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By Walter Kawa

The hydrogenation of phenyl ether, benzyl ether, and phenyl sulfide in the presence of iron catalysts was studied by the Bureau of Mines to gain a better understanding of the role of iron catalysts in the hydrogenation of coal. The carbon-oxygen and carbon-sulfur bonds in these compounds may be similar to some of the carbon-oxygen and carbon-sulfur bonds in coal which react during the early stages of liquefaction by hydrogenation. Experiments were made in batch autoclaves for 4 hours; hydrogen was at a pressure of about 540 atmospheres. In the hydrogenation of phenyl ether at 400° C, metallic iron catalyzed both hydrogenolysis (splitting-hydrogenation) and nuclear hydrogenation (addition of hydrogen to aromatic rings) reactions, Products were principally benzene and cyclohexane. The activity of metallic iron was decreased by adding carbon monoxide or a reactive sulfur-containing organic compound. Ferrous sulfide catalyzed the conversion of phenyl ether to benzene, phenol, and small amounts of cyclohexane. Hydrogenolysis of benzyl ether was catalyzed by metallic iron and to a lesser extent, by ferrous sulfide at 250° C. No nuclear hydrogenation was observed with either catalyst. Conversion of phenyl sulfide to benzene was nearly quantitative in experiments made at 250° C with equimolar quantities of phenyl sulfide and metallic iron or iron as ferric oxide. Conversions of metallic iron and ferric oxide to ferrous sulfide were nearly stoichiometric. No reaction of phenyl sulfide occurred in the presence of ferric oxide and water, and very little occurred in the presence of metallic iron and water. Ferrous sulfide also catalyzed the hydrogenolysis of phenyl sulfide to benzene, but conversion was lower than in experiments with metallic iron or ferric oxide. The activity of ferrous sulfide was increased by adding water and decreased by adding hydrogen sulfide. The results of this study suggest that ferrous sulfide is an active form of iron when iron is used as a catalyst for the hydrogenation of coal.

Jan 1, 1963

By W. J. Crawford, P. M. Gruzensky

"Several experiments have been carried out in efforts to evaluate qualitatively a variety of electrolytes for refining bismuth. Most extensive work was done with the basic tartrate, hydrochloric acid, and hydrofluosilicic acid electrolytes. Deposits that are smooth and adherent can be obtained from these three electrolytes if low cathode current densities are employed. All three electrolytes were effective in purifying crude bismuth considerably, with additional purification indicated in each instance by a reelectrolysis step.With the basic tartrate electrolyte best results were obtained when the electrolyte was at 40° C. and contained at least 100 grams of bismuth per liter. An apparent disadvantage was depletion of bismuth from this electrolyte, causing the deposits to become spongy and nonadherent.The hydrochloric acid electrolyte had the greatest tendency to yield rough, dendritic deposits. Best deposits were obtained at cathode-current densities below 2 amperes per square decimeter. A small amount of glycerin helped to produce a smoother deposit, and adding sulfuric acid or methyl sulfuric acid retarded the deposition of impurities. Very good results were obtained in electrowinning bismuth from a bismuth trichloride-hydrochloric acid electrolyte.Smooth and adherent deposits were obtained from a hydrofluosilicic acid electrolyte, with very good refining as regards lead and silver impurities; however, higher reagent costs and slow decomposition of the electrolyte have discouraged its use.INTRODUCTIONMethods of recovering bismuth from ores and byproducts were underdeveloped for many years because of the limited uses for bismuth, the pharmaceutical industry being the chief consumer. In the past decade or so additional uses for bismuth, particularly in the metallurgical field, have brought about increased demand for the metal with the result that bismuth is being recovered from byproducts that were once discarded. In addition to such uses as low-melting alloys, solders, bearings, die setting, etc., some interest has been indicated in bismuth as a possible coolant for nuclear reactors. The advent of ductile bismuth and bismuth-alloy thermocouple wire has contributed greatly to temperature measurement, particularly in the below-zero range."

Jan 1, 1956

By H. Kim, R. W. Plummer, T. J. Stobbe

"The probability of developing coal workers' pneumoconiosis (CWP) varies among miners in different geographic areas, coal seams, and jobs. Many studies have revealed the correlation between mineral content and the frequency and severity of CWP development still remains controversial. Furthermore, the mineral content and its variability in different areas is unknown.Since mineral content is expected to vary from location to location within a mine, between mines, between coal seams, and over time, this information will be valuable in understanding the variations in CWP incidence, as well as in establishing the appropriate kinds of dust to use in toxicological research programs studying CWP.Size-selective airborne dust samples were collected using 4-stage cassette impactors at 9 different locations in each of five coal seams. These coal seams were the Upper Freeport, Pittsburgh, Kittaning, Coal Burg, and Pocahontas. Mineralogical analyses were done by a x-ray powder diffraction photographic technique.Common minerals found in coal mine dust were illite, calcite, kaolinite, quartz, siderite, dolomite, gypsum, anhydrite, and pyrite. The distribution of minerals in interand intra location samples will be reported. Early results on the mineral content show wide variations between locations.in a mine and between coal seams, and small, but significant, variations between particle sizes.INTRODUCTIONIn spite of its long history of incidence, and the large amount of research conducted on it, coal workers' pneumoconiosis (CWP) is still prevalent among coal miners and needs further research to develop effective preventive and remedial measures. Although the dose-response relationship between simple CWP and coal mine dust has been established (1), the causal agent(s) and the mechanism(s) involved in the progression of simple to complicated CWP are not yet defined. Many plausible hypotheses have been made to explain the mechanisms involved in the disease progression however none of them is satisfactory. In addition, the source of variation in occurrence of CWP among miners in different geographic areas (2), rank of coal seam (3,4), and job (5) remain unsolved."

Jan 1, 1988

By Jr. Watts, J. L. Ambs, B. K. Cantrell, K. L. Rubow

"The University of Minnesota and the U.S. Bureau of Mines collaborated to develop and field test a personal diesel exhaust aerosol sampler (PDEAS). The PDEAS was field tested in five underground coal mines that use continuous miners and a variety of diesel vehicles, including diesel haulage and utility vehicles. One mine was surveyed a second time, with the haulage vehicles fitted with a low-temperature disposable diesel exhaust filter (DDEF). Aerosol samples were collected with a variety of instruments, including the PDEAS and the microorifice, uniform-deposit impactor (MOUDI). This paper presents the diesel exhaust aerosol (DEA) concentration data collected in these mines and assesses the impact of diesel face-haulage equipment, with and without exhaust filters, on underground mine air quality.The average DEA concentration at the haulageway location for five mines, determined by the PDEAS, was 0.89 mg/m3, with a standard deviation of 0.44 mg/m3 • DEA contributed 52 pct, of the respirable aerosol at the haulageway location. Use of the DDEF at one mine reduced DEA by 95 pct, with a standard deviation of 6 pct, and filter life averaged 10 h. DEA contributed a large proportion of the respirable aerosol concentrations in mines with diesel equipment, and a substantial reduction was achieved with use of a DDEF. INTRODUCTIONDiesel equipment is gaining popularity in underground coal mines. There are an estimated 1,951 units of diesel equipment in 152 underground coal mines compared with 1,100 units in 110 mines 5 years ago (J).5 This increased use is due to the recognition that diesel-powered vehicles are more versatile, which can contribute to increased productivity compared with their electrically powered counterparts. Approximately 33 pct of the diesel vehicles haul coal, 45 pct haul personnel and materials, and- 22 pct perform other duties, such as roof bolting, rock dusting, and road maintenance. Most mines using diesel equipment are located in Kentucky, Utah, Virginia, and Colorado."

Mar 1, 1992

By A. M. Dale, J. Standeven, B. Evanoff

We encountered several areas of methodologic uncertainty during development of a data collection method for use with vibrating hand tools in metal assembly. A local manufacturer sought our assistance designing a data collection method for evaluating and predicting risks of upper extremity disorders associated with use of vibrating hand tools. Current methods of vibration measurement are described in ISO 5349 [2]. However, the complexity of measuring vibration along with other exposures such as force and posture has limited the number of workplace-based studies of upper extremity disorders that have included direct measurements of vibration. Data from this preliminary study was used to look at two issues: a comparison of vibration values between production and non-production workers when performing the same task, and a comparison of worker ratings of vibration comfort to direct measurement of tool vibration. Methods Eight experienced production workers used each of six metal fastening tools to install fasteners. Vibration was collected by 3 tri-axial accelerometers, one attached to the tool handle following ISO 5349 recommended locations, one attached to the hand dorsum on the 3rd knuckle and one to the thumb side of the wrist. Data sampling rate was 10,000 samples/second. Hand grip and feed forces were obtained using a Novel pressure sensing mat on the palm. Each trial consisted of installing 10 fasteners per tool for each of the 6 tools. The test set-up placed the wrist in the position typically used by the operator during production. Each worker documented subjective comfort and effort ratings on a seven point scale following each series of fastener installations. One series of testing was completed by three non-production workers inexperienced in fastener installation to simulate use of alternative employees for data gathering. Vibration data for each trial were acquired, digitized, and stored using Lab View. The X, Y, & Z axes were used to calculate the vector sum response for each tri-axial accelerometer. The tool data were digitally filtered following ISO recommendations. Calculated data consisted of the mean RMS over the tool’s on- time, the starting and breaking peak impulses, and the peak of the frequency response. Results Production workers (n=8) were right hand dominant males with a mean age of 55 years and normal hand strength (mean right grip = 106 lbs). Non-production workers (n=3) had similar characteristics. We found large and statistically meaningful differences in hand force during tool use between production and non-production workers (mean production workers = 9.77 lbs, mean non-production workers = 43.30 lbs, p = 0.0001). Vibration values obtained from the hand also showed a statistically meaningful difference (mean in production workers = 0.67 Gs, mean in non-production workers = 1.48Gs, p = 0.0014, figure 1). Experienced worker ratings of comfort during tool use demonstrated a moderate correlation with measured vibration (r=0.63). Worker ratings trended with direct recordings from the tool handle as shown in figure 2.

Jan 6, 2006

By M. C. Malamphy

A general description of the activities and results of bauxite investigation by the Bureau of Mines at its bauxite project in Saline and Pulaski Counties, Ark., has been given in Report of Investigations 4251. The factual data obtained during the project are reported in a series of Reports of Investigations beginning with No. 4251, of which this is the third. The data are accompanied by maps showing the location of holes drilled and deposits developed. Each area upon which work was done is reported by half townships. Each bauxite deposit investigated was assigned a name and a number for ready reference and identification, and its location and name are shown on the appropriate half-township-map. The description of each half township is followed by a description of each deposit developed in that half township.

Jan 1, 1948

By E. D. Gordner

Irrespira ble gutses issuing from the rock fofflb tions ere tJ source of expense ond danger in some metGLl mines. There is a great Variation in the compos i-· tion of such gdses and, os shown 'by recent sampling by the Bureau of ines, the gas rr;;,.y consi$t mostly ct carbon dioxide, (Rocle Strata Gtsses in the Mines of the East Tintic Mining District, by G. E. McElroy, Bu.retau of Mines Serial 2Z75) or f methone (Metruine in Ccalifornia C.old Mines, by B. 0. Picl-Q:lrd i:lnd !.. D. ("iordner, Bure, cf Mines Serial 2303), or nitrogen, sin the present instonce. A nl.liilber of unventilated rt:t.ises in some of the mine of l:l Neva&. district conuin «i'ccumulCltions of l;i hih-nitrogen gas the1t will not supi:ort life or combus­tion. The rdises ore in different geologiecil formations and in widely sep1:1rated. loecslities in the mining district. One ot" two ri::lises in the sme fc.rtr.ation may be full of the gos cand einother nec-r'by be t'ree ot· it. Lives have been lost t:lnd a number of men heave been overcome on enteing unvetilated rtsises in which their­respircable tss hcsd c1ccuni..1.l1::1ted between sldfts. Gener1:1lly, however, the gas see:ns to noozett from the .t'onrbtio:1 ond to ecc1: .. ,i.-1,;.1:.1te so slowly tMt its presence is not suspected t the tfr.1e, bu.t discovered. ed:'t&.c' the raise is t)band.oned. OcCE.isionelly 1 t issues from a ne•.,ly cut cre·tice or fissure under considerca ble pressure and in lar!?e enough '3.'16ntities to overcome or drive 011t men working in unventilated places.

Dec 1, 1922

By Oliver Bowles

"A Product from Mica Mines.Mica commonly occurs in pegmatites which consist of large crystals of feldspar and quartz, mica constituting but a small proportion of the total rockMuch of the feldspar thus thro n out during the process of mining is pure and of high quality, end the Bureau of Mines has suggested that much of it could be utilized for ceramic purposes. Encouragement is given to such utilization by the fact that several mines now worked for mica were formerly operated for the production of feldspar. ""'here mines are not readily accessible to railroads feldspar utilization might not be feasible, for it is a much lower priced product than mica and cannot therefore bear as heavy transportation expense. '""here mines ire located close to railroads, however, such utilization would tend to reduce the cost of mica mining, and at the same time assist in the solution of the waste disposal problem.The Bureau has recently been informed that some of the feldspar from mica mines near Spruce Pine, N.C., is now being sold and shipped away. An extension of this by-product industry is to be recommended.A Mica Deposit in New York City.The Bureau recently received a mica specimen obtained from a. building excavation at 157th St. and Riverside Drive, New York City. The specimen was about 2 by 4 inches in size, and fairly clear though containing numerous hair cracks. It was obtained only 7 or 8 feet below street level. At greater depth and with more careful methods of excavation material of much better quality might be obtained. The material submitted could be used for mica washers but not for sheet mica. It is stated by an official of a prominent mica company that many such fragments are obtainable in this locality and the possibility of the occurrence of a good mica vein is thereby suggested."

Jun 1, 1920

By Steven J. Schatzel, Robert B. Krog

Frictional ignitions are defined as the ignition of a flammable mixture of methane and air that is initiated by frictional heating. Ignitions created through the addition of energy from open flames and exposed electrical circuits are not included in this analysis. Energy released in a roof fall that creates a spark and ignites a methane mixture would be considered a frictional ignition. Frictional ignitions represent the majority of all ignitions in underground coal mines. Over the study period of 1983 to 2005, a total of 1993 ignitions were reported in underground bituminous coal mines in the United States, of which 1589 were frictional ignitions. Reportable ignitions to the Mine Safety and Health Administration (MSHA) are any unintentional occurrences of flame underground regardless of duration. Frictional ignitions were reported in 155 mines and 13 states. Continuous miners represented the largest source for frictional ignitions with 1090 (68.6% of all frictional ignitions). Longwall mining operations represented the highest concentration of frictional ignitions during this study period with 1365 frictional ignitions (85.9% of all frictional ignitions). The 17 mines with the most frictional ignitions were all longwall mining operations and had 1130 frictional ignitions (307 from the shearer) that represented 71.1% of the total. In 1983, mines with frictional ignitions represented 6.9% of operating underground mines and 36.6% of total underground coal production. The percentage of operating underground mines with frictional ignitions and their total production has increased steadily and in 2005 represented 9.8% of active mines and 46.2% of underground coal production. The three coalbeds with the highest number of frictional ignitions (Blue Creek, Pittsburgh No 8, and Pocahontas No 3) had 1049 ignitions that represented 66.0% of all frictional ignitions. The three states with the highest number of frictional ignitions were Alabama (710), Virginia (247), and Pennsylvania (242) that represented 75.5% of the total. Frictional ignitions peaked in 1991 with a high of 114. In 2005, only 34 frictional ignitions were reported. If only frictional ignitions that occur at the face are considered, there have been no fatalities since 1983. Since this time, there were 33 ignitions that caused 53 workers to lose a total of 2912 working days. When including ground falls, then there have been four frictional ignitions with one incident causing two fatalities and injuring eight workers. From 1983-1991, underground productivity and the number of frictional ignitions increased. However, productivity continued to increase from 1991-2000 while total frictional ignitions fell, thereby disproving this connection between productivity and frequency of frictional ignitions. Ninety percent of all frictional ignitions occurred in underground coal mines that liberated more than 393 L/s (1.2 MMcfd million cubic feet per day) of methane through the main ventilation system. Although methane production is not the determining factor for the occurrence of frictional ignitions, it is a good indicator of the anticipated frequency.

By Ronald D. Hill, Elmore C. Grim

1.In 1972 over 595 million tons (51+0 million metric tons) of bituminous coal were mined; 49% of this tonnage was obtained by surface mining methods. Authorities have predicted that the tonnage of surface mined coal will increase in the future, especially since oil and gas resources are becoming limited. 2. Demands for clean air have increased mining activities in the low-sulfur coal deposits in the West. Pollution problems arising from these operations will be considerably different than those found in the East. The deposits are located in arid to semi-arid regions. Coal seams are generally aquifers and are a principle source of fresh water. Therefore mining may result in alteration of groundwater distribution patterns by aquifer disruption. In general, pollution problems associated with western mining are not well characterized. 3.Since any disturbance of the surface will alter the environment in the vicinity of the disturbance, pre-mining planning is a prerequisite to any environmentally successful surface mining operation. If properly carried out, the adverse social, economic, and environmental effects of coal surface mining will be minimized. Certain land areas will be unsuitable for surface mining where: a.Reclamation is not physically or economically possible. b.Mining is incompatible with existing land use plans. c.The proposed mining area is of critical environmental concern. Core drilling is the most satisfactory method of obtaining accurate information for pre-mining planning. 4. Unaccountable strip mining in the past has created problems that are still present today. Contour mining methods that involve the indiscriminate dumping of overburden on the downslope is one of the largest single sources of sediment from strip mining. However, land disturbed by strip mining can be reclaimed. Techniques have been and are being developed by which mining and reclamation are integrated into a single operation. Mountain top removal, head-of-hollow fill, and block cutting are examples in contour surface mining. These methods drastically reduce pollution problems associated with contour stripping.

Jan 1, 1974

By Francis Crowley

Elementary concepts of seismic wave properties are reviewed to establish a framework for discussing seismic noise and its suppression. A liberal number of references is included for those who wish to pursue the topic in detail. A base motion noise level is established for a single surface seismometer. It is argued that simple array processing and seismometer burial should regularly permit us to approach this base noise level which is found in areas free of conspicuous man-made seismic noise sources. The sensitivity of the base seismic level to a number of common disturbances is presented. Solutions that promise to hold the "effective" seismic noise at a site near the base level are given for acoustic, meteorological and fixed local surface sources. Guidelines are suggested for controlling other local man-made sources, e.g. vehicular traffic, by keeping them at sufficiently large distances away from the seismometers to keep noise at permissible levels. These guidelines are speculative and conservative. They should be the subject of future study. The ability to process against general local activity, drilling, and intra- mine sources is limited. Certainly no dramatic gain is to be expected. When strong man-made and/or intramine noise sources are not controllable, detection may well be impossible to achieve, unless the seismometer can be moved close enough to the suspected miner position, i.e. via very deep holes, to compensate for the likely vast differences in strength of the miner signal and the uncontrollable man-made noise sources. However, many intramine sources, e.g., falling water, rock bursts, explosions, etc., may well preclude the existence of a hale miner in their vicinity, and therefore any need to attempt detection of a miner at such locations. The following recommendations are made to enhance the detection and location of a miner signaling seismically. They are: 1. Seismometer burial in slim holes. 2. Narrow band detection, using multiple narrow band filters to cover the likely signal band. 3. Broadband recording and analysis for time-of-arrival estimation.

Jan 1, 1974

By Sivalingam Jeevan, R. L. McConnell

Ground check monitors may be made in several configurations. Each type has unique characteristics and provides different safety attributes when applied to different mine situations. In this paper, the monitor types are discussed in relation to the mine situations. It is shown that the selection of the monitor type can have a significant effect on the safety of the resistance grounded power system. The options are discussed, and the conclusion is drawn that only one monitor configuration can provide maximum safety. Unfortunately no monitors of this configuration are presently available. In addition, when the monitor capabilities and ground wire configurations are considered as a system, it can be shown that certain configurations will lead to maximum safety. This work was supported by U.S. Bureau of Mines grant G0144138.

Jan 1, 1979

By Lester J. Crow

This study advances the use of elemental sulfur in structural materials by demonstrating its value in bonding high-strength, well-graded basalt aggregates to form sulfur-basalt concretes. Sulfur is an excellent bonding agent, and the strength of a thermoplastic sulfur-aggregate mixture depends, to a large degree, on the strength and grain-size distribution of the aggregate used. A 3-cubic-foot, electrically powered mixer with heat applied to the barrel was used to mix the sulfur and aggregate. Sulfur content of several mixtures was varied to obtain the best workability with a minimum of sulfur in excess of that necessary to fill the voids. The average grain sizes and grain-size distributions were also varied to determine their effects on strength. Unconfined compression tests of forty-five 6-by l2-inch cylinders yielded average strendths of 3,348 psi to 10,398 psi. The highest strength single cylinder was 10,717 psi. The cylinders were tested from 24 hours to 6 days after pouring; after 24 hours the rise in strength was very slight. From the results obtained it appears that sulfur can be a useful construction material. An evaluation was made of a high-vacuum application for sulfur concrete. Sulfur has a high vapor pressure at elevated temperatures, 50° to 100° C; consequently, significant losses by sublimation can be expected. At lower temperatures the losses are not significant; however, this factor will limit its use at a higher temperature.

Jan 1, 1970

By Frank J.

The increased demand for aluminum for military purposes during World War II necessitated the development of domestic deposits of alumina-bearing ores. Kaolin, siliceous bauxites, anorthosite, and diaspore-containing clays have been investigated and studied in the laboratory and pilot plant. The Bureau of Mines is preparing a series of reports covering investigations of these ores. The tests contained in this report are restricted to sintering and leaching tests on kaolin from South Carolina, where extensive deposits were proved to exist. The leach liquors were found to have substantially the same composition as those produced from the diaspore-containing clays, and therefore it would be expected that no difficulty would be experienced in producing calcined alumina of relatively coarse particle size and with other properties conforming to the specifications for metallurgical-grade alumina.

May 1, 1947

By J. E. Wilson, J. D. Davis, C. R. Holmes

 The Bureau of Mines-American Gas Association (BM-AGA) method5/ has been used in surveying the carbonizing properties of American coals and, to date, in testing coals from 43 beds. The results in this report apply only to tests in the 18-inch retort at 800°, 900°, and 1,000° C. on coals from 32 beds. Table 1 gives the proximate and ultimate analyses of these coals and the name and location of mines. Coals from Pennsylvania, Virginia, West Virginia, Kentucky, Indiana, and Washington are considered. Seven of the coals are of low-volatile, four of medium-volatile, and twenty-one of high-volatile bituminous rank. One of the high-volatile coals (No. 45) is of high-volatile C rank, whereas all the others are of high-volatile A rank.

Mar 1, 1943

By Fred Turin, Kim Cornelius, Lisa Steiner

NIOSH researchers have been examining underground coal mining activities in order to evaluate work crew hazards. In 1994 a continuous mining machine operator was killed by falling roof during extended cut mining. Many aspects of the incident were used by NIOSH researchers to develop a scenario interview. The goal was to provide a realistic framework for acquiring frank and detailed insights. The interview consists of two sections. The first describes the underground mining conditions. The second recounts the fatal incident. Each section is supplemented by a diagram and a set of questions addressing relevant safety issues. The interview was administered at three mines that actively take extended cuts. Researchers found the scenario approach to be an effective interview tool as well as an effective hazard awareness and safe work practices training platform.

By T. H. Davis

Twelve laboratories from the Western United States and Canada participated in radon progeny intercomparison measurements at the U.S. Bureau of Mines radon calibration facility in March 1987. The participants intercom pared grab-sampling and automated equipment methods at high and low concentrations of radon progeny and condensation nuclei (CN). The objective of this intercomparison was to determine if the measurement procedures and equipment of the North American facilities are equivalent. The sampling results showed good agreement among all participants. The standard deviation for the working level measurements was less than 3.5% for 1.70 working level (WL) and less than 8.8% for 0.21 WL. This relatively good agreement was achieved by using alpha standards calibrated by National Bureau of Standards (NBS) and by closely checking and monitoring airflows.

Jan 1, 1989

To reduce front-end loader (FEL) collision accidents by detecting obstacles in the rear blind area. The Problem Federal regulations require an audible backup alarm to activate when an FEL is backing. Since the device is constantly being activated, the warning soon becomes a normal part of the mine environment and is less effective as a warning device. Also, when several machines are working together, it is difficult to detect by ear alone just which machine is backing. Approach The Bureau defined the location for hazard detection to include an area extending 15 to 20 ft behind the rear bumper of an FEL. Then, existing surveillance and detection technology was assembled, ruggedness, and applied to the FEL's rear blind area to form a new discriminating backup alarm system employing either infrared light, ultrasonics or radar

Jan 1, 1986

By L. H. Banning

The Bureau of Mines conducted pioneering batch and laboratory cyclic tests that simulated plant operation in developing a procedure for acidulating phosphate rock with fluosilicic acid. Both high-grade deslimed phosphate rock and low-grade phosphate rock samples were treated. The most promising results were obtained by acidulating des limed high-grade material. In a series of seven cyclic tests, 85.4 percent of the P20S was recovered in solutions. The average P2O5 content of the phosphoric acid-monocalcium phosphate solutions of the first step was 156 grams per liter, and the average fluorine content was 4.7 grams per liter. Residues had an average fluorine content of 30.7 percent and contained 83.9 percent of the total fluorine in the charge materials. Some fluorine was lost by volatilization.

Jan 1, 1975

By E. K. Stanek, P. Kantabutra, R. A. Wolf

This paper summarizes the cause and effect of induced voltages in multiple conductor cables supplying alternating current power to equipment in under- ground coal mines. The investigation of this phenomenon revealed that the electrical energy produced by the resultant electric arcing between the frames of mobile electric face equipment was of a sufficient magnitude to ignite explosive methane-air mixtures. The results of laboratory tests and field tests made between equipment frames during actual operation in numerous coal mines are discussed. Several methods of eliminating or suppressing the induced voltages to nonincendive levels are also described. It is the purpose of this paper to convey to the mining industry a knowledge of this problem and to recommend methods of eliminating or reducing these induced voltages or arcing currents to safe levels.

Jan 1, 1975