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By C. A. Snyders

This paper investigates the recovery of platinum group metals (PGMs) from a dilute cyanide leach solution containing base metals, in a manner similar to that used for gold extraction in a typical CIP process, and focuses on both the adsorption and elution stages. The carrier-phase extraction of precious metals using activated carbon offers significant advantages over other processes in terms of simplicity, the high pre-concentration factor, rapid phase separation, and relatively low capital and operating costs. As a sorbent, activated carbon is still by far the most important material because of its large surface area, high adsorption capacity, porous structure, negligible environmental toxicity, low cost, and high purity standards. Adsorption tests were performed on a pregnant alkaline leach solution (0.15 ppm Pt, 0.38 ppm Pd, 0.1 ppm Au) resulting from cyanide extraction performed in column leach tests. The initial adsorption rates of platinum, palladium, and gold were very fast and recoveries of these three metals were approximately 90 per cent after 2 hours and 100 per cent, 97.4 per cent, and 99.9 per cent respectively after 72 hours. The parameters that influence the extraction of PGMs and Au were examined to assess their relative importance during the adsorption process in order to provide the basis for process optimization. The concentration of thiocyanate was not identified as significant factor for PGMs adsorption, while nickel concentration was the most significant extraction process parameter. Base metal cyanide complexes adsorb and compete with the PGM complexes for sites on activated carbon, and while copper adsorption can be minimized by adjusting the residence time, nickel adsorbs at approximately the same rate as that of the PGMs, influencing the loading capacity and adsorption kinetics of the PGMs. The feasibility of eluting platinum and palladium cyanide complexes from activated carbon using an analogue of the AARL process was investigated. Platinum and palladium elute from activated carbon almost to completion in 4 to 5 bed volumes at 80°C, while the elution of gold at this temperature is slow, with a significant amount of gold still to be eluted after 16 bed volumes. Cyanide pre-treatment was found to have a significant influence on PGM elution. Higher cyanide concentration in the pre-treatment step results in more efficient elution up to a point, and experiments suggest the possibility of an optimum cyanide concentration, beyond which elution efficiency starts decreasing.

Jan 1, 2012

By S. E. Olsen, K. Tang

Slag-metal and slag-metal-gas heterogeneous equilibria involving MnO-containing slags have been simulated using recently developed Mn-based alloy and IRSID oxide thermochemical databases. A large number of experimental equilibrium data have been used to verify the calculation results. The experimental slag-metal and slag-metal-gas equilibria in MnO-SiO2binary, MnO-SiO2-CaO and MnO-SiO2-Al2O3ternary, MnO-SiO2-CaO-Al2O3quaternary andMnO-SiO2-CaO-Al2O3-MgO higher-order system can be reproduced within experimental uncertainties. The influence of temperature, CO partial pressure and slag chemistry on the Mn-and Si-distribution equilibria have been quantitatively evaluated. This leads to a sound basis for optimizing the manganese ferroalloy production processes. Key words: MnO-containing slag, manganese ferroalloy, equilibrium simulation, thermochemical database

Jan 1, 2004

By R. Asamoah, P. Forson, S. Xu, W. Skinner, M. Zanin

In most auriferous hydrothermal deposits, gold is preferentially associated with pyrite and arsenopyrite minerals, with higher economic gold values noted for the latter and arsenian pyrite minerals. In this paper, surface (Cryo-XPS) and solution (EDTA extraction) analysis were used to characterise pyrite and arsenopyrite minerals under different aqueous conditions involving electrokinetic study and collector interactions to better understand ways of improving the separation of pyrite and arsenopyrite. The evidence showed higher surface oxidation at solution pulp pH values in the range of 4-11 for arsenopyrite relative to pyrite. The observed highest ratio of pyrite to arsenopyrite selectivity was 1.7 at collector concentration of 50 g/t and decreased with an increase in collector concentration. Keywords: EDTA extractable iron, selectivity index, differential flotation, grade engineering

Jan 1, 2020

By N. Hanief

This research involves the investigation of phase transformations in the platinum-chromium coated system. Single-layer 0.1 µm platinum coatings were deposited via electron beam deposition on 99.98 percent pure chromium substrates. Specimens were subjected to systematic heat treatment in a vacuum furnace at 900°C for up to 20 hours. Phase formation and the changes in surface morphology were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM).Both CrPt and Cr3Pt phases are formed during heat treatment for different times at 900°C. Significant changes in the morphology of this coated system were detected after heat treatment at 900°C for 20 hours.

Jan 1, 2012

By S. Bellec

A leaching model for gold ore that takes into account the impact of cyanide and oxygen concentrations as well as gold surface exposure on leaching performance is developed. Cyanide consumption is estimated by an empirical model that is a function of ore particles size distribution as well as cyanide, copper and sulphur concentrations. The proposed model has been validated by data from laboratory leaching tests on the Sleeping Giant gold mine ore. Keywords: gold leaching, modelling, exposure surface.

Jan 1, 2009

By B. Z. Weiss, N. R. Comins, F. Blum

Some aspects of the mechanical behaviour of chromium-containing dual-phase 3CR12 steel were investigated as a function of the temperature and strain rate. The yield stress was found to depend on both the temperature and the strain rate, with no substantial differences between the longitudinal and the transverse directions. The strain-rate sensitivity decreased with increasing temperature. The yield stress could be presented as a function of a temperature-strain-rate parameter. Impact test results showed substantial differences between the energy absorption of the transverse and longitudinal specimens above the ductile-brittle transition temperature. Changes in energy absorption with temperature were gradual for specimens in both orientations, and the transition from ductile to brittle behaviour occurred between 373 and 173 K. Strain rates ahead of the tip of notches with different geometries were calculated and measured experimentally.

Jan 1, 1990

By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluoridesl.2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02?SiO2) with the ammonium acid fluoride (NH4F?XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo-dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012

By J. H. deur Potgieter

This paper, 'A review of the biological treatment of cyanide-bearing waste water' discusses the necessity for the treatment of cyanide-bearing waste water with a view to the avoidance of environmental pollution, and the limitations of the available chemical and physical processes are referred to briefly. The sources of cyanide-bearing waste waters are mentioned. The mechanisms of production and utilization of cyanide by fungi and bacteria are discussed. The work done in connection with the biological removal and destruction of cyanide is summarized, the successes achieved are described, and the relevant processes are listed. In conclusion, some advantages of biological processes for the removal of cyanide are mentioned.

Jan 1, 1991

By C. M. Rule, A. K. Anyimadu, L. Knopjes

Ongoing development work on ultra-fine grinding for various applications at the Group?s concentrators has been conducted by Anglo Platinum over the last few years. Current potential applications for mainstream grinding and concentrate grinding are the subject of a group-wide research and development programme. The first 10 000-litre 2.6 MW IsaMill was jointly developed by Anglo Platinum, Xstrata Technology and Netszch for installation at the Western Limb Tailings Re-treatment project in Rustenburg, South Africa. The unit was commissioned in late 2003/early 2004, and has operated in an intermediate concentrate regrind application successfully since. This paper describes the operational performance to date, as compared with the original duty specifications and objectives. The first mainstream M10 000 IsaMill with a 3 MW drive will be operational in November2006 at the Potgietersrus Platinum (PPL) ?Platreef? Sandsloot Concentrator in South Africa?s Limpopo Province. Key Words: Western Limb Tailings Re-treatment Plant, IsaMilling, Platreef, Platinum, Palladium, PGMs, tailings.

Jan 1, 2006

By I. M. Morsi

The present study investigates the feasibility of using some materials as start-up slags for the extraction of magnesium metal from Egyptian dolomite ores by the Magnethermic technique. The reduction of roasted dolomite (dolime) takes place in a closed evacuated electric arc furnace (small Magnetherm reactor) using ferrosilicon as a reducing agent and liquid start-up slag as a reduction bath under an inert atmosphere. The operational parameters affecting the stabilization of the start-up slag composition and the extraction of magnesium such as reducing agent stoichiometry, reduction temperature, and time were investigated. The dolomitic charge was in the form of sintered briquettes. The charge was reduced under an argon atmosphere in the Magnetherm reactor for constant period and constant temperature. The results showed that the clinker can be used as a start-up slag for the magnethermic process. Also, the optimum conditions for the extraction process were found at 2XSi stoichiometry to give maximum reduction of 80% after 15 minutes reduction time at a temperature of 1550°C. XRD and XRF measurements were used to determine the phases present and the extent of reduction of magnesium, respectively. Keywords magnesium, dolomite ore, magnetherm, magnetherm reactor, silicothermic reduction.

Jun 1, 2013

By V. G. Pienaar, B. M. Mbiya, P. T. Slatter

[a constant b constant cc onstant c' constant D pipe diameter (m) Dshear shear diameter (m) E error function fth theoretical friction factor F function F' function K fluid consistency index (Pa sn) kv valve loss coefficient L pipe length (m) n flow behaviour index N number of data points ?P valve pressure drop (Pa) Q flow rate (m3/s) Re Reynolds number Re3 Reynolds number (Slatter) V average velocity (m/s) Vann annulus velocity (m/s) x variable X number of independent variables y variable Y number of fundamental dimensions z variable µeff effective viscosity (Pa s) ? valve degree of opening d partial derivative ? fluid density (kg/m3) [ ] function]

Jan 1, 2007

By F. L. Wilke

The use of operations research techniques and computer models has become entrenched in the mining industry, particularly in the area of mine planning. The paper considers three major areas where increasing efforts are likely to be directed in the future: the integration of multiple disciplines in a single model; the decentralization of computing capacity within a structured network; and the incorporation of sophisticated techniques such as computer aided design and artificial intelligence.

Jan 1, 1987

By H. M. Chikashi

Keywords: Pyrometallurgy, furnace, bath agitation, regression analysis, entrainment This paper presents the results of linear regression analysis of the influence that each component of slag has on the losses of copper in slag-cleaning-furnace slag. Data used for the analysis are actual plant data collected over the past two years of operation. Facts obtained from the study will be helpful for smelter management to control these components in the flash smelting furnace feed and slag, to levels which will enable better control of copper in slag, and smoother operation of the KCM slag-cleaning furnace.

Jan 1, 2011

By D. O’Beirne

Union Corporation are experimenting with a high-pressure water jet to remove blasted rock from short panels. The advantages are that the jet provides a highly efficient, flexible, and mobile cleaning tool that eliminates much of the lashing. Cost estimates show it to compare favourably with the existing system, with potential savings of 30 cents per ton milled. Equipment and method trials are continuing with the ultimate objective of eliminating hand lashing entirely while retaining the flexibility of the present method of mining.

Jan 1, 1979

By A. Hoogervorst

Cyanide is a key contributor to the efficiency of gold extraction. Public perceptions of cyanide are emotive and following some publicised incidents involving cyanide, the gold mining industry established a voluntary cyanide code for the manufacture, transport and use of cyanide in the production of gold. The paper describes the development of the code, its content and the third party auditing of the code as a means of establishing and maintaining benchmark standards. In adhering to the cyanide code requirements, there are overlaps with other management systems such as ISO 14001 and OHASA 18001 and the paper seeks to show how existing mine systems can readily accommodate cyanide code compliance and that operating and auditing the cyanide code can assist in the integration of mine heath, safety and environmental management systems.

Jan 1, 2009

By S. Mohanty, K. Sarangi, S. Dash, P. P. Patra

Industrial effluent from various industries contains heavy metals that are a serious threat to humans, flora and fauna in water bodies, and the environment. The heavy metals are dumped after precipitation, which has serious environmental consequences. In this paper, a 2D axi-symmetry CFD model has been developed to study the extraction of chromium ion from industrial effluent, in a hollow fibre membrane, using Alamine 336 as the carrier and kerosene as the diluent. The Navier Stokes equation was used to predict the velocity profile of the aqueous and organic phases, and species transport equation, which considers both convective and diffusive mass transfer, was used to predict the concentration profile of the chromium ion in the computational domain. The distribution coefficient was experimentally determined at a pH 4, which was found to be the optimum pH. Numerical simulations were performed considering 11.11 mol/m3 of initial feed concentration for chromium ions and extractant concentration of 0.2 M. Simulations were carried out with various aqueous and organic flow rates, and validated with experimental data. Keywords: CFD, metal extraction, hollow fibre membrane, heavy metals

Jan 1, 2020

By M. Holuzko, Y. R. Zhang, J. Alexander

The use of dual-energy X-ray transmission (DE-XRT) technology in the mining industry has been developing rapidly in the past decade. In many projects, DE-XRT images are analysed to classify ore and waste in sulphide deposits where the sulphides and non-sulphides have distinct characteristics in density. In the current practice of DE-XRT image processing, every pixel in the image gets classified into two categories, depending on the intensity of the pixel from both low and high energy X-ray response. If the pixel’s intensity is above the threshold curve generated in the high-energy and lowenergy scatter plot, it is classified as “higher density” material, and the remaining pixels are classified as “lower density” material. This paper elaborates on an alternative approach to DE-XRT image processing for in-depth characterisation of samples from a lead-zinc sulphide deposit. The detailed characterisation is achieved by providing density distribution of individual rock using DE-XRT laboratory sorting unit (COMEX) located at the University of British Columbia. Instead of classifying the X-ray images into two different classes from one threshold curve, multiple density classes are created between two threshold curves to generate the density distribution. By manipulating the two threshold curves, we can analyse images of samples obtained at different resolutions of density distribution. If the two threshold curves become infinitely close to each other, it will create a single-threshold scenario similar to the current methods being used in the industry. This method provides the ability to change the threshold curves, hence providing more flexibility on material characterisation based on the needs of the operation. Furthermore, the DE-XRT images from individual rock specimens are compared to the test results from hand-held X-ray fluorescence (XRF) analyser as well as assays of various elements for the same set of samples. The data analysis will provide information regarding ore characteristics and also the theoretical performance of the sensor-based sorting. Keywords: Dual-energy X-ray Transmission (DE-XRT), X-ray fluorescence (XRF), ore characterisation, density distribution

Jan 1, 2020

By M. J. Nicol

On page 51, the equation numbered.... On page 52, the equation numbered .... On page 53, the arrangement of the equation.... Canadian reports Asbestos by G.O. Vagt.l0 pp. Chromium by D. G. Law-West. 6 pp. Iron and Steel by T. R. Mclnnis. 15 pp. Titanium and Titanium Dioxide by M. A. Boucher. 7 pp. Vanadium by D. Shaw. 7 pp.

Jan 1, 1984

By M. I. Brittan, E. J. J. van Vuuren

Computer analysis, modelling and optimization of gold recovery plants of the Anglo American Group by M. I. BRITTAN M.Sc. (Eng.), M.S., Ph. D., (Member). and E. J. J. van VUUREN M.Sc., (Visitor). Multiple correlation and regression techniques are used to analyse gold plant operating records. Key variables m the process which Influence the gold recovery are Identified and assembled into a mathematical model. This constitutes a valuable tool for the optimisation of variables such as the rates of reagent addition and for assessing the economics of extending the plant. Substantial short term economic benefits have been realized. The techniques provide a rapid diagnostic service without interfering with normal plant operation. Quantitative results are presented and their implications examined. The value of the method is discussed.

By G. E. Blight

Rates of erosion have been measured for the slopes and top surfaces of a number of gold-tailings dams in the Germiston-Johannesburg-Roodepoort area of the Transvaal. Preliminary results were given in an earlier paper. The present paper gives results for a four-year period of observation, and identifies the major factors affecting the rates of erosion from the surfaces of gold-tailings dams.

Jan 1, 1989