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By A. D. Davis

The Gilt Edge Superfund Site is a former heap-leach gold mine that currently is being remediated in the Black Hills of South Dakota. Mine runoff water is treated before release from the site. The field pH, before treatment, is about 3, and the water contains arsenic and some heavy metals, in addition to sulfate concentrations of about 1400 to 1500 mg/L. In the Keystone area of the Black Hills, naturally occurring arsenic has been detected in ground-water samples from wells. Keystone City Well #4, which is not used currently, showed arsenic concentrations of 36 parts per billion (ppb) and sulfate concentrations of about 19 mg/L. With field samples of water from these sites, a limestone-based method was successful in reducing arsenic and heavy metals concentrations. The results are significant because previous research with the limestone-based method mainly had involved samples prepared with distilled water in the laboratory, in which interference of other ions such as sulfate did not occur. The research indicates the potential for broader field applications of the limestone-based removal method.

Jan 1, 2011

By Olice C. Carter, B. J. Scheiner

The Bureau of Mines investigated the removal of two toxic/heavy metals (cadmium (Cd) and lead (Pb)) from brass foundry wastewater. Polymers, copolymers, guars, and gums were used in conjunction with calcium hydroxide (Ca(OH)2) and magnesium oxide (MgO) to remove the metals from solution. Several polymers were successful in removing Cd and Pb from the wastewater. The concentrations of Cd and Pb were lowered from 19 to 0.01 ppm and from 20 to less than 0.01 ppm, respectively. The methods investigated could easily be adapted to many existing wastewater treatment facilities and/or be used independently.

Jan 1, 1991

By Kenneth N. Han, Jianshe Liu

Various techniques used in the removal of metal ions from effluent streams have been reviewed. These techniques include recovery of metals by biological treatment, chelating agents, adsorption, ion- exchange and chemical precipitation. The main thrust of this paper however, is concerned with the removal of cadmium and zinc ions from the solution by adsorption utilizing liquid fluidized beds. The bed particles used were silica of 150x200 mesh. The range of the concentration of these ions studied was 10-3 to 10-5 M. Important variables examined included flow rate, concentration of metal ions and amount of bed particles. A mathematical model describing the concentration profile of metal ions in the axial direction in liquid fluidized beds has been developed. The equation of continuity was solved numerically and the results were used to predict the recovery of metal ions in fluidized beds.

Jan 1, 1992

By Z. H. Zhou

It is difficult to remove cadmium from raw indium using only electrolytic refining because their standard potentials are similar. In this paper, physical and chemical methods were used to remove Cd from raw indium. Indium metal is vacuum refined for two hours at 400°C with a vacuum pressure of 20 Pa. In this process, 99.70% of the Cd can be removed. The removal rate of Cd reaches 90% to 95% when indium is further smelted for 10 minutes in a 20% glycerin solution of KI and I2 at 180°C. When pre-indium is electrolytic refined in an In2(SO4)3-H2SO4 system, in which the indium content is 80 to 100 g/L, the pH is 2.0-3.0 and the current density is 80 to 100 A/m2, the contents of the impurities decrease and the purity of the indium product reaches 99.99%.

Jan 1, 2007

By A. Guan, K. N. Han, J. J. Kellar, D. A. Boyles

Metal ions associated with effluent streams pose an increasing environmental problem for the mineral industry. Various techniques currently in use to combat this problem including bioremediation, chemical precipitation, and ion exchange are reviewed, and their relative advantages and disadvantages discussed. An alternative technique for metal ion removal, adsorption on surface modified alumina substrates is presented. Alumina surfaces were modified by adsorption of organofunctional silanes, and metal ion removal occurs by chelation of the ion by the adsorbed silane molecules. Experimental data is presented for the removal of cupric ions by this method and is compared to cupric ion removal by adsorption on alumina without prior surface modification.

Jan 1, 1994

By S. Mathur

The southern Florida phosphate deposits that will be mined in the future contain significant amounts of dolomite. Because high MgO levels are undesirable in phosphoric acid production, several flotation schemes for the removal of the dolomite have been attempted. Alternatively, selective flocculation has been suggested as a potential process. A high MgO rock was simulated with a 30:10:60 mixture of apatite, dolomite and silica, respectively. Single mineral selectivity was observed in the apatite-silica and dolomite- silica systems using Polyacrylic acid (PAA) and Poly(ethylene oxide) (PEO) flocculants, respectively. However, no single mineral selectivity was observed in the apatite-dolomite system using PEO. Heteroflocculation, suspected to be the major reason for the loss of selectivity, was minimized by the addition of a site blocking agent (SBA), consisting of a lower- molecular-weight fraction of PEO. Process parameters such as size reduction schemes, flocculant/SBA dosage and pH were investigated to achieve the desired separation. The selectivity obtained in binary mixed-mineral tests was also achieved in the ternary mixed-mineral system, namely, the apatite-dolomite-silica system. In this report, surface chemical characterization of the samples and their flocculation behavior are discussed.

Jan 1, 1995

The future phosphate rock deposits in South Florida contain a significant fraction of dolomite. The high MgO content of the rock is undesirable in the production of phosphoric acid. Several flotation schemes have been attempted to separate dolomite from phosphate rock. Alternately, Selective Flocculation process has been suggested to separate dolomite from apatite. A high MgO content rock was simulated by a 30:10:60 synthetic mixture of apatite, dolomite and silica. Single mineral selectivity was observed in the mixed mineral systems apatite-silica and dolomite-silica with Polyacrylic acid (PM) and Poly(ethylene oxide) (PEO) flocculants respectively but not realized in apatite-dolomite system with PEO flocculant. Heteroflocculation, suspected to be the major reason for loss in selectivity, was minimized by addition of a Site Blocking Agent (lower molecular weight fraction of PEO). Process parameters such as size reduction schemes, flocculant/SBA dosage, and pH were investigated to achieve the desired separation. The selectivity obtained in binary mixed mineral tests was translated into the ternary mixed mineral system, viz. apatite-dolomite-silica. In this presentation surface chemical characterization of the samples and their flocculation behavior will be discussed.

Jan 1, 1994

By Mengxiong Guo, Xuxin Shao

The recent depressant research is summarized, and a new kind of depressant (SCO) has been put forward in this article. Using Na-oleate as a collector and SCO as a depressant, separation of dolomite and phosphate was studied. When SCO was added in the concentration range of 80 g/t to 2kg/t at pH 9.5 ± 0.2, dolomite was absolutely depressed, and apatite kept its floatability. Interestingly, in the mixture of phosphate and dolomite, the dolomite floated. The reasons for such a behavior are investigated through flotation and electrokinetic studies. It was found that the adsorption of dissolved species on dolomite and phosphate resulted in reverse flotation. A concentration of 31.59% P205 and 83.87% recovery of P205 was obtained from the mixture of phosphate and dolomite (2:1) with 26.6% P205 using 210 g/t SCO and Na-oleate 4.93*10-5 M at pH 9.

Jan 1, 1989

By J. G. Groppo, J. G. Justice, B. K. Parekh

Removal of particulates and/or metal ions from mineral/coal processing waste water is a necessity from the environmental point of view. This paper describes application of a novel AC- electrocoagulation technique to remove the particulates as well as metal ions using AC power. A series of laboratory tests conducted on a stable black water sample obtained from a sub-bitminous coal operation provided a clear supernatant (-10 NTU) from the suspension. The process also shows promise in removal of up to 90 percent of phosphate ions and other metal ions (copper and nickel) from solution. A preliminary economic evaluation of the process will also be included.

Jan 1, 1992

By K. N. Han, M. C. Fuerstenau, T. B. Onlin

An investigation of the removal of finely divided silica, coal, and alumina particles less than 20,µm in size has been carried out using liquid fluidized and packed beds. The bed particles used included 48x100, 100x150, and 150>200-mesh silica, corundum, and ilmenite particles. Important variables examined included surface charge, flow rate, pH and amount of bed particles. Surface charge has been identified as the most important variable in this system. Van der Waals force also assumes a very important role in the recovery of fine particles in fluidized and packed beds. In addition to interaction between large and fine particles, interaction between fine particles themselves assumes an important role in the overall recovery.

Jan 1, 1987

By K. N. Han, M. C. Fuerstenau, T. B. Onlin

A mathematical model describing the concentration profile of fine particles in the axial direction in liquid fluidized beds has been developed for the removal of fine particles. A forward finite differentiation technique has been used to solve a continuity equation with a source term to predict the concentration profile and, hence the recovery as a function of time. With the aid of experimental results obtained using a fluidized bed of 3-cm diam, dimensionless parameters were identified. These parameters were used to predict the concentration profile of fine particles in fluidized beds of larger sizes. Four different sizes of fluidized beds, namely, 1.3, 3.0, 4.0, and 7.5 cm in diam, were used in this investigation. The amounts of bed particles used included 4, 8, 16, 24, 59, and 120 g, and the size of bed particles were 48x100, 100x150 and 150x200 mesh.

Jan 1, 1987

By E. Valdiviezo, J. F. Oliveira

Adsorption of residual flotation reagents onto equilibrium fluid cracking catalysts is a promising method of purification of flotation process water. In the present paper, adsorption of sodium dodecyl sulphate (SDS), dodecyl ammonium chloride (DAC) and sodium oleate onto a spent catalyst from petroleum industry was studied by analysing the residual concentration of the surfactant after contact with the zeolite catalyst. The adsorption of the DAC was rather low but SDS and sodium oleate presented a high affinity for the catalyst surface. The loading capacity was 4.2 kg/ton for SDS and 5.5 kg/ton for oleic acid. After the treatment of the loaded catalyst with a HCI 1 N solution these surfactants are desorbed and the catalyst may thus be regenerated. This would be an additional advantage to its low cost, not to mention its condition as a discarded product and its availability in large tonnages.

Jan 1, 1995

By J. R. Tonry

In the grinding of dry non-metallic materials such as rocks, ores, gypsum, lime, and cement clinker, it is recognized that only a relatively small portion of the energy is utilized for actual size reduction, and the major portion of the energy used is converted into heat. As a result, heat is generated inside grinding mills imparting to the ground product a higher temperature than that of the mill feed. In some cases, as for instance in grinding cement clinker and gypsum into finished cement, it may be desirable to keep this temperature increase within certain limits, to avoid any change in the properties of the product and, because consumers may specify a maximum temperature of the finished product for reasons associated, with the tulimate use of the cement. The actual proportions of heat and useful work are somewhat indefinite. Some tests have indicated that nearly all the energy is converted into heat, and. other investigators have found that they could account for "everything except the noise." Investigations sponsored by the American Institute of Mining and Metallurgical Engineers, and carried out with an adiabatic calorimeter, indicated that a surprisingly high 19 percent of the energy might actually be used for size reduc¬tion. However, for the purpose of the following discussion it will be assumed that: (Fig. 1) 10% is lost in motor and gears 10% is lost by radiation and convection from the mill body 10% is used for size reduction, and. that 70% of the energy input leaves the mill as heat in the ground. product. A typical example (Fig. 2) would be a 7x22-ft tube mill operating in open circuit, driven by a 400 hp motor, charged with 77,000 lb of grinding media and producing 70 bbl or 26,300 lb of cement per hour. Reducing this cement from a clinker size of 96 percent passing a No. 16 mesh sieve to a specific surface of 3,230 sq cm per gm (Blaine) will increase the temperature of the cement approximately 143F above the temperature of the feed, as explained later. If the tempera¬ture of the clinker therefore is 125F, the finished cement will be 268F, which in some cases may be too hot. : When cement temperatures approach a range during grinding where dehydration of the gypsum becomes a problem, a logical consideration would be some means of reducing the temperature before it attains the range conducive to gypsum dehydration. Regardless of the varying degrees of heat generated within the mill or mills during grindingto various finenesses, consideration of the maximum safe limit for any type of cement being ground, which may vary fromplant to plant, govern in refining the mill circuit to obtain a safe temperature range. All plants are not necessarily required to do the same cooling job, and may or may not use cement coolers following the grinding circuit. (Not discussed in this paper). In the past, various means have been employed for controlling this temperature increase, Such means have included water cooling of the outside of the mill shell; equipping the shell with cooling fins; injection of moisture inside the mill; ventilation through the mill; and., in cases of closed-circuit grinding, drawing cooling air through the classifier; the purpose in all such cases being to remove heat from the grinding system.

Jan 1, 1958

By X. Baolin, R. Guru, M. Peiravi, M. K. Mohanty, Z. Qian, R. Ma, Z. Yude, L. A. Ackah

"Acid mine drainage (AMD) is produced when exposed pyrite (FeS2) reacts with air and water to form an acidic solution that usually contain contaminant levels of heavy metal ions. AMD can potentially contaminate surface water and soil if not treated. The primary objective of this study was to investigate the removal of dissolved aluminum, iron and zinc metal ions from natural AMD using water treatment residue (WTR), a low-cost adsorbent. WTR sorbent generated as waste material in drinking water treatment plants (WTP) was characterized and utilized for the sorption of Al, Fe and Zn in AMD collected from an abandoned coal mine site in southern Illinois that generates approximately 20 gallons per minute of AMD. Sorption experiments were performed using batch technique to obtain rate and equilibrium data. The effects of various parameters on sorption capacities of WTR were observed by varying contact time, pH of the AMD and WTR dosage. The adsorption studies showed rapid uptake in general for the first 80 minutes for Fe and Zn but much earlier for Zn. Further increase in contact time did not show significant change in equilibrium concentration indicating the onset of adsorption equilibrium. After the batch treatment of the AMD water with the WTR, the removal of Al, Fe and Zn were 99.8%, 99.85% and 95.5% respectively. The pH of AMD increased from 2.64 to a near neutral point of 6.74 after treatment. The laboratory results show that the low-cost WTR, which is an abundantly available industrial waste, has proven potential to significantly reduce the high metal ions in acid mine drainage. INTRODUCTION Mining activities provide the basic raw materials needed for infrastructure development and economic growth world-wide. However, it is well recognized that mining activities have been the cause of a variety of environmental pollutions, including AMD. Water seeping out of an old abandoned mine is generally characterized by low-pH with heavy loads of dissolved sulfates (SO4) and metal species such as Fe, Al and Zn among other dissolved elements categorized as toxic metals. The Bureau of Land Management’s Abandoned Mine Lands (AML) program reported the existence of about 46,000 abandoned mines in the United States. Several environmental problems have been reported to be associated with these mined out sites such as heavy metal poisoning, loss of vegetation, air pollution etc. (Boulanger & Gorman, 2004)."

Jan 1, 2017

By C. Villa Diniz, A. H. Martins, Fiona M. Doyle

It is proposed that battery grade MnO2 can be produced directly from a manganese ore from Azul Mine in Brazil, by leaching with HCI to remove heavy metals selectively. We are working to find a way of selectively separating Cu, Ni, Co, Pb and Fe from the resulting acidic manganese chloride solution, to detoxify it and produce marketable chloride solution. Chelating ion exchange resins are proving more promising for this separation than solvent extraction with commercially available reagents. Results from batch and column ion exchange tests that characterize the behavior of copper, nickel, cobalt, lead and iron are reported.

Jan 1, 1999

By C. Villa Diniz

It is proposed that battery grade Mn02 can be produced directly from a manganese ore from Azul Mine in Brazil, by leaching with HCI to remove heavy metals selectively. We are working to find a way of selectively separating Cu, Ni, Co, Pb and Fe from the resulting acidic manganese chloride solution, to detoxify it and produce marketable chloride solution. Chelating ion exchange resins are proving more promising for this separation than solvent extraction with commercially available reagents. Results from batch and column ion exchange tests that characterize the behavior of copper, nickel, cobalt, lead and iron are reported.

Jan 1, 1999

By A. Papandreou

Industrial wastes nowadays constitute one of the most serious threats for the future of our planet. Researchers around the world have very often proposed many kind of solutions in the management problem of industrial effluents. However in most cases suggested solutions are either too expensive to be applied in industrial scale, or they just transfer the problem (e.g. precipitation creates dangerous sludge) and so they create an even greater problem and threat. In the present study the exploitation of valuable hydraulic and adsorption properties of fly ash is studied. Fly ash can easily and cheaply be shaped into stable pellets. After ageing for a sort period of time, these structures can be used as adsorbents for the removal of heavy metals from industrial effluents. Experiments in aqueous solutions have shown excellent adsorption behavior concerning the removal of cadmium, copper, lead, chromium (III) and zinc. The advantage of this technology, except low cost, is that after saturation the pellets can be easily removed from the liquid phase and stabilized in concrete structures without any problem of desorption or leaching. Moreover in these structures a significant amount of cement in the concrete can be replaced by raw fly ash. (Ashcrete as it is called). The utilization of an industrial byproduct as fly ash in the form of pellets as adsorption means and their stabilization with concrete (or ashcrete) combines the useful properties of a solid waste in the treatment of liquid effluents and constitutes a green low cost technology.

Jan 1, 2006

By W. L. Cornell, F. W. Benn

The U.S. Bureau of Mines investigated froth flotation techniques to remove heavy metals (Pb, Cu, and Zn) from southeast Missouri lead mill tailings. It has been estimated that southeast Missouri contains between 200 and 300 million st of Pb tailings stored above ground. The tailings were classified as two distinct types: (1) pre- 1968 tailings from the Old Lead Belt (some more than 100 years old) and (2) post-1968 tailings from the New Lead Belt. The objectives of the investigation were to reduce the Pb remaining in the tailings to (500 ppm (<0.05% Pb) and to attempt to recover a marketable concentrate to offset a portion of the remediation costs. The remaining dolomite-limestone would then be used as mining backfill or agricultural limestone. Bench- scale froth flotation removed, in percent, 95 Pb, 84 Cu, and 54 Zn, leaving 94% of the original weight containing, in parts per million, 400 Pb, 40 Cu, and 300 Zn from the Old Lead Belt tailings. Separate flotation tests also removed, in percent, 85 Pb, 84 Cu, and 80 Zn, leaving 75% of the original weight containing, in parts per million, 400 Pb, 200 Cu, and 500 Zn from the New Lead Belt tailings . Concentrates recovered from the Old Lead Belt were retreated to produce a final Pb concentrate containing 72% Pb with a cleaner flotation recovery of 79%. Froth flotation proved to be a viable method to remove the heavy metals.

Jan 1, 1992

By J. B. Nanor, J. Lorengo, M. Misra, C. B. Bucknam

The dissolution of mercury during the gold cyanidation process is the cause of many environmental, health and processing problems. The removal of mercury-cyanide complexes from synthetic solutions and process water were investigated using sodium and potassium dimethyl dithiocarhamates and sodium sulfide as precipitating reagents. The results have shown that efficient mercury removal can he achieved by the formation of stable mercury compounds with the addition of potassium dimethyl dithioearhamate. The mercury dimethyl dithioearhamate precipitates are stable under plant operating conditions, and they do not have any deleterious effect on gold adsorption by activated carbon. Furthermore, it is possible to stabilize mercury in the heap during cyanidation by adding dimethyl dithioearhomate.

Jan 1, 1999

By R. J. Rice, K. F. Denning

Effect of iron on the removal of arsenic, mercury and selenium from gold mining effluents. Arsenic, mercury and selenium are common trace elements in gold tailing effluents that require removal before the water is either recycled or returned to a receiving body. One of the better methods of removal of these elements is the use of iron salts whereby, the metal is trapped on the freshly precipitated hydrolyzed iron oxides either by adsorption or enmeshment of the fine particulate and hence, removed from solution. The metal removal is effected by iron to metal ratio, pH, temperature etc. Pilot plant tests have shown that mercury can be reduced to < 5 ppb Hg, while full scale tests on arsenic and selenium have achieved levels of < 50 ppb As and < 10 ppb Se in well controlled systems.

Jan 1, 1993