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By B. Gazea, A. Kontopoulos, A. Kourtis, K. Adam

Static tests give a measure of the balance between acid-producing and acid-neutralising mineral components in a material, while kinetic tests determine acid generation and neutralisation over a long period. Drill-core samples from the amphibolite and gneiss host rocks of the Stratoni lead-zinc sulphide deposit in Greece and mine/mill waste samples from Stratoni and Olympias were examined by the standard acid base accounting, BCR and net acid production tests. Mineralogical data on the materials and resulting residues were used to illustrate the differences between the methods and establish their ranges of applicability. BCR seems to simulate most closely the conditions prevailing during generation of acid mine drainage but is time-consuming and requires elaborate equipment. Acid base accounting is suggested for standard screening; net acid production might be used in the field or for solids with less than 10% S

Jun 19, 1905

By I. A. Scott, T. J. Napier-Munn

Size-by-size partition curves for mineral separation in dense-medium cyclones pivot about a single characteristic point. This is defined for stable, non-segregating media by the medium density and the proportion of the medium reporting to the underflow. The pivot point departs from these values for unstable, conventional media. The phenomenon can be represented by an equation with two parameters defining pivot point coordinates and two the Ep value. On the basis of experiments in a 200 mm cyclone using ferrosilicon media, simple regression equations were developed for the separation parameters in terms of operating conditions (the coefficients were likely to be site-specific). The experiments successfully decoupled the effects of medium density and viscosity and showed that the value of Ep was independent of the former but strongly dependent on the latter. A classification model was used to predict the density of the underflow medium, a knowledge of which is required to determine the pivot parameters. The model correctly reflects the performance trends observed in dense-medium cyclone operation and has the potential to be generalised to a wide range of industrial practice.

Jan 8, 1992

By A. Policard

The question, of the pathogenesis of pneumokoniosis is very important not only from the social and economic points of view but also from the purely biological. The study of the pathogenesis of the disease leads to fascinating problems of cytology and cytochemistry. Two problems present themselves for examination from an analytical and critical point of view: 1. The first reactions of the alveolar walls to inhaled dusts. 2. The precise nature of the action of mineral dusts.

Jan 1, 1947

By Ruddle R. W.

An outline account is given of the smelting of copper and the chemistry of the process. A table provides compositions of the more important minerals from which copper is won by smelting. Roasting is discussed as is smelting using reverberatory furnaces, blast furnaces and flash smelting. A brief discussion of converting covers the upright (Great Falls) converter and the horizontal (Peirce-Smith) converter.

Jan 1, 1953

By Thomas D. E.

Discussion at the Manchester Geological and Mining Society' general meeting held in Manchester, March 14th , 1916, with Leonard R. Fletcher, President, in the Chair, of a paper published in Trans. Instn. Min. Engrs., 1916, vol. L., page 482, comprised the author's written response to suggestions made in previous discussion

Dec 1, 1916

By J. Laskowski, J. Lekki

"The mechanism of joint action of a frother (alpha-terpineol) and a collector (ethyl xanthate) in the flotation of chalcocite has been examined. In order to study the dynamic effects of frother and collector in bubble-particle collisions, the following aspects were investigated : determination of zeta-potential. Measurements of the thickness of fluid film on the surface of chalcocite and adsorption of xanthate, as influenced by alpha-terpineol, induction time and flotation versus concentration of alpha-terpineol and ethyl xanthate.The mechanism of the adsorption-desorption phenomenon on chalcocite with regard to non-ionic molecules, e.g. a-terpineol, has been considered, and the influence of this on the stage and thickness of the intervening wet layer between a bubble and a particle, changing the probability of collision and attachment, is suggested."

Dec 1, 1971

By M. W. Davies, P. N. Smith

The activity of MnO has been measured in the system CaF2-MnO at 1773 and 1873 K and in the system CaF2-CaO-MnO at 1773 K by the method of equilibration with platinum. Large positive deviations from ideal solution laws have been found, but these became less as the lime content rose. The loss of a volatile component made activity measurements impossible in the CaF2-AI203-MnO system, but the boundaries of a two-liquid region have been measured at 1773 K.

Dec 1, 1971

By L. J. Cabri

Although no complete mineralogical balances have been published, the background knowledge and proven, highly sensitive analytical techniques to produce them already exist. For PGE-Cu-Ni sulphide ores a combination of ore microscopy, image analysis and electron microprobe analysis with proton microprobe analysis of sulphides for Pd, Rh and Ru and ion microprobe analysis for Pt, Ir and Rh (in some minerals) should provide the necessary data when combined with reliable assays. Other sulphide ores, such as the Cu-Ni-(PGE) ores of Sudbury, Ontario, require a similar approach except that the ion microprobe would be more suitable for the analysis of Pd, Pt and Rh because of its greater sensitivity. Oxide-silicate ores may be harder to deal with quantitatively, although the potential to confirm the presence of trace PGE within silicates and oxides may be greater than in PGE sulphide and Cu-Ni-(PGE) sulphide ores. However, solid solution of PGE in oxides and silicates still requires thorough documentation and evaluation in terms of their significance for the overall metallurgical balance

Apr 1, 1994

By C. H. J. Beaven, M. P. Jones

Since the various new techniques of automation and computing have enabled vast numbers of mineralogical observations of relatively small samples to be made cheaply and rapidly, the statistical assessment of these measurements has become of vital importance. Much of the theory and most of the procedures of sampling that are used in the mineral industry are based on Gaussian statistics, but modern measuring techniques show that many mineralogical parameters do not necessarily follow the Gaussian distribution function. Consequently, it has become necessary to examine the application of other, more suitable statistical methods in order to derive the maximum amount of useful information from the examination of mineralogical samples. Some of the errors that can be introduced by the use of incorrect distribution functions are discussed and the value of determining the function that is appropriate to the particular parameter that is being measured is shown. Examples are provided of non-Gaussian distribution functions in mineralogical materials that were encountered during prospecting and during mineral treatment operations: a Canadian uranium ore, a Thai tin ore, and gold ore tailings.

Dec 1, 1971

By Winmill T. F.

(Paper presented at the Institution of Mining Engineers' general meeting held in London on 8th June 1916.) The conclusions reached in this paper may be summarized briefly as follows: (1) The method of estimating moisture in coal by determining the loss in weight of a sample heated to 105°-110° Cent, in an air-bath for an hour is untrustworthy, the results so obtained being too low. (2) Dried coal has a very considerable power of absorbing moisture, and a sample, after being dried, must be protected instantly if it is to remain free from moisture. (3) A fairly accurate estimation may be made by heating the coal in a current of dry air at 105° to 110° Cent., and collecting the moisture evolved. (4) In cases in which it is proposed to use the dried coal for any further experiments, the drying must be done in the absence of oxygen, and this can be done simply and quickly by the vacuum method now described

Dec 1, 1916

By NA NA

Hausherr UK Limited Win Order from Italian Cement company Cementerie Di Sardengnu SpA, Qualler Hall complete head gear switch in three weeks, Chief Mins Inspector 'cautiosly optimistic' on safety standards at Privatised Pits.

Jan 11, 1996

By E R. Hassall

Discussiong the importance of minerals and mining, impacts on the environment and remediation, and the need to foster interest in science among young people.

Jan 8, 1997

By H. B. Bell, L. C. Smith

Measurements have been made of the activity of 'FeO' in 'Fe0'-Mn0-Ti02 melts at 1475 degrees C. The results obtained are discussed in terms of ideal mixing of titanates and in terms of a regular solution model. On the basis of the regular solution model activities of Ti02 and MnO in the Fe0-Mn0-Ti02 and Mn0-Ti02 systems have been derived. The data have been shown to be consistent with the liquidus lines in the phase systems. Examples are given of the application of the data to slag-metal equilibria, being used to derive slag-metal data between liquid iron and Fe0-Mn0-Ti02 slags

Dec 1, 1971

By J. Plant

Stream-sediment sampling undertaken to define the regional geochemistry of northern Scotland is described with particular reference to the errors involved. The region is underlain essentially by Moine schists, Caledonian granites and Old Red Sandstone sediments, which are generally characterized by low geochemical relief. Factors in the secondary environment obscure the relationship between trace-metal concentrations in stream sediments and bedrock geology. Investigation of sampling and sample preparation methods indicates that the -100-mesh material is the optimum size fraction for the regional survey of this area: it provides adequate geochemical contrast: it reduced the incidence of spurious high values in the samples investigated and it is available in amounts which are adequate for all the analyses required. Grinding samples improves precision and reduces the preferential volatilisation of metals coprecipitated with hydrous manganese and iron oxides for the optical emission spectroscopic method used initially. A study of the dispersion of metals in the drainage system of an area of Pb-Ba-Mo mineralisation and an area of U-Pb mineralisation, respectively, indicates that a sampling interval of 1 per 2 km2 based on second- or third-order streams is adequate to define anomalous metal concentrations. Regional variation can also be represented on the same interval. Modifications to the sampling procedure to reduce the effects of the secondary environment are complicated by the primary association of Mn and Fe with mineralisation in the area. The ratio of analytical and sampling error to regional variance shows that procedural precision is adequate to prepare regional geochemical maps of northern Scotland, with the exception of Cr, Cu at low concentrations and Pb.

Dec 1, 1971

By Fearnsides W. G.

Discussion at the The Midland Institute of Mining, Civil and Mechanical Engineers' general meeting held in Doncaster on 27th May 1916, on the paper published in Trans. I.Min.E., vol.LI, 1916, p.409-448, included oral contributions by Lupton A. on the mechanisms of subsidence and water egress and by Kendall P.F. on the validity and accuracy of the contour extrapolation technique and the effect of major faults, together with the author's response

Dec 1, 1916

By D. J. Fray, F. Tailoka

Microporous ceramic tubes (15 micrometre pore diameter) and PVC membranes (10 micrometre diameter) have been used as spargers in the electrowinning of copper from concentrated and dilute chloride electrolytes. At a current density of 600 A/m2 and a nitrogen gas sparging flow rate (at NTP) of 1.53 cm3/s per unit electrode length, it was possible to electrowin planar rather than powdery deposits with copper concentrations as low as 0.157 M. To obtain a planar deposit at higher concentrations of cupric chloride the most realistic optimum current density appears to be between 1 000 and 1 500 A/m2.

Jan 4, 1993

By M. Riddell

This paper describes the incipient heatings that occurred below ground in the High Main and Main seams at the mine between the years 1963 and 1966. The possible causes, effects and activities associated with such heatings are discussed in an attempt to establish the precautions necessary to minimize such occurrences. The assessment of as many "norms" as possible is made to enable the earliest detection and level of activity to be determined.

May 23, 1905

By Tawsaporn Nuchanong, Ian Nichol

Investigations of the dispersion of gold in soils and stream sediments associated with three gold deposits in Thailand indicate the existence of different geochemical dispersion patterns in the three areas, demonstrating the need for the adoption of a variety of exploration techniques. The three gold deposits which were investigated were the Phu Tham Phra-Phu Thong Daeng copper-gold prospect, the Doi Tung and the Huai Hin Lab gold prospects. Overall the investigations at the three localities demonstrate clearly that the chances of exploration success can be significantly enhanced if composite soil samples are analysed to ensure a more reliable estimation of the gold content in soils and if both the 63 micrometre fraction and the field-panned concentrates of stream sediments are analysed because of the variable grain size of the gold characterising different gold deposits and surface environments.

Jan 4, 1992

By J. C. Griffiths

There are two kinds of problems concerning the elements of a population : the first is to estimate the proportion of some specific kind of element in the population, e.g. the amount of gold in a block of ground (equals population) or the proportion of mercury in a sample; the second is to estimate the length, breadth, volume, etc., of a specific kind of element, e.g. the grain size of quartz grains in a beach sand or the size, shape and arrangement of lenses of ore in an ore deposit. Given a specific objective, a bounded population, identified elements and the element characteristics of interest, it is then necessary to select a sample of the elements from the population and the problem of sampling requires a decision on how to select the sample. It is also necessary to establish, either by heuristic analysis or empirically, based on long experience, the model frequency distribution of the desired element characteristics: in general, constant-probability models are used as models, the binomial or Poisson for count data and the normal distribution for measurements (or their transformed equivalents). The objective of sampling then becomes to obtain an appropriate statistical estimate of the desired population parameter: for example, the estimators may be the mean (X) and variance (a2): these should be unbiased sufficient estimators of their corresponding parameters (u, a2, respectively). Statistical tests are performed in order to determine that the estimators are of the appropriate kind: all statistical tests are designed to test against bias of a specific kind, although they are stated as tests against randomness. Given a random sample of some population, the estimators are usually stable and adequate to solve the sampling problem. Random samples are simple to define but exceedingly difficult to achieve in practice: in selecting a sample, if every element in the population has an equal chance of occurring, then the sample is a random sample. Interaction between the arrangement of elements in a population, i.e. its structure, and the sample selection process frequently introduces bias—that is, some elements have more chance than others of appearing in the sample and, hence, the sample is not random. An algorithm for dealing pragmatically with this aspect of the sampling problem offers one way of achieving random samples and, therefore, adequate estimators. Examples of the use of this algorithm on various kinds of geological populations, in both field and laboratory, illustrate the requirements for solving sampling problems and the achievement of appropriate estimators.

Dec 1, 1971

"The Archaean komatiite-associated nickel sulphide deposits at Kambalda, Western Australia, exhibit a number of stratigraphic features that are indicative of a strong volcanic control on ore localization, including (1) a restriction to specific basal cumulate metakomatiite host units, (2) confinement within distinctive synvolcanic embayments in the footwall and (3) variations in the internal structure and composition of overlying and adjacent barren metakomatiite flow's and the distribution of interflow metasediments with proximity to the ore zones.The high magnesium content of the host units (up to 45% MgO volatile-free) in comparison with that of aphyric or spinifex- textured lavas (16-32% MgO) has been considered previously to indicate either magmas/lavas rich in intratelluric olivine or selective accumulation of olivine phenocrysts. The marked linear trend of the oreshoots, basal host units, footwall embayments and the volcanic stratigraphic relationships have been used as evidence for local linear feeding fissures. Rare relict igneous olivine in some host units is, however, demonstrably not intratelluric, and there is no direct or indirect evidence of a proximal eruptive site (e.g. footwall feeders, pyroclastic breccias, ultramafic intrusives) at Kambalda such as at some other deposits of this type. Kambalda is interpreted as a distal rather than proximal volcanic environment.Emplacement of the komatiite sequence at Kambalda was probably controlled by the locations of a few specific eruptive sites relative to regional topographic gradients and influenced by the topography of the pre-existing volcanic surface. Olivine enrichment in the basal host units occurred by in-situ fractionation and cumulus crystallization of olivine during longitudinal lava flow within linear lava conduits, possibly centralized on depressions between non-overlapping footwall basalt flows. The distinctive stratigraphic relationships are attributed to localization of lava conduits along the volcanic pitchline, flanked by more slowly moving parts of the flows. There are analogies with the physical volcanology of Modern basaltic and Proterozoic komatiitic lava flows.A corollary of this model is that the lava conduits thermally eroded and assimilated sulphidic sediments, contributing additional sulphur to sulphur-saturated komatiites or possibly inducing sulphide separation in originally sulphur-undersaturated komatiites. The latter would account for the restriction of ores to linear cumulate komatiite host units (thermally active lava conduits) and the locally mutually exclusive, but stratigraphically equivalent, relationship between the ores and sulphidic metasediments at Kambalda."

Jan 1, 1984