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By A. J. Buchan

The wear of steel pipelines used for the transportation of backfill slurries is frequently regarded as an erosion problem only. An investigation was undertaken of the likely contribution to the total 'wear rate' made by corrosion. Use was made of a pipe flow loop with catholically protected specimens and corrosion inhibitors. Laboratory electrochemical tests utilizing a rotating-cylinder electrode were also conducted. The slurries used were classified tailings from two mines at a relative density of 1,7. The velocities were between 2 and 4,9 m/s. Substantial decreases in the wear rate of up to 80 per cent for one slurry and up to 67 per cent for the other were obtained with the use of corrosion control, showing that corrosion and, more importantly, interaction between erosion and corrosion, contribute a significant portion of the overall wear in steel pipelines

Jan 1, 1994

By J. Petersen, K. Shaik

The traditional route utilised for the recovery of Platinum Group Minerals (PGMs) in South Africa involves the concentration of ore by flotation, followed by smelting to produce a PGM rich matte, which is then digested hydrometallurgically to solubilise base metals and Platinum Group Elements (PGE). HCl/Cl2 is conventionally used for PGE dissolution from concentrated material, which is an aggressive reagent associated with high maintenance costs as well as environmental concerns. Of interest is the leaching of PGMs directly from mineral ores, low grade concentrates and tailings in a cyanide-ferricyanide system as a more sustainable alternative. This system has shown favourable Pt recoveries among the Pt minerals, but with sperrylite (PtAs2) displaying highly refractory behaviour. The dissolution of sperrylite is investigated in a cyanide-ferricyanide system in the context of an electrochemical study involving OCP, chrono-amperometry and cyclic voltammetry. This approach allows the assessment of leaching characteristics as well as the investigation of surface passivation, which is believed to contribute to poor Pt recoveries. Some evidence is presented that such passivation is related to the formation of arsenide species on the mineral surface. Keywords: Sperrylite, PGMs, cyanide, ferricyanide, electrochemistry

Jan 1, 2020

Geologists in some underground gold mines collect grab samples from broken ore piles or trucks as a method of grade control. It is often known as muck sampling. Generally, the goal of grab sampling is to try and reconcile the mined grade at the ore source to the predicted grade and/or predict the mill feed grade. The mass of the sample collected is limited by health and safety issues, as well as the capacity of the laboratory to process the samples within a given timeframe. In general terms, grab sampling is known to be problematic because samplers tend to over sample the fines, and/or pick out high-grade fragments; surface sampling of piles does not test material within the pile; muck piles in development drives/faces are likely to be zoned due to the blasting sequence; high or low-grade material may preferentially segregate in the pile during mucking; the five percent mass reject size of the material in muck piles is very large from underground blasting; some correlation usually exists whereby the larger fragments are enriched or depleted in the critical component of value; and the average error made in estimating the true stockpile grade is likely to be high. The method is prone to chronic fundamental sampling, grouping and segregation, delimitation, and extraction errors. Substantial warnings must be given with respect to the use of grab sampling for grade control in gold mines. The method may appear to work sometimes, which can be attributed to a fine gold particle sizing and more disseminated distribution. As with all sampling methods, its appropriateness must be determined by ore characterization and heterogeneity testing to ensure the method suits the ore type.

Jan 1, 2009

By J. Petersen, H. Naderi, H. Zare, M. H. Nikzad, M. Karimi

In the copper electrorefining process, the dissolution of anodes is significantly reduced or even stopped when the passivation phenomenon occurs. The results of this phenomenon are increasing energy consumption, residual formatting, and voltage levels in the cell. In this study, the electrochemical behaviour of blister copper in the presence of sodium persulfate (PDS) was studied. The electrochemical methods of LPR, Tafel, and Electrochemical Impedance Spectroscopy (EIS) were used. The results showed that the addition of sodium persulfate activates the electrode surface and increases the open circuit potential. In the presence of PDS, the polarisation resistance of the electrode shows an increasing or decreasing tendency, based on the PDS concentration. This tendency is probably due to the formation of surface layers (such as slime layer or copper sulfate) and dissolution of this layer at various concentrations of PDS. The lowest polarisation resistance of 1.8 ohms and the highest corrosion current of 60.6×10-3 and 36.6×10-3 A/cm2 from LPR and Tafel techniques respectively were obtained at the concentration of 40 g/l PDS. Based on the results of potentiodynamic and electrochemical impedance spectroscopy tests, the addition of sodium persulfate to the solution reduces the corrosion resistance, therefore the passivation time of the blister copper anode increases. Keywords: Blister copper, electrorefining, sodium persulfate, anodic passivation

Jan 1, 2020

By Y. Zhou, G. Chisakuta, P. Bwando, G. Mitshabu

A newly started copper hydrometallurgical plant was confronted with a manganese oxidation issue in electrowinning. This oxidation, in the absence of the amount of iron required to stabilise the electrolyte oxidation-reduction potential, is known to produce oxidants (MnO2, MnO4) that can cause accelerated degradation of the organic phase components in solvent extraction and corrosion of lead anodes in electrowinning. The overpotential required to build up the protection layer on new anodes causes an increased electrolyte potential that creates oxidized species in the electrowinning tankhouse, and these species come back to solventextraction plant with the recycled spent electrolyte. This paper discusses the impacts of manganese oxidants on the health of a plant organic phase. It also outlines the actions taken using iron scraps and sulfur dioxide to mitigate the problem that happened due to the lack of ferrous iron sulfate available on site, as recommended for better control.

Jan 1, 2023

By RT White

For a number of years the steel tube and pipe industry has worked on resolving problems of product quality. These have largely been resolved and new products have been developed to take advantage of new developments. To fully coordinate market acceptance guidance on use of galvanized piping was also required. This was largely achieved locally in 2004 with the publication by the SABS of ARP 060 - Guidance on the use and application of hot dip galvanized steel piping for the transportation of potable water in South Africa. Use of this document is not easy however and a need to have a simple computer model to assist the specifier was identified. Working with a major tube and pipe manufacturer this is now being developed and this paper will provide the background to the model?s development and its intended use. There is still a need for a partner Code of Practice on the performance of galvanized piping in buried conditions and the need for this will be highlighted together with current available information.

Jan 1, 2006

By J. J. Cilliers, J-A. Lamamy, J. N. Rasera, K. Hadler

Production of oxygen on the moon can be achieved by reduction of lunar soil. One such reduction technology, hydrogen reduction, favours a high proportion of ilmenite in the feedstock. Ilmenite is present in lunar soil as a minor mineral phase, but it can be upgraded using electrostatic separation. This study presents the results of a preliminary investigation into the operating parameters and sensitivities of a free-fall electrostatic mineral separator for lunar applications. Samples of ballotini and ilmenite as well as simple binary mixtures of the two were tribocharged on copper and passed through a uniform electrostatic field. The field is varied to change the electrostatic force acting on the particles. The proportion of material reporting to the positive electrode collectors, negative electrode collectors or the central collector was measured to determine the separation performance. The data confirmed that the charge transferred from the tribocharger to each species is in agreement with the triboelectric series; ballotini was found to charge positively on copper and ilmenite negatively. Particle-particle contacts were dominant, however, resulting in a somewhat symmetrical particle distribution in the collectors. These findings indicate that the copper tribocharger design requires optimisation in order to substantially increase particle-wall contacts. Four binary mixtures with feed grades of ilmenite ranging from 5% to 20% were prepared and tested. This study found that a higher ilmenite head grade resulted in a higher concentrate grade (26.3% from a head grade of 20%) with low recovery (3.4%). In contrast, the lower feed grade resulted in a low concentrate grade but higher recovery. The mass yield of ilmenite was 1.4 times greater for the highest-grade feed than for the lowest. A subsequent study into the reprocessing of middling fraction found a nearly constant relationship between cumulative grade and recovery. This is the first investigation into the effect of feed grade on the concentrate grade and recovery for lunar mineral processing. Keywords: Lunar resources, beneficiation, electrostatic, SRU, ISRU

Jan 1, 2020

By A. van den Berg

Mining of sand in South Africa is rapidly growing to sustain an increasing demand for sand for building purposes. Although mining of sand is regulated by environmental legislation, such as the National Environmental Management Act 107 of 19981, previous bad mining practices have left areas of land degraded and vulnerable to erosion. This study was conducted in the Seringveld Conservancy, where mining of sand has left the landscape with a degraded and unsightly appearance, and where little rehabilitation of the original vegetation has taken place. The aim of the study was to develop rehabilitation techniques for the degraded mined soils on two sand mines, Boekenhout Sand and Krokodil Sand, and to develop an overall strategy of revegetation by regenerating key plant species. Techniques for regenerating indigenous tree species cover, using modified mined sludge if topsoil is not available, were used to develop a practical and cost-effective strategy to be used in revegetation. A comparative trial was used to cultivate indigenous tree species in different soil mixtures. The study is important as it provides new information on the rehabilitation and revegetation of sand mined areas in the Seringveld Conservancy. This study will determine if alternatives could be used to replace topsoil on mined areas where none is available. The study is needed to determine whether revegetation of the mined areas would be possible using indigenous plant species that are difficult to grow. The overall results indicate that replacing topsoil was successful for various modified soil mixtures that could sustain the growth of indigenous vegetation on the sand mines. Different indigenous tree species require different modified soil mixtures for successful propagation. A revegetation strategy was developed to complement and enable the rehabilitation of the mined areas in the Seringveld Conservancy. Keywords Rehabilitation, revegetation, Seringveld, sand mines, Burkea africana, topsoil, germination trials.

Jan 1, 2011

By G. Chisakuta, P. Bwando, G. Mitshabu

By the end of 2022, the south-eastern Copper Belt region of the Democratic Republic of Congo was host to more than 40 small, medium, and relatively large sized copper solvent extraction sites. To date, solvent extraction reagents supplied in this region have never exceeded 50% of ketoxime content. We generated laboratory extraction and strip isotherms and used these with the BASF IsocalcTM modelling software to assess the benefit of using higher ketoxime blends on the main metallurgical performance indicators such as copper recovery and net transfer. Pure ketoxime extractants combine a relatively low strip point and a decent loading capacity, which are most effective as the pH of the pregnant leach solution gets closer to 2.

Jan 1, 2023

By O. O. Ogunmodimu, D. K. Weatherley, M. S. Powell

Discrete element methods (DEM) have provided the ability to resolve the complex phenomena experienced by ore within comminution devices such as tumbling mills. The new developments in DEM techniques and the corresponding increase in computational power have made it more feasible to study the movement of individual ore particles as they traverse a tumbling mill. A range of information can be extracted on individual particle impact histories, such as kinetic energy at the time of collision, velocities of individual particles, per-particle stress tensors, impulse, and collision energy. DEM codes have been modified to provide required information that can be analysed in associated software to investigate the impact of varied operational parameters on the resultant granular dynamics. This paper explores the reaction of individual ore particles to the breakage environment within a tumbling mill using DEM techniques and studies the stressing conditions that would lead to either impact or abrasive breakage. Keywords: DEM, comminution, tumbling mill, breakage

Jan 1, 2020

By K. Sasaki, Y. Oriia, Shigeto Kuroiwa, H. Miki, Yuji Aoki, T. Hirajima, G. P. W. Suyantara

The effect of a sulfite reagent on the floatability of chalcopyrite and enargite was investigated in this paper. The flotation tests using single and mixed minerals were performed under various concentrations of sulfite. The flotation tests using a single mineral showed that the sulfite reagent depressed the natural floatability of both minerals at pH 9. Surprisingly, enargite was floated after the addition of potassium amyl xanthate (PAX) following the sulfite treatment, and the floatability of chalcopyrite depressed under a similar condition. X-ray photoelectron spectroscopy analysis results showed that the sulfate species increased after the sulfite treatment on both minerals. However, the addition of PAX removed this sulfate species and rendered the enargite surface hydrophobic. This phenomenon was not observed on the chalcopyrite surface. FTIR analysis and PAX adsorption studies were performed to support this finding. The flotation of a mixed mineral was in agreement with the flotation of a single mineral, indicating a possibility for selective flotation of chalcopyrite and enargite using the proposed method. Keywords: Flotation, chalcopyrite, enargite, sulfite, potassium amyl xanthate

Jan 1, 2020

Infacon 74 The National Institute for Metallurgy, the South African Institute of Mining and Metallurgy, and the Ferro-Alloy Producers' Association of South Africa extend a cordial invitation to participate in the International Ferro-alloys Congress to be held in Johannesburg, South Africa, in April 1974. Obituary RICHARD AUSTIN COOPER On the 31st March 1972, a once very active member of the Institute, R. A. Cooper, died at the age of 82. He had served on the Council for many years and was Vice-President in 1933/34. ALEXANDER JEREMIAH ORENSTEIN CB., CM.G., C.B.E., LLD., D.Se., M.D., M.R.C.S., F.R.CP., F.R.S.H. Dr Orenstein, who died on the 7th July 1972 at the age of 92, was so well known and so widely acclaimed during his lifetime that it is difficult to add to the tributes which have already been paid to him.

By G. Akdogan, C. Dorfling, L. Bumhira

Hydrometallurgical recovery of rare earth elements from phosphors obtained from end-of-life fluorescent lamps involve leaching followed by extraction of dissolved metals from solution. The similar properties of rare earth elements make selective recovery of individual elements challenging. The aim of the paper was to investigate the extraction of primarily Ce and Tb from a hydrochloric acid leach solution also containing other REEs (Y and Eu) as well as impurity metals (Ca and Al). Batch solvent extraction tests were performed with di-(2-ethylhexyl) phosphoric acid (DEHPA) at various extractant concentrations, pH conditions and organic-to-aqueous ratios. Extraction isotherms and separation factors for the range of conditions tested in the project are presented in the paper. Separation of individual REEs was not possible at the conditions investigated, but a mixed REE product can be obtained in a single extraction stage operated at a pH of 0.5 using 1 M extractant at an O/A ratio of 1; these conditions resulted in complete Y and Eu, 95 % Ce and 99 % Tb extraction with Ca and Al coextraction below 7 %. A better quality mixed REE product can be produced by operating at lower pH and extractant concentration conditions, but this would require a larger number of extraction stages. Keywords: Cerium, fluorescent lamps, phosphors, rare earth elements, solvent extraction, terbium

Jan 1, 2020

By Jean Michel Marino, Jean-Pierre Slama

"The computer methods used by the French Commissariat a l'Energie Atomique, which are applicable to any type of ore deposits, are:(i) Ore reserve estimation. The data are either the core analyses or gamma leggings. To determine the spatial distribution of the ore, three different methods of interpolation are used. Two of these are based on the least-squares theory and the third one is an application of the regionalized variable theory. The interpretations of the orebody by the geologists are introduced in the computer program as often as possible.(ii) Optimal open pit design. From the spatial distribution of ore, the three-dimensional outlines of the optimal pit are determined by a geometrical algorithm which allows different slopes varying with the azimuth.Finally, the optimization of annual successive plans arc discussed."

Jan 1, 2014

By R. W. O. Kersten

Backfilling is one of the options available to the mining engineer in mine design. The decision as to the type of backfill is dependent on the purpose for which it will be used. For example, in a situation where high-grade, steeply dipping multiple reefs are to be mined, the purpose would be the following: ? to facilitate maximum extraction; a ? to minimize loss of fines; ? to allow closely spaced multiple reefs to be mined; and a ? to create a working platform. The physical properties required which will satisfy the abovementioned requirements can then be defined; the design of the fill plant, as well as the transport of the fill, will be governed by these considerations. The same procedure is also adopted in deciding on backfill in single- reef gold mines. The first question to be asked is the purpose of the fill. It may be to reduce the energy release rate, for environmental reasons, to reduce timber usage, to improve productivity, to reduce stoping costs, to obtain higher mining extraction, and so on. Only after one, or a combination, of these factors has been selected, can the specifications for the fill be decided on, and the plant designed accordingly. The introduction of backfill at Sheba Gold Mine will be used to illustrate the procedure adopted by Anglovaal in determining the type of fill required.

Jan 1, 1988

By L. Cheng, Y. Liu, Z. Shen, H. Shang, Y. Li

The pre-concentration process of magnetic coarse particles can discharge waste rock or liberated gangue before milling, which is an effective means to reduce cost and increase the efficiency of the concentrator, but the weakly magnetic ore doesn’t have the effective separation method of coarse particle such as hematite, limonite, ilmenite and so on, Because the composite iron minerals contain both strong and weak magnetic elements, the pre-concentration process cannot be applied, or the existing pre-concentration process has problems of complicated configuration and high operation cost. By researching a new type of external magnetic separation technology, the pre-concentration process of composite iron ore was realised by single equipment, which can have a good recovery rate with simple arrangement. In this paper, the separation principle and structure characteristics of the external magnetic separator were researched, and the magnetic circuit characteristics of the external magnet were analysed. The laboratory tests of vanadium titanium magnetite were conducted, and the test results proved that the external magnetic separator can be applied for the pre-concentration process. The industrial application shows that a product of TFe 24.76% with 90.08% recovery, TiO2 10.10% with 91.78% recovery can be achieved from the feed of TFe 20.67%, TiO2 8.33%. Keywords: Coarse particle pre-concentration, composite iron ore, external magnet, magnetic separator

Jan 1, 2020

This paper describes experimental investigations into the reductive decomposition of arsenopyrite/pyrite (FeAsS/FeS2), a gold and silver bearing iron/arsenic sulphide using metallic iron powder. The main objective was to establish and experimentally confirm the thermodynamic and kinetic feasibility of reductively decomposing the sulphide matrix for precious metals recovery. In this context, cyanidation leach tests were conducted on the reductive leach residues. The arsenopyrite/pyrite flotation concentrate, mainly studied in the hydrochloric acid medium, decomposed through the non?oxidative chemical dissolution reaction and the reductive decomposition reaction for the arsenopyrite and pyrite components, respectively. Desulphurization levels below 65% were achieved at pH values below 0.15 and iron to concentrate ratios above 1, and the system was characterized by overall very slow kinetics. The reaction system had a direct linear relationship with iron to concentrate ratio and an inverse relationship with pH. An analysis of the pyrite/iron galvanic system showed that pyrite forms a partially inert cathodic surface on which the anodic dissolution of iron occurs, supported by the hydrogen evolution reaction. This phenomenon explained the low desulphurization levels and the mineral decomposition seemed to be restricted to the non?oxidative chemical dissolution reaction for the arsenopyrite component. The cyanide leach of the reductive leach residues showed very little improvement in gold recovery. The reductive leach process for arsenopyrite/pyrite has considerable limitations in terms of both desulphurization and precious metals liberation. Keywords: Pyrite, arsenopyrite reductive leaching, hydrogen sulphide, invisible gold

Jan 1, 2009

By J. P. Coetzee

Dr. K. Gebhard In his excellent and comprehensive survey on the future development of the Iron and Steel Industry in South Africa, Mr. Coetzee has also mentioned the direct reduction processes as a possible method of converting iron ore to iron. Mr. Coetzee has made it quite clear that at this stage one should not consider these processes as a 'magic formula' which herald a 'break through'. I agree entirely with this point of view. Once upon a time I held the opposite view, but in the meantime I have revised my views. To do so, I had 40 years at my disposal. In 1930 I had the privilege of being connected with the first commercial sponge iron plant in Germany1 - a plant which was capable of producing 40 tons of sponge iron a day. We were determined to prove that the blast furnace would become obsolete in the near future. We considered it as an unnecessary detour to convert iron ore first into an iron-carbon alloy, which contained further quite a number of undesirable elements, and to remove this carbon by an endothermic process. Direct iron-making seemed to be a logical short cut. Unfortunately, we were not able to establish this 'short cut,', but the life of our sponge iron plant was cut short. We had solved all technical but not the economic problems. Basically the positon is still the same today - mainly economic and to a lesser degree technological aspects determine the rate at which sponge iron plants are installed. More has been said and written than done about direct reduction plants. I think that there are two main reasons for this stagnation in the introduction of direct reduction processes. The first reason is that modern blast furnaces are just too good and too economic ever to be replaced by direct reduction processes on a large scale. This, of course, already limits the field of application for direct reduction plants. The second reason is that sponge iron production and utilisation is based on technical considerations, which increase not only the production cost of sponge iron but also the conversion cost to steel to such an extent that under special conditions only are direct reduction plants an economic proposition. Are these technical considerations still as forceful and valid today as they were when 'direct steelmaking' was first contemplated? The development of sponge iron production as a method of direct

Jan 3, 1971

A set of six design principles for rock engineering was developed by Bieniawski: design objectives; minimum uncertainty; simplicity of design components; state-of-the-art practice; optimization; and constructability. These principles translate into a ten-step design process. Although this methodology was developed for rock engineering, it is applicable to any design process, feasibility study, etc. Diligent use of such a process will ensure that a defensible design or evaluation has been carried out. Recently a ?strategic conversation? process has been identified by Ilbury and Sunter that includes the following ten steps: scope; players; rules of the game; key uncertainties; scenarios; SWOT analysis; options; decisions; measurable outcomes; and meaning of winning. A comparison of these steps with those of the design process shows a remarkable correlation. This is perhaps not surprising since engineering design is a strategic up-front issue, and front end loading in a project is critical to achieve the expected project performance. Based on the close correlation between the strategic conversation and engineering design processes, a circular design process, rather than a linear process, is proposed. The ?circle of design? better reflects the importance of review and monitoring in the two phases of successful design and implementation?defining the design, and executing the design.

Jan 1, 2009

By S. Subramanian, L. Mweene

A siliceous low-grade copper ore from Mpanda Mineral Field (MMF), located in south west Tanzania consisting of SiO2 (58.3%), Fe (10.4 %) and Cu (0.9 %) was initially subjected to selective dispersion-flocculation using sodium trisilicate (STS) as a dispersant and xanthan gum (XG) as a flocculant. Subsequently, the selectively flocculated fraction was floated using a collector combination of potassium ethyl and amyl xanthate (1:1) in the presence of poly-ethylene oxide (PEO) as a silica depressant, to get a copper concentrate. The mineralogical investigations confirmed that the MMF ore was mainly composed of quartz, chalcopyrite and pyrite. Adsorption studies indicated that the adsorption density of XG on MMF ore decreased with an increase in pH, while that of PEO was independent of pH. The adsorption isotherms of XG and PEO on MMF ore exhibited Langmuirian behaviour. The zeta potential studies of MMF ore indicated that the iso-electric point (IEP) was located at pH 2.6, presumably due to its high silica content. In the combined presence of XG and STS, the zeta potential of MMF ore became more negative, with an increase in the concentration of STS. However, in the presence of PEO, the zeta potential of MMF ore became less negative with an increase in the concentration of PEO beyond the IEP, without shifting the IEP. Selective dispersion-flocculation of MMF ore improved the flocculated chalcopyrite grade to 19.8 %, yielding a degree of flocculation and a maximum separation efficiency of 12.1 % and 85.7 % respectively, after three desliming stages in the presence of 30 ppm of STS and 30 ppm of XG. A copper concentrate of 29 % grade and 90 % recovery containing silica of 0.9 % grade and 1.7 % recovery was achieved by flotation of the selectively flocculated component, using PEO as a depressant for quartz. Keywords: Flotation kinetics, flotation machines, flotation bubbles, particle size

Jan 1, 2020