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By E. L. Litchfield

This report of work by the Federal Bureau of Mines has two primary objectives: A survey of the present status and usefulness of the minimum ignition-energy concept, and the presentation of recent data that are believed to bear on the safety problem associated with the ignition of combustible gases by electric discharges. The minimum ignition-energy concept has widespread applicability, especially to safety. The primary obstacle in making theoretical calculations of the requisite ignition energy is the lack of data on chemical kinetics and flame hydrodynamics. The new data on electrical ignition are representative of the great increase in knowledge that can be achieved by proper utilization of geometrical and electrical characteristics associated with the ignition source. CONCEPT OF MINIMUM IGNITION ENERGY The basic concept of a minimum ignition energy (the minimum amount of energy required to cause ignition) follows quite naturally from general physical principles and from the stability (lack of chemical reaction) of the gaseous mixture under the initial conditions. It also follows that if, as a first condition, lossless, instantaneous, and spatially localized energy can be injected and, as a second condition, the relaxation time for conversion of this type of energy to the type required for the reaction is short compared to some characteristic time scale of the ignition phenomenon, the energy requirements will be essentially independent of the type of energy source. Even if condition one cannot be fulfilled, it is sometimes possible to estimate the energy content of the gas required for ignition, and under these circumstances, condition one is fulfilled in effect. There are several instances where results can be interpreted for circumstances that effectively satisfy conditions one and two; these will be discussed later.

Jan 1, 1960

By Gennaro G. Marino

The Bureau of Mines and the University of Illinois investigated surface characteristics and damage to structures from mine subsidence over a room-and-pillar coal mine in Hegeler, IL. Data on three adjacent subsidence sags and associated structural damage were collected, summarized and evaluated. The subsidence sags developed over a 10-year period and took place above a modified room-and-pillar operation mining the Herrin (No. 6) coal at a depth of 130 to 135 ft. Surface vertical displacements of 3.0 to 3.5 ft resulted from extracting 6.1 to 6.4 ft of coal. Ground movements associated with sag formation severely damaged three houses and a radio station building, broke numerous utility lines, and structurally distorted three radio transmission towers. The radio station was remodeled and the towers repaired, but the three houses were subsequently demolished. Surface waters collecting in the subsidence depressions caused failure of radial ground transmission systems. The following subsidence profile characteristics were determined at the radio station and one of the houses, respectively: profile slopes, 0.02 and 0.07; maximum curvatures, 2.3 x 10-4 ft-1 and 3.0 x 10-4 ft-1; and angular distortions, 6.6 x 10-3 and 62.0 x 10-3. Although the house was more severely damaged than the radio station, both structures are classified as severely to very severely damaged.

Jan 1, 1986

Determine the appropriate spacing and alarm levels for carbon monoxide and smoke sensors used for fire detection in underground coal mine conveyor belt entries. Background Fire represents one of the most severe hazards in underground coal mines. Early-warning fire detection in underground coal mines is essential to successfully implement and execute evacuation and control measures. Both carbon monoxide (CO) and smoke sensors have the ability to provide reliable early-warning capability, provided that they are spaced properly and set at the appropriate alarm levels. The U.S. Bureau of Mines conducted a series of large-scale experiments where a small coal fire was used to ignite a conveyor belt at air velocities of 0.76 to 6.1 m/s. The test configuration was purposely designed to model a worst-case fire scenario for fires that develop within conveyor belt entries in underground coal mines. During the tests, CO and smoke levels were continuously measured to determine alarm times and alarm levels as the fire intensity progressed. The data from these tests indicated that for a given sensor spacing, the time to reach a preset alarm threshold depends upon the belt entry air velocity and cross-sectional area. Analysis of this data resulted in the equations and nomographs for CO and smoke sensor spacing, and alarm levels contained in Bureau of Mines RI 9380, "Fire Detection for Conveyor Belt Entries."

Jan 1, 1993

By Yael Miron

Coal mines that undergo self-heatings, and specifically mines that sustain both floor heave and self-heatings, would benefit from the use of sealants to minimize air ingress to susceptible areas. The U.S. Bureau of Mines(USBM) evaluated three sealant systems for this purpose, bentonite-water mixtures, silicate gel, and guar gum gel. The guar gum-based gel was the only sealant that possessed the desired properties of elasticity, ease of preparation, adaptability to the mine, and a long life. In addition, since the gel consists mostly of water, it could quench or cool nearby heatings. Optimal formulations were determined in laboratory tests, and then tested in the USBM Safety Research Coal Mine. Two formulations resulted in stable gels that lasted for at least 12 months in the mine. Semi continuous preparation of gel using an eductor was evaluated and appears feasible. Although guar gum gel is expensive, selective use to prevent heatings in specific areas would be cost-effective, both interms of productivity and enhanced mine safety.

Jan 1, 1995

By Robert A. Cortese, Henry E. Perlee

Coal dust and float coal dust, produced during normal mining operations, in underground coal mines, are carried from the point of origin downstream by the ventilating air, where it deposits on the surfaces of the mine entry. In an explosion, this dust is lifted from the surfaces by the aerodynamic disturbances and, if of sufficient quantity, can continue to propagate the explosion. To prevent the surface coal dust from contributing, it must be inerted, typically by spreading pulverized limestone, i.e., rock dust, over the coal dust surface. To facilitate the dusting operation, the National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory(PRL), developed an automated system that continuously monitors the accumulation of coal dust. This system could activate a rock-dusting machine that disperses rock dust into the ventilation air when dangerous deposits accumulate and deactivate the machine when sufficient inert has been deposited on top of the coal dust. The system consists of a microprocessor-controlled optical float dust deposition meter. This device measures the light intensity reflected from a deposited layer of dust. A standard cap lamp is used as a fixed-position light source. From the reflected light signal, the microprocessor determines the hazard level of the deposited layer and performs the appropriate action. Full-scale studies conducted in the Experimental Mine at PRL's Lake Lynn Laboratory, using alternating thin layers of rock dust and coal dust, successfully demonstrated the operation of the device. Based on the statistical data from these studies, a mathematical model was developed to predict long-term error in total rock dust content using this inerting procedure. Downwind dust dispersion was also examined to provide optimum placement of the dust sensors and to determine the need for better rock dust dispersion techniques.

Jan 5, 1998

By Margaret R. Egan

This Bureau of Mines report presents results from experimental studies on wood crib fires in an intermediate-scale fire tunnel. Gas concentrations, smoke particle characteristics, heat release rates, and ventilation rates were determined. These measurements form a data base for wood, which can be used with previous analyses for coal and future studies of other mine combustibles, to comprehend the potential hazards of these materials in underground mine fires. A knowledge of the combustion products emitted from these materials will benefit fire detection and control. Results show the changes in burning rate and heat release rate produced by different crib configurations and ventilation rates. Also included are the effects that the burning rate has on smoke characteristics and gas production.

Jan 1, 1986

By R. H. Grau, A. Sainato, S. J. Schatzel, T. M. Kohler, A. T. Iannacchione

This Bureau of Mines research study found gas emission rates from an advancing face, and flows and pressure of gas from an exploration drill hole were dependent upon the geology of salt encountered in a domal salt mine. Normal production-grade "pure" salt adjacent to an anomalous' zone was found to have a methane emission rate of less than 5 ft3/ ton (0.1 m3/t) of mined salt from a room advanced by a continuous miner. Extremely low gas flows [less the 4 ft3/h (0.1 m3/h)] and lack of pressure buildup were also observed from this normal salt in a 154-ft (47-m) exploration drill hole. These data indicate that methane emissions should not be a problem when mining in this type of salt. In the adjacent anomalous zone, methane emission rates ranged from 15 to 70 ft3/ton (0.4 to 1.8 m3/t) of mined salt from an advancing face. Gas flows of approximately 42 ft3/h (1.2 m3/h), and pressures in excess of 900 psig (6,200 kPa) were observed in an exploration drill hole when the anomalous zone was encountered. This information suggests a greater methane emission hazard from the anomalous zone than from the associated normal salt. If this trend of increasing emissions problems associated with anomalous zones of salt is common with similar anomalous zones encountered or observed in other domal salt mines, then special control strategies should be employed to minimize this potential mining hazard.

Jan 1, 1984

REFERENCES AND FOOTNOTES 1. U.S. Department of the Interior, Office of Surface Mining. Surface Coal Mining Reclamation: 10 Years of Progress: 1977-1987. Washington, D.C. August 3, 1987.48 pp. (For sale by the Superintendent of Documents, U. S. Government Printing Office, Washington D.C. 20402.) 2. The Rural Abandoned Mine Program (RAMP), authorized by Section 406 of SMCRA, provides for the control and prevention o f erosion and sediment damages from unreclaimed abandoned mine lands. 3. The Small Operator Assistance Program (SOAP), authorized by Section 401(b)(1) and 507(c) of SMCRA authorizes up to 10 percent of the fees collected for the Abandoned Mine Reclamation Fund to be used for technical assistance to help qualified small mine operators obtain techincal data needed for permit applications. Operators who produce fewer than 300,000 tons of coal per year are eligible for assistance. 4. OSM regulations 30 CFR 816.42 and 817.42 require water from areas distrubed by mining activities be in compliance with all applicable state and federal water-quality laws and effluent limitations for coal mining established by the U.S. Environmental Protection Agency. 5. Sourse: Abandoned Mine Lands Fee Collection System, Data from OSM-1 form. 6. Sourse: Abandoned Mine Lands Fee Collection System, Data from OSM-1 form. 7. Source: OSM Field Office Annual Reports. 8. Johnson, W. and G.C. Miller, Abandoned Coal-Mine Lands: nature, extent, and cost of reclamation. U. S. Bureau of Mines, 1979,29 pp. PHOTOGRAPHIC CREDITS Front cover, pp. i, 1, 2 bottom, 7 right, 10 bottom left, l 1 top, l l bottom right, 12 top, 13 bottom, 14 bottom right, 15,16 bottom, 17 top, 17 bottom right, 18 bottom, 19, 20 bottom, 21 top, 22, 23, 24 bottom, 25 bottom, 26 bottom left, 26 bottom right, 27, 28, 29 top, 30 bottom, 32 bottom right, 33 top, 34 top, 35 top left, 35 bottom left, 35 bottom right, 36 top, 37, top right, 37 bottom, 38 bottom, 39, 41, 42 top, 43 bottom, 44 bottom left, 44 bottom right, 45, 46, 47, and 53: Chuck Meyers, OSM. Page 2 top and center: Tony Fuhs. Page 3: John Sharkowicz, OSM. Page 6 left: North American Coal Corp. Pages 6 right, 7 left, l l bottom left, 13 top left, 13 top right, 17 bottom left, 21 bottom, 25 top left, 25 top right, 29 bottom, 30 center, 32 top, 32 bottom left, and 38 top: Bob Welch, OSM. Page 10 top left: Donald Stump, OSM. Pages 10 right, 14 top right, 14 center right, 18 top, and 44 top: Ron Hill, EPA. Page 12 bottom: Texas Utilities Co. Pages 16 top, 20 top, 24 top: Tennessee Valley Authority. Page 26 top right and 26 center left: Richard Dick, U.S. Bureau of Mines. Pages 30 top, 33 bottom left, 33 bottom right, 35 top right, 36 bottom, 37 top left, 40 top, 40 bottom, 42 bottom, 43 top left, and 43 top right: Jim Boyer, OSM. Page 31 top left, and 31 top right: Bruce Wage, Western Energy Co. Page 31 bottom: Rex Wilson, OSM. Page 34 bottom: West Virginia Division of Abandoned Mine Lands. Page 35 center: William Weist, Jr., OSM.

Jan 1, 1992

By C. J. Wilhelm

The disposal of brines produced with crude petroleum and natural gas has been a long-continuing problem to oil and gas operators as well as to farmers and stock-raisers in the vicinity of producing fields. An impartial appraisal of conditions pertaining to the problem of brine disposal leads to the conclusion that study of the technical consideration, with proper weight given to the economic and social factors, is the most desirable approach to this problem. Brine disposal is a problem of such magnitude in certain areas in the State of Kansas that in August 1934 a cooperative agreement was made between the Kansas State Board of Health and the U. S. Bureau of Mines for a cooperative technical study of methods of brine disposal.

Jan 1, 1935

By D. Hurrington

For severlrl 1e1.rs the Bureau of Mines has studied dust and ventili in metal mines a.s a.tfeoting the hea.l th, safety, and efficiency of underground workers. From its beginning this work haa been directed by G, s. Rice, chief mining engineer, A. cooperative agreement was ma.de in 1915 with the u. s. Publi Health Service; since that time tield obmervations 1n metal mines in Arizona, California, Idaho, Montana, Michigan and Nevada, and less extensive observation, in several other States have been made by mining engineers of the U, s. Bureau of Mines, and doctors of the u. s. Pu.blic Heal.th Service. Most of the analyt:J:eal work has been done by chemists, petrographers, and other specialists in the Pittsburgb station ot the Bureau of Mines, Numerous articles have been printed by the otticial and the technical press on this important in•estigation; 1n response to the need for a btiet bibliography of this literature. it has been compiled to facilitate accp1,intance with published data ot1. the subject,

Jul 1, 1922

By L. D. Stewart

The main reasons for developing an induction system for signaling from the cage are, first, to increase safety, and second, to effect economies in the operation of cage and ship hoists, especially when work is being done in the shaft. To-day nearly all mines which employ safe methods have installed safety gates on cages, at the different levels, and at the collar of the shaft. Under the old system in some instances signals could only be Given from the station outside the cage, and in other cases, after the signal was given the only method whereby those riding on the cage could control its movements consisted of pulling the bell-rope hanging in the shaft, an uncertain and somewhat hazardous procedure at best. With the system herein described, however, it is possible, without opening the gates, to signal to the engineer from any place in the shaft whether or not the cage is moving, and finder the same conditions it is possible to converse with the engineer by using the telephone. In short, the cage tender has at all times an opportunity either to signal or talk to the engineer without leaving the cage.

Jan 1, 1931

By J. G. Eisele

Solvent-extraction characteristics of dodecyl phosphoric acid (DDPA) were investigated to determine its potential as a fractional or selective extract-ant for individual elements in a rare-earth-yttrium mixture. The DDPA is an effective extractant for splitting rare-earth mixtures into light and heavy subgroups. Yttrium normally extracts with the heavy rare-earth elements but may be shifted toward an extraction sequence with the light rare-earth elements by increasing the pH. Elements in the light and heavy ends of the rare-earth series can be separated from middle-group rare-earth elements by using diethylenetriaminepentaacetic acid (DTPA) as an aqueous phase counter-extractant. Hydrogen-ion dependency of the distribution coefficients differs from that reported for similar systems at tracer-level concentration.

Jan 1, 1965

By M. P. Youker

USE OF LOW-PRESSURE GAS BURNERS IN OIL- FIELD BOILERS

Feb 1, 1922

By Richard L. Fischer

Constant-volume charges of precipitated PETN (pentaeythrite tetranitrate) at three specific gravities (0.50, 1.00, and 1.50) were used in laboratory tests to examine the effects of changes in explosive properties on free-surface displacement pulses and on crater dimensions. The tests were performed in large blocks of cement-mortar. The values for the detonation velocity, detonation pressure, specific energy, energy density, and energy release rate were calculated from the explosive loading density. Calculated explosive properties were correlated with free-surface displacement pulse measurements, strain energy, and measured crater dimensions. Increases in explosive properties resulted in increased free-surface displacement pulse parameters and crater dimensions. The loading density, detonation velocity, energy density, detonation pressure, and energy release rate were found to be best indicators of explosive performance. Simple acoustic relationships involving impedance ratios were examined and could not be used to predict peak displacement amplitude or strain energy. Data are presented in the customary English units as well as the International System of Units (SI).

Jan 1, 1970

By H. A. Watson

Fluorine-containing polymers are comparatively new materials that exhibit very desirable characteristics not usually found in non-fluorine containing polymers. Among these characteristics are heat and flame resistance, desirable electrical properties, and chemical inertness. Polytetrafluoroethylene and polymonochlorotrifluoroethylene are examples of such polymers commercially available. In practical applications it is reasonable to expect thermal position of these materials if they are subject to high enough temperatures. The temperatures at which thermal decomposition takes place and the nature of the gaseous products of decomposition are considered pertinent data in intelligent use of these materials. The purpose of the tests discussed herein was to determine: (1) The temperatures at which gases were produced when small specimens of the two polymers were located and (2) determine the identity of the major constituents of gaseous products.

Jan 1, 1950

By M. M. Kirk

Forced-air cooling of cold-mold arc furnaces for melting zirconium and similar metals has been investigated and found to be practical from the stand-point of heat transfer. It is believed that this technique offers a significant reduction in explosion hazard from that inherent in water cooling, the current industrial practice. A copper crucible, with longitudinal, integral-type fins and with an outer jacket to confine the airstream, appears to be the best general design for air-cooled operation. Cutting the fins into short segments and bending the segments to produce a herringbone effect increased the airstream's turbulence and was found, on test, to increase the heat transfer up to 35 percent.

Jan 1, 1959

By H. Kim, R. W. Plummer, T. J. Stobbe, W. G. Jones

"Exposure to airborne dust in coal mines has caused respiratory disease in coal miners. The causal agent in these diseases remains unknown, although the minerals found in and around the coal seam have been implicated. Toxicological studies designed to establish the effect of different mineral combinations and concentrations are lacking because the mineral content of coal mine dust has not been defined. This paper reports the initial results of a study done to characterize the mineral content of the coal mine dust found in a mine in the Upper Freepott seam in Northern West Virginia. Coal mine dust samples were collected using 4- stage cassette impactors at nine locations in the mine. The samples were analyzed by an x-ray microdiffraction film technique supplemented by energy dispersive scanning electron microscopy. Primary size modes of about 17 to 20 micrometers from the samples collected at the haulageway and the returnside of the continuous miner were found. From the returnside of the roof bolter samples, a primary size mode of 12to15 micrometers was measured. The minerals found in high percentages were illite, kaolinite, quartz, and calcite. The distribution of minerals in inter· and intra- location samples showed wide variations. Trends in these variations are presented. Stobbe, T. J.; Plummer, R. W.; Kim, H.; Jones. W.: Characterization of coal mine dust. Appl. Ind. Hyg. 2:95· 100; 1986. IntroductionDisease-associated dusts in coal mine environments continue to afflict miners in today's modern mines. The relationship between exposure to coal mine dust and the development of various respiratory diseases has been well recognized; however, the reasons for variation in occurrence of these diseases among miners in different geographic areas,(1) rank of coal seams,(2-3) and jobs (4) remain uncertain. Several papers have reported on the causal agent in the development of these diseases. Davis (5) found that the percentage of the non-coal minerals present in the lungs of deceased miners increased as the level oi pneumoconiosis became more severe. Reisner (6) reported that cell damage caused by coal mine dust increases with the mineral and quartz content of the dust and with the geo· logical age and rank of the coals. Two studies, investigating the in vitro effects of mineral dusts. reported by Seemayer and Manojlovic (7) also obtained positive correlation between cytotoxicity and the mineral content of coal mine dust. Gormly (8) postulated that destruction of macrophages by certain mineral dusts is the first step in the development of pneumoconiosis. In 1980, Adamis and Timar (9) reported that quartz. sandstone, slate. respirable colliery dust. bentonite, illite, and some kaolins had cytotoxic effects on rat peritoneal macrophages""in vitro."" Walton,(10) however, reported that the presence of high clay, illite, and kaolin mineral exposures reversed the hazards associated with increasing quartz exposures. This finding was supported by Le Bouffant and coworkers.(11) They reported that illite present in coal mine dust strongly inhibited the pathogenic effects of quartz while kaolin had a weaker inhibitory effect."

Mar 1, 1989

By Walter R. Storms

"The New Mexico potash exploration described herein was begun in February- 1944 by the Federal Bureau of Mines with the object of determining the amount of potash ore in the United States Potash Reserve in Eddy County, N. Mex., by exploring the deposit from the surface with vertical drill holes. The work was completed in October of the same year after 16 holes had been drilled on the reserve and in the immediate vicinity.The Potash Reserve is located in secs. 26, 27, 34, and 35, T. 20 S., R. 29 E., Eddy County, N. Mex., about 14 miles northeast of the city of Carlsbad. Drilling was done in secs. 26 and 35 of the reserve, in sec. 14 to the north, and secs. 25 and 36 to the east. All work was done on Government-owned, unleased land.The reserve may be reached from Carlsbad by traveling northeast by automobile for about 14 miles on paved U. S. Highway 62. This highway passes through the southern part of the reserve. Other parts may be reached by a State highway which passes along the eastern side of the area, then by poor dirt roads to various drilling sites. A branch of the Atchison, Topeka and Santa Fe Railroad also passes across the southern part of the reserve en route from Carlsbad to the plant and mine of the Potash Co. of America, a few miles northeast of the Project and 22 miles from Carlsbad.Work on the project was greatly facilitated by the help of Ralph H. King, associate geologist, R. K. Bailey, geochemist, H. C. Spicer, geophysicist, Hope Bunker, junior geologist, and R. H Allport, district mining supervisor, all of the Federal Geological Survey; and Charles H. Johnson, who at that time was district engineer for New Mexico for the Mining Branch of the Bureau of Mines."

Apr 1, 1946

By James W. Myers

The Bureau of Mines studied factors affecting ignition of coal mine refuse and on methods for control of burning. Laboratory experiments showed that air permeates more readily through segregated than through nonsegregated refuse and that air permeability is greater through coarse than through fine particle refuse. Minus 3-1/4-inch refuse ignites spontaneously more readily than minus 1/4-inch refuse. The burning of a 1,000-pound conical coal pile was con-trolled by capping with an 18-inch-thick layer of minus 1/4-inch refuse containing 37 percent combustible. In field trials, the burning of refuse at operating mines was controlled by capping with a layer of fine refuse. Water, applied as a spray or by injection, quenched surface flames and cooled the burning waste. Inspection of refuse piles at operating mines showed that the spontaneous ignition tendency is affected by the exposed surface relative to the total volume and the segregation of particles during dumping.

Jan 1, 1966

By Albert L. Toenges

This paper is the fourth of a series5/ that describes some methods and practices of mining coal mechanically where operations are conducted on more than one shift. Many inquiries have been received regarding methods of extracting pillars with mechanized equipment, and this paper deals primarily with this phase of mechanical mining. Some of the questions that have been asked are:

Jan 1, 1942