Search Documents

By R. W. Van Dolah

An important function of stemming used to confine explosives in shot holes in underground coal mines is to minimize the chance of ignition of firedamp or coal dust by the detonation products. Until 1952, the Bureau of Mines approved only the use of fireclay or similar incombustible material for stemming permissible explosives. At least 2 feet of stemming were required except in holes less than 4 feet deep; in such short holes the stemming was required to be half the depth of the hole. Over the years, several special stemming devices have been proposed in the United States as substitutes for fireclay. Many economic and safety advantages were claimed for these devices, but only one approved device has been marketed in this country. Bureau requirements for stemming explosives in coal mines were modified at that time to permit the approved stemming device to be used as a substitute for the required fireclay.

Jan 1, 1961

By R. A. Franks, J. C. Edwards, L. Yuan

To determine the critical air velocity for preventing smoke rollback, diesel-fuel fire experiments were conducted in the National Institute for Occupational Safety and Health’s (NIOSH) Pittsburgh Research Laboratory’s Safety Research Coal Mine. Such information is necessary for preplanning and implementation of ventilation changes during mine fire fighting and rescue operations. The fire intensity varied from 50 to 300 kW depending on the fuel tray area. Airflow in the 2-m- (6.6-ft-) high, 2.9-m- (9.5-ft-) wide coal mine entry was regulated during the course of each experiment. The airflow was measured upwind from the fire as an average over the entry cross-section with an ultrasonic airflow sensor and was recorded dynamically with a mine monitoring system. The extent of smoke reversal was monitored with light-obscuration monitors, ionization smoke sensors and visual observations. Experimental results for the critical air velocity for smoke reversal as a function of fire intensity compared very well with model predictions based upon a computational fluid dynamics fire dynamics simulator.

By W. J. Kroll

This report on the bibliography of zirconium has been confined to those publications and patents that appear to be useful in the commercial development of the metal, both the malleable and the nonmalleable. The methods of production have been stressed and special attention has been given to the alloys. Compounds of importance, like the oxide and chloride, for the manufacture of the metal or of the alloys have been considered. The use of the oxide in refractories anal in the glass and porcelain industries has been omitted. The present survey is critical; that is to say, an attempt has been made to evaluate the effectiveness of suggestions made in the literature. The exhaustive work of Marden and Richy, Bureau of Mines Bulletin 186, published in 1921, has been taken as a base to start from with the intention of bringing the subject up to date with material published in the last 24 years. During this time there was considerable 'advance in the preparation of the metal and Its alloys, and in the development of new uses. On the other hand, there was little progress in the methods of decomposing the ores, so that the chapter on this latter phase is necessarily short.

Jan 1, 1946

By S. P. Sandoval

Previous research by the U.S. Bureau of Mines demonstrated that nonionic surfactants increased the leaching rate of copper in the flask leaching of chalcopyrite with ferric sulfate if sufficient ferric sulfate was present. This research was continued by the Bureau in Part 2 to further explore the application of nonionic surfactants to the dump leaching of chalcopyrite. A polyoxyethylene lauryl ether was selected as the superior nonionic surfactant tested at 25° and 50° C. The addition of the surfactant increased copper leaching by 116 pct at 25° C and 1.0 pct solids and by 61 pct at 50° C and 0.5 pct solids at Fe 3+ concentrations greater than 1 g/L. At 0.1.0 g/L Fe 3+ and below, the addition of the surfactant produced as much as a 35 pct decrease in leaching. Each of the nonionic surfactants studied was found to be heavily adsorbed by a typical chalcopyrite ore, which poses a serious barrier to the application of nonionic surfactants in an actual chalcopyrite dump.

Jan 1, 2010

By Thomas A. Morgan

The distribution of stress adjacent to each of 25 mine openings was determined by the borehole stress-relief method in the FMC Corp. Westvaco trona mine at Westvaco, Wyo. The purpose of the stress determinations was twofold: First, to study the effect on these distributions of various factors such as opening shape, stress level, and loading history; and second, to estimate the distribution of stresses adjacent to extensive high-extraction (85 to 100 percent) areas. Stress distributions in areas of low average stress correspond closely to the theoretical distributions based on elastic theory. However, in areas of high average stress, the stress distributions are of a type associated with plastic failure. The stresses adjacent to a mined-out area supported by remnant pillars were significantly higher than the stresses adjacent to another area in which the remnant pillars were removed.

Jan 1, 1965

By S. H. Ash

The Pennsylvania anthracite-mining region is the only one in the world of major magnitude. As the deposits of anthracite in the United States are limited virt113.lly to Pennsylvania, the difficulties of this industry have been commonly considered a State rather than a national problem. However, there is also national interest in the conservation and wise utilization of all fuel resources and in the control of interstate waterways. The anthracite industry is confronted with the very se:;-ious :problem of accumu.lation of water in many of the mines. This problem must be solved soon if progressively higr-er mi~ing costs are to be avoided. The water proble~ cannot be solved by the operating compa,nies without State or Federal aid, or both, owing to the magnitude of the work requir~d, diversity of interests of the coal ana surfa.ce ovmerships, hazard to the whole mining community, and interests affec~ed outside the mining region. The cost of abati~ the ever-increasing_surface seepage to mine workings and of handling this seepage once it }3s occurred is beyond the economic resources of most ope~ating ma.'18.gements. The data in this paper giving the high lights of the water problem and indicating what appears to be a step in the right direction are based upon observations made during the past year that the industry desires and believes it is to the npublic interesttr to keep mine workings free of flood end surface waters.

May 1, 1941

By Laurance L. Oden

The Bureau of Mines conducted corrosion tests of 18 commercial alloys in H3 P04 -phosphate rock or A1,03 slurry, in 10 pct HF, and in 25 pct H2 SiF6 to simulate three environments anticipated in a Bureau process to extract fluoride values from phosphate rock. Small alloy coupons were rotated in duplicate tests at 4.4 to 21 fps in the slurry at 170° C to determine rates of erosion-corrosion. At 4.4 fps the lowest rates, in mils penetration per year (mpy), were measured for Hastelloy C-276 (<20), Hastelloy B (30), and Inconel 625 (150);the rates increased at 21 fps to 55 mpy, 45 mpy, and 1,000 mpy, respectively. The corrosion rate for all alloys exceeded 40 mpy in either the equilibrium vapor or liquid phases of aqueous solutions containing 10 pct HF or 25 pct H2SiF6 at 100° C. Uniform corrosion in 10 pct HF at 50° C was observed only for Inconel 625 (22 mpy), Hastelloy C-276 (43 mpy), and Illium 98 (17 mpy). Inconel 625 (0.75 mpy), Hastelloy C-276 (1.3 mpy), Illium 98 (1.7 mpy), and Incoloy 825 (0.45 mpy) were attacked uniformly in 25 pct H2SiF6 at 50° C.

Jan 1, 1974

By Robert M. Becker

The evaluation of existing rock stresses from measurements of the change in diameter of a borehole that is stress relieved by overcoring has become a common practice, The stress evaluation has been generally based ,on isotropic relations whereas rock in varying degrees is anisotropic. A plane elasticity solution for a circular hole along one axis of an orthotropic medium is adapted for evaluation of in situ stress from borehole deformation measurements. A consistent triaxial testing approach for determining elastic properties of the overcore is also outlined. Comparison of isotropic with anisotropic interpretations of the state of stress show that large errors in evaluation may occur if the anisotropic character of the rock is neglected.

Jan 1, 1967

By C. Daniel Kealy

Finite-element,, mathematical models that solve LaPlace&apos;s and Richard&apos;s equations numerically were used to locate the phreatic surface within tailings pond embankments and to define the subsurface flow of water from the pond. Both must be known to design structurally and environmentally safe tailings dams. The permeability distribution within and beneath the embankment, the fluid potential values upgradient and downgradient from the embankment, and the geometry and elevation of an approximately impermeable layer at some depth beneath the embankment were used as computer inputs in analyzing over a dozen finite-element models of tailings dams varying structurally from simple to complex. Results predicted with the finite-element model were confirmed with measurements in a laboratory model of a tailings pond and in the field. Of particular importance to the design of safe slopes, all data indicated that the phreatic surface within a tailings dam is concave upward, a configuration opposite that in most earth dams. The close correlation between predicted and experimental values confirmed the practicability of using the finite-element technique to design safe tailings dams.

Jan 1, 1971

Increase the productivity of domestic mining operations by improving the performance of rock drilling systems. Approach Investigate the use of chemical solutions at zero surface charge concentrations as drilling fluid additives to enhance penetration rates and extend bit life. Background Bureau researchers have investigated the use of chemical additives to enhance drilling performance and have found that the most efficient drilling occurred when the drilling fluid was able to maintain a zero surface charge (ZSC) on the rock surface. Laboratory drilling studies using 5/8-inch diameter diamond-impregnated coring bits on rock types such as quartzite, granite, taconite, and marble. Cationic compounds were used as the surface charge neutralizing additives during these tests. The drilling studies demonstrated enhanced drilling performance, however, only at the singular additive concentration that produced the ZSC condition. Bureau researchers made a breakthrough when they found that polyethylene oxide, although a nonionic polymer, was able to maintain the ZSC condition over a wide range of concentrations. Success using polyethylene oxide as the drilling fluid additive during subsequent laboratory tests prompted testing under field conditions.

Jan 1, 1991

As fulfillment of the requirements of Contract H0387019 for the United States Department of the Interior, Bureau of Mines, a complete field kit, for performing on-site determinations of individual employee Time Weighted Average (TWA) exposures to nitrogen dioxide (NO2) and nitric oxide (NO), has been developed by MDA Scientific, Inc. This report provides background information and experimental data validating the use of this kit with confidence to ? 10 percent accuracy.

Jan 1, 1981

By A. E. Isaacson

The U.S. Bureau of Mines determined the effect of common sulfide minerals on the corrosion rates of various types of ferrous alloy grinding media. Data obtained from this study will aid in determining the contribution of any electrochemical reactions between sulfide minerals and grinding media to the total grinding media consumption. Common sulfide minerals used in this study were chalcopyrite, galena, and sphalerite. In the presence of oxygen, chalcopyrite was found to increase the corrosion rate, galena was found to decrease the corrosion rate, and the effect of sphalerite was dependent upon the type of grinding media. Possible electrochemical reactions of these minerals in the presence of grinding media are suggested.

Jan 1, 1989

By Robert K. Koch

The Bureau of Mines investigated separating HF from HF-SiF4-H2O mixtures by passing the mixed gases through a sodium fluoride slurry in an airlift scrubber and forming a mixed precipitate of NaHF2 and Na2SiF6. The oven-dried precipitate was thermally dissociated in two stages. The first stage was carried out at 400° C and dissociated NaHF2 to NaF and HF. Condensation and analysis of the evolved HF proved it to be 97 to 99 weight-percent HF containing 0.79 to 0.99 weight-percent H2O and 10 to 93 ppm silicon. The second stage was carried out at 700° C and dissociated Na2SiF6 to NaF (for recycle) and SiF4. The quantity of HF recovered from gaseous HF-H2O-air mixtures decreased with increasing relative H2O concentrations. Air was beneficial when scrubbing extremely dilute wet HF gases. At HF partial pressures of 0.24 and 0.013 mm Hg in the scrubber entrance gases, HF partial pressures of 6.2 x 10-4 and 9 x 10-6 mm Hg were obtained, respectively, in the scrubber exit gases. Scrubber efficiencies were 99.7 and 99.3 percent.

Jan 1, 1966

By M. L. Glenn

The Bureau of Mines is conducting research on substitutes for chromium-containing alloys in order to conserve imported critical and strategic materials. Part of this research concentrates on finding low-chromium substitutes for heat-resisting stainless steels for the temperature range 600° to 800° C. Ferritic alloys are emphasized that have oxidation resistance provided by chromium contents as low as 10 pct and stress rupture strength provided by the precipitation of the chi(X)-phase intermetallic compound, (Fe36Cr12 (Mo, Ti)10). Initially, research was concentrated on selecting an alloy composition having a minimum chromium content with strengthening provided by the X-phase. An Fe-(10-12 pct)Cr-6 pct Mo-(1.5-2.0 pct)Ti alloy was selected. After the alloy selection, the tensile, stress rupture, and oxidation properties were determined. Stress rupture properties were found to be similar to those of 304 stainless steel. However, the alloys possessed brittleness during both stress rupture and tensile testing, possibly as a result of too high a content of molybdenum and titanium. Higher than expected oxidation rates were found that may be caused by the high molybdenum content.

Jan 1, 1984

By W. W. Adams

"Accidents at coal mines in the United States in September 1926 resulted in the loss of 170 lives, according to information furnished to the Bureau of Mines, Department of Commerce, by State mine inspectors. Of this number 125 occurred at bituminous mines and 45 in the anthracite field. As the bituminous output of coal for September was 48,976,000 tons, and the production of anthracite was 8,444,000 tons, the fatalities reported represented a death rate of 2.55 per million tons for bituminous mines and 5.33 for anthracite mines. The industry as a whole showed a fatality rate of 2.6 per million tons of coal produced in September 1925 the rate for bituminous coal mines was 3.29; the anthracite mines were idle in September last year due to a strike.During the first nine months of the present year 1,759 men have been killed by accidents at the coal mines throughout the United States, resulting in a death rate, per million tons of coal produced, of 3.76 as compared with 3.95 for the same period in 1925. Reports for bituminous mines alone showed a nine-month fatality rate of 3.53 which was about the same as the corresponding rate from January to September in 1925. The anthracite rate for the present year, however, shows a decrease of about 17 per cent; that is, the rate has declined from 6.36 to 5.28.Records covering the first nine months of 1926 show that 12 ""major"" disasters, that is, disasters in which five or more men were killed at one time, have resulted in the loss of 271 lives as against 10 disasters and 199 deaths in the corresponding months in 1925. The fatality rates for these disaster: alone were 0.579 and 0.465, respectively. One major explosion occurred at Tahona, Oklahoma, on September 3, 1926, in which 16 men lost their lives.An analysis of the principal causes of the 1,759 fatalities for the first nine months of the present year shows a reduction in the death rate as a whole and for falls of roof and coal and for explosives, but an increase in haulage, gas and dust explosions, and electricity. The comparative rates for these accidents were:"

Oct 1, 1926

By James W. Martin

This user?s manual analyzes the application, selection and performance of hopper/crusher/conveyor systems used with front-end loaders in surface mining operations. It is designed to be used in conjunction with its companion manual: "Guideline Manual for Front-End Loader Load-and-Carry Applications" Aspects of the application are covered as well as design considerations of the hopper/crusher/conveyor units. Lists of equipment manufacturers, crusher specifications, together with a series of checklists, are included for preliminary analysis.

Jan 1, 1982

By J. H. East, D. Harrington

Fires in metal mines have resulted in some of the worst disasters in American mining history insofar as loss of life is concerned. One fire caused the death of 163 miners and individual less spectacular fires have cost the lives of scores of workers. Metal mines are often very deep, and the men working on numerous levels far removed from direct communication with the surface. In many instances they cannot be warned quickly of an emergency or a mine fire by telephone or other usual method of communication, or by messenger, flashing lights, gongs, sirens, or whistles. Telephones are not paricularly effective as a means of warning unless placed at all strategic points and with attendants always on duty; though telephones well placed have a definite value in any well-pla.mied emergency procedure in mines of all kinds. Messengers are slow and men working in remote parts of a mine would not receive a warning quickly enough. Most metal mines are not electrically lighted, except at or adjacent to shaft stations and in principal haulageways, and this limits the effectiveness of flashing lights. Electric gongs and sirens or whistles have been tried as warning signals, but the sound is quickly deadened and does not travel upward into the stopes, especially those of an extensive volume. Shutting off the compressed air is by no means satisfactory as a warning, as not infrequently it is stopped accidently, so that it loses its value as an alarm. The introduction of water into compressed air lines is undesirable as a fire warning and necessitates considerable care, especially in deep mines; pressure-reducing valves must be provided to reduce pressure that otherwise would break connections or split the pipe. A quick, effective method of warning miners underground of the existence of an emergency requiring them to leave the mine immediately, such as a fire on the surface or underground, is provided by the introduction of stenches in the compressed-air lines. This method of warning is by no means experimental, inasmuch as it has been used successfully for many years in

Jul 1, 1943

By Charles L. Harnes

A mineral pigment is a colored substance dug from the ground, which after treatment can be mixed with a drying oil to form a paint. Not all colored earths, however, can be made into satisfactory pigment. Much depends upon the attractiveness and uniformity of the color and the ease of purification. Mineral pigments are distinguished from chemical pigments by a difference in origin and treatment. Chemical pigments are not found ready-made in the earth but must be synthesized or otherwise obtained from other compounds or elements; for example, cadmium yellow, a chemical pigment, is precipitated from a solution of cadmium chloride, hydrochloric acid, and sodium sulfide.

Jan 1, 1942

By J. R. Ross

A reconnaissance for sources of scandium and a metallurgical investigation of recovery methods for byproduct scandium from uranium mill solutions were conducted by the Bureau of Mines. The work on scandium was undertaken to obtain information on domestic resources and to explore and develop recovery procedures in consonance with the Bureau&apos;s long-range program for conservation and wise utilization of mineral resources. The element scandium is widely distributed in the earth&apos;s crust in trace amounts, but it seldom occurs as an important constituent in any mineral. An exception is thortveitite, (Sc,Y)2 Si207) a rare mineral that contains various amounts of scandium and yttrium and may contain up to 42 percent scandium oxide (SC203). Knowledge of the chemistry of scandium has expanded rapidly in recent years (1, 4, 9)4 but only fragmentary information is available about the metal because it is still largely a laboratory curiosity without established uses (2, 3). A recent study shows some of the physical proper-ties of the metal are (1) density of 3.05 grams per cubic centimeter) (2) melting point of 1,540° C, (3) hexagonal close-packed structure) (4) hardness of about 50 Brinell (500-kilogram load), and (5) an alloy behavior similar to yttrium and rare-earth metals (2). The price of $2,850 a pound for scandium oxide of 99.9 percent purity and $2,700 a pound for oxide of 99 percent purity reflects the scarcity and complex chemistry of the element.

Jan 1, 1962

By John M. Devine

Hydrogen sulphide associated with natural gas was noted as early as at Point Albino, Canada. The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence was by no means common. However, in recent years, with the development of the producing zones of test Texas and the Texas Panhandle, the Production of "sour" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor--frequently a major problem--in the drilling and operation of many wells in those areas. The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is made of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen iron the standpoint of safety and health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. Likewise, the problem of hydrogen-sulphide corrosion of production equipment has been given considerable attention in the literature.

Jan 1, 1931