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By J. P. Beukes

The production of ferrochrome alloy from chromium bearing chromite ores is conducted at high temperature under highly reducing conditions. However, albeit completely unintended, it is impossible to completely exclude oxygen from all high temperature process steps, with the corresponding possibility arising for the generation of small amounts of Cr(VI) species. Certain Cr(VI) species are regarded as a carcinogenic, with specifically airborne exposure to these Cr(VI) species being associated with cancer of the respiratory system. With approximately three-quarters of the world?s viable chromite ore reserves located in South Africa, and annual ferrochrome production approaching almost half of total annual global output, aspects of Cr(VI) generation and control are of particular relevance and importance to the local industry, and naturally to the global industry at large. This paper seeks to examine theoretical and practical aspects associated with Cr(VI)generation (based largely on experience within the local South African industry, but considered to be generally encountered in the broader global industry context), together with mitigating measures that can be applied within the context of the production processes. From the discussions it is clear that significant improvements in various Cr(VI)-related aspects have been made by the South African ferrochrome industry. However, it is also evident that several areas of uncertainty still exist, which require further research in order to better quantify risks and enhance the efficacy of mitigating steps. Keywords Hexavalent chromium, Cr(VI), ferrochrome production, South Africa.

Jan 1, 2010

By N. X. Feng, S. G. Zhou, X. L. Wu, J. P. Peng, Y. Z. Di

"Szaibelyite–suanite type ore is rich in magnesium oxide and boron oxide. We propose a new method to extract both metallic magnesium and valuable residues rich in boron by reduction using metallic aluminium.Thermodynamic analysis of the reactions between aluminum and MgO, Mg2B2O5, and Mg3B2O6 was carried out. The effects of CaF2 addition, temperature, mass of Al, and pellet formation pressure on the extraction of magnesium were also investigated experimentally.The results indicate that the magnesium oxide phase can be displaced from 2MgO-B2O3 and 3MgO·B2O3 by CaO in the reduction system. The reduction ratio of magnesium oxide was 38% without calcium fluoride addition, increasing to 94% with 5.1% calcium fluoride. The reduction ratio increased with increasing temperature and mass of Al. To obtain a higher reduction ratio, the reduction pellet should be formed under a reasonable pressure.IntroductionBoron and its compounds are widely used in textiles, borosilicate glass, metallurgy, fertilizers, and nuclear shielding. Boron resources are mainly found in Turkey, the USA, Russia, and China. In Liaoning, China, there are abundant szaibelyite–suanite type ores that are rich in magnesium oxide and boron oxide. Szaibelyite and suanite ores are used to produce borax by a carbon dioxide– soda process. Annually, 2 Mt of waste materials containing 3–20% B2O3 and 2–25% MgO are produced during the process. It is necessary to make use of these waste materials containing high concentrations of boron oxide and magnesium oxide to avoid environmental problems as well as for economic reasons (Ozdemir and K1pcak, 2007)"

Jan 1, 2016

By S. R. Xie, S. Gong, E. P. Li, S. S. He, Y. J. Sun, S. J. Li

"Based on the complicated geological production conditions and abnormal strata behavior of the fully mechanized caving face No. 102 in the Xinyang Coal Mine, we analyze the breaking and forming process of distinguishing key block structures in close spaced coal seams. This analysis establishes an integrated mechanical model of these distinguishing structures. Furthermore, the horizontal force TAB generated by downward key blocks A and B is quantified, as is the Pressure PG exerted by key block B on caved gangue. Finally, the interaction mechanism is revealed. Analysis of the results using Mathematica reveal the following: 1. Both TAB and PG exhibit approximately inverse relationships to coal pillar width b; 2. TAB exhibits an approximately exponential relationship with mining height M of which the base is greater than 1; 3. PG exhibits an approximately arctangent relationship with mining height M. Combining these results with field observations, we conclude that the area in the vicinity of supports 100#–120# in the upper area of working face No. 102 is the likely zone of abnormal strata behavior. Thus, this area was classified as a key control area. Based on these results, the graded support control technique is proposed. Application of this technique in the field resulted in a reduction in the rate of hydraulic support system malfunction from 47% to 7% in the key control area. In addition, during times of periodic mining pressure, the roof caving height value never exceeded 0.3 m and the maximum spalling depth never exceeded 0.2 m. Overall, the results indicate that this new technique has markedly increased the stability of surrounding support rock material. IntroductionClose-spaced coal seams are widely distributed in China, and mining proceeds from the uppermost to the lowermost seam (Zhang et al., 2008). In the case of coal seams in close proximity, a particular set of risk factors becomes pertinent. These include disturbance of lower seams during the mining of overlying ones and the decrease in mechanical stability of lower coal seams following repeated movement of key blocks in main coal seam roofs. This inevitably results in behaviour such as heavy wall spalling and support damage to fully mechanized caving faces in lower-lying coal seams, which necessitates a significantly increase in the measures to support surrounding rock material (Zhang et al., 2010; Huang et al., 2013; Xie et al., 2013)."

Jan 1, 2016

A modified germanium recovery process in conventional zinc metallurgy, based on the understanding that ferric hydroxide has strong ability to coprecipitate germanium element, was presented. The relaxed lab-scale experiments were conducted to evaluate its technological feasibility. The experimental results obtained show the new process has great competitive advantage over the conventional one.

Jan 1, 2008

By T. M. Espach

This paper gives an account of the changes that have taken place since the previous paper on trackless mining equipment at Prieska Copper Mines (August 1973). Details are given of the modifications to the equipment. the maintenance of equipment and road ways. the training of operators. and the operating costs.

Jan 1, 1979

By A. B. Holland-Batt

The application of Reichert spirals and cone concentrators within the South African mineral industry is discussed, and the procedures used in the acquisition of design data are outlined. Computing techniques developed by Mineral Deposits Limited for the processing of test data for use in the design of production circuits are described.

Jan 1, 1982

By A. G. R. Coreejes, G. Ferreira

The paper sets out briefly the methods used for the planning and control of the construction work at Grootegeluk Coal Mine near EIIisras, Transvaal. It includes a discussion of the programming, the updating of programmes, and the progress reporting.

Jan 1, 1982

By J. P. McDonald, P. L. Mattison, J. M. W. Mackenzie

A variety of processing problems in the hydrometallurgical extraction of uranium in the U.S.A. are contrasted with those in South Africa. In U.S. plants, for example, problems are often encountered in the separation of vanadium, molybdenum, and uranium, and in the contamination of the circuit with organic acids. South African plants often experience problems with dissolved silica in the feed, clarification of feeds, and problems associated with synthetic polyelectrolytes. Individual situations are examined, along with the analytical techniques that assist in solving specific problems. Successful approaches that have been applied to mechanical and chemical problems in' uranium solvent-extraction plants are discussed.

Jan 1, 1981

By R. C. Urquhart, W. P. Channon, D. D. Howat

The mode of current transfer between electrode and slag in the submerged-arc furnace . by W. P. CHANNON, B.Sc.(Eng.)(Student Member), R. C. URQUHART, M.Sc.(Eng.), ;'h.D.(Visitor), and D. D. HOWAT, B.Sc., Ph.D.(Fellow) An account is given of a laboratory experiment in which the resistivity of a primary slag like those produced in the manufacture of high-carbon ferrochromium was measured at current densities typical of operation in a submergedarc furnace. It was shown that the current flow from graphite elec trode to molten slag obeys Ohm's Law when electrode current densities are less than 12 A/cm". At higher current densities, arcing occurs from the electrode tip to the slag, causing an imbalance in the rate of heating in the furnace burden.

Jan 8, 1974

By R. J. Mason

The paper discusses the claim that the remains of mines in Southern Africa date from ancient times, rather than from a more modern period. The evidence indicates that these mines were excavated by Iron Age Black people, who moved into South Africa from about A.D. 100 onwards. Details are given of the finds made in 1981 in an investigation of the remains of copper mines in the Dwarsberg, which probably date from the nineteenth century.

Jan 1, 1982

By R. J. Kriek, J. J. Cruywagen, W. J. Engelbrecht

Selective photo reduction, using the semiconductor TiO2 under UV irradiation, has been investigated as a possible recovery and/or separation method for the PGM's rhodium, palladium and platinum. The effect of pH value and concentration of the sacrificial reducing agent (ethanol) on the rate of reduction of Rh (III), Pd (II) and Pt(IV) ions have been determined separately for these ions as well as for some mixtures. Conditions favourable for the reduction and adsorption (or precipitation) on TiO2 have been established. It has been found that already deposited Pt or Pd metal promotes reduction of Rh (III) ions at a pH value where it would not otherwise be reduced. A method for the separation of a mixture comprising Rh (III), Pd(II) and Pt (IV), based on photo reduction and adsorption on the TiO2, is proposed.

Jan 1, 1995

By P. R. Labrum, H. A. D. Kirsten

The literature on shotcrete is reviewed with the object of identifying aspects that have not been addressed specifically in terms of its structural performance and manufacture as applied to underground mines. The programme and results of a series of full-scale tests on mesh- and fibre-reinforced shotcrete panels are presented, from which it is concluded that fibre-reinforced shotcrete is competent, especialy at large deformations, and is equivalent in structural performance to mesh-reinforced shotcrete for a fibre content of 3 per cent by mass: furthermore, that the support design systems developed for mesh-reinforced shotcrete are directly applicable to fibre-reinforced shotcrete. The Q-NATM system for the design of temporary tunnel support is presented briefly as one such system. It provides for the integrity of the excavation to be considered in terms of its competence and displacement determinateness, and represents the first systematic procedure for the design of temporary tunnel support. Finally, the support designed on the basis of the Q-NATM system for the main and cross-cut tunnels on the production level in the proposed BA5 block cave at Premier Mine is presented as a practical example of the design of fibre-reinforced shotcrete as part of an overall support system.

Jan 1, 1990

The Water Year Office for South Africa has supplied a provisional list of scientific congresses and meetings due to be held during 1970 with "Water" as the main or secondary theme, as follows: February: SARCCUS conference on "Water for Progress," Lourenco Marques. March 16-20: Annual Congress, Institute for Water Pollution Control, Cape Town. May: Possible S.A. Akademie conference on Cooling Tower Experiments, Pretoria. May: Annual Meeting of Association of Municipal Electricity Undertakings, Potchefstroom. May 27-29: Congress on "Water Resources of Natal", Durban. June 29/July 4: Annual Congress, South African Association for the Advancement of Science, Cape Town. July 2: Joint meeting of South African Association for the Advancement of Science and S.A. Akademie, Stellenbosch. July: Winter School, Federation of University Engineering Students. July: Youth Science Week. Foundation for Education, Science and Technology. July 21-24: The South African Tunneling Conference. September: Proposed SARCCUS conference on water in Nature Conservation, Skukuza. November 16-20: International Convention on "Water for the Future", Pretoria.

By J. S. Preston

The properties of some recently developed solvent-extraction reagents for the separation of cobalt and nickel sulphate solutions are reported. New commercial extractants based on alkyl phosphonic and alkyl phosphinic acids are described. These reagents show much improved selectivity for cobalt compared with established extractants. Some novel extractants developed at Mintek for the selective recovery of nickel in the presence of cobalt are also described. These reagents, which are based on mixtures of carboxylic acids and non-chelating oximes, are of interest in that no commercial nickel-selective reagents are currently available. Graphs showing metal loading and stripping, and pH-functionality, are presented. together with details of the metal separations achieved in batch countercurrent- extraction experiments with the various reagents.

Jan 1, 1983

By C. L. M. Gough, L. A. Vermeulen, D. D. Howat

Formulae expressing the dependence of the mass of a grinding ball on the amount of material milled by a ball mill are derived. It is shown that, with the aid of these formulae, it is relativel rsimple for the results of a marked-ball test to be analysed and for the relative performance and cost-effectiveness 0 the various types of ball under test to be evaluated. Predictions based on theory and the results obtained in a marked-ball test in a ball mill are compared detail and shown to be in close agreement. The difficulties associated with marked-ball tests are considered, and an explanation for the decrease in the calculated consumption of the balls, which follows naturally from the theory, is presented. The marked-ball anomaly explained, and it is demonstrated that the ball consumption in a ball mill can be predicted with fair accuracy from the results of a marked-ball test.

Jan 1, 1983

By C. E. Feather, G. M. Koen

The significance of the mineralogical and surface characteristics of gold grains in the recovery process by C. E. FEATHER B.Se. Hons. (Cape Town)* and G. M. KOEN D.Se. (Pretoria)* A description is given of the nature and occurrence of gold at various stages in the process of its recovery from Witwatersrand and related ores. Electron microprobe investigations show that the surface of gold grains in the ore is already coated. During metallurgical processing, further coatings, mainly hydrated iron oxides, accumulate on the grains. Theories are advanced for the formation of these coatings, and the adverse effects on metallurgical operations are discussed.

By S. Budavari

The effects of shaft pillars left in deep-level hard-rock mines during the extraction of tabular deposits were studied some time ago, resulting in the formulation of design principles and procedures, which have been used with success in the design of shaft pillars in the deep-level gold mines of South Africa. The method has not yet been utilized in the design of shaft pillars in shallow and moderately deep hard-rock mines. The purpose of the present study was to remedy the situation since a great number of deposits are worked at those depths. The object of this paper is to present governing equations for the components of stress and differential movement as derived by use of an elastic model. The pillar is taken to be circular in the plane of a horizontal deposit. On the basis of the numerical results obtained, a study was made of the distribution of the vertical strain and tilt along the axis of the shaft, and of the vertical stress along the shaft and across the pillar. In every case investigated, the most adverse geometry was taken into consideration. By use of an empirical criterion and the results of some in situ observations, the determination of pillar dimensions and differential displacement components for South African gold-mining conditions is demonstrated. Pillar dimensions for shallow and moderate depths are compared with those accepted for deep-level conditions.

Jan 1, 1986

By M. H. Moys

Accurate models of mill power are becoming more necessary as the design, operational, and control requirements for grinding mills become more stringent. Models of mill power are reviewed briefly, and a new semi-phenomenological model is derived. The conventional torque-arm model for mill power is combined with a model of the tendency of the load in a mill to centrifuge at high speeds, to describe mill power that can be related to several design variables (such as mil geometry, mill speed, and liner design) and control variables (such as load volume, slurry rheology, and mill speed in the case of variable-speed milling). The semiphenomenological nature of the model allows rational conclusions to be reached concerning the effect of various aspects of mill-load behaviour on mill power. The model is shown to be capable of describing reality with much greater accuracy than is achieved by empirical models such as the Bond model.

Jan 1, 1993

By R. H. Matjie, J. R. Bunt, C. A. Strydom

"A number of conventional and advanced analytical techniques (proximate and ultimate analysis, low-temperature oxygen-plasma ashing, X-ray diffraction, X-ray fluorescence spectrometry, coal petrography, and lightelement electron microprobe analysis) have been integrated and crosschecked to provide detailed characterization of coals from the Highveld coalfield in South Africa, as a basis for better understanding of the mineralogical and chemical properties of the individual coal sources that are blended as feedstocks for combustion and carbon conversion processes. The techniques included methods to quantify the abundance and composition of the mineral matter (minerals and non-mineral inorganic elements), and also the abundance and chemical composition of the individual macerals in the individual coals concerned.Kaolinite is the most abundant of the minerals in the coals studied, with lesser but still significant proportions of quartz, mica and/or illite, dolomite, calcite, and pyrite. Small but variable proportions of anatase, goyazite, and siderite are present in some coal samples. Electron microprobe analysis, based on a special configuration for light-element study, shows that the vitrinite contains less carbon and more oxygen, and has significantly higher concentrations of nitrogen and organic sulphur, than the inertinite macerals in the same samples. Minor proportions of organically-associated inorganic elements, including titanium, were also identified in some of the maceral components.A comprehensive knowledge of the minerals and non-mineral inorganic elements in the coals used for feedstock preparation, obtained by integration of data from these advanced analytical techniques with more conventional analyses, may be of benefit in understanding the processes that take place during coal utilization, and also in avoiding or ameliorating some of the operational and environmental problems that may occur in different sectors of the coal utilization industry."

Jan 1, 2016

With the increased variability of today's large-scale mining operations, consistent flotation performance is important to improving and sustaining overall recovery through the circuit. The Newcrest Telfer Mine has implemented advanced process control technology to obtain stable level operation and consistent mass pull in the copper rougher and scavenger flotation circuits. The final result has been an overall reduction in variability, which impacts on both copper and gold recovery. This paper describes the methodology and implementation of the improvements in control at the Newcrest Telfer Mine as being an essential part of the business for minerals processing.

Jan 1, 2007