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By B. M. Munyungano

Rössing Uranium Mine operates a recovery circuit with continuous ion exchange followed by solvent extraction. Serious organic degradation problems were encountered during 1985/6, 2000 and 2005 in the solvent extraction plant. The preferential loss of the tertiary amine extractant was observed during the above-mentioned period. Previous investigations revealed that the tertiary amine was breaking down to nitrosamine, which cannot take part in the exchange reaction with U3O8. A reduction in the redox potential of the solvent extraction plant feed to below 500 mV halted this preferential loss. A lot of effort has been made to try and understand the actual mechanism for nitrosamine formation. Current understanding for the degradation is that formation is due to high nitrates on the strip side of the circuit emanating from nitrates from the precipitation process using ammonia. It is the current belief that pH lower than 3.7 on the strip side results in loading of nitrates onto the solvent. If oxidizing conditions prevail on the extraction side of the solvent extraction circuit, the tertiary alamine will then degrade into nitrosamine. This phenomenon is yet to be established and verified. It has, however, been established that the above process is brought about the following conditions ?High redox potential greater than 550 mV predominately caused by a high Fe3+/Fe2+ratio (4:1) ?Perception that if Fe2+<0.5 g/lit will contribute to high redox ?High concentrations of NO-3 in the conc eluate (feed to SX)/ammonium sulphate (NO-3> 4 g/l based on historic values) ?Presence of Mo as a catalyst ?Tests also have proved that the presence of nitrous acid in a concentration of 1 g/lat 550 mV leads to formation of nitrosamines from alamine.

Jan 1, 2007

By A. J. Jager, G. R. Adams

The pattern of mining-induced fractures ahead of stope faces in deep-level gold mines, as revealed by petroscopic observations, is described. It is shown that there are zones of fractured and unfractured rock ahead of the face, which are about I m wide and continue as discrete entities for at least 12 m parallel to the face and at least 5 m vertically. These zones do not form continuously as mining progresses, but develop from time to time, leaving a solid zone between the fractured zones. The maximum depth of fracturing ahead of the face depends on the rate of energy release.

Jan 1, 1980

By J. H. Bulloch

This paper describes detailed fractographic analyses of several specimens that had undergone corrosion-fatigue tests at high stress ratios in simulated pressurized water-reactor environments. The distribution and morphology of non-metallic manganese sulphide inclusions are shown to strongly affect the growth of environmentally assisted cracks (EAC), and certain features suggest that a hydrogen-assisted mechanism is responsible for the observed EAC growth. The incidence of transient EAC growth in isolated regions suggests that the critical conditions that trigger this type of growth are the &apos;right&apos; local chemistry at the crack tips and imposed mechanical conditions.

Jan 1, 1987

By C. -T. Mutale, A. S. Tuling

Titanium can exist in three different oxidation states. Its oxides are numerous and in presence of iron and oxygen, iron-titanium oxide compounds can also form. Some of the oxides are non-stoichiometric, making the determination of the thermodynamic properties of titanium and its oxides in molten steel and in slag difficult. Therefore, for the assessment of titanium activity in molten steel using the electrochemical measurements of oxygen partial pressure, the identification of oxides in equilibrium with titanium is important. This paper reports on an investigation of solid titanium oxide inclusions, which have been identified by combining different methods of analysis on quenched samples. These samples were taken from a Fe-Ti-melt at 1600°C, quenched in cold water then mounted and polished for optical microscopy. The oxide inclusions were analysed using transmission electron microscopy (TEM) with energy dispersive spectroscopy (EDS). Both single crystal and polycrystalline diffraction patterns were used to identify the oxides by comparing the d spacings with those in the ICDD X-Ray Diffraction (XRD) database. XRD was used to analyse the oxide particles on the top of slow cooled samples. It was found in the TEM study that the similarity of the diffraction patterns of the various phases meant that unique identification was difficult to achieve in some of the diffraction patterns. However, TiO, Ti2O3, Ti3O5, Ti4O7were identified in quenched samples, while TiO2, FeO.TiO2and iron oxides were seen in slow cooled samples. It was also confirmed that the type of oxides is related to titanium content of the samples. Keywords: Titanium, Titanium Oxides, Iron, TEM, XRD, thermodynamic.

Jan 1, 2004

O.F.S. Branch Proceedings of the Annual General Meeting Held on Wednesday, 4th August, 1976 Mr G. J. C. Young (Chairman) was in the Chair. Also present was Dr R. E. Robinson, President of the South African Institute of Mining and Metallurgy. NlM reports Report no. 175 Copper extraction by leaching magnetites from Palabora Mining Company. (12th Apr., 1967; re-issued Jun. 1976) Report no. 1632 A mineralogical examination of beach-sand concentrates from a pilot plant at Richards Bay. (20th May, 1974; re-issued Jun. 1976.) Report no. 1825 The full automation of a Philips 1220 X -ray spectrometer. A Philips 1220 X-ray spectrometer (semi-automatic) Report no. 1840 The spectrophotometric determination of total uranium in silicate ores and leach liquors by use of bromo-PADAP. Report no. 1841 The determination of aC1;d-soluble uramum in silicate ores and solutions. AS & TS National Award The Associated Scientific and Technical Societies of South Africa has decided to make two National Awards this year. These awards, given in recognition of outstanding contributions to science and the application of science, will be made to Dr T. L. Wadley for his invention of the Tellurometer system of distance measurement and to Mr H. Scheffel for his design of the High Stability Bogie. Treatment of waste water A major international symposium, organized jointly by the Water and Environment Group of the Society of Chemical Industry and the Environment Group of The Chemical Society of London, will be held in London in 1977. Down-the-hole drilling Atlas Copco announces the publication of a revised and enlarged version of one of the booklets in their series &apos;Mining and Construction Methods&apos;. This 40-page booklet is entitled &apos;Down-the-hole drilling with COP drills&apos;.

Jan 10, 1976

By F. M. Russell

Scheduling the extraction and rates of production for an underground mining operation is a common task carried out during the life of a mine, from the initial feasibility study through to the final production phase. The scheduling process can be complex when several requirements have to be satisfied, for example, match mill capacity and maximize net present value while constrained by mining sequence and availability of resources. Many mines have computer programs relevant to their operation but because they are site-specific they need considerable reprogramming to be adapted to other operations. Other methods currently in use also suffer drawbacks: manual spreadsheets are laborious, computerized spreadsheets cannot handle sufficient constraints, and operations research techniques require a complex mathematical model to be set up. The use of network analysis techniques has been proposed previously but the unavailability, until recently, of easily used computer programs has not allowed this approach to be developed. There are now many programs which can be used; however, the particular program which has been adapted to mine scheduling is Metier&apos;s &apos;Artemis-PC&apos; running on IBM-XT or compatible machine. The use of network analysis offers many advantages, including the use of a logical mining sequence; activities can be as detailed as required; related activities can be readily incorporated, and costs can be easily extracted. A heuristic approach is necessary to optimize the schedule, but the ease and speed of program execution enables this to be readily achieved, while leaving the mining engineer in full control. The paper discusses the problems encountered in mine scheduling and current solutions. It then details the use of network analysis techniques and the application of the Artemis-PC program to solve mine scheduling problems.

Jan 1, 1987

For many of us, formal academic education slows abruptly when we leave a tertiary institute of learning. We start applying and connecting newly acquired knowledge with the practicalities of a career, and begin to think in a manner that is technology-oriented. Subsequent vocational advancement is offered by the .many mining and professional journals that circulate through departments, and by conferences and schools that are organized in-house and via the SAIMM and other professional institutions. The importance of these schools cannot be overstated: they combine people and developing technology to the benefit of the industry as a whole.

Jan 1, 1992

Introduction and Background For many years people were aware of the vast deposits of titaniferous magnetite containing vanadium in the Bushveld Complex. From 1957 onwards some exploitation of this ore was carried out by Minerals Engineering of S.A. (later the Vantra Division of Highveld Steel and Vanadium Corporation Limited), who produced vanadium pentoxide via a roast-leach process. Canadian Institute of Mining and Metallurgy The Finance and Executive Committees of the Canadian Institute of Mining and Metallurgy have agreed that members of SAIMM should be invited to register at all future CIM meetings at the same rate as CIM members.

Jan 1, 1980

FOURTH INTERNATIONAL CONFERENCE ON VACUUM METALLURGY This Conference will take place in Tokyo from June 4th-8th 1973. The language used will be English. Inquiries should be addressed to: Mr S. Tabata, Conference Secretariat, The Iron and Steel Institute of Japan, (Nippon Tekko Kyokai), Keidanren Kaikan (3rd Floor), 9-4, Otemachi 1 - Chome, Chiyoda-ku, Tokyo, JAPAN. SYMPOSIUM ON BLAST FURNACE (A.I.M.M.) February 15-17, 1972 Circulars setting out the programme for the symposium, and registration forms, may be obtained from the Secretary of the S.A.I.M.M.

By M. Rossouw

The paper sets out the strategic importance of South Africa?s mining and minerals sector to the national economy. It relates how inexorable and accelerating urbanization and industrialization in emerging markets, especially in China and India, will translate into sustained demand for the minerals that South and southern Africa have in abundance. It warns that while countries buying raw materials from South Africa use these inputs as the basis on which to build value-added, employment-creating industries, South Africa is failing to exploit the economic benefits inherent in its mineral wealth, exacerbating its shortage of skills.

Jan 1, 2011

Bougainville Copper Limited (BCL) operates a 50 Mtpy copper/gold/silver mine and concentrator on Bougainville Island, Papua New Guinea. BCL has installed an in-house developed data logging and supervisory process control system using a DEC PDP 11/73 mini-computer in the mill and has recently installed a similar system in the crushing plant. Together with the central DEC VAX 11/780 computer, they form part of a high speed, fibre optic, local area network in the concentrator. The in-house developed software, known as BIAS (Bougainville Copper Information and Automation System), was developed as a low cost option to interface to a number of different existing plant input/output systems while providing the capability to make maximum use of computer networking facilities. The package includes the more usual control system colour displays and data logging features, but also makes provision for two novel features: (a) Any user connected to the computer network can access the system displays. This allows metallurgists and management to monitor (but not control) plant operation from their offices. (b) Specialized application programs for performing advisory and supervisory control, dynamic simulation, and data analysis are easily incorporated into the system. The mill process system currently runs rougher/scavenger flotation stabilizing control and general data logging. The crushing plant system currently performs data logging only; however it will soon be augmented with the facility to run dynamic crushing plant simulations. Future developments will concentrate on making greater use of the detailed information available from the mine&apos;s fully automatic truck dispatch system which runs on a VAX 11/780 computer. Milling process control will be expanded to examine possible economic control of the operation of regrind and cleaner flotation circuits. An advisory water management system to optimize water supply within powerhouse generating capacity constraint will also be investigated.

Jan 1, 1987

By S. M. Rupprecht

"SynopsisOver the last decade in South Africa, there has been a significant increase in the number of mining operations, both open pit and underground, which use independent contractors to carry out mining activities. Often mine owners will choose the contractor option without fully understanding the consequences of undertaking this option. Traditionally, contract mining has come at a cost premium of about 15% to 20% compared to an owner mining scenario. However, due to the large number of junior mining companies entering the mining arena in South Africa contract mining rates have increased, with cost premiums as high as 50% being reported. This paper looks at the merits of owner mining versus contract mining and describes under what conditions it may be favourable to select the one option over the other. In addition, the methodology of entering into contract negotiations with the objective of establishing a fair and sustainable relationship is discussed.IntroductionOver the last decade in South Africa, there has been a significant increase in the number of mining operations, both open pit and underground, which use independent contractors to carry out mining activities. Surface mining, for example, may use contractors to conduct drilling and blasting operations or load and haul operations. Underground mining may contract out work such as shaft sinking, mining, support, construction work, cover drilling, sweeping and vampings. Common surface operations such as mineral beneficiation, waste disposal, security, and product transport may also be outsourced to contractors.Many companies have a business model that utilizes contractors for the entire mining cycle, maintaining a small head office to provide direction and control. The difficulty with this option is that often mining companies will choose the contractor option without fully understanding the implications."

Jan 1, 2015

By M. U. Ozbay

This paper presents an overview of the research that has been carried out to improve the understanding of the fracture processes occurring in rock under high levels of stress. The onset and growth of fractures are studied by means of laboratory model testing, and the results obtained are used in the calibration and validation of the numerical model DIGS, which is based on displacement discontinuity. The results obtained so far have shown that, while there are overall similarities between the experimental results and the numerical simulations, improvements to the experimental procedures and the DIGS are required for a detailed mechanistic understanding of shear-band orientations and extension fractures.

Jan 1, 1996

Infacon 74 Members are reminded of the International Ferro-Alloys Congress that is to take place in Johannesburg between 22nd April and 1st May, 1974. The Congress is being held jointly by the National Institute for Metallurgy, the Ferro Alloy Producers&apos; Association of South Africa, and the South African Institute of Mining and Metallurgy. Correspondence and enquiries should be addressed to The Secretary, Organizing Committee, INFACON 74, Private Bag 7, Auckland Park 2006. The gold deposits of the farms Lisbon and Berlyn in the Eastern Transvaal by v. c. H. R. BRERETON. Published in the Journal November 1973. AUTHOR&apos;S CORRECTIONS The following amendments should be made.

Jan 2, 1974

The auriferous Carbon Leader reef which is the subject of this study can be subdivided into two types of sedimentological units, each with its characteristic spatial variability. For the longwall mining method applied at Western Deep Levels gold mine, subdivision of the orebody improves the estimation of the actual error variance, but not the grade estimates themselves. This can only be achieved by choosing oreblocks of a size and shape that are maximal parallel to the longwall and minimal at right angles to it, within the limits of mining restrictions. While simple kriging is the only method that gives unbiased results, the difference between untransformed and logtransformed kriging is negligible.

Jan 1, 1987

Alexander Sutulov. Mineria Ghilena 1545-1975 (Mining in Chile 1545-1975). Santiago, Centre of Investigation of Mining and Metallurgy, 260 pp. (In Spanish). G. B. Rothenburg. Speciality steels. D.S.A., Noyes Data Corp., 1977. 270 pp. Witbank Middelburg Branch A General Meeting was held at the Wit bank Golf Club on 20th April, 1977, at 17h30. Treatment of waste water An International Research Symposium on New Processes of Waste Water Treatment and Recovery is to be held in London from 6th to 8th September, 1977. It NIM reports Report no. 1708 An examination of the suitability of various reducing agents for the production of ferrochromium. (27th Feb., 1975; re-issued May 1977). Report no. 1724 The preparation and reduction of chrornite pellets containing a reducing agent. (14th Apr., 1975; re-issued Mar. 1977). Report no. 1854 The interaction of pyrite, oxygen, and xanthate. (8th Mar., 1977). Report no. 1876 The ultrasonic determination of the mud level in a thickener and the resin level in an ion-exchange column. (6th May, 1977). Report no. 1878 The electrochemical dissolution of galena in aqueous solutions. (5th May, 1977). Report no. 1881 n-Octylaniline, a new extractant for noble metals.(28th Mar., 1977). Report no. 1883 The determination of iron, chromium, titanium, and tungsten by X-ray-fluorescence spectrometry. (31st Mar., 1977). Report no. 1889 Entropy relations in the formation of complexes of silver (1), mercury (II), and cadmium (II) with llwnodentate liyaruls. (5th May, 1977). Mechanics of granular materials A conference on the above subject is to be held in London on 8th and 9th September, 1977, under the auspices of the Institute of Mathematics and Its Applications.

Jan 1, 1977

Fig. 4 and 5 of the paper &apos;The analysis of ventilation and cooling requirements for mines&apos; by J. van der WaIt, E. M. de Kock, and L. K. Smith are positioned incorrectly in the February issue (J.B. Afr. Inst. Min. Metal., vol. 83, no. 2, Feb. 1983). Extractive metallurgy of zinc At a professional development seminar to be held in Montreal (Canada) from 18th to 22nd April, 1983, specialists from industry and university will discuss the extractive metallurgy of zinc from ore to finished metal with special emphasis on the theory and practice of modern technology.

Jan 1, 1983

1. Book review Gold and silver handbook: On geology, exploration, production, economics of large tonnage, low grade deposits, published by S.W. Ivosevic. 227 pp. $29.50 + 3.25 for shipping and handling. Available from the publisher, 207 World Savings Building, 12211 West Alameda Parkway, Denver, Colorado 80228, D.S.A. Reviewer: D.G. Krige 2. New Canadian publications Canadian mines: perspective from 1983. Ottawa, Canadian Government Publishing Center, 1984. $4.20. The Canadian iron ore industry: current and emerging problems.

Jan 1, 1985

By L. Bam, R. Machaka, S. Chikosha, N. S. Muchavi

"Parts manufactured through power metallurgy (PM) typically contain pores that can be detrimental to the final mechanical properties. This paper explores the merits of 3D X-ray computed tomography over traditional microscopy for the characterization of the evolution of porosity in metal injection moulding (MIM) and direct powder rolling (DPR) products. 17-4 PH stainless steel (as-moulded, as-debound and sintered) dog-bone samples produced via MIM and Ti-HDH strips (as-rolled and sintered) produced via DPR and were analysed for porosity. 3D microfocus X-ray tomography (XCT) analysis on specimens from both processes revealed spatial variations in densities and the existence of characteristic moulding and roll compaction defects in agreement with traditional microscopic microstructural analysis. It was concluded that micro-focus XCT scanning can be used to study MIM and DPR parts for the characterization of the amount, position and distribution of porosity and other defects. However, the majority of the sub-micron sized pores could not be clearly resolved even at the highest possible instrument resolution. Higher-resolution scans such as nano-focus XCT could be utilized in order to fully study the porosity in MIM and DPR parts. IntroductionMetal injection moulding (MIM) is a novel process, which combines the advantages of powder metallurgy (PM) and plastic injection moulding. MIM has found widespread applications in the cost-effective production of high-sintered density small parts with complicated shapes and mechanical properties equivalent to those of wrought materials (German and Bose, 1977; Machaka and Chikwanda, 2015; German, 2013). There are four basic processing steps involved in MIM, namely; feedstock preparation, injection moulding, debinding and sintering. These steps are discussed in greater detail elsewhere (Machaka, Seerane and Chikwanda, 2014; German and Bose, 1977; Machaka and Chikwanda, 2015; German, 2013).Feedstock preparation involves mixing metal powder with a carefully selected composition of polymeric binder materials at a specific temperature. The feedstock is then granulated and injected into a predefined mould die with the desired shape. The part produced during the moulding step is referred to as a ‘green’ component. The green component typically contains no porosity since the spaces between adjacent powder particles are readily filled with the binder materials (German and Bose, 1977; Li, Li and Khalil, 2007). Debinding is the systemic removal of the binder components by chemical, catalytic, or/and thermal means while maintaining the shape of the component. The part produced after the debinding step is referred to as a ‘brown’ component. Debinding is known to be the source of porosity in brown components (Ji et al., 2001; Tsai and Cen, 1995). Finally, the brown debound part is sintered to full or nearfull density (Sotomayor, Varez and Levenfeld, 2010). The sintering step and associated densification closes up the majority of the pores. Sintered MIM parts are typically sintered to high density (95–99%) and retain an irreducible amount of residual porosity (Barriere, Liu and Gelin, 2003; German, 1990)."

Jan 1, 2016

By C. T. Connor, O&apos

The fifth University of Cape Town (UC1)/University of Stelenbosch (US) Minerals Processing Symposium was held at the Faculty of Engineering, University of Stelenbosch on Friday, 8th August, 1986. This series was initiated in 1982, the symposia being held alternately in Cape Town and Stelenbosch. The South African Institute of Mining and Metallurgy has kindly agreed to sponsor this event for the next three years. Cokemaking On the initiative of the European Cokemaking Commitee, the First International Cokemaking Congress will be held in Essen (F.R. Germany) from 13th to 19th September, 1987. It is being organized by the Steinkohlenbergbauverein, together with the Verein Deutscher Eisenhitenleute.

Jan 1, 1986