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By H. Manurung, I. M. Bendiayasa, W. Astuti, and H. T. B. M. Petrus, F Anggara, K. C. Wanta

The leaching kinetics of cerium (Ce) and yttrium (Y) in sodium-hydroxide-digested non-magnetic coal fly ash using acetic acid were investigated. The variables analysed were pH, solid-to-liquid ratio (S/L), and temperature. The results show that cerium and yttrium's maximum recovery was 57.33% and 58.36%, respectively, under leaching temperature of 90°C for Ce and 60°C for Y at pH of 1,74 and 10 g/mL solid-liquid ratio in 240 minutes. Increasing the leaching time to more than 120 minutes did not significantly improve the results. After the magnetic separation process, the ICP-OES analysis shows a slight increase in the concentration of cerium and yttrium on nonmagnetic components. The XRD and ICP-OES analysis for the sample before and after silicate digestion shows that 40% silicate was dissolved. The calculation of apparent activation energies of leaching using the Arrhenius law for the leaching of cerium and yttrium gives 22.72 kJ/mol and 35.84 kJ/mol, respectively. The kinetic leaching model of cerium and yttrium all fit Dickinson's new shrinking core model. The calculation results show that the leaching reaction is controlled by combining interface transfer and diffusion across the product layer.

Nov 6, 2024

By R. P. King

Held on the 22nd March 1972 at Kelvin House. Four papers were presented at this colloquium, which was attended by approximately 120 people. The first paper, 'Flotation Research Work at the N.I.M. research group, University of Natal on the modelling of a Flotation Process' was presented by Dr R. P. King, the leader of the N.I.M. Research Group in the Department of Chemical Engineering at the University of Natal. A discussion panel, under the chairmanship of Dr R. E. Robinson with Mr M. Dawson (PMC), Mr E. Roux (FOSKOR), and Dr B. K. Loveday (NIM), discussed the potential application of the theoretical work on flotation modelling to industrial processes, and alternative approaches to providing a way of control of flotation plants. The second paper, 'Fundamental Studies of the Flotation Process the Work of the National Institute) for Metallurgy', was presented by Dr N. P. Finkelstein. The discussion panel for this paper was under the chairmanship of Professor D. D. Howat,and had as its members Mr H. P. Carlisle (JCI), Professor D. le Roux (University of Pretoria), and Mr E. Rudolph (Anglo American Research Laboratories). A lively discussion on this paper ensued, with several contributions from the floor. After lunch, Mr S. K. de Kok, Assistant Consulting Metallurgist, Anglo Vaal, presented a paper on 'The Flotation of Copper and Zinc Sulphide from Prieska Ore'. The paper was discussed by a panel comprising Dr V. C. Lovell (NIM), Mr A. Gilbert (General Mining), and Dr D. Legge (Anglo Vaal), under the chairmanship of Dr L. Bushell. This discussion, in which many members of the audience participated, revolved around the difficulties associated with the production of copper and zinc concentrates and the lack of fundamental information on the behaviour of copper and zinc sulphides in flotation. The final presentati0n was a paper, 'The Recovery by Flotation of Cassiterite contained in Gravity Concentration Plant Tailings', presented by Mr E. B. Viljoen (Metallurgy Department, Goldfields South Africa Limited). The discussion, led by a panel consisting of Mr O. Tant (Goldfields Laboratories), Mr J. Levin (NIM), and Mr R. I. Shanks (NIM), under the chairmanship of Mr H. Cross (Goldfields South Africa Limited) referred particularly to the use of new reagents for the flotation of tin, with particular emphasis on the fundamental relationship between reagent composition and its ability to float this type of mineral.

Jan 4, 1972

By J. L. Taylor

The belt-filtration plant at Chemwes Limited has been in operation for three years. The plant design is discussed. Operational and engineering problem areas are reported, and where possible the modifications or practices that led to their solution are mentioned. Capital and operating costs, together with selected general operating data, are also included.

Jan 1, 1983

By John Freer

As an innovation on the annual programme, the Excursions Sub-Committee organized a social get together of the Institute's Councillors and their families on Sunday, 27th February, 1983. Asian Mining - change of date The Second Asian Mining Conference, previously announced as being held in Manila, The Philippines, from 5th to 8th November, 1984, will now be held in Manila from 11th to 14th February, 1985.

Jan 1, 1983

1. Books on management The following are available from Knowledge Resources, P.O. Box 3954, Randburg 2125. . Competitive advantage of nations, by Professor Michael Porter from Harvard Business School. This book highlights the importance of industries in contributing towards national competitiveness. It is being regarded as one of the 10 best business books published during 1990. . The borderless world, by Kenichi Ohmae, Managing Director of McKinsey in Japan. This deals with business in the new interlinked economy. . Megatrends 2000, by John Naisbitt and Patricia Aburdene. This book outlines the mega/macro trends that will

Jan 1, 1991

By J. Manchisi

Laboratory investigations were conducted to establish the feasibility of bioleaching a mixed copper oxide/sulphide rougher concentrate from Nchanga Mine on the Zambian Copperbelt. The objective was to determine the kinetics and extent of copper extraction for this material. Batch experiments were conducted under different solution conditions in stirred tank bioreactors. The progress of (bio)leaching was monitored through measurements of soluble ferrous and ferric iron, copper, pH, and redox potentials, while bacterial activity was monitored online through 02 and C02 gas utilization rates. About 20 per cent copper was solubilized within 2 hours in all cases of non-oxidative (abiotic), oxidative (abiotic), and bioleaching experiments. This was attributed to the dissolution of mainly copper oxides. Subsequently, bioleaching experiments resulted in an overall copper extraction of 93 per cent, with up to 8 g.L-1 copper after six leaching days, compared to 58 per cent copper extraction in the abiotic oxidative acid leaching experiments. However, there was little effect of time (i.e. poor dissolution kinetics) on copper recovery for abiotic non-oxidative acid leaching of the material. Hence, the rate of sulphide leaching increased due to the activity of bacteria. Thus, the material is potentially bioleachable under mesophilic conditions. However, more exhaustive test work needs to be conducted to establish the effect of bioleaching variables and heat requirement.

Jan 1, 2012

By S. Wakita, K. Aoki, Y. Mito, K. Date

It is of great importance to prevent a leakage of hazardous substances from underground storage plants, because this certainly leads to a fatal disaster for human societies. Therefore, effective grouting system needs to be developed, which can inject cement grout into low-permeable rock masses. Authors have carried out a series of laboratory injection tests using a fracture model and field tests in low-permeable rock masses. In these tests, not only was the superiority of dynamic grouting confirmed, but also the relationship between grouting-efficiency and injection parameters was investigated. In this paper, the results of laboratory injection tests and field tests together with theoretical approaches to them are mentioned. L’empêchement de la fuite des substances dangereuses des galeries de stockage est un traitement très important pour protéger la société humaine contre la comtamination catastrophique. Par conséquent, un procédé d’injection efficace doit être mis au point, qui peut injecter du coulis de ciment dans le rocher ayant une perméabilité basse. Les auteurs ont effectué une série d'essais d'injection en laboratoire en utilisant un modèle de rupture et d'essais sur le terrain dans le rocher ayant une perméabilité basse. Dans ces essais, était non seulement la supériorité du l’injection dynamique confirmée, mais aussi le rapport entre l’efficacité de l’injection et les paramètres d'injection a été étudié. Dans cet article, les résultats des essais d'injection en laboratoire et des essais sur le terrain ainsi que les méthodes théoriques pour les essais sont mentionnés. Es ist wichtig, Durchsickerns gefährlicher Substanzen aus unterirdischen Lagerstellen zu verhindern, weil dies für die menschliche Gesellschaft unter Umständen zu verheerenden Unfällen führen kann. Daher muß ein effizientes VerfugesSystem entwickelt werden, welches erlaubt den Mörtelschlamm in wenig durchlässige Felsenmassen einzuspritzen. Die Autoren haben eine Serie von Laboreinspritzungsversuchen mit einem Bruchmodell und Feldversuche an wenig durchlässigen Felsenmassen durchgeführt. Diese Versuche zeigten nicht nur die Überlegenheit des dynamischen Verfugens, sondern wurde dabei auch das Verhältnis zwischen Verfugen und Leistungsfähigkeit sowie den Einspritzungparametern untersucht. In dieser Studie werden die Ergebnisse der Laboreinspritzungtests und die Feldversuche zusammen mit den entsprechenden theoretischen Ansätzen erläutert.

Jan 1, 2003

By M. Coetzee

The susceptibility of experimental low-nickel Cr-Mn-N stainless steels to hot cracking, sensitization, and pitting corrosion in the as-welded condition was investigated. These steels were developed for deep-drawing applications and are similar in composition to type 201 stainless steel. In order to obtain good formability, the rapid rate of work-hardening (characteristic of the 200-series steels) was decreased by the addition of copper. The behaviour of two sets of alloys during fusion welding was investigated: 17Cr-7Mn-4Ni-o.5Cu steels containing 0.001 to 0.27 per cent nitrogen, and 17Cr-7Mn-2Ni-o.1N steels with copper contents varying between 0.01 and 3.11 per cent. Al the steels in these two sets initially solidify as d-ferrite, which transforms partially to austenite during cooling. As the nitrogen level increases, the microstructure of an autogenous-weld metal ranges from large amounts of d -ferrite, martensite, and Widmanstätten austenite, to austenitic structures with small amounts of vermicular d -ferrite. The formation of d -ferrite during solidification and the presence of ferrite retained in the weld metal indicate that the experimental alloys will not be susceptible to hot cracking during welding. Except for the alloy with 0.27 per cent nitrogen, the resistance to pitting corrosion of the experimental steels in the as-welded condition is inferior to that of type 304 stainless steel. None of the experimental steels is susceptible to intergranular attack in the as welded condition. The alloys with 0.19 and 0.27 per cent nitrogen have properties (corrosion and microstructure) similar to those of type 304 stainless steel in the as-welded condition.

Jan 1, 1996

By HORNICKA OSTRAVA

The Czechoslovak Scientific-Technical Institute has arranged the international conference 'Hornicka Ostrava' for four or five days at the end of October, 1969, as part of the preparation for the international 'Miners' Congress' on deep coalextraction in 1970. The keynote of the conference is 'New Techniques in coal mining,' and will be covered by five groups dealing mainly with: 1. New trends in the opening of mines, optimal parameters, projections, equipment, utilization of computers for economic analyses, etc. 2. Increase in efficiency of coal extraction in deep mines, technology, concentration, pressure control, optimization of material and coal transport. 3. Modernization of devices for increased safety and working conditions, new trends in explosives, new techniques for reducing environmental diseases. 4. Innovations in deep level coal extraction, mechanization, rationalization, automation, etc. 5. Other topics about modern techniques in mining. Address your enquiries to: Ing. Karel Kalas (Secretary of the Conference), Dum Techniky Cs YTS, Ostrava 1, Jesenkiho 7-9, Czechoslovakia.

National Coal Board. Gate belt conveyors. London, H.M.S.O. (Price 95p.) Although the preface of this handy little book states that it has been written for the guidance of miningoperation trainees, it will prove valuable to the practising engineer as well. NIM reports Report no. 1733 A mineralogical investigation of weathered carbonatite from Salpeterkop. (14th Apr., 1975; re-issued 28th Feb., 1978). Report no. 1823 The recovery of gold and pyrite from a residue dump at Crown Mines. (10th Jul., 1976; re-issued 28th Feb., 1976). Report no. 1829 An investigation of weathered carbonatite from Salpeterkop. (20th Jul., 1976; reissued 28th Feb., 1978). Report no. 1932 A BASIC computer programme for the evaluation of intensity data from the Telsec Lab-X-250 Analyser. (12th Jan., 1978). Report no. 1940 The extraction of the noble metals with n-octylaniline,and its application to the analysis of platinum-bearing materials. (30th Jan., 1978). Report no. 1945 Analyses of the NIMROC reference samples for minor and trace elements. (28th Feb., 1978). International futures conference A conference entitled 'The Road Ahead' is being organized by the 1820 Settlers National Monument Foundation to be held in Grahamstown from 3rd to 7th July, 1978. Conference of metallurgists The technical programme has been established for the 17th Annual Conference of Metallurgists sponsored by the Metallurgical Society of the Canadian Institute of Mining and Metallurgy. This year the Conference will be held in Montreal, Quebec, on 27th to 31st August, 1978, together with the 8th Hydrometallurgy Meeting.

Jan 1, 1978

The January General Meeting of the Institute was held in Kelvin House, Johannesburg, on 15th January, 1969 at 4.30 p.m. Mr R. C. J. Goode (President) was in the Chair. There were also present eighteen Members, including Messrs F. P. Bath, H. Britten, J. K. E. Douglas, P. Lambooy, V. C. Robinson, W. T. Stobart and P. W. J. van Rensburg (Council Members), Messrs J. C. Hall, P. C. Pirow, Dr D. I. Legge, Messrs E. R. Rudolph, H. R. Reid, Dr N. Stutterheim, Messrs B. F. van der Merwe, L. W. P. van den Bosch, D. T. Watt, M. Youngworth and T. Zadkin. Two Associate Members, Dr P. R. Jochens and Mr D. A. Viljoen. Two Students, Messrs R. P. W. Henrard and D. Ossin. Sixteen Visitors, including Messrs I. Barnes, B. F. Bath, S. Botha, P. A. du Plessis, K. Edwards, Dr F. S. Fulton, Messrs H. Grant, B. Havenga, L. Kok, Dr D. Lasar, R. Sandler, C. W. Wolhuter and J. D. Young. Secretary, Mr D. C. Visser. Total present: Forty. MINUTES The President: "May we confirm the minutes of the meeting held on the 20th November, 1968, as published in the December, 1968, issue of the Journal?" Agreed. MEMBERSHIP The President: "I have much pleasure in announcing that the names of the under-mentioned candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following grades: Members: Basil James Jackson and James Petrie Archibald. Associate Members: Ronald Creasy, Hugh Angus McCallum and John Barton Cunliff. Graduate: Hermanus Isak Johannes van der Merwe. Affiliate: Edgar Ramsay. Student: Petrus Daniel Wolmarans. MEMBERS TRANSFERRED TO A HIGHER GRADE From Affiliate to Associate Member: Neil Bradfield and Mervyn Bayard Allman. "I welcome the newly elected members to the Institute and congratulate those members who have been transferred to a higher grade." (Applause). GENERAL BUSINESS The President: "Are there any matters to raise under this heading? If not, we will proceed to the next item on the agenda which is the presentation of today's paper."

Notices EIGHTH WORLD MINING CONGRESS The Eighth World Mining Congress will be held in Lima, Peru, from 3rd to 8th November, 1974. The theme of the Congress is 'Prognosis of mining development up to the year 2000', with the following subthemes: INF ACON 74 Readers are reminded of the International Ferro-alloys Congress being organized by the National Institute for Metallurgy, in conjunction with the Ferro Alloy Producers' Association of South Africa and the South African Institute of Mining and Metallurgy.

Notices COMPETITION FOR STUDENT MEMBERS OF THE SOUTH AFRICAN INSTITUTE OF MINING AND METALLURGY Each year the Institute offers a prize (or prizes should the entries warrant it) of up to RlOO for the best paper or dissertation on a topic appropriate to the interests of the Institute. The competition is open to all Student Members of the Institute. APPLICATION AND PRACTICAL OPERATION OF HYDROCYCLONES Dr H. F. Trawinski of Amberger Kaolinwerke, Hirschau, West Germany, gave a very interesting lecture on this subject to an audience of over one hundred, composed largely of members of the Institute, on 15th August, 1973, at the University of the Witwatersrand. ROTARY INTERNATIONAL Applications are invited before 15th March, 1974, for the following awards of The Rotary Foundation: Post-graduate Fellowships Under-graduate Scholarships Awards for Technical Training Awards for Teachers of the Handicapped. NIM REPORTS Report No. 1509 The instrumentation developed for electrochemical studies of the le(Whing of uranium dioxide. Report No. 1550 A fundamental study of the dissolution in (Wid solutions of uranium minerals from South African ores. Report No. 1552 The preparation and analysis of minerals for use as reference material.Progress report No. 2. Report No. 1556 The spectral analysis of solutions.2. The analysis of leach liquors, concentrates, slags, and residues. Report No. 1559 A cost assessment of the production of elemental sulphur by chlorination roasting. Report No. 1562 Application of a flotation model to an industrial plant

Jan 11, 1973

By R. P. King

The ideas leading to the formulation and utilization of a flotation model are developed. The main theoretical and experimental work that has been carried out by the National Institute for Metallurgy Research Group at the University of Natal is presented. The two experimental flotation plants available to this Group are described.

By R. F. Botha

I want to thank you for inviting me to deliver this, the closing address at the final plenary session of the 15th Congress of the Council of Mining and Metalurgical Institutions. Your Council has an impressive title, and justly so. Consider the expertise, the skill, the capacity, the achievement, that is gathered together here in this room this afternoon.

Jan 1, 1994

By J. Sehata, J. Tshilongo, I. Govender, S. Pikinini, T. L. Moodley, M. Raedani

In the face of dwindling Merensky ore reserves in the early 1990s, Mintek developed the MF2 flotation circuit to economically recover platinum group metals from the shallow upper group-2 chromitite reef. By aligning the primary and secondary grind to the platinum group metal liberation kinetics, excessive fine chromite generation was avoided, and thus one could consistently produce high-grade concentrates (>200 g/t platinum group metals) with low chrome content (<3% Cr2O₃), well within smelter tolerances. This, coupled with upper group- 2's low-cost open-pit mining, made it particularly attractive to investors and mining houses alike. As a result, deeper lying reefs like middle group and lower group with lower platinum group metals grades and complex mineralogy, were primarily mined only for chromite using density-based separation processes (like spirals), of which the waste tailings are best classified as secondary platinum group metals resources. Today, with global platinum group metal demand rising and high grade upper ground-2 reserves rapidly diminishing, the industry must revisit these middle group and lower group tailings. Mineralogical analysis reveals several challenges: Middle group tailings feature platinum group metals locked within silicate matrices, while lower group tailings contain fine chromitite fragments, and are hosted within non-floating laurite grains, each presenting liberation and gangue issues. Smelter constraints still demand concentrates below 3% Cr₂O₃, requiring solutions that consider both platinum group metals recovery and chrome entrainment. To develop a solution, two lower group chrome spiral tailings samples were obtained from a large chrome mine: Sample A (+425 μm – 106 μm) and Sample B (−106 μm). Initial assays showed Sample B contained higher platinum group metal grades but also higher Cr₂O₃. As such, different blends of flotation feeds were evaluated using ratios of 90:10 (C1) and 80:20 (C2) of Sample A to Sample B, targeting the coarse fraction's lower chrome content while recovering valuable platinum group metals from the fines. This work proposes a practical route for mining houses to unlock additional platinum group metal value from lower group ore spiral tailings. By optimising blending ratios and reagent suites, it is possible to meet smelter chrome and platinum group metal grade thresholds, whilst still obtaining economically viable PGM recoveries.

Mar 6, 2026

By Piotr M. Kapias

Keywords: extraction, lead refining, Pb-Tl solutions, PbCl2-TlCl solutions. The theoretical part of the paper presents an analysis of the conditions of Tl extraction from Pb using different extractants and determines the activity coefficients in liquid solutions of Pb-Tl and PbCl2-TlCl. The dependence of the solution activity coefficients upon the composition and temperature is presented in the form of Krupkowski and Krupkowski-Fitzner equations. An analysis and evaluation were made of the influence of the methods of PbCl2 introduction into a Pb-Tl solution upon the efficiency of the Tl extraction process under thermodynamic equilibrium conditions. The analysis made it possible to formulate relevant equations describing the dynamics of the process of Tl extraction from Pb under stirring conditions as well as under the extractant injection into the liquid Pb-Tl solution conditions. In the part concerning experimental work, results are given for tests on the Tl extraction process from Pb-Tl liquid solutions of initial Tl content of approximately 0.05% mass using PbCl2 or, alternatively, Cl2(g) conducted in laboratorial scale. The tests made it possible to establish the influence of time, temperature, mass and the method of introducing the extractants into the liquid upon the level of Tl extraction from a Pb-Tl solution. Labels used in the text. WT1m - TI content in metallic phase, % mass WT1s - TI content in chloride phase, % mass wpTlm - TI content in metallic phase in initial state, % mass W°Tlm - TI content in metallic phase in equilibrium conditions, % mass m°m - initial mass in metallic phase mm - mass in metallic phase mPbC12 - lead chloride mass fed to the system MPbC12-TIC1 - mass in chloride phase MPb - lead atomic mass, g/mole MT1 - thallium atomic mass, g/mole K - Nernst distribution coefficient Xi - mole friction of solution component X°PbC12 - mole friction of PbC12 in saturated solution X°T1C1 - mole friction of T1C1 in saturated solution T - temperature, K R - gas constant, J/(mole K) k - kinetic equation constant, 1/(%-min.) ?i - solution component activity coefficient e - extraction rate, %

Jan 1, 2008

By D. Bessinger, J. Rabe, J. Zietsman, C. Coetzee, P. H. Lamont, J. Muller

The UCAR® CHILL-KOTE? freeze lining concept combines wall cooling with carbon and graphite refractories of higher thermal conductivities to ?chill? the refractory lining by transferring heat from the refractory lining. Effective sidewall water cooling, together with the efficiency of the heat dissipating conductive refractories, lowers the temperature of the lining to below that of the molten process materials. This causes a layer of slag and process metal to solidify or ?freeze? and form a protective ?skull? which completely coats the refractory hot face. Once formed, the slag skull insulates the refractories, reducing heat loss and protect the lining from erosion, chemical attack, thermal shock, and other stresses. The result: extended life and greatly improved refractory performance. The Ilmenite smelting process depends on the presence of a solidified slag skull to protect sidewall refractory material from chemical attach by molten slag. No known refractory material is able to withstand this corrosive material. To date, UCAR has not applied their Chill Kote ? technology in the ilmenite smelting industry. This paper revolves around the results obtained from conducting an ilmenite smelting campaign on a 500kW DC open-arc furnace with a UCAR designed refractory system. The purpose of this test was to establish the effects such a lining has on refractory wear and the reduction-smelting process. Proper thermo-couple management enabled the authors to monitor lining wear for the duration of the campaign. Prior to the pilot-scale campaign, modeling work was completed to evaluate the feasibility of applying UCAR® CHILL-KOTE? technology to ilmenite smelting furnaces. The successful operation of a pilot-scale furnace equipped with the UCAR® CHILL-KOTE? lining as well as concise modeling suggest that it should be a viable option to consider for an industrial-scale furnace.

Jan 1, 2007

By L. K. Smith, E. M. de Kock, J. van der Walt

A systematic approach to the analysis of alternative methods of ventilating and cooling large hot mines is presented. The important factors that have a bearing on ventilation and cooling requirements and practices, such as air flow through the mine, geographical distribution of eat loads, and micro-ventilation considerations, are dealt with. The analysis of these factors leads to definitive ventilation and cooling strategies, air and water process design, specifications of details, and designs of the associated plant and equipment.

Jan 1, 1983

By J. W. Drelich, H. Zeng, L. Xie, X. Cui, Z. Gao, M. Tian, Y. Hu, W. Hu, W. Sun

Flotation is a mineral separation technology that uses the surface hydrophobic difference of valuable minerals and their associated gangue minerals to separate them. The flotation collector adsorbs on the valuable mineral surface to improve its hydrophobicity, and metal ions are usually used as activators to enhance the collector adsorption. Different mineral surfaces show different charging properties and adsorption behaviours with the collector or metal ions. Moreover, the order of adding metal ions and the collector also show significant and different flotation performance for the same mineral. The adsorption or flotation behaviour or both are governed by mineral surface chemistry, such as surface charging and reactivity. In our recent studies, force measurement using atomic force microscopy (AFM) was employed to study the surface charging and adsorption mechanism of metal ions and collectors. By preparing collector-functionalised AFM tips, AFM can directly measure the adsorption strength of the collector on the mineral surface to determine the anisotropy of mineral surface reactivity. The preparation of collector-functionalised AFM tips provides the foundation for further study of the activation role of metal ion in the collector adsorption. The application of AFM for force measurement in the surface chemistry of mineral flotation can provide important information on developing flotation reagents and lays the foundation for the specific regulation of mineral surface characteristics. Keywords: Scheelite; flotation; surface chemistry; AFM force measurement

Jan 1, 2020