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By Elizabeth A. Johnson

The vaporization thermodynamics of the aluminum-silicon carbides Al4SiC4 and Al8SiC7 were studied by the Bureau of Mines over the temperature range of approximately 1,500 to 1,700 K. Vapor pressures were measured by a Knudsen effusion-mass spectrometry technique in which powdered samples were effused from graphite crucibles through small orifices. For each compound, a total of six orifice diameters was tested to verify equilibrium within the cell. Aluminum, mass number 27, was the only vapor species detected over the range 4 to 200 amu. Experimental results are based on the following equations for incongruent decomposition: A14SiC4(cr) - 4A1(g) + SiC(a,hex) + 3C(gr); Al8SiC7(cr) - 8A1(g) + SiC(a,hex) + 6C(gr). The observed vapor pressure-temperature relationships determined with a cell orifice area of 2.0 x 10-3 cm2 for Al4SiC4 and 1.81 x 10-3 cm2 for A18SiC7 are the following: Log P - (-18,682/T) + 12.476, for Al4SiC4 (1,550 to 1,643 K) and Log P = (-19,308/T) + 12.421, for Al8SiC7 (1,526 to 1,784 K), with P in pascals and T in kelvins. Third-law analysis of the data provided the following heats of formation: A14SiC4 ?H at 298.15 K - -50.0 kcal/mol and A18SiC7 ?H at 298.15 K - -92.1 kcal/mol.

Jan 1, 2011

As fulfillment of the requirements of Contract H0387019 for the United States Department of the Interior, Bureau of Mines, a complete field kit, for performing on-site determinations of individual employee Time Weighted Average (TWA) exposures to nitrogen dioxide (NO2) and nitric oxide (NO), has been developed by MDA Scientific, Inc. This report provides background information and experimental data validating the use of this kit with confidence to ? 10 percent accuracy.

Jan 1, 1981

By D. Harrington

In this period of generally increasing taxes of various kinds, one hears less complaint by mining companies about the high cost of workmen's accident compensation than was the case a few years ago, the reason perhaps being that other and more pressing phases of the tax problem now over shadow the heavy expenditures for compensation premiums which a few years ago were considered a severe burden on the mining industry. Nevertheless, the financial expenditures of the mining industry in higher compensation benefits and hospitalization or in higher premium rates, or both, instead of being less have actually increased in many States in the past year. In the spring of 1937, proposals for increased benefits to injured employees in compensation, hospitalization, or medical aid were actively before legislatures in California, Connecticut, Georgia, Idaho, Illinois, Indiana, Iowa, Kansas, Kentucky, Massachusetts, Michigan, Minnesota, New Mexico, Oregon, Pennsylvania, South Carolina, Texas, Utah, Washington, Wyoming, and possibly other States. In some cases, the proposed increases in benefits were so much greater than expenditures for similar items in the past that premium rates per $100 of payroll would almost certainly rise sharply. At this same time, occupational-disease-compensation coverage also was under consideration by legislatures in Arkansas, California, Delaware, Idaho, Indiana, Kansas, Massachusetts, Michigan, Minnesota, Montana, Nebraska, New Jersey, Ohio, Pennsylvania, Tennessee, Utah, and Washington. Sooner or later (and probably within the next few years) occupational-disease compensation will be accorded practically as wide recognition as accident compensation receives at present, and, unquestionably, mining in all of its branches will be affected more or less drastically. Hence, the present outlook is that the mining industry, in company with practically all other industrial activities, will be confronted by materially higher compensation costs than those of the past or the present, to which rather violent exception has been taken, at least in some States and at some times.

Jan 1, 1938

By Gregory Krohn

This report investigates the effects of adding a layer of extra padding to the palm area of leather gloves typically worn by low seam coal miners. The first study showed that added glove padding provides more potential protection but does not affect manual dexterity. The second study, in a simulated low seam coal mine, showed no significant differences using padded and non-padded gloves in crawling, shoveling, timbering, and cart pushing task completion times. In general, subjects preferred the padded gloves although they expressed some complaints about awkardness and loss of sensitivity. Recommendations are given for the design of padded gloves that will provide comfort, protection, and maximum hand sensitivity for miners.

Jan 1, 1980

By Nan C. Jensen

Modern high-temperature metallurgical processes have created a demand for raw material for furnace parts and lining that not only will with-stand high temperatures is but will not react with the substance being melted in the furnace. Spark-plug insulators, laboratory ware, tanks for the glassmaking making industry, and saggers and kiln furniture for the chinaware and pottery trades also must be made of materials hat have high melting points. Among the minerals that can be employed for such refractory uses ore those commonly known as the "sillimanite group' -kyanite, andaluste, sillimanite, and dumortierite - and the allied minerals topaz and pinite. Consideration of the occurrence, properties, qualities, uses, and sources of supply of these commodities and the markets for them constitute the subject of this paper. General Features of Kyanite and Related Minerals Kyanite, andalusite, and sillimanite ire composed of three elements - aluminum, silicon, and oxygen ? and are called aluminum silicates. The have

Jan 1, 1943

By J. B. Littlefield

The Greenburg-Smith impinger was developed at the Bureau of Mines in cooperation with the United States Public Health Service in 1922 in the course of an investigation of dust-sampling instruments available at that time. Although it is not used extensively outside of the United States, it is now soused in this country to collect samples for the determination of any dustiness, and most of the information correlating degree of dustiness with physiological effect has been obtained by the impinger method. The chief disadvantages in the use of the regular impinger, especially in mines and other places accessible with difficulty, are its bulk weight, and power requirements. It requires a source either of electricity or of compressed air, which necessitates connections and extension of existing supply lines to each sampling point; the only alternative is the use of a relatively large pump hand-operated with considerable effort.

Jan 1, 1937

By C. W. Sill

[In the original Norris and Fay method for determining selenium, selenious acid is reduced by an excess of standard thicsulfate in accordance with the following reaction: H2Se03 + 4Na2S203 + 4HC1 = Na2SeS406 + Na2S406 + 4NaC1 + X20. (1) The excess thiosutfate is then back-titrated with standard iodine solution. The disadvantages of ouch a method are obvious. On an unknown sample, the quantity of thiosutfate required would be difficult to determine; a definite excess is required, but large back titrations would be undesirable. Inasmuch as thiosulfate is decomposed by acid, considerable error may be introduced in this method, the amount depending on the acidity, temperature, concentration of excess thiosulfate, duration of contact between thiosulfate and acid, and other factors, In a critical study of the Norris and Fay method, Coleman and McCrosky3/ show that the method is accurate to less than .1 part per thousand if the excess of this sulfate Is not greater than 5 ml. of 0.1 N solution (in 1.0 ml. of 0.x4 N sulfuric acid) whether the titration is made at 0° or 20°C. A greater excess produced unsatisfactory values at either temperature. Coleman and McCrosky regulated the excess thiosulfate by adding 5-ml. portions of thiosulfate solution followed by the addition of 1 to 3 drops of 2.5 percent potassium iodide in the presence of starch. If a starch-iodine blue color formed locally around the drops of potassium Iodide, the reduction of selenious acid was not complete. On stirring the solution, the local blue color fades and another 5-ml. portion of thiosulfate is added. When addition of potassium iodide fails to produce a local blue color, reduction of selenious acid is complete, and the excess thiosulfate is then back-titrated with standard Iodine solution. The number of equivalents involved in the reduction of selenious acid by either thiosulfate or iodide is the same, and therefore no correction need be made for the potassium iodide. This procedure is much better than the original Norris-Fay titration, but acidity and time would stilt be rather critical factors subject to variation with individual technique. Also, the method still requires the lose of two standard solutions, a rather undesirable factor from the standpoint of routine application.]

Jan 1, 1954

By William J. Campbell

This Bureau of Mines report describes a study conducted to determine the relationship of mineral habit to particle size and shape characteristics for prismatic, acicular, fibrous, and asbestiform varieties of tremolite. Particle measurements were made with the petrographic microscope at X 1,250 and the scanning electron microscope at magnifications up to X 10,000. All of the varieties of tremolite, upon Wiley milling, produced a significant percentage of particles that meet the Federal regulatory criteria for counting as asbestos fibers. However, only the asbestiform variety gave milled particles that fell into a size range of >10 µm in length and <0.5 µm in width; some medical scientists consider this range significant for production of adverse health effects.

Jan 1, 1979

By Webster S. Anderson

Bureau of Mines planer mining tests on the phosphate bed of the Douglas mine, near Drummond, Mont., indicated that a competent bed with a Mohs&apos; scale hardness of 3 to 4 cannot be mined economically with the planer. Although planer mining was feasible where the bed was fractured enough for a 4-inch depth of cut to be consistently maintained, the depth of cut in the competent beds at the Douglas mine did not exceed 0.5 inch. Average production rates were 0.15 ton per minute and 9 tons per man-shift.

Jan 1, 1966

By T. M. Romslo

"The Keystone and St. George properties are in the so-called Johnson Camp area and adjoin a property that in recent years has become a steady producer of low-to medium-grade copper-zinc ores. The Keystone Copper Co. was active intermittently from 1908 to 1938 and during 1926 to 1937 produced a recorded 1,100 tons of 5 percent copper ore. There is no evidence that ore has been produced from the St. George property.In the Johnson Camp area both igneous and sedimentary rocks ranging in age from pre-Cambrian to Quaternary are exposed. The ore bodies are in the Paleozoic rocks and occur principally in the Abrigo formation, which is composed mainly of limestones and shales. The rocks of the productive zones are metamorphosed and are cut by systems of fractures and faults. Chalcopyrite and sphalerite, the principal ore minerals, replace altered limestones to form deposits locally called mantos and chimneys.Investigation of the Keystone and St. George deposits by the Bureau of Mines included topographical and geological mapping of the surface and the underground workings and diamond drilling from the surface. A total of 10,067.8 feet was drilled in 22 holes. The drilling started November 13, 1947, and was completed August 19, 1948.This report records factual information obtained during the course of the investigation."

Jul 1, 1949

By Steven M. Shope

An essential element of the Bureau of Mines electromagnetic location and communication system for trapped miners is a quantitative knowledge of the surface and above-surface electromagnetic fields created by an underground transmitter. The field solutions given in this report use approximations in which the displacement currents are negligible for low frequencies. The earth is represented by a homogeneous half-space model in which a dipole source is immersed. The vertical magnetic field equipotential contours at and above the surface are graphically mapped. The volumes of the regions bounded by these contours are directly related to the geometrical zones of signal detectability. Knowledge of the detectability zones will enable the proper search strategies to be developed for airborne detection of trapped miners.

Jan 1, 1983

By Martin H. Stanczyk

The direct dissolution of a typical zinc sulfide flotation concentrate by elevated temperature and pressure leaching was investigated. The concentrate assayed about 55 percent Zn, 32 percent S, 6 percent Fe, and 1 percent Pb and contained minor quantities of copper and precious metals. The influence of various factors on the dissolution of the zinc in acidic and ammoniacal pulps when using oxygen as the oxidant was determined. The tests revealed that the sphalerite was difficult to oxidize. Complete dissolution of the mineral required vigorous and intimate nixing of the gaseous, liquid, and sold phases. The addition of pyrite or sulfuric acid to water slurries of the concentrate was required to obtain a high zinc extraction when leaching under acidic conditions. The quantity of pyrite and acid used was about 0.125 and 0.25 pound, respectively, per pound of zinc sulfide contained in the leach charge. In tests with acid, about 96 percent of the zinc was extracted from the concentrate in 1 hour at 200° C. when the oxygen partial pressure was 75 pounds per square inch gage or higher. Leaching with a continuous flow of air as the oxidant gave results that were almost as good as those obtained when oxygen was used, In tests with air fed through the autoclave at 320 liters per hour, 95 percent of the zinc was dissolved in 1 hour, Acid leach solutions assaying approximately 58 grams Zn per liter and containing Fe, Ni, Cr, and Cu impurities were produced in the better tests. The leached residue consisted essentially of red iron oxide together with substantially all of the lead and precious metals.

Jan 1, 1961

By W. G. Pariseau

A U.S. Bureau of Mines case study of pillar recovery in high-grade ore near the Ross shaft at, the Homestake Mine, Lead, SD, has demonstrated the usefulness of the finite-clement method for the evaluation of shaft pillar mining plans and shaft stability. This report, one of three in a series describing the Ross shaft pillar case study, focuses on the premining stability analysis. The two-dimensional computer program UTAH2 was used in advance of pillar mining; results suggested that the shaft would remain stable. Subsequent reports describe parts 2 and 3 of the study. In part 2, borehole extensometers and other instruments were installed to provide data for model verification and shaft monitoring. Results of the recalibrated two-dimensional model confirmed the premining stability evaluation. However, after mining began, great concern developed because of the appearance of cracks and other signs of ground movement over considerable distances from the area of active pillar miping. In part 3, an intense three-dimensional modeling effort using UTAH3 was initiated. The results again showed that the shaft would remain safe. Three-dimensional analyses of alternative pillar mining scenarios indicated that more of the shaft pillar ore reserve could be recovered than previously thought.

Jan 1, 2010

By F. A. Rutledge, B. S. Webber, J. M. Moss

"INTRODUCTION The United States, with its vast resources of relatively low-grade zinc been the world's leading producer of zinc -metal for many years. The expanded zinc production during the period, 1939-44, inclusive, was induced by favorable premium prices and has depleted the known ore reserves in the United States. The 1943-44 rate of zinc production cannot long be maintained in the United States, especially if premium prices are removed. Domestic zinc reserves, have been depleted to such an extent that it is doubtful if our mines will again be able to completely and continually fulfill the needs of this country.The Bureau of Mines, anticipating a postwar consumer demand for 550,000 to 750,000 tons of slab zinc and an additional 100,000 tons for use in paints and chemicals, sent two engineers to Sedanka Island in July 1945 to investi¬gate the deposits near Biorka Harbor.ACKNOWLEDGMENTIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion the Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director."

Nov 1, 1946

By John A. Organiscak

The Bureau of Mines conducted a survey of eight shearer longwall operations to identify factors that affect respirable dust generation from longwall roof supports. The longwalls surveyed were in coal seams located in different geographic regions of the United States. Data were collected on mining (geologic) conditions, support design, operational characteristics, and amount of respirable dust generated from roof supports. Analysis indicated that mining conditions are the main factors that affect the generation of dust during roof support movement. Both roof strength and depth of cover above the coal seam showed relationships with the amount of support dust generated. Several practices are currently employed to effectively control roof support dust; however, some of these controls are limited. More research and development is needed to improve dust control technology for longwall roof supports.

Jan 1, 1985

By James C. Cawley

The Bureau of Mines conducted an investigation to statistically determine the mean current or voltage for resistive, inductive, and capaci-tive circuits that would cause spark ignitions in 8.3% methane-air, 5.3% propane-air, and 7.8% ethylene-air mixtures. Each mean ignition current or voltage was determined on the basis of 100 trials. Each trial consisted of 400 revolutions, 200 in each polarity, at 80 rpm of the standard breakf1ash apparatus. In general, spark ignition curves published in UL 913 for resistive and inductive circuits represent approximately the mean current values determined in this study, while published capacitive circuit values in methane are considerably less than the mean voltage values from this study, especially for a capacitance of less than 100 ~F. For resistive and inductive circuits, spark ignitions were obtained at currents con-siderably below those in the published curves, but this study was not optimized to find minimum ignition values. This report defines "safety factor" as applied to intrinsic safety testing as the energy ratio of the mean values of ignition current or voltage for two test gases. The safety factors presented in this report are not constant with voltage or current and, therefore, are not recommended for use.

Jan 1, 1986

By R. E. Coleman

The molecular species occurring at the mineral-reagent interface of the galena-aqueous potassium ethyl xanthate system was studied by developing a technique for using an attenuated reflection method in conjunction with standard infrared spectroscopy procedures. Lead ethyl xanthate was detected from the infrared spectra of all galena surfaces treated in the pH range of 7 to 11. At pH 8.5, lead ethyl xanthate formed as a film chemically bonded to the galena surface. A solvent extraction sampling method was employed with infrared spectroscopy to obtain quantitative data on the lead ethyl xanthate removed from the galena surface. The data showed that between pH 7 and 11 thy quantity of lead ethyl xanthate physically adsorbed decreased as the pH was decreased; in the same pH range, the quantity of free lad ethyl xanthate in the aqueous medium remained constant, and the amount of unreacted xanthate varied.

Jan 1, 1966

By Charles Will Wright

The purpose of this paper is to present briefly certain preliminary results of the study of mining methods by the United States Bureau of Mines; to show the relative importance of each method in terms of tonnages mined and man-hours consumed; to give to the mining engineers and particularly to the young student of mining a better understanding of the principal mining methods; and to indicate changes now in progress and to present suggestions for improvements in the art of mining. Questions of mine development and details of underground practice such as drilling and blasting, loading, hauling, hoisting, ventilating, pay systems and mine management are omitted, as these have been or will be discussed in other bureau publications.

Jan 1, 1931

By Bernadette C. Michalski

Mineral raw materials, labor, capital, and technology form the basis of industrial production. The augmentation of one or all of the elements--labor, capital, and technology--will result in industrial growth. Thus, an increase in the labor force would increase output. A similar result would be achieved by expanding capital investment and supplying labor with more equipment. Finally, industrial growth can be achieved by introducing more productive methods and techniques born of technological advancement. The Soviet Union has employed these elements in many patterns to catapult from an agricultural to an industrial economy in four decades. The early history of the Soviet Union was marked by limited capital and borrowed technology, forcing the Soviets to concentrate on an abundant labor reserve to support the industrial program. The source of this reserve was the rural population. In [1928], 80 percent of the working population was employed in agriculture. This figure dropped to 43 percent by 1956, whereas industrial employment in the same period increased from 8 to 31 percent.3/

Jan 1, 1960

By John C. Machisak

The thirty-fifth consecutive National Safety Competition sponsored and conducted annually by the Federal Bureau of Mines, Department of the Interior, closed with several noteworthy accomplishments to its credit. Some of them are: 1. A record low injury-frequency rate of 18.293 disabling work injuries per million man-hours equal to that established in 1957. 2. The third lowest injury-severity rate (4,335). 3. The second highest number of mines and quarries participating (672) 4. A record number of participants finishing the competitive year without a disabling work injury. 5. All recipients of Sentinels of Safety trophies free of disabling work injuries for the first time since 1952.

Jan 1, 1961