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By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluoridesl.2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02?SiO2) with the ammonium acid fluoride (NH4F?XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo-dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012

By T. Tamura

It is known that the CaO-FetO-P2O5slag system has a wide liquid miscibility gap at steelmaking temperatures and this two-liquid slag phase has many advantages such as high activities of both FetO and CaO and high amount of P2O5. The phosphorus distribution ratio between the two-liquid slag and molten steel was confirmed to be higher than that between CaOsat.-FetO-P2O5slag and molten steel. The two-liquid slag may be useful for dephosphorization of molten steel and reduction of slag volume. Furthermore, the phase equilibrium of two-liquid CaO-FetO-P2O5slagsaturated with MgO was measured to determine the applicability of the two-liquid slag to dephosphorization in steelmaking process. Keywords: slag, refractories, solid solution, two-liquid phase, dephosphorization, steelmaking, phase equilibrium.

Jan 1, 2004

By B. W. Wallace

Permitted explosives in South Africa are those explosives approved by the relevant State authority for use in fiery coal mines. The main tests that an explosive must pass for this approval are the gallery tests derived from the Buxton (U.K.) classification. These tests are described briefly. In addition, the safety of permitted explosives is affected by their ability to deflagrate, and to produce a naked flame after blasting, rather than to detonate fully. Tests done on this phenomenon are discussed. A further potential hazard of explosives is after-blast fume. The testing and behaviour of several permitted explosives in this respect are covered, both in the laboratory and in the field. Performance testing of permitted explosives, specifically the double-pipe, underwater, and ballistic mortar tests, and their relationship to field use, are considered in some detail. The application of traditional and new tests to permitted explosives leads to guidelines for the safe and efficient formulation and use of these products.

Jan 1, 1986

By B. K. Loveday

A model for the leaching of non-porous particles by B. K. LOVEDAY*, Ph.D. (Fellow) A model has been developed for the prediction of the rate of leaching for an assemblage of non-porous particles in terms of size-distribution parameters. Expressions are developed for batch and continuous operation, and an example of the application of the model is given.

Jan 9, 1975

By P. M. Scott

The South African Institute of Mining and Metallurgy held a colloquium on 'The Selection of Equipment for Underground Mining' in Johannesburg on 22nd September, 1982, which, judged by the interest shown, was an unqualified success. Mintek 50 As announced earlier, the Council for Mineral Technology (Mintek) will be celebrating fifty years of growth in 1984 and is organizing an international conference, MINTEK 50, on its areas of special expertise. Drilling Once again the South African Drilling Association will be holding a technical symposium in 1983. ILAFA Congresses The Instituto Latinoamericano del Fierro y el Acero (ILAFA) has scheduled the following congresses for 1983:

Jan 1, 1983

By H. Ruthert

An understanding of wear in systems conveying solids is extremely important from the standpoints of design and economics. The lifetime of any bulk solids-handling system depends on the type of solids present and the operating parameters of the transportation system. The relationship between wear in backfill pipelines on South African gold mines and the transportation system's operating parameters is well understood. However, the effect of the transported solids on the pipe wear is less well understood, because of an inability to characterize particle sharpness. The sharpness of the particles, together with their size and hardness, is responsible for the aggressivity of particles, or their ability to cause damage and wear. This paper presents a novel method for the characterization of particle sharpness. The results presented rank particles according to the sharpness of their surfaces.

Jan 1, 1993

By I. M. Wolf, S. A. Usmar, L. A. Cornish

The limiting criterion in the use of stainless steel for certain forming operations such as coining is its hardness, which determines parameters such as required striking pressure, wear on dies, and integrity of pattern detail. Attention is given here to the development of ultra-soft ferritic stainless steels for coinage. In the first instance, the influence of carbon content on the striking properties of a series of commercial and experimental 17%Cr alloys was evaluated. It was found that a lower carbon content permitted the striking of relatively highly profiled and intricate patterns, provided that the hardness did not exceed 125 HV. Hardnesses as low as 115 HV were achieved in the fully annealed condition, but these alloys required high striking pressures. In a further study, three grades of experimental 14%Cr ferritic stainless steels were produced with a view to optimizing the ductility. When the residual impurities were minimized, hardness values of about 100 HV and lower were achieved. Micro-alloying additions allowed the heat-treatment response and grain size to be controlled. Excellent tensile properties, with elongations of up to 42 per cent, were achieved in the fuly annealed condition, and highly profiled patterns were produced in coining trials.

Jan 1, 1993

By S. Asokan, CVGK Murty, R. Upadhyay

The principal mineral sources of titanium are rutile, anatase (both TiO2), ilmenite (FeTiO3) and leucoxene (a weathered ilmenite of variable concentration of TiO2 but similar to pseudorutile Fe2Ti3O9). These titaniferous minerals along with their value added products like Synthetic Rutile and TiO2 slag constitute ?Titanium Feed-stocks? for TiO2 pigment, Ti metal and welding electrodes industries. Unlike in other industries, the demand driver for titanium minerals is not the metal, but the TiO2 pigment ?a specialty chemical. Of the total titanium feedstocks usage in the world, about 93 % is consumed in TiO2pigment, with only about 3 % is utilized in metal production. India?s heavy mineral sands resources are among the largest and also one of the richest grades in the world. The country?s Ilmenite resource base stands at 348 million tonnes of Ilmenite (18% of the total world reserves)along with 18 million tonnes of Rutile, 21 million tonnes of Zircon, 8 million tonnes of Monazite, 107 million tonnes of Garnet and 107 million tonnes of Sillimanite. Though the grades (Total Heavy Minerals (THM) present in the sand) of Indian deposits are relatively rich, the contained ilmenite are termed as sulphate grade with 50-53% TiO2 (Chavra deposit of Kerala and Ratangiri deposit of Maharastra are an exception with 60% of TiO2). While superior grades with adequate reserves lead to a cost advantage in ilmenite production, the lower TiO2 percentage allows the direct use of Indian ilmenite only in the production of TiO2 pigment through sulphate route and for the chloride pigment production; such ilmenite is required to be upgraded either to Synthetic Rutile (SR) or TiO2 slag. However, in order to produce TiO2 slag in India at a globally competitive cost, the issues like high power tariff, inadequate infrastructure, expensive logistics, less enthusiastic market preferences, supply-demand gaps are to be adequately addressed. This paper deals with some of the above issues and possible solutions thereto in production of TiO2 slag from Indian ilmenite.

Jan 1, 2007

By k. Lebecki, S. Trzcionka

The prototype and test results of the instrument for quick determination of incombustible content in deposited dust as a protection against coal dust explosion propagation are presented. Presently existing methods do not permit to obtain quick information about incombustible content, needed for the proper protection of workings. As the operating principle for the e instrument the dependence of reflection of infrared radiation intensity on incombustible content in the sample is chosen. The construction is based on the modern electronics. The measurement will be done at the sampling site. The range of the instrument is 0-100% of incombustible, direct reading, autonomous supply, weight no more than 0.5 kg, and is intrinsically safe according to EN Standards. During the Conference the instrument will be commercialized.

Jan 1, 2003

By J. H. Lazarus

The evolution of backfill-distribution systems for deep gold mines is examined. The status of current technology for the design of backfill-distribution systems is considered with reference to pipeline pressure gradients, pipeline wear rates, and slurry flow regimes. The effect of an increase in the relative density of the slurry on the performance of backfill-distribution systems is illustrated. Future trends regarding the design of backfill-distribution systems are discussed.

Jan 1, 1993

By J. D. Wells

An account is given of the planning required for the rehabilitation of land that is to be disturbed by opencast mining, and of the preparation of rehabilitation of land that is to the Inspector of Mines. The plans Include the provisions that are to be made to allow for climatic conditions, land use, vegetation and wildlife, surface-water resources, geology and ground water, soils, land capability, rehabilitation method, location of discard dumps and slurry ponds, pollution control, and costs. . . Monitoring of the operation is the only way that the rehabilitation plan can be improved, and both monitoring and planning are essential when provision is being made for the closure of a mine.

Jan 1, 1986

Four engineering products and three consumer products have received awards in the 1978 Shell Design Awards competition organized by the Design Institute of the South African Bureau of Standards. Norman Hanson Visiting Fellowship The Norman Hanson Visiting Fellowship, supported jointly by the National Development Fund for the Building Industry (inaugurated by the Building Industries Federation (8.A.)), the Institute of S.A. Architects, the Association of S.A. Quantity Surveyors, and the National Building Research Institute of the CSIR exists to finance fully or wholly visits by eminent authorities from overseas to South Africa for the purposes of seminars, informed discussions, consultation, and possible active participation in scientific, technological, and development projects of importance to the building industry.

Jan 1, 1979

By L Singheiser, W. Willenborg, M. Mueller, K. Hilpert

The limitation of fossil fuel resources and the necessity of reducing CO2emission require an increase of the efficiency of power plants by using combined cycle power systems. Pressurized Pulverized Coal Combustion (PPCC) is a potential concept to realise these objectives. The direct use of hot flue gas for driving a gas turbine requires a hot gas cleanup to achieve corrosion prevention of the turbine blading. One of the main problems is the alkali release during the coal combustion process. Molten coal ash slag has a high potential for alkali retention which depend son the alkali oxide activity in the slag. Knudsen Effusion Mass Spectrometry (KEMS) was used to determine thermodynamic data of alkali gas species over molten coal ash slags and of alkali oxides in molten coal ash slags. The main interest of the investigations focused on the structural dependence of the thermodynamic properties of the alkalis. It was found that there is a strong correlation between the thermodynamic properties and the ratio of nonbridging oxygen to tetrahedral oxygen (NBO/T). An increase of the polymerization of the slag results in a decrease of the alkali oxide activity in the slag and thus a decrease of the alkali partial pressure over the slag. Keywords: coal ash slag, structure, alkali oxide activity, alkali vapour pressure, PPCC, KEMS.

Jan 1, 2004

[Council for 1993/94 President Dr H. Scott-Russell President Elect J. A. Cruise Vice Presidents Senior D. A. J. Ross-Watt Junior P. D. K. Robinson]

Jan 1, 1994

Council for 1998/99 President R.P. Mohring President Elect J.R. Dixon Vice Presidents Senior junior M.H. Rogers Dr L.A. Cramer Immediate Past President Honorary Treasurer Dr N.A. Barcza J.A. Cruise

Jan 1, 1985

COUNCIL FOR 1989/90 President Dr O.K.H. Steffen President-elect Mr H.G. Mosenthal Senior R.D. Beck Vice Presidents Junior ].P. Hoffman Immediate Past President C.E. Fivaz Honorary Treasurer Dr H. Wagner

Jan 1, 1990

COUNCIL FOR 1987/88 President B.C. Alberts President-elect C.E. Fivaz Vice Presidents Senior Junior Dr O.K.H. Steffen H.G. Mosenthal Immediate Past President Dr H. Wagner Honorary Treasurer Dr H. Wagner

Jan 1, 1988

COUNCIL FOR 1988/89 President C.E. Fivaz President-elect Dr O.K.H. Steffen Senior H.G. Mosenthal Vice Presidents Junior R.D. Beck Immediate Past President B.C. Alberts Honorary Treasurer Dr H. Wagner

Jan 1, 1989

COUNCIL FOR 1990/91 President H.G. Mosenthal President Elect RD. Beck Senior J.P. Hoffman Vice Presidents Junior Or H. Scott-Russell Immediate Past President Or O.K.H. Steffen Honorary Treasurer OrH. Wagner

Jan 1, 1991

Council for 1995/96 President D.A. J. Ross-Watt President Elect Dr N.A. Barcza Vice Presidents Senior R.P. Mohring Immediate Past President J.A. Cruise Junior J.R. Dixon Honorary Treasurer J.A. Cruise

Jan 1, 1996