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By J. H. Perry, D. W. Houseknecth, C. A. Kertis, A. T. Iannacchione

Major problems facing the development of coal and gas resources of the Hartshorne Coalbeds include the complex distribution of minable and unminable coal, high methane content and bed pressure, faulting, variations in degree of dip, presence of natural gas fields in associated sandstones, and legal problems, caused by local geologic characteris- tics, in identifying gas origin. This Bureau of Mines study provides pertinent geologic information for long-range planning of subsurface coal and gas production from the Hartshorne Coalbeds. Pittsburg, Coal, Hughes, and Atoka Counties, OK, have approximately 1 billion metric tons (1.1 billion short tons) of Hartshorne coal in place. The methane resource of Hartshorne Coalbeds is estimated at 9.2 billion m3 (325 billion ft3) and varies with overburden and rank, These estimates were compiled from gas well density logs, coal-core data, out- crop measurements, abandoned mine maps, and the literature. The Hartshorne Coalbeds represent a valuable coal and gas resource which at present is contributing nothing to coal and gas production. This report discusses potential problems and serves as a reference for future exploration and development work. Recognition of these potential geologically related problems prior to development of this basin will reduce hazards and allow for an economic recovery of these resources.

Jan 1, 1983

By J. Roger Loebenstein

Demand for arsenic exceeded supply in 1980, and the major domestic and foreign producers allocated available supplies to customers. Major demand was about evenly divided between industrial chemicals and agricultural chemicals. Legislation and Government Programs.-In June 1980, the Environmental Protection Agency (EPA) listed inorganic arsenic as a hazardous air pollutant.2 Proposed regulations on arsenic emissions were to be announced on an industry-by-industry basis at a future date, and public comment on the listing and on specific regulations was to be heard.

Jan 1, 1981

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

3. Application of Proposed Revised Standards 57.11-50 to Mines Surveyed 3.1 Subparagraph (a) 1 "Each mine shall have at least two separate and properly maintained escapeways from each working place to the surface which are so positioned that physical or environmental damage to one will not lessen the effective¬ness of the other, and which meet the requirements of travelways and man hoisting standards These escape¬ways shall reach to within 1000 feet horizontally or 300 feet vertically of each working place " 3. 1. 1 Discussion This section will deal with the 1000 and 300 feet distance requirements, Section 3. 5 will deal with the "environmental damage" provisions. During the course of the mine surveys, it became obvious that one mine's 1000 foot distance was nowhere near equal to another' s --not in the actual distance but in the time required to traverse that distance. This -Ls true for the 300-foot requirement as well. The most obvious example is that one could traverse down a 300-foot raise much faster than climbing up the same distance. The temptation is strong to recommend that the distance requirement be changed to travel times instead. However, this approach would unfortunately lead to a lot of subjective evaluations. Having a time requirement for an entire mine evacuation (Subparagraph 6) is one thing, time requirements and the requisite inspection proce¬dures for each working place are quite another.

Jan 1, 1976

By E. K. Stanek, P. Kantabutra, R. A. Wolf

This paper summarizes the cause and effect of induced voltages in multiple conductor cables supplying alternating current power to equipment in under- ground coal mines. The investigation of this phenomenon revealed that the electrical energy produced by the resultant electric arcing between the frames of mobile electric face equipment was of a sufficient magnitude to ignite explosive methane-air mixtures. The results of laboratory tests and field tests made between equipment frames during actual operation in numerous coal mines are discussed. Several methods of eliminating or suppressing the induced voltages to nonincendive levels are also described. It is the purpose of this paper to convey to the mining industry a knowledge of this problem and to recommend methods of eliminating or reducing these induced voltages or arcing currents to safe levels.

Jan 1, 1975

By K. C. Dean

Time and motion studies were made by the Federal Bureau of Mines on the hand and machine dismantling of scrapped auto starter motors, generators, and alternators for recovery of copper, aluminum, and iron. The studies showed that an individual with power handtools and convenient access to a hydraulic press, power bandsaw, acetylene torch, and power lathe could, in an 8-hour day, disassemble about 100 starters, or 150 generators, or 30 alternators. The scrap copper yield would be 280, 390, and 45 pounds, respectively, and the iron yield would be about seven times the copper weight. About 100 pounds of aluminum would be obtained from the alternators.

Jan 1, 1976

By J. G. Walters

The method for predicting coke strength developed at Steinkohlenberg-bauverein, Germany, in which experimental parameters are readily determined by small-scale laboratory tests, was found to be applicable to cokes produced from industrially used blends of American coals. Predicted 1-inch ASTM tumbler indices for four industrial blends were found to be in excellent agreement with the experimentally determined values. The laboratory determined prediction parameters include the proximate analysis of the coal the size consist of the coal, and Ruhr dilatometer test data.

Jan 1, 1971

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

7. Hoisting Systems Hoists used solely for emergency escape use should above all, be simple and dependable. The hoist systems' motive power should be independent of all other mine equipment so that only an emergency in the immediate vicinity of the hoist will render it inoperative. The hoist should receive the same high level of inspection as is normal with any other man hoisting system. It should be operated at regular intervals, and must include sufficient safety devices to ensure safe operation when hoisting men. Of equal importance, however, safety devices must be included to safeguard the hoist system from in¬advertant damage due to inspection, maintenance or operator error In an emergency situation the hoist operator will be under considerable stress and the system must be simple and foolproof to operate. Under normal circumstances the hoist will only be operated during the regular inspection cycle. Because of this very low operational use rate, certain requirements, normally associated with man hoisting, can be relaxed. In particular the wire rope installation requirements, in terms of drum and sheave diameter and fleet angles, can be reduced provided that rope inspection during the system life is maintained at a high level. The following section includes recommended guidelines for emergency hoist system design, installation, operation, maintenance and inspection A summary of available hoisting equipment and components is included in Appendix C. Emergency Hoist Guidelines All hoists designated as part of a mine emergency escape system shall meet the requirements of the Emergency Hoist Guidelines. Where these hoists are also utilized for hoisting other than emergency hoisting, the requirements of Title 30, Code of

Jan 1, 1976

By N. F. LeJeune

For a number of years the Bureau of mines has conducted semi-annual surveys to determine the changes in the characteristics of the motor gasoline being sold in the United States. The Bureau of Mines surveys, from April, 1917, to January, 1943, indicated a progressive decrease in the end point range. The survey for July, 1923 showed an interruption in this progressive decrease. This interruption, as shown in Table 1, in the line marked "Difference," was apparently a definite one, for the data obtained in the surveys of July, 19233, January, 19244, and the present one, apparently substantiate it. The figures in Table 1 were obtained by averaging the end points of the least volatile and most volatile samples of gasoline. For example, of 850 samples analyzed in 1919, the 10 per cent (85 samples) having the highest end points and the 10 per cent having the lowest end points were grouped, and the end points of each group averaged. These averages are represented in the table as the "Maximum 10 per cent" and the ?Maximum 10 per cent," respectively. The same scheme was used on the succeeding surveys.

Jan 1, 1924

By Thomas G. Carnahan

The Bureau of Mines conducted research to simulate in situ leaching of a chalcopyrite ore. The purpose was to obtain a direct comparison between moderate-temperature and elevated-temperature in situ leaching of copper trom minus la-inch ore and to analyze the sulfuric acid and oxygen requirements of the leaching system. Experiments employing oxygen were conducted at 35° and 90° C on 362-and 367-1b ore charges, respectively, under flooded conditions and at 400 psig. At 90° C, 47 pct of the copper was extracted in 913 days of leaching; at 35° C, 27 pct of the copper was extracted in 915 days. Diffusion into and out of the ore fragments con-trolled the rate of leaching. Oxygen consumption was 1.46 lb/lb of copper extracted at 35° C and 3.15 lb/lb of copper extracted at 90° C. Sulfuric acid requirements of the ore were 5.49 and 7.48 lb/lb of copper extracted at 35° and 90° C, respectively.

Jan 1, 1982

By J. M. Stuve

A novel calorimetric solution technique, recently developed at the Bureau of Mines, was tested using synthetic samples of chalcocite (CU2S) and covellite (CuS). The solution of these refractory sulfides was accomplished by oxidation with bromine in a moderately acidic, aqueous solution. The resulting values for the standard enthalpies of formation (?Hf°, 298.15) for CU2S(c) and CuS(c) were -18.1 ±1.1 kcal/mol and -13.3 ±1.1 kcal/mol, respectively. These values are in good agreement with published formation values derived from other methods of physicochemical measurement.

Jan 1, 1982

Reduce the noise levels to which operators of double-drum longwall shearers are exposed without compromising the operational effectiveness of the shearer. The Problem Noise produced by double-drum longwall shearers can be harmful to machine operators. Typical noise levels at the lead-drum operator position range from 100 to 105 dBA, and Federal noise regulations allow only one to two hours of exposure per shift at these levels. Noise radiated by the shearer cutting drum is the primary contributor to the overall noise level. However, test of a noise-controlled cutting drum developed by the Bureau of Mines reduced the operator noise level to 95 dBA, thereby increasing the allowable operating time to four hours per shift. Approach The key design aspect of the noise-controlled shearer drum is its reduced vibration-al response to coal-cutting forces. Laboratory studies have shown that these forces are concentrated in the low-frequency region (500 Hz and below). Since the cylindrical core and the cantilevered I plate-like helix of the standard shearer drum are easily excited by these forces (natural vibration frequencies be-

Jan 1, 1985

To test the feasibility of hydraulic borehole mining for the recovery of phosphate ore from the deep, water-saturated deposits of northeastern Florida. Approach Phosphate ore is remotely extracted through a Bureau of Mines-developed hydraulic borehole mining system. Hydraulic borehole mining can remove underground ore deposits that cannot be economically mined by the usual open pit or underground methods. It is environmentally compatible, causing none of the surface disruption or ground water pollution usually associated with other methods of mining. Selectivity of the borehole mining system also allows economical recovery of small or discontinuous ore deposits while minimizing the removal of host rock. The hydraulic borehole mining system has been used successfully in the past to mine uranium ore and oil sands. (For examples of these and other applications of borehole mining see T Technology News Nos. 97, 95, 63, 56, and 48) How it Works A 16-inch-diameter borehole is drilled from the surface down into the buried mineral deposit, and the mining tool is installed. The borehole mining tool consists of a 12-inch-diameter pipe string and accessories capped with a three-passage swivel, and ending with a mining section. The mining section has four slurry inlets and an eductor located near the bottom of the section and a single cutting nozzle located near the top. The tool generates a high velocity water jet that erodes and slurrifies the ore. The slurry is drawn through the inlet into the eductor which lifts it to the surface where it is deposited into a slurry discharge sump. All the support equipment is located and operated on the surface; only the mining tool portion of the system is underground during the recovery operation.

Jan 1, 1983

By R. A. Isberg, D. A. Parrish, H. Kramer

This report describes the design and implementation of UHF radio and closed-circuit television systems in the Black River room and pillar limestone mine near Butler, Pendleton County, Kentucky. Prior to designing the radio system, measurements of signal attenuation on 812 and 466 mHz were made in the slope tunnel and in the straight and level crosscuts in the mine. Two distributed antenna systems fed by two sets of base stations provide approximately 75% coverage of the mine. Passive reflectors are used for extending signals into intersecting crosscuts and two-way signal boosters will be used to extend signals to the perimeter and obstructed areas of the mine. Fourteen mine vehicles were equipped with mobile radios equipped with digital identification, alarm and status encoders. Fifteen portable transceivers also were used. Six closed-circuit television cameras provide surveillance of critical transfer points of the belt conveyor system, and the loading dock at the base of the slope and an ash disposal area in the mine. Two-way radio communication and closed-circuit television have saved considerable man. hours, increased production, reduced maintenance costs and enhanced safety. Innovative developments were the use of passive reflectors and two-way signal boosters for extending signals into intersecting crosscuts, development of lightweight signal margin measuring equipment, modifications of mobile digital encoders to automatically send status information from mine vehicles such as numbers of loads of ore delivered, hot engine, etc., and the use of CATV technology for multiplexing audio, digital and video signals onto coaxial cables from the surface to the mine.

Jan 3, 1981

By Karl C. Dean

The Bureau of Mines studied the precipitation of copper from dilute acidic sulfate solutions using shredded automobile scrap in a rotary drum. The tests established that the scrap in the rotary drum precipitated copper faster and more completely than shredded, detinned, tinplate scrap in a launder, with comparable iron consumption. Although power is required to rotate the drum, the faster precipitation and continuous recovery of cement copper are advantages of the tumbler method. Cost evaluation indicates that the rotary drum method, which uses relatively low-cost and readily available shredded automobile scrap, is competitive with the launder method, which uses relatively high-cost shredded tinplate scrap or detinned shredded cans.

Jan 1, 1968

By Lloyd A. Morley

To reduce safety and production problems, it is essential that the electrical operating characteristics of coal mining equipment and their electrical subsystems be clearly understood. The Bureau of Mines and the Pennsylvania State University have developed techniques to monitor and analyze several of the critical parameters. A unique system for measuring traction locomotive consumption at the machine has been assembled and utilized. Conclusions from 27 continuous miners show that voltage levels are directly tied to machine efficiency. The Bureau of Mines and Pennsylvania State University, along with West Virginia University, are currently monitoring and accessing mine power transients. Results exhibit that voltage transients of three to five times the line -to-line value are common on underground distribution systems.

Jan 1, 1975

By R. V. Ramani, A. S. C. Owili-eger

The rapid depletion of shallower coal reserves dictate that mining in the future will be deeper and more complex with more difficult natural conditions. Consequently, an increase in methane emission is expected. It is becoming evident that more accurate predictions and better planning are necessary to design efficient methane drainage systems. This objective can be achieved by the utilization of the knowledge of the physics of gas flow through coal seams and rock strata and by the application of digital computers in the solution of methane flow problems. Although the methane emission models described here have not been adequately applied to existing field operations, good agreement between actual field measurements reported in literature and the simulation results indicates the potential of these models for initial flow quantity approximations and ventilation planning. This report has, therefore, introduced to the mine operator yet another application of computers as a planning tool. AREAS FOR FURTHER RESEARCH The study reported here is by no means complete. Extensive research efforts should be directed to the following areas: (a) Better understanding of the physics of gas flow through porous media which exhibit fracture permeability. (b) Determination of field parameters which control gas migration. (c) Investigation of the effects of the rate of penetration on the emission rate and fracture propagation.

Jan 1, 1974

By Maria I. De Rosa

Table 19 and figure 7 show the number of fires and fire injuries for surface coal mines by state during 1990-1999. Table 19 also shows by state the risk rates, employees' working hours, lost workdays, and coal production. For surface coal mines, 215 fires occurred in 21 states during 1990-1999. Ninety-four of those fires caused 93 injuries and I fatality (the yearly average was 21.5 fires and 9.3 fire injuries). Fourteen fires and seven injuries involved contractors. The Ewhr value was 729 x 10° hr (In = 0.026), the CP value was 6,355 x 10° st (Fn = 0.034), and the LWD value was 8,141. Kentucky had the most fires and fire injuries (45 fires and 23 injuries), followed by Pennsylvania (33 fires and 14 injuries), West Virginia (25 fires and 14 injuries), and Indiana (20 fires and 8 injuries). Among these states, Pennsylvania had the highest fire risk rate value (Frr=0.145), while Kentucky had the highest injury risk rate value (In 0.041).

Jan 1, 2004

By James D. Noll, Jon A. Hummer, Aleksandar D. Bugarski, George H. Jr. Schnakenberg, Steven E. Mischler, Larry D. Patts

The National Institute for Occupational Safety and Health conducted a study to determine the effects of selected, state-of-the-art emission control technologies on the ambient concentrations of particulate matter and gases emitted by underground diesel-powered mining equipment. Tests were conducted in an isolated zone of an underground mine to evaluate the effectiveness of alternative fuel formulations, namely, water-fuel emulsions, blended biodiesel fuels, ultralow sulfur diesel fuel, and #1 diesel; and selected exhaust after treatment devices, namely, diesel oxidation catalysts (DOCs), diesel particulate filter (DPF) systems, and filtration systems designed around high-temperature disposable filter elements. The results showed that using a cold-weather and warm-weather water-fuel emulsion formulation reduced mass concentrations of elemental carbon (EC) by about 70% and 85%, respectively. The 20% and 50% soy biodiesel blends reduced EC by 49% and 66%, respectively. The reductions were slightly less pronounced for the 20% and 50% yellow grease biodiesel blends—33% and 56%, respectively. EC concentrations were unaffected by using ultralow sulfur diesel in place of #1 diesel. Use of the reformulated fuels did not substantially alter the concentrations of nitric oxide and carbon monoxide. However, a measurable increase in the nitrogen dioxide (NO2) peak concentration was observed during the biodiesel tests. The ArvinMeritor (AM) fuel-burner DPF system with a palladium-catalyzed DOC reduced EC concentrations by 92%. The diesel filter elements from Donaldson Co., Inc., and Filter Service & Testing Corp. reduced the EC concentration of the mine air by 92% and 70%, respectively. When the palladium-based DOC was used with the AM DPF, it raised the average and peak downstream NO2 concentrations by a factor of three. Tests of the AM DPF system with a platinum-catalyzed DOC and CAP/ETG catalytic particulate oxidizer system had to be terminated because the elevated NO2 concentrations threatened to overexpose the operator. The tests with only a selected DOC also resulted in increased NO2 concentrations in mine air.

Jan 8, 2006

By G. B. Atkinson

The Bureau of Mines, in cooperation with McDermitt Mine, investigated a method for recovering mercury metal from mercury sulfide flotation concentrate by a hydrometallurgical technique. This preliminary report shows the feasibility of leaching mercury with a cupric chloride solution and electrowinning mercury from the solution. Proposed chemical reactions are shown in equations 1 through 3: 2CuC12 + HgS + 2CuCl + HgC12 + S°; (1) electrolysis HgC12 ?Hg + C12; (2) 2CuC1 + C12 ? 2CuC12. (3) A bench-scale leaching-electrowinning apparatus capable of treating 2.36 kg of sulfide concentrate in 11 days was operated continuously. An acid chloride solution containing, in grams per liter, 70 Ca, 60 Cu, 30 Fe, and 80 Hg was used as both leachant and electrolyte; 99.5 pct of the mercury was solubilized from the sulfide concentrate. Electrolysis of the leaching solution recovered mercury metal at an average current efficiency of 32 pct and an average energy consumption of 1.2 kwhr/lb Hg. Results from a preliminary economic evaluation indicated that a plant producing 31,500 flasks of mercury per year would have a capital cost of $3.7 million and an operating cost of $62 per flask of mercury.

Jan 1, 1983

Provide mine safety personnel, MSHA inspectors, and original-equipment manufacturers with guidelines and a check list for inspecting rollover protection structures (ROPS) being used in mining operations. The Problem ROPS are provided on mobile surface mining equipment to protect operators from such safety hazards as machine rollovers, falling objects, and collisions. However, the protective capability of a ROPS can be greatly reduced if it is damaged. Certain kinds of damage, such as hair- line cracks, corrosion, and loosened bolts, may occur as a result of normal machine use but may not be recognized as unsafe by untrained personnel. Therefore, the Bureau of Mmes designed a manual which can be used by mine personnel when inspecting ROPS equipment. The Manual The manual was prepared to help acquaint mine safety personnel and MSHA inspectors with typical ROPS deficiencies and their causes. It provides a systematic means for inspecting ROPS so that the identified deficiencies and their causes can be corrected. It is suggested that an inspection of the ROPS be conducted after every 1,000 h of equipment operation, or sooner if the structure has been subjected to any unusual loads which could cause damage, such as a rollover, highwall caving, or collision. The manual also details common deficiencies in the structure and attachment hardware which may affect the service life. The checklist, when used as instructed in the manual, provides a means for systematically inspecting the structure to ensure maximum protective capability and conformance with applicable Federal regulations.

Jan 1, 1986