Search Documents

By R. Blickensderfer

Laboratory wear testing was conducted by the Bureau of Mines on a variety of typical wear-resistant alloys used in mining and mineral-processing equipment to establish their relative spalling and abrasion resistance. Test specimens in the form of 75-mm-diam balls were subjected to repeated impacts until they broke, spalled excessively, or received several hundred thousand impacts. Pin specimens removed from the balls were evaluated for high-load abrasive wear. The alloys in-cluded commercial forged steels, cast steels, manganese steels, and four types of white cast iron, with a range of heat treatments. The effects of hardness and microstructure on impact wear and abrasive wear are discussed. The data should help mine operators select the compositions and heat treatments that best suit service conditions.

Jan 1, 1985

By Richard D. Miller

This publication contains routine analyses and related source data for 295 natural gas samples from 18 States collected during calendar year 1963 as part of a continuous survey of the United States for occurrences of helium in natural gas. This survey has been conducted by the Bureau of Mines since 1917. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863/ and 576.4/

Jan 1, 1965

By Bernard Lewis

This report summarizes fundamental research and technical studies conducted by the Explosives and Physical Sciences Division of the Bureau of Mines from July 1, 1949, to June 30, 1950. It is the fourteenth of a series of annual reports whose aim has been to bring to the reader a résumé of the research results that have appeared in published form during each fiscal year under the authorship of members of the staff. These are referred to throughout the report.

Jan 1, 1951

By W. J. Kroll

This report on the bibliography of zirconium has been confined to those publications and patents that appear to be useful in the commercial development of the metal, both the malleable and the nonmalleable. The methods of production have been stressed and special attention has been given to the alloys. Compounds of importance, like the oxide and chloride, for the manufacture of the metal or of the alloys have been considered. The use of the oxide in refractories anal in the glass and porcelain industries has been omitted. The present survey is critical; that is to say, an attempt has been made to evaluate the effectiveness of suggestions made in the literature. The exhaustive work of Marden and Richy, Bureau of Mines Bulletin 186, published in 1921, has been taken as a base to start from with the intention of bringing the subject up to date with material published in the last 24 years. During this time there was considerable 'advance in the preparation of the metal and Its alloys, and in the development of new uses. On the other hand, there was little progress in the methods of decomposing the ores, so that the chapter on this latter phase is necessarily short.

Jan 1, 1946

By Serge Rudchenko

A study to determine the potential use of retaining structures in open pit backfilling. Research and review of the open pit mine environment, mine waste disposal, and past and current use of retaining structures. A development of specific structures, the culvert/ tunnel concept, and an anchor block retaining concept. The cost benefit of retaining structures used for in-pit backfilled waste.

Jan 1, 1981

By W. Dan Walker

In an effort to keep mine hoist accidents to a minimum and to impart to managers and workers the essential elements that enter into safe installation and maintenance of hoisting equipment, the Bureau of Mines presents this Information Circular as a guide. Hoisting of men and materials is an essential operation in many mines and has become so commonplace that some persons are likely to ignore day-to-day inspections or become lax in the operating phases. With proper maintenance and operation, hoists can be exceptionally safe. However, lack of strict attention can invite tragedy or costly shutdowns.

Jan 1, 1961

By H. Reginald Hardy

This report describes the results of a research project carried out to investigate the feasibility of using transducer arrays, located on surface or in shallow boreholes, above an active coal mine to detect and locate the source of underground microseismic activity which normally occurs during mining. The initial stage of the project involves the design and development of a self-contained mobile microseismic monitoring facility capable of use in remote field locations. Following this a variety of transducers, and transducer field installation techniques were investigated to obtain optimum sensitivity and high signal-to-noise characteristics. Preliminary efforts were also undertaken to develop semi-automated techniques for analysis of microseismic field data. Using the facilities and techniques developed field studies were carried out at a number of surface locations over a central Pennsylvania coal mine operating at depths of the order of 500 feet. In particular studies were con-ducted over a previously mined development area, troubled by extensive problems of roof instability, and over two longwall panels during mining. Although many of the field studies were carried out during the development stage of the project, results in general have been most encouraging. Limited results were obtained over the development area, however excellent microseismic signals, correlating with underground strata instability, were detected over both long-wall areas, proving the general feasibility of surface monitoring techniques. More recent studies, carried out as part of a subsequent project, and utilizing modified geophone installation techniques at a third longwall site, have verified explicitly the feasibility of measuring underground microseismic activity from surface locations. Sections of typical field data are included in this report along with a brief review of the studies carried out at each of the field sites. Detailed analysis of data obtained at the second and third longwall test sites will be presented in a later report.

Jan 1, 1974

By L. J. E. Hofer

THIS BULLETIN analyzes and summarizes research at the Bureau of Mines dealing with the preparation, properties, and reactions of iron carbides in the period 1948-60, part of which was sponsored by Wright Air Development Laboratories. The objective was to develop better catalysts for the synthesis of methane and higher hydrocarbons from hydrogen and carbon monoxide. The investigations resulted in the first adequate characterization of epsilon iron carbide, which later proved to be an important intermediate in the tempering of martensite in steel. At temperatures near 170° C, the carbon in carbon monoxide reacts nearly quantitatively with finely divided alpha iron to form an iron carbide in which the metal atoms occupy the positions of the close packed hexagonal arrangement with lattice parameters of ao=2.754 A and co=4.349 A. The carbide has a composition within 2 atomic percent of that required for the formula Fe2C, a Curie point of about 370° C, a specific magnetization of 160.4 ergs per gauss-gram Fe at 50° C, and a ferromagnetic moment of 1.70 Bohr magnetons. Epsilon iron carbide can be converted to chi iron carbide by thermal treatment at 343° C for about 70 hours. The chi iron carbide so formed has a Curie point of 247° C, a specific magnetization of 142.5 ergs per gauss-gram Fe at 50° C, a ferromagnetic moment of 1.72 Bohr magnetons per iron atom, and a paramagnetic moment of 5.5 Bohr rnagnetons per iron atom. Direct synthesis of this carbide from carbon monoxide at 240° C indicates a composition within 7 atomic percent of that required for Fe2C. Chi iron carbide can be converted to cementite at 550° C in about 315 minutes. The theta iron carbide so prepared has a Curie point of 210° C, a specific magnetization of 147.3 ergs per gauss gram Fe at 50° C, a ferromagnetic moment of 1.72 Bohr magnetons per iron atom, and a paramagnetic moment of 3.9 Bohr magnetons per iron atom. Pure chi iron carbide reacts to form theta iron carbide by the elimination of free carbon. In the presence of an excess of free iron in intimate contact with the carbide, chi iron carbide reacts with the free iron to form theta iron carbide. The second reaction proceeds at an appreciable rate at 320° C and can be used to snythesize finely divided theta iron carbide with no free-carbon impurity at low temperatures. The ease of the reaction in the presence of free iron suggests that chi iron carbide is an intermediate in the tempering of epsilon iron carbide to theta iron carbide as it proceeds in steels. Experiments on carbon steel show that the magnetic moment of the iron atoms in martensite is about 2.2 Bohr magnetons per atom, a value approximately the same as that of the iron atoms in alpha iron. The Curie points of epsilon iron carbide, chi iron carbide, and theta iron carbide were found -in various specimens of tempered steel to be 10° to 20° C lower than normal values. This shift is probably the result of manganese in solid solution. Preparations of various compositions of epsilon iron carbonitrides show many effects of extensive isomorphism between epsilon iron carbide and epsilon iron nitride. The action of carbon monoxide on finely divided alpha iron at 400° C results in free carbon deposits containing filaments about 0.1 micron in diameter and several times as long. The filaments are characterized by nuclei of dense material located midway from each end of the filament. Although carbiding to near completion at 240° C over periods of about 300 hours produces a preparation containing no appreciable percentage of epsilon iron carbide, very brief periods of carbiding of the order of a minute result in the formation of detectable epsilon iron carbide even at temperatures as high as 325° C. The data indicate that epsilon iron carbide is an intermediate in the formation of chi iron carbide during its formation from carbon monoxide in the gas phase. Attempts to convert cementite to chi iron carbide by cold work increased the Curie point but did not change the X-ray powder diffraction pattern.

Jan 1, 1966

By Harry R. Nicholls

A simple economical method has been developed for determining the in situ longitudinal and shear velocities in rock from which its elastic constants can be calculated. By detonating small charges of high explosives in shallow drill holes near a free surface, both longitudinal and shear waves were generated simultaneously. Accelerometers and velocity gages mounted to the rock surface were used to record the arrival time for both waves over travel path lengths from 50 to 450 feet, Measurements were made in two rock types. From the arrival time measurements, the longitudinal and shear wave velocities were calculated. From these velocities and the density of the rock, the elastic constants were calculated. The dynamic elastic constants of drill core samples of the two rock types were determined in the laboratory by the resonant-frequency method, The lab- oratory and in situ elastic constants are compared and significant differences noted. In general, there is less spread in the in situ data than in the laboratory data, and Poisson's ratio does not fall outside the theoretical limits for the in situ data as is often the case for laboratory-determined elastic constants.

Jan 1, 1961

By George L. Richert

The Minas de Matahambre is situated on the north coast of Cuba, in the Province of Pinar del Rio, approximately 150 miles west of Havana. This nine is the only producer of copper in Cuba, and has been worked for the past 15 years. In 1921 the property was affiliated with The American Metal Co., Ltd., and has been worked by them since that time under the direction of Mr. D. D. Homer, General Manager. Extracts from P. D. Wilson's ?Preliminary report on the geology at Minas de Matahambre? have been freely used in this report.

Jan 1, 1929

By Oliver C. Fursman, Lloyd H. Banning

This research was undertaken to determine the feasibility of producing steel from hydrogen - reduced , pyrophoric iron powder . Before steelmaking tests were begun , investigations were made to develop procedures for handling the pyrophoric powder safely , and melting tests were made in a single - phase , electric - arc furnace to determine inert gas requirements for preventing powder oxidation . Steelmaking tests were conducted in a conventional electric - arc furnace , usually by a two - slag basic procedure . Results of the research indicated that ( 1 ) pyrophoric powder can be handled safely and can be prevented from oxidizing excessively during charging and melting in electric - arc steelmaking furnaces ; ( 2 ) little , if any , more electrical energy is required for melting Cerro Bolivar iron powder per unit of contained iron than is required for melting heavy melting scrap ; ( 3 ) high - quality steel can be produced readily from high- grade iron powder , having recoveries up to 95 percent of the total iron ; ( 4 ) steel can be produced from simulated titaniferous , chromiferous , and manganiferous iron powders ; and ( 5 ) the electrical energy required for melting increases with increase in the proportion of slag - forming constituents in the furnace charge .

Jan 1, 1964

By Robert Stefanko

Test procedures for evaluating underground coal mine trailing cable splices are formulated. The tests are utilized to evaluate several trailing cable splices. The laboratory results are compared with actual field observations and experience. The results are utilized to define quantitatively the generalized terms of the 1969 Health and Safety Act. Recommended specifications and procedures for testing by MESA Department of Approval and Testing personnel are included. Failure points in splices are detailed and presented for use by a MESA training program and manufacturers attempting to improve product quality.

Jan 1, 1974

By R. D. Berkenkotter

This report describes a weighted method for evaluating the mean and variance of assay data from samples of different length . The method , which produces unbiased estimates from which valid confidence limits can be computed , is appropriate for bedded deposits of variable bed thickness and for vein deposits of variable vein width . Assay data from the bedded Florida phosphate deposit is used to illustrate the procedure .

Jan 1, 1964

By E. H. Boyle

The Bureau of Mines has evaluated the potential availability of silver from 436 mines and deposits in 41 market economy countries (MEC?s) comprising five major economic categories of deposits: predominantly silver deposits and predominantly zinc, lead, copper, and gold deposits. This study evaluated the long-term cost and availability of primary silver production from 53 producing and 13 nonproducing predominantly silver properties in 11 MEC's and estimated the total recoverable silver from 370 properties as a coproduct or byproduct of zinc, lead, copper, or gold production. This study resulted in estimates of a demonstrated resource of 5.99 billion tr oz of recoverable silver as of January 1984. Of this total, 23.5 pet is in the 66 mines and deposits classified as predominantly silver properties. The largest quantity of recoverable silver, 43.9 pct, lies in the 121 properties classified as predominantly zinc, with 26.5 pct in 120 properties classified as predominantly copper, 4.1 pet in 21 predominantly lead properties, and 2.0 pct in 108 predominantly gold properties. At current silver prices, the economics of silver production favor silver that is a byproduct or coproduct of zinc, lead, copper, or gold, and much of the silver production in the United States from the predominantly silver mines is at an economic disadvantage in comparison with silver production in other countries.

Jan 1, 1986

By R. S. Dean

The development of metallurgical processes may be divided into periods : First , the discovery of a basic reaction which brings about the production of the desired product from the available raw material ; second , a long stage of mechanical development during which little or no attention is paid to the reaction itself ; and third , a careful study of the reaction . Most metallurgical processes are to -day approaching the end of the second period . This we may illustrate by the steel process . The reaction of carbon with iron ore to produce pig iron and the subsequent refinement of the pig iron by an oxidation reaction is very old . Development in modern times has been almost entirely mechanical , the development of the blast furnace , furnace , the Bessemer process , the Siemens process , and even the Aston process for wrought iron being mechanical improvements almost entirely . Metallurgy is now entering a phase where the reactions are being considered . The question of how far can they be made to proceed is being repeatedly asked . As mechanical processes are improved , we approach a limit to which our basic reactions can be pushed which is determined by the nature of the reactions themselves . We want to know : How far can iron be decarbonized by iron oxide ? How low can the oxygen of copper be reduced by any given reaction? How efficiently can the fuel in a zinc reduction process be used ? The demand for purer metals and lower production costs has forced these and similar questions upon us . How are we to answer them ? The determination of these equilibria or end points of metallurgical reactions by direct means is fraught with difficulty because here we must overcome mechanical difficulties which too often become the limiting factors even in the laboratory and we do nottherefore get the actual limit to which the reaction itself may be carried . Further , there are so many reactions of metallurgical materials that to survey each separately is a job to give pause to any experimenter or group of experimenters .

Dec 1, 1930

By Nabil A. Bibawy

An improved method for preparing gravimetric standard gas mixtures of helium-4 in nitrogen has been developed by the U.S. Bureau of Mines. A single-pan 12-kg analytical balance that has a sensitivity of 3 mg is used to prepare the mixture. The balance will accommodate a cylinder having a volume of approximately 4 L that weighs approximately 5 kg. The method has been improved to a precision of ±O.04 pct by performing four successive dilutions, by improved handling of gases in the manifold, and by using an improved analytical method to select high-purity gases.

Jan 1, 1990

By R. J. Evans

The generation and disposal of solid waste from electric utility plants using a lime or limestone wet-scrubbing system and the potential effects on the environment were estimated for 1975 and 1980. The study indicated that in 1975 approximately 5.8 million tons of desulfurization solid waste (50 percent solids) will be generated. In 1980, when it is estimated that desulfurization will become commercially accepted, approximately 71.4 million tons of this material will be generated for disposal and/or utilization. The desulfurization waste material when combined with lime, fly ash, and water may have potential for use as a roadbase material, landfill reclamation, and synthetic aggregate.

Jan 1, 1974

By L. S. Harner

This paper which describes the milling practice at the Golden Cycle mill is one of a series of similar papers being prepared by the United States Bureau of Mines. The mill of the Golden Cycle Corporation, formerly known as the Golden Cycle Mining and Reduction Co., is located at Colorado Springs, Colorado, and has been operated since 1907. It is now and has been from its inception almost exclusively a custom mill.

Jan 1, 1933

By Jr. Hazen

This report documents 653 sets of sample data involving 78,366 assays obtained from past exploration for various minerals and metals. Most of these data have been taken from published reports describing exploration projects, conducted jointly by the Bureau of Mines and the Geological Survey, for the Strategic Minerals Program from 1940 through 1949. Means and standard deviations have been computed for the exploration assay data and have been plotted on graphs for 22 minerals and metals. A mathematical model, based on the binomial distribution, has been developed to explain the configuration of the plots of the exploration means and standard deviations. The two statistics, mean and standard deviation, which describe assay data, have been used for simulating probability models. These probability models then have been combined with the binomial model of the exploration assays and related to the sequential decision process associated with exploration drilling for mineral deposits. These probability regions can be used to form the basis for sequentially predicting the probable range of the average grade of mineral or metal that may be expected as an exploration drilling program is continued after the initial discovery of mineralization has been made.

Jan 1, 1966

By J. E. Hamak

This publication contains analyses and related source data for 266 natural gas samples from 20 States and 2 foreign countries. None of the analyses have been previously published in annual reports. All samples were obtained and analyzed as part of the U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1992