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By C. D. Winkler

Vanadium-based sulphuric acid catalyst has been utilized to oxidize SO2 to SO3 since the early 1900s. This versatile product displaced the expensive and easily poisoned platinum-based catalyst in nearly all applications by the 1930s. MECS has been manufacturing the vanadium-based catalyst since 1925 and today is the leading supplier in the world of sulphuric acid catalysts in a variety of forms. Currently, MECS has worldwide customer/technical support for the catalyst as well as a dedicated catalyst manufacturing plant in Martinez, California. MECS also has a strong technical and research and development programme dedicated to creating new and improved products and services. This paper will describe some of the technical details of vanadium-based sulphuric acid catalysts as well as offering a unique look into how caesium-promoted MECS catalysts can be used in single and double absorption acid plants, and off-gas plants running on irregular gas feeds, to reduce emissions and preheater run times. An update on MECS technical services extended for use in characterizing converter performance is also presented.

Jan 1, 2009

By R. T. Jones

The 20 Mt reverberatory furnace slag dump at Nkana in Zambia contains a substantial quantity of cobalt. A 40 MW DC arc furnace has been built at Chambishi for the purpose of recovering cobalt from the slag. The technology was jointly developed by Mintek and Anglovaal Mining Ltd (Avmin), and the furnace was designed by Bateman Titaco. Testwork at the 150?250 kW scale was conducted at AVRL, and larger scale piloting was conducted at Mintek (in partnership with Avmin) in a 3 MW DC arc furnace. Approximately 840 tons of Nkana dump slag (ranging from 0.66% Co) was processed at power levels around 1-2 MW. Good overall cobalt extraction was achieved, and approximately 100 tons of cobalt-bearing alloy was produced (containing 5 to 14% Co). This testwork demonstrated that the Nkana dump slag could be processed in a DC arc furnace of suitable design, to produce a cobalt-bearing alloy suitable for further hydrometallurgical processing. Bateman Titaco were contracted to design and build the furnace, and the design team contained representatives from Avmin and Mintek. The project was conceived as a fast-track exercise, and many activities had to be run in parallel. Notable features of the furnace include an ABB power supply, a Concast conductive hearth, the refractory design, and copper cooling in the sidewalls. Power to the furnace was switched on during January 2001.

Jan 1, 2002

By N. Watson

Historically the insurance industry's involvement in any project has been relatively late in the process. Often it was a case of the last item to be ticked off the checklist has been to ensure that the insurance is in place. However, in more recent times insurers have imposed more restrictions on the cover they are prepared to provide, which has in some cases necessitated a change in the contracting structure to accommodate the insurance policy(ies). In addition, changing contractual practices have changed the allocation of risk between the various parties involved. This calls for a more proactive approach to the design and implementation of an insurance program for both the construction and operational phases of any resource project. This paper explores how a risk managed approach to the design and implementation of an insurance program for a resource project can align itself with current management approaches to project development. From the authors' experience, this approach is best adopted early on in the project (often in conjunction with the bankable feasibility study) and follows AZ/NZS4360 to objectively examine and compare a wide range of risk exposures of the project in a time-effective manner across the following areas: ? personnel; ? environment; ? general management; ? compliance - legislation, systems, protocols; ? asset management; ? change management; ? financial impacts to the organisation; ? products/services; ? service delivery; and ? technology. Having identified and then analysed the risk exposures according to common consequence and likelihood ratings the next step is to develop a risk map of all considered exposures. The true value of this approach lies in the development and implementation of a risk treatment plan for identified exposures where the exposure is unacceptable. The plans will lead to the optimal solution to the appropriate risk prevention, risk mitigation and risk transfer options available. This paper also examines other benefits to the project that may arise from adopting a risk managed approach in addition to the ability to design an insurance program which recognises the exposures and the ability of the organisation (and other project parties) to retain risk.

Jan 1, 2007

By A. Koning

Pressure hydrometallurgy operations require vessels to be lined with an impermeable membrane for corrosion protection and one or more courses of refractory or ceramic brick. Examples of unit operations that utilize composite lining systems include pressure oxidation autoclaves, sulphide precipitation autoclaves, chloride leach reactors, flash vessels, cyclone separators, and direct contact condensers (heater vessels and quench vessels). The refractory lining must satisfy multiple requirements: it must thermally insulate the membrane from process fluid, be structurally stable, provide erosion resistance, be chemically compatible with process fluid, and provide an economic service life. New hydrometallurgical processes are pushing the pressure, and temperature with each new generation of plants. A fundamental understanding of all factors affecting the mechanical stability of the lining system is essential as lining designs move further away from the industry?s experience base. The method of designing a refractory lined vessel is examined taking into account the impact of irreversible chemical swell, operating factors, design factors, and installation factors. The effect of geometry and incorporating additional degrees of freedom to the analysis is explored using two-dimensional and three-dimensional finite element analysis (FEA). The effect of these additional degrees of freedom on the results of the one-dimensional model are discussed. Keywords refractory lining design,autoclave, finite element analysis.

Aug 1, 2013

By T. Tamura

It is known that the CaO-FetO-P2O5slag system has a wide liquid miscibility gap at steelmaking temperatures and this two-liquid slag phase has many advantages such as high activities of both FetO and CaO and high amount of P2O5. The phosphorus distribution ratio between the two-liquid slag and molten steel was confirmed to be higher than that between CaOsat.-FetO-P2O5slag and molten steel. The two-liquid slag may be useful for dephosphorization of molten steel and reduction of slag volume. Furthermore, the phase equilibrium of two-liquid CaO-FetO-P2O5slagsaturated with MgO was measured to determine the applicability of the two-liquid slag to dephosphorization in steelmaking process. Keywords: slag, refractories, solid solution, two-liquid phase, dephosphorization, steelmaking, phase equilibrium.

Jan 1, 2004

By R. Haldenwang, R. Erasmus, P. T. Slatter, R. P. Chhabra

Notches are used routinely for measuring the flow rate of water with free surface flows. As far as can be ascertained, no work has been done to investigate the performance of these flow rate measurement devices for non-Newtonian suspensions. The Flow Process Research Centre at the Cape Peninsula University of Technology has investigated the flow rate of kaolin and bentonite suspensions from a tank for two notch shapes, namely rectangular and triangular, and for 3 different concentrations of each suspension. The notches were calibrated using water and then the kaolin and bentonite suspensions were tested in them. The rheological characterisation of the fluids was done with a Paar Physica MC-1 rotary viscometer fitted with a cup and roughened bob. Analysis of the results shows a significant increase in discharge coefficient with increase in concentration, and the discharge coefficient has been correlated to the yield stress. This is the first such study, and further investigation is needed to confirm and extend these findings.

Jan 1, 2007

By S. Kahraman

The correlations between the modulus ratio and penetration rate of rotary and percussive drills were statistically investigated using the raw data obtained from the experimental works of different researchers. An inverse power law was found between the modulus ratio and the penetration rate of rotary and diamond drills. The penetration rate of rotary drills and diamond drills decrease with an increasing modulus ratio. The penetration rates of percussive drills increase with an increasing modulus ratio. There are significant linear correlations between the penetration rates of percussive drills and the modulus ratio. In one of the cases of percussive drilling, a strong correlation between the penetration rate and the modulus ratio was found for the rocks having a porosity value lower 1.23 %. It can be concluded that the modulus ratio might be a representative measure of rock drilling efficiency. However, further study is necessary to check the validity of the derived equations for other rock types. The effect of porosity on the correlations between the modulus ratio and penetration rate needs to be further investigated.

Jan 1, 2003

By J. A. C. Diering

All underground openings are three-dimensional, and in many cases it is not valid to analyse two-dimensional sections. This has been a problem in the past owing to the magnitude and complexity of three-dimensional stress analysis. In this paper a three-dimensional boundary element approach, using non-conforming quadratic elements, which is specifically applicable to underground excavations, is described. In addition, the philosophy of application of stress analyses is discussed. Three case histories are presented to demonstrate the practical nature of the approach as a tool in solving mining problems.

Jan 1, 1987

By S. Badr, R. Mendoza, M. U. Ozbay, M. D. G. Salamon

ABSTRACT: The use of coal pillars at depth is fraught with problems due roof control difficulties and the possible occurrence of coal or pillar bumps. In the USA the largest and most important application of pillars at depth is in longwalling, where chain pillars are the customary supports of the multiple entry developments. At first, the chain pillars were designed using conventional approaches, where the principle is that the strength of the pillar should exceed the load imposed on it. Such approach to design led to larger and larger pillars at great depths, but instead of eliminating, it tended to aggravate the roof control problems. Eventually the idea was born that small sized yielding pillars, which have proved to be successful elsewhere, might provide the answer to this pressing problem as well. The aim of this paper is to study the modes of pillar failure at great depths, using two solution methods. The first of these comprises some elementary solutions obtained with the aid of a simplified conceptualization of the rock mass. This model consists of a strain-softening coal seam sandwiched between two stratified masses. The second approach utilizes FLAC3D, which is a commercially available three-dimensional numerical modeling software package. To gain a better insight, both the strain-softening and ideally plastic Mohr-Coulomb constitutive laws embodied in FLAC3D were exploited. As expected, the width to height ratio of the pillar has proved to be the primary factor that determined the behavior of the pillars. Narrow pillars fail in a stable manner without the occurrence of instabilities. Intermediate w/h ratio pillars under the appropriate loading conditions, may fail suddenly and may even collapse totally. Squat pillars do show the potential for sudden, coal bump like side failure, but because the remaining large width of the inner core, the ruble around the pillar provides sufficient confinement so as to reestablish stability. Finally, the study revealed that the traditional Mohr-Coulomb law does not provide a useful insight into the failure of coal pillars. RESUME: L’utilisation des piliers de charbon dans les mines souterraines de grande profondeur occasionne des problèmes due aux difficultés de control de plafond et possibles fracture ou explosions au niveau des piliers. Aux Etats-Unies d’Amérique, l’utilisation des piliers dans les mines souterraines de charbon comme moyen de support est considèrees comme étant la plus grande et la plus importantes des méthodes utilisée dans le ‘’ longwalling method’’ ou une série des piliers sont disposé de manière à supporter les multiple entrées d’exploitation de charbon. En premier lieu, cette série des piliers étaient construit de manière conventionnelle avec un principe basé sur le fait que le poids exerce sur les piliers doit être inférieur a la force que ces piliers exerce sur le plafond. Ce principe a conduit a ce que le volume des piliers augmente au fur et à mesure que la profondeur au de la mine augmente. Malheureusement, au lieu de résoudre le problème de support, ce principe n’a fait qu’aggraver le problème de contrôle de plafond. Eventuellement une idée s’est dégagé allant du fait que les piliers endommagés de taille moyenne qui se sont avérés être efficaces ailleurs, pourraient fournir un indice à ce particulier problème. Le but de cette recherche est celui d’étudier les différent types de ruptures qu’un pilier peut occasionner lorsqu’il est utilisé a grande profondeur, tout en utilisant deux possible méthodes. La première d’entre elle comprend quelques solutions élémentaires obtenues avec l’aide d’une méthode simplifié et conceptuelle de la masse de la roche. Ce modèle consiste à prendre en sandwich la bande de minerais de charbon entre deux masses stratigraphiques sans pour autant endommager le plafond. La seconde méthode nécessite l’utilisation du ‘’ FLAC3D’’, qui est un logiciel commercialisé disposant d’un modèle numérique en 3 dimensions. Dans le but d’obtenir

Jan 1, 2003

By J. P. Bergh

The advent of low-quality export coal demand has brought a new range of possibilities to the South African coal industry. Products that traditionally were only of value to the domestic or combustion industry sectors now have the potential to be exported, with only minor amounts of upgrading required through beneficiation. Comparatively high steam-coal export prices can be obtained for lowquality export coal, which enhances the economic feasibility of expanding low-quality thermal coal exports. There are, however, increasing concerns about the feasibility of lower quality thermal coal exports and the broader implications. These concerns relate to the environmental impact of low-quality thermal coal production for export and the inherent threat to the security of domestic thermal coal supply in South Africa. Against this background, this paper serves to explain the extended value chain in the production of export coal. The technical and economic advantages and disadvantages of low-grade exports versus coal production for domestic use are evaluated. The value chain estimation is calculated by the beneficiation modelling and characterization of two coals. Based on the value estimation, the lowgrade export production scenario, and finally the modelling of potential pollutant distribution, are described. Keywords coal beneficiation, techno-economics, thermal coal, dense medium processing, dry processing, fine coal processing, environmental impact.

Nov 1, 2013

By N. T. Beukes

An engineering house?s perspective of required inputs in designing a copper electrowinning tank house and ancillary equipment calls for both understanding of the key fundamental controlling mechanisms and the practical requirements to optimize cost, schedule and product quality. For direct or post solvent extraction copper electrowinning design, key theoretical considerations include current density and efficiency, electrolyte ion concentrations, cell voltages and electrode over potentials, physical cell dimensions, cell flow rates and electrode face velocities, and electrolyte temperature. Practical considerations for optimal project goals are location of plant, layout of tank house and ancillary equipment, elevations, type of cell furniture, required cathode quality, number and type of cells, material of construction of cells, structure and interconnecting equipment, production cycles, anode and cathode material of construction and dimensions, cathode stripping philosophy, plating aids, acid mist management, piping layouts, standard electrical equipment sizes, electrolyte filtration, impurity concentrations, bus bar and rectifier/transformer design, electrical isolation protection, crane management, sampling and quality control management, staffing skills and client expectations. All of the above are required to produce an engineered product that can be designed easily, constructed quickly and operated with flexibility.

Jan 1, 2009

By E. A. Brinkmann

A kinetic model framework for single particle kinetics in combined diffusion and adsorption processes is presented. The framework applies to the general case in which both diffusion and the adsorption reaction play important roles in determining the overall rate in processes where the migrating species can both adsorb and accumulate. The technique, which should be applicable to a wide range of reaction mechanisms, consists of an iterative integration procedure for the coupled diffusion and reaction equations. The case of a reversible linear adsorption reaction rate is developed. In order to verify the technique as a legitimate method of model development, an analytical solution for the identical case is derived and compared to the numerical solution. Excellent agreement exists between the two solutions.

Jan 1, 1987

By M. M. Manamela

Paper written on project work carried out at the University of Pretoria in partial fulfilment of the requirements of the B Tech degree at the Tshwane University of Technology This work tested whether ore particle size affects the carbon-based pre-reduction of titaniferous magnetite. Pre-reduction is performed at a temperature of some 1100°C in a rotary kiln, in the Highveld Steel process. Laboratory isothermal reduction measurements were performed with ore-coal mixtures at this temperature, to test the effect of ore particle size. The results show that size does limit the degree of reduction for particles larger than 15 mm.

Jan 1, 2005

By L Singheiser, W. Willenborg, M. Mueller, K. Hilpert

The limitation of fossil fuel resources and the necessity of reducing CO2emission require an increase of the efficiency of power plants by using combined cycle power systems. Pressurized Pulverized Coal Combustion (PPCC) is a potential concept to realise these objectives. The direct use of hot flue gas for driving a gas turbine requires a hot gas cleanup to achieve corrosion prevention of the turbine blading. One of the main problems is the alkali release during the coal combustion process. Molten coal ash slag has a high potential for alkali retention which depend son the alkali oxide activity in the slag. Knudsen Effusion Mass Spectrometry (KEMS) was used to determine thermodynamic data of alkali gas species over molten coal ash slags and of alkali oxides in molten coal ash slags. The main interest of the investigations focused on the structural dependence of the thermodynamic properties of the alkalis. It was found that there is a strong correlation between the thermodynamic properties and the ratio of nonbridging oxygen to tetrahedral oxygen (NBO/T). An increase of the polymerization of the slag results in a decrease of the alkali oxide activity in the slag and thus a decrease of the alkali partial pressure over the slag. Keywords: coal ash slag, structure, alkali oxide activity, alkali vapour pressure, PPCC, KEMS.

Jan 1, 2004

A number of issues relating to the computational aspects of pillar design are addressed in this paper. The computation of average pillar stress values is important when attempting to establish criteria for pillar design and in the analysis of the stability of tabular pillar layouts. One of the default ?classic? numerical methods that are used to determine pillar stresses is the displacement discontinuity method. In many instances it is not clearly understood that this approach does suffer from some limitations, particularly in relation to the fact that in coarse element simulations, the simulated average pillar stress (APS) can depend on the chosen mesh size. The nature of this error is highlighted in this paper and some strategies are suggested to bound the magnitude of these errors. It is demonstrated as well that the popular linear stiffness approximation to pillar or seam compressibility does appear to allow reasonably accurate estimates of the average pillar stress when either the pillar height is varied or when the seam modulus differs from the host rock modulus. A practical implication of this study is that if the seam modulus is noticeably lower than that of the host rock, such as for coal seams, it is important to use a linear stiffness constitutive model for the pillars rather than a ?rigid? pillar assumption. This added complexity seems unnecessary, however, when simulating hard rock pillars in mines where the seam modulus is very similar to that of the surrounding rock.

Jan 1, 2011

By K. H. Zhang, Y. P. Gao, J. Q. Zhao, Q. Li, J. C. Ma

Compared with sinusoidal oscillation, non-sinusoidal oscillation enhances the ability to control waveform and meets different oscillation requirements by adding an independent parameter, which is the key technology for high-efficiency continuous casting. A new waveform of mould non-sinusoidal oscillation is proposed in this paper, that is, a velocity waveform that is composed only of straight lines and parabolas, which not only has good dynamic characteristics, but also further enhances the feature of non-sinusoidal oscillation. Compared with sinusoidal oscillation, the negative strip time is reduced by 15.9%, the maximum negative strip velocity difference is increased by 38.3%, and the maximum positive strip velocity difference is decreased by 27.8%. The formulas of oscillation process parameters can be clearly deduced, and the isoplethic curves of oscillation process parameters when multi-parameter simultaneously changes are drawn. The negative strip time decreases as the modification ratio, frequency, and casting speed increase, but increases as stroke increases. In order to maintain the stability of negative strip time, an oscillation synchronous control model for optimising oscillation basic parameters was developed. Through practical application, the mean oscillation mark depths decreased by 10.1 μm and the flux consumption is increased from 0.37 kg/t to 0.45 kg/t in the non-sinusoidal oscillation model, which meets the requirements of normal production.

Oct 24, 2025

By K. Y. Lee, J. M. Park, C. W. Park

Laboratory-scale experiments were carried out to investigate the effect of ladle slag composition on the decreasing behaviour of aluminum content in steel, i.e., reoxidation of molten steel in contact with slag, using a vertical tube furnace. The steel composition and the slag system chosen were for ultra low carbon and CaO-Al2O3-FeO-MnO-MgO based to simulate ULC steel grades. It has been observed that the reoxidation rate shows a good relationship with (T. Fe) content in slag. In case of (T. Fe) content higher than 1.5 weight per cent, the reoxidation rate increases linearly with increasing (T. Fe) content. For a given (T. Fe) content, it decreases with the increasing (CaO)/(Al2O3) ratio of the slag. However, in the case of (T. Fe) content lower than 1.5 weight percent, no particular relationships are observed between the reoxidation rate and (T. Fe) content or the (CaO)/(Al2O3) ratio of the slag. These results were used to propose for an aim a slag composition for the ULC steel grades in a steelmaking plant. Keywords: slag deoxidation, slag killing, slag composition control, IF steel, ULC steel grade

Jan 1, 2004

By L. A. Vermeulen, D. D. Howat

A study was made of the performance of a rod mil operating without liter bars and with different arrangements of liter bars in the lining. . The results show that striking improvements in performance, increased throughput, and reduced consumption of liner metal and electrical energy can be obtained by a change in the geometry of the liter-bar arrangements within a mil. Rod mils of equal size fitted with the same arrangement of liter bars but operating at different speeds presented apparent anomalies in the relative consumption efficiency of electrical energy for the production of material smaller than 75 µ m. Marked savings in the consumption of liner metal were achieved by the use of an arrangement of alternating lines of higher and lower liter bars. A study of the relative performances of two large tube mils showed that the use of liter bars in one of the mils resulted in a marked reduction in the consumption of liner metal and electrical energy per ton of material smaller than 75 µ m in the product.

Jan 1, 1986

By A. García-Gutiérrez, A. Aragón-Jerónimo, R. Salazar-Mendoza

A theoretical analysis of a two-region solid-liquid flow system in horizontal pipes is presented, which considers a stationary bed of drill cuttings as a porous medium (-region) below of a two-phase dispersed flow (-region).The method of volume averaging was applied in this study to derive a rigorous mathematical model in which each variable is precisely defined. This model includes the volume-averaged transport equations for both the two-phase dispersed flow and the porous medium regions and terms from a macroscopic forces balance. The solution of the two-region model allowed evaluation of the behaviour of pressure gradient as a function of velocity, total volume fraction of cuttings and the relationship of the height of the stationary bed and pipe diameter. The solution is based on a backward finite difference explicit scheme. The simulated physical system is a pipe of 4.135 m in horizontal length and 0.0508 m in diameter. A one-dimensional, mesh-centred grid, consisting of 100 nodes, is used. The numerical results were compared with experimental data on slurry flows and a good agreement was found. Keywords: two-phase, cuttings transport, solid-liquid flow, drilling modelling, volume averaging.

Jan 1, 2007

By D. W. Dew

Billiton Process Research has carried out extensive research over the past four years to develop new process technology using bioleaching for extraction of copper and nickel from their sulphide concentrates. Continuous pilot scale and laboratory batch testwork has been carried out with adapted mesophile bacterial cultures at40°C?45°C, moderate thermophile cultures at 50°C?55°C and thermophile cultures at 65°C?85°C. Pilot scale work has demonstrated the commercial viability of mesophile cultures for bioleaching of secondary copper sulphide and nickel sulphide concentrates. Moderate thermophiles offer benefits in terms of reduced cooling requirements for commercial reactors and, in the case of bioleaching of nickel concentrates, some selectivity over bioleaching of pyrite. Continuous pilot scale testwork has shown that thermophiles achieve efficient bioleaching of primary copper sulphide and nickel sulphide concentrates, giving much higher recoveries than achieved by bioleaching with a mesophile or moderate thermophile culture.

Jan 1, 2000