Search Documents

By Lee F. Robinson, Angus W. Morrison, Norman M. Anderson

About 100 years ago the acid and chlorine oxidation routes for gold extraction were abandoned in favour of cyanide/ oxidation processes. Now a return to acid processing is in progress. One publication in particular led HM C Technology to investigate the reaction of dilute nitric acid and alkaline metal chlorides with refractory gold ores.(l) The one stage system of gold and silver recovery from sulphidic ores is described below. It is rapid and does not use large or expensive plant or special pressure equipment. It eliminates calcining followed by cyanidisation and shows a simple way of recovering the gold directly. Patents have been granted in some countries (2).

Jan 1, 1990

By Patricio A. Riveros

Various types of commercial ion exchange resins were evaluated with respect to their ability to extract gold from cyanide leach solutions. Large differences were found among the various resins in terms of selectivity and gold loading. The hydrophi­licity and the charge density appear to be the main factors that determine the resin characteristics. Polystyrene weak-base resins, such as Dowex MWA-1, exhibited the best all-round performance.

Jan 1, 1990

By Pierre Ollivier, Dominique Morin

A general study of gold refractory arsenopyrite pyrite concentrate bioleaching has been carried out including two continuous bioleach testworks at different sizes, namely one at a laboratory scale with a 100 1 unit at a 2 kg/d dry solid flowrate and the other at a pilot scale at a 100 kg/d dry solid flowrate. Both tests show a 80% bioleaching of arsenopyrite in about four days of treatment and with the same kinetic. Pyrrhotite is attacked at the earlier stage of the bioleaching but pyrite remains unaffected. The weak potential of oxidation associated with the decomposition of arsenopyrite and the abundance of arsenite leads to a high grade of elemental sulfur in the bioresidue which consumes the major part of the cyanide during the gold recovery, furthermore, the arsenite and ferrous produced in solution have to he oxidized to obtain a stable precipitate in the waste products and as outlined in previous works of other authors on this subject the addition of iron to obtain a Fe/As molar ratio at least above 3 is necessary. The agitation equipment used in the pilot unit allowed an optimisation study calculation for scaling-up the design and power requirements of an industrial installation, For the pretreatment of a gold refractory As high-graded concentrate the reagent cost has the greatest part in the operating cost of the biooxidation step due to the necessary retreatment of the biosolution, In that conditions the power cost is quite marginal, actually it is significant for the treatment of pure pyrite.

Jan 1, 1990

By Chris A. Fleming, Daan Seymore

The Golden Jubilee Mine in South Africa is the first mine in the Western World to introduce resin-in­pulp technology for the recovery of gold from a cyanide-leached slurry. Located in the Eastern Transvaal region of the country, the plant processes approximately 375 metric tons• of ore per day, of which over 90 per cent is mined in an open pit adjacent to the metaflurgical plant, while the remaining 5 to 10 per cent is trucl<ed in from two small high-grade deposits, located about 10 kilometers from the plant. The gold grade in the open pit is about 1 git, while the values m the two high-grade deposits range between 5 and 15 git. At the current treatment rate, the proven reserves m the three locations will last about another 10 years. Early testwork indicated that the ore was not well suited to conventional filtration processing or to heap leaching because of its high cfay content, and that carbon-m-pulp (CIP) would probably prove to be the most viable metallurgical route. Tcstwork to establish the feasibility of CIP for this application was carried out at Mintek in 1985. This worl<, which was based on batch-leaching and carbon-loading tests, indicated that CIP was technically feasible, but that both the rate of gold loading and the gold-loading capacity of the carbon were inferior to those obtained with Witwatersrand ores. The poor adsorption characteristics of the carbon were attributed to the abnormally high concentration of natural organic compounds (humates and fulvates) in the ore. Batch tests were therefore also carried out with strong-base resins, since resins are known (1] to be far less susceptible to organic fouling than is activated carbon. The results were very promising, and pointed to fast kinetics and a high loading capacity. (Fig. 1 ). Notwithstanding these findings, it was decided to recover gold with activated carbon at Golden Jubilee Mine because the CIP process was, by then, well established in South Africa and elsewhere in the world, whereas resin-in-pulp (RIP) was unproven technology. The r>lant was commissioned in September 1986 and, for 18 months, operated in a carbon-in-leach (CIL) configuration, i.e. with a total of . six leach tanks, the last four of which contained activated carbon. As could have been predicted from the laboratory results, the performance of the CIL plant was generally poor, low gold loadings on the carbon (less than 1500 git) and high losses of soluble gold (0.2 to 0.3 p.p.m.) bemg characteristic of the operation. Consequently, it

Jan 1, 1990

By Kurt O'Bryan, Gary Beerkircher

WaterFlush Technology offers maximum comminution performance benefits over to­day's more common comminution methods. These benefits will be presented with case studies of existing installations, and the projected performance gains for circuits scheduled to begin operation in 1992.

Jan 1, 1992

By Chris Joyce, Peter Ryan

Investigation of the occurrence and significance of acid drainage from mine sites in Australia has received a degree of attention in recent years. For contemporary and future projects, particularly those in hi1;1her rainfall areas, the focus on prediction and resolution of acid drainage issues is. likely to increase. This paper describes the preventative and remedial measures adopted at three metalliferous mines in northern Australia at which acid drainage was identified as a key issue with respect to project environmental management and rehabilitation. The thre case studies respectively comprise an active, ·1 recently decommissioned and an abandoned operatiou which was rehabilitated in the mid '80s.

Jan 1, 1991

By D. A. Baker, W. J. Mullin, T. P. Philip, P. A. Korpi

Some of you will recall from the last Randol conference held in Cairns, Australia in April 1991 that I shot my mouth off when I declared that I believe that these conferences are covering only a small slice of the overall mining industry pie because the major emphasis is on ore processing. The attendees at these conferences to date have been composed principally of metallurgists, which naturally leads to a preponderance of papers on this important feature, but it is only one of the areas of the mining business.

Jan 1, 1992

By Walter Hoecker

The dissolution of gold in cyanide_ leaching has been we11 published with the genera1 acceptance that gold is oxidised by oxygen and stabilized by complexation with cyanide [1]. The dissolution of gold is essentially an electrochemical process. The rate of the anodic gold dissolution is controlled by the cyanide concentration. - (2) While the cathode reduction of oxygen is controlled by dissolved oxygen concentration - (3) There are a number of factors influencing the concentration of oxygen, and if 1owered substanth.lly will effect the efficiency of the leaching plant. These include: "' salinity "' temperature "'partial pressure "'oxygen consumption rate The use of pure oxygen for· cyanidation is only beneficial if oxygen is rate limiting, Conversely a slurry saturated with air (typically 5 - 8 ppm) may not be enough for maximum leach rate. The diagram below shows the maximum dissolved oxygen levels obtainable with pure oxygen and air. DISSOLVED OXYGEN (MAXIMUM) IN WATER At steady state, the rate of the cathodic reaction must equal the rate of the anodic reaction. Thus the rate of gold dissolution is dependent on both the· cyanide and oxygen concentrations. - (4) Using an average of Do/Den =· 1.5 [2] (where Do and Den are the oxygen and cyanide diffusion coefficients) the table below illustrates the maximum effective oxygen concentrations for given cyanide levels in clean water [3].

Jan 1, 1992

By Cao Changlin, Gong Qian, Hu Jiexue

The thiosulfate, effects copper of concentrations of and ammonia ou the extractlon of gold from sulfide gold concentrate have been studied. The experimental results showed that it is possible to reduce thiosulfate concentration. Above 95% of gold extraction was obtained in O. 2M thiosulfate leaching solution in two hours under the suitable conditions. Therefore, the process of washing residue was simplified, the consumption of thiosulfate and the loss of thiosulfate carried were reduced. by washing residued.

Jan 1, 1992

By Keith Sarbutt, I. Jackman

The recovery of gold from a high grade telluride/sulphide flotation concentrate was investigated. Conventional cyanidation resulted in very slow rates of gold extraction. Historically, the refractory nature of tellurides has been overcome by fine grinding, the use of excess lime and long leach times. In some instances, pre­oxidation of the tellurides has also been necessary, to render the gold soluble in cyanide solutions. The former conditions did improve the rate of gold extraction from the present sample, but final recovery was still unacceptable. Chemical oxidation of the tellurides and leaching with oxygen improved gold recovery further. However, it was found that simple modifications to the cyanidation conditions overcame the detrimental effects of the complex chemistry involved in leaching a telluride concentrate. The incorporation of a solution change, or the application of a carbon-in-leach procedure increased the recovery of gold to over 97 percent in 96 hours. In every case, leaching was enhanced by the addition of lead salts.

Jan 1, 1990

By H. D. R. Browner, D. A. Marsh

The need for a product dewatering step between the milling/classification and leach/carbon stages of gold plants has traditionally been performed by thickeners. Whether these be the 'conventional' or 'high-rate' types both require considerable initial capital outlay even without provision for standby facilities. In addition, their sensitivity (both mechanically and metallurgically) to changing feed conditions often results in these being considered 'high-risk' items of equipment, requiring a high degree of attention from operating personnel.

Jan 1, 1992

By William R. Bond, Jim V. Rouse, Laura L. Damon

As noted by Damon (1990), "The time that a heap (of gold ore) is on the reusable leach pad is of critical economic importance." The Interim Neutralization Study, conducted by Brohm Mining Corporation (Brohm), at the request of the South Dakota Department of Water and Natural Resources and reported by Damon indicated that improvements could be made in leaching and pointed out the need for a better understanding of the gold ore leach procedures. To provide data on an actual heap, personnel from Brohm and GEOCHEM installed a series of pressure/vacuum lysimeters in an active Brohm heap, and conducted subsequent testwork to evaluate the efficiency of leaching. The objectives of the testwork included efforts to:

Jan 1, 1992

By Alan Fricker, Bill Owers

Cyprus Gold NZ Ltd will be recovering residual cyanide from their CIT, operation in New Zealand. The process will use air to strip the cyanide from the acidified barren pulp. DSffi. Industrial Development, who were involved in the bench and pilot studies for Cyprus, have extended the concept to pregnant pulp. The stripping of pregnant pulp eliminates the substantial loss of cyanide through carbon catalysed oxidation during the adsorption stage. A 50% increase in cyanide recovery was obtained from an extensive laboratory investigation. The presence of a cyanide recovery circuit enables leaching to be conducted, without detriment, at pHs at least as low as 9, with consequential 50% reductions in the consumption of lime and sulphuric acid. There should be a small reduction in carbon consumption, and a significant improvement in the quality of the final effiuent, at least in terms of cyanide, cyanates, copper, zinc and sulphur. A small but significant increase in gold recovery can be expected too. There is a net economic advantage of NZ$1.20/tonne of ore by stripping pregnant rather than barren pulp.

Jan 1, 1990

By Abbas Zaidi, Betty L. W. Ou

Wastewaters generated during the extraction of gold from the ore can contain a variety of contaminants such as cyanide, heavy metals and arsenic. Proper management of these wastewaters is therefore necessary to minimize the negative impact of gold mining and milling operations on the environment. The Wastewater Technology Centre (WTC),located in Burlington, Ontario, Canada, has been involved in several studies related to the evaluation of various effluent treatment technologies which are relevant to the treatment and proper management of gold mill effluents. These studies have included bench and pilot scale tests, and the evaluation offull-scale systems. Furthermore, the WTC staff developed protocols for cyanide analysis in gold mill effluents, and a mathematical model for predicting the degradation of cyanide in tailings ponds. The information generated by the WTC staff has been referenced in several reports and papers published over the last ten years (Schmidt et.al. 1982, Simovic & Snodgrass 1989, Whittle et.al. 1989, Zaidi et.al. 1989, Zaidi et.al. 1991). Recently, the WTC has started to develop a micro­computer based expert system for use by decision makers in the gold mining industry and relevant government agencies who are involved in process design, process evaluation, costing, evaluation of the best practicable technology, approval of suggested effluent management systems, and so on. This paper presents some relevant background information and a discussion of the latest version of the expert system being developed by the WTC.

Jan 1, 1992

By Barry J. Hansen

Mining can make two major contributions to the cleanup of the environment. The first of these is the extractive technology that has become highly developed as a result of centuries of development. Of equal impor­tance are the methodology of analysis and the development of engineering solutions that are the stock in trade of the mining industry. Despite the differences between the industries, the processes for the development of a mine and the cleanup of a hazardous waste site are similar. The characteristics that impact the ability to develop a suitable process for treating an ore body or correct­ing an environmental problem are those relat­ed to the distribution of the contaminant or metal in the host material.

Jan 1, 1991

By Frank Ladwig, Stephen Gos

Tailings and/or wastewater generated from gold extraction plants employing cyanida­ tion must often be treated to remove the cyanides and heavy metals for environmental reasons and/or gold extraction inhibition reasons, due to the presence of heavy metals like copper, which have a detrimen­ tal effect during cyanidation. In recent years, the treatment of effluents contain­ ing cyanides and heavy metals has been widely studied, Among chemical treatment methods, the use of hydrogen peroxide has been universally employed as a viable option. However, in some cases, effluents containing high concentrations of heavy metals and/or solids decompose the hydrogen peroxide, an undesirable side reaction. The addition of stabilizers or other peroxygen compounds together with hydrogen peroxide can, however, considerably reduce the rate of decomposition and thus result in detoxi­ fication costs, which are considerably less than the standard detoxification process using hydrogen peroxide. In some cases, the reaction rate can also be increased, resul­ ting in lower investment costs for new detoxification plants. This paper deals with the results of developmental work performed in the recent past and introduces some new processes with the aim of optimizing reagent consumption and costs.

Jan 1, 1992

By W. Hoecker, S. Watson

The use of oxygen (Goldox™) in gold leaching has emerged as a significant modification in the past nine years. The Goldox™ process was ori gi na 11 y developed by Afrox Ltd ( part of the BOC Group) and is currently used in South Africa, Australia, Canada and the United States. Although a variety of benefits have been observed with oxygen, this paper out 1 i nes the main ones with reference to Australian plant data. The case studies were categorised into the ore type: Oxide, blends and primary ore.

Jan 1, 1992

By Hans von Michaelis

Metallurgists are trained to seek synergisms and to optimize trade-offs in the selection of processes and flowsheets. The subject of my paper and the focus of this entire conference is on synergisms involving more than just metallurgical recovery, but encompassing mining and environmental management too. Operators have always known that by recycling tailings water they could recover some cyanide and lime values or reduce the amount of new flotation reagent additions. The trade-offs have changed at many US mines today where concern about avian mortality necessitates that water in the tailings pond be detoxified. This is just one example of how selection of processes and technology today requires integration of environmental management. MUDDER & GOLDSTONE (1989) showed how cyanide can be recovered from tailings slurries by an acidification­volatilization-reabsorption (A VR) process which was installed in New Zealand, and which in 1992 is being commissioned also at Nerco DeLamar Silver Mine as described by OMOFOMA & HAMPDEN (1992). FRICKER (1990) and FRICKER & OWERS (1992) show how using A VR to recover cyanide from pregnant pulps ahead of gold recovery improves the yield of recoverable cyanide while improving the performance of the gold recovery step and detoxifying the tailings. This is an excellent example of the synergisms that can be achieved ,y applying a "systems approach."

Jan 1, 1992

By Ulf Marklund, Manfred Lindvall

Fighting the challenge of diminishing ore grades, low base metal prices and a changing pattern of ore supply, Boliden has now taken the second generation of the fully­autogenous grinding concept on stream, Using new design and a highly-developed process control system the benefits of conventional two stage autogenous grinding technology are obtained with a wide range of ore types. The APC grinding system has been developed further. A new design of the Boliden Pebble Extractor together with an advanced control strategy make the performance of the APC concept superior to all other grinding systems with any ore quality. The capacity and simplicity of the autogenous grinding concept is equivalent to the best SAG installations but the operational costs are up to 25 % lower than for SAG or other primary ball or rod mill systems. The concept is as flexible as conventional crushing and rod mill installations but investment and operating costs are of the order of 25 % lower. Also, from the metallurgical point of view, the different types of autogenous grinding system outperform all other comminution systems including SAG. From 1989 to 1991 four fully autogenous grinding sections have been installed at various concentrators at the Boliden company. Old crushing plants and rod and pebble grinding circuits have finally been replaced by highly productive and cost-efficient autogenous grinding equipment. Significant savings in operational costs have already been reported. Power consumption and maintenance costs have been reduced significantly. Productivity expressed as milled tonnes per operator has been improved. Metallurgical results have developed favourably.

Jan 1, 1992

By Marshall A. Koval

The future of mining in the United States is in question. The cumulative effects of federal, state and local environmental legislation threaten its survival as the cost of compliance skyrockets. Legislation has created pol ari zat ion between government and industry followed by court action, further increasing costs and delays on permitting and remediations. Regulations often call for excessive and rigid requirements that result in unrealistic compliance goals costing tens of millions of dollars. The costs often exceed the value of the remedy. A growing concern is that proper scientific methodologies and engineering practices are being sacrificed because of political and public pressures.

Jan 1, 1991