for the characterisation of roof stability. The sensor test bed consists of a sonic/ultrasonic wave response sensor, a laser surface profiler and a surface temperature sensor. These sensors are mounted on an articulated robot manipulator for performing remote-controlled or fully automated diagnoses. A number of laboratory and field sonic/ultrasonic tests were conducted. A high-energy ultrasonic transducer and an impact device were used to resonate rock slabs. The fracture depths of the slabs were found to be inversely related to the measured resonance frequencies. The agreement between identified and actual dimensions was acceptable. Field tests also showed that loose rock on the surface can be clearly distinguished from solid formation by comparing their wave responses. The robotic laser profiler part of the RSTB was used to measure surface geometry. Different scanning methods are being developed to achieve the fastest and most precise measurements and to provide pertinent information about rock joints and major fractures

Dec 1, 1994

By A. L. W. Lips, T. J. R. Barclay, E. Rothery, S. H. White

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994 (originally entitled: The Broken Hill base metal deposit - a tectonically transported and modified basinal deposit within the Proterozoic Willyama fold and thrust belt). A regional structural study was undertaken which incorporated the role of shears. Their positions were identified from earlier mapping, from regional aeromagnetic data and by additional field work. Kinematic studies determined movement histories and petrological studies of the fault rocks formed within the shears identified the relationship between the movements and regional metamorphism. It was found that the shears formed a part of an earlier, major thrust event with transport from NW to SE and a later, minor one in the reverse direction. Neither had any significant effect on the mineralisation apart from local displacement, but the shuffling of the basin stratigraphy adds to the difficulty of recognising the original volcanic and sedimentary protoliths of the metamorphosed sequence. The mineralisation at Broken Hill mine is confined to a single recognisable thrust slice within a shear corridor. It is stratabound with locally transgressive remobilisation due to the high-temperature thrusting and some metasomatic alteration as a result of the retrograde shearing. This variation accounts for the different genetic models applied to the deposits in the past

Jun 17, 1905

By B. H. Smith

"Most of the discoveries of nickel sulphide deposits in Western Australia have followed the search for gossans. The chances of further discoveries depend on improving our understanding of the cover of strongly leached and transported materials that obscure approximately 85% of the area of the Yilgarn Block that has nickel sulphide mineralization potential. The lateritic profiles that are observed on the Yilgarn Block today were formed over a period of more than 100 m.y. of warm and humid climates. This lateritized land surface has been preserved by induration during subsequent arid climates as well as by the structural stability of the Yilgarn Block.In geochemical surveys of lateritied terrain samples have to be taken from at least the saprolite zone usually by drilling so that confident predictions can be made of the significance of analytical data. Account must be taken of the mineralogy of samples, as well as the nature of the horizon of a laterite profile that is being sampled, owing to the concentrating effects on trace elements of Fe and Mn oxides.Multivariate techniques have been applied successfully to analytical data in gossan recognition when textural evidence is ambiguous. Pathfinder geochemistry has also been used in gossan recognition and the most significant recent advance has come from studies of platinum group metals in nickel sulphides and their dispersion during weathering."

Jan 1, 1984

By D. L. Buchanan, ed. sci.

The issue comprises 10 contributions on PGE mineralisation, of which 9 were presented at the symposium organised by the IAGOD Commission on Ore Deposits in Mafic and Ultramafic Rocks and the BRGM-CNRS University of Orleans research group. The editor's introduction and summary of the papers is presented together with the title page, contents list and cover photograph of a harzburgite ridge, dunite boundary and chromite quarry in the Shetland ophiolite on Unst

Apr 1, 1994